CN1244481C - Anti-false bottle cap with thermo-color and invisible fluorescence display as well as mfg. and operation method - Google Patents
Anti-false bottle cap with thermo-color and invisible fluorescence display as well as mfg. and operation method Download PDFInfo
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- CN1244481C CN1244481C CN 03117218 CN03117218A CN1244481C CN 1244481 C CN1244481 C CN 1244481C CN 03117218 CN03117218 CN 03117218 CN 03117218 A CN03117218 A CN 03117218A CN 1244481 C CN1244481 C CN 1244481C
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- Prior art keywords
- bottle cap
- fake
- mark
- ink
- fluorescent
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- 238000000034 method Methods 0.000 title claims abstract description 26
- 238000007639 printing Methods 0.000 claims abstract description 34
- 239000003973 paint Substances 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 230000037452 priming Effects 0.000 claims abstract description 4
- 230000003647 oxidation Effects 0.000 claims description 24
- 238000007254 oxidation reaction Methods 0.000 claims description 24
- 239000003085 diluting agent Substances 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 239000007921 spray Substances 0.000 claims description 9
- 239000002966 varnish Substances 0.000 claims description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000004381 surface treatment Methods 0.000 claims description 6
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 238000007650 screen-printing Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 11
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000002537 cosmetic Substances 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 238000006073 displacement reaction Methods 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 33
- 239000000047 product Substances 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 4
- 229910002114 biscuit porcelain Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 101100160821 Bacillus subtilis (strain 168) yxdJ gene Proteins 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
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- 229920003023 plastic Polymers 0.000 description 1
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Abstract
The present invention relates to an anti-counterfeiting bottle cap and a manufacture and use method thereof. The bottle cap is printed with a thermo-allochroic ink layer and an invisible fluorescent display ink layer of trademarks, patterns, characters and letters to form two kinds of anti-counterfeiting marks, wherein the two kinds of marks can be used singly or simultaneously, and can be arranged in a displacement mode. Two kinds of mixing ink can be used for printing one kind of mark. In identification, the thermo-allochroic ink layer changes color or disappears after heating, and the invisible fluorescent display ink layer is displayed by the irradiation of an ultraviolet lamp. The place between the printing layers and the bottle cap can be painted by priming paint, and the surface of the bottle cap can be painted by surface paint to obtain the effects of brightness and clearness. The anti-counterfeiting bottle cap has double-anti-counterfeiting effects, and with the displacement arrangement, the present invention has the advantages of difficult imitation and favorable anti-counterfeiting effect. The present invention is suitable for various bottle type vessels and especially for alcohol type and cosmetic vessels.
Description
(1) technical field: the present invention relates to a kind of bottle cap that anti-fake mark arranged and manufacturing, using method, be specially adapted to bottle cap containers such as drinks and cosmetics, belong to the mouth piece class (B65D) and the typographic(al) mark technology class (B41M) of storing material and transfer cask.
(2) background technology:
Chinese patent ' anti-fake bottle lid ' (patent No. 93244688.4) discloses a kind of light-emitting phosphor bisque that is printed with on bottle cap, the bottle cap of the anti-fake mark that detects with ultraviolet light; Chinese patent ' touches the color-changing anti-counterfeit bottle cap ', and (patent No. 98213465) discloses a kind of bottle cap that is printed with the temperature sensitive ink anti-fake mark on bottle cap again.Though both all can differentiate and prevent fake and forged bottled product, its antifalse effect is a mono-, and every kind of structure is subject to copy, and antifalse effect is poor.
