Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide a high electron mobility transistor and a preparation method thereof so as to reduce the on-resistance of the device.
In order to achieve the above purpose, the technical scheme adopted by the embodiment of the invention is as follows:
In one aspect of the embodiment of the invention, a method for preparing a high electron mobility transistor is provided, which comprises the steps of sequentially forming a channel layer, a first isolation layer, a first doping layer, a barrier layer, a low-energy-gap tunneling layer, an aluminum arsenide etching barrier layer, a first N-type doping layer, an indium gallium arsenide etching barrier layer and a second N+ type doping layer on a substrate, depositing metal on the second N+ type doping layer to form a source electrode and a drain electrode respectively, etching the second N+ type doping layer in a region between the source electrode and the drain electrode and terminating at the indium gallium arsenide etching barrier layer to form a first groove, sequentially etching the indium gallium arsenide etching barrier layer and the first N-type doping layer in the first groove and terminating at the aluminum arsenide etching barrier layer to form a second groove, etching the aluminum arsenide etching barrier layer in the second groove and terminating at the low-energy-gap tunneling layer to form a third groove, wherein the first groove, the second groove and the third groove are communicated to form a gate groove, and depositing metal in the gate groove to form a gate electrode in contact with the low-energy-gap tunneling layer.
Optionally, a buffer layer is also formed between the substrate and the channel layer.
Optionally, a second doping layer and a second isolation layer are sequentially formed between the buffer layer and the channel layer.
Optionally, the low-energy gap tunneling layer is a gallium arsenide layer or an indium gallium arsenide layer.
Optionally, etching the second N+ doped layer in the region between the source and the drain and terminating in the InGaAs etch stop layer to form the first recess includes etching the second N+ doped layer in the region between the source and the drain by citric acid and terminating in the InGaAs etch stop layer to form the first recess.
Optionally, sequentially etching the InGaAs etch stop layer and the first N-doped layer in the first recess and terminating in the AlAs etch stop layer to form a second recess includes sequentially etching the InGaAs etch stop layer and the first N-doped layer in the first recess with succinic acid and terminating in the AlAs etch stop layer to form a second recess.
Optionally, the thickness of the aluminum arsenide etching barrier layer and the indium gallium arsenide etching barrier layer is 1nm to 5nm.
Optionally, the thickness of the channel layer is 5-15 nm, the thickness of the first isolation layer is 3-8 nm, the thickness of the barrier layer is 12-20 nm, the thickness of the low-energy-gap tunneling layer is 1-5 nm, the thickness of the first N-type doped layer is 10-40 nm, and the thickness of the second N+ type doped layer is 30-80 nm;
Optionally, the first doped layer and the second doped layer are planar doped layers.
In another aspect of the embodiment of the invention, a high electron mobility transistor is provided, which comprises a substrate, a channel layer, a first isolation layer, a first doping layer, a barrier layer, a low-energy-gap tunneling layer, an aluminum arsenide etching barrier layer, a first N-type doping layer, an indium gallium arsenide etching barrier layer and a second N+ type doping layer which are sequentially arranged on the substrate, wherein a grid groove is formed on the surface of the first N-type doping layer, penetrates through the second N+ type doping layer, the indium gallium arsenide etching barrier layer, the first N-type doping layer and the aluminum arsenide etching barrier layer in sequence to expose the low-energy-gap tunneling layer, a source electrode and a drain electrode which are in contact with the second N+ type doping layer are arranged on two sides of the grid groove, and a grid electrode which is in contact with the low-energy-gap tunneling layer is arranged in the grid groove.
