CN111334107A - Coating and working solution for 3D painting and preparation and use methods thereof - Google Patents
Coating and working solution for 3D painting and preparation and use methods thereof Download PDFInfo
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- CN111334107A CN111334107A CN202010326058.0A CN202010326058A CN111334107A CN 111334107 A CN111334107 A CN 111334107A CN 202010326058 A CN202010326058 A CN 202010326058A CN 111334107 A CN111334107 A CN 111334107A
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- 238000000576 coating method Methods 0.000 title claims abstract description 58
- 239000011248 coating agent Substances 0.000 title claims abstract description 56
- 238000010422 painting Methods 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims description 18
- 239000012224 working solution Substances 0.000 title claims description 16
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000049 pigment Substances 0.000 claims abstract description 22
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 21
- 150000001718 carbodiimides Chemical class 0.000 claims abstract description 16
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004744 fabric Substances 0.000 claims abstract description 11
- 239000000835 fiber Substances 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims description 29
- 239000003973 paint Substances 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 5
- 238000007598 dipping method Methods 0.000 claims 1
- 238000007711 solidification Methods 0.000 claims 1
- 230000008023 solidification Effects 0.000 claims 1
- 239000012209 synthetic fiber Substances 0.000 claims 1
- 229920002994 synthetic fiber Polymers 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 9
- 230000001070 adhesive effect Effects 0.000 abstract description 9
- 238000007665 sagging Methods 0.000 abstract description 7
- 230000032683 aging Effects 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 5
- 238000001035 drying Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 4
- 239000012860 organic pigment Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- MOVRNJGDXREIBM-UHFFFAOYSA-N aid-1 Chemical compound O=C1NC(=O)C(C)=CN1C1OC(COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)CO)C(O)C1 MOVRNJGDXREIBM-UHFFFAOYSA-N 0.000 description 1
- -1 aliphatic carboxylate Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The inventor provides a coating for 3D painting, which comprises the following components in parts by mass: 90-100 parts of polyurethane resin and 3-8 parts of carbodiimide curing agent; 1-8 parts by mass of pigment. The coating has good aging resistance and strong base material adhesive force, and solves the problem of adhesive force of the water-based pigment on cloth fibers; the carbodiimide is used as a curing agent and is matched with a blender containing water and an alcohol ether auxiliary agent when in use, the opening period is very long after the carbodiimide is independently mixed with polyurethane resin, and the storage time of the coating is 6-12 months. The prepared coating has reasonable viscosity, good anti-sagging performance, normal-temperature curing and convenient use.
Description
Technical Field
The invention relates to the field of painting supplies, in particular to a 3D painting coating, a working solution, and preparation and application methods thereof.
Background
At present, the pigments for art painting are mainly divided into water-based pigments and oil-based pigments. Oily pigments have a large odor, contain a large amount of organic solvents and even harmful substances, have large environmental pollution and poor environmental protection, and are replaced by aqueous pigments gradually.
The prior commonly used water-based pigments are divided into two types, one type is slurry which is formed by directly dispersing inorganic or organic pigments by using water as a medium, but the picture coating has the problems of over-strong rigidity, easy cracking and powder removal, weak adhesive force on the coated surface, easy shedding for a long time and the like.
The other is inorganic or organic pigment slurry taking water-based acrylic resin as a carrier, although the slurry has strong adhesive force, the slurry has poor adhesive force to textile base materials, poor wear resistance, poor bending resistance, poor durability and easy oxidation, and aging phenomena such as yellowing, fading, staining, pulverization and the like easily occur for a long time, wherein the organic pigment has bright color and is particularly caused by poor acrylic resin performance and poor aging resistance of the organic pigment.
The current water-based pigment for art painting has the problem of weak sagging resistance, and is suitable for painting with a coating of less than 1 mm; and the coating is more than 1mm, and the 3D picture with three-dimensional effect is easy to sag.
