CN111185079B - 一种焚烧烟气中酸性气体的资源化处理方法 - Google Patents
一种焚烧烟气中酸性气体的资源化处理方法 Download PDFInfo
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- CN111185079B CN111185079B CN201911228360.6A CN201911228360A CN111185079B CN 111185079 B CN111185079 B CN 111185079B CN 201911228360 A CN201911228360 A CN 201911228360A CN 111185079 B CN111185079 B CN 111185079B
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- flue gas
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- incineration
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- 239000003546 flue gas Substances 0.000 title claims abstract description 107
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 103
- 239000007789 gas Substances 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 33
- 239000002253 acid Substances 0.000 title claims abstract description 31
- 238000010521 absorption reaction Methods 0.000 claims abstract description 172
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 97
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 40
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 235000010265 sodium sulphite Nutrition 0.000 claims abstract description 19
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 13
- 239000011593 sulfur Substances 0.000 claims abstract description 13
- 239000002699 waste material Substances 0.000 claims abstract description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000460 chlorine Substances 0.000 claims abstract description 8
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 8
- 230000002378 acidificating effect Effects 0.000 claims abstract description 7
- 238000004064 recycling Methods 0.000 claims abstract description 7
- 238000004939 coking Methods 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 33
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000003513 alkali Substances 0.000 claims description 12
- 239000000428 dust Substances 0.000 claims description 11
- 239000012452 mother liquor Substances 0.000 claims description 9
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- 238000010791 quenching Methods 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- 239000000295 fuel oil Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 239000010742 number 1 fuel oil Substances 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 238000004056 waste incineration Methods 0.000 abstract description 12
- 238000000746 purification Methods 0.000 abstract description 7
- PODWXQQNRWNDGD-UHFFFAOYSA-L sodium thiosulfate pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-]S([S-])(=O)=O PODWXQQNRWNDGD-UHFFFAOYSA-L 0.000 abstract description 6
- 150000007513 acids Chemical class 0.000 abstract description 3
- 239000013064 chemical raw material Substances 0.000 abstract description 3
- 239000002894 chemical waste Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 239000002910 solid waste Substances 0.000 abstract description 3
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 42
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 42
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000004065 wastewater treatment Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 238000012824 chemical production Methods 0.000 description 2
- 239000010813 municipal solid waste Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000009469 supplementation Effects 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/507—Sulfur oxides by treating the gases with other liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1406—Multiple stage absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
- B01D53/502—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/64—Thiosulfates; Dithionites; Polythionates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
