CN112029542B - Hydro-gasification system and method - Google Patents
Hydro-gasification system and method Download PDFInfo
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- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
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- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
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Abstract
Description
技术领域technical field
本公开涉及煤加氢气化技术领域,尤其涉及一种加氢气化系统及方法。The present disclosure relates to the technical field of coal hydrogenation and gasification, and in particular, to a hydrogenation and gasification system and method.
背景技术Background technique
加氢气化炉通过喷嘴分别向炉体内通入高温氢气、氧气和煤粉,氧气和氢气发生燃烧反应,燃烧产生的热量将高温氢气温度进一步提高。煤粉来自高压发料罐,高压发料罐与气化炉保持一定压差,将煤粉输送到气化炉内,然后与高温氢气发生加氢气化等放热反应。High-temperature hydrogen, oxygen and pulverized coal are respectively introduced into the furnace body through nozzles, and the oxygen and hydrogen undergo a combustion reaction, and the heat generated by the combustion further increases the temperature of the high-temperature hydrogen. The pulverized coal comes from the high-pressure feeding tank. The high-pressure feeding tank and the gasifier maintain a certain pressure difference, and the pulverized coal is transported into the gasifier, and then undergoes an exothermic reaction such as hydrogenation and gasification with high-temperature hydrogen.
由于煤粉通过喷嘴进入炉体时,在喷嘴出口氢气和煤粉对撞,发生第一次反应,生成煤焦油,然后随着煤粉和高温氢气充分混合,进一步反应放热,生成轻质煤焦油。反应区温度从上到下温度逐渐升高,但是对撞存在一定的返流,高温气体从反应区下段返流至反应区上段,提高了反应区上段的温度,导致反应区上段的温度监测设备反馈的温度较高,使系统减少氧气的通入量,导致与煤粉接触的氢气的温度较低,降低了煤粉在喷嘴口的升温速率,造成第一次反应时产生的煤焦油的量较少,从而导致整体的油收率较低。When the pulverized coal enters the furnace body through the nozzle, the hydrogen and the pulverized coal collide at the nozzle outlet, and the first reaction occurs to generate coal tar, and then the pulverized coal and the high-temperature hydrogen are fully mixed to further react and release heat to generate light coal. tar. The temperature of the reaction zone gradually increases from top to bottom, but there is a certain backflow in the collision, and the high-temperature gas flows back from the lower part of the reaction zone to the upper part of the reaction zone, which increases the temperature of the upper part of the reaction zone and causes the temperature monitoring equipment in the upper part of the reaction zone. The feedback temperature is higher, which reduces the amount of oxygen in the system, resulting in a lower temperature of the hydrogen in contact with the pulverized coal, which reduces the heating rate of the pulverized coal at the nozzle mouth, resulting in the amount of coal tar produced during the first reaction. less, resulting in a lower overall oil yield.
因此,现有技术中,通过对反应区上段的温度监测控制氧气的通入量,无法保证与煤粉接触的氢气的温度达到预设温度,导致气化系统整体的油收率较低。Therefore, in the prior art, by monitoring the temperature of the upper section of the reaction zone and controlling the amount of oxygen introduced, it is impossible to ensure that the temperature of the hydrogen in contact with the pulverized coal reaches the preset temperature, resulting in a low oil yield of the gasification system as a whole.
发明内容SUMMARY OF THE INVENTION
为了解决上述技术问题或者至少部分地解决上述技术问题,本公开提供了一种加氢气化系统及方法。In order to solve the above technical problems or at least partially solve the above technical problems, the present disclosure provides a hydrogasification system and method.
