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CN1269973C - Warm up method of combustion supporting air through coal gas from blast furnace hot blast stove in high temperature - Google Patents

Warm up method of combustion supporting air through coal gas from blast furnace hot blast stove in high temperature Download PDF

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CN1269973C
CN1269973C CN 200410009644 CN200410009644A CN1269973C CN 1269973 C CN1269973 C CN 1269973C CN 200410009644 CN200410009644 CN 200410009644 CN 200410009644 A CN200410009644 A CN 200410009644A CN 1269973 C CN1269973 C CN 1269973C
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CN1600868A (en
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郭鸿志
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University of Science and Technology Beijing USTB
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Abstract

本发明提供了一种高风温高炉热风炉煤气、助燃空气预热方法,特征是:使用1台无机传热换热器,用280~320℃热风炉烟气将热风炉和小型高效蓄热式燃烧装置燃用高炉煤气预热到170~190℃;用1对计算机自动控制的小型高效蓄热式燃烧装置燃烧170~190℃的高炉煤气,将热风炉助燃空气预热到1050~1100℃。从而,确保热风炉热风温度达到1300~1350℃。其优点在于:预热系统设备少,高温空气预熟设备长寿、高效、小型、计算机自动控制,节省高热值的宝贵的焦炉煤气,只烧低热值的富余的高炉煤气,使热风炉的风温达到1300~1350℃的国际先进水平,可降低吨铁焦比60~70kg,增加喷煤量100~120kg,增加铁产量9~10.5%,1年左右收回投资。

The invention provides a method for preheating hot blast stove gas and combustion-supporting air of a high-blast furnace, which is characterized in that: using one inorganic heat transfer heat exchanger, the hot blast stove and the small-scale high-efficiency heat storage The blast furnace gas is preheated to 170-190°C by the type combustion device; the blast furnace gas of 170-190°C is burned by a pair of small-scale high-efficiency regenerative combustion devices automatically controlled by computers, and the combustion-supporting air of the hot blast stove is preheated to 1050-1100°C . Therefore, it is ensured that the temperature of the hot air in the hot blast stove reaches 1300-1350°C. Its advantages are: less preheating system equipment, high temperature air precooking equipment, long life, high efficiency, small size, computer automatic control, saving precious coke oven gas with high calorific value, only burning surplus blast furnace gas with low calorific value, making the air of the hot blast stove The temperature reaches the international advanced level of 1300-1350 ℃, which can reduce the ton iron-coke ratio by 60-70kg, increase the amount of coal injection by 100-120kg, increase iron production by 9-10.5%, and recover the investment in about one year.

Description

一种高风温高炉热风炉煤气、助燃空气预热方法A method for preheating hot blast stove gas and combustion-supporting air of high blast furnace

技术领域technical field

本发明属于高炉气体预热技术领域,特别是提供了一种高风温高炉热风炉煤气、助燃空气预热方法。The invention belongs to the technical field of blast furnace gas preheating, and in particular provides a method for preheating high blast furnace hot blast stove gas and combustion-supporting air.

