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CN1260324C - Organic fireproofing plugging - Google Patents

Organic fireproofing plugging Download PDF

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Publication number
CN1260324C
CN1260324C CN 200310111118 CN200310111118A CN1260324C CN 1260324 C CN1260324 C CN 1260324C CN 200310111118 CN200310111118 CN 200310111118 CN 200310111118 A CN200310111118 A CN 200310111118A CN 1260324 C CN1260324 C CN 1260324C
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fireproof
organic
calcium carbonate
weight
plugging material
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Expired - Fee Related
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CN 200310111118
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CN1626619A (en
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覃文清
戚天游
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Sichuan Fire Research Institute of Ministry of Public Security
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Sichuan Fire Research Institute of Ministry of Public Security
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Abstract

The present invention discloses an organic fireproof plugging material which relates to a fireproof material, particularly to a fireproof plugging material used for plugging penetrative openings and building gaps. The organic fireproof plugging material aims to solve the problems of bad plasticity and bad pliability of the existing plugging materials. The organic fireproof plugging material is prepared by mixing the following raw materials according to the percentage by weight: 33 to 38 of diethyl silicon oil, 32 to 37 of light calcium carbonate or/and large calcium carbonate, 1 to 3 of expanded perlite or /and expanded vermiculite, 17 to 23 of filler and 3 to 6 of flame retardant agent, wherein the flame retardant agent is at least one kind of aluminium hydroxide, hydrated zinc borate and magnesium hydroxide; the filler is at least one kind of natural diatomite, talc powder and bentone. The organic fireproof plugging material is suitable for the fireproof plugging of holes and gaps of electric wires, cables, pipelines, and the like of power plants, transformer stations, industrial and mining factory buildings, high buildings, and the like for preventing the spread of flame and smog, and the plugging material has the advantages of good fireproof performance and long-term plasticity and pliability.

Description

有机防火堵料Organic fireproof blocking material

技术领域technical field

本发明涉及耐火材料,特别是封堵贯穿性开口和建筑缝隙的防火堵料。The invention relates to a refractory material, especially a fireproof blocking material for sealing penetrating openings and building gaps.

背景技术Background technique

根据GBJ 16-87《建筑设计防火规范》和GB 50045-95《高层民用建筑设计防火规范》,作为房屋建筑防火分区的墙和楼板的贯穿物(如电缆、风管等)穿过时所形成的开口等处,必须对其进行防火封堵,以防止火灾发生时从一个分区扩散到另一个分区以及有毒烟气的蔓延。有机防火堵料是最常用的防火封堵材料。According to GBJ 16-87 "Code for Fire Protection Design of Buildings" and GB 50045-95 "Code for Fire Protection Design of High-Rise Civil Buildings", the penetrations (such as cables, air ducts, etc.) Openings, etc., must be fireproofed to prevent the spread of fire from one partition to another and the spread of toxic fumes in the event of a fire. Organic fireproof blocking material is the most commonly used fireproof sealing material.

但是,目前使用的有机防火堵料,在使用过程中,因为粘接剂老化以及环境温度等原因而常常固化。固化后,有的体积收缩而形成缝隙,造成封堵不严密,留下了安全隐患;再者固化后较为坚硬,不便于电缆的检修更换。还有的堵料其耐火性能不好,在火灾发生时易烧裂而不能有效阻止火焰和烟气蔓延。However, the currently used organic fireproofing materials are often cured due to the aging of the adhesive and the ambient temperature during use. After curing, some volume shrinks to form gaps, resulting in imprecise sealing, leaving a safety hazard; moreover, it is relatively hard after curing, which is not convenient for cable maintenance and replacement. Some blocking materials have poor fire resistance, and are easy to burn and crack when a fire occurs, but cannot effectively prevent the flame and smoke from spreading.

发明内容Contents of the invention

鉴于上述,本发明的目的就是解决有机防火堵料在使用过程中固化而不利于施工、检修的缺陷,提供一种耐火性能高、可塑性和柔韧性好的有机防火堵料。In view of the above, the purpose of the present invention is to solve the defect that the organic fireproof blockage is unfavorable for construction and maintenance during use, and to provide an organic fireproof blockage with high fire resistance, good plasticity and flexibility.

本发明采用二乙基硅油,能使堵料具有长期的可塑性和柔韧性;并采用不燃性无机填料与填/接缝隙材料、阻燃剂、防火材料合理配比来实现其目的。The invention adopts diethyl silicone oil, which can make the blocking material have long-term plasticity and flexibility; and adopts non-combustible inorganic filler, filling/connecting gap material, flame retardant, and fireproof material in a reasonable ratio to achieve its purpose.

