CN1266184A - Method and system for determining active ion - Google Patents
Method and system for determining active ion Download PDFInfo
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- CN1266184A CN1266184A CN 99103637 CN99103637A CN1266184A CN 1266184 A CN1266184 A CN 1266184A CN 99103637 CN99103637 CN 99103637 CN 99103637 A CN99103637 A CN 99103637A CN 1266184 A CN1266184 A CN 1266184A
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- active ion
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- nonionic
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- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Abstract
The present invention relates to a method for detecting active ion produced by some active substances and its measuring system, and said active substance is an artificial fibre containing fine carbide particles with permanent spontaneous polarity. Said method includes the following steps: continuously introducing CO2-removed air into active ion generation source to carry active ion, then introducing distilled water and measuring distilled water conductivity increment resulted from absorbing active ion in carrier air. Its measuring system includes: non-ioninc inactive gas supply source, sample cover with active ion generation source, container with distilled water for absorbing air with active ion, measuring instrument for measuring water sample conductivity, pipeline for connecting all portions and temp. controller and/or inactive carrier gas flow-speed controlling instrument.
Description
The present invention relates to a kind of assay method and mensuration system thereof of active ion.Comparatively specifically, in the former measuring method of the assay method mentioned of the present invention and the detected active ion of measuring system since lack suitable means be detect less than.
The said active ion of this paper is a kind of negative ion, and this kind ion can show activation (invigorating effect) by making automatic control nervous system and former moving (motorial) nervous system normalization on biosome.As a result, the people under this kind active ion influence knows from experience generation such as sleep stimulation, ataraxy, wholesome effect such as set up.
Yet,, use conventional voltmeter to be difficult to its mensuration because the quantity of active ion is few.Therefore designed a kind of surveying instrument that detects few quantity charged particle, this kind instrument can be with the electrically charged quantitative measurment that swims on the dust in air particle.But active ion promptly uses this comparatively delicate also to be difficult to detect because quantity is few.Therefore, do not have suitable means detection of active ion to reach in the prior art quantitatively estimates the quantity of active ion at all.
The objective of the invention is to provide the means of a kind of simply and easily detection and quantitative measurment active ion, as method and measuring system; Although this kind active ion is recognized still do not have effective means to detect in the prior art and the quantitative measurment active ion widely for the useful physiological action of biosome.
In other words, the inventor has done extensive investigations, purpose is the method that will develop a kind of detection and quantitative measurment active ion, although result's right and wrong are direct, still a kind of detection and method for quantitatively determining of active ion have been found, this method is that the nonionic inert carrier gas that will have active ion contacts with distilled water, by measuring because the increase of the electric conductivity of the water that active ion causes detects active ion.
Therefore, the present invention's method of measuring active ion may further comprise the steps:
(a) the nonionic inert gas is continuously contacted with active ion generation source, so that gas has active ion;
(b) inert gas that has active ion is contacted with distilled water;
(c) distilled water is measured its electric conductivity with after the inert gas of carrying active ion contacts
Above method in step (a) afterwards, (b) is further comprising the steps of before in step:
(d) to make it the temperature of the distilled water that contacted with inert gas in the step (b) equal substantially for the control temperature of inert gas that has an active ion; And/or
(e) control has the flow velocity of the inert gas of active ion, makes it substantial constant.
The measuring system of detection of active ion of the present invention comprises:
(A) nonionic inert gas delivery source;
(B) hydrostatic column that the vertical extension of Temperature Detector and well heater is installed is housed, this container one end is equipped with inert gas entrance, and the other end relative with inlet is equipped with the inert gas outlet, and active ion generation source material is equipped with at the container middle part;
(C) distilled water and the container that has thermostat are housed;
(D) connect the inlet of prolongation container (B) and article one pipeline of nonionic inert gas (A) supply source;
(E) connect outlet that prolongs container (B) and the second pipeline that the container (C) of distilled water is housed;
(F) use is contained in the instrument of the electric conductivity of the middle distilled water of electrode measurement container (C) in the distilled water.
