CN111596135A - Method for analyzing resistance characteristics of electrodeposited gold structure - Google Patents
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Abstract
Description
技术领域technical field
本发明涉及材料检测领域,尤其涉及一种电沉积金结构的电阻特性分析方法。The invention relates to the field of material detection, in particular to a resistance characteristic analysis method of an electrodeposited gold structure.
背景技术Background technique
电沉积金结构具有优良的电学特性、强抗腐蚀能力、化学和光学特性,被广泛应用于集成电路、生物传感、电子通讯和航空航天等领域。电沉积金结构的电阻特性会直接影响到信号的传输效率,所以电沉积金结构电阻的测量变得尤为重要。Electrodeposited gold structures have excellent electrical properties, strong corrosion resistance, chemical and optical properties, and are widely used in integrated circuits, biosensing, electronic communications, and aerospace. The resistance characteristics of the electrodeposited gold structure will directly affect the transmission efficiency of the signal, so the measurement of the resistance of the electrodeposited gold structure becomes particularly important.
目前,测量电沉积金结构电阻的方法一般采用探针台进行四探针测量。但是,这种方法对电沉积金结构的粗糙度要求极高,并且探针与电沉积金结构的接触面积也会导致测量结果的不稳定,进而影响电沉积金结构电阻的测量结果的准确性。At present, the method for measuring the resistance of electrodeposited gold structures generally uses a probe station for four-point probe measurement. However, this method has extremely high requirements on the roughness of the electrodeposited gold structure, and the contact area between the probe and the electrodeposited gold structure will also lead to unstable measurement results, which in turn affects the accuracy of the measurement results of the electrodeposited gold structure resistance. .
发明内容SUMMARY OF THE INVENTION
本发明的目的在于提供一种电沉积金结构的电阻特性分析方法,利用电化学工作站对电沉积金结构的电阻特性进行分析,更为准确的表征电沉积金结构的电阻特性。The purpose of the present invention is to provide a method for analyzing the resistance characteristics of the electrodeposited gold structure, using an electrochemical workstation to analyze the resistance characteristics of the electrodeposited gold structure, and to more accurately characterize the resistance characteristics of the electrodeposited gold structure.
本发明提供了一种电沉积金结构的电阻特性分析方法,该方法包括以下步骤:The invention provides a resistance characteristic analysis method of electrodeposited gold structure, the method comprises the following steps:
提供多个金叉指电极,多个金叉指电极的电阻相关参数不同;Provide multiple gold interdigitated electrodes, and the resistance-related parameters of multiple gold interdigitated electrodes are different;
利用电化学工作站检测多个电沉积金结构在中频正弦电压下的阻抗;Using an electrochemical workstation to detect the impedance of multiple electrodeposited gold structures under intermediate frequency sinusoidal voltage;
根据多个所述电沉积金结构在中频正弦电压下的阻抗分析电沉积金结构的电阻特性。The resistance characteristics of the electrodeposited gold structures were analyzed according to the impedance of a plurality of the electrodeposited gold structures under the intermediate frequency sinusoidal voltage.
可选地,各个金叉指电极的电阻相关参数为金叉指电极的高度和金叉指电极的表面粗糙度。Optionally, the resistance-related parameters of each gold interdigitated electrode are the height of the gold interdigitated electrode and the surface roughness of the gold interdigitated electrode.
可选地,正弦电压的频率范围为100Hz到500kHz,正弦电压的振幅为5mV,直流偏压为0V。Optionally, the frequency range of the sinusoidal voltage is 100Hz to 500kHz, the amplitude of the sinusoidal voltage is 5mV, and the DC bias voltage is 0V.
可选地,提供多个金叉指电极包括:Optionally, providing a plurality of gold interdigitated electrodes includes:
提供多个金叉指状种子;Provides multiple golden interdigitated seeds;
利用电化学沉积法在不同的多个电沉积参数的控制下对多个叉指状种子一一对应的进行处理,获得多个金叉指电极。A plurality of interdigitated seeds are processed in a one-to-one correspondence under the control of various electrodeposition parameters by an electrochemical deposition method to obtain a plurality of gold interdigitated electrodes.
可选地,电沉积参数包括电沉积时间、正向脉冲电镀电流和反向刻蚀电流。Optionally, the electrodeposition parameters include electrodeposition time, forward pulsed plating current and reverse etch current.
可选地,各个电沉积参数包括的电沉积时间不同;Optionally, the electrodeposition time included in each electrodeposition parameter is different;
各个电沉积参数包括的正向脉冲电镀电流的大小和脉宽相同;The magnitude and pulse width of the forward pulse plating current included in each electrodeposition parameter are the same;
各个电沉积参数包括的反向刻蚀电流的大小和持续时间不同。The magnitude and duration of the reverse etch current included in each electrodeposition parameter were different.
可选地,提供多个金叉指状种子包括:Optionally, providing a plurality of golden interdigitated seeds includes:
提供衬底;provide a substrate;
在衬底上形成金种子层;forming a gold seed layer on the substrate;
对金种子层进行图形化处理,获得金叉指状种子。The gold seed layer is patterned to obtain gold interdigitated seeds.