本发明的有机防火堵料,有如下按重量份计量的原料混合构成:The organic fireproof blockage of the present invention is composed of the following raw materials mixed in parts by weight:

二乙基硅油33~38,轻质碳酸钙或重质碳酸钙32~37,膨胀珍珠岩或膨胀蛭石1~3,填料17~23,阻燃剂3~6,上述阻燃剂是氢氧化铝、水合硼酸锌和氢氧化镁中的至少一种。Diethyl silicone oil 33~38, light calcium carbonate or heavy calcium carbonate 32~37, expanded perlite or expanded vermiculite 1~3, filler 17~23, flame retardant 3~6, the above flame retardant is hydrogen At least one of aluminum oxide, zinc borate hydrate, and magnesium hydroxide.

上述阻燃剂的总配量是3~6重量份,当选用其中的两种或三种时,各原料的配量在总配量范围内任意调整。The total dosage of the above flame retardants is 3-6 parts by weight. When two or three of them are selected, the dosage of each raw material can be adjusted arbitrarily within the range of the total dosage.

上述的填料是天然硅藻土、滑石粉和膨润土中的至少一种。填料总配量是17~23重量份,当选用其中的两种或三种时,各原料的配量可在总配量范围内任意调整。The above-mentioned filler is at least one of natural diatomite, talcum powder and bentonite. The total amount of fillers is 17-23 parts by weight. When two or three of them are selected, the amount of each raw material can be adjusted arbitrarily within the range of the total amount.

本发明中的二乙基硅油,它具有耐高、低温性和优良的耐老化性及化学稳定性,能使堵料具有长期的可塑性和柔韧性。轻质碳酸钙和重质碳酸钙为填/接缝隙材料。填料是天然硅藻土、滑石粉和膨润土中的至少一种,均为无毒、能耐高温的不燃性材料。其中,天然硅藻土的主要功能是提高堵料的柔韧性和耐热性;滑石粉的加入能使堵料具有适应伸缩等变形的能力;膨润土可以改善堵料的可塑性。膨胀珍珠岩和膨胀蛭石是防火材料,二者均为质轻、导热系数低的多孔性材料,能提高堵料的耐火性能。阻燃剂是氢氧化铝、水合硼酸锌和氢氧化镁中的至少一种。三者均为高效、价廉、无毒的无机阻燃剂,可以提高堵料的耐火性能,并且能有效地抑制堵料受火时烟气的生成。The diethyl silicone oil in the present invention has high and low temperature resistance, excellent aging resistance and chemical stability, and can make the blocking material have long-term plasticity and flexibility. Light calcium carbonate and heavy calcium carbonate are gap filling/connecting materials. The filler is at least one of natural diatomite, talcum powder and bentonite, all of which are non-toxic, non-combustible materials capable of high temperature resistance. Among them, the main function of natural diatomite is to improve the flexibility and heat resistance of the blockage; the addition of talcum powder can make the blockage have the ability to adapt to deformation such as expansion and contraction; bentonite can improve the plasticity of the blockage. Expanded perlite and expanded vermiculite are fireproof materials, both of which are porous materials with light weight and low thermal conductivity, which can improve the fire resistance of the blockage. The flame retardant is at least one of aluminum hydroxide, zinc borate hydrate and magnesium hydroxide. All three are high-efficiency, cheap and non-toxic inorganic flame retardants, which can improve the fire resistance of the blockage, and can effectively inhibit the generation of smoke when the blockage is exposed to fire.

本发明经国家防火建筑材料质量监督检验中心检验,检测结果见表1:The present invention is inspected by the National Fireproof Building Material Quality Supervision and Inspection Center, and the test results are shown in Table 1:

表1  本发明的有机防火堵料的性能指标   序号   检验项目   技术指标   实测结果   结论 1 耐火性能(min)   一级:≥180二级:≥120三级:≥60 194~241 一级合格   2   外观   塑性固体,具有一定柔韧性   符合要求   合格   3   密度(kg/m3)   ≤2.0×103   1.6×103   合格   4   耐水性(天)   ≥3,无溶胀   符合要求   合格   5   耐油性(天)   ≥3,无溶胀   符合要求   合格   6   腐蚀性(天)   ≥7,无锈蚀及腐蚀现象   符合要求   合格 Table 1 Performance index of the organic fireproof blocking material of the present invention serial number Test items technical indicators results of testing in conclusion 1 Fire resistance (min) Level 1: ≥180 Level 2: ≥120 Level 3: ≥60 194~241 Qualified 2 Exterior Plastic solid, with some flexibility meet the requirements qualified 3 Density(kg/m 3 ) ≤2.0×10 3 1.6×10 3 qualified 4 Water resistance (days) ≥3, no swelling meet the requirements qualified 5 Oil resistance (days) ≥3, no swelling meet the requirements qualified 6 Corrosive (days) ≥7, no rust and corrosion meet the requirements qualified

