CN111171965B - 一种运行清洗多功能复合清洗液 - Google Patents
一种运行清洗多功能复合清洗液 Download PDFInfo
- Publication number
- CN111171965B CN111171965B CN202010063652.5A CN202010063652A CN111171965B CN 111171965 B CN111171965 B CN 111171965B CN 202010063652 A CN202010063652 A CN 202010063652A CN 111171965 B CN111171965 B CN 111171965B
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- CN
- China
- Prior art keywords
- acid
- cleaning
- inhibitor
- cleaning solution
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000004140 cleaning Methods 0.000 title claims abstract description 70
- 239000002131 composite material Substances 0.000 title claims abstract description 29
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003112 inhibitor Substances 0.000 claims abstract description 22
- 102000004190 Enzymes Human genes 0.000 claims abstract description 21
- 108090000790 Enzymes Proteins 0.000 claims abstract description 21
- 150000007524 organic acids Chemical class 0.000 claims abstract description 12
- 108010010803 Gelatin Proteins 0.000 claims abstract description 11
- 229920000159 gelatin Polymers 0.000 claims abstract description 11
- 239000008273 gelatin Substances 0.000 claims abstract description 11
- 235000019322 gelatine Nutrition 0.000 claims abstract description 11
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 11
- FUVKFLJWBHVMHX-UHFFFAOYSA-N 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonamide Chemical compound NS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F FUVKFLJWBHVMHX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 230000000149 penetrating effect Effects 0.000 claims description 21
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 19
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 18
- 102000004882 Lipase Human genes 0.000 claims description 14
- 108090001060 Lipase Proteins 0.000 claims description 14
- 239000004367 Lipase Substances 0.000 claims description 14
- -1 alkyl aminopropionic acid Chemical compound 0.000 claims description 14
- 235000019421 lipase Nutrition 0.000 claims description 14
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 12
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 12