本公开提供了一种加氢气化系统,包括:气化炉、用于向所述气化炉内输送氢气的第一输送管道、用于向所述气化炉内输送氧气的第二输送管道和用于向所述气化炉内输送煤粉的第三输送管道;其中,The present disclosure provides a hydrogenation gasification system, comprising: a gasifier, a first delivery pipeline for delivering hydrogen into the gasifier, and a second delivery pipeline for delivering oxygen into the gasifier and a third conveying pipeline for conveying pulverized coal into the gasifier; wherein,
所述第一输送管道和所述第三输送管道之间设置有第一控制部件,用于控制输送至所述气化炉内的氢气和煤粉的质量比;A first control component is arranged between the first conveying pipeline and the third conveying pipeline, for controlling the mass ratio of hydrogen and coal powder conveyed into the gasifier;
所述第一输送管道和所述第二输送管道之间设置有第二控制部件,用于控制输送至所述气化炉内的氢气和氧气的质量比。A second control component is disposed between the first conveying pipe and the second conveying pipe, for controlling the mass ratio of hydrogen and oxygen conveyed into the gasifier.
本公开提供的加氢气化系统中,氢气通过第一输送管道输送至气化炉中,氧气通过第二输送管道输送至气化炉中,氧气和部分氢气在气化炉中发生燃烧反应,释放大量热量,对未发生燃烧反应的氢气进行加热,煤粉通过第三输送管道输送至气化炉内,与高温氢气发生反应,生成煤焦油。为了保证气化炉内有充足的氢气与煤粉反应,根据向气化炉内通入的煤粉的质量,通过调节第一控制部件,改变第一输送管道的通气量,从而调节气化炉内通入的氢气的质量;为了将气化炉中氢气的温度加热至预设温度,根据通入的氢气的质量,通过调节第二控制部件,改变第二输送管道的通气量,从而调节气化炉内通入的氧气的质量,即,气化炉内氧气的通入量由氢气的通入量决定,避免了气化炉内的温度变化对氧气通入量的影响,即避免了对撞产生的返流对氧气通入量的影响,从而实现了对气化炉内氢气温度的精确控制,保证了煤粉的升温速率,从而提高了氢气和煤粉反应时煤焦油的产量,提高了气化系统的油收率。In the hydrogenation gasification system provided by the present disclosure, the hydrogen is transported to the gasifier through the first transport pipeline, the oxygen is transported to the gasifier through the second transport pipeline, and the oxygen and part of the hydrogen undergo a combustion reaction in the gasifier to release A large amount of heat heats the hydrogen that has not undergone combustion reaction, and the pulverized coal is transported to the gasifier through the third transportation pipeline, and reacts with the high-temperature hydrogen to generate coal tar. In order to ensure that there is sufficient hydrogen in the gasifier to react with the pulverized coal, according to the quality of the pulverized coal introduced into the gasifier, the gasifier can be adjusted by adjusting the first control component to change the ventilation volume of the first conveying pipeline. The quality of hydrogen introduced into the gasifier; in order to heat the temperature of the hydrogen in the gasifier to the preset temperature, according to the quality of the hydrogen introduced, by adjusting the second control part, the ventilation volume of the second conveying pipeline is changed, so as to adjust the gas The quality of oxygen introduced into the gasifier, that is, the amount of oxygen introduced into the gasifier is determined by the amount of hydrogen introduced, which avoids the influence of temperature changes in the gasifier on the amount of oxygen introduced, that is, avoids The impact of the backflow generated by the collision on the amount of oxygen inflow, thus realizing the precise control of the hydrogen temperature in the gasifier, ensuring the heating rate of the pulverized coal, thereby increasing the production of coal tar when the hydrogen and the pulverized coal react, increasing the oil yield of the gasification system.
可选地,所述气化炉设置有多个喷嘴,每个所述喷嘴均包括第一进气通道、第二进气通道和进料通道,所述第一进气通道与所述第一输送管道连通,所述第二进气通道与所述第二输送管道连通,所述进料通道与所述第三输送管道连通。Optionally, the gasifier is provided with a plurality of nozzles, each of the nozzles includes a first intake channel, a second intake channel and a feed channel, the first intake channel and the first intake channel The conveying pipeline is in communication, the second air inlet channel is in communication with the second conveying pipeline, and the feeding channel is in communication with the third conveying pipeline.
可选地,所述第一进气通道、所述第二进气通道和所述进料通道互不连通。Optionally, the first intake channel, the second intake channel and the feed channel are not communicated with each other.
可选地,所述第一进气通道围设于所述第二进气通道外侧。Optionally, the first air intake passage is surrounded outside the second air intake passage.