The discoloring temperature of above-mentioned ' touching the color-changing anti-counterfeit bottle cap ' temperature sensitive ink layer is for touching the temperature of hand, it is human body temperature, be about 35～37 ℃, when summer, ambient temperature surpassed 35 ℃, touch temperature sensitive ink layer pattern literal automatic color-changing on the bottle cap, if the trade mark character pattern disappears automatically, the trade mark that the customer can't be declared recognize commodity etc. influence the normal sale of commodity.Be printed with the light-emitting phosphor powder on above-mentioned ' anti-fake bottle lid ', demonstrate peculiar pattern by the irradiation luminous bisque of purple light during use, trade mark, literal etc. (seeing that the 1st page of 13-15 of this document specification sheets is capable).This as can be seen luminous bisque also can show pattern under daylight, trade mark, literal (luminescent powder is coloured), when shining, purple light just shows a kind of distinctive (luminous) pattern, trade mark, literal (as the luminous bisque that is coated with on the existing invoice), the antifalse effect of this non-concealed fluorescent anti-fake bottle lid is poor.
(3) summary of the invention:
The present invention will solve temperature sensitive ink layer discoloring temperature is low on the existing anti-fake bottle lid the defective and the problem of non-concealed fluorescent layer and single ink lay antifalse effect difference addressed.Its technical scheme is as follows: the oxidation tint concealed fluorescent shows anti-fake bottle lid, it is characterized in that on the surface of bottle cap original paper or pass on the inside face of the transparent body on the bottle cap that trade mark, pattern, literal, alphabetical part are arranged, be coated with the printed layers of following A or B feature: A. and establish thermal color-changing printing ink layer 1 and concealed fluorescent demonstration ink lay 2, to form oxidation tint anti-fake mark 1
0Or/and concealed fluorescent shows anti-fake mark 2
0And it is the temperature change powder of 50 ℃ of variable colors that this thermal color-changing printing ink layer 1 adopts minimum temperature; It is stealthy that this concealed fluorescent shows that ink lay 2 adopts under daylight, the fluorescent material of show tags during with UV-irradiation.B. establish oxidation tint and concealed fluorescent and show two kinds of mixed ink layers 3, mix anti-fake mark 3 to form
0And the interior minimum temperature that adopts of mixed ink is temperature change powder and employing stealth under daylight of 50 ℃ of variable colors, the fluorescent material of show tags during with UV-irradiation.On the above-mentioned bottle cap if simultaneously oxidation tint anti-fake mark 1 is set
0Show anti-fake mark 2 with concealed fluorescent
0The time, can adopt dislocation to arrange.
The component of thermal color-changing printing ink is: temperature becomes powder 20%～40%, silk screen seal or bat printing varnish 60%～80%, diluent butanone or cyclohexanone, or 783 neutral drying retardants; Its color is red, brown, blue, yellow, green or black.
Concealed fluorescent shows that the component of printing ink is: fluorescent material is 20%～30%, silk screen seal or bat printing varnish 70%～80%, diluent butanone or cyclohexanone, or 783 neutral drying retardants; Its color is red, yellow, blue, purple or white.Using above two kinds of diluent or neutral drying retardants that added by China ink why disproportional, is because diluent has volatility, constantly volatilization of dilution in printing process, and the continuous retrogradation of printing ink will constantly add diluent according to circumstances.
The oxidation tint concealed fluorescent shows the manufacture method of anti-fake bottle lid, it is characterized in that this method adopts following C or D or E or F:C, show ink component preparation printing ink by above-mentioned oxidation tint and concealed fluorescent, (thermal color-changing printing ink layer 1 and concealed fluorescent show ink lay 2 to press said structure, or mixed ink layer 3) directly printing out trade mark, pattern, literal, letter on the bottle cap original paper or apply printing ink on original trade mark, pattern, literal, letter, then is finished product after the printing oven dry.Oxidation tint and concealed fluorescent show that ink lay adopts pad printer planographic or the printing of screen printing machine cambered surface, and both sieve numbers are 300 orders～500 orders;
D after primer spray surface treatment on the bottle cap original paper, prints by above-mentioned C method again, and the oven dry back is a finished product;
E after primer spray surface treatment on the bottle cap original paper, prints by above-mentioned C method, and oven dry is finished product (the method is applicable to the anti-fake mark that dislocation is arranged) behind the topcoating again;
F, after primer spray surface treatment on the bottle cap original paper, oven dry is handled behind the topcoating again, is printed as finished product (the method is applicable to the inferior photochromic anti-fake mark that does not have light) by above-mentioned C method again.
