CN1283661A - White starch emulsoid - Google Patents
White starch emulsoid Download PDFInfo
- Publication number
- CN1283661A CN1283661A CN 99111765 CN99111765A CN1283661A CN 1283661 A CN1283661 A CN 1283661A CN 99111765 CN99111765 CN 99111765 CN 99111765 A CN99111765 A CN 99111765A CN 1283661 A CN1283661 A CN 1283661A
- Authority
- CN
- China
- Prior art keywords
- starch
- emulsoid
- white
- polyvinyl alcohol
- formaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002472 Starch Polymers 0.000 title claims abstract description 31
- 235000019698 starch Nutrition 0.000 title claims abstract description 31
- 239000008107 starch Substances 0.000 title claims abstract description 31
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 21
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 21
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 11
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 15
- 239000003292 glue Substances 0.000 claims description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 12
- 229920002554 vinyl polymer Polymers 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 5
- 235000011837 pasties Nutrition 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 229920001592 potato starch Polymers 0.000 claims description 3
- 244000017020 Ipomoea batatas Species 0.000 claims description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 235000021374 legumes Nutrition 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 5
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 238000009413 insulation Methods 0.000 description 4
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- -1 Dichlorodiphenyl Acetate ethene Chemical compound 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 240000006677 Vicia faba Species 0.000 description 1
- 235000010749 Vicia faba Nutrition 0.000 description 1
- 235000002098 Vicia faba var. major Nutrition 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000004523 agglutinating effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
A white starch emulsoid is prepared from starch, polyvinyl alcohol, polyvinyl acetate, formaldehyde, hydrochloric acid and water. Its advantages include short drying time, no environmental pollution, natural decomposing and high adhesion.
Description
The present invention is the white glue with vinyl in a kind of tackiness agent.
Traditional Virgin's milk is pure chemistry product preparations, though can satisfy the agglutinating needs, its rate of drying is relatively slow, and the raw materials cost height has certain pollution to environment, to human body and certain irritating smell infringement.
Purpose of the present invention will provide a kind of time of drying short exactly, and cost is low, and is free from environmental pollution, human body do not produced the white glue with vinyl of pungent odour.
Content of the present invention is such, by starch 10～27%, and polyvinyl alcohol 20～37%, polyvinyl acetate emulsion content 10～18%, formaldehyde 1～3%, hydrochloric acid 1～3% water 12～58% is formed.Its production method is that polyvinyl alcohol is added water 95～100 ℃ of time dissolvings 3～6 hours of heating, put into a certain amount of hydrochloric acid and formaldehyde, when making dissolving polyvinyl alcohol solution well be cooled to 90 ℃, the starch that will be diluted to pasty state lentamente in advance joins in the polyvinyl alcohol solution, and insulation mixed 30 minutes, put into polyvinyl acetate emulsion when cooling to 60～70 ℃ again, stir and got the W-Gum white glue with vinyl in 2 hours.And described starch can use corn, beans, potato class (as potato, sweet potato etc.) or other crop starch.
Effect of the present invention is such, owing to added W-Gum or other starch, the consumption of chemical feedstocks reduces, and cost is significantly reduced, 1/5th of the former approximately white glue with vinyl of cost, and, owing to directly do not use vinyl acetate between to for plastic, reduced production cost, do not need reactor Dichlorodiphenyl Acetate ethene to carry out polymerization in the production, reduce equipment, thereby reduced the equipment input.On the other hand, traditional about 8 hours of time of drying of white glue with vinyl or longer, and about 7～7.5 hours of the time of drying of white glue with vinyl of the present invention shortened about 30 minutes than traditional white glue with vinyl, and white glue with vinyl of the present invention contains organism, after abandoning as waste, in soil, can be absorbed degraded by microorganism, free from environmental pollution, once synthetic aborning, no waste is got rid of, and also produce irritating smell during use hardly, and its cohesive force to timber, laminate, fiberboard etc. is identical with traditional white glue with vinyl.In addition, white glue with vinyl of the present invention does not freeze in the time of 0～5 ℃.
Embodiment 1, a kind of white starch emulsoid, by W-Gum 22%, polyvinyl alcohol 30%, polyvinyl acetate emulsion content 15%, formaldehyde 2%, hydrochloric acid 2%, water 29% is formed.Its production method is polyvinyl alcohol to be added water heat 98 ℃ and dissolved 5 hours, put into a certain amount of hydrochloric acid and formaldehyde, when making dissolving polyvinyl alcohol solution well be cooled to 90 ℃, the starch that will be diluted to pasty state (being as the criterion to hang hand) lentamente in advance joins in the polyvinyl alcohol solution, and insulation mixed 30 minutes, put into polyvinyl acetate emulsion when cooling to 65 ℃ again, stir and got white starch emulsoid in 2 hours.