Disclosure of Invention
Therefore, the 3D painting coating which has strong adhesion with the fabric surface and good durability, wear resistance, bending resistance and sagging resistance, and the preparation and use methods thereof are needed.
In order to achieve the above purpose, the inventor provides a coating for 3D painting, which comprises the following components in parts by mass: 90-100 parts of waterborne polyurethane resin and 3-8 parts of carbodiimide curing agent; 1-8 parts by mass of pigment.
Further, the viscosity of the coating is 60000 and 80000 mpa.s.
Further, the coating is sealed and stored after vacuum defoaming, and the effective period is 6-12 months.
The inventor also provides a preparation method of the coating for 3D painting, which comprises the following steps: adding 90-100 parts by mass of waterborne polyurethane resin, 3-8 parts by mass of carbodiimide curing agent and 1-8 parts by mass of pigment into a reaction kettle, and uniformly dispersing to obtain the 3D painting paint.
Further, the dispersion time of the coating for 3D painting is 5-20 minutes.
The inventor further provides a working solution for 3D painting, which is obtained by uniformly blending any one of the coatings with 0-20 wt% of a matched blender; the preparation method of the matching agent comprises the following steps: adding 60-80 parts by mass of water and 10-30 parts by mass of alcohol ether auxiliary agent into a reaction kettle, and dispersing uniformly to obtain the matched blender.
Further, the dispersion time of the matching agent is 5-10 minutes.
The inventor provides a using method of working solution for 3D painting, the working solution is dipped by a painting brush to paint on cloth fibers, and the thickness of a picture coating after curing is 0.5-5 mm.
Further, the picture coating has a tack-free time of 0.4 to 0.8 hours at 20 to 30 ℃.
Compared with the prior art, the technical scheme develops a reasonable polyurethane water-based pigment formula system, adopts the water-based polyurethane resin as the main component of the coating, has a stable chemical structure, can provide good aging resistance and physical properties for the coating, has strong adhesive force to a fabric substrate, and solves the problem of adhesive force of the water-based pigment on cloth fibers; the carbodiimide is used as a curing agent and is matched with a blender containing water and an alcohol ether auxiliary agent when in use, the open period is very long after the carbodiimide is independently mixed with the waterborne polyurethane resin, the storage time of the coating is 6-12 months, the defect that a bi-component pigment containing the curing agent needs to be prepared and used on site when in use is solved, and the problem of material waste caused by untimely use is greatly reduced. The prepared coating has reasonable viscosity, good anti-sagging performance, normal-temperature curing and convenient use.
Detailed Description
In order to explain technical contents, structural features, and objects and effects of the technical means in detail, the following detailed description is given with reference to specific embodiments.
The alcohol ether auxiliary agent is an oxygen-containing solvent, mainly low-carbon alcohol ether of ethylene glycol and propylene glycol. The alcohol ether auxiliary agent has ether bond and hydroxyl; the former has lipophilicity and can dissolve polar compounds, and the latter has hydrophilicity and can dissolve water-soluble compounds. The alcohol ether auxiliary agent is mixed with other solvents in the solvent paint for use, and can keep the leveling property of a coating film after most of the solvents are volatilized. The alcohol ether type auxiliary agent has good compatibility with water, and is widely used for water-based paint.
The carbodiimide curing agent used in the present embodiment is a carbodiimide curing agent of scott.
In the embodiment, the blending auxiliary agent 1 is dodecanol, the blending auxiliary agent 2 is ethanol, the blending auxiliary agent 3 is glycerol ether, and the blending auxiliary agent 4 is aliphatic carboxylate.
Example 1
Adding 95 parts by mass of waterborne polyurethane resin, 5 parts by mass of carbodiimide curing agent and 2 parts by mass of pigment into a reaction kettle, and uniformly dispersing for 10 minutes to obtain the 3D painting paint. The viscosity of the coating is 60000 and 80000 mpa.s.
Adding 68 parts by mass of water, 5 parts by mass of blending aid 1, 12 parts by mass of blending aid 2, 5 parts by mass of blending aid 3 and 10 parts by mass of blending aid 4 into a reaction kettle, and dispersing uniformly for 5min to obtain the matched blending agent 1.