Single anti-fake mark 1
0Or 2
0And mixing anti-fake mark 3
0Process for making adopt above-mentioned E.
The component of above-mentioned priming paint is: acrylic acid 20%～30%, H-4 epoxy paint curing agent 5%～6%, silver-colored aluminium paste 8%～9%, X-5 acrylic diluents 5%～6%, copper bronze 4%～5%; The component of above-mentioned finish paint is: two groups of phenol varnish 28%～29%, H-4 epoxy paint curing agent 14%～15%, X-10 polyurethane or styrene diluent 57%～58%.
The oxidation tint concealed fluorescent shows the using method of anti-fake bottle lid, it is characterized in that the true and false method of differentiating bottle interior product is: G, with the oxidation tint anti-fake mark (1 that contains on the bottle cap
0) or (3
0), make temperature rise to 50C when above, this mark disappears or becomes other color, and it is cooled to 50C when following, will recover original color; H shows anti-fake mark (2 with the concealed fluorescent that contains on the bottle cap
0) or (3
0), be stealthy under daylight, when using UV-irradiation, then there is the fluorescent display mark at this place.
Beneficial effect of the present invention:
(1) be printed with oxidation tint and concealed fluorescent show tags or with the mark of mixed ink printing simultaneously on same bottle cap, solved that single anti-fake mark is easily imitated, the problem of antifalse effect difference, the double anti-forge effect is arranged, particularly best results is arranged in dislocation.
(2) by the oxidation tint anti-fake mark of the printing ink to manufacture of the present invention preparation, heating is approximately to more than the 50C in the using method when it is discerned the false from the genuine, and mark disappears or variable color, touches to discern the false from the genuine with hand and compares, and increases imitation difficulty, and antifalse effect improves.
(3) surface brush finish paint can guarantee anti-fake mark light, bright-coloured, clear.
(4) change technological process, but the inferior photochromic anti-fake mark of the nothing of meet requirements light.
(5) adopt concealed fluorescent to show that ink lay is better than the non-invisible printing ink layer antifalse effect that demonstration is arranged under the existing daylight.
(4). description of drawings:
Fig. 1 constructional drawing of the present invention
Fig. 2 Figure 1A-A cutaway view
Fig. 3 Figure 1B-B cutaway view
Fig. 4 bottle cap original paper 4
0Scheme drawing
Fig. 5 only has the thermal chromic markers scheme drawing
Fig. 6 misplace arrange scheme drawing it-(double labeling 1
0With 2
0All locate what and differentiate state)
Fig. 7 Fig. 6 C-C cutaway view
Fig. 8 misplaces and arranges two (marks 1 of scheme drawing
0Be the discriminating state, mark 2
0Be non-discriminating state)
Fig. 9 mixing anti-fake mark 3
0Scheme drawing
(5). the specific embodiment:
See Fig. 1, Fig. 2 is in 4 times garden cambered surfaces 4 of a bottle cap
1On be provided with oxidation tint anti-fake mark 1 (' trade mark ' two words) and concealed fluorescent simultaneously and show anti-fake mark 2
0(' literal ' two words), this place forms thermal color-changing printing ink layer 1 and concealed fluorescent shows ink lay 2.See Fig. 1, Fig. 3, Fig. 9, garden cambered surface 4 on another bottle cap 4
2On be provided with and mix anti-fake mark 3
0(' pattern ' two words), it is located at passes the transparent body 4 on the bottle cap 4
3Medial surface on, it shows that by oxidation tint and concealed fluorescent two kinds of mixed inks print out ' pattern ' two words at this place, this place has also formed mixed ink layer 3.Differentiate concealed fluorescent show tags 3
0The time, with ultraviolet light from the transparent body 4
2External radiation gets final product.