可选地,在所述衬底上形成金种子层包括:Optionally, forming a gold seed layer on the substrate includes:
在所述衬底上定义叉指区域;defining an interdigital region on the substrate;
采用电镀法在叉指区域电镀金种子层。A gold seed layer is plated on the interdigital region by electroplating.
可选地,电镀液为金的无机盐溶液。Optionally, the electroplating solution is an inorganic salt solution of gold.
可选地,电镀液的pH值为6.5-7.5,电镀液的温度为25℃~55℃。Optionally, the pH value of the electroplating solution is 6.5-7.5, and the temperature of the electroplating solution is 25°C to 55°C.
与现有技术相比,本发明提供的电沉积金结构的电阻特性分析方法,对多个具有不同电阻相关参数的金叉指电极,在不同频率的正弦电压下的阻抗进行测量,避免了接触式测量中由于电沉积金结构本身的结构不同,以及对电沉积结构测量时的接触面积不同对测量结果的影响。在此基础上,利用该阻抗测量结果表征不同电沉积金结构在不同频率下的阻抗变化,可以准确的分析出电沉积金结构的电阻特性,在后续对电沉积金结构的电阻进行测量时,可参考上述电沉积金结构的电阻特性,实现对电沉积金结构的电阻的准确测量。Compared with the prior art, the method for analyzing the resistance characteristics of the electrodeposited gold structure provided by the present invention measures the impedance of a plurality of gold interdigitated electrodes with different resistance-related parameters under sinusoidal voltages of different frequencies, avoiding contact. In the measurement, due to the difference in the structure of the electrodeposited gold structure itself, as well as the influence of the different contact areas during the measurement of the electrodeposited structure on the measurement results. On this basis, using the impedance measurement results to characterize the impedance changes of different electrodeposited gold structures at different frequencies, the resistance characteristics of the electrodeposited gold structures can be accurately analyzed. In the subsequent measurement of the resistance of the electrodeposited gold structures, The resistance of the electrodeposited gold structure can be accurately measured by referring to the resistance characteristics of the electrodeposited gold structure.
附图说明Description of drawings
此处所说明的附图用来提供对本发明的进一步理解,构成本发明的一部分,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。在附图中:The accompanying drawings described herein are used to provide further understanding of the present invention and constitute a part of the present invention. The exemplary embodiments of the present invention and their descriptions are used to explain the present invention and do not constitute an improper limitation of the present invention. In the attached image:
图1为本发明提供的一种叉指电极的结构示意图;1 is a schematic structural diagram of an interdigital electrode provided by the present invention;
图2为本发明提供的一种将叉指电极放入去离子水中的示意图;Fig. 2 is a kind of schematic diagram of putting the interdigital electrode into deionized water provided by the present invention;
图3为本发明提供得一种叉指电极的等效电路图;3 is an equivalent circuit diagram of a kind of interdigital electrode provided by the present invention;
图4为本发明提供的一种电沉积金结构的电阻特性分析方法的步骤流程图;Fig. 4 is the step flow chart of the resistance characteristic analysis method of a kind of electrodeposited gold structure provided by the present invention;
图5为本发明提供的一种利用电化学工作站对将金叉指电极进行电阻特性检测时的结构示意图;Fig. 5 is a kind of structural schematic diagram when the electrochemical workstation is used to detect the resistance characteristics of gold interdigitated electrodes provided by the present invention;
图6为本发明提供的不同反向电流制备金叉指电极的电镜图;6 is an electron microscope image of gold interdigitated electrodes prepared by different reverse currents provided by the present invention;
图7为本发明提供的一种不同反向电流和不同电镀时间制备金叉指电极的频率-阻抗图;7 is a frequency-impedance diagram of gold interdigitated electrodes prepared by a kind of different reverse currents and different electroplating times provided by the present invention;
图8为本发明提供的一种不同厚度金叉指电极的频率-阻抗图。FIG. 8 is a frequency-impedance diagram of a gold interdigitated electrode with different thicknesses provided by the present invention.
具体实施方式Detailed ways
以下,将参照附图来描述本公开的实施例。但是应该理解,这些描述只是示例性的,而并非要限制本公开的范围。此外,在以下说明中,省略了对公知结构和技术的描述,以避免不必要地混淆本公开的概念。Hereinafter, embodiments of the present disclosure will be described with reference to the accompanying drawings. It should be understood, however, that these descriptions are exemplary only, and are not intended to limit the scope of the present disclosure. Also, in the following description, descriptions of well-known structures and techniques are omitted to avoid unnecessarily obscuring the concepts of the present disclosure.
在附图中示出了根据本公开实施例的各种结构示意图。这些图并非是按比例绘制的,其中为了清楚表达的目的,放大了某些细节,并且可能省略了某些细节。图中所示出的各种区域、层的形状以及它们之间的相对大小、位置关系仅是示例性的,实际中可能由于制造公差或技术限制而有所偏差,并且本领域技术人员根据实际所需可以另外设计具有不同形状、大小、相对位置的区域/层。Various structural schematic diagrams according to embodiments of the present disclosure are shown in the accompanying drawings. The figures are not to scale, some details have been exaggerated for clarity, and some details may have been omitted. The shapes of the various regions and layers shown in the figures, as well as their relative sizes and positional relationships are only exemplary, and in practice, there may be deviations due to manufacturing tolerances or technical limitations, and those skilled in the art should Regions/layers with different shapes, sizes, relative positions can be additionally designed as desired.
