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CN111162074B - Semiconductor structure and method of forming the same - Google Patents

Semiconductor structure and method of forming the same Download PDF

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CN111162074B
CN111162074B CN201811321624.8A CN201811321624A CN111162074B CN 111162074 B CN111162074 B CN 111162074B CN 201811321624 A CN201811321624 A CN 201811321624A CN 111162074 B CN111162074 B CN 111162074B
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CN111162074A (en
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王楠
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Semiconductor Manufacturing International Shanghai Corp
Semiconductor Manufacturing International Beijing Corp
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D84/00Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
    • H10D84/80Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs
    • H10D84/82Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components
    • H10D84/83Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components of only insulated-gate FETs [IGFET]
    • H10D84/85Complementary IGFETs, e.g. CMOS
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D62/00Semiconductor bodies, or regions thereof, of devices having potential barriers
    • H10D62/60Impurity distributions or concentrations
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D84/00Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
    • H10D84/01Manufacture or treatment
    • H10D84/0123Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
    • H10D84/0126Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
    • H10D84/0165Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs the components including complementary IGFETs, e.g. CMOS devices
    • H10D84/0195Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs the components including complementary IGFETs, e.g. CMOS devices the components including vertical IGFETs
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D84/00Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
    • H10D84/01Manufacture or treatment
    • H10D84/02Manufacture or treatment characterised by using material-based technologies
    • H10D84/03Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology
    • H10D84/038Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology using silicon technology, e.g. SiGe

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Abstract

一种半导体结构及其形成方法,形成方法包括:形成基底,基底包括PMOS区,基底包括衬底以及凸出于衬底的半导体柱,PMOS区的半导体柱包括第一半导体柱以及位于第一半导体柱上的第二半导体柱,第二半导体柱中Ge的摩尔体积百分比大于第一半导体柱中Ge的摩尔体积百分比;在PMOS区第一半导体柱的底部内形成PMOS漏区;形成PMOS漏区后,形成包围半导体柱的栅极结构,PMOS区的栅极结构覆盖第一半导体柱和第二半导体柱的交界处且露出第二半导体柱的顶部,被栅极结构覆盖的半导体柱作为沟道层;形成栅极结构后,在第二半导体柱的顶部内形成PMOS源区。本发明实施例有利于改善PMOS晶体管的稳定性问题,比如热载流子效应以及自发热效应等。

Figure 201811321624

A semiconductor structure and a method for forming the same, the forming method includes: forming a base, the base includes a PMOS region, the base includes a substrate and a semiconductor pillar protruding from the substrate, the semiconductor pillar in the PMOS region includes a first semiconductor pillar and a semiconductor pillar located in the first semiconductor In the second semiconductor column on the column, the molar volume percentage of Ge in the second semiconductor column is greater than the molar volume percentage of Ge in the first semiconductor column; a PMOS drain region is formed in the bottom of the first semiconductor column in the PMOS region; after the PMOS drain region is formed , forming a gate structure surrounding the semiconductor column, the gate structure of the PMOS region covers the junction of the first semiconductor column and the second semiconductor column and exposes the top of the second semiconductor column, and the semiconductor column covered by the gate structure serves as the channel layer ; After the gate structure is formed, a PMOS source region is formed in the top of the second semiconductor pillar. The embodiments of the present invention are beneficial to improve the stability of the PMOS transistor, such as the hot carrier effect and the self-heating effect.

Figure 201811321624

Description

半导体结构及其形成方法Semiconductor structure and method of forming the same

技术领域technical field

本发明涉及半导体制造领域,尤其涉及一种半导体结构及其形成方法。The present invention relates to the field of semiconductor manufacturing, and in particular, to a semiconductor structure and a method for forming the same.

背景技术Background technique

随着半导体制造技术的飞速发展,半导体器件朝着更高的元件密度,以及更高集成度的方向发展,半导体工艺节点遵循摩尔定律的发展趋势不断减小。晶体管作为最基本的半导体器件目前正被广泛应用,因此随着半导体器件的元件密度和集成度的提高,为了适应工艺节点的减小,不得不断缩短晶体管的沟道长度。With the rapid development of semiconductor manufacturing technology, semiconductor devices are developing in the direction of higher component density and higher integration, and the development trend of semiconductor process nodes following Moore's Law is decreasing. As the most basic semiconductor device, transistors are currently being widely used. Therefore, with the increase in the component density and integration of semiconductor devices, in order to adapt to the reduction of process nodes, the channel length of transistors must be continuously shortened.