可选地,每个所述喷嘴的轴线均指向所述气化炉的轴线设置,以在所述喷嘴的下方形成物料对撞区。Optionally, the axis of each of the nozzles is directed to the axis of the gasifier, so as to form a material collision zone below the nozzles.
可选地,所述气化炉的侧壁设置有进气口,所述进气口位于所述物料对撞区的下方。Optionally, a side wall of the gasifier is provided with an air inlet, and the air inlet is located below the material collision zone.
可选地,还包括加热装置,所述加热装置与所述第一输送管道连通。Optionally, a heating device is also included, and the heating device communicates with the first conveying pipeline.
本公开还提供了一种加氢气化方法,The present disclosure also provides a hydrogenation gasification method,
向气化炉内通入第一质量的氢气和第二质量的氧气;Passing a first mass of hydrogen and a second mass of oxygen into the gasifier;
向气化炉内通入煤粉;Passing pulverized coal into the gasifier;
向所述气化炉内通入第三质量的氢气,以使所述气化炉内的氢气的质量和煤粉的质量的比值在第一预设范围内,所述氢气的质量为所述第一质量和所述第三质量之和;Passing a third mass of hydrogen into the gasifier, so that the ratio of the mass of the hydrogen in the gasifier to the mass of the pulverized coal is within a first preset range, and the mass of the hydrogen is the the sum of the first mass and the third mass;
向所述气化炉内通入第四质量的氧气,以使所述气化炉内的氢气的质量和氧气的质量的比值在第二预设范围内,所述氧气的质量为所述第二质量和所述第四质量之和。The fourth mass of oxygen is introduced into the gasifier, so that the ratio of the mass of hydrogen and the mass of oxygen in the gasifier is within the second preset range, and the mass of the oxygen is the first The sum of the second mass and the fourth mass.
可选地,在所述向气化炉内通入第一质量的氢气和第二质量的氧气之前,还包括:Optionally, before the introduction of the first mass of hydrogen and the second mass of oxygen into the gasifier, it also includes:
对氢气进行加热。The hydrogen is heated.
可选地,在所述对氢气进行加热之前,还包括:Optionally, before the hydrogen is heated, it also includes:
确定向气化炉内通入第一质量的氢气和第二质量的氧气的质量比。Determine the mass ratio of the first mass of hydrogen and the second mass of oxygen fed into the gasifier.
可选地,在所述向气化炉内通入第四质量的氧气之后,还包括:Optionally, after the oxygen of the fourth mass is introduced into the gasifier, it also includes:
对物料对撞区的下方进行温度采集,且在温度高于设定温度时,通入氢气。The temperature is collected below the material collision zone, and when the temperature is higher than the set temperature, hydrogen is introduced.
附图说明Description of drawings
此处的附图被并入说明书中并构成本说明书的一部分,示出了符合本公开的实施例,并与说明书一起用于解释本公开的原理。The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments consistent with the disclosure and together with the description serve to explain the principles of the disclosure.
为了更清楚地说明本公开实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,对于本领域普通技术人员而言,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the embodiments of the present disclosure or the technical solutions in the prior art, the accompanying drawings that are required to be used in the description of the embodiments or the prior art will be briefly introduced below. In other words, on the premise of no creative labor, other drawings can also be obtained from these drawings.
图1为本公开实施例所述加氢气化系统的结构示意图;FIG. 1 is a schematic structural diagram of a hydrogenation gasification system according to an embodiment of the disclosure;
图2为本公开实施例所述加氢气化系统中喷嘴处的结构示意图;FIG. 2 is a schematic structural diagram of a nozzle in a hydrogenation gasification system according to an embodiment of the present disclosure;
图3为本公开实施例所述喷嘴的结构示意图;3 is a schematic structural diagram of a nozzle according to an embodiment of the disclosure;
图4为本公开实施例所述加氢气化方法的流程示意图。FIG. 4 is a schematic flow chart of the hydrogasification method according to the embodiment of the disclosure.
