CN1242983A - Composition containing opacifier or pearling agent and at least a kind of emtrol - Google Patents
Composition containing opacifier or pearling agent and at least a kind of emtrol Download PDFInfo
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- CN1242983A CN1242983A CN 99110688 CN99110688A CN1242983A CN 1242983 A CN1242983 A CN 1242983A CN 99110688 CN99110688 CN 99110688 CN 99110688 A CN99110688 A CN 99110688A CN 1242983 A CN1242983 A CN 1242983A
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Abstract
本发明涉及含有一种表面活性剂碱,至少一种调理剂,至少一种线型的饱和长链脂肪族醇或含至少50%重量的具有22个碳原子的醇的脂肪族醇混合物,和至少一种遮光剂和/或珠光剂的新型组合物。应用线型的饱和长链脂肪族醇或含至少50%重量的具有22个碳原子的醇的脂肪族醇混合物产生珠光效果和/或增强含有至少一种表面活性剂碱和至少一种遮光剂和/或珠光剂的组合物的珠光效果。该组合物特别可作漂洗掉的产品,用于洗涤和调节角蛋白物质。The present invention relates to a surfactant base, at least one conditioning agent, at least one linear saturated long-chain aliphatic alcohol or an aliphatic alcohol mixture containing at least 50% by weight of alcohols having 22 carbon atoms, and Novel compositions of at least one opacifier and/or pearlescent agent. Application of linear saturated long-chain aliphatic alcohols or aliphatic alcohol mixtures containing at least 50% by weight of alcohols having 22 carbon atoms to produce pearlescent effects and/or enhance And/or the pearlescent effect of the composition of pearlescent agent. The composition is especially useful as a rinse-off product for cleansing and conditioning keratinous substances.
Description
The present invention relates to a kind of at least a surfactant alkali that contains, the saturated long-chain fatty alcohol of at least a line style or contain the mixture of aliphatic alcohol that at least 50% weight has a kind of alcohol of 22 carbon atoms, the compositions of at least a opacifier and/or pearling agent; It is as the application of pearling agent; A kind of cosmetic composition, in the cosmetics acceptable medium, contain at least a surfactant alkali, the saturated long-chain fatty alcohol of at least a line style or contain the mixture of aliphatic alcohol of a kind of alcohol with 22 carbon atoms of at least 50% weight, the conditioner of at least a opacifier and/or pearling agent and at least a keratin substances.The invention still further relates to the application of above-mentioned composition as the insoluble conditioner reagent that suspends.
As everyone knows, under the effect of atmosphere or machinery and chemical treatment (as dyeing, bleach and/or do in the operation of permanent curl), the experiencing of hair (as damaging and/or becoming fragile) degree is different, thereby is difficult to untie and finalize the design, and lacks flexibility.
In order to impel hair to untie and make its softness, glossy and flexible, there is the people once to advise using conditioner in the compositions as hair, especially insoluble conditioner cleaning and treatment of keratinous material.
The conditioner of known some insoluble class as (gathering) siloxanes or oils, can make conditioner be evenly dispersed in the medium, and not reduce viscosity or the cleaning or the character foamy of compositions.Siloxanes also can be provided on the keratin substances of handling, so that they have softness, gloss and easy unfolded character after using.
Know, some product, particularly cosmetic product, they have as the iris, flicker or metallized outward appearance or effect, extensively be subjected to the attention of consumer, this is based on its esthetic requirement and they can make product have this fact of colourful outward appearance.The reagent that this effect is provided is to contain usually to keep being dispersed in the compositions, and can catoptrical crystalline pearling agent.
" pearling agent " this term means a kind of reagent that produces as the iris, flicker or metallization outward appearance or effect.
Effectively keep the reagent of insoluble conditioner in suspension to be difficult to obtain, because this is a problem that is difficult to solve, for this reason, propose to use the derivant or the polysaccharide of long-chain ester, as xanthane glue, yet the derivant of long-chain ester can produce crystallisation problems, and this causes the viscosity of compositions to change at any time; Gelating agent is defectiveness also, and promptly on the one hand, it is difficult to produce foam with the composition of detergent that contains Herba Xanthii glue (it is bad to cause foam), and on the other hand, such compositions lacks level and smooth structure, and it is mobile to be drop by drop, can not get the welcome of user.
