CN1283581C - Method of producing mineral polymerized material using k-enriched rock - Google Patents
Method of producing mineral polymerized material using k-enriched rock Download PDFInfo
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- CN1283581C CN1283581C CNB031005624A CN03100562A CN1283581C CN 1283581 C CN1283581 C CN 1283581C CN B031005624 A CNB031005624 A CN B031005624A CN 03100562 A CN03100562 A CN 03100562A CN 1283581 C CN1283581 C CN 1283581C
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- potassium
- potassium feldspar
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- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 42
- 239000011707 mineral Substances 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 38
- 239000011435 rock Substances 0.000 title claims abstract description 15
- 239000000463 material Substances 0.000 title abstract description 41
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 44
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 38
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000011591 potassium Substances 0.000 claims abstract description 37
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 37
- 238000001354 calcination Methods 0.000 claims abstract description 31
- 239000002994 raw material Substances 0.000 claims abstract description 26
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 25
- 239000000843 powder Substances 0.000 claims abstract description 23
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 19
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 17
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 17
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 17
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 12
- 239000010881 fly ash Substances 0.000 claims abstract description 11
- 238000001914 filtration Methods 0.000 claims abstract description 8
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 7
- 239000003245 coal Substances 0.000 claims abstract description 6
- 239000002893 slag Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 4
- 230000020477 pH reduction Effects 0.000 claims abstract description 3
- 238000007711 solidification Methods 0.000 claims abstract description 3
- 230000008023 solidification Effects 0.000 claims abstract description 3
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract 17
- 239000002861 polymer material Substances 0.000 claims abstract 11
- 239000002440 industrial waste Substances 0.000 claims abstract 6
- 239000004615 ingredient Substances 0.000 claims abstract 6
- 238000002360 preparation method Methods 0.000 claims description 17
- 238000000227 grinding Methods 0.000 claims description 8
- 239000004570 mortar (masonry) Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000084 colloidal system Substances 0.000 claims description 2
- 239000010434 nepheline Substances 0.000 claims description 2
- 229910052664 nepheline Inorganic materials 0.000 claims description 2
- 239000010454 slate Substances 0.000 claims description 2
- 239000010435 syenite Substances 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- -1 pegmatite Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 10
- 238000000465 moulding Methods 0.000 abstract description 4
- 238000013461 design Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000001556 precipitation Methods 0.000 abstract 1
- 235000010755 mineral Nutrition 0.000 description 26
- 239000004576 sand Substances 0.000 description 15
- 235000017550 sodium carbonate Nutrition 0.000 description 13
- 235000015320 potassium carbonate Nutrition 0.000 description 11
- 229910000323 aluminium silicate Inorganic materials 0.000 description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 239000011449 brick Substances 0.000 description 6
- 239000002699 waste material Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 238000007906 compression Methods 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000012452 mother liquor Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000002910 solid waste Substances 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000010433 feldspar Substances 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 238000007599 discharging Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000013467 fragmentation Methods 0.000 description 2
- 238000006062 fragmentation reaction Methods 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 235000006481 Colocasia esculenta Nutrition 0.000 description 1
- 240000004270 Colocasia esculenta var. antiquorum Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 208000034189 Sclerosis Diseases 0.000 description 1
- 230000004523 agglutinating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 229910001579 aluminosilicate mineral Inorganic materials 0.000 description 1
- 229940115440 aluminum sodium silicate Drugs 0.000 description 1
- SXQXMCWCWVCFPC-UHFFFAOYSA-N aluminum;potassium;dioxido(oxo)silane Chemical compound [Al+3].[K+].[O-][Si]([O-])=O.[O-][Si]([O-])=O SXQXMCWCWVCFPC-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000010891 toxic waste Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/041—Aluminium silicates other than clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Processing Of Solid Wastes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
