CN1124754A - Flash set adhesive and its preparing process - Google Patents
Flash set adhesive and its preparing process Download PDFInfo
- Publication number
- CN1124754A CN1124754A CN 95110122 CN95110122A CN1124754A CN 1124754 A CN1124754 A CN 1124754A CN 95110122 CN95110122 CN 95110122 CN 95110122 A CN95110122 A CN 95110122A CN 1124754 A CN1124754 A CN 1124754A
- Authority
- CN
- China
- Prior art keywords
- group
- stirred
- abs
- methacrylic acid
- methacrylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 6
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 15
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 15
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000004090 dissolution Methods 0.000 claims abstract description 6
- -1 hydroxyl-ethyl-propyl-benzene peroxide Chemical class 0.000 claims abstract description 6
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 5
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 5
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical class COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- 241000521257 Hydrops Species 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 206010030113 Oedema Diseases 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 239000005864 Sulphur Substances 0.000 claims description 4
- 238000005538 encapsulation Methods 0.000 claims description 4
- 210000002700 urine Anatomy 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 238000009472 formulation Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 2
- 229920005439 Perspex® Polymers 0.000 abstract 2
- 238000004806 packaging method and process Methods 0.000 abstract 2
- 239000004926 polymethyl methacrylate Substances 0.000 abstract 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 abstract 1
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000004568 cement Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 241000272814 Anser sp. Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The quick-solidifying adhesive especially suitable for car's oil tank, chemical apparatus and refrigerator's evaporator includes components A and B, which are mixed at ratio of 1:1 on using it. The component A is prepared through mixing and thoroughly dissolving methylacrylic acid, nitrile rubber and ABS, then adding perspex, gluside, triethylamine, catalyst and thiourea standing for several hours for thorough dissolution, and packaging. The component B is prepared through mixing and thoroughly dissolving methylacrylic acid with ABS, then adding perspex, hydroxyl-ethyl-propyl-benzene peroxide, and oxalic acid standing for several hours for thorough dissolution, and packaging.
Description
The present invention relates to the tackiness agent and the preparation technology of a kind of metal or nonmetallic tackiness agent and preparation technology, particularly steel, plastics, pottery, glass.
Be used for metal and nonmetal common tackiness agent, bonding plane cements at 12～48 hours after fixing, and the operating time is long, the working efficiency that influence is produced and keeped in repair.As strength universal glue (Qiu city wild goose Nan Qianglijiaochang is appointed in Hebei), can glue metal, pottery, glass, bonding plane requires to handle clean, set time, bonding plane was met easily disengagement of heat, and preferably once uses up behind the Kaifeng more than 12 hours, otherwise remainder very rapid hardening lost efficacy, and caused waste.
The object of the present invention is to provide a kind of quick cementation, heat-resisting, repeatedly use and do not solidify, prepare simple SGA-39 rapid cure adhesive and preparation technology thereof.
The present invention is achieved in that prescription is that first group and second group ratio of mixture are 1: 1, wherein:
A. the first group is made up of methacrylic methyl esters 63.31%, nitrile rubber 11.09%, ABS11.09%, methacrylic acid 5.99%, asccharin 0.58%, triethylamine 1.46%, catalyzer 0.49%, sulphur urine 0.002%;
B. the second group is made up of basic methyl acrylate 60.97%, ABS21.98%, methacrylic acid 5.28%, hydrop second propyl benzene 11.72%, oxalic acid 0.05%.
Preparation technology of the present invention presses the operation of recipe ingredient content:
A. prepare first group 100 grams, earlier methacrylic acid 5.99 grams are put into reactor, after input nitrile rubber 11.09 grams, ABS11.09 gram are stirred to dissolving fully, put into methacrylic methyl esters 69.31 gram, asccharin 0.58 gram, triethylamine 1.46 grams, catalyzer 0.49 gram, sulphur urine 0.02 gram again and be stirred to uniform dissolution, encapsulation after 4 hours.
B. prepare second group 100 grams, other gets reactor, after putting into methacrylic acid 5.28 gram, ABS21.98 gram and being stirred to dissolving fully, puts into methyl methacrylate 60.97 grams, hydrop second propyl benzene 11.72 grams, oxalic acid 0.05 gram again, be stirred to uniform dissolution, encapsulation after 4 hours.