The derivant of long chain ether or thioether, as at patent application EP457,688 and WO 98/03155 in narrated those, also be known.But, these reagent except make compositions opaque, do not bring pearl effect to compositions, in other words, give not enoughly.
Existing people attempts improving pearl effect by adding thickening agent and/or other pearling agents, still, in this case, viscosity become too big and/or compositions no longer stable.
The applicant finds, and it also is a purpose of the present invention, promptly use a kind of saturated long-chain fatty alcohol of line style or contain at least 50% weight, have the mixture of aliphatic alcohol of a kind of alcohol of 22 carbon atoms, can produce a kind of pearl effect, be improved so that contain the pearl effect of the compositions of at least a surfactant alkali and at least a opacifier and/or pearling agent.
A theme of the present invention contains at least a surfactant alkali exactly, the fatty alcohol mixture of at least a line style, saturated long-chain fatty alcohol or a kind of alcohol that contains 22 carbon atoms with at least 50% weight and the compositions of at least a opacifier and/or pearling agent.
Can be according to compositions of the present invention as a kind of pearly-lustre basic components of cosmetic composition, the pearl effect that it produced is better than from opacifier and/or pearling agent resulting.
Another theme of the present invention be use the saturated long-chain fatty alcohol of line style or contain the mixture of aliphatic alcohol of a kind of alcohol that contains 22 carbon atoms of at least 50% weight and a kind of opacifier as the pearly-lustre basic components.
Said composition shows splendid uniformity and the stability as pearling agent, and viscosity is also good, and they are applied to keratin substances is gratifying.
Narration and example below having read, all the other themes of the present invention have just come into plain view.
The saturated long-chain fatty alcohol of line style or with respect to the mixture total weight amount contains 22 carbon atoms that have of at least 50% weight, especially contains the C that has of at least 70% weight
22The fatty alcohol mixture of alcohol.
Usually, the saturated long-chain fat alcohol mixture of line style contains C
16-C
24Aliphatic alcohol.For the mixture total weight amount, C
16And C
24Aliphatic alcohol generally all is less than 2% weight, and C
18Chain is less than 10% weight.
This class aliphatic alcohol, particularly Condea company are with trade name Nafol 1822 C product solds, and it contains the 0.5%C that has an appointment
16, 4%-6%C
18, 15%-19%C
20, 74-78%C
22With about 1.5%C
24, or Condea company is with trade name Nafol 2298 product solds, and it contains 98%C
22Alcohol.
Can be selected from according to operable pearling agent of the present invention and/or opacifier:
A) aliphatic dialkyl ether, it is a solid being less than or equal under about 30 ℃ temperature, for example as the dialkyl ether of formula (I):
(I) wherein R and R ' can be identical or different for R-O-R ', represent one saturated or unsaturated, line style or the branched 12-30 carbon atom that contains, the alkyl of preferred 14-24 carbon atom, R and R ' to choose the chemical compound that will make formula (I) be solid when temperature is less than or equal to about 30 ℃.In more detail, R and R ' are equal to.
R and R ' preferably represent stearyl.
According to the adaptable dialkyl ether of the present invention is insoluble in compositions.
These chemical compounds can be according to patent application DE 4,127, the method preparation described in 230.
Operable within the scope of the invention two hard ester acyl group ethers are commercially available, are particularly sold with title Cutina KE3178 by Henkel company.
B) contain 27-48 carbon atom and the alcohol corresponding to formula (II) of 1 or 2 ether and/or thioether or sulfoxide radicals is arranged:
R
1-X-[C
2H
3(OH)]-CH
2-Y-R
2(II) R wherein
1And R
2Be equal to mutually, represent line style C
12-C
24Alkyl; X represents an oxygen atom, sulphur atom or a sulfoxide radicals or a methylene; Y represents an oxygen atom, sulphur atom or sulfoxide radicals or methylene; When Y represents a methylene, at R
1And R
2The summation of carbon number is in the scope of 24-44 in the base, preferred 28-40 (containing);
When Y does not represent a methylene, at R
1And R
2The summation of the carbon atom that exists in the base in the scope of 24-44, preferred 28-40 (containing);
When X or Y represented sulfoxide group, Y or X did not represent sulfur.
According to the preferably such chemical compounds of the applied formula of the present invention (II) chemical compound, wherein X represents oxygen, and Y represents methylene, and R
1And R
2Representative contains the group of 12-22 carbon atom.
These chemical compounds can be according to patent EP 457,688 preparations.