- 239000001630 malic acid Substances 0.000 claims description 12
- 235000011090 malic acid Nutrition 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 12
- 229960003237 betaine Drugs 0.000 claims description 11
- 102000003855 L-lactate dehydrogenase Human genes 0.000 claims description 10
- 108700023483 L-lactate dehydrogenases Proteins 0.000 claims description 10
- 108091005804 Peptidases Proteins 0.000 claims description 10
- 239000004365 Protease Substances 0.000 claims description 10
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 9
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 9
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 9
- 239000005642 Oleic acid Substances 0.000 claims description 9
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 9
- 235000010323 ascorbic acid Nutrition 0.000 claims description 9
- 239000011668 ascorbic acid Substances 0.000 claims description 9
- 229960005070 ascorbic acid Drugs 0.000 claims description 9
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 9
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 235000021313 oleic acid Nutrition 0.000 claims description 6
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 6
- 239000001632 sodium acetate Substances 0.000 claims description 6
- 235000017281 sodium acetate Nutrition 0.000 claims description 6
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000001509 sodium citrate Substances 0.000 claims description 5
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 5
- 239000001540 sodium lactate Substances 0.000 claims description 5
- 235000011088 sodium lactate Nutrition 0.000 claims description 5
- 229940005581 sodium lactate Drugs 0.000 claims description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- 229940070765 laurate Drugs 0.000 claims description 3
- 229940049964 oleate Drugs 0.000 claims description 3
- 235000011056 potassium acetate Nutrition 0.000 claims description 3
- 235000011083 sodium citrates Nutrition 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- ZWGSXIDHYSLQGT-UHFFFAOYSA-N 3-hydroxypropyl dimethyl phosphate Chemical compound P(=O)(OCCCO)(OC)OC ZWGSXIDHYSLQGT-UHFFFAOYSA-N 0.000 claims description 2