晶体管沟道长度的缩短具有增加芯片的管芯密度,增加开关速度等好处。然而随着沟道长度的缩短,晶体管源极与漏极间的距离也随之缩短,栅极对沟道的控制能力变差,使亚阈值漏电(subthreshold leakage)现象,即所谓的短沟道效应(short-channeleffects,SCE)更容易发生,晶体管的沟道漏电流增大。The shortening of the transistor channel length has the benefit of increasing the die density of the chip, increasing the switching speed, etc. However, with the shortening of the channel length, the distance between the source and the drain of the transistor is also shortened, and the gate's ability to control the channel becomes worse, resulting in the phenomenon of subthreshold leakage, the so-called short channel. Effects (short-channel effects, SCE) are more likely to occur, and the channel leakage current of the transistor increases.

因此,为了更好的适应器件尺寸按比例缩小的要求,半导体工艺逐渐开始从平面晶体管向具有更高功效的三维立体式的晶体管过渡,如全包围栅极 (Gate-all-around,GAA)晶体管。全包围栅极晶体管中,栅极从四周包围沟道所在的区域,与平面晶体管相比,全包围栅极晶体管的栅极对沟道的控制能力更强,能够更好的抑制短沟道效应。全包围栅极晶体管包括横向全包围栅极(Lateral Gate-all-around,LGAA)晶体管和垂直全包围栅极(Vertical Gate-all-around,VGAA)晶体管,其中,VGAA的沟道在垂直于衬底表面的方向上延伸,有利于提高半导体结构的面积利用效率,因此有利于实现更进一步的特征尺寸缩小。Therefore, in order to better meet the requirement of scaling down the device size, the semiconductor process gradually begins to transition from planar transistors to three-dimensional transistors with higher power efficiency, such as gate-all-around (GAA) transistors . In a fully surrounding gate transistor, the gate surrounds the area where the channel is located. Compared with a planar transistor, the gate of a fully surrounding gate transistor has stronger control over the channel and can better suppress short-channel effects. . All-around gate transistors include lateral gate-all-around (LGAA) transistors and vertical gate-all-around (VGAA) transistors, wherein the channel of VGAA is perpendicular to the lining. Extending in the direction of the bottom surface is beneficial to improve the area utilization efficiency of the semiconductor structure, and thus is beneficial to achieve further feature size reduction.

发明内容SUMMARY OF THE INVENTION

本发明实施例解决的问题是提供一种半导体结构及其形成方法,优化半导体器件的性能。The problem solved by the embodiments of the present invention is to provide a semiconductor structure and a method for forming the same, so as to optimize the performance of the semiconductor device.

为解决上述问题,本发明实施例提供一种半导体结构的形成方法,包括:形成基底,包括PMOS区,所述基底包括衬底以及凸出于所述衬底的半导体柱,所述PMOS区的半导体柱包括第一半导体柱以及位于所述第一半导体柱上的第二半导体柱,所述第二半导体柱中Ge的摩尔百分比大于所述第一半导体柱中Ge的摩尔百分比;在所述PMOS区第一半导体柱的底部内形成PMOS 漏区;形成所述PMOS漏区后,形成包围所述半导体柱的栅极结构,所述PMOS 区的栅极结构覆盖所述第一半导体柱和第二半导体柱的交界处且露出所述第二半导体柱的顶部,被所述栅极结构覆盖的所述半导体柱作为沟道层;形成所述栅极结构后,在所述第二半导体柱的顶部内形成PMOS源区。To solve the above problem, an embodiment of the present invention provides a method for forming a semiconductor structure, including: forming a substrate including a PMOS region, the substrate including a substrate and a semiconductor pillar protruding from the substrate, and the PMOS region has The semiconductor pillar includes a first semiconductor pillar and a second semiconductor pillar located on the first semiconductor pillar, the mole percentage of Ge in the second semiconductor pillar is greater than the mole percentage of Ge in the first semiconductor pillar; in the PMOS A PMOS drain region is formed in the bottom of the first semiconductor pillar; after the PMOS drain region is formed, a gate structure surrounding the semiconductor pillar is formed, and the gate structure of the PMOS region covers the first semiconductor pillar and the second semiconductor pillar. At the junction of the semiconductor pillars and exposing the top of the second semiconductor pillar, the semiconductor pillar covered by the gate structure serves as a channel layer; after the gate structure is formed, on the top of the second semiconductor pillar A PMOS source region is formed within.

