CN1116982C - Multi-purpose absorbent and protective sheet materials - Google Patents
Multi-purpose absorbent and protective sheet materials Download PDFInfo
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- CN1116982C CN1116982C CN98808513A CN98808513A CN1116982C CN 1116982 C CN1116982 C CN 1116982C CN 98808513 A CN98808513 A CN 98808513A CN 98808513 A CN98808513 A CN 98808513A CN 1116982 C CN1116982 C CN 1116982C
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/14—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a face layer formed of separate pieces of material which are juxtaposed side-by-side
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
- B65D81/26—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
- B65D81/264—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing liquids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
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- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Wrappers (AREA)
Abstract
Description
有关申请的相互参照Cross-references to relevant applications
本申请是我们在1997年8月26提出的较早申请,美国系列号08/918,486的部分继续申请。This application is a continuation-in-part of our earlier application, US Serial No. 08/918,486, filed August 26, 1997.
发明领域Field of Invention
本发明涉及了一种薄片材料,适于保护支承面免受放在其上面的各种物品或物质的影响,反之亦然。本发明还涉及了这样的薄片材料,它还能吸收各种物品和/或物质带着或渗出的各种液体,或者作为供选用的方式,能中和这种液体的有害的或不希望的性质。The present invention relates to a sheet of material suitable for protecting a support surface from various objects or substances placed thereon and vice versa. The present invention also relates to sheet materials which are also capable of absorbing various liquids entrained or exuded by various articles and/or substances, or alternatively neutralizing the harmful or undesirable effects of such liquids. nature.
发明背景Background of the Invention
在目前技术中已经熟知了用于保护物体或物质免受支承面影响和/或保护支承面免受物体或物质影响的薄片状材料。这种材料可用于提供永久形式的保护,但最通常的是与情况或用途有关的保护,仅需要或利用一段有限的时间,然后就丢弃。Sheet-shaped materials for protecting objects or substances from support surfaces and/or protecting support surfaces from objects or substances are already known in the state of the art. This material can be used to provide a permanent form of protection, but most commonly it is situation or use related protection that is only needed or utilized for a limited period of time and then discarded.
使用这种薄片材料的一种普通情形是待消费的食品的准备,如准备供烧煮的几片肉。此时保护性薄片材料可提供双重保护作用:保护食物不被柜台面之类支承面弄脏或其它污染,以及保护柜台面不被食物表面上血水及其它液体或物质弄脏。保护性薄片材料还可保护支承面不受到如尖锐物体或切割工具(如用于准备食物的小刀或劈刀)撞击的实际损坏。A common situation in which such sheet materials are used is the preparation of food products to be consumed, such as slices of meat for cooking. In this case the protective sheet material provides dual protection: protection of the food from soiling or other contamination of the support surface such as the counter top and protection of the counter top from blood and other liquids or substances on the surface of the food. The protective sheet material also protects the support surface from physical damage such as impact from sharp objects or cutting implements such as a knife or cleaver used for food preparation.
这种情形下要采用的保护性薄片材料通常包括吸收性的纸类制品薄材,它们可包括不渗透的底层或涂层。这种材料相当便宜和用于相当短的时间,然后就丢弃。尽管这种材料的确在物质或物体与支承面之间形成一个中间隔离层,但它们的性能并未达到希望,因为物质或物体仍继续与吸收性材料接触,而吸收材料已吸收了放在它们上面的物体或物质所带着或渗出的液体。另外,这种材料对尖锐物体或切割工具的损坏也比较敏感,从而通常不能对这类可能的损坏为支承面提供适当保护。Protective sheet materials to be employed in such cases typically include absorbent paper product sheets which may include an impervious backing or coating. This material is relatively cheap and used for a relatively short time before it is discarded. Although such materials do form an intermediate barrier between the substance or object and the support surface, they do not perform as expected because the substance or object continues to be in contact with the absorbent material which has absorbed the material placed on them. A fluid carried by or exuded by an object or substance above. In addition, this material is also relatively sensitive to damage from sharp objects or cutting tools, so that it usually does not provide adequate protection of the bearing surface against such possible damage.
因此,希望提供一种薄片材料,它可用于具有多种多样的用途,来保护物体和物质免受支承面的影响,反之亦然。Accordingly, it would be desirable to provide a sheet material which can be used in a variety of applications for protecting objects and substances from support surfaces and vice versa.
也希望提供这样的薄片材料,它能够吸收由物体和物质带着或渗出的液体,以及把这种液体与物体和物质隔离。It would also be desirable to provide sheet materials that are capable of absorbing liquids entrained or exuded by objects and substances, and isolating such liquids from the objects and substances.
还希望提供这样的薄片材料,它在经久耐用的同时,还可容易和便宜地制造,因而在使用后可以丢弃。It would also be desirable to provide a sheet of material which, while being durable, is also easy and inexpensive to manufacture so that it can be discarded after use.
发明概述Invention overview
本发明提供了一种多用途的薄片材料,它包括具有对着的第一和第二表面的吸收层,与第一表面连接并在第一表面上横向延伸的基本上不吸收、基本上不渗液的阻挡系统,上述阻挡系统包括连续的阻挡网格;以及基本上连续覆盖第二表面的基本上不渗液的隔离层,其中上述连续的阻挡网格是抗切割的。The present invention provides a multipurpose sheet material comprising an absorbent layer having opposing first and second surfaces, a substantially nonabsorbent, substantially nonabsorbent layer attached to and extending laterally across the first surface. A liquid permeable barrier system, said barrier system comprising a continuous barrier mesh; and a substantially liquid impermeable barrier layer substantially continuously covering the second surface, wherein said continuous barrier mesh is cut resistant.
