[go: up one dir, main page]

CN111519436B - 一种添加有石墨烯的服装面料生产工艺 - Google Patents

一种添加有石墨烯的服装面料生产工艺 Download PDF

Info

Publication number
CN111519436B
CN111519436B CN202010213596.9A CN202010213596A CN111519436B CN 111519436 B CN111519436 B CN 111519436B CN 202010213596 A CN202010213596 A CN 202010213596A CN 111519436 B CN111519436 B CN 111519436B
Authority
CN
China
Prior art keywords
raw materials
graphene
fiber raw
synthetic fiber
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN202010213596.9A
Other languages
English (en)
Other versions
CN111519436A (zh
Inventor
任礼新
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Clarence Technology Co ltd
Original Assignee
Hefei Clarence Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Clarence Technology Co ltd filed Critical Hefei Clarence Technology Co ltd
Priority to CN202010213596.9A priority Critical patent/CN111519436B/zh
Publication of CN111519436A publication Critical patent/CN111519436A/zh
Application granted granted Critical
Publication of CN111519436B publication Critical patent/CN111519436B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01G—PRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
    • D01G13/00—Mixing, e.g. blending, fibres; Mixing non-fibrous materials with fibres
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24—Viscose
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

本发明公开了一种添加有石墨烯的服装面料生产工艺，使用合成纤维原料和胶粘纤维原料为原材料，经和毛、开松、混合、梳绒得到生条，然后将生条使用氯化铜和石墨烯溶液进行浸染，得打浸染生条，然后进行并条、织造，最后，水洗后得到面料，本发明克服了现有技术的不足，使该石墨烯合成纤维面料的耐用性得到了增强。

