CN1114040A - Air energy heat circulation exchanger - Google Patents
Air energy heat circulation exchanger Download PDFInfo
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- CN1114040A CN1114040A CN94106955A CN94106955A CN1114040A CN 1114040 A CN1114040 A CN 1114040A CN 94106955 A CN94106955 A CN 94106955A CN 94106955 A CN94106955 A CN 94106955A CN 1114040 A CN1114040 A CN 1114040A
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B39/00—Evaporators; Condensers
- F25B39/04—Condensers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F12/00—Use of energy recovery systems in air conditioning, ventilation or screening
- F24F12/001—Use of energy recovery systems in air conditioning, ventilation or screening with heat-exchange between supplied and exhausted air
- F24F12/002—Use of energy recovery systems in air conditioning, ventilation or screening with heat-exchange between supplied and exhausted air using an intermediate heat-transfer fluid
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F3/00—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
- F24F3/12—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
- F24F3/14—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification
- F24F3/147—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification with both heat and humidity transfer between supplied and exhausted air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B41/00—Fluid-circulation arrangements
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D5/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, using the cooling effect of natural or forced evaporation
- F28D5/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, using the cooling effect of natural or forced evaporation in which the evaporating medium flows in a continuous film or trickles freely over the conduits
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2339/00—Details of evaporators; Details of condensers
- F25B2339/04—Details of condensers
- F25B2339/041—Details of condensers of evaporative condensers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/52—Heat recovery pumps, i.e. heat pump based systems or units able to transfer the thermal energy from one area of the premises or part of the facilities to a different one, improving the overall efficiency
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/56—Heat recovery units
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Sorption Type Refrigeration Machines (AREA)
- Other Air-Conditioning Systems (AREA)
Abstract
Description
本发明涉及空气能热量循环交换机。The invention relates to an air energy heat circulation exchanger.
空气调节是调节室内空气的能量状态和空气性质,用以满足人体的舒适和生理卫生要求。而室内空气的污染源主要来源于室内物品及人体的新陈代谢运动。封闭式气流循环是将室内污浊空气吸入制冷后继续输入室内,这种气流循环的结果是污浊程度不断加深并反复地恶性循环,对人体健康极为不利。如果引入100%的新鲜室外空气,相应的耗电量需增加1.2倍以上,因此高能耗及低能量转换效率是现行空调的缺陷。Air conditioning is to adjust the energy state and air properties of indoor air to meet the comfort and physiological hygiene requirements of the human body. The sources of indoor air pollution mainly come from the metabolic activities of indoor objects and human body. Closed air circulation is to suck indoor dirty air into the room after being refrigerated. The result of this air circulation is that the degree of pollution will continue to deepen and repeat a vicious cycle, which is extremely harmful to human health. If 100% fresh outdoor air is introduced, the corresponding power consumption needs to increase by more than 1.2 times, so high energy consumption and low energy conversion efficiency are the defects of current air conditioners.
换言之,若要满足一定空间里的需氧量,以及应有的制冷(热)要求,以目前的空调机而言,需要耗费大量的电能。In other words, to meet the oxygen demand in a certain space and the cooling (heating) requirements, the current air conditioners need to consume a lot of electric energy.
热力学第二定律指出:热量能自发地从高温物体传向低温物体,而不能自发地从低温物体传向高温物体。卡诺循环(Carnot cycle)、劳伦茨循环(Lorenz cycle)是热力效率最高的理想循环,也是各类空调的指导理论。依据上述理论研制的现行各类空调机,其制冷过程均需耗费很大能量才能将热能从低温物体泵送至高温物体。因此制冷过程必然是高能量的耗费及过量耗能过程,而且现行的各类空调机其热力循环效率远低于卡诺循环效率。The second law of thermodynamics states that heat can spontaneously transfer from a high-temperature object to a low-temperature object, but cannot spontaneously transfer from a low-temperature object to a high-temperature object. Carnot cycle and Lorenz cycle are ideal cycles with the highest thermodynamic efficiency, and are also the guiding theory for various air conditioners. According to the current various air conditioners developed according to the above theory, the refrigeration process all needs to consume a lot of energy to pump heat energy from low-temperature objects to high-temperature objects. Therefore, the refrigeration process must be a process of high energy consumption and excessive energy consumption, and the thermodynamic cycle efficiency of various types of air conditioners is far lower than the Carnot cycle efficiency.
能否借助于被制冷空气的能量(室外热空气能量)来补偿制冷循环所需的能量,使耗能的制冷过程转为能量的存储和产生动力的过程,只要其获得的能量≥制冷所需的能量,即可使制冷系统自动运行。这需要较高的蒸发温度和较低的冷凝温度,并且在换热过程中获得空调所必需的冷(热)峰值温度。Can the energy of the refrigerated air (outdoor hot air energy) be used to compensate the energy required for the refrigeration cycle, so that the energy-consuming refrigeration process can be transformed into a process of energy storage and power generation, as long as the energy obtained is greater than the energy required for refrigeration The energy can make the refrigeration system operate automatically. This requires a higher evaporating temperature and a lower condensing temperature, and obtains the cold (hot) peak temperature necessary for air conditioning during the heat exchange process.