阻挡系统可包括许多离散的阻挡元件,或者可包括连续的阻挡网格,并且可以作成任何希望的构形。在面对支承面的隔离层表面上,供选用的胶粘剂层或元件可用于提高使用时的稳定性。阻挡系统可以与隔离层作成一体或与隔离层直接接触,使得作用在阻挡系统上的力绕过吸收层传到隔离层上。The barrier system may comprise a plurality of discrete barrier elements, or may comprise a continuous grid of barriers, and may be of any desired configuration. On the surface of the release layer facing the support surface, an optional adhesive layer or element may be used to increase stability in use. The barrier system may be integral with the release layer or in direct contact with the release layer such that forces acting on the barrier system are transferred to the release layer bypassing the absorbent layer.
附图简述Brief description of attached drawings
尽管本技术说明包括了特别指出和明确申请本发明专利范围的权利要求,但可以相信,根据结合附图的以下描述,将会更好地理解本发明,在附图中同一编号表示同一部分,其中:Although the technical description includes the claims that specifically point out and clearly apply for the patent scope of the present invention, it is believed that the present invention will be better understood according to the following description in conjunction with the accompanying drawings. In the accompanying drawings, the same number represents the same part, in:
图1是一个部分切割的透视图,表示了本发明多用途吸收和保护性薄片材料的一个实施例;Figure 1 is a partially cut perspective view showing an embodiment of the multipurpose absorbent and protective sheet material of the present invention;
图2是一个部分切割的透视图,表示了本发明多用途吸收和保护性薄片材料的另一个实施例;Figure 2 is a partially cut perspective view showing another embodiment of the multipurpose absorbent and protective sheet material of the present invention;
图3是一个部分切割的透视图,表示了本发明多用途吸收和保护性薄片材料的另一个实施例;Figure 3 is a partially cut perspective view showing another embodiment of the multipurpose absorbent and protective sheet material of the present invention;
图4是一个部分切割的透视图,表示了本发明多用途吸收和保护性薄片材料的另一个实施例;Figure 4 is a partially cut perspective view showing another embodiment of the multipurpose absorbent and protective sheet material of the present invention;
图5是一个部分切割的透视图,表示了本发明多用途吸收和保护性薄片材料的另一个实施例;Figure 5 is a partially cut perspective view showing another embodiment of the multipurpose absorbent and protective sheet material of the present invention;
图6是一个部分切割的透视图,表示了本发明多用途吸收和保护性薄片材料的另一个实施例;Figure 6 is a partially cut perspective view showing another embodiment of the multipurpose absorbent and protective sheet material of the present invention;
图7是一个部分切割的透视图,表示了本发明多用途吸收和保护性薄片材料的另一个实施例;Figure 7 is a partially cut perspective view showing another embodiment of the multipurpose absorbent and protective sheet material of the present invention;
图8是一个部分切割的透视图,表示了本发明多用途吸收和保护性薄片材料的另一个实施例;Figure 8 is a partially cut perspective view showing another embodiment of the multipurpose absorbent and protective sheet material of the present invention;
图9是一个部分切割的透视图,表示了本发明多用途吸收和保护性薄片材料的另一个实施例;以及Figure 9 is a partially cut perspective view showing another embodiment of the multipurpose absorbent and protective sheet material of the present invention; and
图10是一个部分切割的透视图,表示了本发明多用途吸收和保护性薄片材料的另一个实施例。Figure 10 is a perspective view, partially cut away, showing another embodiment of the multipurpose absorbent and protective sheet material of the present invention.
发明详述 Invention Details
图1描绘了本发明多用途薄片材料10的一个实施例。薄片材料10包括一个液体吸收层20、一个不渗液的底层30、以及一个包括许多单独阻挡条40的阻挡系统。所示薄片材料10的方位适于放置在支承面(图中未示)上,如柜台面或桌子上,其底层30与支承面接触,而阻挡条从支承面朝外。在所示实施例中,薄片材料10还包括一个供选用的胶粘剂系统35,它位于本来要与支承面接触的隔离层或底层30的面朝外的表面上。Figure 1 depicts one embodiment of a
薄片材料10一般包括为所希平面尺寸的平面片状结构,并具有同样基本上为平面的两个对着的主面。这种薄片材料的“层”通常也基本上是平面和/或确定了接触面的平面。底层30完全覆盖了吸收层的一个表面,使得包含在其中的液体不能通过底层30和进入放置薄片材料10的任何支承面上。阻挡条40沿着与底层30对着的吸收层表面延伸,在所示实施例中一般形成了平行的线条。
吸收层可由任何适于吸收和/或包含任何相关液体的材料制成。合适的材料包括由天然(纤维素等)和/或合成纤维制成的纤维薄条或薄片材料,包括空心纤维和毛细管纤维、吸收性泡沫聚合物、吸收性胶质聚合物材料、水凝胶、天然淀粉和树胶、等等。特别相关的材料包括如纸板的纤维素基材。吸收层可包括单独一层材料或包括具有许多成分相同或不同层的叠层结构。此外,吸收层可包括一条载体薄条,它本身可以有吸收性或没有吸收性,但可以带着吸收材料。在本发明薄片材料中吸收层的作用是吸收和隔绝液体,使得薄片材料即使在已吸收了一些液体之后,仍保持其功能、支承和保护作用,以及放在阻挡系统上的物体或物质仍保持与留在吸收层中的液体分开。The absorbent layer may be made of any material suitable for absorbing and/or containing any relevant liquids. Suitable materials include fibrous thin strips or sheet materials made of natural (cellulose, etc.) and/or synthetic fibers, including hollow fibers and capillary fibers, absorbent foam polymers, absorbent colloidal polymer materials, hydrogels , native starches and gums, etc. Materials of particular interest include cellulosic substrates such as paperboard. The absorbent layer may comprise a single layer of material or comprise a laminated structure having a number of layers of the same or different composition. In addition, the absorbent layer may comprise a carrier web, which may or may not be itself absorbent, but may carry absorbent material therewith. The role of the absorbent layer in the sheet material of the present invention is to absorb and insulate liquids so that even after the sheet material has absorbed some liquid, it retains its function, support and protection, and objects or substances placed on the barrier system remain Separate from liquid left in absorbent layer.
