[go: up one dir, main page]

CN1138293A - Lipophilic solid cosmetic composition comprising acidic dye - Google Patents

Lipophilic solid cosmetic composition comprising acidic dye Download PDF

Info

Publication number
CN1138293A
CN1138293A CN 94194583 CN94194583A CN1138293A CN 1138293 A CN1138293 A CN 1138293A CN 94194583 CN94194583 CN 94194583 CN 94194583 A CN94194583 A CN 94194583A CN 1138293 A CN1138293 A CN 1138293A
Authority
CN
China
Prior art keywords
acid
oil
composition
cosmetic composition
ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 94194583
Other languages
Chinese (zh)
Other versions
CN1113642C (en
Inventor
远藤义则
山本利通
谷口登志也
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of CN1138293A publication Critical patent/CN1138293A/en
Application granted granted Critical
Publication of CN1113642C publication Critical patent/CN1113642C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

一种亲油性固体化妆组合物，含0.01-1wt％的酸性染料及0.01-0.5wt％的具有一个或多个官能团的水溶性有机酸。该化妆组合物可提供良好的着色性，长的持久性和良好的色彩稳定性。在本发明的一个优选实施方案中，该组合物进而含有油基染料。在本发明的另一个优选实施方案中，可将水溶性有机酸作为溶剂的溶液加入该组合物中。A lipophilic solid cosmetic composition, containing 0.01-1wt% acid dye and 0.01-0.5wt% water-soluble organic acid with one or more functional groups. The cosmetic composition provides good pigmentation, long wear and good color stability. In a preferred embodiment of the invention, the composition further comprises oil-based dyes. In another preferred embodiment of the invention, a solution of a water-soluble organic acid as a solvent can be added to the composition.

