CN111449069A - 一种海藻酸包膜种衣剂及其制备方法 - Google Patents
一种海藻酸包膜种衣剂及其制备方法 Download PDFInfo
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- 239000011248 coating agent Substances 0.000 title claims abstract description 63
- 229920000615 alginic acid Polymers 0.000 title claims abstract description 44
- 229960001126 alginic acid Drugs 0.000 title claims abstract description 44
- 235000010443 alginic acid Nutrition 0.000 title claims abstract description 44
- 239000000783 alginic acid Substances 0.000 title claims abstract description 44
- 150000004781 alginic acids Chemical class 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title abstract description 11
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
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- PRPINYUDVPFIRX-UHFFFAOYSA-N 1-naphthaleneacetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CC=CC2=C1 PRPINYUDVPFIRX-UHFFFAOYSA-N 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
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- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 claims description 6
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- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims description 5
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- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 claims description 3
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
- A01C1/06—Coating or dressing seed
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N29/00—Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
- A01N29/02—Acyclic compounds or compounds containing halogen attached to an aliphatic side-chain of a cycloaliphatic ring system
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- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
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- A—HUMAN NECESSITIES
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- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
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- A—HUMAN NECESSITIES
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- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/26—Oxidation products of dithiocarbamic acid derivatives, e.g. thiuram sulfides
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