背景技术Background technique

随着高炉大型化,高炉炼铁技术正向高效、长寿、高风温、大喷煤量方向发展。提高风温有利于高炉生产,可降低焦比,增加喷煤量,提高产量,降低生产成本。高风温技术在世界各主要产钢国家得到普遍应用。目前欧州及日本的大型高炉平均风温已达1250℃,正向1300~1350℃迈进。而我国高炉热风炉平均风温仅1000℃左右。国外高风温技术主要采用燃优质煤气,空气、煤气双预热的方法。国内大部分钢铁企业高热值的焦炉煤气十分宝贵,低热值的高炉煤气有富余。因此,我国高炉热风炉高风温技术只能采用以燃烧高炉煤气产生的高温烟气和热风炉低温烟气为热源,预热煤气、助燃空气的方法。例如中国专利申请CN1084792C“高风温高炉热风炉空气、煤气预热方法”于2002年5月15日公开了如下技术方案:使用3台热管换热器,用280~320℃热风炉烟气同时对热风炉燃用空气、高炉煤气第一次预热至130~150℃;再使用2台热管换热器,将烟气发生炉燃烧高炉煤气产生的900~1000℃的高温烟气先后对空气和高炉煤气进行第二次预热,使空气预热到400~450℃,高炉煤气预热到300~350℃,在全烧高炉煤气的条件下,使送风温度达到1250~1310℃。该技术方案存在的问题是:With the large-scale blast furnace, blast furnace ironmaking technology is developing in the direction of high efficiency, longevity, high blast temperature, and large coal injection volume. Raising the air temperature is beneficial to blast furnace production, which can reduce the coke ratio, increase the amount of coal injection, increase the output and reduce the production cost. High air temperature technology has been widely used in major steel-producing countries in the world. At present, the average wind temperature of large blast furnaces in Europe and Japan has reached 1250°C, and is heading towards 1300-1350°C. However, the average air temperature of blast furnace hot blast stove in my country is only about 1000°C. Overseas high wind temperature technology mainly adopts the method of burning high-quality gas and preheating both air and gas. Coke oven gas with high calorific value is very precious in most domestic iron and steel enterprises, and blast furnace gas with low calorific value is surplus. Therefore, the high blast temperature technology of blast furnace hot blast stove in my country can only use the high temperature flue gas produced by burning blast furnace gas and the low temperature flue gas of hot blast stove as heat source, and the method of preheating gas and combustion air. For example, the Chinese patent application CN1084792C "Method for preheating air and gas of blast furnace hot blast furnace with high blast temperature" disclosed the following technical scheme on May 15, 2002: using 3 heat pipe heat exchangers, using 280-320 ℃ hot blast stove flue gas to simultaneously For the hot blast furnace, the air and blast furnace gas are preheated to 130-150°C for the first time; then, two heat pipe heat exchangers are used to transfer the high-temperature flue gas of 900-1000°C produced by the flue gas generator to the air successively. Perform second preheating with blast furnace gas to preheat air to 400-450°C and blast furnace gas to 300-350°C. Under the condition of fully burning blast furnace gas, the air supply temperature reaches 1250-1310°C. The problem that this technical scheme exists is:

(1)预热系统设备和管道数量多、体积庞大、占地面积和占用空间大。两次预热共用5台热管换热器、1座烟气燃烧炉。高炉热风炉现场拥挤,空中各种管路交错。因此,该技术方案如付诸实施局限性大,很多高炉热风炉现场摆不开这么多预热设备和管道。(1) The preheating system has a large number of equipment and pipelines, is bulky, and occupies a large area and space. The two preheatings share 5 heat pipe heat exchangers and 1 flue gas combustion furnace. The site of the blast furnace hot blast stove is crowded, and various pipelines are staggered in the air. Therefore, this technical scheme has great limitations as being put into practice, and so many preheating equipment and pipelines cannot be placed on the spot of many blast furnace hot blast stoves.

(2)预热系统设备和管道的散热面积大,散热损失大。(2) The heat dissipation area of the preheating system equipment and pipeline is large, and the heat dissipation loss is large.

(3)第二次预热仍采用热管换热器,不是最优选择。在高温条件下金属换热器寿命短、体积庞大、温度效率和热效率低。应该采用长寿、高效、小型的蓄热式燃烧装置。(3) The heat pipe heat exchanger is still used for the second preheating, which is not the best choice. Under high temperature conditions, metal heat exchangers have short life, bulky volume, low temperature efficiency and thermal efficiency. A long-life, high-efficiency, and small regenerative combustion device should be used.

发明内容Contents of the invention

本发明的目的在于:提供一种高炉热风炉煤气、助燃空气预热方法,只烧高炉煤气,使高炉热风炉的风温进一步提高到1300~1350℃的国际先进水平;优选高温预热设备,减少预热系统设备和管道数量、占地面积、占用空间和散热损失,提高温度效率和热效率。The object of the present invention is to provide a method for preheating blast furnace hot blast stove gas and combustion-supporting air, which only burns blast furnace gas to further increase the blast temperature of blast furnace hot blast stove to the international advanced level of 1300-1350°C; high-temperature preheating equipment is preferred, Reduce the number of preheating system equipment and pipes, floor area, occupied space and heat dissipation loss, and improve temperature efficiency and thermal efficiency.