本发明是一种以空气能量为主要制冷(热)循环动力的低压差热泵空调机。低压差热泵既可液气混合输送,亦可液气分离输送。空气能是指自然空气中所含有的可被用来制冷(热)的这部分能量。微分冷却管是一种单位面积热流量大,并可使终点传热温差无限趋近于零的高效换热器,工作介质对是指制冷剂和吸收剂组合,如水和溴化锂(LiBr)或氨(NH3)和水,或水和氯化锂(LiCl)等。本发明的热力交叉循环机是由空气能双向蒸发器、空气能双向冷凝器、低压差能量转换热泵构成的室外新鲜空气空调机,其温-熵图为呈交叉状的热力循环,可充分利用空气能量来补偿冷(热)过程所需的动力循环,因而具有极高的热力循环效率。本发明热力交叉循环机的另一特征是空气调节中冷(热)量的输出均需采用100%的室外新鲜空气才能获得最佳热力循环效率。The invention is a low-pressure difference heat pump air conditioner with air energy as the main refrigeration (heat) cycle power. The low-pressure differential heat pump can be used for both liquid-gas mixed transportation and liquid-gas separation transportation. Air energy refers to the part of energy contained in natural air that can be used for cooling (heating). The differential cooling tube is a high-efficiency heat exchanger with a large heat flow per unit area and can make the temperature difference of the end heat transfer infinitely close to zero. The working medium pair refers to the combination of refrigerant and absorbent, such as water and lithium bromide (LiBr) or ammonia (NH 3 ) and water, or water and lithium chloride (LiCl), etc. The thermal cross-cycle machine of the present invention is an outdoor fresh air air conditioner composed of an air-energy two-way evaporator, an air-energy two-way condenser, and a low-pressure differential energy conversion heat pump. Its temperature-entropy diagram is a cross-shaped thermodynamic cycle, which can be fully utilized The energy of the air is used to compensate the power cycle required for the cold (heat) process, so it has a very high thermodynamic cycle efficiency. Another feature of the thermal cross cycle machine of the present invention is that 100% of outdoor fresh air is required for the output of cold (heat) in the air conditioning to obtain the best thermal cycle efficiency.
本发明是以室外高温空气为能源直接达到加热及降温效果,一般冷凝器和室外气温△T=13~15℃,蒸发器和蒸发温度△T=8~12℃,而本发明的△T=0.1~0.5℃,可充分利用空气能达到热交换的目的。The present invention uses outdoor high-temperature air as the energy source to directly achieve heating and cooling effects. Generally, the condenser and outdoor air temperature △T=13-15°C, the evaporator and evaporation temperature △T=8-12°C, and the present invention's △T= 0.1 ~ 0.5 ℃, can make full use of air to achieve the purpose of heat exchange.
换言之,本发明引入100%的室外空气,流经本发明装置后,导出冷(热)空气,不但可充分地获得需氧量,且因充分运用室外空气的高(低)温度构成循环,理论上的EER值极高,即,以最低的能量损耗去产生最大的制冷(热)效果。In other words, the present invention introduces 100% outdoor air, flows through the device of the present invention, and exports cold (hot) air, which not only can fully obtain the oxygen demand, but also makes full use of the high (low) temperature of the outdoor air to form a cycle, theoretically The EER value above is extremely high, that is, to produce the greatest cooling (heating) effect with the lowest energy loss.
在本发明循环过程中,工作介质(Working substance)循环与现有方式不同,主要是在于:一般吸收模式由四部分组成,即蒸发器、发生器、冷凝器、吸收器,而本发明的蒸发器包含发生器功能,冷凝器包含吸收器功能,一般型发生器必须藉助废热或蒸气,蒸发器必须藉助冰水做二次热交换,本发明则不需要。In the circulation process of the present invention, the working medium (Working substance) circulation is different from the existing method, mainly because: the general absorption mode is composed of four parts, namely evaporator, generator, condenser, absorber, and the evaporation of the present invention The generator contains the function of the generator, and the condenser contains the function of the absorber. The general type generator must use waste heat or steam, and the evaporator must use ice water for secondary heat exchange, but the present invention does not need it.
本发明的目的在于提供一种空气能热量循环交换机。The object of the present invention is to provide an air energy heat circulation exchanger.
本发明的目的是这样实现的,即通过提供一种空气能热量循环交换机,由空气能双向蒸发器、空气能双向冷凝器、低压差能量转换热泵组成,以可被循环运用的工作介质对流布于空气能双向蒸发器及空气能双向冷凝器上,利用引流的空气能量作为热量转换动力以造成流动工作介质对在空气能双向蒸发器上贮存能量,而于空气能双向冷凝器上释放热量,且被循环,并使空气同时在空气能双向蒸发器释放能量,于空气能双向冷凝器上吸收能量。The object of the present invention is achieved by providing an air energy heat circulation exchanger, which is composed of an air energy bidirectional evaporator, an air energy bidirectional condenser, and a low-pressure differential energy conversion heat pump, and can be circulated by a working medium convection distribution On the air energy two-way evaporator and air energy two-way condenser, the air energy of the diversion is used as the heat conversion power to cause the flowing working medium to store energy on the air energy two-way evaporator, and release heat on the air energy two-way condenser. And it is circulated, and the air releases energy in the air-energy two-way evaporator at the same time, and absorbs energy in the air-energy two-way condenser.
本发明的优点在于它能以最低能耗实现最好制冷效果。The advantage of the present invention is that it achieves the best cooling effect with the lowest energy consumption.
