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CN1122444C - Natural fruit sugar enriching agent and preparing method thereof - Google Patents

Natural fruit sugar enriching agent and preparing method thereof Download PDF

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CN1122444C
CN1122444C CN 00104406 CN00104406A CN1122444C CN 1122444 C CN1122444 C CN 1122444C CN 00104406 CN00104406 CN 00104406 CN 00104406 A CN00104406 A CN 00104406A CN 1122444 C CN1122444 C CN 1122444C
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hydrolysate
fruit
sugar
enriching agent
protease
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CN1314085A (en
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韩尚吉
韩文勇
韩京姬
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Abstract

The present invention discloses a natural glycoside fruit sugar enriching agent and a preparing method thereof. The sugar enriching agent is prepared from raw materials, such as sweet chrysanthemum glycoside enzyme hydrolysis objects, liquorice glycoside enzyme hydrolysis objects, hesperidin enzyme hydrolysis objects, honey, pure boron, CaCl2, H2O, etc., by a certain weight proportion. The sugar enriching agent of the present invention mainly has obvious effects on enhancing fruit sugar degree, strengthening fruit appearance colors, coloring in advance, forming fruit waxiness in advance, ripening, increasing yield, etc. The sugar enriching agent does not have poison, residues or environmental pollution, and achieves a safe nuisanceless standard to people and livestock crops. The present invention has the advantages of simple and easy production technology, low price of the raw materials, local acquirement, and no treating problem of the three wastes in a production process.

Description

Natural fruit sugar enriching agent and preparation method thereof
Technical field
The present invention relates to a kind of plant hormone, specifically be meant a kind of natural fruit sugar enriching agent and preparation method.
Technical background
Along with improving constantly of living standards of the people, the people have higher requirement to the quality of consumer products, particularly capability and performances such as the taste of agricultural product, mouthfeel, color have been proposed higher requirement.Some can play agricultural product (as fruit) and promote the growing plants hormone constantly to be studied out, " farming one is clear " produced as the aloof from politics and material pursuits effect liquid fertilizer of Changchun farming one Co., Ltd, " sweetener " that the fresh-keeping factory in Jianyang, Sichuan produces, " ethrel " that Peng Pu chemical plant, Shanghai produces, " Sai Jilong " that the earlier real company in Germany produces etc. have facilitation to plant growing and fruit maturation.But comparatively speaking, " farming one is clear ", " sweetener " are poor slightly to the raising pol effect of fruit, and fruit color and wax are formed the phase a little later, and cost is higher." ethephon ", " Sai Jilong " toxicity grading standard belong to low toxicity.
" agriculture Digest " reported that Japan had developed fruit pol reinforcing agent in eighties invention in 1985 in the bound volume, its prescription is pure boron 200g, sucrose 2.4Kg, and calcium chloride 0.7g, hesperidinase 70g is dissolved in the 100Kg water, stir.This liquid is sprayed on the fruit tree blade face, not only can increase the sugariness (can make the pol of fruit increase by 22%) of fruit, and can also make fruit more tasty.This reinforcing agent is suitable for tangerine orange and watermelon, muskmelon etc., and its scope of application is narrow, is restricted.
Summary of the invention
The objective of the invention is provides the natural fruit sugar enriching agent that a kind of result of use is good, scope is wide, cost is low at above-mentioned deficiency.Another object of the present invention provides the preparation method of natural fruit sugar enriching agent.Technical scheme of the present invention is as follows:
A kind of natural fruit sugar enriching agent, make by weight by the following raw materials according component:
Stevioside protease hydrolysate 5～6 liquiritin protease hydrolysates 5～6
Hesperidinase hydrolysate 5～6 honey 2.4～3
Pure boron 0.15～0.16 CaCl 20.0001～0.001 H 2O 50
The material component of above-mentioned natural fruit sugar enriching agent preferred version by weight ratio is:
Stevioside protease hydrolysate 5 liquiritin protease hydrolysates 5
Hesperidinase hydrolysate 5 honey 2.4
Pure boron 0.15 CaCl 20.0005 H 2O 50
The physicochemical property of this product is: the opaque liquid aqua of crocus, the giving off a strong fragrance flavor is arranged, and proportion is 1.03, and pH value is 5-6, and effective ingredient is 35.1%, and adhesion strength and penetration are preferably arranged, and is nontoxic, noresidue, non-environmental-pollution.