Description

The lipophilic solid cosmetic composition that contains acid stain
(technical field)
The present invention relates to a kind of lipophilic solid cosmetic composition, it has good dyeing property, long-term lasting effect and good color stability, for example, is applicable to the make-up composition of lip pomade, eye shadow, rouge and foundation cream.
(conventional art)
The coloring agent (as pigment and dyestuff) that is used for lipophilic solid cosmetic composition is mainly used in cosmetic purpose, for example lip pomade, eye shadow, rouge and foundation cream; Think that skin provides color.Here employed coloring agent not only should provide tempting color, and can also satisfy the general characteristic of making make-up composition.That is to say that this class feature comprises the outward appearance uniformity, good coloring and use the long-lasting stable color in back when using.
Disclose according to GB patent 1,173,743, contain the dyestuff that is insoluble to oil in the cosmetics or the mixture that is insoluble to oil and is dissolved in the dyestuff of oil is benefited.
In addition, the lip pomade and the lipophile cosmetics of oil base dye mixture or oil base dyestuff and acid dye composition have also been disclosed in this technical field.
JP publication S63-119405 has disclosed a kind of transparent Solic cosmetic, it has the good transparency, appearance stability and excellent practicality and dyestuff dissolubility thereof, it is characterized in that containing the partial ester of 12-hydroxy stearic acid, rosiny polyol ester and polyhydric alcohol and branched chain fatty acid, perhaps the ester of polyhydric alcohol and unsaturated fatty acid.
JP publication H1-90110 has disclosed a kind of transparent Solic cosmetic, it has the stability and the first-class practicality and the dye stability of the good transparency, appearance, its characteristics are the partial ester of amide containing resin, rosin pentaerythritol ester, polyglycereol and side chain fat acid, the perhaps ester of polyglycereol and unsaturated fatty acid.
JP publication H1-287011 discloses, a kind of emulsifying lip pomade, and it has vivid color, contains water solublity mineral hargil, water and fluorescence class dyestuff.
JP publication H3-86808 has disclosed a kind of lip pomade, it has excellent practicality, as good color representation, spreadability, tack, long-term persistence, good surface appearance and stability, the ester compounds of forming by oxyacid and aliphatic alcohol that contains solid carbon hydrogen compound, the 15-16% of 13-21%, the liquid of 20-65% or pasty state Hydrocarbon, and oil base dyestuff.
JP publication H3-90013 has disclosed a kind of lip pomade, it has excellent practicality, as good color representation, spreadability, tack, long-term persistence, good surface appearance and stability contain the ester compounds of being made up of polyhydric alcohol and aliphatic alcohol of solid carbon hydrogen compound, the 15-60% of 13-21%, liquid-type pasty state Hydrocarbon and the oil base dyestuff of 20-65%.
JP publication H3-236307 has disclosed a kind of lipophile cosmetics, and its not diaphoresis has the high chroma color, it is characterized in that containing 0.01-30wt% gama-alumina (a certain relative surface area of tool), and the oil base dyestuff of 0.01-10wt%.
Yet acid stain is exposed to easily decolouring under the atmospheric humidity, can cause the variation of color itself.For cosmetics (as lip pomade), nondiscoloration preferably.Like this, with regard to conventional art, lipophile cosmetics (as the cream lip) tendency that contains acid stain is used for dead color, because dark-coloured decolouring can be so unobvious.
At this, by containing a kind of acid stain of tool water-soluble organic acid, obtained a kind of lipophilic solid cosmetic composition, it has good coloring, and long-term persistence and good color stability are promptly passed in time and are decoloured few.
Simultaneously, consider safety, need be with a spot of dyestuff coloring effect that offers the best.As everyone knows, dyestuff is difficult to dissolve in the lipophilic solid cosmetic composition equably, because it has the trend with other lipophile component separating, therefore needs its content as much as possible little.
At this, by also containing a kind of oil base dyestuff, obtained a kind of lipophilic solid cosmetic composition, it has good coloring, long-term persistence, good color stability and the outward appearance uniformity of improvement.The total amount of dyestuff is few, and tone range is wide.
(purpose of the present invention)
The object of the present invention is to provide a kind of lipophilic solid cosmetic composition, it has good coloring, long-term persistence and good color stability.
