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CN1112383C - 用含取代茚基的金属配合物制备的烯烃聚合物 - Google Patents

用含取代茚基的金属配合物制备的烯烃聚合物 Download PDF

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Publication number
CN1112383C
CN1112383C CN98805626A CN98805626A CN1112383C CN 1112383 C CN1112383 C CN 1112383C CN 98805626 A CN98805626 A CN 98805626A CN 98805626 A CN98805626 A CN 98805626A CN 1112383 C CN1112383 C CN 1112383C
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CN
China
Prior art keywords
dimethyl
alkyl
silane titanium
titanium
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN98805626A
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English (en)
Chinese (zh)
Other versions
CN1258303A (zh
Inventor
L·T·卡尔
D·D·范德伦德
P·N·尼卡斯
J·T·巴顿·
J·C·史蒂文斯
D·R·帕里克
D·J·曼戈尔德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of CN1258303A publication Critical patent/CN1258303A/zh
Application granted granted Critical
Publication of CN1112383C publication Critical patent/CN1112383C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Paints Or Removers (AREA)
CN98805626A 1997-05-01 1998-05-01 用含取代茚基的金属配合物制备的烯烃聚合物 Expired - Fee Related CN1112383C (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US4541097P 1997-05-01 1997-05-01
US4534897P 1997-05-01 1997-05-01
US60/045,348 1997-05-01
US60/045,410 1997-05-10
PCT/US1998/008859 WO1998049211A1 (en) 1997-05-01 1998-05-01 Olefin polymers prepared with substituted indenyl containing metal complexes

Publications (2)

Publication Number Publication Date
CN1258303A CN1258303A (zh) 2000-06-28
CN1112383C true CN1112383C (zh) 2003-06-25

Family

ID=26722669

Family Applications (1)

Application Number Title Priority Date Filing Date
CN98805626A Expired - Fee Related CN1112383C (zh) 1997-05-01 1998-05-01 用含取代茚基的金属配合物制备的烯烃聚合物

Country Status (14)

Country Link
EP (1) EP0977787A1 (pt)
JP (1) JP2001522399A (pt)
KR (1) KR20010020425A (pt)
CN (1) CN1112383C (pt)
AR (1) AR012645A1 (pt)
AU (1) AU742617B2 (pt)
BR (1) BR9808704A (pt)
CA (1) CA2288893A1 (pt)
NO (1) NO995294L (pt)
PL (1) PL336594A1 (pt)
RU (1) RU2200169C2 (pt)
TR (1) TR199902884T2 (pt)
TW (1) TW375624B (pt)
WO (1) WO1998049211A1 (pt)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2666708T3 (es) * 1998-11-02 2018-05-07 Dow Global Technologies Llc Interpolímeros reo-fluidificantes de etileno/alfa-olefina y su preparación
US7524911B2 (en) 2004-03-17 2009-04-28 Dow Global Technologies Inc. Adhesive and marking compositions made from interpolymers of ethylene/α-olefins
CN1976965B (zh) * 2004-03-17 2012-10-10 陶氏环球技术有限责任公司 用于形成乙烯多嵌段共聚物的包含梭移剂的催化剂组合物
RU2364606C2 (ru) * 2004-12-23 2009-08-20 Чайна Петролеум и Кемикал Корпорейшен Катализатор для полимеризации олефинов и его использование
US7989543B2 (en) * 2005-03-17 2011-08-02 Dow Global Technologies Llc Adhesive and marking compositions made from interpolymers of ethylene/α-olefins
AR055880A1 (es) 2005-03-17 2007-09-12 Dow Global Technologies Inc Fibras hechas con polimeros de propileno alfa-oleofinas, metodo de obtencion de dichas fibras, hilado y genero que comprende dichas fibras
JP5226973B2 (ja) * 2007-06-15 2013-07-03 三井化学株式会社 エチレン系共重合体、該共重合体を含む組成物ならびにその用途
JP5858935B2 (ja) * 2010-03-02 2016-02-10 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマー組成物
JP5574916B2 (ja) * 2010-10-26 2014-08-20 三井化学株式会社 オレフィン重合体の製造方法
WO2015046705A1 (ko) 2013-09-26 2015-04-02 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 중합체의 제조방법
KR101603016B1 (ko) 2013-09-26 2016-03-11 주식회사 엘지화학 촉매 조성물 및 이를 포함하는 중합체의 제조방법
US9376519B2 (en) 2013-09-26 2016-06-28 Lg Chem, Ltd. Transition metal compound, catalytic composition including the same, and method for preparing polymer using the same
EP3053954B1 (en) * 2013-10-30 2023-12-06 LG Chem, Ltd. Modified olefin resin
JP6702854B2 (ja) * 2014-02-28 2020-06-03 三井化学株式会社 架橋体とその製造方法および用途、ならびにエチレン系共重合体
JP6739435B2 (ja) 2015-01-06 2020-08-12 エスシージー ケミカルズ カンパニー，リミテッド ＳｉＯ２−層状複水酸化物ミクロスフェアおよびその作製方法
KR102054466B1 (ko) * 2015-12-22 2019-12-11 주식회사 엘지화학 전이금속 화합물을 포함하는 촉매 조성물 및 이를 이용한 중합체의 제조방법
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
US11952480B2 (en) 2018-02-05 2024-04-09 Exxonmobil Chemical Patents Inc. Enhanced processability of LLDPE by addition of ultra-high molecular weight density polyethylene
EP3970989A4 (en) * 2019-05-17 2023-05-24 Bridgestone Corporation MULTI-COMPONENT COPOLYMER, RUBBER COMPOSITION, RESIN COMPOSITION, TIRE AND RESIN PRODUCT