在本公开的上下文中,当将一层/元件称作位于另一层/元件“上”时,该层/元件可以直接位于该另一层/元件上,或者它们之间可以存在居中层/元件。另外,如果在一种朝向中一层/元件位于另一层/元件“上”,那么当调转朝向时,该层/元件可以位于该另一层/元件“下”。为了使本发明所要解决的技术问题、技术方案及有益效果更加清楚明白,以下结合附图及实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。In the context of this disclosure, when a layer/element is referred to as being "on" another layer/element, it can be directly on the other layer/element or intervening layers/elements may be present therebetween. element. In addition, if a layer/element is "on" another layer/element in one orientation, then when the orientation is reversed, the layer/element can be "under" the other layer/element. In order to make the technical problems, technical solutions and beneficial effects to be solved by the present invention clearer, the present invention will be further described in detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are only used to explain the present invention, but not to limit the present invention.
此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本发明的描述中,“多个”的含义是两个或两个以上,除非另有明确具体的限定。“若干”的含义是一个或一个以上,除非另有明确具体的限定。In addition, the terms "first" and "second" are only used for descriptive purposes, and should not be construed as indicating or implying relative importance or implying the number of indicated technical features. Thus, a feature defined as "first" or "second" may expressly or implicitly include one or more of that feature. In the description of the present invention, "plurality" means two or more, unless otherwise expressly and specifically defined. "Several" means one or more than one, unless expressly specifically defined otherwise.
在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should be noted that the terms "installed", "connected" and "connected" should be understood in a broad sense, unless otherwise expressly specified and limited, for example, it may be a fixed connection or a detachable connection Connection, or integral connection; may be mechanical connection or electrical connection; may be direct connection or indirect connection through an intermediate medium, may be internal communication between two elements or an interaction relationship between the two elements. For those of ordinary skill in the art, the specific meanings of the above terms in the present invention can be understood according to specific situations.
电沉积金结构具有优良的电学特性、强抗腐蚀能力、化学和光学特性,被广泛应用于集成电路、生物传感、电子通讯和航空航天等领域。电沉积金结构可以分为硬金结构和软金结构。Electrodeposited gold structures have excellent electrical properties, strong corrosion resistance, chemical and optical properties, and are widely used in integrated circuits, biosensing, electronic communications, and aerospace. Electrodeposited gold structures can be divided into hard gold structures and soft gold structures.
硬金结构通常添加了铁、钴、镍等金属来增加金结构的机械性能,在电学互联和PCB板等方面得到应用。The hard gold structure usually adds iron, cobalt, nickel and other metals to increase the mechanical properties of the gold structure, and is used in electrical interconnection and PCB boards.
软金结构纯度较高,信号保真度高成为集成电路的互联、封装、MEMS、X射线光学元件等是一种不可替代的部分。软金结构的电阻特性会直接影响到信号的传输效率,所以电沉积金结构电阻的测量变得尤为重要。但由于金材料的电阻率低,导致了电沉积金结构的电阻特性灵敏度高,受测量环境影响大,测量困难;在科研领域中,最为常用的测量电沉积金结构电阻的方法是采用探针台进行四探针测量,但是这种方法对电沉积金结构的粗糙度要求极高,并且探针与电沉积金结构的接触面积也会导致测量结果的不稳定,这些因素都会严重影响测量结果的准确性,导致这个方法在测量小尺度器件电阻的可信度降低。Soft gold structure has high purity and high signal fidelity, and it has become an irreplaceable part of integrated circuit interconnection, packaging, MEMS, X-ray optical components, etc. The resistance characteristics of the soft gold structure will directly affect the transmission efficiency of the signal, so the measurement of the resistance of the electrodeposited gold structure becomes particularly important. However, due to the low resistivity of gold materials, the resistance characteristics of electrodeposited gold structures are highly sensitive, greatly affected by the measurement environment, and difficult to measure. In the field of scientific research, the most commonly used method to measure the resistance of electrodeposited gold structures is to use a probe However, this method has extremely high requirements on the roughness of the electrodeposited gold structure, and the contact area between the probe and the electrodeposited gold structure will also lead to unstable measurement results. These factors will seriously affect the measurement results. The accuracy of this method reduces the reliability of this method in measuring the resistance of small-scale devices.