The present invention also aims to provide a kind of lipophilic solid cosmetic composition, it uses a spot of dyestuff but to have same effect.
The present invention also aims to provide a kind of lipophilic solid cosmetic composition, its outward appearance uniformity and tone range with improvement is wide.
(detailed description of the present invention)
The present invention relates to a kind of lipophilic solid cosmetic composition, it contains by weight: (a) acid stain of 0.01-1%; (b) 0.01-0.5% has the water-soluble organic acid of one or more functional groups; And the oil base dyestuff that is preferably 0.01-2%.
Dyestuff and organic acid
Make-up composition of the present invention contains the acid stain of 0.01-1wt%, and preferred content is 0.01-0.25wt%.The acid stain that uses among the present invention is that those are enough to be used safely in the acid stain in the cosmetics, for example D﹠amp; C Red #28 (according to the Red of Japanese health benefit portion (to call MHW in the following text) rules and regulations #104-(1)), D﹠amp; C Red #6 (according to the Red of MHW rules and regulations #201), FD﹠amp; C Yellow #5 (according to the Yellow of MHW rules and regulations #4) and FD﹠amp; C Yellow #6 ((according to the Yellow of MHW rules and regulations #5)).But the acid stain former state adds in the make-up composition, or adds as the mixture with fatty acid ester.
Make-up composition of the present invention contains the water-soluble organic acid with one or more functional groups of 0.01-0.5wt%, and preferred content is 0.05-0.1wt%.The example of water-soluble organic acid is a citric acid, anhydrous citric acid, lactic acid, tartaric acid and malic acid.
Can decolour though people generally know acid stain, itself and organic acid be mixed mutually can improve its coloring and the stability of color in time.As long as there is a small amount of organic acid just can observe this effect, when organic acid content is at least 0.5 times (weight) of acid stain, can be observed remarkable result.
Make-up composition of the present invention also can contain the oil base dyestuff of 0.01-2wt%, and preferred content is 0.01-0.5wt%.The oil base dyestuff that uses among the present invention is that those are enough to be used safely in the oil base dyestuff in the cosmetics, as D﹠amp; C Red #21 (according to the Red of MHW rules and regulations #223), D﹠amp; C Red #27 (according to the Red of MHW rules and regulations #218) and D﹠amp; C Or-ange #5 (according to the Orange of MHW rules and regulations #201).In the present invention, add the oil base dyestuff, compare, only use more a spot of dyestuff just can obtain identical coloring effect with only adding acid stain.From angle to skin safety and product stability, add article and be necessary for minimum flow.In addition, the combination of dyestuff has enlarged the kind of tone.But oil base dyestuff former state adds in the make-up composition, perhaps adds as the mixture with fatty acid ester, and acid stain is also like this.
Solvent
In the present invention, organic acid can be incorporated in the make-up composition, be about to it and be dissolved in the 0.1-5wt% that accounts for make-up composition, preferred 0.5-3wt% is most preferably in the solvent of 0.7-1.5wt%.Solvent can be selected from water, have the monohydric alcohol and the polyhydric alcohol of 1-6 carbon atom.The example of solvent is water, ethanol, isopropyl alcohol, glycerol, two glycerol, triglycerin, ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, 1,3 butylene glycol and 1, the 4-butanediol.By adding the organic acid as solvent solution, organic acid can be evenly dispersed in the make-up composition, sees it is preferred from the angle of method.Find also that in addition some combination of dyestuff and solvent can improve the stability of color.Moreover because some polyhydric alcohol has good adhesion to skin, the combination of itself and dyestuff can improve coloring.The selection of type of solvent to consider its in make-up composition with the intermiscibility of other composition, also to consider the needs of resultant product simultaneously.
The selectivity composition
Except that this paper those disclosed composition, lipophilic solid cosmetic composition of the present invention also can contain the following ingredients that make-up composition contains usually.
In general, make-up composition of the present invention contains the lipophilicity substance of 30-98wt%, and lip pomade is 60-98wt%, and preferred content is 80-95wt%, also contains the pigment of 0-65wt%, and lip pomade is 0-39wt%, and preferred content is 2-20wt%.
Lipophilicity substance