- OABYVIYXWMZFFJ-ZUHYDKSRSA-M sodium glycocholate Chemical compound [Na+].C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCC([O-])=O)C)[C@@]2(C)[C@@H](O)C1 OABYVIYXWMZFFJ-ZUHYDKSRSA-M 0.000 claims description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 8
- 239000007788 liquid Substances 0.000 abstract description 5
- 230000007774 longterm Effects 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 29
- 238000005260 corrosion Methods 0.000 description 12
- 230000007797 corrosion Effects 0.000 description 12
- 239000012459 cleaning agent Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 6
- 229940082004 sodium laurate Drugs 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 5
- 230000005764 inhibitory process Effects 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 108010088351 lactate dehydrogenase 4 Proteins 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 description 3
- 239000005750 Copper hydroxide Substances 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 229910001956 copper hydroxide Inorganic materials 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- GNHOJBNSNUXZQA-UHFFFAOYSA-J potassium aluminium sulfate dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GNHOJBNSNUXZQA-UHFFFAOYSA-J 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000010865 sewage Substances 0.000 description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 2
- WBEHKXQILJKFIN-UHFFFAOYSA-N 2-amino-2-methyltetradecanoic acid Chemical compound CCCCCCCCCCCCC(C)(N)C(O)=O WBEHKXQILJKFIN-UHFFFAOYSA-N 0.000 description 2
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 239000001506 calcium phosphate Substances 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 235000011010 calcium phosphates Nutrition 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000001119 stannous chloride Substances 0.000 description 2
- 235000011150 stannous chloride Nutrition 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229940083575 sodium dodecyl sulfate Drugs 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
-
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Abstract
