CN1278609C - Thiophthanate methyl water dispersible granular agent and its formula - Google Patents
Thiophthanate methyl water dispersible granular agent and its formula Download PDFInfo
- Publication number
- CN1278609C CN1278609C CN 200410026344 CN200410026344A CN1278609C CN 1278609 C CN1278609 C CN 1278609C CN 200410026344 CN200410026344 CN 200410026344 CN 200410026344 A CN200410026344 A CN 200410026344A CN 1278609 C CN1278609 C CN 1278609C
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- Prior art keywords
- sodium
- agent
- methyl
- thiophanate
- thiophthanate
- Prior art date
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 title abstract description 3
- 239000003795 chemical substances by application Substances 0.000 title abstract 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 5
- 239000000843 powder Substances 0.000 claims abstract description 30
- 239000011230 binding agent Substances 0.000 claims abstract description 14
- 239000000080 wetting agent Substances 0.000 claims abstract description 11
- 239000005842 Thiophanate-methyl Substances 0.000 claims description 30
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 claims description 30
- 239000004562 water dispersible granule Substances 0.000 claims description 19
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 15
- -1 polyoxyethylene formaldehyde Polymers 0.000 claims description 14
- 239000011734 sodium Substances 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 239000007884 disintegrant Substances 0.000 claims description 9
- 239000007859 condensation product Substances 0.000 claims description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 8
- 235000011152 sodium sulphate Nutrition 0.000 claims description 8
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 6
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 6
- 229920005610 lignin Polymers 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 3
- 229960000892 attapulgite Drugs 0.000 claims description 3
- 125000001924 fatty-acyl group Chemical group 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052625 palygorskite Inorganic materials 0.000 claims description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 239000004480 active ingredient Substances 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 230000001788 irregular Effects 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 239000000741 silica gel Substances 0.000 claims description 2
- 229910002027 silica gel Inorganic materials 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 238000005338 heat storage Methods 0.000 abstract description 10
- 239000000203 mixture Substances 0.000 abstract description 9
- 238000009472 formulation Methods 0.000 abstract description 6
- 238000002360 preparation method Methods 0.000 abstract description 6
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 5
- 239000000375 suspending agent Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 239000012752 auxiliary agent Substances 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 abstract 6
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 description 8
- 239000000428 dust Substances 0.000 description 7
- 238000005469 granulation Methods 0.000 description 7
- 230000003179 granulation Effects 0.000 description 7
- 238000007873 sieving Methods 0.000 description 7
- 244000141359 Malus pumila Species 0.000 description 6
- 235000011430 Malus pumila Nutrition 0.000 description 6
- 235000015103 Malus silvestris Nutrition 0.000 description 6
- 230000001133 acceleration Effects 0.000 description 6
- 239000000470 constituent Substances 0.000 description 6
- 230000035613 defoliation Effects 0.000 description 6
- 238000005187 foaming Methods 0.000 description 6
- 238000012216 screening Methods 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- 238000003912 environmental pollution Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000645 desinfectant Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000012395 formulation development Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses an agricultural use bactericide, particularly a thiophthanate-methyl water dispersion granular agent and a formulation. The thiophthanate methyl water dispersion granular agent of the present invention has regularly or irregularly granular shape, and the formulation comprises the components according to the percentage by weight: 40 to 80% of thiophthanate-methyl raw powder, 2 to 8% of wetting agent, 3 to 10% of dispersion agent, 3 to 8% of disintegrating agent, 5 to 40% of diluting agent and 2 to 10% of binding agent; the components in the formulation are mixed and stirred for uniformity and pulverized; thus, the mother powder is prepared; the mother powder and binding agent are uniformly mixed, granulated, dried and sieved; thus, the thiophthanate-methyl water dispersion granular agent is prepared. The thiophthanate-methyl water dispersion granular agent overcomes the disadvantages of suspending agents and wettable powder; in preparation and use processes, the present invention reduces the use cost of peasants and environment pollution. Because auxiliary agents with different components are added, the present invention has the advantages of high content of active components, small environment pollution, quick disintegration speed, good dispersion property, stable heat storage property, high bactericidal effect and good safety in use, etc.
Description
Technical field
The present invention relates to a kind of disinfectant use in agriculture, particularly thiophanate-methyl water-dispersible granules and component content thereof.