Used lipophilicity substance is selected from solid lipophilicity substance, fluid oil, oily gellant and composition thereof among the present invention.Those skilled in the art can select these compositions according to the make-up composition that will make.(, preferably add the mixture of solid lipophilicity substance, fluid oil and oleogel agent for containing the make-up composition that surpasses 10% pigment as foundation cream, eye shadow and rouge.
The solid lipophilicity substance
The solid lipophilicity substance can serve as firming agent in make-up composition of the present invention.It helps the formation of solid structure in the compositions.This solid is the mixture of low-melting organic compound or high molecular weight material, at room temperature is solid or pasty state.Solid can be wax, Hydrocarbon, fatty acid, aliphatic alcohol, natural fat or ester, but is not limited thereto.
Can use natural, mineral and synthetic wax herein.The limiting examples of the native paraffin of animal origin has Cera Flava, spermaceti, lanoline, shellac wax; Or plant origin, as Brazil wax, candelilla wax, Fructus Lauri nobilis, sugarcane wax; Or mineral sources, as ceresine, ceresin, montan wax, paraffin, crystallite, vaseline, oil and petrolatum wax.The limiting examples of synthetic wax is the polyhydric alcohol ether-ester, as Polyethylene Glycol, hydrocarbon wax, silicon wax and Tissuemat E.Also can use synthetic glycerine three esters of wax form, as the ester of linear fatty acid.Most preferred wax is ceresine, ceresin, lanoline, crystallite, Brazil wax, Cera Flava and paraffin.
Here employed fatty acid can be saturated, undersaturated, straight or branched.Limiting examples is lauric acid, myristic acid, Palmic acid, stearic acid and mountain Yu acid.
Here employed nonlimiting examples of fatty alcohols is octyl group, decyl, lauryl, myristyl, cetyl, stearyl and mountain Yu base alcohol.
Here the limiting examples of employed natural fat is a cupu oil, Petiolus Trachycarpi oil, Japan wax, hydrogenated vegetable oil, castor oil hydrogenated and cholesterol.
Here the limiting examples of employed ester has myristic acid myristyl ester, Palmic acid, myristyl ester, stearic acid myristyl ester, Palmic acid cetyl ester, stearic acid cetyl ester, lactic acid cetyl ester, lactic acid stearyl, cholesteryl stearate, Cholesterol 3.beta.-oleate, cholesteryl palmitate ester, lauric acid cholesterol ester, myristic acid cholesterol ester, linoleic acid cholesterol ester and ricinoleic acid cholesterol ester.
Fluid oil
Fluid oil can serve as emollient, and gives cosmetics cohesive and drag characteristic.Fluid oil is free flowable material at ambient temperature.Fluid oil also can be volatile.Described fluid oil can be hydrocarbon ils, natural oil, aliphatic alcohol, fat fat acid esters, silicone oil etc., but is not limited thereto.
The limiting examples of employed Hydrocarbon has liquid paraffin, Squalene, petroleum liquid, mineral oil and liquid polybutene among the present invention.
Natural oil used herein is generally the mixture of saturated and unsaturated fatty acid.The limiting examples that derives from the natural oil of plant comprises almond oil, olive oil, Oleum sesami, safflower oil, American Avocado Tree oil, Oleum Gossypii semen, simmondsia oil, Oleum Ricini, rapeseed oil, soybean oil, palm kernel oil and Oleum Cocois.The limiting examples that derives from the natural oil of animal is ermine oil and egg oil.
The nonlimiting examples of fatty alcohols of using among the present invention is isooctadecane alcohol, lanolin alcohol, oleyl alcohol, hexadecanol, octyldodecanol, inferior oleyl alcohol, linolenyl alcohol and arachyl alcohol.
The fatty acid that uses among the present invention can be natural or synthetic, saturated, unsaturated, straight or branched.Employed nonlimiting examples of fatty acids has adipic acid, sad, capric acid, isostearic acid, linoleic acid, ricinoleic acid, oleic acid, petroleum acids and erucic acid among the present invention.
The limiting examples of the fatty acid ester that uses among the present invention has ricinoleic acid cetyl ester, oleic acid cetyl ester, cetyl octanoate, acetic acid cetyl ester, tricaprylin, the lanolin fatty acid isopropyl ester, the linoleic acid isopropyl ester, isopropyl myristate, isopropyl palmitate, acid isopropyl, isopropyl stearate, ethyl lactate, ethyl glutamate, ethyl laurate, Ethyl linoleate, ethyl methacrylate, ethyl myristate, ethyl palmitate, diisopropyl adipate, myristic acid octyl group dodecyl ester, octyl palmitate, different octyl pelargonate, lactic acid octyl group dodecyl ester, different n-nonanoic acid tridecane ester, the different tridecane ester of different n-nonanoic acid, cetyl stearic, oleic acid oil base ester, isononyl isononanoate, myristic acid iso stearyl ester, dipentaerythritol ester, two n-nonanoic acid DOPCP and two (caprylic/capric) propylene glycol.Other ester that is suitable for comprises triglyceride, as Trivent OCG, tricaprin, isostearic acid triglyceride, adipic acid triglyceride.
