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CN1260803C - A method for forming shallow grooves - Google Patents

A method for forming shallow grooves Download PDF

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CN1260803C
CN1260803C CN 01132667 CN01132667A CN1260803C CN 1260803 C CN1260803 C CN 1260803C CN 01132667 CN01132667 CN 01132667 CN 01132667 A CN01132667 A CN 01132667A CN 1260803 C CN1260803 C CN 1260803C
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layer
oxide
polysilicon layer
oxide layer
polysilicon
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CN1404128A (en
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赖二琨
陈昕辉
黄宇萍
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Macronix International Co Ltd
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Abstract

The invention provides a method for forming a groove structure, which at least comprises the following steps: forming a pad oxide layer on a substrate; forming a first polysilicon layer on the pad oxide layer; forming an oxide layer on the first polysilicon layer; forming a second polysilicon layer on the oxide layer; removing part of the second polysilicon layer, the oxide layer, the first polysilicon layer and the pad oxide layer to expose part of the substrate; and etching the second polysilicon layer and part of the substrate to form a trench structure in the substrate and expose the oxide layer. The etching depth of the trench structure is well controlled by the etched thickness of the second polysilicon layer.

Description

一种浅沟槽的形成方法A method for forming shallow grooves

技术领域technical field

本发明涉及一种形成浅沟槽的方法,尤其涉及一种可以降低浅沟槽形成时的微载(micro-loading)与降低边角凹陷(corner recess)的浅沟槽形成方法。The invention relates to a method for forming shallow trenches, in particular to a method for forming shallow trenches that can reduce micro-loading and corner recesses during formation of shallow trenches.

背景技术Background technique

传统区域氧化隔离元件的缺点是在场氧化期间,其很容易受到在氮化层底下、狭小的有源区域产生的高应力而导致缺陷形成;其次,也很容易因Kooi效应而产生缺陷。当几何尺寸逐渐缩小,鸟嘴侵入(bird’s beak encroachment)占用场氧表面积的大部分时,愈容易导致缺陷的形成。因而,隔离0.35微米以下的半导体元件时,克服传统方法的缺点以形成良好的隔离区域是很重要的。The disadvantage of traditional area oxide isolation devices is that they are prone to defect formation due to the high stress generated in the narrow active region under the nitride layer during field oxidation; secondly, defects are also easily generated due to the Kooi effect. When the geometric size gradually shrinks, the bird's beak encroachment occupies most of the oxygen surface area of the field, which is more likely to lead to the formation of defects. Therefore, when isolating semiconductor elements below 0.35 microns, it is very important to overcome the shortcomings of traditional methods to form good isolation regions.

在集成电路制作过程中使用浅沟槽隔离(shallow-trench isolation)技术来隔离元件是一种做法。一般而言,在一半导体底材上使用氮化硅作为遮罩,使用非等向性蚀刻制作过程来形成陡峭的沟槽。接着,以氧化物填满沟槽以形成浅沟槽隔离元件,其表面是与底材的表面具有同一水平高度。It is a practice to use shallow-trench isolation (shallow-trench isolation) technology to isolate components during the fabrication of integrated circuits. Generally, steep trenches are formed on a semiconductor substrate using silicon nitride as a mask and anisotropic etching process. Next, the trench is filled with oxide to form a shallow trench isolation device whose surface is at the same level as the surface of the substrate.

不幸的是,对于高整合电路而言,在蚀刻浅槽结构时,会有微载的情形产生;如此时间模式的(time-mode)蚀刻导致难以控制浅沟槽结构的深度。在浅沟槽隔离形成之后,边角凹陷的问题也会导致浅沟槽隔离的劣化。Unfortunately, for highly integrated circuits, when etching the shallow trench structure, there will be microloading; such time-mode etching makes it difficult to control the depth of the shallow trench structure. After the STI is formed, the problem of corner dishing can also lead to the degradation of the STI.