本发明的技术方案是:Technical scheme of the present invention is:

使用1台无机传热换热器,用280~320℃的热风炉烟气将热风炉和小型高效蓄热式燃烧装置燃用高炉煤气预热到170~190℃;用1对计算机控制的小型高效蓄热式燃烧装置燃烧170~190℃的高炉煤气,将热风炉助燃空气预热到1050~1100℃。Use 1 inorganic heat transfer heat exchanger to preheat the hot blast stove and small high-efficiency regenerative combustion device to 170-190 ℃ with the flue gas of the hot blast stove at 280-320 ℃; use a pair of computer-controlled small The high-efficiency regenerative combustion device burns blast furnace gas at 170-190°C, and preheats the combustion-supporting air of the hot blast stove to 1050-1100°C.

本发明的构成是:使用1台无机传热换热器,用280~320℃的热风炉烟气将热风炉和小型高效蓄热式燃烧装置燃用高炉煤气预热到170~190℃;(2).用1对计算机控制的小型蓄热式燃烧装置燃烧170~190℃的高炉煤气,将热风炉助燃空气预热到1050~1100℃。具体工艺为:The composition of the present invention is: use one inorganic heat transfer heat exchanger, use the flue gas of the hot blast stove at 280-320 ℃ to preheat the blast furnace gas to 170-190 ℃ for the hot-blast stove and the small-scale high-efficiency regenerative combustion device; 2). Use a pair of computer-controlled small regenerative combustion devices to burn blast furnace gas at 170-190°C, and preheat the combustion-supporting air of the hot blast stove to 1050-1100°C. The specific process is:

如图1所示,本发明预热高炉煤气所用的1台无机传热换热器1布置在热风炉9通往烟囱2的烟气管道Y上。进、出无机传热换热器1的热风炉烟气温度分别为280~320℃和150~160℃。被预热到170~190℃的高炉煤气经高炉煤气管道G分别送入热风炉9和小型高效蓄热式燃烧装置4的燃烧器。As shown in FIG. 1 , an inorganic heat transfer heat exchanger 1 used for preheating blast furnace gas in the present invention is arranged on the flue gas pipe Y leading to the chimney 2 from the hot blast stove 9 . The flue gas temperatures of the hot blast stove entering and exiting the inorganic heat transfer heat exchanger 1 are respectively 280-320°C and 150-160°C. The blast furnace gas preheated to 170-190° C. is sent to the hot blast stove 9 and the burner of the small-scale high-efficiency regenerative combustion device 4 respectively through the blast furnace gas pipeline G.

小型高效蓄热式燃烧装置4的助燃空气经鼓风机3和空气管道K供入燃烧器,燃烧器点火用焦炉煤气由管道J供入。燃用焦炉煤气的点火烧嘴装配高压电点火装置、紫外光敏火焰检测装置,确保高炉煤气点火燃烧过程自动控制安全可靠。经预热的170~190℃的高炉煤气在小型高效蓄热式燃烧装置中的高速烧嘴或亚高速烧嘴与空气燃烧,所产生的高温烟气在蓄热室上方空间高速旋转,然后气流分布均匀地进入蓄热球床,与陶瓷球进行高效换热后,150~160℃的烟气经换向机构5和引风机6排出。热风炉助燃空气经鼓风机7和换向机构5进入小型高效蓄热式燃烧装置4的蓄热室,被陶瓷球加热到1050~1100℃,经热风阀8和热风管道R送到热风炉燃烧室。小型高效蓄热式燃烧装置由计算机自动控制,因此能确保在只烧高炉煤气条件下,高炉热风炉风温达到1300~1350℃。其中,小型高效蓄热式燃烧装置的蓄热体是直径为10~30mm的高铝高硅质陶瓷球。The combustion-supporting air of the small-scale high-efficiency regenerative combustion device 4 is supplied to the burner through the blower 3 and the air pipe K, and the coke oven gas used for ignition of the burner is supplied through the pipe J. The ignition burner for burning coke oven gas is equipped with a high-voltage electric ignition device and an ultraviolet photosensitive flame detection device to ensure the safety and reliability of the automatic control of the blast furnace gas ignition and combustion process. The preheated 170-190°C blast furnace gas burns with air in the high-speed burner or sub-high-speed burner of the small high-efficiency regenerative combustion device, and the high-temperature flue gas generated rotates at high speed in the space above the regenerator, and then the Evenly distributed into the heat storage pebble bed, after efficient heat exchange with ceramic balls, the flue gas at 150-160 °C is discharged through the reversing mechanism 5 and the induced draft fan 6. The combustion-supporting air of the hot blast stove enters the regenerator of the small-scale high-efficiency regenerative combustion device 4 through the blower 7 and the reversing mechanism 5, is heated to 1050-1100°C by the ceramic ball, and is sent to the combustion chamber of the hot blast stove through the hot blast valve 8 and the hot blast pipeline R . The small high-efficiency regenerative combustion device is automatically controlled by the computer, so it can ensure that the blast furnace hot blast stove air temperature reaches 1300-1350 °C under the condition of only burning blast furnace gas. Among them, the regenerator of the small-scale high-efficiency regenerative combustion device is a high-alumina and high-silicon ceramic ball with a diameter of 10-30 mm.