- C01D5/14—Preparation of sulfites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/304—Alkali metal compounds of sodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/204—Inorganic halogen compounds
- B01D2257/2045—Hydrochloric acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Treating Waste Gases (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911228360.6A CN111185079B (zh) | 2019-12-04 | 2019-12-04 | 一种焚烧烟气中酸性气体的资源化处理方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911228360.6A CN111185079B (zh) | 2019-12-04 | 2019-12-04 | 一种焚烧烟气中酸性气体的资源化处理方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111185079A CN111185079A (zh) | 2020-05-22 |
| CN111185079B true CN111185079B (zh) | 2022-02-08 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201911228360.6A Active CN111185079B (zh) | 2019-12-04 | 2019-12-04 | 一种焚烧烟气中酸性气体的资源化处理方法 |
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| Country | Link |
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| CN (1) | CN111185079B (zh) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118874189B (zh) * | 2024-07-03 | 2025-11-25 | 深圳市场渡技术有限公司 | 一种垃圾焚烧烟气净化方法和设备 |
Citations (8)
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|---|---|---|---|---|
| CN101176837A (zh) * | 2006-11-10 | 2008-05-14 | 湖北汉海矿业投资有限公司 | 石煤钒矿焙烧废气的控制与治理新工艺 |
| CN102079734A (zh) * | 2009-11-26 | 2011-06-01 | 浙江启明药业有限公司 | 一种工业化生产四氯苯酐的循环经济综合处理方法 |
| CN106076067A (zh) * | 2016-08-03 | 2016-11-09 | 安徽八化工股份有限公司 | 一种用于处理氯化苯生产中尾气的装置 |
| CN208626950U (zh) * | 2018-08-08 | 2019-03-22 | 株洲中车南方环保科技有限公司 | 一种小型垃圾焚烧炉烟气吸附塔 |
| CN109795990A (zh) * | 2018-12-07 | 2019-05-24 | 常州齐晖药业有限公司 | 一种综合处理二氧化硫废气和硫化碱废水的方法 |
| CN109843415A (zh) * | 2016-08-18 | 2019-06-04 | 太平洋绿色科技股份有限公司 | 集成湿式洗涤系统 |
| CN110314500A (zh) * | 2019-06-21 | 2019-10-11 | 光大绿色环保管理(深圳)有限公司 | 一种湿法脱酸的设备及方法 |
| CN110508101A (zh) * | 2019-09-02 | 2019-11-29 | 南京圣创科技有限公司 | 一种多区变温吸收的高效烟气脱硫方法及装置 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2415064A1 (en) * | 2002-12-23 | 2004-06-23 | Nova Chemicals Corporation | Selective chemical binding for olefins/paraffins separation |
| US7772449B2 (en) * | 2007-08-01 | 2010-08-10 | Stone & Webster Process Technology, Inc. | Removal of acid gases and sulfur compounds from hydrocarbon gas streams in a caustic tower |
| CN101332408A (zh) * | 2008-06-24 | 2008-12-31 | 常熟富士莱医药化工有限公司 | 硫辛酸生产中的氯化氢与二氧化硫混合废气的回收装置 |
| CN104645785A (zh) * | 2013-11-22 | 2015-05-27 | 杨继群 | 一种氯化氢和二氧化硫混合气体的分离回收方法 |
| KR102472112B1 (ko) * | 2014-10-24 | 2022-11-28 | 리써치 트라이앵글 인스티튜트 | 가스 스트림으로부터 산 가스를 제거하기 위한 통합 시스템 및 방법 |
| ES2722750T3 (es) * | 2014-12-19 | 2019-08-16 | Outotec Finland Oy | Procedimiento y planta para la producción energéticamente eficaz y mejorada de ácido sulfúrico |
-
2019
- 2019-12-04 CN CN201911228360.6A patent/CN111185079B/zh active Active
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| CN101176837A (zh) * | 2006-11-10 | 2008-05-14 | 湖北汉海矿业投资有限公司 | 石煤钒矿焙烧废气的控制与治理新工艺 |
| CN102079734A (zh) * | 2009-11-26 | 2011-06-01 | 浙江启明药业有限公司 | 一种工业化生产四氯苯酐的循环经济综合处理方法 |
| CN106076067A (zh) * | 2016-08-03 | 2016-11-09 | 安徽八化工股份有限公司 | 一种用于处理氯化苯生产中尾气的装置 |
| CN109843415A (zh) * | 2016-08-18 | 2019-06-04 | 太平洋绿色科技股份有限公司 | 集成湿式洗涤系统 |
| CN208626950U (zh) * | 2018-08-08 | 2019-03-22 | 株洲中车南方环保科技有限公司 | 一种小型垃圾焚烧炉烟气吸附塔 |
| CN109795990A (zh) * | 2018-12-07 | 2019-05-24 | 常州齐晖药业有限公司 | 一种综合处理二氧化硫废气和硫化碱废水的方法 |
| CN110314500A (zh) * | 2019-06-21 | 2019-10-11 | 光大绿色环保管理(深圳)有限公司 | 一种湿法脱酸的设备及方法 |
| CN110508101A (zh) * | 2019-09-02 | 2019-11-29 | 南京圣创科技有限公司 | 一种多区变温吸收的高效烟气脱硫方法及装置 |
Non-Patent Citations (1)
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