其中,1-气化炉;2-第一输送管道;3-第二输送管道;4-第三输送管道;5-第一控制部件;6-第二控制部件;7-喷嘴;71-第一进气通道;72-第二进气通道;73-进料通道;8-进气口;9-加热装置;10-进水口;11-粗煤气出口。Among them, 1-gasifier; 2-first conveying pipeline; 3-second conveying pipeline; 4-third conveying pipeline; 5-first control part; 6-second control part; 7-nozzle; 71-th An air inlet channel; 72 - the second air inlet channel; 73 - the feed channel; 8 - the air inlet; 9 - the heating device; 10 - the water inlet; 11 - the crude gas outlet.
具体实施方式Detailed ways
为了能够更清楚地理解本公开的上述目的、特征和优点,下面将对本公开的方案进行进一步描述。需要说明的是,在不冲突的情况下,本公开的实施例及实施例中的特征可以相互组合。In order to more clearly understand the above objects, features and advantages of the present disclosure, the solutions of the present disclosure will be further described below. It should be noted that the embodiments of the present disclosure and the features in the embodiments may be combined with each other under the condition of no conflict.
在下面的描述中阐述了很多具体细节以便于充分理解本公开,但本公开还可以采用其他不同于在此描述的方式来实施;显然,说明书中的实施例只是本公开的一部分实施例,而不是全部的实施例。Many specific details are set forth in the following description to facilitate a full understanding of the present disclosure, but the present disclosure can also be implemented in other ways different from those described herein; obviously, the embodiments in the specification are only a part of the embodiments of the present disclosure, and Not all examples.
现有技术中,通过对气化炉内反应区上段进行温度监测控制氧气通入气化炉中的质量,由于氢气和煤粉对撞存在一定的返流,高温气体从反应区下段返流至反应区上段,提高了反应区上段的温度,导致反应区上段的温度监测设备反馈的温度较高,使系统减少氧气的通入量,无法保证与煤粉接触的氢气的温度达到预设温度,导致气化系统整体的油收率较低。In the prior art, the quality of oxygen introduced into the gasifier is controlled by monitoring the temperature of the upper section of the reaction zone in the gasifier. Due to the collision of hydrogen and pulverized coal, there is a certain backflow, and the high-temperature gas flows back from the lower section of the reaction zone to the gasifier. The upper section of the reaction zone increases the temperature of the upper section of the reaction zone, resulting in a higher temperature feedback from the temperature monitoring equipment in the upper section of the reaction zone, which reduces the amount of oxygen introduced into the system and cannot guarantee that the temperature of the hydrogen contacting the pulverized coal reaches the preset temperature. As a result, the overall oil yield of the gasification system is low.