Embodiment 2, a kind of white starch emulsoid, by potato starch 18%, polyvinyl alcohol 25%, polyvinyl acetate emulsion content 16%, formaldehyde 1.8%, hydrochloric acid 2%, water 37.2% is formed.Its production method is polyvinyl alcohol to be added water heat 97 ℃ and dissolved 4 hours, put into a certain amount of hydrochloric acid and formaldehyde, when making dissolving polyvinyl alcohol solution well be cooled to 90 ℃, the starch that will be diluted to pasty state (furnishing is hung the paste of hand) lentamente in advance joins in the polyvinyl alcohol solution, and insulation mixed 30 minutes, put into polyvinyl acetate emulsion when cooling to 65 ℃ again, stir and got the W-Gum white glue with vinyl in 2 hours.
Embodiment 3, a kind of white starch emulsoid, by broad bean starch 10%, polyvinyl alcohol 20%, polyvinyl acetate emulsion content 10%, formaldehyde 1%, hydrochloric acid 1%, water 58% is formed.Its production method is polyvinyl alcohol to be added water heat 98 ℃ and dissolved 5 hours, put into a certain amount of hydrochloric acid and formaldehyde, when making dissolving polyvinyl alcohol solution well be cooled to 90 ℃, the starch that will be diluted to pasty state (being as the criterion to hang hand) lentamente in advance joins in the polyvinyl alcohol solution, and insulation mixed 30 minutes, put into polyvinyl acetate emulsion when cooling to 65 ℃ again, stir and got white starch emulsoid in 2 hours.
Claims (6)
1, a kind of white starch emulsoid, by starch 10～27%, polyvinyl alcohol 20～37%, polyvinyl acetate emulsion content 10～18%, formaldehyde 1～3%, hydrochloric acid 1～3%, water 12～58% is formed.
2, a kind of production method of white starch emulsoid as claimed in claim 1, it is characterized in that polyvinyl alcohol is added water 95～100 ℃ of time dissolvings 3～6 hours of heating, put into a certain amount of hydrochloric acid and formaldehyde, when making dissolving polyvinyl alcohol solution well be cooled to 90 ℃, the starch that will be diluted to pasty state lentamente in advance joins in the polyvinyl alcohol solution, and be incubated mixing 22～38 minutes, and put into polyvinyl acetate emulsion when cooling to 60～70 ℃ again, stir and got the W-Gum white glue with vinyl in 2 hours.
3, white starch emulsoid as claimed in claim 1 is characterized in that described starch is W-Gum.
4, white starch emulsoid as claimed in claim 1 is characterized in that described starch is potato starch.
5, white starch emulsoid as claimed in claim 1 is characterized in that described starch is sweet potato starch.
6, white starch emulsoid as claimed in claim 1 is characterized in that described starch is legume starch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99111765 CN1283661A (en) | 1999-08-05 | 1999-08-05 | White starch emulsoid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99111765 CN1283661A (en) | 1999-08-05 | 1999-08-05 | White starch emulsoid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1283661A true CN1283661A (en) | 2001-02-14 |
Family
ID=5275287
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99111765 Pending CN1283661A (en) | 1999-08-05 | 1999-08-05 | White starch emulsoid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1283661A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101058701B (en) * | 2007-05-30 | 2010-05-26 | 陈峰磊 | Water soluble adhesive |
| CN101208400B (en) * | 2005-07-01 | 2011-05-25 | 阿克佐诺贝尔涂层国际有限公司 | Adhesive composition and method |
| CN102234494A (en) * | 2010-04-21 | 2011-11-09 | 王钱生 | Preparation method of water-resistant plant adhesive |
| CN102936472A (en) * | 2012-12-05 | 2013-02-20 | 湖南神力铃胶粘剂制造有限公司 | Preparation method of novel waterproof quick-drying and freeze-proofing white emulsion |
| CN110330916A (en) * | 2019-06-13 | 2019-10-15 | 浙江安吉朝辉新材料有限公司 | A kind of high-viscosity glue |
| CN113025764A (en) * | 2021-02-01 | 2021-06-25 | 惠东伟品综合制品有限公司 | Leather and repairing method thereof |
-
1999
- 1999-08-05 CN CN 99111765 patent/CN1283661A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101208400B (en) * | 2005-07-01 | 2011-05-25 | 阿克佐诺贝尔涂层国际有限公司 | Adhesive composition and method |
| CN101058701B (en) * | 2007-05-30 | 2010-05-26 | 陈峰磊 | Water soluble adhesive |
| CN102234494A (en) * | 2010-04-21 | 2011-11-09 | 王钱生 | Preparation method of water-resistant plant adhesive |
| CN102936472A (en) * | 2012-12-05 | 2013-02-20 | 湖南神力铃胶粘剂制造有限公司 | Preparation method of novel waterproof quick-drying and freeze-proofing white emulsion |
| CN110330916A (en) * | 2019-06-13 | 2019-10-15 | 浙江安吉朝辉新材料有限公司 | A kind of high-viscosity glue |
| CN113025764A (en) * | 2021-02-01 | 2021-06-25 | 惠东伟品综合制品有限公司 | Leather and repairing method thereof |
| CN113025764B (en) * | 2021-02-01 | 2022-05-06 | 惠东伟品综合制品有限公司 | Leather and repairing method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |