CN1265268A - Pesticide composition containing fipronil - Google Patents
Pesticide composition containing fipronil Download PDFInfo
- Publication number
- CN1265268A CN1265268A CN 99126078 CN99126078A CN1265268A CN 1265268 A CN1265268 A CN 1265268A CN 99126078 CN99126078 CN 99126078 CN 99126078 A CN99126078 A CN 99126078A CN 1265268 A CN1265268 A CN 1265268A
- Authority
- CN
- China
- Prior art keywords
- compound
- cis
- sharp strength
- phoxim
- imidacloprid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 15
- 239000000575 pesticide Substances 0.000 title abstract description 3
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 title abstract 2
- 239000005899 Fipronil Substances 0.000 title abstract 2
- 229940013764 fipronil Drugs 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 claims abstract description 21
- 230000000361 pesticidal effect Effects 0.000 claims abstract description 18
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 claims abstract description 18
- 229950001664 phoxim Drugs 0.000 claims abstract description 18
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000375 suspending agent Substances 0.000 claims abstract description 6
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 5
- 239000005906 Imidacloprid Substances 0.000 claims description 17
- 229940056881 imidacloprid Drugs 0.000 claims description 17
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 claims description 17
- 239000005663 Pyridaben Substances 0.000 claims description 15
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims description 14
- 239000005875 Acetamiprid Substances 0.000 claims description 14
- KAATUXNTWXVJKI-IKCNDWCXSA-N [cyano-(3-phenoxyphenyl)methyl] (1r,3s)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-IKCNDWCXSA-N 0.000 claims description 14
- 239000003814 drug Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 7
- 239000008187 granular material Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 4
- 238000009736 wetting Methods 0.000 claims description 4
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims description 3
- 239000005877 Alpha-Cypermethrin Substances 0.000 claims description 3
- 241000238631 Hexapoda Species 0.000 claims description 3
- WNCBICRHUMGMOW-UHFFFAOYSA-N P(=S)(O)(O)O.C1(=CC=CC=C1)CC#N Chemical compound P(=S)(O)(O)O.C1(=CC=CC=C1)CC#N WNCBICRHUMGMOW-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000001294 propane Substances 0.000 claims description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 claims description 2
- OMFXVFTZEKFJBZ-HJTSIMOOSA-N corticosterone Chemical compound O=C1CC[C@]2(C)[C@H]3[C@@H](O)C[C@](C)([C@H](CC4)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 OMFXVFTZEKFJBZ-HJTSIMOOSA-N 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 4
- 235000009566 rice Nutrition 0.000 abstract description 4
- 241001124076 Aphididae Species 0.000 abstract description 3
- 241001414720 Cicadellidae Species 0.000 abstract description 3
- 241001498622 Cixius wagneri Species 0.000 abstract description 3
- 241001414989 Thysanoptera Species 0.000 abstract description 3
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 abstract 1
- 239000005660 Abamectin Substances 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 229950008167 abamectin Drugs 0.000 abstract 1
- MBNMHBAJUNHZRE-UHFFFAOYSA-M thiosultap monosodium Chemical compound [Na+].OS(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O MBNMHBAJUNHZRE-UHFFFAOYSA-M 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 description 15
- 230000003449 preventive effect Effects 0.000 description 14
- 239000002270 dispersing agent Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 230000002195 synergetic effect Effects 0.000 description 6
- -1 alkyl sulfonic acid alkali metal salt Chemical class 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 239000000080 wetting agent Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 241000209094 Oryza Species 0.000 description 3
- 241000500437 Plutella xylostella Species 0.000 description 3
- 230000000740 bleeding effect Effects 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 230000000749 insecticidal effect Effects 0.000 description 3
- 210000004894 snout Anatomy 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 241001060517 Dicranolaius bellulus Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241001600408 Aphis gossypii Species 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 241000258916 Leptinotarsa decemlineata Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 241001622642 Parnara bada Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000001418 larval effect Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The pesticide composition includes fipronil and at least one of compound composed of Imidan, phoxim, monosultap, sanmite,abamectin and alpha-crpermethrin and may be produced to wettable powder, suspending agent and granulated product. It has high pesticidal efficiency and can be used in preventing and killing rice borers, plant hopper, thrips, aphid, leafhopper and other crop pests.
Description
The present invention relates to have highly active Pesticidal combination.Compound (A) and at least a specific insecticide (B) as the active ingredient representative are wherein arranged.
The chemical name of compound (A) is (±)-5-amino-1-(2.6-two chloro-2,2,2-three chloro-[β-tolyl)-4-trifluoromethyl sulfonyl pyrazoles-3-carbonization nitrile.Be a kind of highly active insecticide, can be used for preventing and treating crop pests such as fruit tree, vegetables, grain.In order to enlarge insecticidal spectrum, delaying drug resistance produces, and it can use with other compound, and sharp strength spy belongs to a brand-new compound family for existing insecticide, both at home and abroad also not mentioned it and other compound compositions of patent.
The objective of the invention is the effect that Pesticidal combination showed of compound (A) and some specific compound composition or the stack that activity level has exceeded each composition activity, or enlarged the insecticidal spectrum of one pack system compound.The Pesticidal combination that the present invention is based on this compound (A) and the formation of some specific compound has synergy or enlarges the insecticidal spectrum sphere of action provides one group of Pesticidal combination.
Pesticidal combination provided by the invention is characterised in that to comprise the special and at least a one group of compound (B) that is selected from Imidacloprid (imidacloprid), phoxim (phoxim), desinsection list, pyridaben (pyridaben), acetamiprid (abamecin), cis-, trans-cypermethrin (alphacypermethrin), composition of (A) sharp strength.Their chemical name is respectively and is:
Imidacloprid: 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine (imidacloprid B
1)
Phoxim: o, o-diethyl-d-oximido phenylacetonitrile thiophosphate (phoxim B
2).
Desinsection list: 2-N, N dimethylamine base-1-sodium thiosulfate base-3-propane thiosulfate (B
3).
Pyridaben: 2-tertiary butyl-5-(4-tertiary butyl benzylthio)-4-chlorine pyridazine-3 (2H)-ketone (pyridaben B
4).
Acetamiprid: it is by 80%Avermecfin B
1A and Avermecfin B
1Compound (the abamecfin B that b forms
5).
Cis-, trans-cypermethrin: (IR cis) S and (IS cis) R-alpha-cyano-(3-benzyloxy phenoxy base)-3 (2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester (alphacypermethrin B
6).
Weight ratio between compound in the Pesticidal combination of the present invention (A) and the compound (B) generally is:
For (A) and Imidacloprid (B
1) be preferably 5-25 for 1-50
For (A) and phoxim (B
2) be preferably 1.5-25 for 1-50
For (A) and desinsection list (B
3) be preferably 5-25 for 1-50
For (A) and pyridaben (B
4) be preferably 5-20 for 1-50
For (A) and acetamiprid (B
5) be preferably 0.5-20 for 0.1-5
For (A) and cis-, trans-cypermethrin (B
6) be preferably 1-5 for 0.1-5
The effective component content of Pesticidal combination of the present invention is 5-90%.
Pesticidal combination A+B involved in the present invention
1A+B
2A+B
3A+B
4A+B
5A+B
6Can be used for preventing and treating the insect such as diamond-back moth, aphid, snout moth's larva, plant hopper, thrips, rice beetle, leafhopper, lepidopterous larvae, fly class, coleopteran pest, mite class of crops such as vegetables, grain, fruit tree.
Pesticidal combination A+B involved in the present invention
1A+B
2A+B
3A+B
4A+B
5A+B
6Preferably suspending agent, granule, also wetting powder.
Adoptable surfactant has anionic surfactant and nonionic surface active agent.It comprises alkylsurfuric acid salt, alkyl sulfonic acid alkali metal salt and amido, dialkyl group succinate sodium sulfonate salt, alkylphenol polyoxyethylene formaldehyde condensation products succinic acid half ester sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol alkylphenol polyoxyethylene sulphate, alkylnaphthalene sulfonate, fatty acid or fatty acid ester sulphate, alkylphenol polyoxyethylene and fatty alcohol-polyoxyethylene ether etc., and that can give an example has farming newborn 8000 series, lignosulfonates, NNO, a dispersing agent MF etc.
The mixture that contains each active component in the wetting powder, inert carrier and filler and one or more wetting agents, carrier is generally mineral inert carrier such as kaolin, bentonite etc.It is more excellent in 10-80% that the wetting powder of the Pesticidal combination of this invention contains 5-90% (weight) usually) active mixture, 1-20% (more excellent is 1-10%) (weight) dispersant, the wetting agent of 1-10% (more excellent is 2-8%) (weight), 1-10% (more excellent is 2-5%) (weight) bleeding agent, inert solid carrier and the filler of 5-70% (weight) (more excellent is 10-80%), the Pesticidal combination of forming jointly by them.
Granule is with active ingredient and fine grainly is dispergated carrier, adds that granulations such as binding agent, colouring agent, dispersant form.It is 1-20% (weight) (the more excellent 1-10% of being) that granule contains effective composition.
The suspending agent of this insecticides is water-soluble relatively poor active component constantly to be stirred in water with emulsifier, dispersant, wetting agent etc. pulverize, make it evenly to disperse and suspend, can suitably add suitable suspending agent such as thickener, antifreezing agent, stabilizing agent, bleeding agent, defoamer as required, comprise the active substance of 1-80% (weight) (the more excellent 5-50% of being).
Pesticidal combination provided by the present invention possesses the insecticide efficiency height, can effectively prevent and treat the insect such as snout moth's larva, plant hopper, thrips, rice beetle, diamond-back moth, aphid, leafhopper, lepidopterous larvae, fly class, coleopteran pest, mite class of the crop of causing harm.Control is significantly higher than compound alone (A), or the preventive effect of compound alone (B), and has reduced the application dosage of every kind of active substance significantly.The present invention simultaneously can replace the insecticide pesticide kind of present high poison, high residue.The present invention not only has ecological significance, also has important environment protection significance simultaneously.
Following examples describe the present invention in detail, and embodiment mainly is for the present invention is described but not is used for limiting the present invention.
Embodiment 1 is the formulation preparation example, and embodiment 2-7 is a biological Examples.Embodiment 1:(1) suspending agent:
Active component A with 5% (purity 95%) and 10% and active component B
1(purity 93%) and 5% is as 33 of emulsifier
#, 4% NNO, 0.2% thickener xanthans, 3% sodium lignin sulfonate, 0.5% stabilizing agent benzoic acid, 2% antifreeze glycol as wetting agent as dispersant, mix with the proper quantity of defoaming agent n-butanol, in high-speed shearing machine, evenly pulverize and mix.(2) granule:
Active component A with 1.5% (purity 95%) and 3% active component B
1Produce granule with 2% binding agent, 0.5% colouring agent, 40% potter's clay, 2% dispersant and filler by coating method.(3) with 3% active component A (purity 95%) and 22% active component B
1(purity 93%) and 5% is evenly mixed through ultramicro grinding as the JFC of bleeding agent etc. as wetting agent and calcium lignosulfonate, 4% NNO as dispersant, 2% and to be produced.Embodiment 2 sharp strength are held with Imidacloprid and used with water rice hopper control efficiency place: period is investigated in the Xinyi: the 7 day time behind the medicine: 1998
| Medicament | Effective ingredient (ai/hm) | Worm refers to (%) | Preventive effect (%) | Expection preventive effect (coby method) |
| Sharp strength spy | ????20 | ????7.4 | ????60 | |
| Sharp strength spy | ????25 | ????7.6 | ????64.2 | |
| Imidacloprid | ????10 | ????5.0 | ????62.8 | |
| Imidacloprid | ????15 | ????4.8 | ????64.8 | |
| Sharp strength spy+Imidacloprid | ????20+10 | ????6.6 | ????89.2 | ????85.17 |
| Sharp strength spy+Imidacloprid | ????25+10 | ????5.2 | ????90.1 | ????86.7 |
| Sharp strength spy+Imidacloprid | ????20+15 | ????5.9 | ????87.4 | ????85.9 |
| Sharp strength spy+Imidacloprid | ????25+15 | ????8.0 | ????93.3 | ????87.4 |
Conclusion: sharp strength is special to be used preventive effect with Imidacloprid and is higher than it and uses the expectancy theory preventive effect with, illustrates that sharp strength is special to have used synergistic effect with Imidacloprid.Embodiment 3 sharp strength are special to be used with snout moth's larva of rice control efficiency place with the insecticide list: Xinyi spraying times a: control time: 7 day time behind the medicine: 1998
| Medicament | Effective ingredient (ai/hm) | Worm refers to (%) | Control (%) | Expection control (coby method) |
| Sharp strength spy | 20 | ?7.0 | ?62.1 | |
| Sharp strength spy | 25 | ?9.8 | ?63.8 | |
| Insecticide | 400 | ?12 | ?60.9 | |
| Insecticide | 450 | ?9.0 | ?59.2 | |
| Sharp strength spy+insecticide | 20+400 | ?8.5 | ?87.3 | ?85.2 |
| Sharp strength spy+insecticide | 20+450 | ?9.6 | ?86.7 | ?84.5 |
| Sharp strength spy+insecticide | 25+400 | ?7.3 | ?89.3 | ?85.6 |
| Sharp strength spy+insecticide | 25+450 | ?6.8 | ?90.1 | ?85.3 |
Conclusion: the special preventive effect of using with the insecticide list of sharp strength is higher than it and uses the expectancy theory preventive effect with, illustrates that sharp strength spy has used synergistic effect with the insecticide list.
Embodiment 4 sharp strength are special to be used with flower Ji, paddy rice rice plant skipper control efficiency with phoxim
Place: Xinyi spraying times: once
Investigation period: 7 day time behind the medicine: 1998
| Medicament | Effective ingredient (ai/hm) | Worm refers to (%) | Control (%) | Expection control (coby method) |
| Sharp strength spy | 20 | ?7.7 | ?59.2 | |
| Sharp strength spy | 25 | ?8.2 | ?63.1 | |
| Phoxim | 1500 | ?10.3 | ?63.4 | |
| Phoxim | 2000 | ?9.8 | ?64.2 | |
| Sharp strength spy+phoxim | 20+1500 | ?6.5 | ?87.2 | ?85.1 |
| Sharp strength spy+phoxim | 20+2000 | ?5.4 | ?88.7 | ?85.4 |
| Sharp strength spy+phoxim | 25+1500 | ?9.8 | ?89.2 | ?86.0 |
| Sharp strength spy+phoxim | 25+2000 | ?10.2 | ?90.4 | ?86.8 |
Conclusion: the special preventive effect of using with phoxim of sharp strength is higher than it and uses the expectancy theory preventive effect with, illustrates that sharp strength spy has used synergistic effect with phoxim.The sharp strength of embodiment 5 are special to be used with cotton aphid control efficiency place with pyridaben: Pei County, Jiangsu spraying times: second survey period: 7 day time behind the medicine for the second time: 1998
| Medicament | Effective ingredient (ai/hm) | Worm refers to (%) | Control (%) | Expection control (coby method) |
| Sharp strength spy | 1000 | ?8.9 | ?64.3 | |
| Sharp strength spy | 1500 | ?9.0 | ?62.5 | |
| Pyridaben | 1000 | ?7.3 | ?60.1 | |
| Pyridaben | 1500 | ?8.4 | ?63.4 | |
| Sharp strength spy+pyridaben | 1000+1000 | ?9.2 | ?88.1 | ?85.8 |
| Sharp strength spy+pyridaben | 1500+1500 | ?10.8 | ?89.4 | ?86.3 |
Conclusion: the special preventive effect of using with pyridaben of sharp strength is higher than it and uses the expectancy theory preventive effect with, proves that sharp strength spy has used synergistic effect with pyridaben.The sharp strength of embodiment 6 are special to be used with Chinese cabbage diamond-back moth control efficiency place with acetamiprid: Shouguang, Shandong dispenser period: larva stage of invasion spraying times: once investigate period: 7 day time behind the medicine: 1998
| Medicament | Effective ingredient (ai/hm) | Worm refers to (%) | Control (%) | Expection control (coby method) |
| Sharp strength spy | 20 | ?7.6 | ?60 | |
| Sharp strength spy | 25 | ?6.3 | ?62.1 | |
| Acetamiprid | 15 | ?5.2 | ?55.0 | |
| Acetamiprid | 20 | ?4.8 | ?60.0 | |
| Sharp strength spy+acetamiprid | 20+15 | ?8.4 | ?87.3 | ?85.0 |
| Sharp strength spy+acetamiprid | 25+20 | ?7.9 | ?87.4 | ?86.0 |
| Sharp strength spy+acetamiprid | 25+15 | ?10.2 | ?84.5 | ?82.3 |
| Sharp strength spy+acetamiprid | 25+20 | ?9.8 | ?89.7 | ?84.5 |
Conclusion: sharp strength is special to be used preventive effect with acetamiprid and is higher than it and uses the expectancy theory effect with, proves that sharp strength is special to have used synergistic effect with acetamiprid.The sharp strength of embodiment 7 are special uses control efficiency place to colorado potato beetle with cis-, trans-cypermethrin: Guangdong dispenser period: larval phase spraying times: once investigate period: the 7 day time behind the medicine: 1998
| Medicament | Effective ingredient (ai/hm) | Worm refers to (%) | Control (%) | Expection control (coby method) |
| Sharp strength spy | 15 | ?10.2 | ?59.3 | |
| Sharp strength spy | 20 | ?9.8 | ?62.4 | |
| Cis-, trans-cypermethrin | 1 | ?7.8 | ?56.7 | |
| Cis-, trans-cypermethrin | 1.5 | ?7.3 | ?58.3 | |
| Sharp strength spy+cis-, trans-cypermethrin | 15+1 | ?8.3 | ?83.7 | ?82.4 |
| Sharp strength spy+cis-, trans-cypermethrin | 15+1.5 | ?8.4 | ?85.1 | ?83.0 |
| Sharp strength spy+cis-, trans-cypermethrin | 20+1 | ?5.6 | ?86.3 | ?83.4 |
| Sharp strength spy+cis-, trans-cypermethrin | 20+1.5 | ?6.0 | ?88.7 | ?84.3 |
Conclusion: the special preventive effect of using with cis-, trans-cypermethrin of sharp strength is higher than it and uses the expectancy theory preventive effect with,
Illustrate that sharp strength spy has used synergistic effect with cis-, trans-cypermethrin.
Claims (5)
1 one groups of Pesticidal combinations is characterized in that comprising compound (A) (sharp strength spy) and at least a specific following one group of compound (B); The structural formula of A is:
Compd B is respectively:
Imidacloprid: 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine
(imidacloprid?B
1)；
Phoxim: o, o-diethyl-d-oximido phenylacetonitrile thiophosphate (phoxim B
2);
Desinsection list: 2-N, N dimethylamine base-1-sodium thiosulfate base-3-propane thiosulfate (B
3);
Pyridaben: 2-tertiary butyl-5-(4-tertiary butyl benzylthio)-4-chlorine pyridazine-3 (2H)-ketone
(pyridaben?B
4)；
Acetamiprid: it is by 80%Avermecfin B
1A and Avermecfin B
1The change that b forms
Compound (abamecfin B
5);
Cis-, trans-cypermethrin: (IR cis) S and (IS cis) R-alpha-cyano-(3-benzyloxy phenoxy
Base)-3 (2, the 2-dichloroethylene)-2, the 2-dimethyl cyclopropane carboxylic acid
Ester (alphacypermethrin B
6);
2 Pesticidal combinations according to claim 1 is characterized in that the weight ratio between compound in the composition (A) and the compound (B) is:
For (A) and Imidacloprid (B
1) be preferably 5-25 for 1-50
For (A) and phoxim (B
2) be preferably 1.5-25 for 1-50
For (A) and desinsection list (B
3) be preferably 5-25 for 1-50
For (A) and pyridaben (B
4) be preferably 5-20 for 1-50
For (A) and acetamiprid (B
5) be preferably 0.5-20 for 0.1-5
For (A) and cis-, trans-cypermethrin (B
6) be preferably 1-5 for 0.1-5
3 Pesticidal combinations according to claim 1, the effective component content that it is characterized in that composition is 5-90%.
4 one or multinomial a kind of preparation of compositions methods according to claim 1-3 is characterized in that, medicament can be processed into wetting powder, suspending agent and granule etc.
Pesticidal combination described in the 5 claim 1-3 can be used for preventing and treating the multiple kinds of crops insect pest.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99126078A CN1129358C (en) | 1999-12-15 | 1999-12-15 | Pesticide composition containing fipronil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99126078A CN1129358C (en) | 1999-12-15 | 1999-12-15 | Pesticide composition containing fipronil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1265268A true CN1265268A (en) | 2000-09-06 |
| CN1129358C CN1129358C (en) | 2003-12-03 |
Family
ID=5284315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99126078A Expired - Fee Related CN1129358C (en) | 1999-12-15 | 1999-12-15 | Pesticide composition containing fipronil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1129358C (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100340169C (en) * | 2005-08-11 | 2007-10-03 | 徐克华 | Compound pesticide of fipronil and pridaphenthione |
| CN100364979C (en) * | 2006-02-28 | 2008-01-30 | 浙江大学 | A kind of aryl pyrazole chrysanthemum compound and its application |
| CN100433979C (en) * | 2007-01-18 | 2008-11-19 | 江苏太湖地区农业科学研究所 | Compound insecticide containing fipronil and Etrofolan |
| JP2010510193A (en) * | 2006-11-17 | 2010-04-02 | ビーエーエスエフ ソシエタス・ヨーロピア | Method for increasing dry biomass in plants |
| WO2011161071A2 (en) | 2010-06-23 | 2011-12-29 | Basf Se | Nematicidal mixtures for use in sugar cane |
| CN102726435A (en) * | 2011-04-09 | 2012-10-17 | 浙江森得保生物制品有限公司 | Specifically effective formula for controlling Pleonomus canaliculatus Faldemann |
| CN102771503A (en) * | 2012-08-03 | 2012-11-14 | 广西汇丰生物科技有限公司 | Granule containing chitin |
| CN104522006A (en) * | 2014-12-19 | 2015-04-22 | 湖南化工研究院有限公司 | Composition for preventing and controlling lepidoptera and homopteran pests |
| US9271448B2 (en) | 2010-06-09 | 2016-03-01 | Basf Se | Method for cultivating sugar cane |
| CN105686963A (en) * | 2016-03-19 | 2016-06-22 | 上海申亚动物保健品阜阳有限公司 | Insectifuge pet shampoo |
| US9615503B2 (en) | 2011-09-23 | 2017-04-11 | Basf Se | Method for cultivating sugar cane |
| US9913473B2 (en) * | 2006-11-10 | 2018-03-13 | Basf Se | Crystalline modification of fipronil |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101204155A (en) * | 2007-12-12 | 2008-06-25 | 海南利蒙特生物农药有限公司 | Fipronil and monosultap compound pesticide |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19548872A1 (en) * | 1995-12-27 | 1997-07-03 | Bayer Ag | Synergistic insecticidal mixtures |
| CN1102023C (en) * | 1998-07-08 | 2003-02-26 | 安万特杭州作物科学有限公司 | Fipronil compound pesticide |
-
1999
- 1999-12-15 CN CN99126078A patent/CN1129358C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100340169C (en) * | 2005-08-11 | 2007-10-03 | 徐克华 | Compound pesticide of fipronil and pridaphenthione |
| CN100364979C (en) * | 2006-02-28 | 2008-01-30 | 浙江大学 | A kind of aryl pyrazole chrysanthemum compound and its application |
| US9913473B2 (en) * | 2006-11-10 | 2018-03-13 | Basf Se | Crystalline modification of fipronil |