Also can use non-volatile and volatility, straight chain, side chain and ring-type silicone oil, as dimethicone, phenyl dimethicone and SILIBIONE OIL 70047 V20 DC-21330 DC21330.
The oil gellant
For the gelling or the viscosity control of filling a prescription adds oily gellant.The polyhydric alcohol that the limiting examples of the oily gellant that uses among the present invention has benzaldehyde and has at least 5 bases, as dibenzylidene xyllitol, condensation product to the tribenzal sorbitol, metallic soap such as calcium stearate, calcium palmitate, the lithium salts of 2-ethyl hexane, 1, the aluminum salt of 2-hydroxystearic acid, the amide of N-acylamino acid, ester and amide derivatives, as lauroyl glutamic acid two butyramides, lauroyl glutamic acid stearmide, two hexanoyl lysine lauramides, two hexanoyl lysine lauroyl amine salt, two hexanoyl lysine lauryls, two hexanoyl lysine lauroyl phenylalanine lauramides; Dextrin fatty acid ester and 1,2-hydroxystearic acid.
Pigment
The limiting examples of the pigment that uses among the present invention has Talcum, Muscovitum, hargil, potter's clay, zinc oxide, nylon powder, ultramarine, pearl pigment (bismuth oxychloride, guanine), ferrum oxide, titanium dioxide, contains odenite, calcium carbonate, tar pigment and other organic pigment.Carrying out surface-treated pigment with siloxanes and derivant, metallic soap, fluorine compounds and derivant thereof, lecithin and derivant thereof, aminoacid and salt thereof etc. also can use.
Before being used for manufacturing process pigment also can be dispersed in as top under the fluid oil item disclosed oiliness valency matter.The form that pigment can be pre-dispersed in oil medium such as the Oleum Ricini is buied or is buied with dry powder form, and the latter can be dispersed in the selected medium subsequently by the formulatory.
Other selectivity composition
The compositions made from the inventive method optionally contains some compositions except that mentioned component, as long as the general pH value of making as a whole lipophilic solid cosmetic composition is in the 4-7 scope.
The selectivity composition comprises antioxidant, preservative agent, antiinflammatory, astringent, pH buffer agent, spice, ultraviolet and infrared screening agent, non-ionic surface active agent (as fatty acid ester and polyoxyalkylene fatty acid ester), amphion and anion surfactant (as lecithin and phosphate), vitamin and skin conditioning agent.
Antioxidant and preservative agent can be formulated in the compositions of the present invention usually, so that product is more attractive to consumer.The antioxidant of practicality and preservative agent have tocopherol, dibenzylatiooluene, methyl butex and propyl parabene.The general content of these compositions is no more than 1% respectively.
The practicality skin conditioning agent is β-glycyrrhetinic acid and derivant, plant extract, allantoin, collagen protein and extract and treated elastic fiber.
(embodiment)
Following embodiment can illustrate compositions of the present invention, but and not only is confined to this.Remove and to indicate the place especially, when ratio is all by weight for all percentages.
Table 1
Composition Content (%)
Embodiment 1 Embodiment 2 Embodiment 3
????D&C?Red #28 (according to the Red of MHW rules and regulations #104(1))
Anhydrous citric acid
????D&C?Red #27 (according to the Red of MHW rules and regulations #218)
Butanediol ???- ???-
Ethanol ???- ???-
Distilled water ???- ???-
Ceresin
Microwax
Candelilla wax
Paraffin
Oleum Ricini
Liquid paraffin
The purification lanoline
Liquid lanolin
Tricaprylin
Red is (according to the Red of MHW rules and regulations #202)
Red (according to the Red#201 of MHW rules and regulations)
Yellow pigment is (according to the Yellow of MHW rules and regulations #?4?Aluminum)
Titanium dioxide
Ferrum oxide
Amount to
Lip pomade shown in the embodiment 1-3 in the table 1 can be prepared by suitable in the art method.As method for optimizing, can use following method.With acid stain, oil base dyestuff and pigment and a certain amount of Oleum Ricini respectively blending get up.Anhydrous citric acid is dissolved in solvent makes 5% solution.With the dye mixture that obtains thus, pigment composition mixes with other composition (fusion and the dissolving under 100-120 ℃ of condition of these compositions) mutually with organic acid soln.The mixture that finally obtains is inclined in the mould, obtained stick lip balm.