Background technology
At present, disinfectant use in agriculture is a lot, and thiophanate-methyl is wherein a kind of.It has the bactericidal activity height, and security performance is good, the characteristics that fungicidal spectrum is wide.But the former powder of thiophanate-methyl is made generally in wetting powder in using at present and suspending agent uses.Because wetting powder dust pollution in processing and use is serious, and environment and health are had very big harm, and shortcomings such as effective rate of utilization is low, lasting period weak point, therefore be the formulation that falls behind and be on the verge of to eliminate relatively in the present formulations of pesticide; Though suspending agent is the environmental protection preparation, high to the process conditions requirement aborning, can not realize the preparation of high-load at present, and its production, packing and cost of transportation are also higher, thereby cause the increase of production and use cost.
Summary of the invention
Purpose of the present invention is exactly in order to overcome the environmental pollution that exists in the prior art, to be detrimental to health and shortcoming such as use cost height and a kind of high-load of developing, environment-friendly type, availability height, and thiophanate-methyl water-dispersible granules and component content thereof easy to use.Water-dispersible granules is to grow up on the basis of wetting powder and suspending agent, this formulation has overcome the shortcoming of suspending agent and wetting powder, had both the low advantage of environmental protection and use cost, in processing and use, having reduced the pollution of environment and reduced peasant's use cost, is a main trend of present pesticidal preparations formulation development.
The objective of the invention is to be realized that by following technical scheme the active ingredient of thiophanate-methyl water-dispersible granules is thiophanate-methyl, it is characterized in that this granula is rule or irregular particle shape, its component content is by percentage to the quality:
The former powder of thiophanate-methyl: 40%～80%;
Wetting agent: 2%～8%,
Dispersant: 3%～10%,
Disintegrant: 3%～8%,
Thinner: 5%～40%,
Binding agent: 2%～10%.
Wherein:
Wetting agent can be a kind of of phenethyl phenol polyethenoxy ether condensation product, alkylphenol polyoxyethylene formaldehyde condensation products, sodium alkyl benzene sulfonate, sodium alkyl sulfate, alkyl phosphoric acid sodium, phenethyl phenol polyethenoxy ether sodium sulfate and alkylphenol-polyethenoxy base sodium sulphate;
Dispersant can be Fluhyzon formaldehyde condensation products sodium sulfonate, alkylphenol formaldehyde condensation product sodium sulphate, sodium lignin sulfonate, a kind of to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, polycarboxylic acids sodium;
Disintegrant can be a kind of of bentonite, Attapulgite, starch, inorganic sodium, white carbon and silica gel;
Thinner can be a kind of of kaolin, precipitated calcium carbonate, diatomite, potter's clay, white clouds tin soil;
Binding agent can be that binding agent is a kind of of denaturated sodium polyacrylate 80, No. 72, polyethylene glycol, No. 3, modified polyvinyl alcohol, No. 45, lignin, No. 54, lignin, modified polyacrylic acid sodium 50.
Owing to added the auxiliary agent of heterogeneity, make the present invention have the active component content height among the present invention, environmental pollution is little, and disintegration rate is fast, and dispersive property reaches heat storage steady performance well, bactericidal potency height in use, and safety is good.
Description of drawings
Accompanying drawing is preparation method's of the present invention process chart.
Embodiment
The present invention will be described in more detail below in conjunction with drawings and Examples:
Embodiment 1
Take by weighing the former powder 72% of thiophanate-methyl, wetting agent phenethyl phenol polyethenoxy ether formaldehyde 3%, dispersant sodium lignin sulfonate 6%, sodium sulphate 5%, thinner precipitated calcium carbonate 8%, it is pressed conventional method mix, after stirring, obtain female powder through the airslide disintegrating mill pulverizing, the binding agent denaturated sodium polyacrylate 80 of female powder and 6% is mixed, granulation then, oven dry, sieving obtains about 96% 70% thiophanate-methyl water-dispersible granules.Through the check active constituent content is 70.8%, moisture≤2.5%, and pH value 7.1, screening (by 75 μ m sieve) 〉=98%, suspensibility 〉=65%, lasting foaming characteristic (1min)≤10mL, wetability≤1min, dust≤3.0%, the acceleration heat storage stability is qualified.Being used to prevent and treat apple tree spot defoliation dosage in force is 700～875mg/kg, and control efficiency is 78～98%.