| JP2010510193A (en) * | 2006-11-17 | 2010-04-02 | ビーエーエスエフ ソシエタス・ヨーロピア | Method for increasing dry biomass in plants |
| CN100433979C (en) * | 2007-01-18 | 2008-11-19 | 江苏太湖地区农业科学研究所 | Compound insecticide containing fipronil and Etrofolan |
| US9271448B2 (en) | 2010-06-09 | 2016-03-01 | Basf Se | Method for cultivating sugar cane |
| WO2011161071A2 (en) | 2010-06-23 | 2011-12-29 | Basf Se | Nematicidal mixtures for use in sugar cane |
| CN102726435A (en) * | 2011-04-09 | 2012-10-17 | 浙江森得保生物制品有限公司 | Specifically effective formula for controlling Pleonomus canaliculatus Faldemann |
| US9615503B2 (en) | 2011-09-23 | 2017-04-11 | Basf Se | Method for cultivating sugar cane |
| CN102771503A (en) * | 2012-08-03 | 2012-11-14 | 广西汇丰生物科技有限公司 | Granule containing chitin |
| CN102771503B (en) * | 2012-08-03 | 2014-01-08 | 广西汇丰生物科技有限公司 | Granule containing chitin |
| CN104522006A (en) * | 2014-12-19 | 2015-04-22 | 湖南化工研究院有限公司 | Composition for preventing and controlling lepidoptera and homopteran pests |
| CN105686963A (en) * | 2016-03-19 | 2016-06-22 | 上海申亚动物保健品阜阳有限公司 | Insectifuge pet shampoo |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1129358C (en) | 2003-12-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1129358C (en) | Pesticide composition containing fipronil | |
| CN101755819A (en) | Insecticidal composition having chlorantraniliprole | |
| CN102349528A (en) | Insecticidal composition containing chlorantraniliprole and indoxacarb | |
| CN101700039A (en) | Rynaxypyr and dursban insecticidal composition | |
| CN101836641B (en) | Oil-suspending agent disinfestation composition containing spinosyns and emamectin benzoate | |
| JP7019566B2 (en) | Liquid pesticide composition | |
| CN101755812A (en) | Insecticidal composition having chlorantraniliprole and thiamethoxam | |
| CN1537428A (en) | Composite of herbicide | |
| CN101755760A (en) | Insecticidal composition having chlorantraniliprole and nitenpyram | |
| CN101700025A (en) | Synergistic insecticidal composition | |
| CN101700035A (en) | Imidacloprid composition | |
| DE69908848T2 (en) | Sprayable insecticidal composition with increased effectiveness | |
| CN1579160A (en) | Synergetic pesticidal composition | |
| CN103155935B (en) | Binary pesticide composition | |
| KR20000067951A (en) | Process and composition for the antiparasitic treatment of the surroundings of animals | |
| CN105613511B (en) | A kind of agricultural pesticide composition and application thereof | |
| CN1559215A (en) | Pesticide compositions contg. Admire | |
| CN101743975A (en) | Insecticidal composition containing pymetrozine and nitenpyram | |
| CN101700030A (en) | Rynaxypyr and hexaflumuron insecticidal composition | |
| CN1286372C (en) | Composition containing hexaflumuron as pesticide for killing pests in paddy field | |
| CN1094223A (en) | Compound pyrethrin pesticide | |
| CN102232386A (en) | Insecticidal composition containing flubendiamide and imidacloprid | |
| CN1620869A (en) | A plurality of synergistic insecticidal composition | |
| CN104026146B (en) | A kind of binary insecticides and purposes | |
| CN116784336A (en) | A kind of composition containing bisamide insecticide and its application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20031203 Termination date: 20131215 |