And uniformly mixing 95 wt% of coating and 5 wt% of matching blender 1 to obtain the working solution.
Painting on the cloth by using the working solution, wherein after the picture is dried, the picture coating is firmly combined and has good sagging resistance, and the thickness of the coating is 1-3 mm; the surface drying time of the picture coating at 20-30 ℃ is 0.4-0.8 hour, and the actual drying time of the coating is 6 days. (the surface dry time testing method is a finger touch method, and the actual dry time is based on the stable time of the performance test)
In some embodiments, the drying can also be carried out at 50-70 ℃, the surface drying time is 0.2-0.3h, and the actual drying time is 3 days.
Example 2
Adding 90 parts by mass of waterborne polyurethane resin, 3 parts by mass of carbodiimide curing agent and 1 part by mass of pigment into a reaction kettle, and uniformly dispersing for 10 minutes to obtain the 3D painting paint. The viscosity of the coating is 60000 and 80000 mpa.s.
Adding 68 parts by mass of water, 5 parts by mass of blending auxiliary agents 1, 12 parts by mass of blending auxiliary agents 2, 5 parts by mass of blending auxiliary agents 3 and 10 parts by mass of blending auxiliary agents 4 into a reaction kettle, and uniformly dispersing for 10min to obtain a matched blending agent 2.
And uniformly mixing 90 wt% of coating and 10 wt% of matching blender 2 to obtain the working solution.
Painting on the cloth with the working liquid, drying the picture, combining the picture coating firmly, coating the thickness of the coating to be 1-5mm, surface drying time of the picture coating at 20-30 ℃ to be 0.4-0.8 h, and the actual drying time of the whole coating to be 7 days. (the surface dry time testing method is a finger touch method, and the actual dry time is based on the stable time of the performance test)
Example 3
100 parts by mass of waterborne polyurethane resin, 8 parts by mass of carbodiimide curing agent and 8 parts by mass of pigment are added into a reaction kettle, and the paint for 3D painting is obtained after uniform dispersion for 20 minutes. The viscosity of the coating is 60000 and 80000 mpa.s.
Adding 68 parts by mass of water, 5 parts by mass of blending auxiliary agents 1, 12 parts by mass of blending auxiliary agents 2, 5 parts by mass of blending auxiliary agents 3 and 10 parts by mass of blending auxiliary agents 4 into a reaction kettle, and dispersing uniformly for 8min to obtain a matched blending agent 3.
And (3) uniformly mixing 85 wt% of the coating with 15 wt% of the matching blender 3 to obtain the working solution. Painting on the cloth with the working liquid, drying the picture, combining the picture coating firmly, wherein the coating thickness is 0.5-2mm, the surface drying time at 20-30 ℃ in the picture coating is 0.4-0.5 h, and the actual drying time of the whole coating is 5 days. (the surface dry time testing method is a finger touch method, and the actual dry time is based on the stable time of the performance test)
Example 4
The difference between the embodiment 4 and the embodiment 1 is that the working solution in the embodiment 4 is not added with a matched blender, and the pattern drawn on the surface of the cloth by the working solution in the embodiment 4 has the coating thickness of 2-5mm, so that the coating effect is stronger in stereoscopic impression, the concave-convex surface is clear, the texture is thick, the color is bright, and the line edge angle is more prominent.
The coatings of examples 1 to 4 were stored in a sealed and dark place at normal temperature, and were not cured within 12 months, and were still usable. The coating is stable to water, does not react with water, can be blended by a blending system taking water as a main body, reduces the damage of the traditional oily blending agent to painters, has the coating thickness of 5mm, good anti-sagging performance and obvious 3D effect, and is suitable for 3D painting.