相应的,本发明实施例还提供一种半导体结构,包括:基底,所述基底包括PMOS区,所述基底包括衬底以及凸出于所述衬底的半导体柱,所述 PMOS区的半导体柱包括第一半导体柱以及位于所述第一半导体柱上的第二半导体柱,所述第二半导体柱中Ge的摩尔百分比大于所述第一半导体柱中 Ge的摩尔百分比;PMOS漏区,位于所述PMOS区第一半导体柱的底部内;栅结构,包围所述半导体柱,所述栅极结构覆盖所述第一半导体柱和第二半导体柱的交界处且露出所述第二半导体柱的顶部,被所述栅极结构覆盖的所述半导体柱作为沟道层;PMOS源区,位于所述第二半导体柱的顶部内。Correspondingly, an embodiment of the present invention further provides a semiconductor structure, comprising: a base, the base includes a PMOS region, the base includes a substrate and a semiconductor pillar protruding from the substrate, the semiconductor pillar of the PMOS region comprising a first semiconductor column and a second semiconductor column located on the first semiconductor column, the mole percentage of Ge in the second semiconductor column is greater than the mole percentage of Ge in the first semiconductor column; the PMOS drain region is located in the the bottom of the first semiconductor pillar in the PMOS region; a gate structure surrounding the semiconductor pillar, the gate structure covering the junction of the first semiconductor pillar and the second semiconductor pillar and exposing the top of the second semiconductor pillar , the semiconductor pillar covered by the gate structure serves as a channel layer; the PMOS source region is located in the top of the second semiconductor pillar.

与现有技术相比,本发明实施例的技术方案具有以下优点:Compared with the prior art, the technical solutions of the embodiments of the present invention have the following advantages:

本发明实施例中所述PMOS区的半导体柱包括第一半导体柱以及位于第一半导体柱上的第二半导体柱,所述第二半导体柱中Ge的摩尔百分比大于第一半导体柱中Ge的摩尔百分比,后续在所述半导体柱内形成沟道层、在PMOS 区第一半导体柱的底部内形成PMOS漏区以及在第二半导体柱的顶部内形成 PMOS源区后,所述PMOS区靠近源区的沟道层中Ge的摩尔百分比大于靠近漏区的沟道层中Ge的摩尔百分比,在半导体领域中,PMOS漏区电压通常高于源区,因此靠近漏区的沟道层中电场更强,通过使所述PMOS区靠近源区的沟道层中Ge的摩尔百分比较高,有利于提高PMOS晶体管靠近源区的沟道层载流子的迁移率,从而提升PMOS晶体管的电学性能;通过使所述PMOS 区靠近漏区的沟道层中Ge的摩尔百分比较低,有利于使PMOS区靠近漏区的沟道层载流子的迁移率较低,从而有利于改善PMOS晶体管靠近漏区的沟道层的热载流子效应(Hot Carrier Effect,HCI)以及自发热效应(Self-HeatingEffect,SHE)等稳定性问题,进而提升了半导体结构的电学性能。In the embodiment of the present invention, the semiconductor pillar of the PMOS region includes a first semiconductor pillar and a second semiconductor pillar located on the first semiconductor pillar, and the mole percentage of Ge in the second semiconductor pillar is greater than the mole percentage of Ge in the first semiconductor pillar After the channel layer is subsequently formed in the semiconductor pillar, the PMOS drain region is formed in the bottom of the first semiconductor pillar in the PMOS region, and the PMOS source region is formed in the top of the second semiconductor pillar, the PMOS region is close to the source region The mole percentage of Ge in the channel layer is greater than the mole percentage of Ge in the channel layer near the drain region. In the semiconductor field, the voltage of the PMOS drain region is usually higher than that of the source region, so the electric field in the channel layer near the drain region is stronger. , by making the molar percentage of Ge in the channel layer of the PMOS region close to the source region higher, it is beneficial to improve the mobility of carriers in the channel layer of the PMOS transistor close to the source region, thereby improving the electrical performance of the PMOS transistor; The molar percentage of Ge in the channel layer of the PMOS region close to the drain region is lower, which is beneficial to make the mobility of carriers in the channel layer of the PMOS region close to the drain region lower, thereby helping to improve the PMOS transistor close to the drain region. The stability problems such as Hot Carrier Effect (HCI) and Self-Heating Effect (SHE) of the channel layer of the channel layer are improved, thereby improving the electrical performance of the semiconductor structure.

