CN1254505A - Agricultural compound bactericide - Google Patents
Agricultural compound bactericide Download PDFInfo
- Publication number
- CN1254505A CN1254505A CN 99125998 CN99125998A CN1254505A CN 1254505 A CN1254505 A CN 1254505A CN 99125998 CN99125998 CN 99125998 CN 99125998 A CN99125998 A CN 99125998A CN 1254505 A CN1254505 A CN 1254505A
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- Prior art keywords
- represent hydrogen
- represent
- alkyl
- general formula
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003899 bactericide agent Substances 0.000 title claims abstract description 12
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 11
- 150000001875 compounds Chemical class 0.000 title abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 27
- 239000001257 hydrogen Substances 0.000 claims abstract description 27
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 15
- LVDKZNITIUWNER-UHFFFAOYSA-N Bronopol Chemical compound OCC(Br)(CO)[N+]([O-])=O LVDKZNITIUWNER-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229960003168 bronopol Drugs 0.000 claims abstract description 13
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 5
- 125000004414 alkyl thio group Chemical group 0.000 claims abstract description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 24
- 239000002131 composite material Substances 0.000 claims description 10
- 230000002070 germicidal effect Effects 0.000 claims description 8
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 5
- 239000007900 aqueous suspension Substances 0.000 claims description 4
- 239000006013 carbendazim Substances 0.000 claims description 4
- 239000000645 desinfectant Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims description 3
- HXHWSAZORRCQMX-UHFFFAOYSA-N albendazole Chemical group CCCSC1=CC=C2NC(NC(=O)OC)=NC2=C1 HXHWSAZORRCQMX-UHFFFAOYSA-N 0.000 claims description 3
- 229960002669 albendazole Drugs 0.000 claims description 3
- RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 claims description 3
- MITFXPHMIHQXPI-UHFFFAOYSA-N benzoxaprofen Natural products N=1C2=CC(C(C(O)=O)C)=CC=C2OC=1C1=CC=C(Cl)C=C1 MITFXPHMIHQXPI-UHFFFAOYSA-N 0.000 claims description 3
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical group C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 claims description 3
- 239000000375 suspending agent Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 abstract description 4
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 244000061176 Nicotiana tabacum Species 0.000 abstract 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 235000007164 Oryza sativa Nutrition 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 201000010099 disease Diseases 0.000 abstract 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract 1
- 235000013399 edible fruits Nutrition 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 235000009566 rice Nutrition 0.000 abstract 1
- 235000013311 vegetables Nutrition 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 description 5
- -1 papermaking Substances 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- 238000012271 agricultural production Methods 0.000 description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- JXBLYSQTCABEMR-UHFFFAOYSA-N 1,3-dihydrobenzimidazol-2-ylidene(methoxycarbonyl)azanium;chloride Chemical compound [Cl-].C1=CC=C2NC(=[NH+]C(=O)OC)NC2=C1 JXBLYSQTCABEMR-UHFFFAOYSA-N 0.000 description 1
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 241000235070 Saccharomyces Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a new pesticide prepared by compounding bronopol and benzimidazole bactericide or acid salt thereofA bactericide is used. The benzimidazole bactericide is represented by a general formula , wherein R in the formula1Represents hydrogen or alkyl. R2Represents hydrogen, alkyl, alkoxy, alkylthio. R3Represents hydrogen or alkyl. The compound agent shows good synergistic performance and is suitable for preventing and killing various diseases of rice, fruit trees, vegetables and tobacco.
Description
It is composite with as a kind of new disinfectant use in agriculture to the present invention relates to bronopol and benzimidazole germicide or its ackd salt.
The bronopol chemical name is a 2-bromo-2-nitro-1, ammediol.This compound is the earliest as a kind of industrial bactericide, is widely used in aspects such as water treatment, leather, papermaking, cosmetics be anticorrosion.After be developed again and be used for agricultural seed treatment.Bronopol all has high activity to most bacteriums and fungi, can kill or suppress the growth of germ under extremely low concentration fully.
The benzimidazole germicide of general formula (I)
(R in the formula
1Represent hydrogen, alkyl.R
2Represent hydrogen, alkyl, alkoxyl, alkylthio group.R
3Represent hydrogen, alkyl.) be the important disinfectant use in agriculture of a class.For Saccharomyces, Dendrochium and Basidiomycotina all have effect preferably.This series bactericidal agent is used for agricultural production with the form of simple substance or strong acid salt usually, and the form of strong acid salt has better control efficiency generally speaking.