According to the technical scheme, a reasonable polyurethane water-based pigment formula system is developed, polyurethane resin is used as a main component of the coating, the stable chemical structure of the polyurethane resin can provide good aging resistance and physical properties for the coating, the adhesive force of the base material is strong, and the problem of the adhesive force of the water-based pigment on cloth fibers is solved; the carbodiimide is used as a curing agent and is matched with a blending agent containing water and an alcohol ether auxiliary agent when in use, the opening period is very long after the carbodiimide is independently mixed with polyurethane resin, the storage time of the coating is 6-12 months, the defect that a bi-component pigment containing the curing agent needs to be prepared and used on site when in use is solved, and the problem of material waste caused by untimely use is greatly reduced. The prepared coating has reasonable viscosity, good anti-sagging performance, normal-temperature curing and convenient use.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or terminal that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or terminal. Without further limitation, an element defined by the phrases "comprising … …" or "comprising … …" does not exclude the presence of additional elements in a process, method, article, or terminal that comprises the element. Further, herein, "greater than," "less than," "more than," and the like are understood to exclude the present numbers; the terms "above", "below", "within" and the like are to be understood as including the number.
It should be noted that, although the above embodiments have been described herein, the invention is not limited thereto. Therefore, based on the innovative concepts of the present invention, the technical solutions of the present invention can be directly or indirectly applied to other related technical fields by making changes and modifications to the embodiments described herein or by using equivalent structures or equivalent processes performed in the present specification, and are included in the scope of the present invention.
Claims (9)
1. The coating for 3D painting is characterized by comprising the following components in parts by mass: 90-100 parts of waterborne polyurethane resin and 3-8 parts of carbodiimide curing agent; 1-8 parts by mass of pigment.
2. The coating of claim 1, wherein the coating has a viscosity of 60000 and 80000 mpa.s.
3. The paint of claim 1, wherein the paint is hermetically stored after vacuum defoaming, and the effective period is 6-12 months.
4. A method of preparing a paint for 3D painting according to claim 1, comprising the steps of: adding 90-100 parts by mass of waterborne polyurethane resin, 3-8 parts by mass of carbodiimide curing agent and 1-8 parts by mass of pigment into a reaction kettle, and uniformly dispersing to obtain the 3D painting paint.
5. The method according to claim 4, wherein the 3D paint has a dispersion time of 5-20 minutes.
6. The working solution for 3D painting is characterized by being prepared by uniformly blending the coating of any one of claims 1 to 3 and 0 to 20 weight percent of matched blending agent; the preparation method of the matching agent comprises the following steps: adding 60-80 parts by mass of water and 10-30 parts by mass of alcohol ether auxiliary agent into a reaction kettle, and uniformly mixing to obtain the matched blender.
7. A drawing working solution according to claim 6, wherein the dispersion time of the matching blender is 5-10 minutes.
8. A use method of working solution for 3D painting is characterized in that a painting brush is used for dipping the working solution to paint on natural fiber or synthetic fiber cloth, and the thickness of a picture coating after solidification is 0.5-5 mm.
9. Use according to claim 8, wherein the top dry time of the picture coating at 20-30 ℃ is 0.4-0.8 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010326058.0A CN111334107A (en) | 2020-04-23 | 2020-04-23 | Coating and working solution for 3D painting and preparation and use methods thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010326058.0A CN111334107A (en) | 2020-04-23 | 2020-04-23 | Coating and working solution for 3D painting and preparation and use methods thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111334107A true CN111334107A (en) | 2020-06-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202010326058.0A Pending CN111334107A (en) | 2020-04-23 | 2020-04-23 | Coating and working solution for 3D painting and preparation and use methods thereof |
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| CN (1) | CN111334107A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114262561A (en) * | 2021-12-10 | 2022-04-01 | 福建华峰运动用品科技有限公司 | Fiber-containing coating, application and cloth with 3D and fiber effects |
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| CN114262561A (en) * | 2021-12-10 | 2022-04-01 | 福建华峰运动用品科技有限公司 | Fiber-containing coating, application and cloth with 3D and fiber effects |
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Application publication date: 20200626 |