基于此,本发明实施例提出一种结合生物传感领域常用的叉指电极,来对电沉积金结构电阻特性进行分析。图1示出了一种叉指电极的结构示意图。如图1所示,叉指电极是一种生物传感领域常用的叉指状微型电极,具有特异性好,生物保真度高,灵敏度高和检测速度快等优点。在生物检测、环境监测和食品安全等领域有着重要的作用和广阔的应用前景。在叉指电极的工作区域滴上不同浓度的检测溶液来检测其频率-阻抗的变化,从而来对叉指电极的电阻进行检测。其中,检测溶液可以为去离子水。图2示出了一种测量叉指电极电阻的示意图。如图2所示,201为叉指电极,202为去离子水。滴入去离子水202后,叉指电极201的等效电路图如图3。其中,Rs为叉指电极的等效电阻,Cdl和Cdi为叉指电极的等效电容。Based on this, the embodiment of the present invention proposes an interdigital electrode commonly used in the field of biosensing to analyze the resistance characteristics of the electrodeposited gold structure. Figure 1 shows a schematic structural diagram of an interdigital electrode. As shown in Figure 1, the interdigitated electrode is a commonly used interdigitated microelectrode in the field of biosensing, which has the advantages of good specificity, high biological fidelity, high sensitivity and fast detection speed. It has an important role and broad application prospects in the fields of biological detection, environmental monitoring and food safety. Different concentrations of detection solutions are dropped on the working area of the interdigital electrode to detect the change of its frequency-impedance, so as to detect the resistance of the interdigital electrode. Wherein, the detection solution can be deionized water. FIG. 2 shows a schematic diagram of measuring the resistance of interdigital electrodes. As shown in Figure 2, 201 is an interdigital electrode, and 202 is deionized water. After the
图4示出了本发明实施例提供的一种电沉积金结构的电阻特性分析方法,如图4所示,该电沉积金结构的电阻特性分析方法包括以下步骤:FIG. 4 shows a method for analyzing resistance characteristics of an electrodeposited gold structure provided by an embodiment of the present invention. As shown in FIG. 4 , the method for analyzing resistance characteristics of the electrodeposited gold structure includes the following steps:
步骤101,提供多个金叉指电极,多个金叉指电极的电阻相关参数不同。
本发明实施例中,为了提高表征不同电沉积金结构的电阻特性的准确性,提供了多个具有不同电阻相关参数的金叉指电极。本发明实施例在分析金叉指电极的电阻特性时将金叉指电极放置到检测溶液中。相比现有技术,在测量电沉积金结构时,需要将探针与电沉积金结构进行接触,本发明实施例的方法能够提高电阻检测的可信度以及可操作性,且对电沉积金结构本身的结构要求较低。示例性的,上述电阻相关参数可以是金叉指电极的高度和金叉指电极的表面粗糙度。In the embodiment of the present invention, in order to improve the accuracy of characterizing the resistance characteristics of different electrodeposited gold structures, a plurality of gold interdigitated electrodes with different resistance-related parameters are provided. In the embodiment of the present invention, the gold interdigitated electrode is placed in the detection solution when the resistance characteristic of the gold interdigitated electrode is analyzed. Compared with the prior art, when measuring the electrodeposited gold structure, it is necessary to contact the probe with the electrodeposited gold structure. The method of the embodiment of the present invention can improve the reliability and operability of the resistance detection, and has a good effect on the electrodeposited gold structure. The structure itself has lower structural requirements. Exemplarily, the above-mentioned resistance-related parameters may be the height of the gold interdigitated electrode and the surface roughness of the gold interdigitated electrode.
步骤102,利用电化学工作站检测多个金叉指电极在不同的频率正弦电压下的阻抗。
本发明实施例中,图5示出了一种利用电化学工作站对金叉指电极的电阻特性进行分析的示意图。参照图5,在对不同的金叉指电极进行电阻特性分析时,先将该金叉指电极的阴极和阳极与电化学工作站进行电连接,然后将该金叉指电极放置到检测溶液中。再利用该电化学工作站获取具有不同电阻相关参数的多个金叉指电极在不同频率的正弦电压下的频率-阻抗图谱。示例性的,该电化学工作站可以是华晨CHI660E电化学工作站。In the embodiment of the present invention, FIG. 5 shows a schematic diagram of analyzing the resistance characteristics of gold interdigitated electrodes by using an electrochemical workstation. Referring to FIG. 5 , when analyzing the resistance characteristics of different gold interdigitated electrodes, the cathode and anode of the gold interdigitated electrodes are first electrically connected to the electrochemical workstation, and then the gold interdigitated electrodes are placed in the detection solution. The electrochemical workstation is then used to obtain frequency-impedance maps of multiple gold interdigitated electrodes with different resistance-related parameters under sinusoidal voltages of different frequencies. Exemplarily, the electrochemical workstation can be a Brilliance CHI660E electrochemical workstation.
步骤103,根据多个电沉积金结构在不同频率的正弦电压下的阻抗分析电沉积金结构的电阻特性。
本发明实施例中,通过具有不同电阻相关参数的多个金叉指电极在不同频率的正弦电压下的频率-阻抗图谱,对电沉积金结构的电阻特性进行分析。本发明实施例电沉积金结构的电阻特性分析方法的整个过程能够避免由于接触性测量对实际结果造成的改变,更为精确、直接的表征电沉积金结构本身的电阻特性。In the embodiment of the present invention, the resistance characteristics of the electrodeposited gold structure are analyzed by frequency-impedance spectra of a plurality of gold interdigitated electrodes with different resistance-related parameters under sinusoidal voltages of different frequencies. The whole process of the method for analyzing the resistance characteristics of the electrodeposited gold structure in the embodiment of the present invention can avoid the change of the actual results caused by the contact measurement, and more accurately and directly characterize the resistance characteristics of the electrodeposited gold structure itself.