无论如何,在形成浅沟槽隔离元件时,如何改善其特性,并且降低半导体元件可靠度劣化,是很重要的课题。In any case, when forming shallow trench isolation devices, how to improve their characteristics and reduce the reliability degradation of semiconductor devices is a very important issue.

发明内容Contents of the invention

鉴于上述的发明背景中,本发明提供一种形成浅沟槽隔离元件的方法;沟槽的深度由多晶硅的厚度所控制,而非传统的时间模式(time-mode)所控制In view of the above-mentioned background of the invention, the present invention provides a method for forming shallow trench isolation devices; the depth of the trench is controlled by the thickness of the polysilicon, rather than the traditional time-mode (time-mode) control

本发明的另一目的在于提供一种形成沟槽隔离元件的的方法。利用多晶硅层可以避免沟槽隔离元件形成时的微载现象与Kooi效应。Another object of the present invention is to provide a method for forming a trench isolation device. The use of the polysilicon layer can avoid the micro-loading phenomenon and the Kooi effect during the formation of the trench isolation device.

本发明的再一目的在于提供形成沟槽隔离元件的方法;在形成沟槽的衬里层(liner layer)时,多晶硅层的氧化可以避免沟槽的边角凹陷情形产生。Another object of the present invention is to provide a method for forming a trench isolation device; when forming the liner layer of the trench, the oxidation of the polysilicon layer can avoid the occurrence of recessed corners of the trench.

根据以上所述的目的,揭示了一种沟槽结构的形成方法,至少包括:形成垫氧化层于底材上;形成第一多晶硅层于垫氧化层上;形成氧化层于第一多晶硅层上;形成第二多晶硅层于氧化层上;移除部分第二多晶硅层、氧化层、第一多晶硅层与垫氧化层以暴露出部分底材;及蚀刻第二多晶硅层与部分底材以形成沟槽结构于底材中,并暴露出氧化层。沟槽结构的蚀刻深度藉由第二多晶硅层的被蚀刻的厚度有良好的控制。According to the purpose described above, a method for forming a trench structure is disclosed, at least comprising: forming a pad oxide layer on the substrate; forming a first polysilicon layer on the pad oxide layer; forming an oxide layer on the first polysilicon layer on the silicon layer; forming a second polysilicon layer on the oxide layer; removing part of the second polysilicon layer, the oxide layer, the first polysilicon layer and the pad oxide layer to expose part of the substrate; and etching the second polysilicon layer The two polysilicon layers and part of the substrate form a trench structure in the substrate and expose the oxide layer. The etch depth of the trench structure is well controlled by the etched thickness of the second polysilicon layer.

附图说明Description of drawings

本发明配合以下的图可以有更深入的了解:The present invention can have a deeper understanding with the following figures:

图1A至图1F为以本发明方法形成浅沟槽隔离元件的一连串剖面示意图。FIG. 1A to FIG. 1F are a series of schematic cross-sectional views of shallow trench isolation devices formed by the method of the present invention.

具体实施方式Detailed ways

本发明的半导体设计可被广泛地应用到许多半导体设计中,并且可利用许多不同的半导体材料制作,当本发明以一较佳实施例来说明本发明方法时,熟悉此领域者应有的认知是许多的步骤可以改变,材料及杂质也可替换,这些一般的替换无疑地亦不脱离本发明的精神及范畴。The semiconductor design of the present invention can be widely applied in many semiconductor designs, and can utilize many different semiconductor materials to make, when the present invention illustrates the method of the present invention with a preferred embodiment, those who are familiar with this field should recognize It is known that many steps can be changed, and materials and impurities can also be replaced, and these general replacements undoubtedly do not depart from the spirit and scope of the present invention.

其次,本发明用示意图详细描述如下,在详述本发明实施例时,表示半导体结构的剖面图在半导体制作过程中会不依一般比例作局部放大以利说明,然不应以此作为有限定的认知。此外,在实际的制作中,应包含长度、宽度及深度的三维空间尺寸。Secondly, the present invention is described in detail as follows with schematic diagrams. When describing the embodiments of the present invention in detail, the cross-sectional view showing the semiconductor structure will not be partially enlarged according to the general scale in the semiconductor manufacturing process for the convenience of explanation, but it should not be used as a limiting cognition. In addition, in actual production, the three-dimensional space dimensions of length, width and depth should be included.