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- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
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Abstract
本发明涉及一种海藻酸包膜种衣剂及其制备方法,包括海藻酸0.5‑3份、黄土80‑95份,保水剂1‑3份、杀虫剂0.1‑0.3份、杀菌剂0.1‑0.3份,生根剂0.1‑0.15份,驱避剂0.05‑0.1份,警戒性染料0.01‑0.05份,余量为水,将海藻酸、黄土、保水剂、杀虫剂、杀菌剂、生根剂、水与种子按照比例添加混合,通过药用包衣锅进行丸化包衣,再添加驱避剂,最后添加警戒性染料进行丸化包衣,本发明的种衣剂具有增强作物抗干旱、寒冷、盐碱等多种抗逆能力,促进植物根系发育,提高种苗成活率,并明显提高作物产量的特点。
Description
技术领域
本发明属于种子包衣剂领域,具体地说涉及一种海藻酸包膜种衣剂及其制 备方法。
背景技术
种子包衣是指利用粘着剂或成膜剂,用特定的种子包衣机,将杀菌剂、杀 虫剂、微肥、植物生长调节剂、着色剂或填充剂等非种子材料,包裹在种子外 面,以达到种子成球形或者基本保持原有形状,提高抗逆性、抗病性,加快发 芽,促进成苗,增加产量,提高质量的一项种子技术。种衣剂能迅速固化成膜, 因而不易脱落。用种衣剂包过的种子播种后,能迅速吸水膨胀。随着种子内胚 胎的逐渐发育以及幼苗的不断生长,种衣剂将含有的各种有效成分缓慢地释放, 被种子幼苗逐步吸收到体内,或缓慢释放到种子附件的土壤中,从而达到防治 苗期病虫害、促进作物生长发育、提高作物产量的目的。种子包衣已被列为我 国重点推广的农业技术项目。
同时,随着我国逐步向海洋进军,海洋中的大量生物逐渐的被人类所认识 并逐渐利用,海藻是海洋中数量巨大的一种植物,其含有的海藻酸具有激植物 体内防御酶系统活性,增强作物抗干旱、寒冷、盐碱等多种抗逆能力;均衡调 节植物生长,促进花芽分化,提高座果率,减少落果、裂果;促进植物根系发 育,提高对土壤养分、水分的吸收利用;增加叶绿素含量,提高光合作用效率, 大幅度提高产量,改善品质。海藻酸对种苗的初期发育和分化具有重要作用, 因此,将海藻酸用作包衣剂的一种成分对种苗初期的生长具有重要作用。
发明内容
针对现有技术的种种不足,现提出一种含有海藻酸的种衣剂,能够有效提 高种子发育初期耐寒抗病抗旱的能力,有效提高种子的成活率,有效保证种苗 的后续生长。
为实现上述目的,本发明提供如下技术方案:
一种海藻酸包膜种衣剂,包括海藻酸0.5-3份、黄土80-95份,保水剂1-3份、 杀虫剂0.1-0.3份、杀菌剂0.1-0.3份、生根剂0.1-0.15份、驱避剂0.05-0.1份、警戒性 染料0.01-0.05份,余量为水。
优选地,所述保水剂包括但不限于吸水树脂。
优选地,所述杀虫剂包括但不限于吡虫啉、三唑磷、灭多威。
优选地,所述杀菌剂包括但不限于50%多菌灵和/或75%的百菌清可湿性粉。
优选地,所述生根剂包括但不限于萘乙酸生根粉。
优选地,所述驱避剂为N,N-二乙基-3-甲基苯甲酰胺、氯乙烯-偏氯乙烯共 聚物、邻苯二甲酸二甲酯、四甲基秋兰姆二硫化物中的任意一种或至少两种的 混合。
优选地,所述警戒性染料包括但不限于胭脂红、酸性大红或玫瑰红。
另,本发明还提供一种海藻酸包膜种衣剂的制备方法,将海藻酸、黄土、 保水剂、杀虫剂、杀菌剂,生根剂、水与种子按照比例添加混合,通过药用包 衣锅进行丸化包衣,再添加驱避剂,最后添加警戒性染料进行丸化包衣。
本发明的有益效果是:
1、海藻酸能够刺激植物体内防御酶系统活性,增强作物抗干旱、寒冷、盐 碱等多种抗逆能力,促进植物根系发育,提高对土壤养分、水分的吸收利用, 有效提高种子的成活率。
2、本发明包含杀虫剂和杀菌剂能够防止害虫危害幼苗或土壤中的种子,并 有效的防止病菌侵害,保证种苗成长,提高作物产量。
3、本发明制得的种子,在种衣的外层包覆有驱避剂或警戒性染料,能够有 效的防止鸟类的破坏。
具体实施方式
下面将结合本发明实施例,对本发明实施例中的技术方案进行清楚、完整地 描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施 例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提 下所获得的所有其他实施例,都属于本发明保护的范围。
实施例一
一种海藻酸包膜种衣剂,包括海藻酸0.5份、黄土80份,保水剂吸水树脂1份、 杀虫剂吡虫啉0.1份、杀菌剂为50%多菌灵0.1份,生根剂为萘乙酸生根粉0.1份, 驱避剂N,N-二乙基-3-甲基苯甲酰胺0.05份,警戒性染料胭脂红0.01份,余量为 水。
按照以下方法制备,取以上种衣剂100g,将海藻酸、黄土、保水剂、杀虫剂、 杀菌剂,生根剂、水与1kg油菜种子按照比例添加混合,通过药用包衣锅进行丸 化包衣,再添加驱避剂,最后添加警戒性染料进行丸化包衣,即可。
实施例二
一种海藻酸包膜种衣剂,包括海藻酸1份、黄土85份、保水剂吸水树脂1.5份、 杀虫剂三唑磷0.15份、杀菌剂为75%的百菌清可湿性粉0.15份,生根剂萘乙酸生 根粉0.12份,驱避剂氯乙烯-偏氯乙烯共聚物0.07份,警戒性染料酸性大红0.02份, 余量为水。
按照以下方法制备,取以上种衣剂100g,将海藻酸、黄土、保水剂、杀虫剂、 杀菌剂,生根剂、水与1kg油菜种子按照比例添加混合,通过药用包衣锅进行丸 化包衣,再添加驱避剂,最后添加警戒性染料进行丸化包衣,即可。