According to the present invention, the line style saturated fatty alcohol that contain at least 50% weight, has 22 carbon atoms can be 0.5%-15% weight for the gross weight of final composition, preferred 0.5%-5% weight, more preferably 0.5%-3% weight.
According to the present invention, pearling agent and/or opacifier can be 0.5%-15% weight for the gross weight of final composition, preferred 0.5%-5% weight, more preferably 1%-3% weight.
Opacifier/C
22The ratio of aliphatic alcohol generally is 0.2-8, preferred 0.3-5.
According to a kind of preferred version of the present invention, cosmetic composition also can contain the conditioner of keratin substances.
Thereby another theme of the present invention is exactly the novel cosmetic compositions, particularly foam is regulated and cleaning composition, in the cosmetics acceptable medium, contain a kind of surfactant alkali, at least a conditioner, the saturated long-chain fatty alcohol of at least a line style or contain fatty alcohol mixture and at least a opacifier and/or the pearling agent of a kind of alcohol with 22 carbon atoms of at least 50% weight.
The compositions that makes so also has good cleaning and foam performance, and can make keratin substances, and especially hair and/or skin feel very soft.
When this polymer is applied to hair, except their cleaning character, also hair there is conditioning performance, the hair of promptly handling smoothly, is easily untied and soft feel.Hair looks nature, no greasy dirt.
According to the present invention, the compositions that contains conditioner is stable.The particularly interior during use situation that does not discharge conditioner or thickening agent in compositions uncontrollably takes place.Finally, compositions has novel and structure fusing.Foam is light, rinsing easily.
Another theme of the present invention is a method of using said composition washing and conditioning.
It is to use a kind of fatty alcohol mixture with a kind of alcohol of 22 carbon atoms that contains the saturated long-chain fatty alcohol of at least a line style or contain at least 50% weight that the present invention also has a theme, with at least a opacifier and/or the pearling agent reagent as the insoluble conditioner that suspends in the cosmetic composition, the foam that particularly contains surfactant alkali in the acceptable water-bearing media of cosmetics is regulated and cleaning compositions.
When compositions contained at least a conditioner, these conditioners generally were selected from poly-alpha-olefin, fluorocarbon oil, and fluorine wax, fluorubber, carboxylate, cationic polymer, siloxanes, mineral, plant or animal oil, ceramide, the false vitalility is through amide and its mixture.
The mixture of cosmetics acceptable medium preferred water or water and cosmetics or Dermatology acceptable solvent (as single alcohol, polyhydric alcohol, glycol ether or fatty acid ester), they can use separately or use as mixture.
To mention lower aliphatic alcohols especially, as ethanol or isopropyl alcohol, polyhydric alcohol, as diethylene glycol, glycerol, sorbitol, the alkyl ether of glycol ether and ethylene glycol or diethylene glycol.
Compositions of the present invention also can contain at least a additive, and it is selected from chelating agen, softening agent, foam conditioner, dyestuff, other pearling agents, hydrating agents, dandruff removing agent or anti-cortex bleeding, other suspending agents, contains line style or the C of branch
16-C
60The fatty acid of chain, hydroxy acid, electrolyte, thickening agent, fatty acid ester, fatty glyceride, surfactant, spice, antiseptic, sunscreen, protein, vitamin, polymer and any other are usually used in the additive of cosmetics.
According to the present invention, the additives ratio that exists in the compositions, for composition total weight, can be in the 0-40% weight range.The accurate consumption of every kind of additive depends on its characteristic, and the people who is familiar with this area is easy to determine.
Much less, those skilled in the art that can be careful and select above-mentioned one or more chemical compounds to be added to according in the compositions of the present invention, like this and compositions of the present invention favourable character that internal relation arranged can (or basically not can) be subjected to the adverse effect of the interpolation of this imagination.
Form according to compositions of the present invention can be the lotion or the foam of gel, Emulsion, butyrous, more or less thickening.
Can be used for the processing angle protein substance according to compositions of the present invention, as hair, skin, eyelashes, eyebrow, fingernail, lip, hair, especially hair.
Said composition also can be used for washing and clean keratin substances, as hair and skin.
,, be shaped generally as product according to compositions of the present invention as hair especially for washing, nurse, nurse one's health or keeping hair style or make keratin substances.