以下结合附图,描述本发明的实施例,其中:Embodiments of the present invention are described below in conjunction with the accompanying drawings, wherein:
图1是本发明交换机热力循环温熵TS图;Fig. 1 is the temperature entropy TS figure of heat exchanger thermodynamic cycle of the present invention;
图2是理想的卡诺循环、劳伦茨循环与本发明热力循环的TS对比图;Fig. 2 is ideal Carnot cycle, Lorentz cycle and the TS contrast figure of thermodynamic cycle of the present invention;
图3是本发明空气能热量循环交换机制冷过程示意图;Fig. 3 is a schematic diagram of the refrigeration process of the air energy heat circulation exchanger of the present invention;
图4是图3中A-A线剖视图;Fig. 4 is A-A line sectional view among Fig. 3;
图5是图3中B-B线剖视图;Fig. 5 is B-B line sectional view among Fig. 3;
图6是本发明热力循环、卡诺循环、劳伦茨循环所用工作介质的比较图;Fig. 6 is the comparative diagram of working medium used in thermodynamic cycle, Carnot cycle and Laurenz cycle of the present invention;
图7是相应于图6的压焓Ph比较图;Fig. 7 is a comparison diagram corresponding to the pressure-enthalpy Ph of Fig. 6;
图8是本发明热力循环改变成热力三角循环的TS图;Fig. 8 is the TS figure that thermodynamic cycle of the present invention changes into thermodynamic triangle cycle;
图9是本发明热力循环机的窗型实施例。Fig. 9 is a window-type embodiment of the thermal cycler of the present invention.
参见图1,它是空气能热量循环交换机温熵TS图(TEMPERATUREENTROPY),在制冷循环中:See Figure 1, which is the temperature entropy TS diagram (TEMPERATUREENTROPY) of the air energy heat cycle exchanger. In the refrigeration cycle:
T2是热峰值温度,也是室外空气干球(DRY BULB)温度。 T2 is the thermal peak temperature, which is also the dry bulb (DRY BULB) temperature of the outside air.
T2=TK(热峰值是最高温度点)。T 2 =T K (thermal peak is the point of highest temperature).
T1是冷峰值温度,也是冷风输出温度。T 1 is the cold peak temperature and also the output temperature of the cold air.
T1=T0(冷峰值是最低温度点)。T 1 =T 0 (cold peak is the lowest temperature point).
T4是空调房间的空气湿球(WET BULB)温度。 T4 is the air wet bulb (WET BULB) temperature of the air-conditioned room.
T3是冷凝空气的排气湿球温度。 T3 is the exhaust wet bulb temperature of the condensing air.
Ⅰ区:1-J-2过程是制冷工作介质对从To~TK的连续温度变化吸热(储存空气能量)过程;所对应的被制冷空气侧区是Ⅱ区:2-J-1过程是被制冷空气从TK~To的连续温度变化放热过程。Ⅲ区:3-J-4过程是制冷工作介质对从T3~T4的连续温度变化放热过程;所对应的Ⅳ区:4-J-3过程是冷凝空气从T4~T3的连续温度变化完全湿吸热过程。Zone Ⅰ: 1-J-2 process is the process of the cooling working medium absorbing heat (storing air energy) from the continuous temperature change from T o to T K ; the corresponding refrigerated air side zone is Zone Ⅱ: 2-J-1 The process is the exothermic process of the continuous temperature change of the refrigerated air from T K to T o . Zone Ⅲ: 3-J-4 process is the heat release process of the refrigeration working medium to the continuous temperature change from T 3 to T 4 ; the corresponding zone Ⅳ: 4-J-3 process is the process of condensing air from T 4 to T 3 Continuous temperature change is a completely wet endothermic process.
2-3是从高温至低温(TK~T3)绝热泵送过程。2-3 is adiabatic pumping process from high temperature to low temperature (T K ~ T 3 ).
4-1是绝热膨胀过程。4-1 is adiabatic expansion process.
△1J4的面积是制冷循环所需的功W1;△23J的面积是制冷循环所获得的空气能W2,W2可完全转化为有用功。J点是制冷工作介质对的吸热线和放热线交点。The area of △1J4 is the work W 1 required by the refrigeration cycle; the area of △23J is the air energy W 2 obtained by the refrigeration cycle, and W 2 can be completely converted into useful work. Point J is the intersection of the heat absorption line and the heat release line of the refrigeration working medium pair.
逆时针走向的△1J4是空气能热量循环交换机中的制冷机,顺时针走向的△23J是空气能热量循环交换机中的空气能发动机,J点是制机和空气能发动机的串联点。The anticlockwise △1J4 is the refrigerator in the air energy heat circulation exchanger, the clockwise △23J is the air energy engine in the air energy heat circulation exchanger, and the J point is the series connection point of the machine and the air energy engine.
制冷循环所需补偿的功为W1-W2=△WThe work to be compensated by the refrigeration cycle is W 1 -W 2 =△W
热力能效比EER= (Q吸)/(△W) ;其中Q吸是制冷量Thermal energy efficiency ratio EER = (Q absorption)/(△W); where Q absorption is the cooling capacity
当W2≥W1时可借助于空气能量W2而自动运行,这时EER→∞。When W 2 ≥ W 1 , it can run automatically with the help of air energy W 2 , then EER→∞.
当冷峰值温度To降低时:T4也随之下移、J点也随之下移、W1和W2同时增加、△W=W1-W2并不增加,可见空气能热量循环交换机在耗功的制冷过程中同时又获得空气能量W2 When the cold peak temperature T o decreases: T 4 also moves down, J point also moves down, W 1 and W 2 increase at the same time, △W=W 1 -W 2 does not increase, it can be seen that the air energy heat cycle The switch also obtains air energy W 2 during the power-consuming cooling process
图2是理想的卡诺循环、劳伦茨循环和空气能热量循环交换机的TS对比图。Figure 2 is a TS comparison chart of the ideal Carnot cycle, Lorenz cycle and air energy heat cycle exchanger.
是卡诺循环。 is the Carnot cycle.