底层可由适于在不渗透相关液体的吸收层表面上形成连续层或涂层的任何材料制成。合适的材料包括胶接或叠合在吸收层上的聚合薄膜、直接浇铸或挤压在吸收层上的热塑性树脂、金属膜、或者其它印刷、喷溅或其它专门方式涂复的不渗透涂层等。底层可包括单独一层的材料,或包括具有许多成分相同或不同层的叠层结构。The backsheet may be made of any material suitable for forming a continuous layer or coating on the surface of the absorbent layer impermeable to the liquid of interest. Suitable materials include polymeric films glued or laminated to the absorbent layer, thermoplastic resins cast or extruded directly on the absorbent layer, metallic films, or other impermeable coatings that are printed, sprayed, or otherwise specially applied wait. The base layer may comprise a single layer of material, or comprise a laminated structure having many layers of the same or different composition.
阻挡条可由适于形成所希尺寸、形状和间隔的任何材料制成。按照本发明,阻挡条基本上不吸收和基本上不渗透相关液体。在一个优选实施例中,阻挡条由疏水材料制成,它排斥相关的液体而不被液体湿润。合适的材料包括胶接或叠合在吸收层上的聚合薄膜带,直接浇铸或挤压在吸收层上的热塑性、热固性或者交联树脂或热固性泡沫,用胶粘剂之类胶接在吸收层上的带涂层的纸或纸板带,等等。阻挡条可包括单独一层的材料,或包括具有许多成分相同或不同层的叠层结构。阻挡系统可具有适于特定用途的任何所希望的厚度。1,5到100密耳之间的厚度已证明适于使用。约在0.010到0.150英寸之间的阻挡宽度已证明适于使用,而阻挡间隔(相邻阻挡元件之间的间隔)约在0.030到0.500英寸之间。尽管阻挡系统可包括不同尺寸、形状和/或厚度的元件,或者厚度变化的元件,但目前最好是阻挡系统可提供一个基本上为平面的表面,它基本上平行于薄片材料的主平面。Barrier bars may be made of any material suitable for forming the desired size, shape and spacing. According to the present invention, the barrier strip is substantially non-absorbent and substantially impermeable to associated liquids. In a preferred embodiment, the barrier strip is made of a hydrophobic material which repels the associated liquid without being wetted by it. Suitable materials include polymeric film tapes glued or laminated to the absorbent layer, thermoplastic, thermoset or cross-linked resins or thermoset foams cast or extruded directly on the absorbent layer, adhesives or the like bonded to the absorbent layer Coated paper or cardboard strips, etc. Barrier strips may comprise a single layer of material, or comprise a laminated structure having many layers of the same or different composition. The barrier system can have any desired thickness suitable for a particular application. Thicknesses between 1,5 and 100 mils have proven suitable for use. Barrier widths of between about 0.010 and 0.150 inches have proven suitable for use, while barrier spacing (spacing between adjacent barrier elements) is between about 0.030 and 0.500 inches. Although the barrier system may comprise elements of different sizes, shapes and/or thicknesses, or elements of varying thickness, it is presently preferred that the barrier system provide a substantially planar surface which is substantially parallel to the major plane of the sheet material.
供选用的胶粘剂系统35可包括一个带状、网状、离散或连续压敏胶涂层或层,或者目前技术中已知的其它胶粘剂系统,以便在薄片材料10和支承面之间提供粘结力。这个供选用的特性提供了高于底层和支承面之间摩擦系数的附加侧向稳定性。根据胶粘剂的粘性和/或薄片材料的构造,可希望具有防粘衬或其它构形。其它构形可利用非粘性但有较高摩擦系数的材料,它可抵抗在大多数常见支承面上的滑动。The optional adhesive system 35 may comprise a tape, web, discrete or continuous coating or layer of pressure sensitive adhesive, or other adhesive systems known in the art to provide a bond between the
一种有意义的方式是一个与底层成整体的可选择激活的胶粘剂系统,它在底层外表面受压时被激活来使外表面产生粘性。这种材料包括聚合材料或其它薄片材料,它至少在作为阻挡区的一个表面上,被压凸/压凹成一种被抬高的“波纹”图案,直到阻挡区被变形到使结构超出二维形状之前,它可防止在它之间或之内的物质(胶粘剂)与外表面接触。有代表性的结构公布在如下一起被委托转让、同在审理中(已承认)的美国专利申请系列号中:Hamiltom和McGuire 1996年1月10日申请的08/584,683,名称为“目标面受压时可对目标面释放密封的复合材料及其制造方法”,Hamiltom和McGuire 1996年11月8日申请的08/744,850,名称为“具有受可变形阻挡区保护物质的材料及其制造方法”,McGuire,Tweddell和Hamiltom 1996年11月8日申请的08/745,339,名称为“抵抗嵌套的三维薄片材料及其制造方法和设备”,Hamiltom和McGuire 1996年11月8日申请的08/745,340,名称为“改进的贮存卷材”,Hamiltom,McGuire,Tweddell和Otten1997年6月6日申请的08/869/602,名称为“在目标面上分配和散布物质的可选择激活的薄片材料”,以及Hamiltom和McGuire 1997年7月16日申请的[ ],代理部门记录号6761,名称为“具有把物质传送到目标面上的多级逐步激活作用的薄片材料”。以上这些申请引入这里作为参考。One approach of interest is an integral, selectively activatable adhesive system to the substrate that is activated when the outer surface of the substrate is compressed to make the outer surface tacky. Such materials include polymeric or other sheet materials that are embossed/debossed in a raised "wave" pattern on at least one surface that acts as a barrier until the barrier is deformed so that the structure exceeds two dimensions Before being shaped, it prevents the substance (adhesive) between or within it from contacting the outer surface. A representative structure is disclosed in the following co-assigned, co-pending (admitted) U.S. Patent Application Serial No. 08/584,683, filed Jan. 10, 1996, by Hamilton and McGuire, entitled "Target Face Receiving Composite Materials Releasing Seals to Target Surfaces When Pressed and Methods of Making the Same," 08/744,850, filed November 8, 1996, by Hamilton and McGuire, entitled "Materials Having Substance Protected by Deformable Barriers and Methods of Making the Same" , McGuire, Tweddell, and Hamilton, 08/745,339, filed November 8, 1996, entitled "Three-Dimensional Flake Materials Resistant to Nesting and Methods and Apparatus for Making The Same," 08/745,340 filed November 8, 1996, Hamilton and McGuire , entitled "Improved Storage Membranes," 08/869/602, filed June 6, 1997, by Hamilton, McGuire, Tweddell, and Otten, entitled "Selectively Activatable Sheet Materials for Distributing and Spreading Substances on a Target Surface" , and [ ], filed July 16, 1997, by Hamilton and McGuire, Attorney's Department Record No. 6761, entitled "Laminar Materials with Multi-Level Gradual Activation for Delivery of Substances to Target Surfaces." These above applications are incorporated herein by reference.