Prepare the method for above-mentioned natural fruit sugar enriching agent, it is characterized in that:
A, at first extract stevioside protease hydrolysate, liquiritin protease hydrolysate, hesperidinase hydrolysate, to cut into slices the stevia rebaudianum, Radix Glycyrrhizae, orange peel of (or pure broken) respectively according to being soaked in water 6～12 hours with 1: 10 part by weight of water, soaking temperature is 40 ℃～50 ℃, then filter and extract three kinds of stevioside protease hydrolysates, liquiritin protease hydrolysate, hesperidinase hydrolysate respectively with silk
B, filter respectively respectively with honey, pure boron, calcium chloride and water mixed dissolution, and then with silk,
C, above-mentioned a, the described filtered fluid of b step added water mix, stir then, product.
Above-mentioned preparation method, the water in wherein said each step is cold water.
Sweet substance in raw material stevia rebaudianum, Radix Glycyrrhizae, the orange peel all belongs to glycoside, normal and the enzyme of above-mentioned three kinds of glycosides is present in the plant jointly, enzyme can promote the common glycoside hydrolysis that exists and generate sugar and aglycon, sugar moieties comprises the invert sugar 8 kinds of sugar such as (grape and fructose) in maltose, galactose, rutinose, rhamnose, arabinose, gentiobiose and the honey, mixes the influence that can strengthen sugariness mutually based on different types of eight kinds of sugar of high sugariness-stevioside.When extracting the glycosides enzyme from plant corpus, 40 ℃～50 ℃ cold water of biology enzyme optimum temperature are solvent, extract " enzymatic hydrolysis glycosides ".If the heating water temperature is more than 50 ℃ the time, enzyme will be damaged, the activity of inhibitory enzyme, and can not carry out enzymatic reaction.Natural invert sugar in the honey easily is dissolved in water, so directly can extract invert sugar after honey and water-soluble the separating (glucose of equivalent and the mixture of fructose) and its outer nutrient, plant hormone etc.Add micro-basic species-CaCl after the hydrolysis of carbohydrate thing 2Can promote the mutarotation balance of fructose and glucose.The effect that adds boron is a plant absorbing boron, and boron is in the formation of plant corpus inner cell wall composition and the Foliage Absorption of promotion sugar, and boron is to regulate material as the short control of glucose metabolism to work, to promote the synthetic of sucrose.
Sugar-increasing agent of the present invention mainly be to the pol that improves fruit (as sugar [yielding such as pears, apple, grape, peach, plum, apricot, cherry and muskmelon, watermelon, face melon, tomatoes) and strengthen the fruit appearance color, ahead of time painted, ahead of time form the fruit wax, accelerate the ripening, volume increase etc. all has significant effect.The present invention is sprayed on and not only can strengthens pol 2-3.5 degree on fruit tree leaf and the fruit, and make fruit more bright-coloured, good to eat, giving off a strong fragrance flavor arranged.Can satisfy the consumer to the taste of agricultural product, the requirement of mouthfeel with the fruit after the present invention's processing, for the fruit and the sugar [yielding producer, listing ahead of time, the producer's economic benefit be can improve, the production and the development of the food processing industrys such as storage, fruit wine, beverage, can of fruit simultaneously also can be promoted and promote.Sugar-increasing agent of the present invention is nontoxic, noresidue, non-environmental-pollution, reaches the non-harmful standard of people and animals' crop safety.Its production technology is simple, and the prices of raw and semifnished materials are cheap, can obtain on the spot, does not have disposal of three wastes problem in the production process.Sugar-increasing agent of the present invention notices that on using method three select: (one) sprayed 2-3 effect to fruits results in batches before one month better; (2) muskmelon, watermelon, tomato were sprayed 2 times before 3 weeks of results from beginning behind the fallen flowers in batches; (3) spray concentration is 400 times-500 times (valid density is 877.5ppm-702ppm).
The toxicity test of natural fruit sugar enriching agent of the present invention reaches and other plant hormone comparative trial, being described as follows different fruit impact effects tests:
One, natural glycosides (GIYcoside) sugar content increase of fruits agent acute toxicity testing (seeing Table)
The sample title: the agent of natural glycosides (GIYcoside) sugar content increase of fruits, crocus, pH value 4-6, proportion 1.03 (19 ℃), the animal of first experiment and repeated experiments is provided by laboratory animal section of Medical College.