示例性的,上述提供多个金叉指电极可以包括以下步骤:Exemplarily, the above-mentioned providing a plurality of gold interdigitated electrodes may include the following steps:
步骤1011,提供多个金叉指状种子。提供多个金叉指状种子可以包括:提供衬底;在衬底上形成金种子层;对金种子层进行图形化处理,获得金叉指状种子。具体的,该衬底可以为SiO2衬底。在衬底上形成金种子层可以是:在SiO2衬底上通过电子束蒸发制备金种子层。对金种子层进行图形化处理,获得金叉指状种子可以是,对金种子层进行光刻,获得叉指状电镀区域图形,该叉指状电镀区域图形即为金叉指状种子。可以理解,也可以利用其它方法对金种子层进行图形化处理,本发明实施例对此不作限定。在得到金叉指状种子后,本发明实施例还包括对金叉指状种子表面残余的光刻胶进行刻蚀。Step 1011, providing a plurality of golden interdigitated seeds. Providing a plurality of gold interdigitated seeds may include: providing a substrate; forming a gold seed layer on the substrate; and patterning the gold seed layer to obtain gold interdigitated seeds. Specifically, the substrate may be a SiO 2 substrate. Forming the gold seed layer on the substrate may be: preparing the gold seed layer by electron beam evaporation on a SiO 2 substrate. The gold seed layer is patterned to obtain gold interdigitated seeds, which can be obtained by photolithography on the gold seed layer to obtain an interdigitated electroplating area pattern, which is the gold interdigitated seed. It can be understood that other methods may also be used to perform patterning processing on the gold seed layer, which is not limited in this embodiment of the present invention. After obtaining the gold interdigitated seeds, the embodiment of the present invention further includes etching the residual photoresist on the surface of the gold interdigitated seeds.
作为一种具体的示例,对金种子层进行光刻,获得叉指状电镀区域图形可以为:在金种子层上旋涂1.5微米厚的NR1500光刻胶并以120℃前烘2min,采用UV接触式光刻机进行曝光,150℃进行坚膜,随后显影40s,获得叉指电极的待电镀图形,示例性的,根据实际的需求,待电镀图形的电镀区域面积可以为0.25cm2,辅助电镀区域2cm2。As a specific example, performing photolithography on the gold seed layer to obtain an interdigitated electroplating area pattern may be: spin-coating a 1.5-micron-thick NR1500 photoresist on the gold seed layer and pre-baking at 120°C for 2 minutes, using UV Exposure with a contact lithography machine, harden the film at 150° C., and then develop for 40 s to obtain the to-be-plated pattern of the interdigital electrode. Exemplarily, according to actual requirements, the area of the electro-plated area of the to-be-plated pattern can be 0.25 cm 2 . Electroplating area 2cm 2 .
步骤1012,利用电化学沉积法在不同的多个电沉积参数的控制下对多个叉指状种子一一对应的进行处理,获得多个金叉指电极。示例性的,该电化学沉积法可以为电镀法,该电沉积参数可以为电沉积时间、正向脉冲电流和反向刻蚀电流。Step 1012 , using an electrochemical deposition method to process a plurality of interdigitated seeds in a one-to-one correspondence under the control of a plurality of different electrodeposition parameters to obtain a plurality of gold interdigitated electrodes. Exemplarily, the electrochemical deposition method may be an electroplating method, and the electrodeposition parameters may be electrodeposition time, forward pulse current and reverse etching current.
作为一种具体的示例,利用电镀法对叉指状种子进行处理,获得金叉指电极的过程可以为:采用交直流源表提供正向脉冲电镀电流和反向刻蚀电流。该正向脉冲电镀电流用于在阴极表面进行离子的放电和金属的沉积;该反向刻蚀电流用于刻蚀掉电沉积期间表面形成的尖锐凸起,并使刻蚀掉的离子运动到扩散层中来补充金离子浓度,进而改变金结构微观形貌。As a specific example, the process of using the electroplating method to process the interdigitated seeds to obtain gold interdigitated electrodes can be as follows: using an AC and DC source meter to provide a forward pulse plating current and a reverse etching current. The forward pulsed electroplating current is used for ion discharge and metal deposition on the cathode surface; the reverse etching current is used to etch away sharp protrusions formed on the surface during electrodeposition, and move the etched ions to The concentration of gold ions is supplemented in the diffusion layer, thereby changing the microscopic morphology of the gold structure.
本发明实施例中,金叉指电极电阻相关参数为金叉指电极的高度和金叉指电极的表面粗糙度。可以通过不同的电镀时间来获得不同高度的金叉指电极。可以通过不同的反向刻蚀电流来获得不同表面粗糙度的金叉指电极。制备不同电阻相关参数的金叉指电极时可以采用相同的正向脉冲电镀电流。例如,正向脉冲电镀电流20mA,脉冲宽度为2ms。In the embodiment of the present invention, the parameters related to the resistance of the gold interdigitated electrode are the height of the gold interdigitated electrode and the surface roughness of the gold interdigitated electrode. Gold interdigitated electrodes with different heights can be obtained by different plating times. Gold interdigitated electrodes with different surface roughness can be obtained by different reverse etching currents. The same forward pulse plating current can be used to prepare gold interdigitated electrodes with different resistance-related parameters. For example, the forward pulse plating current is 20mA, and the pulse width is 2ms.