Compositions of the present invention can be, especially the form of shampoo, rinse or built-in (leave in) conditioner, be used to make the composition forms of hair permanent curl, aligning, dyeing or bleaching, or used before or after dyeing, bleaching, permanent curl or straightening hair with the form of compositions, or between two steps of permanent curl and hair straightening, use in addition.Preferred composition is washing and the composition, foam that is used for hair and/or skin.
Especially, be the foaming-detergent compositions according to compositions of the present invention, as shampoo, shower gels or bubble bath.In this specific embodiments of the present invention, compositions contains surface washing activating agent alkali, and it is normally aqueous.
The surfactant that forms washing soda can be selected from anion, both sexes, nonionic, amphion, cationic surfactant, all can separately or as mixture.
The minimum of washing soda should just in time make final composition have enough gratifying foaming and/or washability.
Like this, according to the present invention, for the gross weight of final composition, washing soda can be a 4%-30% weight, preferred 6%-25% weight, more preferably 8%-20% weight.
Be suitable for surfactant of the present invention particularly described as follows these:
(i) anion surfactant:
Within the scope of the invention, its characteristic is not critical feature.
Like this, within the scope of the invention, be adaptable anion surfactant, use separately or as mixture, can mention the salt (especially alkali metal salt, particularly sodium salt, ammonium salt, amine salt, amino alkoxide or magnesium salt) of (non-limitative illustration) following compounds especially: alkyl sulfate, alkyl ether sulfate, alkylamidoalkyl ether sulfate, alkyl aryl polyether sulfate, monoglyceride sulfate; Alkylsulfonate, alkylphosphonic, alkylamidoalkyl sulfonate, alkylaryl sulfonate, alpha-alkene sulfonate, alkane sulfonate; Alkyl sulfo succinate, alkyl ether sulfo succinate, alkylamidoalkyl sulfosuccinate; The alkyl sulphosuccinamate; Alkyl sulfoacetate; Alkyl ether phosphate; Acyl sarcosinates; Acyl isethinate and N-acyl taurine salt, the alkyl of all these different chemical compounds or acyl group preferably contain 8-24 carbon atom, and preferred phenyl of aryl and benzyl.In also applicable anion surfactant, also can point out soap, as oleic acid, castor oil acid, Palmic acid and stearate, cocinic acid or hydrogenated coconut oleic acid; Acyl-lactate, wherein acyl group contains 8-20 carbon atom.Also may use the weak anionic surfactant,, also have poly-alkoxylation (C as D-galactoside alduronic acid and its salt
6-C
24) alkyl ether carboxylic acid, poly-alkoxylation (C
6-C
24) the alkyl aryl ether carboxylic acid, poly-alkoxylation (C
6-C
24) salt of alkylamidoalkyl ether carboxylic acid and they, particularly those contain 2-50 ethylene oxide group, reach their mixture.
According to the present invention, used anion surfactant preferred alkyl sulfate and alkyl ether sulfate and its mixture.
(ii) non-ionic surface active agent:
Non-ionic surface active agent itself be the chemical compound known (particularly referring to M.R.Porter, Blackie ﹠amp; Son (Glasgow and London) publishes, " Handbook ofSurfactants ", 1991, the content of the relevant this respect of pp.116-178 one book), within the scope of the invention, their characteristic is not critical feature.Like this, they can be especially selected from (non-limiting listing) polyethoxylated, poly-propoxylation or bound to polyglycerol fatty acid, alkyl phenol, the salmefamol with an aliphatic chain that contains (for example) 8-10 carbon atom or alcohol, the number of oxirane or propylene oxide group especially can be in the scope of 2-50, and the number of glycerol group especially can be in the scope of 2-30.Also can point out the copolymer of oxirane and expoxy propane, the condensation substance of oxirane and expoxy propane and aliphatic alcohol; The polyethoxylated fatty acid amide preferably has the 2-30 moles of ethylene oxide, and the bound to polyglycerol fatty acid amide on average contains the 1-5 mole, particularly 1.5-4 mole of glycerin group; The polyethoxylated aliphatic amine preferably has 2-30 moles of ethylene oxide group; Ethoxylated fatty acid ester with anhydro sorbitol of 2-30 moles of ethylene oxide; Sucrose fatty acid ester, cithrol, alkylpolyglycosides, N-alkylated glucamine derivant, the oxidation amine is as (C
10-C
14) alkyl amine oxide or N-amidopropyl morpholine oxide.Should be noted that alkylpolyglycosides constitutes suitable especially non-ionic surface active in the scope of the invention.