In general formula (I), with R
1Be hydrogen, R
2Be hydrogen, R
3Carbendazim for the methyl representative.With R
1Be normal-butyl, R
2Be hydrogen, R
3Benomyl for the methyl representative.With R
1Be hydrogen, R
2Be rosickyite base, R
3In agricultural production, obtained extensive use for the albendazole of methyl representative is all own.
We find to have demonstrated splendid Synergistic performance under study for action surprisingly when bronopol and benzimidazole germicide or its ackd salt are composite.Though its synergy mechanism also is not determined at present.But has potential using value undoubtedly.
The objective of the invention is to provide a kind of new by bronopol with have the benzimidazole germicide of general formula (I) or the compound sterilizing mixture of its ackd salt.R in the formula
1Represent hydrogen, alkyl.R
2Represent hydrogen, alkyl, alkoxyl, alkylthio group.R
3Represent hydrogen, alkyl.
Another object of the present invention is to provide this compound mixture type and and technology of preparing and the application in agricultural production.
A component of the composite bactericide that the present invention relates to is a bronopol, and its chemical name is a 2-bromo-2-nitro-1, ammediol.
Another component of the composite bactericide that the present invention relates to has general formula (I)
The benzimidazole sterilization.R in the formula
1Represent hydrogen, alkyl.R
2Represent hydrogen, alkyl, alkoxyl, alkylthio group.R
3Represent hydrogen, alkyl.That have typical meaning is carbendazim (R
1Represent hydrogen, R
2Represent hydrogen, R
3Represent methylidene).Benomyl (R
1Represent normal-butyl, R
2Represent hydrogen, R
3Represent methylidene).Albendazole (R
1Represent hydrogen, R
2Represent n-pro-pyl, R
3And its their strong acid salt represent methylidene).
The agent shape of composite bactericide of the present invention can be wetting powder, aqueous suspension agent, colloidal suspending agent, and the content of its effective ingredient bronopol (mass ratio) can be between 0.1～90%.Be preferably in 1.5～50%.The content of benzimidazole germicide (mass ratio) can be between 0.1～90%.Be preferably between 5～75%.The required auxiliary agent of using comprises carrier, wetting agent, dispersant, thickener, defoamer, crystallization inhibitor etc. during the preparation formulation.
Wherein carrier comprises silicon bath soil, kaolin, atlapulgite, white carbon etc.Its consumption can be preferably between 20～80% between 10～90%.
Wetting agent and dispersant are various in style, and common a kind of surfactant can play wetting and peptizaiton simultaneously.Wetting agent and dispersant commonly used in pesticidal preparations have lignin sulfonic acid sodium salt or calcium salt, dodecyl sodium sulfate, alkylphenol polyoxyethylene, alkylphenol polyoxyethylene phosphate (salt), oxirane and propylene oxide block polymer etc.Total consumption of wetting agent and dispersant can be preferably between 5%-10% between 3%-15%.
Thickener and defoamer are used for the preparation of colloidal suspending agent or aqueous suspension agent.Thickener commonly used has carboxymethyl cellulose, methylcellulose, polyvinyl alcohol, polyacrylamide, xanthans etc.Its consumption can be regulated as the case may be, generally is no more than 10%.Be preferably between the 0.2-5%.Defoamer can be selected silicone based defoamer, polyalcohol and ester defoamer thereof etc. for use.Its consumption is generally between 0.05%-1%.
Example one wetting powder (wt/wt)
Bronopol 20%
Benomyl 20%
Ultra-fine silicon bath soil 50%
Sodium lignin sulfonate 4%
Calcium lignosulfonate 3%
Dodecyl sodium sulfate 3%
Example two wetting powders (wt/wt)
Bronopol 10%
Carbendazim hydrochloride 40%
Ultra-fine silicon bath soil 40%
Sodium lignin sulfonate 6%
Dodecyl sodium sulfate 4%
Example three aqueous suspensions (wt/wt)
Carbendazim 25%
Bronopol 10%
Sodium lignin sulfonate 6%
Polyoxyethylene nonylphenol ether 4%
Xanthans 0.2%
Silicone defoaming agent 0.3%
Water surplus
Claims (8)
1. the represented benzimidazole germicide of bronopol and general formula (I) or its ackd salt are composite with as new disinfectant use in agriculture, R in the formula
1Represent hydrogen, alkyl.R
2Represent hydrogen, alkyl, alkoxyl, alkylthio group, R
3Represent hydrogen, alkyl.
2. according to claim 1, the agent type of composite bactericide is wetting powder, aqueous suspension agent, colloidal suspending agent.
3. according to claim 1, the shared mass ratio of bronopol is 0.1～90% in the composite bactericide.