作为一种具体的示例,为了获得具有不同高度的金叉指电极,电镀时间可以为5min、8min、10min或15min。此时,可以采用定时器控制电镀时间,由此可以控制电镀厚度,达到所需电镀厚度时,取出阴极电镀件。As a specific example, in order to obtain gold interdigitated electrodes with different heights, the plating time may be 5 min, 8 min, 10 min or 15 min. At this time, a timer can be used to control the electroplating time, so that the electroplating thickness can be controlled, and when the required electroplating thickness is reached, the cathode electroplating parts are taken out.
为了获得不同表面粗糙度的金叉指电极,可以通过设置不同的反向刻蚀电流的大小来实现。反向刻蚀电流能够改变刻蚀效率,使刻蚀掉的金离子重新补充到扩散层中来进行再分布。基于此,可以改善金结构的填充质量,从而改变金叉指电极的表面粗糙度。In order to obtain gold interdigitated electrodes with different surface roughness, it can be achieved by setting different magnitudes of reverse etching currents. The reverse etching current can change the etching efficiency and make the etched gold ions replenish into the diffusion layer for redistribution. Based on this, the filling quality of the gold structure can be improved, thereby changing the surface roughness of the gold interdigitated electrode.
示例性的,本发明实施例在取出电镀件后,还可以采用干法刻蚀和湿法清洗去除衬底上的光刻胶,完成电镀实验,得到多个金叉指电极。Exemplarily, after the electroplating parts are taken out in the embodiment of the present invention, dry etching and wet cleaning may be used to remove the photoresist on the substrate to complete the electroplating experiment and obtain a plurality of gold interdigitated electrodes.
为了不影响后续利用电化学工作站对不同金叉指电极电阻特性测量的准确定,以及防止电叉指电极本身的短路问题,在得到多个金叉指电极之后,还可以采用离子束刻蚀掉金叉指电极表面上多余的金种子层。In order not to affect the subsequent accurate determination of the resistance characteristics of different gold interdigitated electrodes by the electrochemical workstation, and to prevent the short circuit problem of the electrical interdigitated electrodes themselves, after obtaining multiple gold interdigitated electrodes, ion beam etching can be used to remove them. The excess gold seed layer on the surface of the gold interdigitated electrode.
可以理解,为了使后续工艺兼容性较好,对环境友好,降低电镀液生产和后处理的难度,电镀液可以采用中性的金的无机盐溶液。例如,亚硫酸金盐电镀液。此时,电镀液pH值为6.5-7.5,呈酸碱中性。为了提高电镀层的质量,在电镀前,可以先将电镀槽中的中性的亚硫酸金盐电镀液用恒温水浴加热至40℃,并以200r/min的转速搅拌半小时使离子在镀液中更均匀的扩散。在电镀过程中,将显影后的金叉指状种子放入电镀槽中作为阴极,阳极采用20cm×10cm的镀3微米厚的矩形铂金的钛网,阳极与阴极的距离为8cm。It can be understood that, in order to make the subsequent process better compatible, environmentally friendly, and reduce the difficulty of production and post-processing of the electroplating solution, the electroplating solution can use a neutral gold inorganic salt solution. For example, gold sulfite plating baths. At this time, the pH value of the electroplating solution is 6.5-7.5, which is neutral in acid and alkali. In order to improve the quality of the electroplating layer, before electroplating, the neutral gold sulfite electroplating solution in the electroplating tank can be heated to 40 ℃ with a constant temperature water bath, and stirred at a speed of 200r/min for half an hour to make the ions in the plating solution for a more uniform diffusion. During the electroplating process, the developed gold interdigitated seeds were placed in the electroplating tank as the cathode, and the anode was a 20cm×10cm rectangular platinum-plated titanium mesh with a thickness of 3 μm, and the distance between the anode and the cathode was 8cm.
作为一种具体的示例,本发明实施例利用不同的反向刻蚀电流来刻蚀掉金叉指电极在沉积过程中形成的锐利的纳米晶粒结构,进而改变所沉积的金叉指电极的微观结构。由于微观结构的改变,金叉指电极的电阻也会发生改变。As a specific example, the embodiment of the present invention uses different reverse etching currents to etch away the sharp nano-grain structure formed by the gold interdigitated electrode during the deposition process, thereby changing the deposited gold interdigitated electrode. micro structure. As the microstructure changes, the resistance of the gold interdigitated electrode also changes.