是劳伦茨循环。 is the Lorenz cycle.
是空气能热量循环交换机。 It is an air energy heat circulation exchanger.
在相同的TK和To条件下卡诺循环耗功最大,制冷量最小;空气能热量循环交换机制冷量最大耗功最小;劳伦茨循环介于卡诺循环和空气能热量循环交换机之间,TK和To的温差越大上述对比也越明显。Under the same T K and T o conditions, the Carnot cycle consumes the most power and the cooling capacity is the smallest; the air energy heat circulation exchanger has the maximum cooling capacity and the minimum power consumption; the Lorentz cycle is between the Carnot cycle and the air energy heat circulation exchanger , the greater the temperature difference between T K and T o , the more obvious the above contrast.
微分传热管的传热过程是充分的、无限微分的不等温过程,其终点传热温差无限趋近于零。因而1-J-2和3-J-4可以认为是可逆的连续温度变化过程。空气能热量循环交换机是由两个可逆的连续温度变化和两个等熵过程所构成。The heat transfer process of the differential heat transfer tube is a sufficient, infinitely differential, non-isothermal process, and the temperature difference at the end of the heat transfer infinitely approaches zero. Therefore, 1-J-2 and 3-J-4 can be considered as reversible continuous temperature change process. The air energy heat circulation exchanger is composed of two reversible continuous temperature changes and two isentropic processes.
图3是空气能热量循环交换机制冷过程示意图。Fig. 3 is a schematic diagram of the refrigeration process of the air energy heat circulation exchanger.
空气能双向蒸发器1通过导热片5换热。参见图4,以平行排列的平面状金属导热片将空气能双向蒸发器1分隔成Ⅰ区和Ⅱ区。Ⅰ区是导热片5和dxn微分绝热片20组成的To~TK的制冷工作介质无限微分不等温吸热(储能)区,TS图对应于1-J-2与Ⅰ区对应的被制冷空气侧是Ⅱ,导热片5和波纹导热片7组成的从TK~To的被制冷空气的无限微分不等温放热区dyn流道,T-S图对应于2-J-1。波纹导热片7是薄金属材料制成的,dyn方向的导热量可视为零,可在dyn方向将导热片绝热切割为很多条形温区,其次是增大导热片与空气的换热面积dxn微分绝热片20用热阻较大的非金属材料制成,在dxn方向将导热片绝热切割成很多条形温区。因此导热片被dxn、dyn绝热切割成无数个(dxn、dyn)微等温导热面,而每一个微等温面和彼此相邻的微等温面(dxy+1、dyn)或(dxn、dyn-1)的温度既不相等,其温差又趋向于零。由于空气能双向蒸发器1的导热面是无限微分的不等温导热面,因此可以认为空气能双向蒸发器是从To~Tk(或Tk~To)的连续温度变化导热面,并且两侧的温度变化过程是同步的。The air energy two-
处于热峰值温度TK的室外空气a1,在送风扇12推动作用下沿a2方向在Ⅱ区的dyn流道内充分地连续温度变化加热导热片5,放热至冷峰值温度To的冷风a3经出风调节窗14输入室内,其被制冷过程在T-S图上对应于2-J-1(Tk-To)和连续温度变化放热过程。The outdoor air a 1 at the heat peak temperature T K is driven by the
吸收剂Ⅰ和制冷剂X组成的稀溶液g1经输液管16均匀分配各个g1分配管从节流阀17喷入Ⅰ区平行排列的各个dxn流道内,按g1→g12→g2方向流动,回路管11是dxn流道拐弯处。g1→g12→g2在dxn流道内的吸热过程在T-S图上对应于1-J-2(To-Tk)的连续温度变化吸热过程,在等压状态P1下,g1从冷峰值温度To充分地连续温度变化被加热至热峰值温度TK,g1内含的液态制冷剂X逐步吸热蒸发为过热温度Tk-To=△T的汽态制冷剂X2,g1也相应地被加热成过热温度△Tg2的浓溶液。The dilute solution g1 composed of absorbent I and refrigerant X is evenly distributed through the
由于空气能双向蒸发器1的换热过程是在微等温面上进行的,而每一个微等温面又总是使其导热片两面的制冷工作介质对Ⅰ、Ⅹ和被制冷空气的温度尽其可能地趋于等温,其终点传热温差必然趋向于零,因此制冷工作介质对从To~TK的吸热过程是无热损的可逆过程;而应用于实际热交换的空气能双向蒸发器1,其传热温差为0.1~0.5℃而没有必要去苛求传热温差→0。Since the heat exchange process of the air energy two-
空气能双向蒸发器1的热泵性表现在,g2和X2强烈过热,在To~Tk的可逆吸热过程中储存了△T这部分空气能量W2,其制冷的过程又同时是储能过程。The heat pump performance of the air energy two-
空气能双向冷凝器2也是由导热片5换热。参见图5,以平行排列的平面状金属导热片将空气能双向冷凝器2分隔为Ⅲ区和Ⅳ区。Ⅲ区是导热片5和dxn微分绝热片20组成的制冷工作介质对g2和X2从T3~T4的连续不等温被冷凝而液化放热区,T-S图对应于3-J-4。与Ⅲ区对应的冷凝空气侧是Ⅳ区导热片5和dyn微分绝热片21组成的从T4~T3的冷凝空气无限微分不等温完全湿吸热区,T-S图对应于4-J-3。导热片的外侧贴合多孔吸水材料制成的膜式蒸发面6,其膜面具有良好的贮水、吸水性和较大的多孔表面积。贮水性可大大提高膜式蒸发面6和导热片5的传热系数;多孔性可形成较大的蒸发表面积;使其冷凝过程成为温度较低的完全湿吸热过程。由于湿空气的定压比热Cp1比空气定压比热Cp2大得多,由此T4~T3温差较小。dxn微分绝热片20和dyn微分绝热片21均用热阻较大的非金属材料制成,导热片5的两面被微分绝热切割为无限多个(dxn、dyn)微分等温导热面,因而使空气能双向冷凝器2的导热片5成为从T4~T3的连续温度变化导热面。The air energy two-
从空气能双向蒸发器1输出的冷风a3在室内吸取热、湿量后,成为人体舒适度所需温、温度a4,被排风扇19强制吸入Ⅳ区的dyn流道内沿a5方向在膜式蒸发面6上充分吸收水汽,从湿球温度T4升至湿球温度T3的饱和态a6而排向大气。The cold air a3 output from the air energy two-
从空气能双向蒸发器1流出的压力为P1的g2和X2被低压差热泵15泵压至P2,经液汽输送管13分配给空气能双向冷凝器2的各个液汽分配管3从喷孔喷入Ⅲ区的dxn流道内,沿g2→g1方向从T3至T4充分地、连续不等温放热而逐步液化为过冷稀溶液g1。g1经输液管16和节流阀17流入空气能双向蒸发器1……如此往复循环。The pressure of g2 and X2 flowing out from the air energy two-way evaporator 1 is P1, which is pumped to P2 by the low-pressure
空气能双向冷凝器2的换热过程也是在无限微分的微分不等温导热面上进行的,其终点传热温差→0,因此从T3~T4的冷凝过程和其对应的从T3~T4的被冷凝过程和其对应的从T4~T3的冷凝空气湿吸热过程均是可逆连续温度变化过程。The heat exchange process of the air energy two-
