CN111406756A - Compound insecticide - Google Patents
Compound insecticide Download PDFInfo
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- CN111406756A CN111406756A CN201910006335.7A CN201910006335A CN111406756A CN 111406756 A CN111406756 A CN 111406756A CN 201910006335 A CN201910006335 A CN 201910006335A CN 111406756 A CN111406756 A CN 111406756A
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- chlorpyrifos
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- 150000001875 compounds Chemical class 0.000 title claims abstract description 22
- 239000002917 insecticide Substances 0.000 title claims abstract description 8
- 239000005944 Chlorpyrifos Substances 0.000 claims abstract description 31
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000575 pesticide Substances 0.000 claims abstract description 18
- 239000000375 suspending agent Substances 0.000 claims description 10
- 239000004530 micro-emulsion Substances 0.000 claims description 5
- 239000004562 water dispersible granule Substances 0.000 claims description 5
- 239000004563 wettable powder Substances 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 3
- 239000003094 microcapsule Substances 0.000 claims description 3
- -1 suspoemulsions Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 15
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 13
- 235000009566 rice Nutrition 0.000 abstract description 13
- 230000000749 insecticidal effect Effects 0.000 abstract description 7
- 241001498622 Cixius wagneri Species 0.000 abstract description 5
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 abstract description 3
- 238000001228 spectrum Methods 0.000 abstract description 3
- 229960005199 tetramethrin Drugs 0.000 abstract description 3
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 241000209094 Oryza Species 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 13
- 241000238631 Hexapoda Species 0.000 description 8
- 241001556089 Nilaparvata lugens Species 0.000 description 8
- 241000607479 Yersinia pestis Species 0.000 description 8
- 230000002045 lasting effect Effects 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 241000258937 Hemiptera Species 0.000 description 5
- 230000009471 action Effects 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- 239000005822 Propiconazole Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 4
- 230000001018 virulence Effects 0.000 description 4
- 241001124076 Aphididae Species 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 231100000053 low toxicity Toxicity 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000176086 Sogatella furcifera Species 0.000 description 2
- 241000700605 Viruses Species 0.000 description 2
- 238000004166 bioassay Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000000361 pesticidal effect Effects 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- DVWJFTGEISXVSH-CWVFEVJCSA-N (1R,3S,5S,7Z,11R,12S,13Z,15Z,17Z,19Z,21R,23S,24R,25S)-21-[(2R,3S,4S,5S,6R)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-12-ethyl-1,3,5,25-tetrahydroxy-11-methyl-9-oxo-10,27-dioxabicyclo[21.3.1]heptacosa-7,13,15,17,19-pentaene-24-carboxylic acid Chemical compound CC[C@H]1\C=C/C=C\C=C/C=C\[C@@H](C[C@@H]2O[C@@](O)(C[C@H](O)[C@H]2C(O)=O)C[C@@H](O)C[C@@H](O)C\C=C/C(=O)O[C@@H]1C)O[C@@H]1O[C@H](C)[C@@H](O)[C@H](N)[C@@H]1O DVWJFTGEISXVSH-CWVFEVJCSA-N 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 241001465977 Coccoidea Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241001466044 Delphacidae Species 0.000 description 1
- 241000195620 Euglena Species 0.000 description 1
- 241001466042 Fulgoromorpha Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241000500891 Insecta Species 0.000 description 1
- 241001470017 Laodelphax striatella Species 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 241001466030 Psylloidea Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- LRZWFURXIMFONG-HRSIRGMGSA-N afidopyropen Chemical compound C([C@@]1(C)[C@H]2[C@]([C@H]3[C@@H](O)C=4C(=O)OC(=CC=4O[C@]3(C)[C@@H](O)C2)C=2C=NC=CC=2)(C)CC[C@@H]1OC(=O)C1CC1)OC(=O)C1CC1 LRZWFURXIMFONG-HRSIRGMGSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000001055 chewing effect Effects 0.000 description 1
- 238000012272 crop production Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000009191 jumping Effects 0.000 description 1
- 230000001418 larval effect Effects 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000003986 organophosphate insecticide Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- YQUVCSBJEUQKSH-UHFFFAOYSA-N protochatechuic acid Natural products OC(=O)C1=CC=C(O)C(O)=C1 YQUVCSBJEUQKSH-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004548 suspo-emulsion Substances 0.000 description 1
- 229930183279 tetramycin Natural products 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- WKOLLVMJNQIZCI-UHFFFAOYSA-N vanillic acid Chemical compound COC1=CC(C(O)=O)=CC=C1O WKOLLVMJNQIZCI-UHFFFAOYSA-N 0.000 description 1
- TUUBOHWZSQXCSW-UHFFFAOYSA-N vanillic acid Natural products COC1=CC(O)=CC(C(O)=O)=C1 TUUBOHWZSQXCSW-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a compound insecticide, which contains two active components of dicyclopropyl tetramethrin and chlorpyrifos. The compound pesticide has good control effect on rice planthopper. The insecticidal spectrum is enlarged while the dosage is reduced, the labor cost is reduced, the pollution to the environment is reduced, and the drug resistance is not easy to generate.