在使用中,把薄片材料放在如柜台面、桌面或地板面的支承面上,再把物体或物质放在其上面。物体或物质可以是食品或其它任何相关的物品,它要在任何操作过程中被摆弄或者搬动或处理。薄片材料也可用于物体的贮存,以收集剩余的液体。物体或物质由阻挡条支承,阻挡条防止物体或物质基本上不与吸收层直接接触,由此不会被所含液体污染或弄湿。在使用之后,或者在吸收层已被液体充分污染或饱和时,以可靠的方式把薄片材料丢弃。In use, the sheet material is placed on a support surface such as a counter top, table top or floor surface and an object or substance is placed thereon. The object or substance may be food or any other related item which is to be handled or carried or handled during any operation. Sheet material can also be used for object storage to collect remaining liquid. The object or substance is supported by the barrier strip, which prevents the object or substance from substantially direct contact with the absorbent layer, and thus from contamination or wetting by contained liquid. After use, or when the absorbent layer has been sufficiently soiled or saturated with liquid, the sheet material is discarded in a reliable manner.
薄片材料最好有充分的弯曲性和适应性,使得它可以贴合有些不规则或有轮廓的支承面。对于某些要发放或包装的构形,也希望薄片材料在一个或几个方向上有充分的适应性,使得它自身可以成卷,形成更紧密的构形。选择薄片材料中有关元件的材料,以及通过适当的结构设计来保持较低的弯曲模量(小的截面积、垂直于薄片材料平面的最小厚度等),有助于达到所希望的弯曲程度。The sheet material is preferably sufficiently flexible and conformable that it can conform to somewhat irregular or contoured support surfaces. For certain dispensing or packaging configurations, it is also desirable that the sheet material has sufficient flexibility in one or more directions so that it can roll itself into a more compact configuration. Selection of materials for the relevant elements of the sheet material, and keeping the flexural modulus low by proper structural design (small cross-sectional area, minimum thickness perpendicular to the plane of the sheet material, etc.), helps to achieve the desired degree of bending.
如果希望用于特定的用途,本发明薄片材料的吸收层或其它任何元件可包含或引入某种活性材料,它可激活放在薄片材料上的物体或物质,和/或激活物体或物质带着的或渗出的液体。这种活性可包括一些活性剂,用于在使用时中和、分离、消毒或改变固体或液体材料的性质或者在薄片材料周围的大气环境。相关的特种活性剂可以是改变诸如水状液体、血基液体、油等液体性质的活性剂。对某些用途所希望的常见性质是除臭性质、抗菌性质、凝固性质等。材料的例子包括碳酸氢钠、纤维蛋白原、以及以适当形式掺杂的其它材料。If desired for a particular application, the absorbent layer or any other element of the sheet material of the present invention may contain or incorporate an active material that activates an object or substance placed on the sheet material, and/or activates the object or substance with or oozing fluid. Such actives may include active agents for neutralizing, separating, sanitizing or altering the properties of the solid or liquid material or the atmosphere surrounding the sheet material in use. A relevant specialty active agent may be one that alters the properties of liquids such as aqueous liquids, blood-based liquids, oils, and the like. Common properties that are desirable for certain uses are deodorizing properties, antibacterial properties, coagulating properties, and the like. Examples of materials include sodium bicarbonate, fibrinogen, and other materials doped in appropriate forms.