实施例三
一种海藻酸包膜种衣剂,包括海藻酸1.5份、黄土88份、保水剂吸水树脂1.5 份、杀虫剂三唑磷0.18份、杀菌剂为75%的百菌清可湿性粉0.2份,生根剂萘乙酸 生根粉0.13份,驱避剂氯乙烯-偏氯乙烯共聚物0.08份,警戒性染料酸性大红0.015 份,余量为水。
按照以下方法制备,取以上种衣剂100g,将海藻酸、黄土、保水剂、杀虫剂、 杀菌剂,生根剂、水与1kg油菜种子按照比例添加混合,通过药用包衣锅进行丸 化包衣,再添加驱避剂,最后添加警戒性染料进行丸化包衣,即可。
实施例四
一种海藻酸包膜种衣剂,包括海藻酸2份、黄土90份,保水剂吸水树脂2份、 杀虫剂灭多威0.2份、杀菌剂为75%的百菌清可湿性粉0.18份,生根剂萘乙酸生根 粉0.13份,驱避剂邻苯二甲酸二甲酯0.08份,警戒性染料胭脂红0.03份,余量为水。
按照以下方法制备,取以上种衣剂100g,将海藻酸、黄土、保水剂、杀虫剂、 杀菌剂、生根剂、水与1kg大白菜种子按照比例添加混合,通过药用包衣锅进行 丸化包衣,再添加驱避剂,最后添加警戒性染料进行丸化包衣,即可。
实施例五
一种海藻酸包膜种衣剂,包括海藻酸3份、黄土95份,保水剂吸水树脂3份、 杀虫剂吡虫啉0.3份、杀菌剂为50%多菌灵0.3份,生根剂萘乙酸生根粉0.15份,驱 避剂四甲基秋兰姆二硫化物0.1份,警戒性染料酸性大红0.05份,余量为水。
按照以下方法制备,取以上种衣剂100g,将海藻酸、黄土、保水剂、杀虫剂、 杀菌剂、生根剂、水与1kg大白菜种子按照比例添加混合,通过药用包衣锅进行 丸化包衣,再添加驱避剂,最后添加警戒性染料进行丸化包衣,即可。
实施例六
一种海藻酸包膜种衣剂,包括海藻酸2.5份、黄土90份,保水剂吸水树脂1.5 份、杀虫剂吡虫啉0.15份、杀菌剂为50%多菌灵0.2份,生根剂萘乙酸生根粉0.15 份,驱避剂四甲基秋兰姆二硫化物0.1份,警戒性染料酸性大红0.05份,余量为水。
按照以下方法制备,取以上种衣剂100g,将海藻酸、黄土、保水剂、杀虫剂、 杀菌剂、生根剂、水与1kg大白菜种子按照比例添加混合,通过药用包衣锅进行 丸化包衣,再添加驱避剂,最后添加警戒性染料进行丸化包衣,即可。
实验实施例
将实施例一至实施例四处理的油菜种子和大白菜种子作为实验组,分别记 为实验组1、2、3、4、5和6,其中每个实验组中的油菜种子和大白菜种子相同。
对照组的油菜和大白菜种子不做任何处理,记为CK,对照组的种子与实验 组相同。
供试油菜,其种子质量检测结果:纯度≥85%,净度≥98%,发芽率≥80%。
供试大白菜,其种子质量检测结果:纯度≥96%,净度≥98%,发芽率≥85%。
表1实验组和对照组油菜发芽率及产量比较
| 组别 | 1 | 2 | 3 | CK |
| 发芽率% | 95 | 94 | 97 | 85 |
| 产量Kg/667m<sup>2</sup> | 170.2 | 175.6 | 179.1 | 121.1 |
| 苗期30天株高cm | 15.4 | 14.9 | 14.8 | 14.2 |
表2实验组和对照组对大白菜发芽率及产量比较
| 组别 | 4 | 5 | 6 | CK |
| 发芽率% | 95.6 | 96.4 | 95.8 | 91.2 |
| 产量Kg/667m<sup>2</sup> | 5811 | 5752 | 7098 | 3169 |
| 苗期30天株高cm | 14.1 | 14.7 | 16.0 | 13.5 |
结果表明采用本发明的种子包衣剂能有提高油菜、大白菜等十字花科作物 的发芽率,作物产量得到大幅度提高,并且起到促进苗期植株生长等作用。
以上已将本发明做一详细说明,以上所述,仅为本发明之较佳实施例而已, 当不能限定本发明实施范围,即凡依本申请范围所作均等变化与修饰,皆应仍 属本发明涵盖范围内。
Claims (8)
1.一种海藻酸包膜种衣剂,其特征在于,包括海藻酸0.5-3份、黄土80-95份,保水剂1-3份、杀虫剂0.1-0.3份、杀菌剂0.1-0.3份、生根剂0.1-0.15份、驱避剂0.05-0.1份、警戒性染料0.01-0.05份,余量为水。
2.根据权利要求1所述的一种海藻酸包膜种衣剂,其特征在于,所述保水剂包括但不限于吸水树脂。
3.根据权利要求1所述的一种海藻酸包膜种衣剂,其特征在于,所述杀虫剂包括但不限于吡虫啉、三唑磷、灭多威。
4.根据权利要求1所述的一种海藻酸包膜种衣剂,其特征在于,所述杀菌剂包括但不限于50%多菌灵和/或75%的百菌清可湿性粉。
5.根据权利要求1所述的一种海藻酸包膜种衣剂,其特征在于,所述生根剂包括但不限于萘乙酸生根粉。
6.根据权利要求1所述的一种海藻酸包膜种衣剂,其特征在于,所述驱避剂为N,N-二乙基-3-甲基苯甲酰胺、氯乙烯-偏氯乙烯共聚物、邻苯二甲酸二甲酯、四甲基秋兰姆二硫化物中的任意一种或至少两种的混合。
7.根据权利要求1-6所述的一种海藻酸包膜种衣剂,其特征在于,所述警戒性染料包括但不限于胭脂红、酸性大红或玫瑰红。
8.一种如权利要求7所述的海藻酸包膜种衣剂的制备方法,其特征在于,将海藻酸、黄土、保水剂、杀虫剂、杀菌剂、生根剂、水与种子按照比例添加混合,通过药用包衣锅进行丸化包衣,再添加驱避剂,最后添加警戒性染料进行丸化包衣。
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