Before each the use, the first group mixed to mix well by 1: 1 with the second group and get final product.Through experiment test, adhesive face shearing resistance 150Kg/cm
2, anti-grain intensity 450Kg/cm
2, heatproof-60～120 ℃.Bonding back 15～30 minutes, sticky object can change down road production process or repairing over to, has significantly shortened the bonding operating time, has improved working efficiency, repeatedly uses and does not solidify, and under household condition preserves more than 6 months.
The present invention can quick at normal temperatures bonding copper removal beyond all metals, remove polypropylene, outer all plastics of polyethylene and fluoroplastics and pottery, stone implement, timber, things such as cement, be need not strict the processing by maxxaedium, the particularly suitable automotive oil tank, wheel box, chemical industry equipment, household electrical appliances, the assembling maintenance of instrument measurer pressurized vessel, especially the manufacturing of evaporator of electric refrigerator and repairing, product percent of pass 99%, time is short, the efficient height, be convenient to rationally arrange technology, save a large amount of starting material, reduce cost, on producing, realize outstanding substantial technical progress, and preparation technology is simple, is beneficial to large scale application in the maintenance.
Claims (2)
1. rapid cure adhesive, prescription are first group and second group ratio of mixture 1: 1, wherein:
A. the first group is made up of methacrylic methyl esters 63.31%, nitrile rubber 11.09%, ABS11.09%, methacrylic acid 5.99%, asccharin 0.58%, triethylamine 1.46%, catalyzer 0.49%, sulphur urine 0.002%;
B. the second group is by basic methyl acrylate 60.97%, and ABS21.98%, methacrylic acid 5.28%, hydrop second propyl benzene 11.72%, oxalic acid 0.05% are formed.
2. the preparation technology of a claim 1, it is standby to get component by formulation content:
A. prepare the first group, earlier methacrylic acid is put into reactor, after dropping into nitrile rubber, ABS and being stirred to dissolving fully, put into methacrylic methyl esters, asccharin, triethylamine, catalyzer, sulphur urine again and be stirred to uniform dissolution, encapsulation after 4 hours;
B. prepare the second group, other gets reactor, after putting into methacrylic acid, ABS and being stirred to dissolving fully, puts into methyl methacrylate again, hydrop second propyl benzene, and oxalic acid is stirred to uniform dissolution, encapsulation after 4 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95110122 CN1124754A (en) | 1995-03-23 | 1995-03-23 | Flash set adhesive and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95110122 CN1124754A (en) | 1995-03-23 | 1995-03-23 | Flash set adhesive and its preparing process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1124754A true CN1124754A (en) | 1996-06-19 |
Family
ID=5077542
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 95110122 Pending CN1124754A (en) | 1995-03-23 | 1995-03-23 | Flash set adhesive and its preparing process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1124754A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993991A (en) * | 2012-10-31 | 2013-03-27 | 安徽东方金河精密机械制造有限公司 | Acrylate-structured adhesive |
| CN101981149B (en) * | 2008-03-21 | 2013-09-18 | 杰克瑞特公司 | Compositions for structural adhesives |
| CN104371573A (en) * | 2014-10-31 | 2015-02-25 | 青岛昌安达药业有限公司 | Durable wood adhesive |
| CN107735473A (en) * | 2017-06-01 | 2018-02-23 | 苏州佳亿达电器有限公司 | Encapsulants for solar photovoltaic panels |
-
1995
- 1995-03-23 CN CN 95110122 patent/CN1124754A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101981149B (en) * | 2008-03-21 | 2013-09-18 | 杰克瑞特公司 | Compositions for structural adhesives |
| CN102993991A (en) * | 2012-10-31 | 2013-03-27 | 安徽东方金河精密机械制造有限公司 | Acrylate-structured adhesive |
| CN102993991B (en) * | 2012-10-31 | 2014-02-05 | 安徽东方金河精密机械制造有限公司 | Acrylate-structured adhesive |
| CN104371573A (en) * | 2014-10-31 | 2015-02-25 | 青岛昌安达药业有限公司 | Durable wood adhesive |
| CN107735473A (en) * | 2017-06-01 | 2018-02-23 | 苏州佳亿达电器有限公司 | Encapsulants for solar photovoltaic panels |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| REG | Reference to a national code |
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