Mensuration of the present invention system also comprises:
(G) temperature control equipment and/or
(H) gas flow rate control device; These two kinds of devices are all at the middle part of the second pipeline of the inlet of outlet that connect to prolong container (B) and container (C).
Choose wantonly at the middle part that connects article one pipeline (D) that prolongs container (B) and nonionic inert gas supply source (A) device of removing ionic material is housed.
The roughly description of accompanying drawing
Fig. 1 is for detecting and measure the synoptic diagram of the measuring system of active ion.
Fig. 2 is another synoptic diagram that has the detection of temperature controller and Gas Flow Velocity Controller and measure the measuring system of active ion of the present invention.
Fig. 3 for the electric conductivity of distilled water along with feeding has the time variation diagram of the inert gas of active ion, active ion is to be emitted by the regenerated fiber that contains superfine calcium carbide particle.
Below, with reference to the accompanying drawings the present invention is described in detail.Fig. 1 is for a kind of detection of novelty and measure measuring system device example schematic by the active ion that ion gun discharged.
Be full of the source material S that can emit active ion in Sample sleeve (sample-holder) container 1.
When active ion is measured, the nonionic inert gas that is contained in the gas cylinder 4 is imported decarburization groove 6 to remove wherein contained CO by pipeline 5
2, remove CO
2Inert gas import the inlet that is contained in the Sample sleeve top by pipeline 7.When inert carrier gas flows when contacting with sample S, just entrained by inert carrier gas by the active ion that S emits.The inert gas of carrying active ion is discharged from the outlet of Sample sleeve 1 bottom, arrives the container 10 that distilled water 11 is housed through pipeline 8.Inert gas is discharged in the air by exporting 12 after blowing to distilled water 11 surfaces at last.Therefore, inertia with active ion be imported in the distilled water 11 so that the electric conductivity of distilled water increases with the growth of the time that is blown into of the inert gas of carrying active ion.Distilled water 11 in the container 10 remains on a specific temperature under the effect of constant temperature instrument 9.Be immersed in two electrodes 13,13 in the distilled water 11 ' link to each other with measuring instrument 14, to measure the electric conductivity of water.
The material of container 10 that distilled water 11 is housed is without any the factor of the electric conductivity that may have influence on distilled water, this point is very important, can produce certain ion as chamber wall and enter in the distilled water consideration based on this respect, although the deviation that meter 14 is produced can obtain correcting by blank assay, traditional glass material such as soda glass are inapplicable because it can discharge that the electric conductivity that causes water produces the basic ion of deviation.
Owing to the electric conductivity of water depends on that temperature changes, be crucial so under constant temperature, measure the electric conductivity of distilled water 11.Although have no particular limits, the electric conductivity of distilled water is measured temperature and is generally 20～22 ℃.
Therefore, preferably with the inert gas of carrying active ion to import in the distilled water 11, as 20～22 ℃ with the basic equal temperature of distillation water-bath 11 self-temperatures.For reaching this purpose, as shown in Figure 2, temperature controller is housed at the middle part of pipeline 8, temperature controller includes the spiral line type or the serrate pipeline 15 that are immersed in the calibration cell 16.
Install Gas Flow Velocity Controller 17 additional and also be preferred, as needle-valve is combined with air flow measuring apparatus, the down direction that is installed in temperature controller 16 on the pipeline 8 to be to control the flow velocity of carrier gas, as flow velocity in 98 ± 2 ml/min.
Because temperature controller 16 and Gas Flow Velocity Controller 17 have been installed, measured value is more stable, therefore uses the measured value electric conductivity of just can drawing itself and schemes over time.Therefore, the initial value of curve can be known definite.
Implement in this creationary assay method process, the active ion of being emitted by specimen material S is carried by the nonionic inert gas as carrier gas and carries.Because the material S active ion of emitting is few, be obtain accurately, and the electric conductivity numerical value that can reappear, any material that carrier gas itself does not have active ion fully or do not have finally to produce an active ion is very important.Suitable inert gas comprises the potpourri of nitrogen, oxygen, hydrogen, helium, neon, argon gas and above-mentioned gas.If ionic species CO
2Can be removed fully in de-carbon groove 6, conventional method is that air is as vector gas.The air de-carbon can be by making air and organic amine compound such as triethylamine solution, solid alkali metal oxyhydroxide such as KOH, and contacts such as reinforcing yin essence ion exchange resin are carried out.
More than method and measuring system described in the invention can be applicable to measure the active ion that is discharged by different ion releasable material, described typical material comprises certain natural minerals, pottery and contains the fiber or the molded plastic goods of the fine particle of active ion releasable material.A kind of typical mineral that can discharge active ion is the calcium carbide material of extensively being noted in recent years.
Calcium carbide is a kind of mineral matter with following constitutional chemistry:
MX
3B
3Al
3(AlSi
2O
9)
3(O，OH，F)
4，
Wherein M represents Na atom or Ca atom, and X represents Al, Fe, Li, Mg or Mn atom.Can generating also naturally, but the high-crystallinity crystal of the calcium carbide of synthetic is a kind of jewel of great use.Calcium carbide also is a kind ofly can show the mineral material of uniqueness that spontaneous permanent electric polarization and polarization vector are not subjected to the influence of external electric field.Calcium carbide is also launched far infrared radiation except have the strongest permanently-polarised in known mineral material.In addition, calcium carbide also has piezoelectric effect, by this kind effect, can produce bipolar electrode when crystal is subjected to ambient pressure.Calcium carbide also has thermoelectric effect, and by this effect, when the part crystal was heated, electric charge can be gathered in its surface.
Method of the present invention and mensuration system especially are suitable for and measure the active ion that is discharged by fibrous material, in these fibrous materials, contain the natural minerals or the fine particle of stupalith, the calcium carbide as mentioned above that produce active ion.
The example that contains the fibrous material of the fine particle that discharges the active ion material comprises vinal and rayon.
Have been found that humidity influences to some extent to the efficient that the nonionic inert gas carries the active ion process that is discharged by the active ion releasable material.When being active substance as calcium carbide, the calcium carbide that contains the calcium carbide fine particle preferably contains moisture content that is no more than 1.5% weight or the moisture content that more preferably contains 0.3～0.9% weight.Too high when the water cut of fiber, the active ion that is discharged by active material can be absorbed by the moisture content in the fibrous material, so that the electric conductivity of the distilled water that is measured produces minus deviation.Water cut in fibrous material is low excessively, then can't make active material fully effectively discharge active ion.And, suppose that the fibrous material that contains thin calcium carbide particle is used for hygienic article, fibrous material as active ion source S is remained on the approaching temperature of human body realize above-mentioned active ion assay method for 35～39 ℃.
The above water content is calculated by following formula
(water content, %)=(W
1-W
2)/W
1* 100 W wherein
1Be the weight behind the sample bone dry, as before test, heating 1～2 hour W down at 40 ℃
2Be the weight of same sample after test, as passing through inert gas 3 hours down at 35 ℃.
Below, the present invention will describe the method and the mensuration system of detection of active ion with example in detail, as the preparation process of the regenerated fiber of describing in the past that contains the superfine particle of calcium carbide.
According to traditional preparation process, at room temperature stirred 2 hours by the wood pulp of 100 parts of weight, the 20%NaOH solution that adds 350 parts of weight again makes alkali cellulose.CS with alkali cellulose and 30 parts of weight
2Mix, at room temperature stir and obtained sodium cellulose xanthate solution in 3 hours.
Next step, obtaining content of cellulose with the xanthates solution that makes more than the NaOH solution dilution is 8.7%, total alkali 6.0%, the spinning solution of total sulfur content 2.4% (weight).The superfine mix particles of this spinning solution and calcium carbide, the amount of calcium carbide are 1.0% (weight) of content of cellulose, and the calcium carbide particle obtains by wet granulation, and particle diameter is no more than 0.2 μ m, and mean grain size is 0.15 μ m.