本发明涉及工业设备化学清洗技术领域，具体涉及一种运行清洗多功能复合清洗液。所述复合清洗液由以下组分组成：盐酸，有机酸，全氟丁基磺酰胺，渗透剂A，渗透剂B，抑制剂，有机硅，酶，pH调节剂，明胶，水余量。本发明具有高效去除水垢，同时处理周期时间短，腐蚀性低，可以长期或大量使用的优点。
Description
技术领域
本发明涉及工业设备化学清洗技术领域，具体涉及一种运行清洗多功能复合清洗液。
背景技术
水垢的主要成分有碳酸钙、碳酸镁、硫酸钙、磷酸钙、硅酸钙、油脂类及蛋白质等有机组分。水垢导热性很差，会降低传热效率，从而浪费燃料或电力，并且，水垢如果附着在热力设备受热面上时都将危及热力设备的安全、经济运行。
发明专利申请CN 102251247A涉及一种化学清洗剂，具体涉及一种复合型水垢锈垢清洗剂，包括缓蚀剂、水基表面活性剂和水，按照质量百分数计，由以下原料配制而成：缓蚀剂0.3％-1％、水基表面活性剂0.05-0.1％、水80-94％、无机酸5％-15％和羟基乙酸1％-5％。本发明采用无机酸和羟基乙酸按一定比例组合，可有效地综合各种酸洗清洗剂的优点，保证除垢效率的同时又可防止对管道和设备的腐蚀。使用此发明所述清洗剂能将水垢、锈垢等多种复杂垢从设备中彻底地清除下来而不腐蚀设备，提高设备的换热效率，同时具有应用范围广、无污染、腐蚀率低、配制工艺简单、使用方便安全等特点，宜于广泛采用。但是其腐蚀率较大，且无法处理水垢样品中的蛋白质和油脂类杂质，所以在使用过程中存在一定的局限性。
发明专利申请CN1026187A涉及一种原油集输系统(输油管道、加热炉、压力容器等)高效油水垢清洗剂。此种清洗剂采用盐酸、由选自水基表面活性剂中的有机胺盐、聚氧化乙烯烷基酸、十二烷基磺酸钠的任一种或二种以上的混合物、缓蚀剂丁炔二醇和碘化钠混合物以及水组成。利用此种清洗剂可以高效地清除结垢，达到疏管畅流、提高热效率、降低输油压力的目的，还可用于油井解堵增产。此种清洗剂具有应用范围广、腐蚀性低、配制工艺简单、使用方便安全等特点，宜于广泛采用。但是其组分挥发性强，这不仅会降低化学清洗液中除垢组分的有效浓度，而且由于酸雾的形成会对设备空腔以及整个管路产生严重的气相腐蚀。不适长期使用。
发明专利申请CN1074953A涉及一种发动机水垢清洗剂，采用重量百分比37.1-65.2％的草酸，34.2-62.5％的含氯离子金属盐和0.25-1.37％的乌洛托品混合配制而成。使用该专利申请的清洗剂除垢效果好，清洗过程简便，并且能在发动机照常运行中完成清洗工作，能够大大提高汽车的使用效率。此发明具有以下优点：1.高效，以本品的水溶液加入发动机水冷却系统，静置或者运行5-8小时，然后放出水洗，除垢效果高达95％以上；安全，因本品配方经过反复筛选，实验证明本配方对各类金属有良好的保护和防蚀作用，经上百次实验(包括钢铁、铸件及有色金属类浸片实验)，对金属类是安全的；方便储运使用，因本品采用固体配方，原料无毒，无腐蚀，不易燃，所以在储存、运输，使用当中十分安全，使用简便，只按比例溶水，即可使用，利于推广使用；成本低廉；基本上对环境无污染，因本配方无毒配制，使用后的废水基本无毒，符合国家标准。但是清洗周期长，草酸与水垢反应较慢，另外，腐蚀性较高，对于金属制管路有损伤作用，不利于大量使用，也不利于长期使用。
现在，还没有一种运行清洗多功能复合清洗液，可以高效去除水垢，同时处理周期时间短，腐蚀性低，可以长期或大量使用。
发明内容
为了解决现有技术没有一种运行清洗多功能复合清洗液，可以高效去除水垢，同时处理周期时间短，腐蚀性低，可以长期或大量使用的问题，本发明提供一种运行清洗多功能复合清洗液。
一种运行清洗多功能复合清洗液，由以下组分组成：盐酸，有机酸，全氟丁基磺酰胺，渗透剂A，渗透剂B，抑制剂，有机硅，酶，pH调节剂，明胶，水余量。
进一步地，由以下质量百分比组分组成：盐酸1-2％，有机酸20-25％，全氟丁基磺酰胺0.3-0.5％，渗透剂A1-2％，渗透剂B 2-4％，抑制剂0.8-1％，有机硅0.3-0.5％，酶0.1-0.5％，pH调节剂5-10％，明胶5-10％，水余量。
进一步地，由以下质量百分比组分组成：盐酸1-1.5％，有机酸20-22％，全氟丁基磺酰胺0.3-0.4％，渗透剂A1-1.5％，渗透剂B 2-3％，抑制剂0.8-1％，有机硅0.3-0.4％，酶0.1-0.3％，pH调节剂5-8％，明胶8-10％，水余量。
进一步地，由以下质量百分比组分组成：盐酸1.5％，有机酸22％，全氟丁基磺酰胺0.4％，渗透剂A1.5％，渗透剂B 3％，抑制剂0.8％，有机硅0.4％，酶0.3％，pH调节剂8％，明胶8％，水余量。
进一步地，按重量份计，渗透剂A：渗透剂B＝1:1-2。
进一步地，按重量份计，渗透剂A：渗透剂B＝1:2。
进一步地，所述有机酸为多元膦酸、苹果酸、抗坏血酸、油酸中的两种或三种。
进一步地，所述有机酸为多元膦酸和苹果酸。两种酸之间可发生协同作用，提高水垢的去除效率。
进一步地，所述有机酸为苹果酸、抗坏血酸和油酸。三种酸之间可发生协同作用，提高水垢的去除效率。
进一步地，所述渗透剂A为十二烷基苯磺酸钠、甘胆酸钠、十二烷基硫酸钠、油酸盐、月桂酸盐中的一种或多种。
进一步地，所述渗透剂A为油酸盐、月桂酸盐中的一种或多种。
进一步地，所述渗透剂B为两性离子表面活性剂。