如上所述,本发明的有机防火堵料与现有有机防火堵料比较,防火隔热效果显著,理化性能优良,耐候性好,具有优良的耐火性能。本堵料是一种柔性体,封堵性能优良,能适应实际运用中由于温差以及机械变形等形成的缝隙;具有长期的可塑性和柔韧性,便于安装、更换、检修。当火灾发生时,在高温的作用下,堵料中各组份协同作用,使堵料体积稍微膨胀,形成坚固的阻火隔热层,能将各种开口和缝隙封堵严密,有效地阻止火焰传播和烟气蔓延。此外,本发明的有机防火堵料,原料来源丰富易得,生产工艺简单,对管道、电线电缆等无腐蚀作用。As mentioned above, compared with the existing organic fireproof blockage, the organic fireproof blockage of the present invention has remarkable fireproof and heat insulation effects, excellent physical and chemical properties, good weather resistance, and excellent fire resistance. The blockage is a kind of flexible body with excellent sealing performance, which can adapt to the gaps formed by temperature difference and mechanical deformation in actual use; it has long-term plasticity and flexibility, and is easy to install, replace, and repair. When a fire breaks out, under the effect of high temperature, the components in the putty will act synergistically to make the volume of the putty slightly expand to form a strong fire-retardant and heat-insulating layer, which can tightly seal various openings and gaps and effectively prevent fires. Flame spread and smoke spread. In addition, the organic fireproof blocking material of the present invention has rich and easy-to-obtain raw material sources, simple production process, and no corrosive effect on pipes, wires and cables, etc.

本发明适用于电厂、变电站、工矿厂房、高层建筑等场所电线电缆与管道等孔洞、缝隙的防火封堵,阻止火焰和烟雾蔓延。The invention is suitable for fireproofing and sealing holes and gaps of wire cables and pipes in power plants, substations, industrial and mining workshops, high-rise buildings, etc., to prevent flames and smoke from spreading.

下面,再用实施例对本发明作进一步地说明。Below, the present invention will be further described with examples.

具体实施方式Detailed ways

实施例Example

本发明的有机防火堵料,按表2的用量,按重量份数称量各原料组分,捏合均匀成具有一定柔韧性的塑性固体,然后称量、包装即可。For the organic fireproof blockage of the present invention, according to the dosage in Table 2, weigh each raw material component by parts by weight, knead evenly to form a plastic solid with certain flexibility, then weigh and pack.

表2  实施例的原料和配量(重量份)、耐火性能   实施例   1   2   3   4   5   6   主料   二乙基硅油   33   36   34   35   38   37   填/接隙缝材料   轻质碳酸钙   32   37   34   17   重质碳酸钙   36   33   18   填料   天然硅藻土   20   17   10   16   11   14   滑石粉   4   7   4   膨润土   3   11   4 防火材料   膨胀珍珠岩   1.5   2   2   1   3   1   膨胀蛭石   0.5   1   阻燃剂   氢氧化铝   6   5   2   水合硼酸锌   3   4.5   氢氧化镁   3.5   2   耐火性能(min)   241   213   202   225   198   194 Raw materials and proportioning (parts by weight), refractory performance of table 2 embodiment Example 1 2 3 4 5 6 main ingredient diethyl silicone oil 33 36 34 35 38 37 Filler/Gap Material light calcium carbonate 32 37 34 17 Ground calcium carbonate 36 33 18 filler natural diatomaceous earth 20 17 10 16 11 14 talcum powder 4 7 4 Bentonite 3 11 4 Fireproof Materials expanded perlite 1.5 2 2 1 3 1 Expanded Vermiculite 0.5 1 flame retardant Aluminum hydroxide 6 5 2 Zinc borate hydrate 3 4.5 magnesium hydroxide 3.5 2 Fire resistance (min) 241 213 202 225 198 194

Claims (8)