The spinning solution that will contain the calcium carbide particle is put into 50 ℃ spinning bath, and the sulfuric acid of 120g/l, the sodium sulphate of 280g/l, the zinc sulfate of 15g/l are equipped with in this spinning bath.Spinning speed by spinning head is 60m/min, and it is the hole of 0.08mm that this spinning head has 50 diameters, obtains the regenerated fiber that 15 daniers contain thin calcium carbide particle by the stretching of conventional two bath stretch spinning methods after the spinning.Specimen preparation 2
The preparation method of regenerated fiber who contains the calcium carbide particle is substantially identical with above-mentioned specimen preparation 1, its difference only is: the calcium carbide grain diameter in the specimen preparation 1 is no more than 0.2 μ m, and select for use in the specimen preparation 2 with specimen preparation 1 in the calcium carbide particle of same amount, its particle diameter is no more than 1.0 μ m, mean grain size 0.8 μ m.Embodiment 1
Air contacts the back and is flowed out by the bottom of described Sample sleeve 1 with the regenerated fiber that contains the calcium carbide particle, introducing is in 1 liter the Bohemian glass beaker 8 as the volume of conductivity cell (Conductivity cell), with the 500ml temperature is that 21.0 ± 0.1 ℃ distilled water contacts, and is discharged by the mensuration system at last.
Use accurate conductivity meter (accurate LCR measuring instrument model 4285A, Hewlett-Packard's manufacturing) electric conductivity of distilled water in measurement and the record beaker, obtain the curve A among Fig. 3, it is air-flow and the nearly 5 hours duration of contact of regenerated fiber that contains the calcium carbide particle, and electricity is led trend over time.
Replace repeating above measuring process with the regenerated fiber that makes in the specimen preparation 2, obtain the curve B among Fig. 3 by the regenerated fiber that contains the calcium carbide particle that specimen preparation 1 obtains.
Replace containing the regenerated fiber of calcium carbide particle with the conventional regenerated fiber that does not contain the calcium carbide particle, repeat above-mentioned steps and do blank assay, the distillation electrical conductivity of water that obtains duration of contact and be 3 hours is 1.84 μ S/cm.Embodiment 2
The regenerated fiber product that contain the calcium carbide particle by method preparation identical in specimen preparation 1 or 2, the calcium carbide particle is up to 7% of the weight content of regenerated fiber, measure the electric conductivity of these regenerated fiber samples then by the method among the embodiment 1, the results are shown in Table 1, the data in this table show that the different regenerated fiber sample of calcium carbide particle content contacts the electric conductivity of water after 3 hours with water.
Table 1
Embodiment 3
| The electric conductivity of water, μ S/cm | |||
| The calcium carbide maximum particle diameter | ????0.2μm | ????1.0μm | |
| Calcium carbide granule content % weight | ????0.05 | ????2.24 | ????2.10 |
| ????0.1 | ????2,39 | ????2.15 | |
| ????0.2 | ????2.42 | ????2.17 | |
| ????0.3 | ????2.42 | ????2.16 | |
| ????0.5 | ????2.34 | ????2.13 | |
| ????1.0 | ????2.28 | ????2.13 | |
| ????2.0 | ????2.19 | ????2.11 | |
| ????3.0 | ????2.15 | ????2.08 | |
| ????5.0 | ????2.10 | ????2.10 | |
| ????7.0 | ????2.06 | ????2.08 | |
Use the regenerated fiber that contains the calcium carbide particle that makes in the specimen preparation 1 and 2, the method of pressing among the embodiment 1 is measured electric conductivity, difference only is to add the temperature controller 16 be made up of a water bath with thermostatic control and after-combustion pipeline that is dipped in wherein and a gas velocity controller 17 in the used measurement of embodiment 1, and (in this way the temperature with air-flow is controlled at 21 ± 0.1 ℃, airflow rate is controlled at 98 ± 2ml/min), and measured experimental result is described as solid line C and the dotted line D among Fig. 3 respectively.