The beneficial effects of the invention include:
The invention provides a high electron mobility transistor and a preparation method thereof, the method comprises the steps of sequentially forming a channel layer, a first isolation layer, a first doping layer, a barrier layer, a low-energy-gap tunneling layer, an aluminum arsenide etching barrier layer, a first N-type doping layer, an indium gallium arsenide etching barrier layer and a second N+ type doping layer on a substrate. Metal is deposited on the second n+ doped layer to form a source and a drain, respectively. And forming a first groove on the second N+ type doped layer. And forming a second groove on the InGaAs etching barrier layer and the first N-type doped layer. And forming a third groove on the aluminum arsenide etching barrier layer, wherein the first groove, the second groove and the third groove are communicated to serve as a grid groove. Metal is deposited in the gate recess to form a gate electrode in contact with the low energy gap tunneling layer. Thereby forming a schottky contact with the barrier layer below the low-bandgap tunneling layer. Since the low-bandgap tunneling layer is interposed between the gate electrode and the barrier layer, on-resistance between the source electrode and the drain electrode can be reduced. On the basis, the level between the first N-type doped layer and the second N+ type doped layer is set as the InGaAs etching barrier layer, so that the InGaAs etching barrier layer not only can play a role in blocking when etching the second N+ type doped layer, but also can effectively reduce the resistance of ohmic contact of the source electrode and the drain electrode after the device structure is formed because the InGaAs etching barrier layer is made of a low-energy-gap material, and further reduce the on-resistance of the device, thereby being convenient for improving the device performance.
Detailed Description
For the purpose of making the objects, technical solutions and advantages of the embodiments of the present invention more apparent, the technical solutions of the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention, and it is apparent that the described embodiments are some embodiments of the present invention, but not all embodiments of the present invention.
Thus, the following detailed description of the embodiments of the invention, as presented in the figures, is not intended to limit the scope of the invention, as claimed, but is merely representative of selected embodiments of the invention. It should be noted that, under the condition of no conflict, the features of the embodiments of the present invention may be combined with each other, and the combined embodiments still fall within the protection scope of the present invention.
It should be noted that like reference numerals and letters refer to like items in the following figures, and thus once an item is defined in one figure, no further definition or explanation thereof is necessary in the following figures.
In the description of the present invention, it should be noted that the terms "first," "second," "third," and the like are used merely to distinguish between descriptions and are not to be construed as indicating or implying relative importance.
In order to have better device performance, the existing high electron mobility transistor generally adopts two etching barrier layers to realize a double-groove structure, but because the two etching barrier layers are high-energy band gap layers, the formed ohmic contact resistance is larger, and the device performance is influenced. Therefore, in one aspect of the embodiments of the present application, by providing a method for manufacturing a High Electron Mobility Transistor (HEMT), the on-resistance of the device is reduced, and the performance of the device is improved. As shown in fig. 1, the steps of the preparation method are schematically shown, including:
and S010, sequentially forming a channel layer, a first isolation layer, a first doping layer, a barrier layer, a low-energy-gap tunneling layer, an aluminum arsenide etching barrier layer, a first N-type doping layer, an indium gallium arsenide etching barrier layer and a second N+ type doping layer on the substrate.
As shown in fig. 2, a substrate 100 is provided, and the substrate 100 may be a substrate for carrying semiconductor integrated circuit devices, such as gallium arsenide, silicon carbide, and the like. To form an epitaxial layer of a pseudomorphic doped heterojunction field effect transistor (pHEMT), a channel layer 240, a first isolation layer 250, a first doped layer 260, a barrier layer 270, a low-bandgap tunneling layer 280, an aluminum arsenide etch stop layer 290, a first N-doped layer 310, an indium gallium arsenide etch stop layer 320, and a second n+ -doped layer 330 may also be formed sequentially on the substrate 100 described above. The formation of each epitaxial layer can be performed by Chemical Vapor Deposition (CVD), physical Vapor Deposition (PVD), atomic Layer Deposition (ALD), or the like, which is not limited by the present application, and can be reasonably selected according to practical requirements.
And S020, depositing metal on the second N+ type doped layer to form a source electrode and a drain electrode respectively.