Description

一种添加有石墨烯的服装面料生产工艺
技术领域
本发明涉及服装面料生产技术领域，具体属于一种添加有石墨烯的服装面料生产工艺。
背景技术
石墨烯是一种二维碳纳米材料，具有优异的光学、电学、力学特性，其中石墨烯的导热系数最高可达5300W/(m•K)。因此，将石墨烯用于服装面料的生产，可显著提高服装面料的导热性能，同时石墨烯也具有润滑能力，应用于服装面料中可提高面料的滑爽和耐磨性，另外，石墨烯还具有一定的抗菌能力，省生产的面料具有抗菌性能。但是，石墨烯与合成纤维面料中的纤维结合能力差，很难复合到合成纤维上，且水洗后石墨烯容易脱落，使石墨烯合成纤维面料的耐用性较低。
发明内容
本发明的目的是提供一种添加有石墨烯的服装面料生产工艺，提高石墨烯与合成纤维的结合强度，提高石墨烯合成纤维面料的耐用性。
为解决上述问题，本发明所采取的技术方案如下：
一种添加有石墨烯的服装面料生产工艺，包括以下步骤：
(1)和毛，将合成纤维原料和粘胶纤维原料分别进行和毛，其中合成纤维原料在和毛的过程中加入和毛工艺油A，粘胶纤维原料在和毛的过程中加入和毛工艺油B；
(2)开松，将和毛后的合成纤维原料和粘胶纤维原料分别进行开松；
(3)混合，将开松后的合成纤维原料和粘胶纤维原料按质量比90-80:10-20进行混合，形成混合原料；
(4)梳绒，将混合原料使用梳绒机进行梳绒；
(5)浸染，将生条浸入含8wt%的氯化铜溶液中15分钟，然后浸入石墨烯溶液中2-3小时，然后取出80℃干燥8小时，得到浸染生条；
(6)并条，采用二道并合方式对浸染生条进行并条，每道6根条子喂入，并条后进行整经；
(7)织造，将熟条进行织造，水洗后得到面料。
优选地，所述的和毛工艺油A包括和毛油 AL106 1.2wt%、聚乙烯吡咯烷酮0.4wt%、端羧基聚乙二醇3.6wt%、锭子油16%、其余为水；所述的和毛工艺油B为端羧基聚乙二醇4.3wt%、司班-80 3.0wt%、其余为硅胶。
优选地，所述的石墨烯溶液含有13%的石墨烯、7%的纤维素酶、其余为水，其中，石墨烯溶液的pH=6.5，温度为40℃。
优选地，所述的步骤(4)中梳绒时锡林速度为300r/min，刺辊速度为700r/min，道夫速度为23r/min，生条定量为32g/5m。
优选地，所述的步骤(6)中出条速度80-85m/min，熟条条干CV值4.0-4.5％。
优选地，所述的合成纤维原料为涤纶原料或锦纶原料。
本发明与现有技术相比较，本发明的实施效果如下：本发明的生产工艺中，在和毛的过程中加入聚乙烯吡咯烷酮和端羧基聚乙二醇为抗静电剂，使聚乙烯吡咯烷酮和端羧基聚乙二醇与合成纤维原料混合均匀，合成纤维的表面能均匀的锚固聚乙烯吡咯烷酮分子；而浸染的过程中氯化铜与聚乙烯吡咯烷酮和端羧基聚乙二醇进行络合，同时部分氯化铜浸入粘胶纤维原料的内部，使生条上吸附和稳定络合上氯化铜；然后在生条浸入石墨烯溶液后，石墨烯表面的羧基和羟基与聚乙烯吡咯烷酮和端羧基聚乙二醇上的氯化铜进行配位络合，使石墨烯均匀的吸附在生条上，聚乙烯吡咯烷酮和端羧基聚乙二醇在合成纤维原料上起到了对石墨烯的锚定作用；而由于生条在石墨烯溶液中浸泡时间较长，使粘胶纤维中浸入纤维素酶，纤维素酶催化分解部分粘胶纤维，使合成纤维原料之间结构蓬松度增加，使石墨烯片可进入合成纤维原料之间，然后经水洗、干燥、并条后，石墨烯在合成纤维原料上的结合强度得到进一步增强，使该石墨烯合成纤维面料的耐用性得到了增强。
具体实施方式
下面对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
本发明的原料中的石墨烯采用河南六工石墨有限公司LG-1410纳米石墨烯，和毛油 AL106采用杭州富阳富春江化学制品有限公司的产品。
实施例1
添加有石墨烯的服装面料生产工艺，包括以下步骤：将涤纶原料中加入和毛工艺油A，和毛工艺油A包括和毛油 AL106 1.2wt%、聚乙烯吡咯烷酮0.4wt%、端羧基聚乙二醇3.6wt%、锭子油16%、其余为水；将粘胶纤维原料中加入和毛工艺油B，和毛工艺油B为端羧基聚乙二醇4.3wt%、司班-803.0wt%、其余为硅胶；然后，分别进行和毛。和毛完成后，将和毛后的涤纶原料和粘胶纤维原料分别进行开松；然后，将开松后的涤纶原料和粘胶纤维原料按质量比90:10进行混合，形成混合原料。
将混合原料使用梳绒机进行梳绒，梳绒时锡林速度为300r/min，刺辊速度为700r/min，道夫速度为23r/min，生条定量为32g/5m；将得到的生条浸入含8wt%的氯化铜溶液中15分钟，然后浸入石墨烯溶液中2小时，石墨烯溶液含有13%的石墨烯、7%的纤维素酶、其余为水，其中，石墨烯溶液的pH=6.5，温度为40℃，然后取出80℃干燥8小时，得到浸染生条。
采用二道并合方式对浸染生条进行并条，每道6根条子喂入，出条速度80-85m/min，熟条条干CV值4.0-4.5％，并条后进行整经；最后，对熟条进行织造，水洗后得到面料。
实施例2
添加有石墨烯的服装面料生产工艺，包括以下步骤：将锦纶原料中加入和毛工艺油A，和毛工艺油A包括和毛油 AL106 1.2wt%、聚乙烯吡咯烷酮0.4wt%、端羧基聚乙二醇3.6wt%、锭子油16%、其余为水；将粘胶纤维原料中加入和毛工艺油B，和毛工艺油B为端羧基聚乙二醇4.3wt%、司班-803.0wt%、其余为硅胶；然后，分别进行和毛。和毛完成后，将和毛后的锦纶原料和粘胶纤维原料分别进行开松；然后，将开松后的锦纶原料和粘胶纤维原料按质量比85:15进行混合，形成混合原料。
将混合原料使用梳绒机进行梳绒，梳绒时锡林速度为300r/min，刺辊速度为700r/min，道夫速度为23r/min，生条定量为32g/5m；将得到的生条浸入含8wt%的氯化铜溶液中15分钟，然后浸入石墨烯溶液中3小时，石墨烯溶液含有13%的石墨烯、7%的纤维素酶、其余为水，其中，石墨烯溶液的pH=6.5，温度为40℃，然后取出80℃干燥8小时，得到浸染生条。
采用二道并合方式对浸染生条进行并条，每道6根条子喂入，出条速度80-85m/min，熟条条干CV值4.0-4.5％，并条后进行整经；最后，对熟条进行织造，水洗后得到面料。
对照例1
与实施例1的不同在于，和毛工艺油A中无聚乙烯吡咯烷酮。
对照例2
与实施例1的不同在于，将生条浸入含0wt%的氯化铜溶液中15分钟，然后浸入石墨烯溶液中2-3小时。
对照例3
与实施例1的不同在于，石墨烯溶液中无纤维素酶。
将实施例1-2和对照例1-3中的面料利用TC3000热线法导热系数仪测试导热系数，结果如下表：
导热系数的大小代表了面料上石墨烯的负载量，负载量越多，面料的导热系数越大。由上表可知，聚乙烯吡咯烷酮在合成纤维原料上的锚定作用，有效的提高了生条对石墨烯的吸附能力和面料上石墨烯的稳定性，而氯化铜与聚乙烯吡咯烷酮的配合作用进一步提高了生条上石墨烯的负载量，而纤维素酶与生条内粘胶纤维原料的结合，使生条上负载的石墨烯的牢固程度得到显著提高。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。