过热浓溶液g2在T3→T4较低温度的冷凝状态下,其表面分压远低于P2,具有强烈吸收气态制冷剂X2并使其液化而放热的能力。因此空气能双向冷凝器2的超冷凝性表现在低温和低压冷凝两个方面,这是因为g2储存的W2和T3~T4低温冷凝双重作用的结果。超冷凝又可使g1稀溶液过冷,使制冷量增大和To进一步降低,这就更促进了系统的良性循环。The superheated concentrated solution g 2 has the ability to strongly absorb the gaseous refrigerant X 2 and liquefy it to release heat in the condensed state at a lower temperature T 3 → T 4 , its surface partial pressure is much lower than that of P 2 . Therefore, the super-condensability of the air energy two-
在实际循环中空气能双向蒸发器1和空气能双向冷凝器2的不等温传热温差控制在0.1~0.5℃之间而并无必要去苛求传热温差→0,因此1-J-2和3-J-4过程仍有少量不可逆功(EXERGY)损存在。另一方面制冷工作介质对流体往复流动,分配时必然有摩擦阻力存在;41过程并不是等熵过程而是等焓的节流降压过程,也有不可逆功损存在。In the actual cycle, the non-isothermal heat transfer temperature difference between the air-energy two-
上述不可逆过程形成的功损表现为系统净功的损耗△W1。因此空气能热量循环交换机热力循环所需补偿的功WM=△W1+△W,WM>理想空气能热量循环交换机热力循环所需的补偿功△WoWM由低压差能量转换热泵M来提供,低压差热泵M的泵送作用将液态g2和汽态X2同时从P1增压至P2向空气能双向冷凝器2入口输送,使吸收剂和制冷剂按图3进行热力运行,完成能量输送和能量转换过程。The power loss formed by the above irreversible process is expressed as the loss of net work of the system △W 1 . Therefore, the compensation work required for the thermodynamic cycle of the air energy heat cycle exchanger W M = △W 1 + △W, W M > the compensation work required for the thermodynamic cycle of the ideal air energy heat cycle exchanger △W o W M is converted from low pressure differential energy heat pump Provided by M, the pumping action of the low-pressure differential heat pump M simultaneously pressurizes the liquid g2 and vapor state X2 from P1 to P2 and transports them to the inlet of the air energy two-
由于空气能双向蒸发器1和空气能双向冷凝器2的传热温差较小,而P2-P1=△P较小,因此4-1过程的等焓节流功损和制冷工作介质流体摩擦阻力引起的功损也较小,所以系统的总净功损耗△W1也较小。可见空气能热量循环交换机不但有极高的理论EER值,而且有较高的热力完善度(THERMODYNAMIC PERFECT DEGREE),在标准的测试工况条件下,其实际EERm= (Q吸)/(Wm) 值可达20~35。Since the heat transfer temperature difference between the air-energy two-
图6是 工作介质为吸收剂和制冷剂组成的空气能热量循环交换机和 工作介质为共沸或单一制冷剂的卡诺制冷机及 工作介质为非共沸混合制冷剂的劳伦茨制冷机的TS比较图;图7是其相应的压焓Ph比较图(PRESSURE ENTHALPA DIAGRAM)。现行的市售卡诺和劳伦茨制冷机(除大型空调)均采用风冷式冷凝器和风冷式蒸发器。由于风冷式冷凝器的冷凝温度较室外环境温度高13~15℃,风冷式蒸发器的蒸发温度较冷风出口温度低8~12℃,而空气能热量循环交换机的微分传热器的传热温差为0.1~0.5℃,在相同的冷风输出温度和相同的环境温度TK前题下;卡诺、劳伦茨制冷机的冷凝温度高于TK和冷凝压力大于P2而蒸发温度低于To和蒸发压力却低于P1。从图6和图7的对比可知在实际的制冷系统中:冷凝压力愈高,蒸发温度愈低,功耗也愈大,而制冷量反而愈小。Figure 6 is The working medium is an air energy heat cycle exchanger composed of absorbent and refrigerant and Carnot refrigerator with azeotropic or single refrigerant as working medium and The TS comparison diagram of the Laurenz refrigerator whose working medium is a non-azeotropic mixed refrigerant; Figure 7 is the corresponding pressure-enthalpy Ph comparison diagram (PRESSURE ENTHALPA DIAGRAM). The current commercially available Carnot and Lorenz refrigerators (except large air conditioners) all use air-cooled condensers and air-cooled evaporators. Since the condensation temperature of the air-cooled condenser is 13-15°C higher than the outdoor ambient temperature, the evaporation temperature of the air-cooled evaporator is 8-12°C lower than the cold air outlet temperature, and the differential heat exchanger of the air-energy heat circulation exchange The heat temperature difference is 0.1-0.5°C, under the same cold air output temperature and the same ambient temperature T K ; the condensation temperature of Carnot and Lorenz refrigerators is higher than T K and the condensation pressure is higher than P 2 while the evaporation temperature is low In T o and evaporation pressure is lower than P 1 . From the comparison of Figure 6 and Figure 7, it can be seen that in the actual refrigeration system: the higher the condensing pressure, the lower the evaporation temperature, the greater the power consumption, and the smaller the cooling capacity.