1, a kind of organic fire prevention calking, it is characterized in that having the raw material of following amount by weight to mix formation: diethyl silicone oil 33~38, light calcium carbonate is or/and water-ground limestone 32~37, pearlstone is or/and expanded vermiculite 1~3, filler 17~23, fire retardant 3~6, above-mentioned fire retardant are at least a in aluminium hydroxide, hydration zinc borate and the magnesium hydroxide.
2, organic fire prevention calking according to claim 1 is characterized in that said filler is at least a in natural diatomaceous earth, talcum powder and the wilkinite.
3, organic fire prevention calking according to claim 2 is characterized in that having the following raw material of amount by weight: diethyl silicone oil 33, light calcium carbonate 32, natural diatomaceous earth 20, pearlstone 1.5, aluminium hydroxide 6.
4, organic fire prevention calking according to claim 2 is characterized in that being made of the raw material mixing of following metering by weight: diethyl silicone oil 36, light calcium carbonate 37, natural diatomaceous earth 17, talcum powder 4, pearlstone 2, aluminium hydroxide 5.
5, organic fire prevention calking according to claim 2 is characterized in that having the following raw material of amount by weight: diethyl silicone oil 34, light calcium carbonate 34, natural diatomaceous earth 10, talcum powder 7, pearlstone 2, expanded vermiculite 0.5, magnesium hydroxide 3.5.
6, organic fire prevention calking according to claim 2 is characterized in that having the following raw material of amount by weight: diethyl silicone oil 35, water-ground limestone 36, natural diatomaceous earth 16, talcum powder 4, wilkinite 3, pearlstone 1, expanded vermiculite 1, hydration zinc borate 3.
7, organic fire prevention calking according to claim 2 is characterized in that having the following raw material of amount by weight: diethyl silicone oil 38, water-ground limestone 33, natural diatomaceous earth 11, wilkinite 11, pearlstone 3, hydration zinc borate 4.5.
8, organic fire prevention calking according to claim 2 is characterized in that having the following raw material of amount by weight: diethyl silicone oil 37, water-ground limestone 17, light calcium carbonate 18, natural diatomaceous earth 14, wilkinite 4, pearlstone 1, aluminium hydroxide 2, magnesium hydroxide 2.
CN 200310111118 2003-12-08 2003-12-08 Organic fireproofing plugging Expired - Fee Related CN1260324C (en)

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* Cited by examiner, † Cited by third party
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CN101503614B (en) * 2008-02-05 2012-03-07 嵊州市电缆防火附件厂 Preparation of expansion type halogen-free organic fireproofing blocking material
CN101277007B (en) * 2008-05-21 2010-04-07 苍南县永盛电力工程有限公司 Technique and fixed frame for construction of cable fireproof organic block material
CN101423744B (en) * 2008-06-23 2011-11-09 卜伟荣 Preparation method of organic fire prevention calking composition
CN101968061A (en) * 2010-11-19 2011-02-09 苏州顶裕节能设备有限公司 Explosionproof fan
CN103337263B (en) * 2013-06-19 2016-01-20 浙江川科防保材料发展有限公司 A kind of nuclear power cable Combined fireproof plugging module and preparation method thereof
CN104861664A (en) * 2015-04-23 2015-08-26 铜陵祥云消防科技有限责任公司 Bird pecking-proofing fireproof jam material and preparation method thereof
CN104861660A (en) * 2015-04-23 2015-08-26 铜陵祥云消防科技有限责任公司 Weatherproof fireproof jam material and preparation method thereof
CN104845372A (en) * 2015-04-23 2015-08-19 铜陵祥云消防科技有限责任公司 Tension resistant fireproof putty and preparation method thereof
CN104845390A (en) * 2015-04-23 2015-08-19 铜陵祥云消防科技有限责任公司 Mouse, ant and snake resistant fireproof putty and preparation method thereof
CN105958653B (en) * 2016-06-30 2018-10-19 国网山东省电力公司招远市供电公司 A kind of dispatching of power netwoks monitoring early-warning system and its method
CN107746575A (en) * 2017-09-22 2018-03-02 镇江市太浪新材料科技有限公司 A kind of fire retardant for building organic fire prevention calking
CN107805391A (en) * 2017-09-28 2018-03-16 公安部四川消防研究所 A kind of silicon rubber fire retardant module and preparation method thereof
CN107902976A (en) * 2017-09-28 2018-04-13 公安部四川消防研究所 A kind of environmental protection fire retardant module and preparation method thereof
CN110760193A (en) * 2019-11-20 2020-02-07 河南东风电力工程有限公司 Organic fireproof blocking material
CN112961500A (en) * 2021-03-18 2021-06-15 广州德海高分子材料科技有限公司 Non-solidified type sealing fireproof moistureproof silica gel mud and preparation method thereof
CN114907054B (en) * 2022-04-02 2023-05-12 北京交通大学 A kind of non-solidified fireproof plugging silica gel mud and preparation method thereof

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Assignee: SICHUAN TIANFU FIRE MATERIAL CO.,LTD.

Assignor: SICHUAN FIRE Research Institute OF MINISTRY OF PUBLIC SECURITY

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