一种利用钾长石生产矿物聚合材料的方法。该方法是将富钾岩石经破碎、选矿，得到以钾长石为主要物相的粉体。用该粉体与碳酸钠或碳酸钾混合后，在700℃-850℃下煅烧，将熟料粉体与水按1∶4-12的重量比搅拌混合成胶体溶液，再通入CO2进行酸化中和反应，形成偏铝硅酸盐沉淀，经过滤后与高浓度氢氧化钠或氢氧化钾溶液均匀混合，形成偏铝硅酸盐溶胶，再与粉煤灰、高炉炉渣、煤矸石、矿山尾矿等工业废渣和少量高岭土配料混合，经搅拌、成型、固化，即制得矿物聚合材料。过滤得到的澄清含钾溶液可用于制备优等纯碳酸钠和电子级碳酸钾。本发明工艺设计合理，工艺流程简单，生产成本低廉，生产过程符合“清洁生产”的环保要求，原料来源广泛，便于实施推广。
A method for producing mineral polymeric materials from potassium feldspar. In the method, the potassium-rich rock is crushed and beneficiated to obtain a powder with potassium feldspar as the main phase. After mixing the powder with sodium carbonate or potassium carbonate, calcining at 700°C-850°C, stirring and mixing the clinker powder and water at a weight ratio of 1:4-12 to form a colloidal solution, and then injecting CO2 for Acidification and neutralization reaction to form metaaluminosilicate precipitation, which is filtered and evenly mixed with high-concentration sodium hydroxide or potassium hydroxide solution to form metaaluminosilicate sol, and then mixed with fly ash, blast furnace slag, coal gangue, Mine tailings and other industrial waste residues are mixed with a small amount of kaolin ingredients, and after stirring, molding and solidification, mineral polymer materials are obtained. The clear potassium-containing solution obtained by filtration can be used to prepare superior pure sodium carbonate and electronic grade potassium carbonate. The invention has reasonable process design, simple process flow, low production cost, the production process conforms to the environmental protection requirement of "clean production", wide source of raw materials, and is convenient for implementation and popularization.
Description
Technical field
The present invention relates to a kind of method of utilizing potassium felspar sand to produce mineral polymeric material.
Background technology
Mineral polymeric material is the class novel inorganic non-metallic material that new development is in recent years got up.This class material is many to be main raw material with industrial solid wastes or natural aluminium silicate mineral, behind kaolin and appropriate bases silicate solutions thorough mixing, in the cold condition compacted under sclerosis of room temperature to 120 ℃, be that a class is by aluminosilicate gelling composition agglutinating chemical bond stupalith.Because external preparation mineral polymeric material is outside the main raw material divided by industrial solid wastes or aluminosilicate mineral products, batching also needs kaolin (about 1/3), industrial metasilicate (potassium) water glass and sodium hydroxide (potassium).Thereby cost is higher, is difficult for implementing to promote.
Summary of the invention
The purpose of this invention is to provide a kind of method of utilizing potassium felspar sand to produce mineral polymeric material.Technological design of the present invention is reasonable, and technical process is simple, does not have " three wastes " discharging, and with low cost, raw material sources are extensive, are convenient to promotion and implementation.
For achieving the above object, the present invention takes following technical scheme:
A kind of processing method of utilizing potassium felspar sand to produce mineral polymeric material, this method comprises the steps:
(1) raw material calcining step: with potassium felspar sand powder and yellow soda ash or salt of wormwood by 1: grinding behind the parts by weight uniform mixing of 0.8-1.6, in calcining furnace, under 700 ℃ of-850 ℃ of conditions, calcine, calcination time is 0.5h at least;
(2) preparation colloidal sol step: grog powder after will calcining and water are by 1: the parts by weight of 4-12 place reactor fully to mix, and feed CO
2Carry out acidifying neutralization, when the pH value of solution be 8-9 till, filtration obtains the sal filter residue then, adding sodium hydroxide or potassium hydroxide solution in this filter residue, and fully stir promptly make a kind of inclined to one side aluminosilicate colloidal sol;
(3) batch mixes step: with kaolin and industrial residue grinding, stir after, add in the above-mentioned inclined to one side aluminosilicate colloidal sol, stir, promptly make mixed mortar, form mineral polymeric material after the curing.
The present invention adopts feldspar in powder and Na
2CO
3Mix, through medium temperature roast, reaction product is NaAlO
2, KAlO
2, Na
2SiO
3, prepare the essential composition of mineral polymeric material just, can be in order to replace most of kaolin, water glass (potassium) water glass and sodium hydroxide (potassium).Adopt the mineral polymeric material of method preparation of the present invention.Compare with the technology of external preparation same type of material, its main improvements are, carry sal waste residue behind the potassium with feldspar in powder or potassium rich rock and replace industrial metasilicate and most of kaolin, sodium hydroxide, thereby make the production cost of material further reduce about 25～35%.