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993008221A2 (en) * 1991-10-15 1993-04-29 The Dow Chemical Company Elastic substantially linear olefin polymers
CN1076457A (zh) * 1992-02-28 1993-09-22 斯菲里玲有限公司 弹性体乙烯共聚物的制备方法
WO1995014024A1 (en) * 1993-11-18 1995-05-26 Idemitsu Kosan Co., Ltd. Transition metal compound, olefin polymerization catalyst, and process for producing olefin polymer by using said catalyst

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8702902A (nl) * 1987-04-06 1988-11-01 Stamicarbon Etheencopolymeer.
JPH0777754B2 (ja) * 1987-07-07 1995-08-23 三井石油化学工業株式会社 ストレッチ包装用フィルム
RU2073018C1 (ru) * 1989-08-31 1997-02-10 Дзе Дау Кемикал Компани Металлический координационный комплекс, катализатор для ионно-координационной полимеризации, способ ионно-координационной полимеризации
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
EP0705269B1 (en) * 1993-06-24 1997-01-15 The Dow Chemical Company Titanium(ii) or zirconium(ii) complexes and addition polymerization catalysts therefrom
US5447895A (en) * 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts
DE19522013A1 (de) * 1995-06-21 1997-01-02 Hoechst Ag Übergangsmetallverbindung
PL186283B1 (pl) * 1995-10-27 2003-12-31 Dow Chemical Co Kompleks metalu zawierający podstawiony indenyl, koordynacyjny katalizator do polimeryzacji i sposób polimeryzacji koordynacyjnej

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993008221A2 (en) * 1991-10-15 1993-04-29 The Dow Chemical Company Elastic substantially linear olefin polymers
CN1076457A (zh) * 1992-02-28 1993-09-22 斯菲里玲有限公司 弹性体乙烯共聚物的制备方法
WO1995014024A1 (en) * 1993-11-18 1995-05-26 Idemitsu Kosan Co., Ltd. Transition metal compound, olefin polymerization catalyst, and process for producing olefin polymer by using said catalyst

Also Published As

Publication number Publication date
AR012645A1 (es) 2000-11-08
AU7173998A (en) 1998-11-24
CN1258303A (zh) 2000-06-28
EP0977787A1 (en) 2000-02-09
JP2001522399A (ja) 2001-11-13
WO1998049211A1 (en) 1998-11-05
BR9808704A (pt) 2000-07-11
PL336594A1 (en) 2000-07-03
RU2200169C2 (ru) 2003-03-10
NO995294D0 (no) 1999-10-29
TR199902884T2 (xx) 2000-09-21
AU742617B2 (en) 2002-01-10
CA2288893A1 (en) 1998-11-05
TW375624B (en) 1999-12-01
KR20010020425A (ko) 2001-03-15
NO995294L (no) 1999-12-29

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