本发明所述的小型高效蓄热式燃烧装置计算机自动控制的内容包括:1对小型高效蓄热式燃烧装置的自动切换程序控制、燃烧控制、贮热量控制、燃烧装置拱顶温度控制、废气温度控制等。The computer automatic control of the small high-efficiency regenerative combustion device of the present invention includes: 1 automatic switching program control of the small high-efficiency regenerative combustion device, combustion control, heat storage control, combustion device vault temperature control, exhaust gas temperature control etc.

本发明的优点在于:预热系统设备少,高温空气预热设备长寿、高效、小型、计算机自动控制,节省高热值的宝贵的焦炉煤气,只烧低热值的富余的高炉煤气,使热风炉的风温达到1300~1350℃的国际先进水平,可降低吨铁焦比60~70kg,增加喷煤量100~120kg,增加铁产量9~10.5%,1年左右收回投资。The present invention has the advantages of less preheating system equipment, high temperature air preheating equipment with long life, high efficiency, small size, computer automatic control, saving precious coke oven gas with high calorific value, and only burning surplus blast furnace gas with low calorific value, so that the hot blast stove The wind temperature reaches the international advanced level of 1300-1350℃, which can reduce the iron-coke ratio per ton by 60-70kg, increase the amount of coal injection by 100-120kg, increase iron production by 9-10.5%, and recover the investment in about one year.

本发明使高炉热风炉送风温度达到1300~1350℃,比现有技术(CN1084792C)的1250~1310℃提高50℃。但本发明所用设备和管道的数量、体积、占地面积、占用空间、散热损失等大为减少,低温预热仅用1台无机传热换热器就充分利用了高炉热风炉低温烟气余热资源,且排烟温度仅160℃左右,而现有技术(CN1084792C)低温预热则使用3台热管换热器,排烟温度为170℃左右。高温预热,本发明应用现代的高温空气燃烧技术与理论,使用1对小型、高效、长寿、计算机自动控制的蓄热式燃烧装置,燃烧170~190℃的高炉煤气,直接在高效蓄热室内预热助燃空气到1050~1100℃,而现有技术(CN1084792C)应用传统的燃烧技术和预热方法,使用3台相互分离的热设备,即2台高温时短寿、体积庞大的金属热管换热器,和一座烟气燃烧炉来第二次预热空气、煤气,其温度效率和热效率都不高。两者相比较,本发明具有明显的优越性。The invention makes the air supply temperature of the blast furnace hot blast stove reach 1300-1350 DEG C, which is 50 DEG C higher than the 1250-1310 DEG C of the prior art (CN1084792C). However, the number, volume, floor area, occupied space, and heat dissipation loss of the equipment and pipelines used in the present invention are greatly reduced, and only one inorganic heat transfer heat exchanger is used for low-temperature preheating to fully utilize the low-temperature flue gas waste heat of the blast furnace hot blast stove resources, and the exhaust gas temperature is only about 160°C, while the low-temperature preheating in the prior art (CN1084792C) uses three heat pipe heat exchangers, and the exhaust gas temperature is about 170°C. High-temperature preheating, the present invention applies modern high-temperature air combustion technology and theory, uses a pair of small, high-efficiency, long-life, computer-automatically controlled regenerative combustion devices, and burns blast furnace gas at 170-190°C directly in the high-efficiency regenerative chamber Preheat the combustion-supporting air to 1050-1100°C, while the prior art (CN1084792C) uses traditional combustion technology and preheating methods, using 3 sets of thermal equipment separated from each other, that is, 2 sets of short-lived and bulky metal heat exchangers at high temperatures Heater, and a flue gas burner to preheat air and gas for the second time, its temperature efficiency and thermal efficiency are not high. Compared with the two, the present invention has obvious advantages.