设:卡诺制冷机的功耗为Wc,制冷量Qc,EERc Suppose: the power consumption of the Carnot refrigerator is W c , the cooling capacity is Q c , EER c
劳伦茨制冷机的耗功为WL,制冷量Qm,EERL The power consumption of the Lorenz refrigerator is W L , the cooling capacity is Q m , EER L
空气能热量循环交换机的耗功为Wm,制冷量Qm,EERm The power consumption of the air energy heat circulation exchanger is W m , the cooling capacity is Q m , and the EER m
∵Wc>WL>Wm而Qm>QL>Qc ∵W c >W L >W m and Q m >Q L >Q c
∴EERm>EERL>EERc ∴ EER m > EER L > EER c
空气能热量循环交换机具有较大的吸气过热温度,这部分热量由吸收剂的温升来运载,因此空气能热量循环交换机应选择热容量大、导热系数较高的吸收剂;还具有较大的过冷温度(是超冷凝作用的结果),因此制冷量QM较Qc和QL大得多,因卡诺、劳伦茨制冷机EER值较低不能采用100%的室外新鲜空气,而本发明反而能采用100%的室外新鲜空气实现最佳的热力循环效率。The air energy heat circulation exchanger has a large suction superheat temperature, and this part of the heat is carried by the temperature rise of the absorbent, so the air energy heat circulation exchanger should choose an absorbent with large heat capacity and high thermal conductivity; it also has a large Subcooling temperature (the result of super-condensation), so the cooling capacity Q M is much larger than Q c and Q L , because the EER value of the Carnot and Laurents refrigerators is low, 100% outdoor fresh air cannot be used, while On the contrary, the present invention can adopt 100% outdoor fresh air to realize the best thermodynamic cycle efficiency.
参见图3,含湿量X1的室外空气a1在空气能双向蒸发器1内放热到冷峰值温度To的a3冷风,a3的含湿量降为X2,则每Kg输入冷风的凝水量为X1-X2=△X10△X1滴入接水盘10从水管流入积水盘9内,由水泵定时、定量从喷嘴18喷向空气能双向冷凝器2的膜式蒸发面6。空气能双向冷凝器2的冷凝是湿吸热过程,含湿量X3的室内空气a4从空气能双向冷凝器2的膜式蒸发面6上吸收水汽演变为含湿量X4的湿空气a6而排向室外,其每Kg排出空气的耗水量为X4-X3=△X2,空气能热量循环交换机在单位时间输入空气和排出空气是等量的,因此当△X1=△X2时为水平衡点。由于自然空气的含湿量X1和室内的湿负荷X3-X2无法预定(是动态的),因此积水盘内的存水量在△X2>△X1时应由自动供水装置补充,在△X1>△X2时则自动引出。See Figure 3, the outdoor air a1 with moisture content X1 releases heat to the cold air of a3 cold peak temperature T o in the air energy two-
参见图3和图8,当空气能双向蒸发器1作为室内机时,空气能双向冷凝器2作为室外机时,空气能双向蒸发器1的被制冷空气即为室内空气的封闭循环气流;空气能双向冷凝器2的冷凝空气是从室外吸取再排向室外(相当于目前的分离型空调)。这时空气能热量循环交换机的T-S图就演变为图6的
形T-S循环图(以下称热力三角循环机)。Referring to Fig. 3 and Fig. 8, when the air-energy two-
T2是室内空气的干球温度。 T2 is the dry bulb temperature of the room air.
T4是室内空气的湿球温度。 T4 is the wet bulb temperature of the room air.
T3是空气能双向冷凝器2的排气湿球温度。 T3 is the exhaust wet-bulb temperature of the air energy two-
To=T1是冷峰值温度也是空气能双向蒸发器的输出冷风温度。T o =T 1 is the cold peak temperature and also the output cold air temperature of the air energy two-way evaporator.