Thermal color-changing printing ink becomes powder 30% by temperature, bat printing 8810 varnish 70%, and the diluent butanone is formulated, and color is red.Temperature becomes powder and adopts discoloring temperature into more than 50 ℃.
Concealed fluorescent shows printing ink by fluorescent material 25%, bat printing 8810 varnish 75%, and the diluent cyclohexanone is formulated; Its color is blue look.Fluorescent material adopts daylight down for colourless, purple light visible pattern, literal etc.
Adopt the manufacture method following (being above-mentioned E method) of dislocation cloth tagging on the bottle cap: at plastic bottle closure original paper 4
0(see figure 4) surface primer spray layer 5 is handled (see figure 7), printing heat color-changing anti-counterfeit mark 1
0Trade mark ' two word (see figure 5), the printing concealed fluorescent shows anti-fake mark 2
0' literal ' two words, and two groups of dislocation arrange (see figure 6)s, spray plane enamelled coating 6 (see figure 7)s again on the surface, oven dry is finished product then.See Fig. 6, ' trade mark ' located what and added the oxidation tint state, and ' literal ' locates what ultraviolet lamp irradiating state, is the discriminating state.See Fig. 8, ' trade mark ' differentiates state for adding oxidation tint, and ' literal ' locates the stealthy non-discriminating state of what.See Fig. 9, mix anti-fake mark 3
0' pattern ' locates two discriminating states that what adds oxidation tint and fluorescent display.Ink lay 3 surfaces are if topcoating is then bright clear, if do not spray then inferior photochromic for there not being light.
Above-mentioned priming paint is by acrylic acid 23.1%, H-4 epoxy paint curing agent 5.8%, and silver-colored aluminium paste 8.7%, X-5 acrylic diluents 57.8%, copper bronze 4.6% is formulated.Above-mentioned finish paint is by two groups of phenol varnish 28.6%, H-4 epoxy paint curing agent 14.3%, and X-10 polyurethane or styrene diluent 57.1% are formulated.
Claims (8)
1, the oxidation tint concealed fluorescent shows anti-fake bottle lid, and it is characterized in that on the surface of bottle cap original paper (40) or passing on the inside face of the transparent body on the bottle cap has trade mark, pattern, literal, alphabetical part, is coated with the printed layers of following A or B feature:
A establishes thermal color-changing printing ink layer (1) and concealed fluorescent and shows ink lay (2), shows anti-fake mark (20) to form oxidation tint anti-fake mark (10) and concealed fluorescent; And it is the temperature change powder of 50 ℃ of variable colors that this thermal color-changing printing ink layer (1) adopts minimum temperature; It is stealthy that this concealed fluorescent shows that ink lay (2) adopts under daylight, the fluorescent material of show tags during with UV-irradiation;
B establishes oxidation tint and concealed fluorescent and shows two kinds of mixed ink layers (3), mixes anti-fake mark (30) to form; And the interior minimum temperature that adopts of mixed ink is temperature change powder and employing stealth under daylight of 50 ℃ of variable colors, the fluorescent material of show tags during with UV-irradiation.
2. by the described anti-fake bottle lid of claim 1, it is characterized in that the oxidation tint anti-fake mark (10) and the concealed fluorescent that are provided with simultaneously on the bottle cap show that anti-fake mark (20) is that dislocation is arranged.
3. by the described anti-fake bottle lid of claim 1, it is characterized in that the component of thermal color-changing printing ink is: temperature becomes powder 20%～40%, silk screen seal or bat printing varnish 60%～80%, diluent or neutral drying retardant; Its color is red, brown, blue, yellow, green or black.
4. by the described anti-fake bottle lid of claim 1, it is characterized in that concealed fluorescent shows that the component of printing ink is: fluorescent material is 20%～30%, silk screen seal or bat printing varnish 70%～80%, diluent or neutral drying retardant; Its color is red, yellow, blue, purple or white.