In the raw material calcining step in the present invention, described calcination time is preferably 0.5-1.5h.
In the raw material calcining step in the present invention, described potassium felspar sand powder makes from potassium rich rock, potassium rich rock is the various rocks that are rich in potassium felspar sand, comprises in potassium felspar sand rock, rich potassium volcanics, nepheline syenite, pegmatite, rich potassium shale and the k-rich slate one or more.Potassium rich rock adopts method ore dressings such as ordinary method such as gravity treatment through fragmentation, obtains the powder of potassium felspar sand content＞80%, and requiring powder granularity is-200 orders.
In the raw material calcining step in the present invention, yellow soda ash or salt of wormwood are technical grade yellow soda ash or salt of wormwood.The water that uses is ordinary tap water.
In the raw material calcining step in the present invention, the granularity of potassium felspar sand powder and yellow soda ash or salt of wormwood grinding is-200 orders.
In the batch mixes step in the present invention, described kaolin is to add in the above-mentioned inclined to one side aluminosilicate colloidal sol than the weight ratio for 3-5 according to solid-liquid with the industrial residue grinding.
In the batch mixes step in the present invention, kaolin is 1 with the ratio of the parts by weight of industrial residue: 3-6.
In the batch mixes step in the present invention, industrial residue is one or more in flyash, blast-furnace slag, coal gangue and the mill tailings.
In the batch mixes step in the present invention, the grain diameter of kaolin and industrial residue is 50-200 μ m.
In the preparation colloidal sol step in the present invention, sodium hydroxide or potassium hydroxide solution concentration are generally 9-11M, and the weight ratio of sodium hydroxide or potassium hydroxide and filtration gained sal filter residue is 1: 4-8, the two mixes pH value 〉=14 of the prepared colloidal solution in back.In the step of above-mentioned preparation colloidal sol, when preparing inclined to one side aluminosilicate colloidal sol, in the sal filter residue, add high-concentration sodium hydroxide or potassium hydroxide solution; Correspondingly can make inclined to one side sodium aluminium silicate or inclined to one side aluminum potassium silicate colloidal sol.These two kinds of colloidal sols are respectively applied for produces the mineral polymeric material goods with different physicochemical properties.
In the solidification process of batch mixes step in the present invention, can be in mould packing compact forming, leave standstill curing.Its packing compact forming operation: mixed mortar is mixed the mould that thing places required different size, and shaken and smash or slight extrusion forming, to improve the degree of compactness of sample.It leaves standstill curing process: said sample is placed maintenance 72h under room temperature to the 60 ℃ condition.Place room temperature, atmospheric environment spontaneous curing a couple of days after the sample demoulding again, promptly make the mineral polymeric material finished product.In above-mentioned packing compact forming operation, can described mineral polymeric material be made amorphous material according to the needs of reality use, smash moulding in practice of construction cast in situs, shake.
In the preparation colloidal sol step in the present invention, the grog powder add in water extraction, the acidifying and after, filtration obtains the sal filter residue, and filter the settled solution (containing the potassium mother liquor) that obtains is the mixing solutions of a kind of sodium bicarbonate and saleratus, can adopt the conventional chemical method and apparatus, through evaporation, crystallization, separation, drying, produce excellent pure yellow soda ash and election class potassium carbonate.Yellow soda ash can return the raw material calcination stage, recycles.
The mineral polymeric material of method preparation of the present invention, main raw material adopts the sal waste residue and the industrial residue that includes flyash, blast-furnace slag, coal gangue, mill tailings etc. after potassium rich rock extracts salt of wormwood, and a spot of sodium hydroxide or potassium hydroxide (≤6%) and kaolin (≤15%).Make feldspar in powder by potassium rich rock, obtain the roasting grog through medium temperature roast.
Advantage of the present invention is: the present invention utilizes potassium felspar sand powder and yellow soda ash or salt of wormwood for the grog of batching after calcining, and as the main raw material of preparation mineral polymeric material, and obtains being rich in Na by the leaching liquid acidification step of calcination of chamotte
2O or K
2The mother liquor of O.Technological design of the present invention is reasonable, technical process simple, do not have " three wastes " discharging, meets energy-efficient and environmental requirement " cleaner production ".Product-mineral polymeric material of the present invention can be used as building structural materials, replaces common brick and cement products; Or as the fixed sealing material of toxic compounds or atomic waste; Also can be used as structure unit and moulding stock, various anticorrosives etc.Byproduct---contain Na
2O or K
2The mother liquor of O can be produced yellow soda ash and salt of wormwood product through evaporation, crystallization, separation, drying, recycles as calcining raw materials.Raw material sources of the present invention are extensive, and technical process is short, and product cost is low, the economic benefit height, and the payback period is short, is convenient to implement to promote.