附图说明Description of drawings

图1是一种半导体结构的结构示意图;1 is a schematic structural diagram of a semiconductor structure;

图2是另一种半导体结构的结构示意图;2 is a schematic structural diagram of another semiconductor structure;

图3至图9是本发明半导体结构的形成方法一实施例中各步骤对应的结构示意图。3 to 9 are schematic structural diagrams corresponding to each step in an embodiment of a method for forming a semiconductor structure of the present invention.

具体实施方式Detailed ways

半导体器件仍有性能不佳的问题。现结合两种半导体结构分析器件性能不佳的原因。Semiconductor devices still suffer from poor performance. The reasons for the poor performance of the device are now analyzed by combining the two semiconductor structures.

参考图1,示出了一种半导体结构的结构示意图。Referring to FIG. 1, a schematic structural diagram of a semiconductor structure is shown.

所述半导体结构包括:基底,包括PMOS区I,所述基底包括衬底10以及凸出于所述衬底10的半导体柱15,所述PMOS区I半导体柱15的材料为 Si;漏区11,位于所述半导体柱15的底部内;栅极结构16,包围所述半导体柱15,所述栅极结构16覆盖半导体柱15且露出半导体柱15顶部,被所述栅极结构16覆盖的半导体柱15作为沟道层12;源区13,位于所述半导体柱15 的顶部内。The semiconductor structure includes: a base including a PMOS region I, the base including a substrate 10 and a semiconductor pillar 15 protruding from the substrate 10 , the material of the semiconductor pillar 15 in the PMOS region I is Si; a drain region 11 , located in the bottom of the semiconductor pillar 15 ; the gate structure 16 surrounds the semiconductor pillar 15 , the gate structure 16 covers the semiconductor pillar 15 and exposes the top of the semiconductor pillar 15 , the semiconductor covered by the gate structure 16 The pillar 15 serves as the channel layer 12 ; the source region 13 is located in the top of the semiconductor pillar 15 .

所述PMOS区I半导体柱15的材料为Si,所述PMOS区I沟道层12的材料相应也为Si,因此所述PMOS晶体管沟道层12的载流子迁移率较低,相应地,所述PMOS晶体管发生热载流子效应以及自发热效应等稳定性问题的概率较低,但是PMOS晶体管沟道层12的载流子迁移率较低容易导致PMOS 晶体管的性能不佳。The material of the PMOS region I semiconductor pillar 15 is Si, and the material of the PMOS region I channel layer 12 is correspondingly Si, so the carrier mobility of the PMOS transistor channel layer 12 is relatively low, and accordingly, The PMOS transistor has a low probability of occurrence of stability problems such as hot carrier effect and self-heating effect, but the low carrier mobility of the PMOS transistor channel layer 12 may easily lead to poor performance of the PMOS transistor.

参考图2,示出了另一种半导体结构的结构示意图。Referring to FIG. 2, a schematic structural diagram of another semiconductor structure is shown.

所述半导体结构与图1中的半导体结构相同之处在此不再赘述。所述半导体结构与图1中的半导体结构的不同之处在于:所述PMOS区I半导体柱 25的材料为SiGe。The semiconductor structure is the same as the semiconductor structure in FIG. 1 and will not be repeated here. The difference between the semiconductor structure and the semiconductor structure in FIG. 1 is that the material of the semiconductor column 25 in the PMOS region I is SiGe.

相应的,所述PMOS区I沟道层22的材料也为SiGe,SiGe材料能够为 PMOS晶体管的沟道层22提供拉应力,因此PMOS晶体管沟道层22的载流子迁移率较高。在半导体领域中,PMOS漏区23的电压通常高于源区21,因此靠近漏区23的沟道层22中电场更强,PMOS晶体管靠近漏区23的沟道层 22中载流子迁移率较高,容易导致PMOS晶体管靠近漏区23的沟道层22内发生热载流子效应以及自发热效应等稳定性问题,从而降低了半导体结构的电学性能。Correspondingly, the material of the I-channel layer 22 in the PMOS region is also SiGe, and the SiGe material can provide tensile stress to the channel layer 22 of the PMOS transistor, so the carrier mobility of the channel layer 22 of the PMOS transistor is high. In the semiconductor field, the voltage of the PMOS drain region 23 is usually higher than that of the source region 21, so the electric field in the channel layer 22 near the drain region 23 is stronger, and the carrier mobility in the channel layer 22 near the drain region 23 of the PMOS transistor is Higher, it is easy to cause stability problems such as hot carrier effect and self-heating effect in the channel layer 22 close to the drain region 23 of the PMOS transistor, thereby reducing the electrical performance of the semiconductor structure.