(iii) both sexes or zwitterionic surfactant:
The characteristic of both sexes within the scope of the invention or zwitterionic surfactant is not critical characteristics, can be (non-limiting listing) aliphatic secondary amine or tertiary amines derived thing especially, wherein aliphatic group be line style or the branched chain that contains 8-18 carbon atom and contain at least a water solubilization anionic group (for example carboxylate, sulfonate, sulfate, phosphate or phosphonate); Also can point out (C
8-C
20) alkyl betaine, sulfobetaines, (C
8-C
20) alkylamide (C
1-C
6) alkyl betaine or (C
8-C
20) alkylamide (C
1-C
6) the alkyl sulfobetaines.
In amine derivative, can mention the product of selling with title Miranol, as at United States Patent (USP) 2,528,378 and 2,781,354 and classified in the CTFA dictionary, 3rd edition, described in 1982, the corresponding construction of both sexes carboxyl glycinate (Amphocarboxyglycinates) by name and both sexes carboxyl propionate (Amphocarboxypropionates) is as follows:
R
2-CONHCH
2CH
2-N (R
3) (R
4) (CH
2COO-) (2) R wherein
2Represent alkyl (to derive from the sour R that exists in the hydrolysis Oleum Cocois
2-COOR), heptyl, nonyl or undecyl, R
3Represent beta-hydroxyethyl, and R
4Represent carboxymethyl; With
R
2 '-CONHCH
2CH
2(C) (3) wherein for-N (B): B representative-CH
2CH
2OX ', C representative-(CH
2)
z-Y ', z=1 or 2, X ' representative-CH
2CH
2-COOH base or a hydrogen atom, Y ' representative-COOH or-CH
2-CHOH-SO
3The H base, R
2 'Represent the sour R that exists in Oleum Cocois or the hydrolysis Semen Lini oil
9The alkyl of-COOH, alkyl, particularly C
7, C
9, C
11Or C
13Alkyl, C
17Alkyl and isomeric form thereof, or unsaturated C
17Base.
As an example, can point out the Cortex cocois radicis both sexes carboxyl glycinate with trade name MiranolC2M concentrate (concentrate) sale by Rhodia Chimie company.
(IV) cationic surfactant:
Within the scope of the invention, the characteristic of cationic surfactant is not critical characteristics, can be pointed out that (non-limiting listing) especially: optional poly-alkoxylation primary, the salt of Zhongshu aliphatic amine; Quaternary ammonium salt is as tetra-allkylammonium, alkylamide alkyl trialkyl ammonium, triakyl benzyl ammonium, trialkyl hydroxyalkyl ammonium or alkyl pyridine chloride or bromide; Imidazolidine derivatives; Or the amine oxide of cation feature.
Theme of the present invention also relates to the cosmetics processing procedure of a keratin substances such as hair, and it is constructed as follows: compositions defined above is administered on the hair, and then, after making compositions be trapped in the hair arbitrarily, water arbitrarily rinses it.
Compositions of the present invention can mainly prepare according to two processes:
At first under agitation the whole batchings with compositions are heated to about 80 ℃, make mixture be cooled to room temperature then.The secondth, preparation pearly-lustre concentrate, it contains surfactant, opacifier or pearling agent and aliphatic alcohol, water, pH agent and optional antiseptic.Opacifier or pearling agent and aliphatic alcohol under agitation be added to be preheated in about 80 ℃ water and surfactant mixtures.Keep this temperature about 30 minutes, and then mixture was cooled to about 30 ℃.Then with the above-mentioned concentrate of aequum in room temperature, borrow the help of turbo mixer, be added in the shampoo basic components.
Now, give an actual example with following institute and to illustrate the present invention more fully, but can not think that the present invention only limits to described scheme.AM is meant active substance in following content.Example 1
The preparation of following three kinds of shampoo Compositions:
Compositions A and B are according to of the present invention, and compositions C is a reference composition.
