CN111635137A - Formula and preparation method of zirconium silicate-free abrasive brick calcined luster and matte white glaze - Google Patents
Formula and preparation method of zirconium silicate-free abrasive brick calcined luster and matte white glaze Download PDFInfo
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- CN111635137A CN111635137A CN202010531901.9A CN202010531901A CN111635137A CN 111635137 A CN111635137 A CN 111635137A CN 202010531901 A CN202010531901 A CN 202010531901A CN 111635137 A CN111635137 A CN 111635137A
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- glaze
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- 239000011449 brick Substances 0.000 title claims abstract description 9
- 239000002932 luster Substances 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 title claims abstract description 7
- 229910052726 zirconium Inorganic materials 0.000 title claims abstract description 7
- 238000009472 formulation Methods 0.000 title description 2
- 239000002994 raw material Substances 0.000 claims abstract description 29
- 239000000463 material Substances 0.000 claims abstract description 19
- 239000000843 powder Substances 0.000 claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000292 calcium oxide Substances 0.000 claims abstract description 9
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003513 alkali Substances 0.000 claims abstract description 8
- 239000011521 glass Substances 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 8
- 238000000227 grinding Methods 0.000 claims abstract description 7
- 239000010453 quartz Substances 0.000 claims abstract description 7
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 6
- 239000010433 feldspar Substances 0.000 claims abstract description 6
- 239000000454 talc Substances 0.000 claims abstract description 6
- 235000012222 talc Nutrition 0.000 claims abstract description 6
- 229910052623 talc Inorganic materials 0.000 claims abstract description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 5
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims description 7
- 229910052593 corundum Inorganic materials 0.000 claims description 6
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 238000003672 processing method Methods 0.000 claims 1
- 229910052573 porcelain Inorganic materials 0.000 abstract description 4
- 239000000919 ceramic Substances 0.000 abstract description 3
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 230000004927 fusion Effects 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 238000010304 firing Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910052604 silicate mineral Inorganic materials 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 230000035800 maturation Effects 0.000 description 2
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910052656 albite Inorganic materials 0.000 description 1
- 229910001579 aluminosilicate mineral Inorganic materials 0.000 description 1
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 1
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910052647 feldspar group Inorganic materials 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 229910052850 kyanite Inorganic materials 0.000 description 1
- 239000010443 kyanite Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229910052851 sillimanite Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a formula and a manufacturing method of zirconium silicate-free abrasive brick calcined luster and matte white glaze, belonging to the technical field of porcelain production materials, wherein zirconium silicate is not used in the formula, and the formula comprises that the leftover materials of finished products of a glass factory are adopted, namely alkali-free filaments (10-20% of low-expansion filaments), medium-alkali filaments (10-30% of high-expansion filaments) and calcium oxide or calcium carbonate raw materials are adopted for preparing the ceramic. 1 to 15 percent of talcum material, 1 to 10 percent of quartz material, 1 to 10 percent of high-alumina raw material, 5 to 15 percent of kaolin raw material, 10 to 30 percent of potash-soda feldspar and other raw materials, and 10 to 40 percent of fusion cake which is self-developed by the company. The manufacturing method comprises the following steps: grinding the raw materials into powder by a grinder, uniformly stirring the powder in a stirrer, and bagging the powder for use. The formula and the preparation method of the wear-resistant glaze have the advantages that the preparation process is simple and convenient, heating is not needed, common raw materials commonly used in the market are used for preparing the wear-resistant glaze, the zirconium silicate with high manufacturing cost is replaced, the problem that the cost of the wear-resistant glaze of manufacturers is high is solved, the production cost of porcelain manufacturers is reduced, and the wear-resistant glaze is highly approved by various manufacturers.
Description
Technical Field
The invention belongs to the technical field of materials for producing porcelain, and particularly relates to a formula and a manufacturing method of a wear-resistant glaze.
Background
The matte white glaze is commonly called as wear-resistant brick glaze, the surface whiteness and the wear resistance of the glaze are important properties of the wear-resistant brick, according to the wear-resistant glaze prepared and sold in the market, the requirement of the whiteness is met by adding zirconium silicate, the adding amount of the zirconium silicate is between 5 and 15 percent, the requirement of a manufacturer is taken as a standard, and the temperature of a kiln during production is (1140 ℃ -1190 ℃). In recent years, along with the large price rise of zirconium silicate, the cost of the wear-resistant glaze of a manufacturer is high, and a large amount of long-term tests are carried out to solve the problem that the cost of the wear-resistant glaze is too high, so that the problem of replacing the zirconium silicate is solved.