When forming the epitaxial layer of the pHEMT device in S010, as shown in fig. 2, metal may be continuously deposited on the uppermost layer of the epitaxial layer, i.e., the second n+ type doped layer 330 to form the source electrode 340 and the drain electrode 350, respectively, so that ohmic contact of the device is formed by the contact of the source electrode 340 with the second n+ type doped layer 330 and the contact of the drain electrode 350 with the second n+ type doped layer 330, and the source electrode 340 and the drain electrode 350 may be spaced apart in order to ensure the performance of the device.
And S030, etching a second N+ type doped layer in the region between the source electrode and the drain electrode and stopping at the InGaAs etching barrier layer to form a first groove.
As shown in fig. 3, the etching manner may be to coat a photoresist layer on the upper surfaces of the second n+ type doped layer 330 and the source electrode 340 and the drain electrode 350, and form a patterned photoresist layer with a window region after exposing, developing and hard baking, wherein the window region is located in a region between the source electrode 340 and the drain electrode 350, and the second n+ type doped layer 330 exposed in the window region is removed by etching solution or physical etching until the second n+ type doped layer is terminated in the indium gallium arsenide etching barrier layer 320, wherein during etching, a relatively high etching solution may be selected according to the second n+ type doped layer 330 and the indium gallium arsenide etching barrier layer 320, so that the etching depth can be controlled during etching the second n+ type doped layer 330, thereby forming the first groove 361 structure on the second n+ type doped layer 330. After forming the first recess 361, the patterned photoresist layer may be stripped and removed, forming the structure shown in fig. 3.
And S040, sequentially etching the InGaAs etching barrier layer and the first N-type doping layer in the first groove and ending at the AlAs etching barrier layer to form a second groove.
As shown in fig. 4, a photoresist layer is continuously coated on the structure formed in S030, and then a first patterned photoresist layer 410 is formed through processes such as exposure and development, and a window region of the first patterned photoresist layer is located in the first groove 361, so that the indium gallium arsenide etching barrier layer 320 is exposed in the window region. The etching solution and other methods remove the gallium arsenide etching barrier layer 320 exposed in the window area in the first groove 361, then expose the first N-type doped layer 310 below, and then continue to etch the exposed first N-type doped layer 310 until the etching is stopped at the aluminum arsenide etching barrier layer 290, so as to form the second groove 362 on the gallium arsenide etching barrier layer 320 and the first N-type doped layer 310, as shown in fig. 6, wherein when the gallium arsenide etching barrier layer 320 and the first N-type doped layer 310 are etched sequentially, the etching can be performed by the same etching solution, or by two etching solutions, but when the first N-type doped layer 310 is etched, the etching solution with a relatively high etching selection should be selected according to the first N-type doped layer 310 and the aluminum arsenide etching barrier layer 290 to etch the first N-type doped layer 310, so that the etching depth of the first N-type doped layer 310 can be controlled by the aluminum arsenide etching barrier layer 290.
And S050, etching the aluminum arsenide etching barrier layer in the second groove and ending at the low-energy-gap tunneling layer to form a third groove, wherein the first groove, the second groove and the third groove are communicated to serve as a grid groove.
After the structure shown in fig. 6 is formed in S040, the aluminum arsenide barrier layer is continuously removed in the second groove 362 by etching until the low-bandgap tunneling layer 280 under the aluminum arsenide barrier layer is exposed, so as to form the structure shown in fig. 7, and the etching may refer to the above-mentioned manner of forming the first groove 361 and the second groove 362 by etching, which is not repeated here. In this way, the third groove can be formed on the aluminum arsenide barrier layer, and since the second groove 362 is formed in the first groove 361 and the third groove is formed in the second groove 362, the three grooves are sequentially communicated along the forming sequence, and the whole communicated groove can be used as the gate groove 360. In this way, by sequentially etching the second n+ type doped layer 330, the indium gallium arsenide etching barrier layer 320, the first N type doped layer 310 and the aluminum arsenide etching barrier layer 290, a double-groove device structure can be formed, so that the breakdown voltage is improved, and the device has better performance. It should be noted that, when etching the first N-doped layer 310 and the aluminum arsenide etching barrier layer 290, the etching should be performed in two steps, so that the barrier effect can be achieved by the aluminum arsenide etching barrier layer 290 when etching the first N-doped layer 310, and similarly, the etching should be performed in two steps when etching the second n+ doped layer 330 and the indium gallium arsenide etching barrier layer 320.