图1为本公开实施例所述加氢气化系统的结构示意图;图2为本公开实施例所述加氢气化系统中喷嘴处的结构示意图。如图1至图2所示,本公开实施例提供了一种加氢气化系统,包括:气化炉1、用于向气化炉1内输送氢气的第一输送管道2、用于向气化炉1内输送氧气的第二输送管道3和用于向气化炉1内输送煤粉的第三输送管道4;其中,第一输送管道2和第三输送管道4之间设置有第一控制部件5,用于控制输送至气化炉1内的氢气和煤粉的质量比;第一输送管道2和第二输送管道3之间设置有第二控制部件6,用于控制输送至气化炉1内的氢气和氧气的质量比。FIG. 1 is a schematic structural diagram of a hydrogenation gasification system according to an embodiment of the disclosure; FIG. 2 is a schematic structural diagram of a nozzle in the hydrogenation gasification system according to an embodiment of the disclosure. As shown in FIG. 1 to FIG. 2 , an embodiment of the present disclosure provides a hydrogenation gasification system, including: a
本公开提供的加氢气化系统中,氢气通过第一输送管道2输送至气化炉1中,氧气通过第二输送管道3输送至气化炉1中,氧气和部分氢气在气化炉1中发生燃烧反应,释放大量热量,对未发生燃烧反应的氢气进行加热,煤粉通过第三输送管道4输送至气化炉1内,与高温氢气发生反应,生成煤焦油。为了保证气化炉1内有充足的氢气与煤粉反应,根据向气化炉1内通入的煤粉的质量,通过调节第一控制部件5,改变第一输送管道2的通气量,从而调节气化炉1内通入的氢气的质量;为了将气化炉1中氢气的温度加热至预设温度,根据通入的氢气的质量,通过调节第二控制部件6,改变第二输送管道3的通气量,从而调节气化炉1内通入的氧气的质量,即,气化炉1内氧气的通入量由氢气的通入量决定,避免了气化炉1内的温度变化对氧气通入量的影响,即避免了对撞产生的返流对氧气通入量的影响,从而实现了对气化炉1内氢气温度的精确控制,保证了煤粉的升温速率,从而提高了氢气和煤粉反应时煤焦油的产量,提高了气化系统的油收率。In the hydrogenation gasification system provided by the present disclosure, hydrogen is transported to the
上述通过第一输送管道2通入至气化炉1中的氢气的温度不低于氢气的着火点,使氢气通入至气化炉1中与氧气相遇时发生燃烧反应,释放热量,对未发生燃烧反应的氢气起到加热的作用,从而提高煤粉和氢气反应的环境温度,提高煤粉和氢气反应的效率。The above-mentioned temperature of the hydrogen passed into the
为了避免煤粉的浪费,首先将氢气和氧气通入至气化炉1中,通过氢气和氧气发生燃烧反应,提高气化炉1内的温度,在气化炉1内的温度达到预设温度时,通入煤粉,使煤粉与高温氢气接触反应。In order to avoid waste of pulverized coal, hydrogen and oxygen are first introduced into the
在一些实施例中,气化炉1设置有多个喷嘴7,每个喷嘴7均包括第一进气通道71、第二进气通道72和进料通道73,第一进气通道71与第一输送管道2连通,第二进气通道72与第二输送管道3连通,进料通道73与第三输送管道4连通。In some embodiments, the
上述气化炉1的喷嘴7内设置有第一进气通道71、第二进气通道72和进料通道73,氢气经第一进气通道71输入,氧气经第二进气通道72输入,在第一进气通道71和第二进气通道72的出气口处,氢气与氧气相遇,氢气燃烧释放热量,对未燃烧的氢气以及经进料通道73进入的煤粉进行加热升温,使煤粉与氢气发生反应,生成煤焦油。The
通过设置多个上述喷嘴7,将氢气和煤粉在气化炉1内分散输入,增加了氢气和煤粉的接触面积,提高了煤粉的反应速率,并且,有效避免了煤粉集中输入造成部分煤粉无法与氢气接触,导致的煤粉的浪费,从而提高了煤粉的气化效率,并减少了形成的煤渣中的含碳量。By arranging a plurality of the above-mentioned
在一些实施例中,加氢气化系统还包括用于输送氢气的输送主路,输送主路设置有主路调节阀,主路调节阀控制输送主路流量,然后平均分配至各第一输送管道2。每个第二输送管道3均由单独的氧气调节阀控制,第三输送管道4中输送煤粉的质量通过控制发料罐与气化炉1的压差来调节。In some embodiments, the hydrogenation gasification system further includes a main conveying route for conveying hydrogen, the main conveying route is provided with a main route regulating valve, and the main route regulating valve controls the flow rate of the main transportation route, and then evenly distributes it to each
每个喷嘴7出口温度首先根据煤粉输送量的变化,通过第一控制部件5设定的比例计算得到氢气流量,该氢气流量通过主路调节阀来调节,以保持氢煤比不变;然后根据氢气的流量,通过第二控制部件6,计算得到氧气流量,该氧气流量通过各喷嘴7的氧气调节阀来调节,控制每个喷嘴7出口的反应温度,从而实现了每个喷嘴7位置处氧气输入量的单独调节,在氢气的输入量发生改变时,可及时根据氢气的输入量调整氧气的输入量,从而保证气化炉1内氢气的温度保持稳定。The outlet temperature of each