Disclosure of Invention
The technical task of the invention is to provide a formula and a preparation method of zirconium silicate-free abrasive brick calcined luster and matte white glaze aiming at the defects of the prior art.
The technical scheme adopted by the invention for solving the technical problems is as follows: a formula of zirconium silicate-free abrasive brick calcined luster and matte white glaze and a manufacturing method thereof are disclosed, wherein zirconium silicate is not used in the formula, and the leftover material of a finished product of a glass factory is 10-20% of alkali-free filaments (low-expansion filaments), 10-30% of medium-alkali filaments (high-expansion filaments) and 3-6% of calcium oxide or calcium carbonate raw materials. 1 to 15 percent of talcum material, 1 to 10 percent of quartz material, 1 to 10 percent of high-alumina raw material, 5 to 15 percent of kaolin raw material, 10 to 30 percent of potash-soda feldspar and other raw materials, and 10 to 40 percent of fused block (the chemical component is SiO) which is self-developed by the company2:58～68%；Al2O3:7.5～15%；Fe2O3:0.1～0.35%； TiO2Trace amount of the active ingredients; 4-12% of CaO; 3-9% of MgO; k2O:1.5～9%；Na2O:1～2%）。
In the proportion, the leftover material of the finished product in the glass factory is taken as the main raw material, the raw material has low price, and the problem of pollution of the leftover material produced in the glass factory is solved. The alkali-free silk in the mixture ratio comprises the following chemical components: SiO22:59～64%； Al2O3:10～14%； Fe2O3:0.1～0.35%； TiO2Trace amount of the active ingredients; 18-24% of CaO; 1-3.5% of MgO; k2O:0.2～0.6%； Na2O:0.2～1%；B2O31 to 3 percent; ) The glaze maturing temperature and glaze opacity can be adjusted, and the expansion coefficient of the glaze is reduced; medium alkali silk (chemical composition: SiO)2:62～69%； Al2O3:6～9%； Fe2O3:0.1～0.35%； TiO2Trace amount of the active ingredients; 8-11% of CaO; 2-5% of MgO; k2O:0.2～0.6%； Na2O:8～12%；B2O31 to 3 percent; ) The glaze material can be added into the formula, the glaze material maturation temperature and the glaze material opacity can be adjusted, the glaze material expansion coefficient can be improved, and the glaze material maturation temperature and the glaze material opacity can be adjusted in a proper proportion according to the requirements of manufacturers so as to meet the specific requirements of the manufacturers and meet the requirements of actual products.
The talcum is a common silicate mineral, is very soft and has a greasy hand feeling, belongs to a trioctahedral mineral, has a structural formula of (Mg6) [ Si8] O20(OH)4, can be added into the glaze to widen the melting range of the glaze and improve the elasticity and the thermal stability of the glaze.
The quartz is a mineral composed of silicon dioxide in the formula of SiO 2. The pure quartz is colorless and transparent, has glass luster, and the fracture is grease luster. The hardness is 7, no cleavage exists, the shell-shaped fracture is a silicate mineral which is hard, wear-resistant and stable in chemical property, and the crystal brightness and whiteness of the proportioning material are improved. The expansion coefficient of the glaze is reduced, and the wear resistance and hardness of the glaze are improved.
The kaolin in the mixture ratio is a non-metal mineral product, is clay and claystone which mainly uses kaolinite clay mineral, is a common and very important clay mineral in the natural world, is formed by the weathering action of feldspar or other silicate minerals in igneous rock and metamorphic rock in an acid medium which is lack of alkali metal and alkaline earth metal, and the crystal chemical formula of the kaolinite is 2SiO2●Al2O3●2H2O, which belongs to 1:1 type layered silicate, is added into the glaze to improve the suspension property of the glaze and increase the aluminum content of the glaze.
In the formula, the potassium feldspar and the albite are aluminosilicate minerals of alkali metals or alkaline earth metals such as potassium, sodium, calcium and the like, also called feldspar group minerals, and can improve the hardness, the glossiness and the whiteness of the glaze surface when added into the formula.
The medium-high aluminum mineral raw material is also called a kyanite mineral (or a sillimanite mineral) raw material, and the chemical composition is Al2O3 & SO 2. The high-temperature-resistant and high-alkali-resistant composite material has the characteristics of high temperature resistance, acid and alkali resistance, high mechanical strength, good high temperature resistance under heavy load, expansion at high temperature and no shrinkage after cooling, and the wear resistance of the composite material is improved.