在此实施例中,揭示一种沟槽结构的形成方法,至少包括:形成一垫氧化层于底材上;形成第一多晶硅层于垫氧化层上;形成氧化层于第一多晶硅层上;形成第二多晶硅层于氧化层上;移除部分第二多晶硅层、氧化层、第一多晶硅层与垫氧化层以暴露出部分底材;及蚀刻第二多晶硅层与部分底材以形成沟槽结构于底材中,并暴露出氧化层。沟槽结构的蚀刻深度藉由第二多晶硅层的被蚀刻的厚度有良好的控制。接着,在沟槽结构的侧壁形成衬里层的同时,在第一多晶硅层的侧壁上形成侧壁氧化层,可保护沟槽结构,以避免边角凹陷。In this embodiment, a method for forming a trench structure is disclosed, at least including: forming a pad oxide layer on the substrate; forming a first polysilicon layer on the pad oxide layer; forming an oxide layer on the first polysilicon layer On the silicon layer; forming a second polysilicon layer on the oxide layer; removing part of the second polysilicon layer, the oxide layer, the first polysilicon layer and the pad oxide layer to expose part of the substrate; and etching the second The polysilicon layer and part of the substrate form a trench structure in the substrate and expose the oxide layer. The etch depth of the trench structure is well controlled by the etched thickness of the second polysilicon layer. Next, while forming the liner layer on the sidewall of the trench structure, a sidewall oxide layer is formed on the sidewall of the first polysilicon layer, which can protect the trench structure and avoid corner depressions.

参照图1A,在硅底材10上形成垫氧化层20,多晶硅层30、氧化层40与另一多晶硅层50依序在其上形成。在多晶硅层50上形成经图案移转、定义沟槽隔离的光阻层60。Referring to FIG. 1A , a pad oxide layer 20 is formed on a silicon substrate 10 , and a polysilicon layer 30 , an oxide layer 40 and another polysilicon layer 50 are sequentially formed thereon. A pattern-transferred photoresist layer 60 defining trench isolation is formed on the polysilicon layer 50 .

蚀刻多晶硅层50、氧化层40、多晶硅层30与垫氧化层20以暴露出硅底材10的部分表面;然后移除光阻层60,如图1B所示。Etching the polysilicon layer 50 , the oxide layer 40 , the polysilicon layer 30 and the pad oxide layer 20 to expose part of the surface of the silicon substrate 10 ; and then removing the photoresist layer 60 , as shown in FIG. 1B .

本发明的关键步骤之一,蚀刻暴露的硅底材10的表面以在硅底材10中形成沟槽;硅底材10的蚀刻由同时蚀刻的多晶硅层50所控制,并且蚀刻停止于氧化层40。再者,多晶硅层50与硅底材10的同时蚀刻可以避免沟槽形成时的微载(micro-loading)情形。如此,沟槽的深度由多晶硅层50的厚度所控制,如图1C所示。One of the key steps of the present invention is etching the exposed surface of the silicon substrate 10 to form a trench in the silicon substrate 10; the etching of the silicon substrate 10 is controlled by the simultaneously etched polysilicon layer 50, and the etching stops at the oxide layer 40. Furthermore, simultaneous etching of the polysilicon layer 50 and the silicon substrate 10 can avoid micro-loading during trench formation. Thus, the depth of the trench is controlled by the thickness of the polysilicon layer 50, as shown in FIG. 1C.

接着,由沟槽的侧壁氧化而形成衬里层70;在衬里层70形成的同时,多晶硅层30的侧壁氧化层90(side-wall oxide layer)也会形成,如图1D所示;因无氮化硅薄层,故于侧壁氧化层90的高温氧化过程中,不会有Kooieffect的情形。Next, the lining layer 70 is formed by oxidation of the sidewall of the trench; while the lining layer 70 is formed, the sidewall oxide layer 90 (side-wall oxide layer) of the polysilicon layer 30 will also be formed, as shown in FIG. 1D; There is no silicon nitride thin layer, so there will be no Kooi effect during the high temperature oxidation process of the sidewall oxide layer 90 .