热力三角循环机在实际运行时T2是变化的。当T2=T3时,J点和T2、T3点重合一点,W2=0当T3>T2时J点消失。热力三角循环机和空气能热量循环交换机是同一系统也由两个近似可逆的连续温度变化过程、一个绝热泵送过程、一个等焓节流过程构成。The T 2 of the thermodynamic triangular cycle machine changes during actual operation. When T 2 =T 3 , point J coincides with points T 2 and T 3 , and when W 2 =0, point J disappears when T 3 >T 2 . The thermodynamic triangular cycle machine and the air energy heat circulation exchanger are the same system and are also composed of two approximately reversible continuous temperature change processes, an adiabatic pumping process, and an isenthalpic throttling process.
假定空气能热量循环交换机和热力三角循环机是相同的冷峰值温度To。Assume that the air energy heat cycle exchanger and the thermodynamic triangle cycle machine have the same cold peak temperature To.
因为:T2<TK,TK是室外环境温度;Because: T 2 <T K , T K is the outdoor ambient temperature;
T4<T8,T8是室外空气湿球温度;T 4 < T 8 , T 8 is the outdoor air wet bulb temperature;
也就是热力三角循环机热峰值温度低于空气能热量循环交换机,冷凝温度高于热力交叉循环机;由于TK-T8>T2-T4,因此制冷过程热力三角循环机所储存的空气能量小于热力交叉循环机。则热力三角循环机M向系统输入的功WM′应大于空气能热量循环交换机所需的功WM。但是热力三角循环机同样可在耗能的制冷过程中储存空气能量,空气能双向蒸发器1的热泵性和空气能双向冷凝器2的超冷凝性仍然存在,并且传热过程的不可逆损失较小,因此也具有较高的热力循环效率即性能系数EER。That is, the thermal peak temperature of the thermodynamic triangle cycle machine is lower than that of the air energy heat cycle exchanger, and the condensation temperature is higher than that of the thermodynamic cross cycle machine; since T K -T 8 >T 2 -T 4 , the air stored in the thermodynamic triangle cycle machine during the refrigeration process Energy is less than a thermal cross cycle machine. Then the work W M ′ input by the thermodynamic triangular cycle machine M to the system should be greater than the work W M required by the air energy heat cycle exchanger. However, the thermodynamic triangular cycle machine can also store air energy in the energy-consuming refrigeration process, the heat pump of the air-energy two-
如果在热力三角循环机中将制冷工作介质对改换为非共沸(NONAZEOTROPIC)混合制冷剂,那么图8的热力三角循环即变化为
的劳伦茨循环。从图中可以看出劳伦茨循环所需的功能WL>2WM′;且由于吸热线1-2′以下的面积小于以热力三角循环机吸热线Q1-J-2以下的面积;可知热力三角循环机可比劳伦茨制冷机的性能系数EER高二倍以上。若将热力三角循环机的工作介质改换为共沸(AZEOTROPIC)制冷剂或单一制冷剂时其性能系数EER还要进一步降低。因为劳伦茨制冷机和卡诺制冷机在制冷过程中不可能利用空气能量;使空气能双向蒸发器1的热泵性和空气能双向冷凝器2的超冷凝消失。所以空气能热量循环交换机和热力三角循环机只有在使用制冷工作介质对时,才能获得其最大的性能系数。If the refrigeration working medium pair is changed to a non-azeotropic (NONAZEOTROPIC) mixed refrigerant in the thermodynamic triangle cycle machine, then the thermodynamic triangle cycle in Figure 8 is changed to Lorenz cycle. It can be seen from the figure that the function W L > 2W M ' required by the Laurents cycle; and because the area below the endothermic line 1-2' is smaller than the area below the endothermic line Q1-J-2 of the thermodynamic triangle cycle machine; it can be seen The coefficient of performance (EER) of the thermodynamic triangle cycle machine can be more than two times higher than that of the Lorenz refrigerator. If the working medium of the thermodynamic triangle cycle machine is changed to azeotropic (AZEOTROPIC) refrigerant or a single refrigerant, its performance coefficient EER will be further reduced. Because it is impossible for the Lorenz refrigerator and the Carnot refrigerator to utilize air energy in the refrigeration process; the heat pump of the air energy two-
空气能热量循环交换机可制成窗型机。图9是窗型的空气能热量循环交换机。其中心线以上为空气能双向蒸发器1部分,中心线以下为空气能双向冷凝器2部分。The air energy heat circulation exchanger can be made into a window type machine. Fig. 9 is a window type air energy heat circulation exchanger. Above the center line is
室外自然空气a1被送风扇12驱动通过空气能双向蒸发器1的dyn流道放热至冷峰值温度To的a3输入室内,室内空气a4在排风扇19的抽吸作用下经出风调节窗叶28导向后方在空气能双向冷凝器2的dyn流道的膜式蒸发面6上吸取湿、热后,以a6形态排向大气。空气能双向蒸发器1、空气能双向冷凝器2的回流板27用以分隔dxn流道,以使其制冷工作介质对在微分传热器内呈U字形流动。The outdoor natural air a1 is driven by the
在制冷时喷嘴18定时、定量向空气能双向冷凝器2的膜式蒸发面6喷雾,即润湿膜式蒸发面6。水泵23定时、间歇地向电磁控制阀24送水;电磁控制阀24在制冷时向喷嘴18供水、在制热时则向制热喷嘴26供水。水过滤器22可防止污染物进入供水系统。During cooling, the
空气能热量循环交换机在用作制热(热泵)时:空气能双向蒸发器1仍然相同,只是将冷峰值空气输向室外;空气能双向冷凝器2亦仍相,但要将其形成的热峰值空气输入室内。因此,其整体构成须作如下变换:When the air energy heat circulation exchanger is used as heating (heat pump): the air energy two-
1、将空气能双向蒸发器1、空气能双向冷凝器2的制冷工作介质的入口同时切换为出口,出口同时切换为入口使其制冷工作介质对反向运行。1. Switch the inlet of the refrigeration working medium of the air energy two-