Description
Technical Field
The invention belongs to the field of pesticides, and particularly relates to a compounded insecticide of propiconazole and chlorpyrifos.
Background
The afidopyropen is a propylene compound found in biological fermentation products, is a brand-new pesticide for preventing and treating piercing-sucking mouthpart pests, and has the characteristics of quick response, high efficiency, broad spectrum and the like. The action mechanism of the propiconazole is different from that of a conventional insecticide, and the propiconazole plays a role by interfering the regulation and control of an insect vanillic acid transient receptor channel complex, so that the feeding and other behaviors of insects are interfered, the insects are starved and die, the feeding of the insects can be quickly inhibited, and the virus diseases transmitted by insect mediators are effectively reduced; has excellent insecticidal (aphid, whitefly and the like) effect; the lasting period is long; effective against a variety of insect states of pests (ineffective against eggs). Although the dicyclopropionate can stop feeding within hours after application, the knockdown effect is slow. The product has long lasting period, and the lasting effect on aphids can last for 21 days. The dicyclopropyl is effective on both imagoes and larvae, but the drug is recommended to be applied in the larval stage, so that the control effect is better. The dicyclopropyl tetramat can be used for economic crops, field crops, ornamental plants and the like, and can effectively prevent and control piercing-sucking and sucking mouthparts pests, such as aphids, whiteflies, psyllids, scale insects, mealybugs, leafhoppers and the like. The fertilizer can be used for treating leaf surfaces, seeds or soil.
Chlorpyrifos (chlorpyrifos), also called chlorpyrifos, is an excellent organophosphorus insecticide widely used at present. The product has effects of stomach poisoning, contact poisoning and fumigating, and has good control effect on various chewing and piercing-sucking mouthpart pests on rice, wheat, cotton, fruit trees, vegetables and tea trees. Compared with the conventional pesticide, the pesticide has low toxicity, is safe to natural enemies, has a wide insecticidal spectrum, is easy to combine organic matters in soil, has a special effect on underground pests, and has a lasting period of more than 30 days.
As farmland pests cause great loss to crop production every year, and considering that the long-term use of a single variety of pesticide easily promotes the pests to generate resistance and causes greater pollution to the environment, field experiments show that the existing pesticide is mixed with another pesticide with different action mechanisms, the resistance generation can be delayed, the pesticide effect and the residual period can be improved, the using amount is reduced, and the cost is reduced, so that the composition of the propiconazole and the chlorpyrifos is adopted, the insecticidal effect is improved, the insecticidal spectrum is enlarged, the environmental pollution is reduced, and the pesticide application cost is reduced.
Disclosure of Invention
The invention aims to provide a compound insecticide which has high efficiency, low toxicity, long lasting effect, high quick action and environmental protection. In particular to a pesticide preparation taking dicyclopropyl tetramethrin and chlorpyrifos as effective components.