And S060, depositing metal in the gate groove to form a gate electrode contacted with the low-energy-gap tunneling layer.
After forming the gate recess 360 in S050, metal may be deposited within the gate recess 360 to form the gate 370 of the pHEMT device, and the gate 370 is in contact with the low-bandgap tunneling layer 280 to form a schottky contact with the barrier layer 270 under the low-bandgap tunneling layer 280. Since the low-bandgap tunneling layer 280 is interposed between the gate electrode 370 and the barrier layer 270, on-resistance between the source electrode 340 and the drain electrode 350 may be reduced. On the basis, the level between the first N-type doped layer 310 and the second n+ type doped layer 330 is set as the InGaAs etching barrier layer 320, so that the InGaAs etching barrier layer 320 not only can play a role in blocking when the second n+ type doped layer 330 is etched, but also can effectively reduce the ohmic contact resistance of the source electrode 340 and the drain electrode 350 after the device structure is formed because the InGaAs etching barrier layer 320 is made of a low-energy-gap material, thereby further reducing the on resistance of the device and facilitating the improvement of the device performance.
In an embodiment of the present application, low-bandgap tunneling layer 280 may be a gallium arsenide layer or an indium gallium arsenide layer, such that the resistance of source 340 and drain 350 forming an ohmic contact is reduced. The aluminum arsenide etch stop layer 290 is a high energy gap material that can effectively increase the breakdown voltage of the device. The first N-doped layer 310 may be an N-doped layer.
As shown in fig. 5, in order to form the T-shaped gate 370 in the gate recess 360, the second patterned photoresist layer 420 may be further formed on the first patterned photoresist layer 410, so that the second patterned photoresist layer 420 may be trimmed to form a concave shape, so that the T-shaped region in fig. 5 is formed, and after the gate recess 360 is formed as shown in fig. 7, the second patterned photoresist layer 420 and the first patterned photoresist layer are stripped by evaporation of gate metal, so that the T-shaped gate 370 is formed, and thus the performance of the device is further improved.
Optionally, as shown in fig. 2, in order to improve performance of the pHEMT device, a buffer layer 210 may be further formed between the substrate 100 and the channel layer 240, so that a subsequent second doped layer 220 or second isolation layer 230 may be better formed on the substrate 100.
Optionally, a second doped layer 220 and a second isolation layer 230 are sequentially formed between the buffer layer 210 and the channel layer 240, where the second doped layer 220 and the channel layer 240 are separated by the first isolation layer 250, and the second isolation layer 230 is used to separate the second doped layer 240 from the channel layer 240, so as to further ensure the performance of the device. The first isolation layer 250 and the second isolation layer 230 are undoped layers.
Alternatively, since the second N+ type doped layer 330 may be etched by the citric acid and the InGaAs etch stop layer 320 has a good etch stop for the citric acid, when the second N+ type doped layer 330 is etched and terminated at the InGaAs etch stop layer 320 in the region between the source electrode 340 and the drain electrode 350 to form the first recess 361, the second N+ type doped layer 330 may be etched and terminated at the InGaAs etch stop layer 320 by the citric acid to form the first recess 361 on the second N+ type doped layer 330.