Description of drawings
Fig. 1 is the process flow sheet that utilizes potassium felspar sand to produce mineral polymeric material of the present invention.
Embodiment
As shown in Figure 1, raw material is a potassium rich rock, after fragmentation, ore dressing, obtains being rich in the powder of potassium felspar sand.Batching is yellow soda ash or salt of wormwood.Enter in the calcining furnace behind potassium felspar sand powder and the batching thorough mixing and calcine.Grog powder after the calcining adds suitable quantity of water, and fully stirs, and feeds CO simultaneously
2Carry out the acidifying neutralization.The sal filter residue that filtration obtains mixes mutually with sodium hydroxide or potassium hydroxide solution again, through fully stirring, promptly makes a kind of inclined to one side aluminosilicate colloidal sol.Industrial residues such as the flyash of this colloidal sol and certain proportioning, blast-furnace slag, coal gangue, mill tailings are mixed mutually, obtain mixed mortar after fully stirring, moulding is placed under the environment of room temperature to 60 ℃ and left standstill 3-7 days, promptly makes novel inorganic non-metallic material---mineral polymeric material.The mother liquor that filtration obtains can be made into yellow soda ash and salt of wormwood product through evaporation, crystallization, separation, drying.What produced in raw material calcination process and the carbonate drying process contains CO
2Tail gas can recycle, be used for acidifying to the grog leaching liquid.Byproduct yellow soda ash and salt of wormwood can be used as the calcining batching, recycle.
Embodiment 1
As shown in Figure 1, will contain potassium felspar sand＞80% powder, and require grinding to-200 orders, mix by 1: 1.2 weight ratio with yellow soda ash or salt of wormwood, calcine in calcining furnace, the incinerating temperature is 800 ℃, calcination time is 1h, obtains canescence to light green half sintered clinker.Meanwhile, be located at the gas concentration unit of calcining furnace top, with the CO that contains that produces in the calcination process
2Tail gas recycle, and by recycling after the washing tower udst separation.
Above-mentioned grog mixes with water in reactor according to 1: 10 weight ratio behind grinding again, and fully stirs, and feeds CO simultaneously
2Carry out acidifying, to the pH value of solution be till 8 o'clock, filter then.Sodium hydroxide or potassium hydroxide solution with 10M mixes according to 1: 6 weight ratio mutually with the sal filter residue that filtration obtains again, promptly obtains a kind of inclined to one side aluminosilicate colloidal sol after fully stirring.
Kaolin and the weight ratio batching of the mill tailings industrial residue that contains flyash, blast-furnace slag, coal gangue according to 1: 4 are placed in the ball mill, and grinding to grain diameter is 50-100 μ m; Then this particulate material is placed stirrer, be 4: 1 the above-mentioned inclined to one side aluminosilicate colloidal sol of weight ratio adding according to the solid-liquid ratio, and stir, promptly make mixed mortar.
This mixed mortar is mixed thing place mould, and shaken and smash or slight extrusion forming, to improve the degree of compactness of sample.The sample for preparing is placed maintenance 72h under room temperature to the 60 ℃ condition.Place room temperature, atmospheric environment spontaneous curing a couple of days after the sample demoulding again, promptly make the mineral polymeric material finished product.