对某些用途可能希望包括改变保护性薄片材料颜色的特性,以指示出在使用时薄片材料状态发生的改变。例如,可以希望在薄片材料中包括变色成分,由此在吸收液体时吸收层改变颜色。另外,可选择薄片材料中有关元件的颜色,使得阻挡系统和吸收层在开始时为相同的颜色,如白色,直到吸收层改变成反差大的颜色如红色为止。完成这种颜色改变的一种方法是引入食品级的添加剂,例如可买到的商标名KoolAid的粉状调味混合饮料,或者在吸收层之内或之下的其它着色粉末。如果混合饮料或着色粉末遇到液体,它溶解在液体中并“渗”入吸收层,改变吸收层的外观颜色。可由其它功能上发生实际改变来引发颜色的改变,例如在吸收层内抗菌剂已用完或存在细菌的情形。在Fenn等1982年1月19日发布的美国专利号4,311,479中公布了适于这种效果的一个方法,引入这里作为参考。For some uses it may be desirable to include a property of changing the color of the protective sheet material to indicate a change in state of the sheet material during use. For example, it may be desirable to include a color changing component in the sheet material, whereby the absorbent layer changes color when liquid is absorbed. In addition, the color of the relevant elements in the sheet material may be chosen such that the barrier system and the absorbing layer are initially the same color, eg white, until the absorbing layer changes to a contrasting color, eg red. One way to accomplish this color change is to incorporate food grade additives such as powdered flavored drink mixes available under the trade name KoolAid(R), or other colored powders within or beneath the absorbent layer. If the drink mix or coloring powder encounters a liquid, it dissolves in the liquid and "bleeds" into the absorbent layer, changing the apparent color of the absorbent layer. The color change may be caused by other actual changes in function, such as the depletion of antimicrobial agent or the presence of bacteria in the absorbent layer. One method suitable for this effect is disclosed in US Patent No. 4,311,479, issued January 19, 1982 to Fenn et al., incorporated herein by reference.
把阻挡系统设计成使得相邻支承条、支承件或支承区的间隔足够的小,以防止在使用时通常遇到的力下,放在其上面的物体或物质与吸收层基本上接触。阻挡系统还最好在这种常见力下基本上可以抵抗变形,从而保持物体或物质与其下面的吸收层之间分开。用于形成阻挡系统的材料可增加其弹性,使得在使用时可遇到某些轻微程度的变形,但变形是暂时性质的,当外力从物体或物质上移去时,阻挡系统可恢复到其基本上未变形的状态。The barrier system is designed such that the spacing between adjacent support bars, support members or support areas is sufficiently small to prevent objects or substances placed thereon from substantially contacting the absorbent layer under forces normally encountered in use. The barrier system is also preferably substantially resistant to deformation under such common forces, thereby maintaining separation between the object or substance and the underlying absorbent layer. The material used to form the barrier system may increase its elasticity so that some slight degree of deformation may be encountered in use, but the deformation is temporary in nature and the barrier system returns to its original value when the external force is removed from the object or substance. substantially undeformed state.
如果受到由尖锐物体或切割工具,如带有细长而基本上线状边的刀的撞击,则图1薄片材料10的方位最好使得阻挡条40位于基本上垂直于撞击边的方向。这种方位有助于保证撞击边至少与一条,最好是与几条阻挡条接触来分配撞击力,并且保证撞击边不与相比起来更脆弱的吸收层以及其下面的隔离层接触。If struck by a sharp object or cutting implement, such as a knife with an elongated, substantially linear edge, the orientation of the
阻挡系统最好由经久耐用、有弹性、抗切割和/或抗擦伤/磨损的材料制成。可利用目前技术中已知具有这种性质的常见材料,包括这样的材料:它们通常具有高度韧性、较高分子量材料的联锁分子结构、以及较高的滑动摩擦系数。合适的材料包括聚合材料,如EVA、高密度聚乙烯(HDPE)、低密度聚乙烯(LDPE)、线性低密度聚乙烯(LLDPE)、聚氯乙烯(PVC)、塑料溶胶、聚丙烯(PP)、以及聚亚胺酯、加密纸材等。The barrier system is preferably made of a durable, resilient, cut-resistant and/or scratch/abrasion-resistant material. Common materials known in the art to have this property can be utilized, including materials that generally have a high degree of toughness, an interlocking molecular structure of higher molecular weight materials, and a higher coefficient of sliding friction. Suitable materials include polymeric materials such as EVA, high density polyethylene (HDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), polyvinyl chloride (PVC), plastisol, polypropylene (PP) , And polyurethane, encrypted paper, etc.
图2描绘了本发明薄片材料10的另一个实施例。在图2的实施例中,用一个连续的阻挡网格50替代图1实施例的阻挡条来形成一个阻挡系统。阻挡网格50可以整体制成,或者由各离散条的重叠和相交模式形成,离散条相互连接成连续的结构。Figure 2 depicts another embodiment of a
在图2实施例中,阻挡系统相似于图1的系统,但对如刀或尖锐物体的撞击边提供了全方向的保护。因此,可沿着相对于撞击边的任何所希望方向上放置图2的薄片材料10,仍可以对这种撞击边的直接接触为吸收层和隔离层提供保护。In the Figure 2 embodiment, the barrier system is similar to that of Figure 1, but provides omnidirectional protection against impact edges such as knives or sharp objects. Thus, the
本发明薄片材料10的另一个实施例如图3所示。在该实施例中,许多离散的吸收元件60替代了图1和2实施例的连续吸收层20。吸收元件60包括吸收材料的离散沉积物,如适于形成连续吸收层的材料,并且与连续阻挡网格50内的空间连接。因此,由相邻吸收元件表面形成的表面被在其外面延伸的阻挡系统周期性地断开。如图3所示,阻挡系统直接与隔离层接触,使得作用在阻挡系统外表面上的力绕过吸收层而传到隔离层。所以这种构形降低了迫使液体从吸收层流到相关物体或物质上的可能性。Another embodiment of the
如图3的隔室化的吸收材料布局趋向于把液体限制在初始液体沉积的附近,因为不渗透的底层和不吸收、不渗透的连续阻挡网格有效地防止了液体在相邻吸收元件之间的迁移。虽然对某些用途隔室化的吸收材料分布可能是希望的,但对于大多数用途,目前最好是利用连续的吸收层,以提供最大程度的吸收能力。Compartmented absorbent material layouts such as those in Figure 3 tend to confine liquid to the vicinity of the initial liquid deposition because the impermeable backsheet and nonabsorbent, impermeable continuous barrier grid effectively prevents liquid from escaping between adjacent absorbent elements. migration between. While for some applications a compartmentalized distribution of absorbent material may be desirable, for most applications it is presently preferred to utilize a continuous absorbent layer to provide maximum absorbency.