Embodiment 2
Take by weighing the former powder 73% of thiophanate-methyl, wetting agent sodium methylene bis-naphthalene sulfonate 4%, dispersant polycarboxylic acids sodium 5%, disintegrant white carbon 6%, thinner diatomite 8%, after it is mixed, pulverize through airslide disintegrating mill and to obtain female powder, No. 72 binding agents of polyethylene glycol of female powder and 4% are mixed granulation then, oven dry, sieving obtains about 96% 70% thiophanate-methyl water-dispersible granules.Through the check active constituent content is 71.1%, moisture≤2.5%, and pH value 7.4, screening (by 75 μ m sieve) 〉=98%, suspensibility 〉=65%, lasting foaming characteristic (1min)≤10mL, wetability≤1min, dust≤3.0%, the acceleration heat storage stability is qualified.Being used to prevent and treat apple tree spot defoliation dosage is 700～875mg/kg, and control efficiency is 81～90%.
Embodiment 3
Take by weighing the former powder 53% of thiophanate-methyl, wetting agent phenethyl phenol polyethenoxy ether sodium sulfate 6%, dispersant sodium lignin sulfonate 6%, disintegrant Attapulgite 8%, thinner kaolin 20%, after it is mixed, pulverize through airslide disintegrating mill and to obtain female powder, No. 72 binding agents of polyethylene glycol of female powder and 7% are mixed granulation then, oven dry, sieving obtains about 97% 50% thiophanate-methyl water-dispersible granules.Through the check active constituent content is 52.7%, moisture≤2.5%, and pH value 7.3, screening (by 75 μ m sieve) 〉=98%, suspensibility 〉=65%, lasting foaming characteristic (1min)≤10mL, wetability≤1min, dust≤3.0%, the acceleration heat storage stability is qualified.Being used to prevent and treat apple tree spot defoliation dosage is 700～875mg/kg, and control efficiency is 78～96%.
Embodiment 4
Take by weighing the former powder 54% of thiophanate-methyl, wetting agent neopelex 7%, dispersant sodium lignin sulfonate 9%, disintegrant sodium carbonate 6%, thinner diatomite 18%, after it is mixed, pulverize through airslide disintegrating mill and to obtain female powder, No. 54 binding agents of lignin of female powder and 6% are mixed granulation then, oven dry, sieving obtains about 96% 50% thiophanate-methyl water-dispersible granules.Through the check active constituent content is 51.5%, moisture≤2.5%, and pH value 7.3, screening (by 75 μ m sieve) 〉=98%, suspensibility 〉=65%, lasting foaming characteristic (1min)≤10mL, wetability≤1min, dust≤3.0%, the acceleration heat storage stability is qualified.Being used to prevent and treat apple tree spot defoliation dosage is 700～875mg/kg, and control efficiency is 83～91%.
Embodiment 5
Take by weighing the former powder 43% of thiophanate-methyl, wetting agent neopelex 8%, dispersant sodium lignin sulfonate 9%, disintegrant sodium carbonate 8%, thinner diatomite 24%, after it is mixed, pulverize through airslide disintegrating mill and to obtain female powder, modified polyacrylic acid sodium 50 binding agents of female powder and 8% are mixed granulation then, oven dry, sieving obtains about 95% 40% thiophanate-methyl water-dispersible granules.Through the check active constituent content is 41.5%, moisture≤2.5%, and pH value 7.1, screening (by 75 μ m sieve) 〉=98%, suspensibility 〉=65%, lasting foaming characteristic (1min)≤10mL, wetability≤1min, dust≤3.0%, the acceleration heat storage stability is qualified.Being used to prevent and treat apple tree spot defoliation dosage is 700～875mg/kg, and control efficiency is 81～90%.
Embodiment 6
Take by weighing the former powder 46% of thiophanate-methyl, wetting agent sodium methylene bis-naphthalene sulfonate 6%, dispersant is to methyl fatty acyl amido benzene sulfonic acid sodium salt 8%, disintegrant white carbon 6%, thinner diatomite 28%, after it is mixed, pulverize through airslide disintegrating mill and to obtain female powder, No. 45 binding agents of lignin of female powder and 6% are mixed granulation then, oven dry, sieving obtains about 96% 40% thiophanate-methyl water-dispersible granules.Through the check active constituent content is 42.7%, moisture≤2.5%, and pH value 7.5, screening (by 75 μ m sieve) 〉=98%, suspensibility 〉=65%, lasting foaming characteristic (1min)≤10mL, wetability≤1min, dust≤3.0%, the acceleration heat storage stability is qualified.Being used to prevent and treat apple tree spot defoliation dosage is 700～875mg/kg, and control efficiency is 82～94%.
In order to make those of ordinary skill in the art understand the present invention better, the invention provides the preparation method who is used for the thiophanate-methyl water-dispersible granules, following steps are arranged:
A), choose raw material, it is mixed according to the prescription of thiophanate-methyl water-dispersible granules;
B), after carrying out ultramicro grinding with above mixture, airslide disintegrating mill obtains female powder:
C), the female powder that obtains after the ultramicro grinding is mixed by prescription and binding agent;
D), above mixture is carried out granulation on comminutor;
E), above shot-like particle is dried;
F), the shot-like particle with oven dry promptly obtains the thiophanate-methyl water-dispersible granules after sieving.