进一步地，所述渗透剂B为十二烷基氨基丙酸、烷基二甲基甜菜碱、烷基二甲基磺乙基甜菜碱或烷基二甲基羟丙基磷酸脂甜菜碱中的一种或多种。
进一步地，所述抑制剂为Fe3+抑制剂、Cu2+抑制剂、Al3+抑制剂中的至少一种。
进一步地，所述Fe3+抑制剂为盐酸羟胺、氯化亚锡中的一种。
进一步地，所述Cu2+抑制剂为氢氧化铜或氯化铜中的一种。
更进一步地，所述Cu2+抑制剂为氢氧化铜。
进一步地，所述Al3+抑制剂为氢氧化铝、十二水硫酸铝钾或氯化铜中的一种。
更进一步地，所述Al3+抑制剂为十二水硫酸铝钾。
进一步地，所述有机硅为聚二甲基硅氧烷、氟硅氧烷或乙二醇硅氧烷中的任一种。
进一步地，所述酶为蛋白酶、脂肪酶和乳酸脱氢酶的混合物。
进一步地，所述酶按重量份数计，为蛋白酶：脂肪酶：乳酸脱氢酶＝(4-6)：(2-3)：1。
进一步地，所述酶按重量份数计，为蛋白酶：脂肪酶：乳酸脱氢酶＝4：2：1。
进一步地，所述pH调节剂为醋酸钠、醋酸钾、柠檬酸钠、乳酸钠中的一种或多种。
进一步地，所述pH调节剂为乳酸钠和柠檬酸钠。
进一步地，所述pH调节剂为醋酸钠。
本发明所述的一种运行清洗多功能复合清洗液的制备方法为将所有组分进行混合即得。
水垢的主要成分有碳酸钙、碳酸镁、硫酸钙、磷酸钙、硅酸钙等，同时还有少量蛋白质和油脂类物质附着在管壁。本发明为了得到一种去垢速度快，效率高，去垢完全，腐蚀性低的清洗液，付出了创造性劳动，得到了较好的技术效果。
本发明采用无机酸和有机酸进行复配，并优化了有机酸的种类，有利于进一步提高除垢效率，同时降低对管道和设备的腐蚀。
本发明采用两种渗透剂复配使用的方式。由于水垢固定于管壁十分牢固，需要渗透剂使其松动。本发明采用渗透剂A和渗透剂B进行复配，对于松动水垢有非常明显的效果。如果仅采用一种渗透剂，效果较差。另外，如果选用其他类型渗透剂进行复配，例如非离子表面活性剂等，与本发明的渗透剂相比，对水垢的松动效果较差。
另外，本发明还优化了渗透剂A与渗透剂B的质量配比，在合适的质量配比下，二者复配使用具有更好的水垢清理效果。
本发明还使用了pH调节剂，优选为醋酸钠或乳酸钠和柠檬酸钠的组合物。pH调节剂采用弱酸进行调节有助于清洗液中的离子缓慢释放，达到不腐蚀管道的目的。
本发明还创造性地添加了酶，可以更好地促进分解水垢中残留的蛋白质、油脂等杂质，同时，也有利于减小管道与水垢之间的附着力，使得水垢可以更容易松动和脱落，缩短了水垢去除时间。
本发明的复合清洗液在去垢的同时，还具有一定的阻垢效果，尤其是本发明的复配渗透剂、明胶与其它组分共同作用，避免了设备后续运行过程中设备和管道内部结垢。
与现有技术对比，本发明的有益效果是：
1.大大缩短了水垢去除时间；
2.高温清洗时，无机强酸盐酸的挥发性显著降低，化学清洗液中除垢组分的有效浓度相对较大；
3.高温运行清洗时酸雾产生量小，很大程度上避免了设备空腔以及整个管路的气相腐蚀；
4.清洗工序简单，节水，节能；
5.排出污水pH呈中性，无需酸碱中和，易于处理达标，且不会排放到周围环境中造成污染；
6.避免设备后续运行过程中设备和管道内部结垢。
具体实施方式
下面结合具体实施例来进一步描述本发明，本发明的优点和特点将会随着描述而更为清楚，但这些实施例仅是范例性的，并不对本发明的范围构成任何限制。本领域技术人员应该理解的是，在不偏离本发明的精神和范围下可以对本发明技术方案的细节和形式进行修改或替换，但这些修改和替换均落入本发明的保护范围内。
实施例1
一种运行清洗多功能复合清洗液，由以下质量百分比组分组成：盐酸1％，羟基亚乙基二膦酸10％，苹果酸10％，全氟丁基磺酰胺0.3％，十二烷基苯磺酸钠2％，十二烷基氨基丙酸2％，氯化亚锡0.8％，聚二甲基硅氧烷0.3％，酶0.1％，醋酸钠5％，明胶5％，水余量。
酶为蛋白酶、脂肪酶和乳酸脱氢酶的混合物，按重量份数计，为蛋白酶：脂肪酶：乳酸脱氢酶＝4：2：1；
将上述组分混合均匀即得运行清洗多功能复合清洗液。
实施例2
一种运行清洗多功能复合清洗液，由以下质量百分比组分组成：盐酸2％，苹果酸8％，抗坏血酸8％，油酸9％，全氟丁基磺酰胺0.5％，月桂酸钠2％，烷基二甲基甜菜碱4％，氢氧化铝1％，氟硅氧烷0.5％，酶0.5％，醋酸钾10％，明胶10％，水余量。
酶为蛋白酶、脂肪酶和乳酸脱氢酶的混合物，按重量份数计，为蛋白酶：脂肪酶：乳酸脱氢酶＝6：3：1；
将上述组分混合均匀即得运行清洗多功能复合清洗液。
实施例3
一种运行清洗多功能复合清洗液，由以下质量百分比组分组成：盐酸1.5％，氨基三亚甲基膦酸11％，苹果酸11％，全氟丁基磺酰胺0.4％，油酸钠1.5％，烷基二甲基甜菜碱3％，氢氧化铜0.8％，乙二醇硅氧烷0.4％，酶0.3％，乳酸钠4％，柠檬酸钠4％，明胶8％，水余量。
酶为蛋白酶、脂肪酶和乳酸脱氢酶的混合物，按重量份数计，为蛋白酶：脂肪酶：乳酸脱氢酶＝4：2：1；
将上述组分混合均匀即得运行清洗多功能复合清洗液。
实施例4
一种运行清洗多功能复合清洗液，由以下质量百分比组分组成：盐酸1.5％，苹果酸7％，抗坏血酸7％，油酸8％，全氟丁基磺酰胺0.4％，月桂酸钠1.5％，烷基二甲基磺乙基甜菜碱3％，十二水硫酸铝钾0.8％，聚二甲基硅氧烷0.4％，酶0.3％，醋酸钠8％，明胶8％，水余量。