图4描绘了本发明薄片材料10的另一个实施例,它一般与图3相似,但其中连续的阻挡网格50与隔离层30作成整体,最好是作成一体。由于减少了独立元件的数目,这些元件在外力影响下特别是在剪力影响下会相互移动,因此这种构形为最终的整个结构提供了附加的完整性和稳定性。如图3一样,图4实施例也保证了作用在阻挡系统外表面上的力可绕过吸收层传到隔离层上。Figure 4 depicts another embodiment of the
在一般与图2相似的图5实施例中,阻挡系统包括一个连续的阻挡网格50。但是,图5的薄片材料10包括一个连续的阻挡网格50,它包括叠加在相应形状支承元件70上的较薄层或结构。支承元件70可由与阻挡网格50相同的材料、与吸收层20相同的材料、或者与这两个相邻元件不同的材料制成。如图5所示的构形容许对阻挡网格采用较薄的材料,它证明是更便宜,而仍可通过支承元件70为放在薄片材料上的物体或物质与吸收层之间提供所希望的阻挡程度。In the embodiment of FIG. 5, which is generally similar to that of FIG. 2, the barrier system comprises a
图6描绘了本发明薄片材料10的另一个目前优选的实施例。图6实施例一般与图5实施例相似,但区别在于:用于较薄阻挡网格50的支承元件与吸收层20制成整体和一体,并采取了吸收层20的轮廓区25的形状。轮廓区25具有一个在薄片材料平面内的平面形状,它基本上相似于阻挡网格50的形状。虽然可利用多种多样的成形工艺过程来制成吸收层的轮廓区,但目前优选的工艺过程是利用轮廓成形结构来制成一个含纤维的、纤维素基的吸收层,例如在以下一起委托转让的美国专利中公布的工艺过程,引入这里作为参考:Johnson等的4,514,345,Smurkoski等的5,098,522,Trokhan的4,528,239,以及Trokhan的5,245,025。Figure 6 depicts another presently preferred embodiment of the
图6还说明了在薄片材料平面内与图2-5所示构形不同的连续阻挡网格形状。按照本发明,目前认为连续阻挡网格可以作成具有足够开口面积来把液体引入吸收层的任何希望构形。Figure 6 also illustrates a continuous barrier grid shape in the plane of the sheet material that differs from the configuration shown in Figures 2-5. In accordance with the present invention, it is presently contemplated that the continuous barrier grid may be of any desired configuration having sufficient open area to introduce liquid into the absorbent layer.
以上讨论的大多数实施例集中在采用这样的阻挡系统:它包括目前优选的连续阻挡网格,或者作为替代方式,至少包括一个半连续阻挡网格,它在薄片材料平面内在一个规定方向上是连续的。但是,本发明同样可用于不连续的阻挡网格,它包括许多离散的阻挡元件,它们在薄片材料平面内沿多个方向离散。因此,图7描绘了本发明的一种薄片材料10,它具有许多离散的阻挡元件40,如果希望,它们可与底层30制成一体,并且可形成实心或空心构形,如图7所示。这种构形对个别阻挡元件赋予了附加的稳定性,因为它们在薄片材料平面中具有较小的足迹。与图3实施例一样,图7实施例保证了作用在阻挡系统外表面上的力绕过吸收层传到隔离层上。Most of the embodiments discussed above have focused on employing a barrier system that includes a presently preferred continuous barrier grid or, alternatively, at least a semi-continuous barrier grid that is continuously. However, the invention is equally applicable to discontinuous barrier grids comprising a plurality of discrete barrier elements which are discrete in multiple directions within the plane of the sheet material. Accordingly, FIG. 7 depicts a
虽然这种阻挡系统在使吸收层免受撞击边或刀口影响方面,提供了较小的保护方式,但较低的弯曲模量(增加了柔性)使薄片材料更容易贴合具有非平面形状的支承面。较大的贴合程度还促进了更多种运输和/或发放布局,如把薄片材料卷成紧密的形式,或者从连续的成卷制品发放薄片材料。尽管图7描绘了有序布局的阻挡元件,但无定形(无序)的阻挡元件模式可使刀口或边与吸收层接触的可能性降到最小,而同时保持了具有个别阻挡元件的柔性结构。在上述引入的McGuire等的专利申请中更详细地描述了这种无定形模式。While this barrier system provides less protection in terms of keeping the absorbent layer from impacting edges or knife edges, the lower flexural modulus (increased flexibility) makes it easier for the sheet material to conform to surfaces with non-planar shapes. bearing surface. The greater degree of fit also facilitates a greater variety of shipping and/or dispensing arrangements, such as rolling the sheet material into a compact form, or dispensing the sheet material from a continuous roll. Although Figure 7 depicts an ordered layout of barrier elements, an amorphous (disordered) pattern of barrier elements can minimize the possibility of knife edges or edges coming into contact with the absorbent layer while maintaining a flexible structure with individual barrier elements . Such amorphous patterns are described in more detail in the above-incorporated McGuire et al. patent application.