Claims (1)

1.一种添加有石墨烯的服装面料生产工艺，其特征在于，包括以下步骤：
(1)和毛，将合成纤维原料和粘胶纤维原料分别进行和毛，其中合成纤维原料在和毛的过程中加入和毛工艺油A，粘胶纤维原料在和毛的过程中加入和毛工艺油B；
(2)开松，将和毛后的合成纤维原料和粘胶纤维原料分别进行开松；
(3)混合，将开松后的合成纤维原料和粘胶纤维原料按质量比90-80:10-20进行混合，形成混合原料；
(4)梳绒，将混合原料使用梳绒机进行梳绒；
(5)浸染，将生条浸入含8wt%的氯化铜溶液中15分钟，然后浸入石墨烯溶液中2-3小时，然后取出80℃干燥8小时，得到浸染生条；
(6)并条，采用二道并合方式对浸染生条进行并条，每道6根条子喂入，并条后进行整经；
(7)织造，将熟条进行织造，水洗后得到面料；
所述的和毛工艺油A包括和毛油 AL106 1.2wt%、聚乙烯吡咯烷酮0.4wt%、端羧基聚乙二醇3.6wt%、锭子油16%、其余为水；所述的和毛工艺油B为端羧基聚乙二醇4.3wt%、司班-803.0wt%、其余为硅胶；
所述的石墨烯溶液含有13%的石墨烯、7%的纤维素酶、其余为水，其中，石墨烯溶液的pH=6.5，温度为40℃；
所述的步骤(4)中梳绒时锡林速度为300r/min，刺辊速度为700r/min，道夫速度为23r/min，生条定量为32g/5m；
所述的步骤(6)中出条速度80-85m/min，熟条条干CV值4.0-4.5％；
所述的合成纤维原料为涤纶原料或锦纶原料；
所述的石墨烯采用河南六工石墨有限公司LG-1410纳米石墨烯。
CN202010213596.9A 2020-03-24 2020-03-24 一种添加有石墨烯的服装面料生产工艺 Expired - Fee Related CN111519436B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010213596.9A CN111519436B (zh) 2020-03-24 2020-03-24 一种添加有石墨烯的服装面料生产工艺

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010213596.9A CN111519436B (zh) 2020-03-24 2020-03-24 一种添加有石墨烯的服装面料生产工艺

Publications (2)

Publication Number Publication Date
CN111519436A CN111519436A (zh) 2020-08-11
CN111519436B true CN111519436B (zh) 2023-10-31

Family

ID=71901037

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010213596.9A Expired - Fee Related CN111519436B (zh) 2020-03-24 2020-03-24 一种添加有石墨烯的服装面料生产工艺

Country Status (1)