The thiophanate-methyl water-dispersible granules that adopts prescription of the present invention to process the results showed that this product has good dispersiveness, and working substance suspends indefinite duration; Disintegration rate is fast, and disintegration time is less than 3min; Heat storage stability is good; And the height of adhesion rate in use, lasting period are long.The present invention is the bactericidal potency height in production application, through evidence, all can reach more than 80% to scab, ring spot, the powdery mildew leaf mold control efficiency of multiple fruit tree and vegetable; Safety is good, and crops are not had poisoning.
Among the present invention owing to added the auxiliary agent of heterogeneity so that the present invention has the active component content height, Environmental pollution is little, and disintegration rate is fast, and dispersive property reaches well heat storage steady performance, in use kills Bacterium usefulness height, security is good.
Claims (4)
1, a kind of thiophanate-methyl water-dispersible granules, its active ingredient is thiophanate-methyl, it is characterized in that this granula is rule or irregular particle shape, its component content is as follows by percentage to the quality:
The former powder of thiophanate-methyl: 40%～80%
Wetting agent: 2%～8%
Dispersant: 3%～10%
Disintegrant: 3%～8%
Thinner: 5%～40%
Binding agent: 2%～10%.
Described wetting agent can be a kind of of phenethyl phenol polyethenoxy ether condensation product, alkylphenol polyoxyethylene formaldehyde condensation products, sodium alkyl benzene sulfonate, sodium alkyl sulfate, alkyl phosphoric acid sodium, phenethyl phenol polyethenoxy ether sodium sulfate and alkylphenol-polyethenoxy base sodium sulphate.
Described dispersant can be Fluhyzon formaldehyde condensation products sodium sulfonate, alkylphenol formaldehyde condensation product sodium sulphate, sodium lignin sulfonate, a kind of to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, polycarboxylic acids sodium.
2, thiophanate-methyl water-dispersible granules according to claim 1 is characterized in that, wherein: disintegrant can be a kind of of bentonite, Attapulgite, starch, inorganic sodium, white carbon and silica gel.
3, thiophanate-methyl water-dispersible granules according to claim 1 is characterized in that, wherein: thinner can be a kind of of kaolin, precipitated calcium carbonate, diatomite, potter's clay, white clouds tin soil.
4, thiophanate-methyl water-dispersible granules according to claim 1, it is characterized in that wherein: binding agent can be a kind of of denaturated sodium polyacrylate 80, No. 72, polyethylene glycol, No. 3, modified polyvinyl alcohol, No. 45, lignin, No. 54, lignin, modified polyacrylic acid sodium 50.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410026344 CN1278609C (en) | 2004-07-21 | 2004-07-21 | Thiophthanate methyl water dispersible granular agent and its formula |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410026344 CN1278609C (en) | 2004-07-21 | 2004-07-21 | Thiophthanate methyl water dispersible granular agent and its formula |
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| Publication Number | Publication Date |
|---|---|
| CN1596648A CN1596648A (en) | 2005-03-23 |
| CN1278609C true CN1278609C (en) | 2006-10-11 |
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| CN 200410026344 Expired - Fee Related CN1278609C (en) | 2004-07-21 | 2004-07-21 | Thiophthanate methyl water dispersible granular agent and its formula |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101580439B (en) * | 2009-06-11 | 2012-05-23 | 陈琳 | Bactericide for preventing and treating diseases of fruit tree branches and trunks and preparation method thereof |
| CN101779649B (en) * | 2009-12-18 | 2012-11-07 | 陕西美邦农资贸易有限公司 | Bactericidal composition containing phenol cycloheximide and thiophanate-methyl |
| CN101836653A (en) * | 2010-05-28 | 2010-09-22 | 深圳市朗钛生物科技有限公司 | Pesticide composition containing amino-oligosaccharide and thiophanate methyl and use method and application thereof |
| CN102228043A (en) * | 2011-05-06 | 2011-11-02 | 浙江泰达作物科技有限公司 | Bactericide water dispersible granules compounded from difenoconazole and pyraclostrobin and preparation method thereof |
| CN113197213B (en) * | 2021-03-25 | 2022-05-13 | 镇江先锋植保科技有限公司 | Sulfoxaden dry suspending agent and preparation method thereof |
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