图1-7的薄片材料集中于这样的实施例,其中阻挡系统在薄片材料的表面积中占有较小部分,而剩余部分是由覆盖下面吸收层的自由空间组成。相反,图8实施例包括了这样的薄片材料10,它包括了与图7相似的许多离散阻挡元件形式的阻挡系统,但它与盖片80制成一体,盖片80在与底层30对着的另一侧上覆盖着吸收层20。为了促进液体进入吸收层20,盖片80和/或阻挡元件90上设有许多任何所希形状、间隔和布局的排泄孔100。The sheet materials of Figures 1-7 focus on embodiments in which the barrier system occupies a relatively small portion of the surface area of the sheet material, with the remainder consisting of free space covering the underlying absorbent layer. In contrast, the FIG. 8 embodiment includes a
在图8实施例中,吸收层在盖片与底层之间包括了一个比较平的层。但是,这种构形使得阻挡元件(在图8中是空心的,并且与盖片制成一体)变空和基本上在内部没有支承。图9提供了一个与图8相似的替代实施例,但其中对空心阻挡元件90充以一部分吸收层20,吸收层向上伸到阻挡元件的空心一侧。这种构形提供了附加的吸收能力,它超过了基本上为平面的吸收层提供的吸收能力。In the Figure 8 embodiment, the absorbent layer comprises a relatively flat layer between the cover sheet and the backsheet. However, this configuration leaves the blocking element (hollow in FIG. 8 and integral with the cover sheet) empty and essentially unsupported inside. Figure 9 provides an alternative embodiment similar to Figure 8, but in which the
图10说明了的本发明薄片材料10的另一个实施例,它相似于图8和9,但通过盖片80具有形成连续阻挡网格的阻挡系统,盖片80包括下陷95而不是离散的阻挡元件90。开孔100按希望设在盖片和/或下陷95的底部,它形成了落到薄片材料上液体的自然收集点。Figure 10 illustrates another embodiment of the
本发明薄片材料可在多种多样情形下展开,并且可用于多种多样的功能。由这种薄片材料制成的代表性产品及其相应的应用可包括(但不限于)座位垫、食品准备垫、沥干已洗或已煮食品垫、地板垫、抽斗和架子衬垫等。相关物体可包括如肉片、制成品、烘烤物品等食品。相关物质可包括具有足够完整性来跨在阻挡系统上的物质,如面包团等。The sheet materials of the present invention can be deployed in a wide variety of situations and can be used in a wide variety of functions. Representative products made from such sheet materials and their corresponding applications may include, but are not limited to, seating mats, food preparation mats, mats for draining washed or cooked food, floor mats, drawer and shelf liners, and the like. Objects of interest may include food items such as cutlets, finished goods, baked goods, and the like. Substances of interest may include substances with sufficient integrity to straddle the barrier system, such as bread dough and the like.
尽管已经说明和描述了本发明的各个特定实施例,对于熟悉该技术的人员来说,显然可作出各种其它变化和修改而不背离本发明的精神和范围。因此在所附权利要求中试图包括在本发明范围内的所有这种变化和修改。While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
Claims (19)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US91848697A | 1997-08-26 | 1997-08-26 | |
| US08/918,486 | 1997-08-26 | ||
| US666998A | 1998-01-13 | 1998-01-13 | |
| US09/006,669 | 1998-01-13 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1268085A CN1268085A (en) | 2000-09-27 |
| CN1116982C true CN1116982C (en) | 2003-08-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98808513A Expired - Fee Related CN1116982C (en) | 1997-08-26 | 1998-08-10 | Multi-purpose absorbent and protective sheet materials |
Country Status (21)
| Country | Link |
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| EP (1) | EP1007350A1 (en) |
| JP (1) | JP2001514126A (en) |
| KR (1) | KR20010023335A (en) |
| CN (1) | CN1116982C (en) |
| AR (1) | AR016641A1 (en) |
| AU (1) | AU737290B2 (en) |
| BR (1) | BR9812000A (en) |
| CA (1) | CA2301550A1 (en) |
| CO (1) | CO4810386A1 (en) |
| HU (1) | HU223501B1 (en) |
| ID (1) | ID25915A (en) |
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| PL (1) | PL338900A1 (en) |
| SK (1) | SK2632000A3 (en) |
| TR (1) | TR200000508T2 (en) |
| TW (1) | TW375580B (en) |
| WO (1) | WO1999010164A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US7063880B2 (en) | 2000-10-02 | 2006-06-20 | S.C. Johnson Home Storage, Inc. | Sheet material and manufacturing method and apparatus therefor |
| US7056569B2 (en) | 2000-10-02 | 2006-06-06 | S.C. Johnson Home Storage, Inc. | Disposable cutting sheet |
| US7078088B2 (en) | 2000-10-02 | 2006-07-18 | S.C. Johnson Home Storage, Inc. | Disposable cutting sheet |
| US6986931B2 (en) | 2000-10-02 | 2006-01-17 | S.C. Johnson & Son, Inc. | Disposable cutting sheet |
| US7022395B2 (en) | 2000-10-02 | 2006-04-04 | S.C. Johnson Home Storage, Inc. | Disposable cutting sheet |
| US7063879B2 (en) | 2000-10-02 | 2006-06-20 | S.C. Johnson Home Storage, Inc. | Disposable cutting sheet |
| US6979485B2 (en) | 2000-10-02 | 2005-12-27 | S.C. Johnson Home Storage, Inc. | Processing substrate and/or support surface |
| US6991844B2 (en) | 2000-10-02 | 2006-01-31 | S.C. Johnson Home Storage, Inc. | Disposable cutting sheet |
| WO2002074656A1 (en) * | 2001-03-15 | 2002-09-26 | Showa Denko Plastic Products Co,, Ltd. | Liquid-absorbing sheet for packaging perishable food |
| FR2822445B1 (en) * | 2001-03-22 | 2003-08-15 | Christian Pascal | PACKAGING OF INFECTIOUS SAMPLES |
| US7026034B2 (en) | 2003-02-11 | 2006-04-11 | S.C. Johnson Home Storage, Inc. | Processing substrate and method of manufacturing same |