Country Link
CN (1) CN111519436B (zh)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114032653B (zh) * 2021-11-26 2024-06-07 义乌市战马服饰有限公司 一种石墨烯变色抗皱面料生产工艺及其牵伸固定装置
CN115491801B (zh) * 2022-11-22 2023-01-13 天津红晨岛服饰有限公司 一种石墨烯、碳纤维、硅胶复合保温纺线及其制备方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103276532A (zh) * 2013-06-19 2013-09-04 南京际华三五二一环保科技有限公司 一种抗静电滤料的制备方法
CN106120333A (zh) * 2016-06-27 2016-11-16 苏州宇希新材料科技有限公司 一种石墨烯/亚麻复合纤维的制备方法
CN106948068A (zh) * 2017-05-09 2017-07-14 南通薇星纺织科技有限公司 一种防静电的面料及其制备方法
CN107503114A (zh) * 2017-08-23 2017-12-22 江苏英瑞世家实业有限公司 一种生物质石墨烯功能牛仔面料的制备方法
CN108081712A (zh) * 2017-11-30 2018-05-29 湖州科博信息科技有限公司 一种低静电性的沙发垫面料
WO2018166477A1 (zh) * 2017-03-15 2018-09-20 山东圣泉新材料股份有限公司 一种改性纤维制品、制备方法及其用途
CN109972385A (zh) * 2019-04-25 2019-07-05 湖南恒信新型建材有限公司 一种竹木纤维的表面处理方法
CN110085349A (zh) * 2019-02-03 2019-08-02 深圳前海皓隆科技有限公司 一种透明石墨烯负载纳米银线防静电膜及其制备方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI596245B (zh) * 2015-10-20 2017-08-21 聚隆纖維股份有限公司 製備石墨烯摻混天然纖維素纖維的方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103276532A (zh) * 2013-06-19 2013-09-04 南京际华三五二一环保科技有限公司 一种抗静电滤料的制备方法
CN106120333A (zh) * 2016-06-27 2016-11-16 苏州宇希新材料科技有限公司 一种石墨烯/亚麻复合纤维的制备方法
WO2018166477A1 (zh) * 2017-03-15 2018-09-20 山东圣泉新材料股份有限公司 一种改性纤维制品、制备方法及其用途
CN106948068A (zh) * 2017-05-09 2017-07-14 南通薇星纺织科技有限公司 一种防静电的面料及其制备方法
CN107503114A (zh) * 2017-08-23 2017-12-22 江苏英瑞世家实业有限公司 一种生物质石墨烯功能牛仔面料的制备方法
CN108081712A (zh) * 2017-11-30 2018-05-29 湖州科博信息科技有限公司 一种低静电性的沙发垫面料
CN110085349A (zh) * 2019-02-03 2019-08-02 深圳前海皓隆科技有限公司 一种透明石墨烯负载纳米银线防静电膜及其制备方法
CN109972385A (zh) * 2019-04-25 2019-07-05 湖南恒信新型建材有限公司 一种竹木纤维的表面处理方法

Also Published As

Publication number Publication date
CN111519436A (zh) 2020-08-11

Similar Documents

Publication Publication Date Title
CN102704262B (zh) 一种制备牛角瓜纤维纯纺纱的方法
CN111519436B (zh) 一种添加有石墨烯的服装面料生产工艺
CN106521744A (zh) 一种还原氧化石墨烯导电弹性复合纱及其制备方法
CN108517571A (zh) 一种导电再生丝素蛋白纳米纤维膜的制备方法
WO2021243941A1 (zh) 抗起球石墨烯混纺纱纤维复合面料及其制造方法
CN106930097A (zh) 一种改性纤维制品、制备方法及其用途
CN105839409A (zh) 一种羊绒针织物的生态型抗起毛起球整理方法
CN115323577A (zh) 一种耐磨抗菌面料及其制备方法
CN104726997A (zh) 一种生物纤维/竹炭纤维/粘胶纤维混纺面料的制作方法
CN111705387A (zh) 一种静电纺纳米纤维/羊毛抗菌纱线的制备方法
CN103061161A (zh) 一种纳米负离子木棉纤维面料的制备方法及其在家纺产品中的应用
CN108467508A (zh) 一种导电再生丝素蛋白膜及其制备方法
CN114959995B (zh) 一种毛涤高支单经单纬面料的制备方法
CN102199821B (zh) 一种芳砜纶混纺纱生产方法
CN107893278A (zh) 一种涤棉防静电a级功能面料
CN108385252A (zh) 一种抗静电面料的生产工艺
CN102677244A (zh) 一种高支高寒动物纤维混纺纱线的生产工艺
CN117818189B (zh) 一种耐磨抗菌防水pu复合面料
CN107043977A (zh) 一种含海藻酸铜纤维的多元组分混纺纱及制备方法
CN102677245B (zh) 一种高支动物纤维混纺纱线
CN1920141A (zh) 中支羽绒混纺纱的生产方法
CN118461306A (zh) 一种异形截面防污复合纱线及其制备方法和应用
CN115637520A (zh) 一种抗静电面料及其加工方法
CN109576844A (zh) 一种抗静电复合羊毛织物的混纺方法
CN114277479A (zh) 一种抗菌壳聚糖纤维混纺纱和抗菌壳聚糖纤维混纺织物

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20231031

CF01 Termination of patent right due to non-payment of annual fee