In the compound insecticide, the weight ratio of the dicyclopropyl tetramycin to the chlorpyrifos is 1: 50-50: 1, and the preferable weight ratio is 1: 30-30: 1, more preferably in a weight ratio of 1: 10-10: 1.
the compound pesticide can be prepared into dosage forms of the invention, including wettable powder, water dispersible granules, suspending agents, suspoemulsion, microemulsion and microcapsule suspending agents, by matching with auxiliary agents known to persons skilled in the art and by methods known to persons skilled in the art.
The invention has the advantages and beneficial effects of wide insecticidal range of ①, low toxicity of ②, quick action, lasting effect, no residue of ③, no pollution and environmental safety, and the ④ uses a compound preparation, and the two effective components have synergistic effect and lower dosage than the single use, thereby improving the insecticidal effect of the effective components, increasing the safety and reducing the environmental pollution.
The rice planthopper belongs to a Delphacidae pest of Homoptera (Homoptera) of Insecta, common name of Euglena, the piercing and sucking plant juice is used for injuring crops such as rice, common types of the rice are brown planthopper (Nilaparvata lugens), white-backed planthopper (Sogatella furcifera) and Laodelphax striatellus (L aodelphax striatellus), and the rice planthopper is harmful to rice, except that the juice is directly pierced and sucked, the growth is blocked, the rice cluster is withered in serious cases, even the dead straw of the whole field is fallen down, the plant is pierced by spawning, the conduction tissue is damaged, the transportation of nutrient substances is prevented, virus diseases are spread, and great loss is caused.
The applicant firstly carries out the research of formula screening on the dicentrazone and the chlorpyrifos, and determines the indoor bioassay object as the brown planthopper according to the action characteristics of the two components, and the specific experimental conditions and results are as follows:
the indoor bioassay method comprises the steps of adopting a capillary micro-dropping method, enabling the volume of a capillary micro-dropping device to be 1.0 mu L, dropping liquid medicine on the back of the brown plant hoppers head by using the micro-dropping device, processing about 100 brown plant hoppers at each concentration, putting the treated brown plant hoppers into an insect cage, putting rice in the cage for feeding, dropping 100 larvae with acetone as a control, putting the treated brown plant hoppers into a feeding chamber, checking the death rate after 48 hours, statistically processing the data by using SPSS software, calculating the lethal medium concentration, and calculating the co-toxicity coefficient by using a Sunpei method.
The joint virulence of the mixed preparation is expressed by adopting a Sunweier cotoxicity coefficient method:
the theoretical virulence index TTI of the compound formulation is ∑ (the virulence index ATI × of a drug is the percentage of the active ingredient in the compound).
The CTC is synergistic when the CTC is more than 120, antagonistic when the CTC is less than 80, and additive when the CTC is 80-120.
TABLE 1 virulence test results for Nilaparvata lugens with different ratios
The analysis of the results shows that when the dicentrazon methyl and the chlorpyrifos are compounded according to different proportions, the cotoxicity coefficient of all the compound formulas is more than 120, which indicates that the two effective components can have good synergistic action after being compounded.
The following specific examples are intended to illustrate the invention in further detail, but the invention is by no means limited to these examples. The percentages in the formula are weight percentages.
Example one: 25.5% dicyclopropyl tetramethrin chlorpyrifos wettable powder
Example two: 31% dicyclopropyl tetramethrin-chlorpyrifos water dispersible granule
Example three: 22% dicyclopropyl tetramat-chlorpyrifos suspending agent
Example four: 18% dicyloproxyfen-chlorpyrifos suspending agent
Example five: 16% microemulsion of dicrotophos-ethyl and chlorpyrifos
Example six: 15% dicyloproxyfen-chlorpyrifos microcapsule suspending agent
Example seven: 16% dicyclopropyl tetramethrin-chlorpyrifos water dispersible granule
Example eight: 28% dicyloproxyfen-chlorpyrifos suspending agent
Example nine: 30% dicyloproxyfen-chlorpyrifos suspending agent
Example ten: microemulsion of 11% dicrotofen-chlorpyrifos
Example eleven: 31% dicylcyclobuthyl chlorpyrifos wettable powder
Example twelve: 25.5% dicyclopropyl tetramethrin-chlorpyrifos water dispersible granule
According to the twelve examples, a field test of controlling the rice planthoppers by the 16% C-methyl-propidium-chlorpyrifos microemulsion and other compound formulas is carried out, and the synergistic effect after compounding is verified by comparing the effects with the effects of a single agent of 5% C-methyl-propidium-chlorpyrifos suspending agent and a single agent of 40% chlorpyrifos emulsifiable solution. The experiment was carried out in four treatments, each treatment being 4 replicates, the cells being randomly arranged and having a cell area of 30m2The planting habits of all the districts are the same as the local planting habits.