酶为蛋白酶、脂肪酶和乳酸脱氢酶的混合物，按重量份数计，为蛋白酶：脂肪酶：乳酸脱氢酶＝4：2：1；
将上述组分混合均匀即得运行清洗多功能复合清洗液。
对比例1
与实施例4的区别仅在于不添加酶，其余条件均相同。
对比例3
与实施例4的区别仅在于蛋白酶、脂肪酶和乳酸脱氢酶的质量比为1:2:4，其余条件均相同。
对比例4
与实施例4的区别仅在于将苹果酸、抗坏血酸和油酸的混合物替换为等量的苹果酸，其余条件均相同。
对比例5
与实施例4的区别仅在于将苹果酸、抗坏血酸和油酸的混合物替换为等量的抗坏血酸，其余条件均相同。
对比例6
与实施例4的区别仅在于将苹果酸、抗坏血酸和油酸的混合物替换为等量的油酸，其余条件均相同。
对比例7
与实施例4的区别仅在于将月桂酸钠和烷基二甲基磺乙基甜菜碱的混合物替换为等量的月桂酸钠，其余条件均相同。
对比例8
与实施例4的区别仅在于保持月桂酸钠和烷基二甲基磺乙基甜菜碱的混合物总量不变，月桂酸钠和烷基二甲基磺乙基甜菜碱的质量比为2:1，其余条件均相同。
对比例9
与实施例4的区别仅在于将烷基二甲基磺乙基甜菜碱替换为等量的TX-100(TX-100为非离子表面活性剂)，其余条件均相同。
测试例1
按照GB/T25146-2010《工业设备化学清洗质量验收规范》，对实施例1-4和对比例1-9的运行清洗多功能复合清洗液进行洗净率(清洗0.5h)的测试，结果如表1所示。
表1实施例1-4和对比例1-9洗净率测试结果
| 1mm水垢洗净率(％) | |
| 实施例1 | 96 |
| 实施例2 | 98 |
| 实施例3 | 100 |
| 实施例4 | 100 |
| 对比例1 | 72 |
| 对比例3 | 84 |
| 对比例4 | 81 |
| 对比例5 | 83 |
| 对比例6 | 78 |
| 对比例7 | 82 |
| 对比例8 | 88 |
| 对比例9 | 85 |
测试例2
按照GB/T25146-2010《工业设备化学清洗质量验收规范》，对实施例1-4和对比例4-6的运行清洗多功能复合清洗液进行腐蚀率(碳钢)的测试，结果如表2所示。
表2实施例1-4和对比例4-6腐蚀率测试结果
| 腐蚀率(g/(m<sup>2</sup>·h)) | |
| 实施例1 | 0.0238 |
| 实施例2 | 0.0184 |
| 实施例3 | 0.0155 |
| 实施例4 | 0.0119 |
| 对比例4 | 0.0316 |
| 对比例5 | 0.0524 |
| 对比例6 | 0.0480 |
测试例3
碳酸钙阻垢率测试
在500mL的容量瓶中依次加入3mL 40mg/L氯化钙溶液、5mL48.8mg/L碳酸氢钠溶液，加入1g实施例1-4和对比例7-9的运行清洗多功能复合清洗液，加入去离子水定容摇匀。将容量瓶放入多孔恒温水浴锅中，设定温度为80℃，加热10h后取出容量瓶，将取出的容量瓶自然冷却后吸取上层澄清液体分析并测定其中的钙离子含量，计算实施例1-4和对比例7-9的阻垢率。结果如表3所示。
表3实施例1-4和对比例7-9阻垢率测试结果
| 阻垢率(％) | |
| 实施例1 | 98.7 |
| 实施例2 | 99.1 |
| 实施例3 | 99.4 |
| 实施例4 | 99.6 |
| 对比例7 | 82.5 |
| 对比例8 | 88.3 |
| 对比例9 | 85.2 |
本发明方案所公开的技术手段不仅限于上述所公开的技术手段，还包括由以上技术特征任意组合所组成的技术方案。以上所述是本发明的具体实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以作出若干改进和修饰，这些也将视为本发明的保护范围。
Claims (4)
1.一种运行清洗多功能复合清洗液，其特征在于，由以下质量百分比组分组成：盐酸1-2％，有机酸20-25％，全氟丁基磺酰胺0.3-0.5％，渗透剂A 1-2％，渗透剂B 2-4％，抑制剂0.8-1％，有机硅0.3-0.5％，酶0.1-0.5％，pH调节剂5-10％，明胶5-10％，水余量；
所述渗透剂A为十二烷基苯磺酸钠、甘胆酸钠、十二烷基硫酸钠、油酸盐、月桂酸盐中的一种或多种；所述渗透剂B为十二烷基氨基丙酸、烷基二甲基甜菜碱、烷基二甲基磺乙基甜菜碱或烷基二甲基羟丙基磷酸脂甜菜碱中的一种或多种；按重量份计，渗透剂A：渗透剂B＝1:1-2；
所述酶为蛋白酶、脂肪酶和乳酸脱氢酶的混合物；所述酶按重量份数计，为蛋白酶：脂肪酶：乳酸脱氢酶＝(4-6)：(2-3)：1；
所述有机酸为多元膦酸、苹果酸、抗坏血酸、油酸中的两种或三种。
2.根据权利要求1所述的复合清洗液，其特征在于，所述抑制剂为Fe3+抑制剂、Cu2+抑制剂、Al3+抑制剂中的至少一种。
3.根据权利要求1所述的复合清洗液，其特征在于，所述有机硅为聚二甲基硅氧烷、氟硅氧烷或乙二醇硅氧烷中的任一种。
4.根据权利要求1所述的复合清洗液，其特征在于，所述pH调节剂为醋酸钠、醋酸钾、柠檬酸钠、乳酸钠中的一种或多种。
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