| ????A | ????B | ????C | |
| -by the sodium laureth sulfate of 2.2 moles of ethylene oxide ethoxyquins, as a kind of aqueous solution that contains 70%AM | ????14.5g ????AM | ????14.5g ????AM | ????14.5g ????AM |
| -coco group (cocoyl) betanin is as a kind of aqueous solution that contains 30 %AM | 2.3 gram AM | 2.3 gram AM | 2.3 gram AM |
| -Dimethicone (production of Mirasil DM 500,000 Rhodia chemical companies) | ?????- | ????2g | ?????- |
| -also use trimethylamine quaternized (production of JR400 Union Carbide Corporation) with the hydroxyethyl-cellulose of epichlorohydrin cross-linked | ?????- | 0.3 gram AM | ?????- |
| The mixture (opacifier) of the pure and mild 1-of-cetyl (hexadecane oxygen base)-2-octadecanol | 1.5 gram | 1.5 gram | 2.5 gram |
| -C 22Aliphatic alcohol (production of Nafal 1822 C Condea companies) | 1 gram | 1 gram | ??????- |
| -coconut acid single ethanol amide | 0.95 gram | 0.95 gram | 0.95 gram |
| -antiseptic, spice | ????qs | ????qs | ????qs |
| -citric acid, 1H 2O?qs | ????pH5.5 | ????pH5.5 | ????pH5.5 |
| -demineralized water qs | 100 grams | 100 grams | 100 grams |
The pearl effect of compositions A of the present invention and B is better than only containing the compositions C of opacifier.
The foam properties of compositions A and B is good.
Compositions A and B have good viscosity and are stable.Example 2
Three kinds of following shampoo Compositions are produced:
Compositions A and B are according to of the present invention, and compositions C is a reference composition.
| ????A | ????B | ????C | |
| -by the sodium laureth sulfate of 2.2 moles of ethylene oxide ethoxylations, as the aqueous solution that contains 70%AM | ??14.5g ??AM | ??14.5g ??AM | ??14.5g ??AM |
| -coco group (cocoyl) betanin is as the aqueous solution that contains 30%AM | 2.3 gram AM | 2.3 gram AM | 2.3 gram AM |
| -Dimethicone (production of Mirasil DM 500,000 Rhodia chemical companies) | ???- | ??2g | ????- |
| -by the quaternised hydroxyl-ethyl cellulose of trimethylamine (production of JR 400 Union Carbide Corporation) | ???- | 0.3 gram AM | ????- |
| -distearyl ether (opacifier) | 1.5 gram | 1.5 gram | 2.5 gram |
| -C 22Aliphatic alcohol (production of Nafol 1822 C Condea companies) | 1 gram | 1 gram | ?????- |
| -coconut acid single ethanol amide | 0.95 gram | 0.95 gram | 0.95 gram |
| -antiseptic, spice | ???qs | ???qs | ????qs |
| -citric acid, 1H 2O?qs | ??pH5.5 | ??pH5.5 | ???pH5.5 |
| -demineralized water qs | ??100g | ??100g | ??100g |
The compositions C that is better than only containing opacifier according to the pearl effect of compositions A of the present invention and B.
The foam properties of compositions A and B is good.
Compositions A and B have good viscosity and stable.
When using the C that contains 44% weight of having an appointment
22When the aliphatic alcohol alternate sets compound A of alcohol or the Nafol 1822C among the B, find that pearl effect is not enough fully.
Claims (14)
1. cosmetic composition, it is characterized in that, in the cosmetics acceptable medium, contain at least a surfactant alkali, the saturated long-chain fat family alcohol of at least a line style or contain a kind of aliphatic alcohol mixture and at least a opacifier and/or pearling agent that contains the alcohol of 22 carbon atoms of at least 50% weight.
2. according to the compositions of claim 1, feature be aliphatic alcohol or contain have 22 carbon atoms, the aliphatic alcohol mixture of a kind of alcohol of at least 70% weight for the mixture total weight amount.
3. according to each compositions of claim 1 and 2, it is characterized in that pearling agent and/or opacifier are to be selected from:
A) aliphatic dialkyl ether, it is a solid being less than or equal under about 30 ℃ temperature, for example the dialkyl ether of formula (I):
R-O-R ' is (I) wherein: R and R ' can be identical or different, represent saturated or unsaturated a, line style or ramose alkyl, it contains 12-30 carbon atom, preferred 14-24 carbon atom, it is solid being less than or equal under about 30 ℃ temperature that the selection of R and R ' will make formula (I) chemical compound, particularly, R and R ' are equal to;
B) contain 27-48 carbon atom and contain one or two ether and/or the alcohol of thioether or sulfoxide radicals, corresponding to formula (II):
R
1-X-[C
2H
3(OH)]-CH
2-Y-R
2(II) R wherein
1And R
2Represent line style C independently of each other
12-C
14Alkyl; X represents an oxygen atom, sulphur atom or sulfoxide group or methylene; Y represents an oxygen atom, sulphur atom or sulfoxide group or methylene;
When Y represents a methylene, in radicals R
1And R
2The middle carbon number sum that exists is at the scope of 24-44, preferably 28-40 (containing);
When Y does not represent a methylene, in radicals R
1And R
2In the carbon number sum that exists in the scope of 24-44, preferred 28-40 (containing):
When X or Y represented sulfoxide group, Y or X did not represent sulfur.