The acute filling stomach contamination of table one record sheet
Poisonous substance title: GIYcoside sugar auxin proportion 1.03 poisonous substance compound method geometric ratios
Animal varieties and body weight Kunming kind 20-22g, body weight half and half, poisoning dosage 10300mg/Kg-643.75mg/Kg
Group Number of animals TD mg/Kg Administration capacity ml/10g The toxic action performance Death time
1 2 3 4 5 6 7
1 10 10300.00 0.1 2 burnouies are a little recovered normal behind the 4h - - - - - - -
2 10 5150.00 0.1 - - - - - - - -
3 10 2575.00 0.1 - - - - - - - -
4 10 1287.50 0.1 - - - - - - - -
5 10 643.75 0.1 - - - - - - - -
Repeated experiments result and maiden trial come to the same thing
The chemicals of the unknown toxicity of toxicological experiment method, trial test can be earlier is limit dosage (quiet notes can 2g/Kg be limit dosage) with 5g/Kg (per os contamination) dosage, whether this decision needs formally to ask chemical substance dosage that its LD50 tried greater than above-mentioned dosage, has shown that toxicity is little.
The acute toxicity classification of chemical substance, per os LD of rat 50(mg/Kg) be little poison greater than 5000, therefore think that the GIYcoxide sugar auxin belongs to little malicious chemicals.
Test unit: Medical College Hygiene Toxicology research department
Two, the agent of natural glycosides (GIYcoside) sugar content increase of fruits contrasts (seeing Table two) with different plant growth regulator toxicity
Table two
The plant growth regulator title Experimental animal Sex LD 50Cause amount (g/Kg body weight) per os in the row Connect China's pesticide toxicity grading criteria Producer
Match Keelung (disleave spirit) Rat Male female ＞4000 Low toxicity The Germany is real company (seherimg) earlier
Ethrel Rat Male female ＞4229 Low toxicity Peng Pu chemical plant, Shanghai
The natural fruits sugar-increasing agent Rat Male female ＞5000 Little poison Yanji agricultural [technology general headquarters
From table one and table two as can be known: natural fruit sugar enriching agent belongs to little poison than different plant growth regulator toxicity, noresidue again, non-environmental-pollution.
Three, spray different sugar-increasing agents the apple pear fruit quality influenced comparative trial (seeing Table three)
Table three (1996 to 1998 continuous 3 years comparative trials)
Different plant growth regulator spray multiple concentration (X) Sprinkling period and number of times (ten days/moon) The fruit color phase (ten days/moon) The fruit wax formation phase (ten days/moon) Soluble solid content (%) 3 annual means (X) Different growth regulator 500g unit prices (unit)
Natural GIYcoside sugar content increase of fruits agent 400X In/7 2 times in/8 In/8 In/9 13.8 10.00
Farming one clear 200X In/7 2 times in/8 Following/8 Following/9 12.8 8.00
Sweetener 400X In/7 2 times in/8 Following/8 Following/9 12.6 25.00
Contrast (CK) In/7 2 times in/8 Not/8 Following/9 12.3
Annotate: 1. test site: Yanji Xingan township Beijing University fruit tree farm
2.10 year green apple pear tree, seeding row spacing 3m * 6m, 1 hectare of area, several 555 strains of strain.
3. repeat for continuous 3 years 6 times, randomized arrangement is calculated 3 annual means (X)
4. carry out leaf surface spraying test under the same integrated management prerequisite such as clay fertilizer water, measure soluble solid content (%), 3 annual means (X) before and after National Day with saccarimeter
5. farming one clear (aqua) manufacturer: the aloof from politics and material pursuits effect liquid fertilizer in Changchun agricultural one Co., Ltd
Sweetener (pulvis) manufacturer: the fresh-keeping factory of Sichuan tube sun
Natural GLYcoside sugar content increase of fruits agent (aqua) manufacturer: Yanji agrotechnical station
Result of the test shows:
1. natural GLYcoside sugar content increase of fruits agent is more clear than farming one, sweetener, and comparison did sth. in advance for 1 week, significant difference according to fruit color and wax formation phase.
2. sugar-increasing agent improves pol 1.2 degree than farming one clear pol 1 degree that improves than sweetener, improves sugar 1.5 degree than CK, significant difference, and effect is obvious.
3. when sugar-increasing agent sprays with the same multiple concentration of different sugar-increasing agents, reduce cost 6.00 yuan clearly, reduce cost 1.5 yuan than sweetener, the pesticide cost significant difference than farming one.