附图说明Description of drawings

图1为本发明的工艺系统图。其中无机传热换热器1、.烟囱2、.鼓风机3、.1对小型高效蓄热式燃烧装置4A、B、.换向机构5、引风机6、.鼓风机7、.热风阀8、热风炉9包括№1、№2、№3、№4共4座。Fig. 1 is a process system diagram of the present invention. Among them, the inorganic heat transfer heat exchanger 1, the chimney 2, the blower 3, the small-scale high-efficiency regenerative combustion device 4A, B, the reversing mechanism 5, the induced draft fan 6, the blower 7, the hot air valve 8, Hot blast stove 9 comprises totally 4 seats of №1, №2, №3, №4.

具体实施方式Detailed ways

用1台无机传热换热器1布置在热风炉9通往烟囱2的烟气管道Y上。进、出无机传热换热器1的热风炉烟气温度分别为300℃和160℃。被预热到180℃的高炉煤气经高炉煤气管道G分别送入热风炉9和小型高效蓄热式燃烧装置4的燃烧器。One inorganic heat transfer heat exchanger 1 is arranged on the flue gas pipe Y leading to the chimney 2 from the hot blast stove 9 . The flue gas temperatures of the hot blast stove entering and exiting the inorganic heat transfer heat exchanger 1 are respectively 300°C and 160°C. The blast furnace gas preheated to 180° C. is sent to the hot blast stove 9 and the burner of the small-scale high-efficiency regenerative combustion device 4 respectively through the blast furnace gas pipeline G.

小型高效蓄热式燃烧装置4的助燃空气经鼓风机3和空气管道K供入燃烧器,燃烧器点火用焦炉煤气由管道J供入。燃用焦炉煤气的点火烧嘴装配高压电点火装置、紫外光敏火焰检测装置,确保高炉煤气点火燃烧过程自动控制安全可靠。经预热的180℃的高炉煤气在小型高效蓄热式燃烧装置中的高速烧嘴或亚高速烧嘴与空气燃烧,所产生的高温烟气在蓄热室上方空间高速旋转,然后气流分布均匀地进入蓄热球床,与陶瓷球进行高效换热后160℃的烟气经换向机构5和引风机6排出。热风炉助燃空气经鼓风机7和换向机构5进入小型高效蓄热式燃烧装置4的蓄热室,被陶瓷球加热到1070℃,经热风阀8和热风管道R送到热风炉燃烧室。小型高效蓄热式燃烧装置由计算机自动控制,因此能确保在只烧高炉煤气条件下,高炉热风炉风温达到1340℃。其中,小型高效蓄热式燃烧装置的蓄热体是直径为20mm的高铝高硅质陶瓷球。The combustion-supporting air of the small-scale high-efficiency regenerative combustion device 4 is supplied to the burner through the blower 3 and the air pipe K, and the coke oven gas used for ignition of the burner is supplied through the pipe J. The ignition burner for burning coke oven gas is equipped with a high-voltage electric ignition device and an ultraviolet photosensitive flame detection device to ensure the safety and reliability of the automatic control of the blast furnace gas ignition and combustion process. The preheated 180°C blast furnace gas burns with air in the high-speed burner or sub-high-speed burner of the small high-efficiency regenerative combustion device, and the high-temperature flue gas generated rotates at high speed in the space above the regenerator, and then the airflow is evenly distributed The ground enters the heat storage pebble bed, and the flue gas at 160°C is discharged through the reversing mechanism 5 and the induced draft fan 6 after efficient heat exchange with the ceramic balls. The combustion-supporting air of the hot blast stove enters the regenerator of the small-scale high-efficiency regenerative combustion device 4 through the blower 7 and the reversing mechanism 5, is heated to 1070°C by ceramic balls, and is sent to the combustion chamber of the hot blast stove through the hot blast valve 8 and the hot blast pipe R. The small high-efficiency regenerative combustion device is automatically controlled by a computer, so it can ensure that the blast furnace hot blast stove air temperature reaches 1340°C under the condition of only burning blast furnace gas. Among them, the regenerator of the small-scale high-efficiency regenerative combustion device is a high-alumina and high-silicon ceramic ball with a diameter of 20mm.