图3为本公开实施例所述喷嘴的结构示意图。如图3所示,具体地,每个喷嘴7设置一个进料通道73、多个第一进气通道71和多个第二进气通道72,第一进气通道71、第二进气通道72和进料通道73之间互不连通,且第一进气通道71围设于第二进气通道72外侧。FIG. 3 is a schematic structural diagram of a nozzle according to an embodiment of the disclosure. As shown in FIG. 3 , specifically, each
本实施例中,进料通道73设置在喷嘴7的中心位置处,第一进气通道71以进料通道73的中心为圆心均匀设置在进料通道73的外周侧,第二进气通道72设置在第一进气通道71内部,且第一进气通道71和第二进气通道72的轴线重合,使得氢气和氧气在第一进气通道71和第二进气通道72的出气口处即可相遇并发生燃烧反应,以节省氢氧相遇所需空间,并及时对煤粉进行加热升温,提高煤粉的升温效率;并且,绕中心位置处的进料通道73的周向方向排布多个第一进气通道71和第二进气通道72,通过每个第一进气通道71的出气口处均发生燃烧反应,以提高煤粉的升温效率。In this embodiment, the feeding
在一些实施例中,每个喷嘴7的轴线均指向气化炉1的轴线设置,喷嘴7的下方形成物料对撞区,从而使得氢气和煤粉在气化炉1内对撞,使氢气和煤粉充分混合,以便于进行进一步反应,生成轻质煤焦油。其中,所有喷嘴7的轴线可以相交于同一位置处。In some embodiments, the axis of each
在煤粉和氢气对撞之前煤粉与氢气反应生成的物料中包括煤焦油,物料对撞后,物料与氢气继续反应放热,使得对撞点远离喷嘴7的区域的温度随着反应的进行而升高,为了避免物料与氢气反应造成的反应区域升温速率过高,导致大量煤焦油被裂解为甲烷,气化炉1的侧壁设置有进气口8,且进气口8位于氢气和煤粉的对撞区远离喷嘴7的一侧,即,进气口8位于物料对撞区的下方。Before the coal powder and the hydrogen collide, the material generated by the reaction between the coal powder and the hydrogen includes coal tar. After the material collides, the material and the hydrogen continue to react to exothermic heat, so that the temperature of the area where the collision point is far away from the
上述进气口8与输送主路连通,输送主路的氢气为加热后的高温氢气,即进气口8输入的氢气的温度不低于氢气的着火点,由于对撞区远离喷嘴7的区域的环境温度大于氢气的着火点,通过通入上述高温氢气,可对进气口8对应的区域进行降温,防止该区域温度过高,以提高轻质煤焦油的产量;并且,通过通入高温氢气,提高了对撞区以及对靠近喷嘴7的区域的氢气的含量,进一步增加了煤粉与氢气的接触面积,提高了煤粉的反应速率。The above-mentioned
在一些实施例中,还包括加热装置9,加热装置9与第一输送管道2连通。In some embodiments, a heating device 9 is also included, and the heating device 9 communicates with the first conveying
上述加热装置9用于对氢气进行加热,使氢气通入至气化炉1中时温度不低于其自身着火点,以保证氢气在气化炉1内与氧气发生燃烧反应。The above-mentioned heating device 9 is used to heat the hydrogen gas so that the temperature of the hydrogen gas is not lower than its own ignition point when the hydrogen gas is passed into the
具体地,加热装置9与输送主路连通,以保证每个第一输送管道2内的氢气温度均不低于其自身着火点。Specifically, the heating device 9 is communicated with the main conveying path to ensure that the temperature of the hydrogen gas in each first conveying
具体地,气化炉1还设置有粗煤气出口11和进水口10,在煤粉与氢气反应一段时间后,通过进水口10向气化炉1内通入冷水,调节粗煤气出口11处的温度,以终止加氢反应,控制反应时间,避免气化炉1内生成的煤焦油裂解为甲烷,从而提高系统的油收率。Specifically, the
图4为本公开实施例所述加氢气化方法的流程示意图。如图4所示,本公开还提供了一种加氢气化方法,该方法可以由上述实施例提供的加氢气化系统的全部或者部分执行,该方法具体包括:FIG. 4 is a schematic flow chart of the hydrogasification method according to the embodiment of the disclosure. As shown in FIG. 4 , the present disclosure also provides a method for hydrogenation and gasification, which can be performed by all or part of the hydrogenation and gasification system provided in the above embodiments, and the method specifically includes:
步骤S101:向气化炉1内通入第一质量的氢气和第二质量的氧气。Step S101 : introducing a first mass of hydrogen and a second mass of oxygen into the
具体地,第一质量的氢气通过第一输送管道2以及喷嘴7的第一进气通道71输送至气化炉1中,第二质量的氧气经第二输送管道3以及喷嘴7的第二进气通道72输送至气化炉1中,使部分氢气和氧气在气化炉1内燃烧放热,以提高气化炉1内的温度,对气化炉1进行预热,保证煤粉输送至气化炉1内即可与氢气反应,避免煤粉浪费。Specifically, the first mass of hydrogen is transported to the
步骤S102:向气化炉1内通入煤粉。Step S102 : feeding pulverized coal into the
具体地,煤粉依次经第三输送管道4和喷嘴的进料通道73输送至气化炉1中。在上述步骤S102中,保持氢气和氧气的通入,并向气化炉1内通入煤粉,煤粉与高温氢气发生反应,生成煤焦油。Specifically, the pulverized coal is sequentially transported into the
步骤S103:向气化炉1内通入第三质量的氢气,以使气化炉1内的氢气的质量和煤粉的质量的比值在第一预设范围内,氢气的质量为第一质量和第三质量之和。Step S103: Passing a third mass of hydrogen into the
上述步骤S103中,根据向气化炉1内通入的煤粉的质量,通过调节第一控制部件5,调节第一输送管道2的通气量,通入第三质量的氢气,从而调节气化炉1内通入的氢气的质量,即,气化炉1内通入氢气的质量为第一质量的氢气与第三质量的氢气之和,保证了气化炉1内有充足的氢气与煤粉反应。In the above step S103, according to the quality of the pulverized coal introduced into the
步骤S104:向气化炉1内通入第四质量的氧气,以使气化炉1内的氢气的质量和氧气的质量的比值在第二预设范围内,氧气的质量为第二质量和第四质量之和。Step S104: Introduce a fourth mass of oxygen into the
上述步骤S104中,根据通入的氢气的质量,通过调节第二控制部件6,改变第二输送管道3的通气量,通入第四质量的氧气,从而调节气化炉1内通入的氧气的质量,即,气化炉1内通入氧气的质量为第二质量的氢气与第四质量的氧气之和,从而将气化炉1中氢气的温度加热至预设温度范围,并保持在预设温度范围内。In the above-mentioned step S104, according to the quality of the hydrogen introduced, by adjusting the
通过根据煤粉的输入量调节氢气的通入量,保证了气化炉1内具有充足的氢气与煤粉接触反应,且通过根据氢气的质量调节氧气的通入量,保证了氢气的温度稳定保持在预设温度范围内,避免了对撞产生的返流对氧气通入量的影响,从而实现了对气化炉1内氢气温度的精确控制,保证了煤粉的升温速率,从而提高了氢气和煤粉反应时煤焦油的产量,提高了气化系统的油收率。By adjusting the introduction amount of hydrogen according to the input amount of pulverized coal, it is ensured that there is sufficient hydrogen and pulverized coal contact reaction in the
具体地,在向气化炉1内通入第一质量的氢气和第二质量的氧气之前,还包括:对氢气进行加热。并且,氢气加热后的温度不低于氢气温度的预设值,其中,预设值可以为氢气的着火点。Specifically, before passing the first mass of hydrogen and the second mass of oxygen into the
上述步骤中,通过将氢气温度提高至不低于预设值,且氢气温度的预设值可以为不低于氢气的着火点,使氢气通入至气化炉1中与氧气相遇时即可发生燃烧反应,释放热量,对未发生燃烧反应的氢气起到加热的作用,从而提高煤粉和氢气反应的环境温度,提高煤粉和氢气反应的效率。In the above steps, by raising the hydrogen temperature to not lower than the preset value, and the preset value of the hydrogen temperature can be not lower than the ignition point of hydrogen, the hydrogen gas can be passed into the
具体地,在对氢气进行加热之前,还包括:确定向气化炉内通入第一质量的氢气和第二质量的氧气的质量比。Specifically, before the hydrogen is heated, the method further includes: determining the mass ratio of the hydrogen of the first mass and the oxygen of the second mass into the gasifier.