Four, spray the impact effect test (see Table four) of natural fruit sugar enriching agent to the apple pear fruit quality
Table four (1994 to 1998 continuous 5 years test mean value X)
Annotate: apple pear life in 8 years, seeding row spacing 3m * 6m, 2 hectares of areas, 555 strains are under the integrated management measure prerequisite.Leaf surface spraying test repeats annual 2 times, sprays comprehensively, and random sampling front and back on National Day are measured with saccarimeter, individual soluble solid 5 annual means (X) of apple pear sample.Result of the test shows:
1. processing apple pear pol is compared according to (CK) raising pol 1.5～2.1 degree, and fruit color phase and fruit wax formation phase are compared to shine and carry the last week, significant difference, and effect is obvious.
2. handle sample apple pear soluble solid interindividual variation from the 12.0-16.0 degree.
Five, spray the impact effect test (see Table five) of natural fruit sugar enriching agent to different fruits (apple, grape, apricot, plum, muskmelon, watermelon, tomato) quality
Table five (1996 to 1998 continuous 3 years test mean value X)
Annotate: apple life in 5～7 years, seeding row spacing 3m * 6m, 0.5 hectare of area.Grape life in 8 years, seeding row spacing 1m * 1m, 0.3 hectare of pony set area.White apricot life in 7 years, seeding row spacing 6m * 6m, 0.5 hectare of area.The life in 6 years of No. 6 plums, seeding row spacing 4m * 6m, 0.2 hectare of area.Neat sweet No. 3 watermelons, Xi Hong city, each test site, 0.1 hectare of area.Under the same integrated management measure prerequisite, leaf surface spraying test, randomized arrangement, random sampling is measured with saccharometer, individual soluble solid content 3 annual means (X) of each kind sample.
The apple test site: diversified farming orchard, west city, Helong City town, testing crew senior agronomist gold Thailand all.Grape, white apricot, No. 6 plums, No. 3, Qi Tian, watermelon, test site, Xi Hong city: Yanji mayor Bai Xiang physics and chemistry village 2 teams and eastern rural area 4 teams, testing crew senior agronomist Tian Changfu and deep pool, agronomist Jinchang.
Result of the test shows
1. apple is handled comparison according to (CK) raising, and pol has 1.1～1.3 degree, grape 1.0～1.1 degree, and white apricot 2.4 degree, plum 2.0 is spent, muskmelon 3 degree, watermelon 3 degree, Xi Hong city 1.0 degree, significant difference, effect is obvious.
2. the comparison of the fruit color phase of processing such as apple, grape, apricot, plum and fruit wax formation phase is according to carrying the last week, and the significant difference effect is obvious.
Six, spray the impact effect test (see Table six) of natural fruit sugar enriching agent to apple pear and apple fruit quality
Table six (especially big dry year in 1999)
Figure C0010440600101
Annotate: the each point test area has 1 hectare, age of tree life in 15～50 years, 3m * 6m strain number has 555 strains, under the same integrated management prerequisite, leaf surface spraying test, repeat 2 times, random sampling is measured apple pear and apple individual sample soluble solid mean value (X) with saccarimeter before and after National Day.
Result of the test shows;
1. handling the apple pear pol has 3.1～3.5 degree than CK (contrast) raising pol, and fruit color phase and fruit wax formation phase are carried the last week than CK, significant difference, and effect is obvious.
2. the difference of handling between sample apple pear soluble solid individuality is spent from 12.9～18.0.
3. handling apple sugar content has 2.0～3.0 degree than CK raising pol, and fruit color phase and fruit wax formation phase are done sth. in advance a week than CK, significant difference, and effect is obvious.
Seven, spray natural fruit sugar enriching agent apple pear sample test report (seeing Table seven)
Table seven (measuring unit: fruit-bearing forest system of agricultural college of Yanbian University)
Content measurement Handle (spraying the agent of natural GIycoside sugar content increase of fruits) Contrast (ck)
Soluble solid content (%) 13.41 12.00
Fruit look (the blush redness accounts for more than 50%) 58.33 46.15
Local flavor (have or not fragrance deep or light) The giving off a strong fragrance flavor is arranged Light fragrance is arranged
Flesh firmness (Kg/cm43) 9.83 10.81
Total reducing sugar (%) 9.5000 8.5913
Total acid (%) 0.3010 0.2931
Sugar-acid ratio 31.56 29.31
Tannin (%) 0.0832 0.0832
Vitamin C (mg/100g) 4.928 4.576
The test report explanation
Two days 17--18 days of in October, 1998, the apple pear of spraying the agent of natural GIycoside sugar content increase of fruits was handled sample and control sample is tested.From test result mean value number, soluble solid, total reducing sugar, total acid, sugar-acid ratio, Vitamin C content is handled and all is higher than contrast, and flavor component is handled comparison according to dense, and fruit surface blush area is handled comparison according to big; Tannin content is handled and is contrasted together; Flesh firmness is handled and is lower than contrast.