Claims (6)

1.一种亲油性固体化妆组合物，其以重量计含有：1. A lipophilic solid cosmetic composition, which contains by weight:    a)0.01-1％的酸性染料；a) 0.01-1% acid dye;    b)0.01-0.5％的具有一个或多个官能团的水溶性有机酸。b) 0.01-0.5% of a water-soluble organic acid with one or more functional groups. 2.依据权利要求1的亲油性固体化妆组合物，进而含有0.01-2％(重量)的油基染料。2. The lipophilic solid cosmetic composition according to claim 1, further comprising 0.01-2% by weight of an oil-based dye. 3.依据权利要求1或2的亲油性固体化妆组合物，其中所述水溶性有机酸选自柠檬酸、无水柠檬酸、乳酸、酒石酸、苹果酸及其混合物。3. The lipophilic solid cosmetic composition according to claim 1 or 2, wherein the water-soluble organic acid is selected from the group consisting of citric acid, anhydrous citric acid, lactic acid, tartaric acid, malic acid and mixtures thereof. 4.依据权利要求1、2或3的亲油性固体化妆组合物，其中所述水溶性有机酸的含量水平至少为所述酸性染料重量的0.5倍。4. The lipophilic solid cosmetic composition according to claim 1, 2 or 3, wherein said water-soluble organic acid is present at a level of at least 0.5 times the weight of said acid dye. 5.依据权利要求1、2、3或4的亲油性固体化妆组合物，其中将所述水溶性有机酸作为占组合物重量0.1～5％溶剂的溶液引入组合物中，其中所述溶剂选自水、1-6个碳原子的一元醇、多元醇及其混合物。5. The lipophilic solid cosmetic composition according to claim 1, 2, 3 or 4, wherein said water-soluble organic acid is introduced into the composition as a solution in a solvent of 0.1 to 5% by weight of the composition, wherein said solvent is selected from From water, monohydric alcohols with 1 to 6 carbon atoms, polyhydric alcohols and mixtures thereof. 6.一种唇膏组合物，其以重量含有：6. A lipstick composition comprising by weight:    a)0.01-1％的酸性染料；a) 0.01-1% acid dye;    b)0.01-0.5％的具有一个或多个官能团的水溶性有机酸；b) 0.01-0.5% of water-soluble organic acids with one or more functional groups;    c)0.01-2％的油基染料；c) 0.01-2% oil-based dyes;    d)0.1-5％的溶剂；d) 0.1-5% solvent;    e)60-98％的亲油性物质；e) 60-98% lipophilic substances;    f)0-39％的颜料；其中将水溶性有机酸作为所述溶剂的溶液引入组合物中。f) 0-39% pigment; wherein a water-soluble organic acid is introduced into the composition as a solution in said solvent.
CN94194583A 1993-12-24 1994-12-15 Lipophilic solid cosmetic composition containing acid dye Expired - Fee Related CN1113642C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP5328024A JP2831552B2 (en) 1993-12-24 1993-12-24 Oily solid cosmetics containing acid dyes
JP328024/93 1993-12-24
JP328024/1993 1993-12-24