示例性的,参照图6,示出了不同反向刻蚀电流下得到的不同金叉指电极结构的电镜图。其中,图6(a)示出了在0mA反向刻蚀电流下得到的金叉指电极结构的电镜图;图6(b)示出了在0.4mA反向刻蚀电流下得到的金叉指电极结构的电镜图;图6(c)示出了在1.4mA反向刻蚀电流下得到的金叉指电极结构的电镜图;图6(d)示出了在2.0mA反向刻蚀电流下得到的金叉指电极结构的电镜图。可以看出,不同的反向刻蚀电流下获得的金叉指电极的微观结构不同。Exemplarily, referring to FIG. 6 , electron microscope images of different gold interdigitated electrode structures obtained under different reverse etching currents are shown. Among them, Figure 6(a) shows the electron microscope image of the gold interdigitated electrode structure obtained under the reverse etching current of 0mA; Figure 6(b) shows the gold fork obtained under the reverse etching current of 0.4mA Electron microscope image of the finger electrode structure; Figure 6(c) shows the electron microscope image of the gold interdigitated electrode structure obtained under the reverse etching current of 1.4mA; Figure 6(d) shows the reverse etching at 2.0mA. Electron microscope image of the gold interdigitated electrode structure obtained under current. It can be seen that the microstructures of the gold interdigitated electrodes obtained under different reverse etching currents are different.
利用电化学工作站检测图6所示的4种金叉指电极在不同的频率正弦电压下的阻抗。其中,电化学工作站提供的正弦电压的频率范围为100Hz到500kHz,正弦电压的振幅为5mV,直流偏压为0V。The impedance of the four gold interdigitated electrodes shown in Fig. 6 under different frequency sinusoidal voltages was detected by an electrochemical workstation. Among them, the frequency range of the sinusoidal voltage provided by the electrochemical workstation is 100 Hz to 500 kHz, the amplitude of the sinusoidal voltage is 5 mV, and the DC bias voltage is 0 V.
图7示出了不同反向刻蚀电流制备金结构的频率-阻抗图。其中,曲线1为不同频率下金叉指电极阻抗的相位分布曲线图;曲线2为利用大小为1.4A的反向刻蚀电流制备的高度为300nm的金叉指电极在不同频率下的频率-阻抗曲线;曲线3为利用大小为2A的反向刻蚀电流制备的高度为100nm的金叉指电极在不同频率下的频率-阻抗曲线;曲线4为利用大小为0.4A的反向刻蚀电流制备的高度为300nm的金叉指电极在不同频率下的频率-阻抗曲线;曲线5为利用大小为0A的反向刻蚀电流制备的高度为300nm的金叉指电极在不同频率下的频率-阻抗曲线。Figure 7 shows frequency-impedance plots of gold structures fabricated with different reverse etch currents. Among them, curve 1 is the phase distribution curve of the impedance of the gold interdigitated electrode at different frequencies; curve 2 is the frequency of the gold interdigitated electrode with a height of 300nm prepared by using a reverse etching current of 1.4A at different frequencies- Impedance curves; curve 3 is the frequency-impedance curve of gold interdigitated electrodes with a height of 100nm prepared by using a reverse etching current of 2A at different frequencies;
图7中曲线2、曲线4和曲线5分别为利用不同的反向刻蚀电流获得的金叉指电极的频率-阻抗曲线。其中,曲线5中的反向刻蚀电流最小,曲线2中的反向刻蚀电流最大。随着不同反向电流的变化,刻蚀与钝化作用的交替影响,金叉指电极的微观结构呈准单晶-单晶-准单晶-多晶的变化趋势。从图7中可以得到,在0和1.4mA的反向电流下,准单晶结构中镶嵌着众多的缺陷影响着电子的传输,导致它们电阻大于0.4mA反向电流下制备的金结构的电阻。虽然多晶金结构的高度较低,但由于结构中的晶界会严重阻碍电子的传输,导致金结构电阻较大。Curve 2,
从图7中可以看出,曲线3所表示的金叉指电极的在中频区的电阻最大。曲线3所表示的金叉指电极的高度为100nm,其他曲线所表示的金叉指电极的高度均为300nm,故可以基本得出,金叉指电极的高度与金叉指电极的电阻成反比。It can be seen from FIG. 7 that the gold interdigitated electrode represented by curve 3 has the largest resistance in the intermediate frequency region. The height of the gold interdigitated electrode represented by curve 3 is 100 nm, and the height of the gold interdigitated electrode represented by other curves is 300 nm, so it can be basically concluded that the height of the gold interdigitated electrode is inversely proportional to the resistance of the gold interdigitated electrode .