Alternatively, in a similar manner, since succinic acid can etch the gallium indium arsenide etching barrier layer 320, and simultaneously, can also etch the first N-type doped layer 310, and the succinic acid can have good etching stopping property through the aluminum arsenide layer, the gallium indium arsenide etching barrier layer 320 and the first N-type doped layer 310 can be sequentially etched in the first groove 361 and terminated in the aluminum arsenide etching barrier layer 290 to form the second groove 362, and the gallium indium arsenide etching barrier layer 320 and the first N-type doped layer 310 can be sequentially etched through succinic acid and terminated in the aluminum arsenide etching barrier layer 290 to form the second groove 362. Thus, the gallium indium arsenide etching barrier layer 320 and the first N-type doped layer 310 can be etched by one step through the succinic acid, and etching steps are saved.
By using the combination of citric acid and succinic acid at different stages, the gate recess 360 can be effectively formed when the etching barrier layer between the first N-type doped layer 310 and the second n+ -type doped layer 330 is the InGaAs etching barrier layer 320.
Alternatively, setting the thickness of the aluminum arsenide etching barrier layer 290 to be 1nm to 5nm, such as 2, 3, 4nm, etc., and setting the thickness of the indium gallium arsenide etching barrier layer 320 to be 1nm to 5nm, such as 2, 3, 4nm, etc., can effectively improve the performance of the device.
Alternatively, the thickness of the channel layer 240 of the pHEMT device may be set to 5nm to 15nm, for example, 8, 11, 13nm, etc., the thickness of the first isolation layer 250 is 3nm to 8nm, for example, 5nm, 7nm, etc., the thickness of the barrier layer 270 is 12nm to 20nm, for example, 15, 18nm, etc., the thickness of the low-bandgap tunneling layer 280 is 1nm to 5nm, for example, 2,3, 4nm, etc., the thickness of the first N-type doped layer 310 is 10nm to 40nm, and the thickness of the second n+ type doped layer 330 is 30nm to 80nm, so that the performance of the device may be effectively improved, enabling the pHEMT device to have a lower on-resistance.
Optionally, the first doped layer 260 and the second doped layer 220 are planar doped layers, which can effectively reduce the trap effect, and at the same time facilitate the pinch-off voltage control, improve the breakdown voltage of the gate 370, and increase the carrier concentration in the channel layer 240.
In another aspect of the embodiment of the present invention, as shown in fig. 8, a high electron mobility transistor is provided, including a substrate 100, and a channel layer 240, a first isolation layer 250, a first doped layer 260, a barrier layer 270, a low-bandgap tunneling layer 280, an aluminum arsenide etching barrier layer 290, a first N-type doped layer 310, an indium gallium arsenide etching barrier layer 320 and a second n+ type doped layer 330 sequentially disposed on the substrate 100, wherein a gate groove 360 is formed on a surface of the first N-type doped layer 310, the gate groove 360 penetrates through the second n+ type doped layer 330, the indium gallium arsenide etching barrier layer 320, the first N-type doped layer 310 and the aluminum arsenide etching barrier layer 290 in order to expose the low-bandgap tunneling layer 280, a source 340 and a drain 350 contacting the second n+ type doped layer 330 are disposed on two sides of the gate groove 360, and a gate 370 contacting the low-bandgap tunneling layer 280 is disposed in the gate groove 360. Since the low-bandgap tunneling layer 280 is interposed between the gate electrode 370 and the barrier layer 270, on-resistance between the source electrode 340 and the drain electrode 350 may be reduced. On the basis, the level between the first N-type doped layer 310 and the second n+ type doped layer 330 is set as the InGaAs etching barrier layer 320, so that the InGaAs etching barrier layer 320 not only can play a role in blocking when the second n+ type doped layer 330 is etched, but also can effectively reduce the ohmic contact resistance of the source electrode 340 and the drain electrode 350 after the device structure is formed because the InGaAs etching barrier layer 320 is made of a low-energy-gap material, thereby further reducing the on resistance of the device and facilitating the improvement of the device performance.
The above description is only of the preferred embodiments of the present invention and is not intended to limit the present invention, but various modifications and variations can be made to the present invention by those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the protection scope of the present invention.