The survey criteria were: and (5) surveying 10-20 points and 2 clusters per point by a parallel jumping method in each cell after 1d, 3d, 7d and 14d of treatment, slightly placing a white porcelain plate at the base of the rice plant, beating the rice cluster by hands, surveying the number of insects per pot, and calculating the decline rate and the prevention and treatment effect. Specific data (data is the average of three replicates) are as follows:
TABLE 2 field efficacy test results for rice planthopper with different formulations
From the data, in the process of compounding different formulas, under the condition of using the same effective dose, after the dicyclopropyl and the chlorpyrifos are compounded, the control effect of the compound preparation on the rice planthopper is obviously higher than that of two single agents, and the control effect of the compound preparation 1d after the pesticide is applied exceeds that of the two single agents; 3d after the medicine is applied, the control effect of the compound preparation reaches more than 78 percent; 7 days after the pesticide is applied, the prevention and treatment effect of the compound preparation is better than that of 3 days after the pesticide is applied, and the prevention and treatment effect reaches more than 85%; 14 days after the pesticide is applied, the prevention and the treatment of the compound preparation are all more than 85 percent, which indicates that the compound preparation has longer lasting period.
In a word, the compounded preparation of the diproprionate and the chlorpyrifos not only improves the pesticide effect, but also prolongs the lasting period, which shows that the quick-acting property and the lasting period of the compounded preparation are obviously improved compared with the single preparation, and the use cost of farmers can be greatly reduced by using the compounded preparation, thereby having obvious synergistic effect on the safety of crops. The present invention can be implemented without significantly departing from the present invention, and the technical features described in the different technical aspects can be combined in any form to form other technical aspects. The above embodiments and examples are illustrative of the present invention, but are not intended to limit the scope of the present invention, and modifications and substitutions may be made without departing from the spirit of the claims.
Claims (4)
1. A compound insecticide is characterized in that: the active ingredients comprise propiconate and chlorpyrifos, and the weight ratio of the propiconate to the chlorpyrifos is 1: 50-50: 1.
2. the compound pesticide according to claim 1, which is characterized in that: the preferable weight ratio of the propiconazole-diformate to the chlorpyrifos is 1: 30-30: 1.
3. the compound pesticide according to claim 1, which is characterized in that: the preferable weight ratio of the propiconazole-diformate to the chlorpyrifos is 1: 10-10: 1.
4. the compound pesticide according to claim 1, which is characterized in that: the active ingredients and the auxiliary materials are prepared into wettable powder, water dispersible granules, suspending agents, suspoemulsions, microemulsions and microcapsule suspending agents.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910006335.7A CN111406756A (en) | 2019-01-04 | 2019-01-04 | Compound insecticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910006335.7A CN111406756A (en) | 2019-01-04 | 2019-01-04 | Compound insecticide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111406756A true CN111406756A (en) | 2020-07-14 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910006335.7A Pending CN111406756A (en) | 2019-01-04 | 2019-01-04 | Compound insecticide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111406756A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102905528A (en) * | 2010-05-28 | 2013-01-30 | 巴斯夫欧洲公司 | Pesticidal mixtures |
| CN103535360A (en) * | 2007-03-08 | 2014-01-29 | 明治制果药业株式会社 | Pest control composition |
-
2019
- 2019-01-04 CN CN201910006335.7A patent/CN111406756A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103535360A (en) * | 2007-03-08 | 2014-01-29 | 明治制果药业株式会社 | Pest control composition |
| CN102905528A (en) * | 2010-05-28 | 2013-01-30 | 巴斯夫欧洲公司 | Pesticidal mixtures |
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