4. according to each the compositions of claim 1-3, it is characterized in that pearling agent and/or opacifier are selected from:
A) distearyl acyl group ether,
B) formula (II) chemical compound, wherein X represents oxygen, and Y represents methylene, and R
1And R
2Representative contains the group of 12-22 carbon atom.
5. according to each compositions of claim 1-4, it is characterized in that aliphatic alcohol or aliphatic alcohol mixture account for 0.5%-15% for the final composition gross weight, preferred 0.5%-5%, more preferably 0.5%-3% weight.
6. according to each the compositions of claim 1-5, it is characterized in that opacifier and/or pearling agent for the final composition gross weight, account for 0.5%-15% weight, preferred 0.5%-5% weight, more preferably 1%-3% weight.
7. according to the compositions of each claim of front, it is characterized in that also containing at least a conditioner.
8. according to the compositions of each claim of front, it is characterized in that conditioner is selected from poly-alpha-olefin, fluorocarbon oil, fluorine wax, fluorubber, carboxylate, polymer, particularly cationic polymer, siloxanes, mineral, plant or animal oil, ceramide and false vitalility be through amide, and composition thereof.
9. according to each claim compositions of front, it is characterized in that lotion or form of foam with gel, emulsion, creamy, more or less thickening.
10. according to the compositions of each claim of front, it is characterized in that it is a kind of foaming-detergent compositions, as shampoo, shower gels or foam bath agent.
11. use the saturated long-chain fat family alcohol of at least a line style or contain a kind of aliphatic alcohol mixture and at least a opacifier and/or pearling agent of at least 50% weight with alcohol of 22 carbon atoms, in cosmetic composition, especially in foaming adjusting that contains surfactant alkali in the acceptable water-bearing media of cosmetics and the cleaning composition as the reagent of the insoluble conditioner that suspends.
12. the aliphatic alcohol mixture of using saturated long-chain fat family's alcohol of line style or containing the alcohol with 22 carbon atoms of at least 50% weight produces the pearl effect that pearl effect and/or enhancing contain the compositions of at least a surfactant alkali and at least a opacifier and/or pearling agent.
13. use saturated long-chain fat family's alcohol of line style or contain the aliphatic alcohol mixture of alcohol of at least 50% weight with 22 carbon atoms and a kind of opacifier and/or pearling agent as the pearly-lustre basic components.
14. the cosmetics processing procedure of keratin substances, particularly hair is characterized in that, will be applied to described material according to the compositions of claim 1-13 defined, its water is rinsed with choosing at random then.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99110688 CN1242983A (en) | 1998-07-27 | 1999-07-27 | Composition containing opacifier or pearling agent and at least a kind of emtrol |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR98/09562 | 1998-07-27 | ||
| CN 99110688 CN1242983A (en) | 1998-07-27 | 1999-07-27 | Composition containing opacifier or pearling agent and at least a kind of emtrol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1242983A true CN1242983A (en) | 2000-02-02 |
Family
ID=5274641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99110688 Pending CN1242983A (en) | 1998-07-27 | 1999-07-27 | Composition containing opacifier or pearling agent and at least a kind of emtrol |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1242983A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1909876B (en) * | 2004-01-15 | 2010-11-24 | 罗迪亚公司 | Pearlescent concentrates and their use in personal care compositions |
| WO2013189037A1 (en) * | 2012-06-20 | 2013-12-27 | L'oreal | Pearlescent conditioning composition and method for preparing the same |
-
1999
- 1999-07-27 CN CN 99110688 patent/CN1242983A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1909876B (en) * | 2004-01-15 | 2010-11-24 | 罗迪亚公司 | Pearlescent concentrates and their use in personal care compositions |
| WO2013189037A1 (en) * | 2012-06-20 | 2013-12-27 | L'oreal | Pearlescent conditioning composition and method for preparing the same |
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