Claims (13)
1. the assay method of an active ion may further comprise the steps: (a) continuously a kind of nonionic inert gas is contacted with a kind of active ion generation source, so that the gas-entrained active ion; (b) inert gas that will have an active ion contacts with distilled water; And the inert gas that (c) has an active ion is measured the conductance of distilled water with after distilled water contacts.
2. the described active ion assay method of claim 1, wherein the nonionic inert gas is essentially no CO
2Air.
3. the described active ion assay method of claim 1, wherein nonionic inert gas and active ion contact procedure (a) that the source takes place is carried out under constant temperature.
4. the described active ion assay method of claim 3, constant temperature scope wherein is at 35～39 ℃.
5. the described active ion assay method of claim 1, wherein the contact procedure (a) between nonionic inert gas and active ion generation source is under the constant humidity at the active ion emissive source and carries out.
6. the described active ion assay method of claim 5, constant humidity wherein is no more than 1.5% (weight).
7. described active ion assay method one of in the claim 1～6, preceding with step (b) in step (a) back, also comprise step (d): it is substantially the same with the distilled water temperature that it will contact in step (b) (d) to control the inert gas temperature that has active ion.
8. described active ion assay method one of in the claim 1～7, in step (a) back and (b) the preceding step (e) that also comprises: (e) control has the inert gas flow velocity substantially constant of active ion.
9. the detection system of an active ion mensuration comprises: (A) nonionic inert gas supply source; (B) the vertical hydrostatic column of placing that extends, i.e. sampling receptacle, it is equipped with Temperature Detector, well heater, an end is the nonionic inert gas entrance, the other end relative with it is the inert gas outlet, comprising the source material that can launch active ion; (C) have the container of the dress distilled water of thermostat; (D) article one pipeline of the supply source (A) of the inlet of connection extension container (B) and nonionic inert gas; (E) endpiece of the container (B) of connection extension and the second pipeline that the container (C) of distilled water is housed; (F) be used for measuring the analyzer of adorning the distillation electrical conductivity of water in the container (C), its electrode is inserted in the distilled water.
10. the detection system measured of the described active ion of claim 9, it also comprises: (G) be installed on the temperature controller at second pipeline (E) middle part, the endpiece that described second pipeline is used for extending container (B) is connected with the inlet end of conductance measurement instrument (F).
11. claim 9 or 10 described active ion mensuration systems further comprise: (H) be installed on the Gas Flow Velocity Controller at second pipeline (E) middle part, described second pipeline is used for connecting the endpiece that extends container (B) and the inlet end of conductance measurement instrument (F).
12. described active ion is measured system and also comprised one of in the claim 9～11: (I) be installed in article one pipeline (D) in order to remove the device of nonionic inert gas intermediate ion, described article one pipeline (D) is used for connecting inlet end and the nonionic inert gas supply source (A) that extends container (B).
13. described active ion is measured system one of in the claim 9～12, wherein the container of Yan Shening (B) is equipped with temperature controller.
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| CNB991036379A CN1187605C (en) | 1999-03-09 | 1999-03-09 | Method and system for determining active ion |
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| CNB991036379A CN1187605C (en) | 1999-03-09 | 1999-03-09 | Method and system for determining active ion |
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| CN1187605C CN1187605C (en) | 2005-02-02 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101238367B (en) * | 2005-08-11 | 2016-08-10 | Fmc康斯伯格海底股份公司 | Method and apparatus for measuring water conductivity and water volume fraction of aqueous multiphase mixtures |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101238367B (en) * | 2005-08-11 | 2016-08-10 | Fmc康斯伯格海底股份公司 | Method and apparatus for measuring water conductivity and water volume fraction of aqueous multiphase mixtures |
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