图8示出了不同厚度金叉指电极的频率-阻抗图。其中,曲线6为不同频率下金叉指电极阻抗的相位分布曲线图;曲线7为利用大小为0.4A的反向刻蚀电流制备的厚度为300nm的金叉指电极在不同频率下的频率-阻抗曲线;曲线8为利用大小为0.4A的反向刻蚀电流制备的厚度为700nm的金叉指电极在不同频率下的频率-阻抗曲线。通过图8可以看出,在纳米尺度下的金叉指电极的厚度改变对电阻的影响可忽略不计。Figure 8 shows frequency-impedance plots of gold interdigitated electrodes of different thicknesses. Among them, curve 6 is the phase distribution curve of the impedance of the gold interdigitated electrode at different frequencies; curve 7 is the frequency of the gold interdigitated electrode with a thickness of 300nm prepared by using a reverse etching current of 0.4A at different frequencies- Impedance curve;
参照图7和图8,随着测量频率的变化,叉指电极的阻抗主要分为三种状态,双层电容器、结构电阻和介质电容器,分别对应于183Hz到1kHz的低频区、1kHz到50kHz的中频区和50kHz到500kHz的高频区。结合对应的相位曲线分析,在中频区,相应的相位曲线的相位角十分接近0度,可忽略电容特性,即为纯电阻电路。可见,叉指电极中频区的阻抗值的变化几乎等同于结构电阻的变化。Referring to Figure 7 and Figure 8, with the change of the measurement frequency, the impedance of the interdigital electrode is mainly divided into three states, the double-layer capacitor, the structural resistance and the dielectric capacitor, which correspond to the low-frequency region of 183Hz to 1kHz and the low-frequency region of 1kHz to 50kHz, respectively. Mid-frequency region and high frequency region from 50kHz to 500kHz. Combined with the analysis of the corresponding phase curve, in the intermediate frequency region, the phase angle of the corresponding phase curve is very close to 0 degrees, and the capacitance characteristics can be ignored, which is a pure resistance circuit. It can be seen that the change of the impedance value in the intermediate frequency region of the interdigital electrode is almost equal to the change of the structural resistance.
在实际的应用中,利用上述结论,若需要对电沉积金结构进行电阻测量,可以将该电沉积金结构与电化学工作站进行连接。并利用电化学工作站向该电沉积金结构施加中频的正弦电压,从该电化学工作站中获取在中频正弦电压下,该电沉积金结构的阻抗,该阻抗就是该电沉积金结构的电阻。In practical applications, using the above conclusions, if resistance measurement of the electrodeposited gold structure is required, the electrodeposited gold structure can be connected to an electrochemical workstation. The electrochemical workstation is used to apply an intermediate frequency sinusoidal voltage to the electrodeposited gold structure, and the impedance of the electrodeposited gold structure under the intermediate frequency sinusoidal voltage is obtained from the electrochemical workstation, and the impedance is the resistance of the electrodeposited gold structure.
在以上的描述中,对于各层的构图、刻蚀等技术细节并没有做出详细的说明。但是本领域技术人员应当理解,可以通过各种技术手段,来形成所需形状的层、区域等。另外,为了形成同一结构,本领域技术人员还可以设计出与以上描述的方法并不完全相同的方法。另外,尽管在以上分别描述了各实施例,但是这并不意味着各个实施例中的措施不能有利地结合使用。In the above description, technical details such as patterning and etching of each layer are not described in detail. However, those skilled in the art should understand that various technical means can be used to form layers, regions, etc. of desired shapes. In addition, in order to form the same structure, those skilled in the art can also design methods that are not exactly the same as those described above. Additionally, although the various embodiments have been described above separately, this does not mean that the measures in the various embodiments cannot be used in combination to advantage.
以上对本公开的实施例进行了描述。但是,这些实施例仅仅是为了说明的目的,而并非为了限制本公开的范围。本公开的范围由所附权利要求及其等价物限定。不脱离本公开的范围,本领域技术人员可以做出多种替代和修改,这些替代和修改都应落在本公开的范围之内。Embodiments of the present disclosure have been described above. However, these examples are for illustrative purposes only, and are not intended to limit the scope of the present disclosure. The scope of the present disclosure is defined by the appended claims and their equivalents. Without departing from the scope of the present disclosure, those skilled in the art can make various substitutions and modifications, and these substitutions and modifications should all fall within the scope of the present disclosure.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4425197A (en) * | 1981-08-19 | 1984-01-10 | Inoue-Japax Research Incorporated | Method of and apparatus for electrodepositing a metal on a conductive surface |
| CN106047678A (en) * | 2016-05-20 | 2016-10-26 | 江苏大学 | Cell activity detection method and device based on impedance spectroscopy |
| CN108922791A (en) * | 2018-06-01 | 2018-11-30 | 中国科学院上海硅酸盐研究所 | A kind of interdigital electrode and its preparation method and application with nanometer texture surface |
| CN109809359A (en) * | 2019-01-10 | 2019-05-28 | 北方工业大学 | A 2.5D interdigital electrode fabrication method and interdigital electrode |
-
2020
- 2020-05-29 CN CN202010482069.8A patent/CN111596135A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4425197A (en) * | 1981-08-19 | 1984-01-10 | Inoue-Japax Research Incorporated | Method of and apparatus for electrodepositing a metal on a conductive surface |
| CN106047678A (en) * | 2016-05-20 | 2016-10-26 | 江苏大学 | Cell activity detection method and device based on impedance spectroscopy |
| CN108922791A (en) * | 2018-06-01 | 2018-11-30 | 中国科学院上海硅酸盐研究所 | A kind of interdigital electrode and its preparation method and application with nanometer texture surface |
| CN109809359A (en) * | 2019-01-10 | 2019-05-28 | 北方工业大学 | A 2.5D interdigital electrode fabrication method and interdigital electrode |
Non-Patent Citations (1)
| Title |
|---|
| 汪懋华: "《汪懋华文集》", 30 November 2012 * |
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