| DE202008010557U1 (en) * | 2008-08-08 | 2009-12-31 | Scheffer, Georg | Packaging for food with absorbent inserts |
| TR201305180A2 (en) * | 2013-05-02 | 2013-12-23 | Nedim Vidinlisan | Antibacterial thermobox that enables cooked hot transportable foods such as pizza, pita, lahmacun and hamburger to be delivered to the consumer via delivery service |
| EP2824041A1 (en) * | 2013-07-11 | 2015-01-14 | Manfred Zimmer | Package for food such as fish |
| KR101632872B1 (en) * | 2015-01-19 | 2016-06-23 | 박규하 | Protection mat for loading of plate glass |
| CN108396916A (en) * | 2018-04-08 | 2018-08-14 | 李长松 | A kind of fibre web composite environment-friendly type interior wall coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1168925A (en) * | 1967-04-22 | 1969-10-29 | Paul Taylor Developments Ltd | Expendible Tray for Displaying Moist Foodstuffs |
| US3929135A (en) * | 1974-12-20 | 1975-12-30 | Procter & Gamble | Absorptive structure having tapered capillaries |
| US4328275A (en) * | 1980-09-10 | 1982-05-04 | Vargo Louis M | Disposable floor mat |
| US4410578A (en) * | 1981-04-29 | 1983-10-18 | Miller Alan H | Receptacle for moisture exuding food products |
| JPH0445879Y2 (en) * | 1987-06-19 | 1992-10-28 | ||
| DE3922644A1 (en) * | 1989-07-10 | 1991-01-17 | Pietrek Reinhold Gmbh | TRAY FOR SALES PACKS OF FOODSTUFFS |
| DE4039354A1 (en) * | 1990-12-10 | 1992-06-11 | Silver Plastics Gmbh & Co Kg | Moulded dish for packaging e.g. foodstuffs - made of sandwich construction, with impervious skins but absorbent core, one skin being perforated and all layers based on same thermoplastic |
| US5151314A (en) * | 1991-01-31 | 1992-09-29 | Johnson & Johnson Medical, Inc. | Three-layer laminated panel |
| GB2284047A (en) * | 1993-11-16 | 1995-05-24 | Styropack | Transportation containers |
| FI101693B1 (en) * | 1994-03-16 | 1998-08-14 | Enso Gutzeit Oy | food Tray |
| US5709897A (en) * | 1995-09-12 | 1998-01-20 | Pearlstein; Leonard | Absorbent packaging for food products |
| CA2247209C (en) * | 1996-02-22 | 2002-10-08 | Sealed Air Corporation | An absorbent pad |
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1998
- 1998-08-10 BR BR9812000-0A patent/BR9812000A/en not_active Application Discontinuation
- 1998-08-10 JP JP2000507524A patent/JP2001514126A/en not_active Withdrawn
- 1998-08-10 AU AU84583/98A patent/AU737290B2/en not_active Ceased
- 1998-08-10 WO PCT/IB1998/001218 patent/WO1999010164A1/en not_active Ceased
- 1998-08-10 EP EP98935244A patent/EP1007350A1/en not_active Withdrawn
- 1998-08-10 CN CN98808513A patent/CN1116982C/en not_active Expired - Fee Related
- 1998-08-10 HU HU0003530A patent/HU223501B1/en not_active IP Right Cessation
- 1998-08-10 CA CA002301550A patent/CA2301550A1/en not_active Abandoned
- 1998-08-10 KR KR1020007001972A patent/KR20010023335A/en not_active Abandoned
- 1998-08-10 SK SK263-2000A patent/SK2632000A3/en unknown
- 1998-08-10 TR TR2000/00508T patent/TR200000508T2/en unknown
- 1998-08-10 ID IDW20000513A patent/ID25915A/en unknown
- 1998-08-10 PL PL98338900A patent/PL338900A1/en unknown
- 1998-08-10 IL IL13461398A patent/IL134613A/en not_active IP Right Cessation
- 1998-08-14 TW TW087113425A patent/TW375580B/en active
- 1998-08-24 PE PE1998000764A patent/PE50499A1/en not_active Application Discontinuation
- 1998-08-26 CO CO98048799A patent/CO4810386A1/en unknown
- 1998-08-26 MY MYPI98003914A patent/MY115762A/en unknown
- 1998-08-26 AR ARP980104251A patent/AR016641A1/en unknown
-
2000
- 2000-02-24 NO NO20000905A patent/NO20000905L/en not_active Application Discontinuation
- 2000-03-24 NZ NZ503590A patent/NZ503590A/en unknown
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| IL134613A (en) | 2004-06-20 |
| AU737290B2 (en) | 2001-08-16 |
| IL134613A0 (en) | 2001-04-30 |
| ID25915A (en) | 2000-11-09 |
| HUP0003530A3 (en) | 2001-03-28 |
| CN1268085A (en) | 2000-09-27 |
| JP2001514126A (en) | 2001-09-11 |
| CO4810386A1 (en) | 1999-06-30 |
| PL338900A1 (en) | 2000-11-20 |
| AR016641A1 (en) | 2001-07-25 |
| AU8458398A (en) | 1999-03-16 |
| MY115762A (en) | 2003-08-30 |
| CA2301550A1 (en) | 1999-03-04 |
| EP1007350A1 (en) | 2000-06-14 |
| KR20010023335A (en) | 2001-03-26 |
| HUP0003530A2 (en) | 2001-02-28 |
| TR200000508T2 (en) | 2000-07-21 |
| TW375580B (en) | 1999-12-01 |
| NZ503590A (en) | 2002-05-31 |
| NO20000905L (en) | 2000-04-19 |
| NO20000905D0 (en) | 2000-02-24 |
| SK2632000A3 (en) | 2000-08-14 |
| PE50499A1 (en) | 1999-06-16 |
| HU223501B1 (en) | 2004-08-30 |
| WO1999010164A1 (en) | 1999-03-04 |
| BR9812000A (en) | 2000-09-05 |
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