Publications (2)

Publication Number Publication Date
CN1138293A true CN1138293A (en) 1996-12-18
CN1113642C CN1113642C (en) 2003-07-09

Family

ID=18205673

Family Applications (1)

Application Number Title Priority Date Filing Date
CN94194583A Expired - Fee Related CN1113642C (en) 1993-12-24 1994-12-15 Lipophilic solid cosmetic composition containing acid dye

Country Status (7)

Country Link
EP (1) EP0742710A1 (en)
JP (1) JP2831552B2 (en)
CN (1) CN1113642C (en)
AU (1) AU699995B2 (en)
CA (1) CA2179279A1 (en)
CZ (1) CZ174996A3 (en)
WO (1) WO1995017884A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2735688B1 (en) * 1995-06-26 1997-08-14 Oreal USE IN COMBINATION OF AN ALPHA-HYDROXYACID AND A TITANIUM OXIDE FOR SKIN WHITENING
US20030161851A1 (en) * 2002-02-14 2003-08-28 Bonne Bell, Inc. Cosmetic lip product with sour flavor
JP4643366B2 (en) * 2005-06-06 2011-03-02 株式会社資生堂 Oily solid cosmetic
JP5944290B2 (en) * 2012-09-26 2016-07-05 株式会社マンダム Compositions and cosmetics in which fading is prevented
JP6034986B2 (en) * 2015-01-21 2016-11-30 株式会社 資生堂 Makeup cosmetics
WO2016117640A1 (en) * 2015-01-21 2016-07-28 株式会社 資生堂 Makeup cosmetic
JP6153275B1 (en) 2016-04-28 2017-06-28 高級アルコール工業株式会社 Cosmetics
JP6921504B2 (en) * 2016-11-21 2021-08-18 ロレアル Solid cosmetic composition for use in make-up
JP7209179B2 (en) * 2018-12-05 2023-01-20 日本メナード化粧品株式会社 Method for dissolving oil-soluble dye and oil-soluble dye solution

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6037087B2 (en) * 1978-09-28 1985-08-24 花王株式会社 cosmetics
FR2480770A1 (en) * 1980-04-18 1981-10-23 Oreal PROCESS FOR PREPARATION OF SALTS OF ACID COLORANTS, AND OF COPOLYMERS CARRYING TERTIARY AMINE FUNCTIONS, SALTS OBTAINED AND MAKE-UP COSMETIC COMPOSITIONS CONTAINING THEM
JPH0234669A (en) * 1988-07-22 1990-02-05 Kao Corp Dye-containing nacreous pigment and cosmetic containing same
EP0445785B1 (en) * 1990-03-07 1995-08-09 Kao Corporation Plate-like barium sulfate and cosmetic composition

Also Published As

Publication number Publication date
WO1995017884A1 (en) 1995-07-06
CN1113642C (en) 2003-07-09
EP0742710A1 (en) 1996-11-20
JPH07206635A (en) 1995-08-08
CZ174996A3 (en) 1997-01-15
CA2179279A1 (en) 1995-07-06
AU1400695A (en) 1995-07-17
AU699995B2 (en) 1998-12-17
JP2831552B2 (en) 1998-12-02

Similar Documents

Publication Publication Date Title
EP0522618B1 (en) Coloured cosmetic sticks
JP2752855B2 (en) Production method and use of solid dispersion containing polyhydric alcohol in fat body
US5750121A (en) Color cosmetic composition containing alcohol modified wax
DE60019541T2 (en) Structured long-lasting preparation containing a polymer and pasty fatty substances
DE69902079T2 (en) Abrasion-resistant make-up or body care products
US6667047B2 (en) Ultra-stable composition comprising moringa oil and its derivatives and uses thereof
JP2001172119A (en) Cosmetic composition containing hydroxylated fatty acid ester
US4066789A (en) Blends of lanolin wax and esters of aliphatic polyols and fatty acids
CN1113642C (en) Lipophilic solid cosmetic composition containing acid dye
JPWO2008143081A1 (en) Oily solid cosmetic
JPH09235210A (en) Solid cosmetic
CN1211176A (en) Transfer-resistant lip compositions
EP0795312A1 (en) Color cosmetic composition containing alcohol modified wax
JP2017197492A (en) Cosmetic
NZ245628A (en) Cosmetic or dermatological compositions comprising a fatty acid diester of 2,3-butanediol as viscosity agent and emollient
JP2004051500A (en) Solid oily cosmetic
JP3963370B2 (en) Solid cosmetic and method for producing the same
JP7301760B2 (en) Skin topical agent
CN118787570A (en) Oil gelling agent
JP7817822B2 (en) Solid oil-based cleansing cosmetics
CA2368665A1 (en) Oil-based cosmetics containing water-soluble actives
KR101791897B1 (en) Lip cosmetic composition containing amino acid mixture
JP3423069B2 (en) Lipstick
JPS6140204A (en) Cosmetic
FR3117354A1 (en) Composition, in particular cosmetic, with a blurring effect

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20030709

Termination date: 20121215