2、使送风扇反向运转而成为排风扇从室内向室外排风,室内空气经空气能双向蒸发器1的dyn流道放热至冷峰值温度排向大气;使排风扇反向运转而成为送风扇,室外新鲜空气经空气能双向冷凝器2的dyn流道吸热、吸湿至热峰值温度输入室内。2. Turn the supply fan in reverse to become an exhaust fan to exhaust air from indoor to outdoor. The indoor air is discharged to the atmosphere through the dyn flow channel of the air energy two-
3、在空气能双向蒸发器1左侧、在空气能双向冷凝器2右侧的制热喷嘴26在电磁控制阀24和水泵23的作用下定时向空气能双向蒸发器1和空气能双向冷凝器2喷雾用以润湿空气能双向冷凝器2的膜式蒸发面并及时化解空气能双向蒸发器1 dyn流道内的积霜。积水盘内可以加入适量丙三醇(GLYCERINE)甘油溶液以增强空气能双向蒸发器1和空气能双向冷凝器2的热交换性能和防止空气能双向蒸发器1 dyn流道形成冰堵。3. The
空气能热量循环交换机、热力三角循环机由于微分传热器的传热温差小,且冷凝温度较低。即使用作劳伦茨循环和卡诺循环时:与现在的市售空调相比也可使其性能系数EER大大提高。Due to the small heat transfer temperature difference of the differential heat transfer device and the low condensation temperature of the air energy heat cycle exchanger and the thermodynamic triangle cycle machine. Even when used as a Lorentz cycle and a Carnot cycle: Compared with the current commercially available air conditioners, the coefficient of performance EER can be greatly improved.
Claims (18)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94106955A CN1114040A (en) | 1994-06-14 | 1994-06-14 | Air energy heat circulation exchanger |
| ZA946528A ZA946528B (en) | 1994-06-14 | 1994-08-26 | Heat circulatory exchanger using air energy |
| AU71499/94A AU7149994A (en) | 1994-06-14 | 1994-08-26 | Heat circulatory exchanger using air energy |
| GB9418432A GB2293441A (en) | 1994-06-14 | 1994-09-13 | Refrigeration/heat-pump apparatus for cooling/heating air |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94106955A CN1114040A (en) | 1994-06-14 | 1994-06-14 | Air energy heat circulation exchanger |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1114040A true CN1114040A (en) | 1995-12-27 |
Family
ID=5032731
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94106955A Pending CN1114040A (en) | 1994-06-14 | 1994-06-14 | Air energy heat circulation exchanger |
Country Status (4)
| Country | Link |
|---|---|
| CN (1) | CN1114040A (en) |
| AU (1) | AU7149994A (en) |
| GB (1) | GB2293441A (en) |
| ZA (1) | ZA946528B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1743666B (en) * | 2004-09-02 | 2011-03-30 | 淄博绿能环保设备科技有限公司 | Temperature-different two-way heat tube transfer steam-current wind-wheel generating device |
| CN103521955A (en) * | 2013-09-27 | 2014-01-22 | 宣浩 | Cooling device for welding equipment |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GR960100355A (en) * | 1996-10-15 | 1998-06-30 | Nutec Electrical Engineering Co. Ltd | High eer air conditioning apparatus with special heat exchanger. |
| BR9612510A (en) * | 1996-12-11 | 1999-12-28 | Springer Carrier Sa | Evaporation module for an air conditioner, and, air conditioner. |
| CA2255181A1 (en) * | 1997-12-02 | 1999-06-02 | Louis J. Bailey | Integrated system for heating, cooling and heat recovery ventilation |
| CN112174241B (en) * | 2020-10-26 | 2024-12-24 | 清华大学 | A porous material thermal distillation water purification system driven by working fluid circulation |
| CN114893715B (en) * | 2022-04-02 | 2023-11-21 | 安徽宇航派蒙健康科技股份有限公司 | Heating control method and device, system, computer equipment and storage medium thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2474666A1 (en) * | 1980-01-24 | 1981-07-31 | Inst Francais Du Petrole | PROCESS FOR PRODUCING HEAT USING A HEAT PUMP USING A MIXTURE OF FLUIDS AS A WORKING AGENT AND AIR AS A SOURCE OF HEAT |
| FR2564955B1 (en) * | 1984-05-28 | 1987-03-20 | Inst Francais Du Petrole | PROCESS FOR PRODUCING HEAT AND / OR COLD USING A COMPRESSION MACHINE OPERATING WITH A MIXED WORKING FLUID |
-
1994
- 1994-06-14 CN CN94106955A patent/CN1114040A/en active Pending
- 1994-08-26 ZA ZA946528A patent/ZA946528B/en unknown
- 1994-08-26 AU AU71499/94A patent/AU7149994A/en not_active Abandoned
- 1994-09-13 GB GB9418432A patent/GB2293441A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1743666B (en) * | 2004-09-02 | 2011-03-30 | 淄博绿能环保设备科技有限公司 | Temperature-different two-way heat tube transfer steam-current wind-wheel generating device |
| CN103521955A (en) * | 2013-09-27 | 2014-01-22 | 宣浩 | Cooling device for welding equipment |
Also Published As
| Publication number | Publication date |
|---|---|
| ZA946528B (en) | 1996-02-27 |
| AU7149994A (en) | 1995-12-21 |
| GB9418432D0 (en) | 1994-11-02 |
| GB2293441A (en) | 1996-03-27 |
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