Claims (3)

1, a kind of high-blast-temperature hot-blast stove coal gas, combustion air pre-heating mean, it is characterized in that: use 1 inorganic heat transfer interchanger, hotblast stove and small-sized efficient heat accumulating burner capable burning blast furnace gas are preheating to 170~190 ℃ with 280~320 ℃ hot-blast stove fumes; Blast furnace gas with 170~190 ℃ of 1 pair of computer-controlled small-sized heat accumulating burner capable burnings is preheating to 1050~1100 ℃ with the hotblast stove combustion air; The heat storage of small-sized efficient heat accumulating burner capable is that diameter is the high siliceous Ceramic Balls of high alumina of 10~30mm, the combustion air of small-sized efficient heat accumulating burner capable (4) infeeds burner through gas blower (3) and air line K, the burner igniting is infeeded by pipeline J with coke-oven gas, use igniter burner assembling high voltage electric portfire, the UV photosensitive flame detecting device of coke-oven gas, control is safe and reliable automatically to guarantee blast furnace gas ignition process; High combustion rate burner or inferior high combustion rate burner and the air combustion of 170~190 ℃ blast furnace gas in the small-sized efficient heat accumulating burner capable through preheating, the high-temperature flue gas that is produced is at regenerator superjacent air space high speed rotating, air-flow enters the heat-storing sphere bed with being evenly distributed then, after carrying out high efficient heat exchanging with Ceramic Balls, 150~160 ℃ flue gas is discharged through reversing mechanism (5) and induced draft fan (6); The hotblast stove combustion air is heated to 1050~1100 ℃ through the regenerator that gas blower 7 and reversing mechanism (5) enter small-sized efficient heat accumulating burner capable (4) by Ceramic Balls, delivers to the Combustion of Hot Air Furnace chamber through hot blast valve (8) and hot air duct R; Therefore the small-sized efficient heat accumulating burner capable can guarantee that under a burning blast-furnace gas condition, the blast funnace hot blast stove wind-warm syndrome reaches 1300~1350 ℃ by computer controlled automatic.
2, pre-heating mean according to claim 1, it is characterized in that: used 1 the inorganic heat transfer interchanger (1) of described preheating blast furnace gas is arranged in hotblast stove (9) and leads on the flue Y of chimney (2), hot-blast stove fume temperature into and out of inorganic heat transfer interchanger (1) is respectively 280~320 ℃ and 150~160 ℃, is preheating to 170~190 ℃ blast furnace gas is sent into hotblast stove (9) and small-sized efficient heat accumulating burner capable (4) respectively through blast furnace gas pipeline G burner.
3, pre-heating mean according to claim 1 is characterized in that: the content of described small-sized efficient heat accumulating burner capable computer controlled automatic comprises: the automatic switching program control of 1 pair of small-sized efficient heat accumulating burner capable, burning control, the control of storage heat, the control of combustion unit dome temperature and spent air temperture control.
CN 200410009644 2004-10-10 2004-10-10 Warm up method of combustion supporting air through coal gas from blast furnace hot blast stove in high temperature Expired - Fee Related CN1269973C (en)

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CN100398668C (en) * 2005-06-30 2008-07-02 宝山钢铁股份有限公司 A process and device for heating reducing gases such as high-concentration carbon monoxide
CN101603108B (en) * 2009-07-28 2010-11-03 首钢总公司 Method for preventing intergranular stress corrosion of vault of hot blast heater
CN102041337B (en) * 2011-01-13 2012-08-22 北京首钢国际工程技术有限公司 Multi-purpose system for high-temperature preheating of hot blast furnace combustion-supporting air
CN102759419A (en) * 2011-04-28 2012-10-31 宝山钢铁股份有限公司 Determination method for heat redundancy in blast furnace
CN102912055B (en) * 2012-08-29 2014-07-09 北京和隆优化科技股份有限公司 Intelligent optimization control system of blast furnace hot-blast stove
CN102952913B (en) * 2012-11-12 2015-07-15 鞍钢集团工程技术有限公司 Dual-preheating method and device for preheating blast furnace gas by using heat-storage-type preheating furnace
JP5468172B1 (en) * 2013-10-16 2014-04-09 新日鉄住金エンジニアリング株式会社 Hot stove facility
CN105115312A (en) * 2015-09-29 2015-12-02 吴庆华 Method for utilizing kiln flue gas to perform secondary mixed combustion

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