4. according to claim 1, the shared mass ratio of benzimidazole germicide that has general formula (I) in the composite bactericide is 0.1～90%.
5. according to claim 1, R in general formula (I)
1Represent hydrogen, R
2Represent hydrogen, R
3Represent methylidene.Should kill agent is carbendazim and ackd salt thereof.
6. according to claim 1, R in general formula (I)
1Represent normal-butyl, R
2Represent hydrogen, R
3Represent methylidene.Should kill agent is benomyl and ackd salt thereof.
7. according to claim 1, R in general formula (I)
1Represent hydrogen, R
2Represent the rosickyite base, R
3Represent methylidene.Should kill agent is albendazole and ackd salt thereof.
8. according to claim 1, benzimidazole germicide with the form of simple substance or ackd salt as composite component.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99125998 CN1254505A (en) | 1999-12-13 | 1999-12-13 | Agricultural compound bactericide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99125998 CN1254505A (en) | 1999-12-13 | 1999-12-13 | Agricultural compound bactericide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1254505A true CN1254505A (en) | 2000-05-31 |
Family
ID=5284273
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99125998 Pending CN1254505A (en) | 1999-12-13 | 1999-12-13 | Agricultural compound bactericide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1254505A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101708187B (en) * | 2009-02-27 | 2011-05-18 | 上海海洋大学 | Dry powder preparation for preventing and controlling saprolegniasis of aquatic animals and preparation method thereof |
| CN102061643A (en) * | 2010-12-11 | 2011-05-18 | 李洪社 | Novel compound papermaking bactericide |
| CN105123724A (en) * | 2015-09-09 | 2015-12-09 | 江苏省绿盾植保农药实验有限公司 | Bactericidal composition containing picoxystrobin and albendazole |
| US9861094B2 (en) * | 2008-03-13 | 2018-01-09 | Ogf | Composition and method for tissue preservation and embalming |
| CN107593715A (en) * | 2017-11-10 | 2018-01-19 | 张颂忠 | A kind of composition pesticide containing Ningnanmycin |
| CN107821393A (en) * | 2017-11-10 | 2018-03-23 | 惠州市无龄康态健康科技有限公司 | A kind of composition pesticide containing kasugarnycin |
| CN108112593A (en) * | 2016-11-28 | 2018-06-05 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing bronopol |
| CN108112594A (en) * | 2016-11-28 | 2018-06-05 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing bronopol |
| CN108112592A (en) * | 2016-11-28 | 2018-06-05 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing bronopol |
| CN108260594A (en) * | 2017-01-03 | 2018-07-10 | 陕西美邦农药有限公司 | A kind of Synergistic bactericidal composition containing bronopol |
| CN113287621A (en) * | 2021-05-07 | 2021-08-24 | 广东省农业科学院果树研究所 | Application of imidazole derivative A in preparation of pesticide bactericide for preventing and treating banana fusarium wilt |
-
1999
- 1999-12-13 CN CN 99125998 patent/CN1254505A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9861094B2 (en) * | 2008-03-13 | 2018-01-09 | Ogf | Composition and method for tissue preservation and embalming |
| CN101708187B (en) * | 2009-02-27 | 2011-05-18 | 上海海洋大学 | Dry powder preparation for preventing and controlling saprolegniasis of aquatic animals and preparation method thereof |
| CN102061643A (en) * | 2010-12-11 | 2011-05-18 | 李洪社 | Novel compound papermaking bactericide |
| CN105123724A (en) * | 2015-09-09 | 2015-12-09 | 江苏省绿盾植保农药实验有限公司 | Bactericidal composition containing picoxystrobin and albendazole |
| CN108112593A (en) * | 2016-11-28 | 2018-06-05 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing bronopol |
| CN108112594A (en) * | 2016-11-28 | 2018-06-05 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing bronopol |
| CN108112592A (en) * | 2016-11-28 | 2018-06-05 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing bronopol |
| CN108260594A (en) * | 2017-01-03 | 2018-07-10 | 陕西美邦农药有限公司 | A kind of Synergistic bactericidal composition containing bronopol |
| CN107593715A (en) * | 2017-11-10 | 2018-01-19 | 张颂忠 | A kind of composition pesticide containing Ningnanmycin |
| CN107821393A (en) * | 2017-11-10 | 2018-03-23 | 惠州市无龄康态健康科技有限公司 | A kind of composition pesticide containing kasugarnycin |
| CN113287621A (en) * | 2021-05-07 | 2021-08-24 | 广东省农业科学院果树研究所 | Application of imidazole derivative A in preparation of pesticide bactericide for preventing and treating banana fusarium wilt |
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