在反应开始前,设定第一质量的氢气和第二质量的氧气的质量比,然后将第一质量的氢气加热并输送至气化炉1中,使氢气与氧气反应提高气化炉1内的温度,同时,使高温氢气充满气化炉1,以保证煤粉加入至气化炉1后的升温速率,保证煤粉与氢气充分反应,避免煤粉的浪费。Before the reaction starts, the mass ratio of the first mass of hydrogen and the second mass of oxygen is set, and then the first mass of hydrogen is heated and transported to the
具体地,在向气化炉1内通入第四质量的氧气之后,还包括:对物料对撞区的下方进行温度采集,且在温度高于设定温度时,通入氢气。Specifically, after feeding the fourth mass of oxygen into the
为了防止对撞区下方区域温度过高,导致轻质煤焦油的产量下降,在该区域中设置温度监测部件,监测该区域的实时温度,在实时温度高于预设的最高温度时,通入氢气,以对该区域实现降温的效果,提高轻质煤焦油的产量。In order to prevent the temperature of the area below the collision zone from being too high, resulting in a decrease in the production of light coal tar, a temperature monitoring component is set in this area to monitor the real-time temperature of the area. When the real-time temperature is higher than the preset maximum temperature, the Hydrogen, in order to achieve the effect of cooling the area and increase the production of light coal tar.
上述步骤中,通过上述进气口8将氢气通入至对撞区下方区域中,进气口8与输送主路连通,输送主路的氢气为加热后的高温氢气,即进气口8输入的氢气的温度不低于氢气温度的预设值,由于对撞区下方的温度大于氢气温度的预设值,通过通入上述高温氢气,可对进气口8对应的区域进行降温,防止该区域温度过高,以提高轻质煤焦油的产量;并且,通过通入高温氢气,提高了对撞区以及对靠近喷嘴7的区域的氢气的含量,进一步增加了煤粉与氢气的接触面积,提高了煤粉的反应速率。In the above-mentioned steps, the hydrogen gas is introduced into the area below the collision zone through the above-mentioned
最后,在煤粉反应一端时间后,向气化炉1内通入冷水,调节气化炉1出口温度,以终止加氢反应,控制反应的时间,避免煤焦油裂解生成甲烷,从而提高系统的油收率。Finally, after the pulverized coal has reacted for one end of time, cold water is introduced into the
其他技术特征与上述系统的实施例相同,并能带来相同或者类似的技术效果,在此不再一一赘述,具体可参照上述实施例的描述。Other technical features are the same as the embodiments of the above system, and can bring about the same or similar technical effects, which will not be repeated here. For details, please refer to the description of the above embodiments.
需要说明的是,在本文中,诸如“第一”和“第二”等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来,而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。而且,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。在没有更多限制的情况下,由语句“包括一个……”限定的要素,并不排除在包括所述要素的过程、方法、物品或者设备中还存在另外的相同要素。It should be noted that, in this document, relational terms such as "first" and "second" etc. are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply these There is no such actual relationship or sequence between entities or operations. Moreover, the terms "comprising", "comprising" or any other variation thereof are intended to encompass a non-exclusive inclusion such that a process, method, article or device that includes a list of elements includes not only those elements, but also includes not explicitly listed or other elements inherent to such a process, method, article or apparatus. Without further limitation, an element qualified by the phrase "comprising a..." does not preclude the presence of additional identical elements in a process, method, article or apparatus that includes the element.
以上所述仅是本公开的具体实施方式,使本领域技术人员能够理解或实现本公开。对这些实施例的多种修改对本领域的技术人员来说将是显而易见的,本文中所定义的一般原理可以在不脱离本公开的精神或范围的情况下,在其它实施例中实现。因此,本公开将不会被限制于本文所述的这些实施例,而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。The above descriptions are only specific embodiments of the present disclosure, so that those skilled in the art can understand or implement the present disclosure. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the present disclosure. Therefore, the present disclosure is not intended to be limited to the embodiments described herein, but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
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