Further, the preparation method of the wear-resistant glaze formula comprises the following steps: grinding the raw materials into powder by a grinder, putting the powder into a stirrer to be uniformly stirred, and directly bagging the powder without heating for use.
The formula and the preparation method of the wear-resistant glaze have the advantages that the preparation process is simple and convenient, heating is not needed, common raw materials commonly used in the market are used for preparing the wear-resistant glaze, the zirconium silicate with high manufacturing cost is replaced, the problem that the cost of the wear-resistant glaze of manufacturers is high is solved, the production cost of porcelain manufacturers is reduced, and the wear-resistant glaze is highly approved by various manufacturers.
Detailed Description
Example 1: low-temperature firing formula
Taking 10-20 parts of leftover alkali-free filaments (namely low-expansion filaments) and 15-25 parts of medium-alkali filaments (namely high-expansion filaments) of finished glass factories, 1-5 parts of calcium oxide or calcium carbonate raw materials, 3-10 parts of talc, 1-5 parts of quartz, 3-5 parts of high-alumina raw materials, 8-12 parts of kaolin, and 10-35 parts of potassium-sodium feldspar and other raw materials, matching with 20-30 parts of frits developed by the company, grinding the raw materials into powder by a grinder, uniformly stirring the powder in a stirrer, bagging the powder, and transporting the powder to various manufacturers. The method comprises the steps of ball milling, glazing the surface of the ceramic tile by using a glazing disc after grinding, and achieving the required whiteness and brightness after firing at the temperature of 1130-1160 ℃.
Example 2: high-temperature firing formula
Taking 5-10 parts of offal alkali-free filaments (low-expansion filaments) of finished products of a glass factory, 15-25 parts of medium-alkali filaments (high-expansion filaments), 2-6 parts of calcium oxide or calcium carbonate raw materials, 2-6 parts of talc, 5-10 parts of quartz, 4-6 parts of high-alumina raw materials, 8-12 parts of kaolin raw materials and 25-40 parts of potassium-sodium feldspar and other raw materials, matching with 40 parts of frits developed by the company, grinding the raw materials into powder by a grinder, uniformly stirring the powder in a stirrer, bagging the powder, conveying the powder to various manufacturers, loading the powder into the ball mill, glazing the powder on the surface of a ceramic tile by using a glazing disc after grinding, and achieving the required whiteness and brightness at the firing temperature of 1160-1190 ℃.
Claims (2)
1. A formula and a manufacturing method of zirconium silicate-free abrasive brick calcined luster and matte white glaze are characterized in that: the formula does not use zirconium silicate, and adopts 10-20% of alkali-free silk (namely low-expansion silk), 10-30% of medium-alkali silk (namely high-expansion silk) and 3-6% of calcium oxide or calcium carbonate raw materials in the offal of the finished product of a glass factory. 1 to 15 percent of talcum material, 1 to 10 percent of quartz material, 1 to 10 percent of high-aluminum raw material, 5 to 15 percent of kaolin raw material, 10 to 30 percent of potash-soda feldspar and other raw materials10-40% of self-developed fused block (chemical component: SiO)2:58～68%；Al2O3:7.5～15%；Fe2O3:0.1～0.35%；TiO2Trace amount of the active ingredients; 4-12% of CaO; 3-9% of MgO; k2O:1.5～9%； Na2O:1～2%；）。
2. The formula and the preparation method of the zirconium silicate-free abrasive brick calcined luster and matte white glaze according to claim 1 are characterized in that: the processing method comprises the following steps: grinding the raw materials into powder by a grinder, uniformly stirring the powder in a stirrer, and bagging the powder for use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010531901.9A CN111635137A (en) | 2020-06-12 | 2020-06-12 | Formula and preparation method of zirconium silicate-free abrasive brick calcined luster and matte white glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010531901.9A CN111635137A (en) | 2020-06-12 | 2020-06-12 | Formula and preparation method of zirconium silicate-free abrasive brick calcined luster and matte white glaze |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111635137A true CN111635137A (en) | 2020-09-08 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010531901.9A Withdrawn CN111635137A (en) | 2020-06-12 | 2020-06-12 | Formula and preparation method of zirconium silicate-free abrasive brick calcined luster and matte white glaze |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111635137A (en) |
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2020
- 2020-06-12 CN CN202010531901.9A patent/CN111635137A/en not_active Withdrawn
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Application publication date: 20200908 |
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