接着以高密度等离子体化学气相沉积的氧化硅,伴随之后的化学机械研磨方式形成沟槽结构80。之后,以适当的方法移除氧化层40与多晶硅层30,如图1E所示。Then silicon oxide is deposited by high-density plasma chemical vapor phase, followed by chemical mechanical polishing to form the groove structure 80 . Afterwards, the oxide layer 40 and the polysilicon layer 30 are removed by appropriate methods, as shown in FIG. 1E .

之后,移除垫氧化层20;本发明的关键步骤之一,在移除垫氧化层20时,侧壁氧化层90可以保护沟槽结构80,以避免边角凹陷,如图1F所示。After that, the pad oxide layer 20 is removed; one of the key steps of the present invention, when the pad oxide layer 20 is removed, the sidewall oxide layer 90 can protect the trench structure 80 to avoid corner recesses, as shown in FIG. 1F .

以上所述仅为本发明的较佳实施例而已,并非用以限定本发明的申请专利范围;凡其它未脱离本发明所揭示的精神下所完成的等效改变或修饰,均应包含在下述的权利要求范围内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the patent scope of the present invention; all other equivalent changes or modifications that do not deviate from the spirit disclosed in the present invention should be included in the following within the scope of the claims.

Claims (9)

1. the formation method of a groove structure, this method comprises at least:
Form pad oxide on ground;
Form first polysilicon layer on this pad oxide;
Form oxide layer on this first polysilicon layer;
Form second polysilicon layer on this oxide layer;
Remove this second polysilicon layer of part, this oxide layer, this first polysilicon layer and this pad oxide to expose this ground of part; And
This second polysilicon layer of etching and this ground of part to be forming this groove structure in this ground, and expose this oxide layer.
2. method as claimed in claim 1 is characterized in that, also comprises forming backing layer on the first side wall of this groove structure.
3. method as claimed in claim 2 is characterized in that, also comprises forming sidewall oxide on second sidewall of this first polysilicon layer.
4. method as claimed in claim 1 also comprises:
Dielectric layer and is inserted in this groove structure on this oxide layer;
This dielectric layer of planarization and this oxide layer; And
Remove this first polysilicon layer and this pad oxide.
5. method as claimed in claim 4 is characterized in that, above-mentioned deposition step forms with the high density plasma CVD method.
6. the formation method of a groove structure, this method comprises at least:
Form pad oxide on ground;
Form first polysilicon layer on this pad oxide;
Form oxide layer on this first polysilicon layer;
Form second polysilicon layer on this oxide layer;
Remove this second polysilicon layer of part, this oxide layer, this first polysilicon layer and this pad oxide to expose this ground of part;
This second polysilicon layer of etching and this ground of part to be forming groove structure in this ground, and expose this oxide layer; And
Form simultaneously backing layer on the sidewall of this groove structure with sidewall oxide on the sidewall of this first polysilicon, this sidewall oxide is in order to protecting this groove structure, to avoid the corner depression.
7. method as claimed in claim 6 is characterized in that, also comprises:
Insert dielectric layer in this groove structure with this oxide layer on; And
This dielectric layer of planarization and this oxide layer.
8. method as claimed in claim 7 is characterized in that above-mentioned dielectric layer comprises silicon oxide layer at least.
9. method as claimed in claim 7 is characterized in that above-mentioned dielectric layer comprises polysilicon layer at least.
CN 01132667 2001-09-06 2001-09-06 A method for forming shallow grooves Expired - Fee Related CN1260803C (en)

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CN 01132667 CN1260803C (en) 2001-09-06 2001-09-06 A method for forming shallow grooves

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CN1260803C true CN1260803C (en) 2006-06-21

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