Difference between processing sample apple pear soluble solid individuality is from 12.4---and 16.0.
Embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment
The material component proportioning of natural fruits sugar-increasing agent is:
Stevioside protease hydrolysate 5Kg liquiritin protease hydrolysate 5Kg
Hesperidinase hydrolysate 5Kg honey 2.4Kg
Pure boron 150g CaCl 20.5g
H 2O 50Kg
The preparation method:
A, at first extract stevioside protease hydrolysate, liquiritin protease hydrolysate, hesperidinase hydrolysate: the 0.5Kg stevia rebaudianum of section is added 5Kg, temperature soaks in 40 ℃～50 ℃ cold water after 12 hours with the Sang Shi filtration, filtered fluid is stand-by; Equally, the 0.5Kg Radix Glycyrrhizae of section is added 5Kg, temperature soaks in 40 ℃～50 ℃ cold water after 12 hours with the silk filtration, filtered fluid is stand-by; The 0.5Kg orange peel of section is added 5Kg, temperature soaks in 40 ℃～50 ℃ cold water after 12 hours with the filtration of mulberry cloth, filtered fluid is stand-by;
B, 2.4Kg honey add 10Kg cold water dissolving back and filter with silk, and filtered fluid is stand-by; The pure boron of 150g adds 1Kg cold water dissolving back and filters with mulberry cloth, and filtered fluid is stand-by; 0.5gCaCl 2Add 0.5Kg cold water dissolving back and filter with mulberry cloth, filtered fluid is stand-by;
C, the stevioside protease hydrolysate 5Kg with in the above-mentioned a step, liquiritin protease hydrolysate 5Kg, hesperidinase hydrolysate 5Kg and the described filtered fluid of b step mix with the cold water of the 23.5Kg after filtering, stir then, product.

Claims (4)

1, a kind of natural fruit sugar enriching agent, make by weight by the following raw materials according component:
Stevioside protease hydrolysate 5～6 liquiritin protease hydrolysates 5～6
Hesperidinase hydrolysate 5～6 honey 2.4～3
Pure boron 0.15～0.16 CaCl 20.0001～0.001
H 2O 50
2, natural fruit sugar enriching agent according to claim 1 is characterized in that the material component preferred version by weight ratio of described natural fruit sugar enriching agent is:
Stevioside protease hydrolysate 5 liquiritin protease hydrolysates 5
Hesperidinase hydrolysate 5 honey 2.4
Pure boron 0.15 CaCl 20.0005
H 2O 50
3, prepare the method for the described natural fruit sugar enriching agent of claim 1, it is characterized in that:
A, at first extract stevioside protease hydrolysate, liquiritin protease hydrolysate, hesperidinase hydrolysate, with the stevia rebaudianum, Radix Glycyrrhizae, orange peel of section respectively according to being soaked in water 6～12 hours with 1: 10 part by weight of water, soaking temperature is 40 ℃～50 ℃, then filter respectively and extract three kinds of stevioside protease hydrolysates, liquiritin protease hydrolysate, hesperidinase hydrolysate with silk
B, filter respectively respectively with honey, pure boron, calcium chloride and water mixed dissolution, and then with silk,
C, above-mentioned a, the described filtered fluid of b step added water mix, stir then, product.
4, method according to claim 3 is characterized in that the water in described each step is cold water.
CN 00104406 2000-03-17 2000-03-17 Natural fruit sugar enriching agent and preparing method thereof Expired - Fee Related CN1122444C (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8435588B2 (en) 2005-11-23 2013-05-07 The Coca-Cola Company High-potency sweetener composition with an anti-inflammatory agent and compositions sweetened therewith
CN101816304B (en) * 2010-04-15 2012-11-07 浙江大学 Quality modifier for improving watermelon sugar and using method thereof
CN103315118A (en) * 2013-06-01 2013-09-25 俞定元 Licorice skin plums
CN110870478B (en) * 2018-08-30 2021-09-14 沈阳中化农药化工研发有限公司 Solid preparation containing biphenyl compounds and application thereof

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