Embodiment 2
In embodiment 2, burning prepares burden prepares the sal filter residue as being equipped with to have adopted yellow soda ash in the sinter process; In the step of preparation colloidal sol, when preparing inclined to one side aluminosilicate colloidal sol, in the sal filter residue, add high-concentration sodium hydroxide solution; In the batch mixes step, kaolin and flyash are prepared burden according to 1: 4 weight ratio.Except that above-mentioned condition, remaining processing parameter is identical with embodiment 1.Adopting above-mentioned sal colloid waste residue and flyash is main raw material, and the physicochemical property of the mineral polymeric material of preparation is as follows:
Ultimate compression strength: 40～56MPa (fired common brick select quality: 19.62MPa; GB5101-85)
Acid resistance: 94.31～99.997% (quality standards of acid resisting brick: 〉=99.80WB%; GB8488-87)
Alkali resistance: 99.92～99.994% (quality standards of glass Mosaic: 〉=99.88WB%; GB7697-89)
Volume density: 1.6～1.8g/cm
3(heavy-load bearing brick density for building: 1.8～2.0g/cm
3)
Thermal conductivity: about 0.08～0.8W/m ℃
Water-intake rate: 6.0～16.0% (water-intake rates of excellent vitrified brick: be not more than 25%; GB/T2542-92)
Mohs hardness: be about 4.5～6.0
Mineral polymeric material of the present invention is a kind of novel inorganic non-metallic material, and China does not still have corresponding national standards to its specification of quality at present.According to its function and purposes, can only roughly compare with fired common brick.Mineral polymeric material is the novel building structured material that utilizes a kind of less energy-consumption of industrial solid wastes preparation in a large number, have excellent performance, and preparation technology is simple relatively, thereby has favorable actual application prospect.
Mineral polymeric material of the present invention has following major advantage:
1, compression strength is high. By the mineral polymeric material of mine solid waste preparation, compression strength reaches 40-56MPa, can satisfy the requirement of building structural materials fully. Adopt the mineral polymeric material of modified processing route technology preparation, compression strength can reach more than the 60MPa, thereby has more widely range of application.
2, has fire line. Raw materials is natural mineral raw, or various industrial residue or mill tailings, thereby material has good fire protecting performance.
3, raw material sources are wide, and are with low cost. Raw material can adopt various sa natural mineral raws or industrial residue, mill tailings, and wide material sources are with low cost.
4, curable toxic waste. Various industrial residues or mill tailings are made after the mineral polymeric material, and the poisonous element or the compound that wherein contain namely are cured in material internal. Because materials itself has the ability that very strong acid and alkali-resistance corrodes and weatherability changes, thereby can not cause new pollution to surrounding environment.
5, production technology is simple, and energy consumption is extremely low. The technological process of production is generally: material powder preparation → batching → injection molding or half dry-pressing formed → leave standstill curing → material product. The material cured temperature generally maintains room temperature to 60 and ℃ gets final product, thereby the energy consumption of its production process is extremely low.
Process of the present invention can consume flyash in a large number, and the consumption of flyash is up to 55～70% in the batching. Therefore, process of the present invention is a kind of a large amount of, low-cost manufacturing technique method that consumes flyash.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CNB031005624A CN1283581C (en) | 2003-01-17 | 2003-01-17 | Method of producing mineral polymerized material using k-enriched rock |
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| Application Number | Priority Date | Filing Date | Title |
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| CNB031005624A CN1283581C (en) | 2003-01-17 | 2003-01-17 | Method of producing mineral polymerized material using k-enriched rock |
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| CN1517321A CN1517321A (en) | 2004-08-04 |
| CN1283581C true CN1283581C (en) | 2006-11-08 |
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| CNB031005624A Expired - Lifetime CN1283581C (en) | 2003-01-17 | 2003-01-17 | Method of producing mineral polymerized material using k-enriched rock |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR074183A1 (en) * | 2008-10-29 | 2010-12-29 | Du Pont | TREATMENT OF WASTE CURRENTS |
| US20140065039A1 (en) * | 2010-11-26 | 2014-03-06 | Bogdan Z. Dlugogorski | Extraction of alkali metals and/or alkaline earth metals for use in carbon sequestration |
| CN102503440A (en) * | 2011-10-10 | 2012-06-20 | 山东硅元新型材料有限责任公司 | Method for producing ceramic products by utilizing Canada oil sand tailings |
| CN110548477B (en) * | 2018-05-30 | 2020-11-10 | 中国科学院过程工程研究所 | A kind of adsorption material and its preparation method and use |
| CN110092597B (en) * | 2019-05-21 | 2020-11-20 | 中国地质大学（北京） | A kind of geopolymer material, suitable retarder and high temperature resistant cement slurry prepared |
| CN117567133B (en) * | 2023-11-28 | 2024-11-19 | 萍乡市绿宝科技集团有限公司 | High-strength inner wall ceramic tile and preparation method thereof |
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2003
- 2003-01-17 CN CNB031005624A patent/CN1283581C/en not_active Expired - Lifetime
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| CN1517321A (en) | 2004-08-04 |
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