5. by the described anti-fake bottle lid of claim 1, it is characterized in that linging enamelled coating (5) between printed layers and bottle cap original paper, printed layers surface brush top coat layer (6).
6. by the manufacture method of the described anti-fake bottle lid of claim 1, it is characterized in that this method adopts following C or D or E or F:
C. by the preparation of ink component described in claim 3 or the claim 4 printing ink, directly on the bottle cap original paper, print by the described structure of feature A in the claim 1 again; Be mixed ink perhaps, directly on the bottle cap original paper, print by the described structure of feature B in the claim 1 again by claim 3 and the described ink component mixed preparing of claim 4; Then to becoming finished product after the printed layers oven dry; Its oxidation tint and concealed fluorescent show that ink lay adopts pad printer planographic or the printing of screen printing machine cambered surface, and both sieve numbers are 300 orders～500 orders;
D. after primer spray surface treatment on the bottle cap original paper, print by above-mentioned C method, the oven dry back is a finished product again;
E. after primer spray surface treatment on the bottle cap original paper, print by above-mentioned C method, oven dry is finished product behind the topcoating again;
F, after primer spray surface treatment on the bottle cap original paper, oven dry is handled behind the topcoating again, prints the back by above-mentioned C method again and is finished product.
7, by the described anti-fake bottle lid of claim 5, it is characterized in that the component of priming paint is: acrylic acid 20%～30%, curing agent 5%～6%, silver-colored aluminium paste 8%～9%, diluent 50%～60%, copper bronze 4%～5%; The component of finish paint is: two groups of phenol varnish 28%～29%, curing agent 14%～15%, polyurethane or styrene diluent 57%～58%.
8, show the using method of anti-fake bottle lids by claim 1 or 2 described oxidation tint concealed fluorescents, it is characterized in that the true and false method of differentiating bottle interior product is: G, the oxidation tint anti-fake mark (1 that contains on the bottle cap
0) or (3
0), make temperature rise to 50C when above, this mark disappears or becomes other color, and it is cooled to 50C when following, will recover original color; H, the concealed fluorescent that contains on the bottle cap is shown anti-fake mark (2
0) or (3
0), be stealthy under daylight, when using UV-irradiation, then there is the fluorescent display mark at this place.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03117218 CN1244481C (en) | 2003-01-23 | 2003-01-23 | Anti-false bottle cap with thermo-color and invisible fluorescence display as well as mfg. and operation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03117218 CN1244481C (en) | 2003-01-23 | 2003-01-23 | Anti-false bottle cap with thermo-color and invisible fluorescence display as well as mfg. and operation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1431130A CN1431130A (en) | 2003-07-23 |
| CN1244481C true CN1244481C (en) | 2006-03-08 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03117218 Expired - Fee Related CN1244481C (en) | 2003-01-23 | 2003-01-23 | Anti-false bottle cap with thermo-color and invisible fluorescence display as well as mfg. and operation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1244481C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102602593A (en) * | 2012-03-30 | 2012-07-25 | 浙江圣林包装有限公司 | Anti-counterfeiting plastic combined bottle cap with split seal |
| US9365314B2 (en) * | 2012-11-16 | 2016-06-14 | Owens-Brockway Glass Container Inc. | Product and package with a photosensitive use-evident feature |
| CN104443743B (en) * | 2014-03-27 | 2016-05-25 | 杨直玮 | RFID label special anti-counterfeiting bottle cap |
| CN107436303B (en) * | 2017-07-10 | 2020-11-13 | 深圳九星印刷包装集团有限公司 | Time lapse indicating device |
| CN111301018B (en) * | 2019-12-31 | 2021-06-18 | 绍兴上虞天勤包装有限公司 | Printing process of cosmetic packaging bottle cap |
| JP7296348B2 (en) * | 2020-09-18 | 2023-06-22 | 日立グローバルライフソリューションズ株式会社 | washing machine |
-
2003
- 2003-01-23 CN CN 03117218 patent/CN1244481C/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| CN1431130A (en) | 2003-07-23 |
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