为了解决所述技术问题,本发明实施例中所述PMOS区的半导体柱包括第一半导体柱以及位于第一半导体柱上的第二半导体柱,所述第二半导体柱中Ge的摩尔百分比大于第一半导体柱中Ge的摩尔百分比,后续在所述半导体柱内形成沟道层、在PMOS区第一半导体柱的底部内形成PMOS漏区以及在第二半导体柱的顶部内形成PMOS源区后,所述PMOS区靠近源区的沟道层中Ge的摩尔百分比大于靠近漏区的沟道层底部中Ge的摩尔百分比,在半导体领域中,PMOS漏区的电压通常高于源区,因此靠近漏区的沟道层中电场更强,通过使所述PMOS区靠近源区的沟道层中Ge的摩尔百分比较高,有利于提高PMOS晶体管靠近源区的沟道层载流子的迁移率,从而提升PMOS 晶体管的电学性能;通过使所述PMOS区靠近漏区的沟道层中Ge的摩尔百分比较低,有利于使PMOS区靠近漏区的沟道层载流子的迁移率较低,从而有利于改善PMOS晶体管靠近漏区的沟道层的热载流子效应以及自发热效应等稳定性问题,进而提升了半导体结构的电学性能。In order to solve the technical problem, in the embodiment of the present invention, the semiconductor pillar of the PMOS region includes a first semiconductor pillar and a second semiconductor pillar located on the first semiconductor pillar, and the mole percentage of Ge in the second semiconductor pillar is greater than that of the first semiconductor pillar. Molar percentage of Ge in a semiconductor pillar, after forming a channel layer in the semiconductor pillar, forming a PMOS drain region in the bottom of the first semiconductor pillar in the PMOS region, and forming a PMOS source region in the top of the second semiconductor pillar, The mole percentage of Ge in the channel layer near the source region of the PMOS region is greater than the mole percentage of Ge in the bottom of the channel layer near the drain region. In the semiconductor field, the voltage of the PMOS drain region is usually higher than the source region, so it is close to the drain region. The electric field in the channel layer of the PMOS region is stronger, and by making the mole percentage of Ge in the channel layer of the PMOS region close to the source region higher, it is beneficial to improve the mobility of carriers in the channel layer of the PMOS transistor close to the source region, Thereby, the electrical performance of the PMOS transistor is improved; by making the mole percentage of Ge in the channel layer of the PMOS region close to the drain region lower, it is beneficial to make the mobility of carriers in the channel layer of the PMOS region close to the drain region lower, Therefore, it is beneficial to improve the stability problems such as the hot carrier effect and the self-heating effect of the channel layer of the PMOS transistor close to the drain region, thereby improving the electrical performance of the semiconductor structure.

为使本发明实施例的上述目的、特征和优点能够更为明显易懂,下面结合附图对本发明的具体实施例做详细的说明。In order to make the above objects, features and advantages of the embodiments of the present invention more clearly understood, specific embodiments of the present invention will be described in detail below with reference to the accompanying drawings.

图3至图9是本发明半导体结构的形成方法一实施例中各步骤对应的结构示意图。3 to 9 are schematic structural diagrams corresponding to each step in an embodiment of a method for forming a semiconductor structure of the present invention.

参考图3至图5,形成基底,包括PMOS区I,所述基底包括衬底112(如图5所示)以及凸出于所述衬底112的半导体柱120(如图5所示),所述PMOS 区I的半导体柱120a包括第一半导体柱113(如图5所示)以及位于所述第一半导体柱113上的第二半导体柱114(如图5所示),所述第二半导体柱114 中Ge的摩尔百分比大于所述第一半导体柱113中Ge的摩尔百分比。Referring to FIGS. 3 to 5 , a base is formed, including the PMOS region I, the base includes a substrate 112 (as shown in FIG. 5 ) and a semiconductor pillar 120 (as shown in FIG. 5 ) protruding from the substrate 112 , The semiconductor pillar 120a of the PMOS region I includes a first semiconductor pillar 113 (as shown in FIG. 5 ) and a second semiconductor pillar 114 (as shown in FIG. 5 ) on the first semiconductor pillar 113 (as shown in FIG. 5 ). The mole percentage of Ge in the semiconductor pillars 114 is greater than the mole percentage of Ge in the first semiconductor pillars 113 .

通过使所述第二半导体柱114中Ge的摩尔百分比大于所述第一半导体柱 113中Ge的摩尔百分比,后续在所述半导体柱120内形成沟道层、在PMOS 区I第一半导体柱113的底部内形成PMOS漏区以及在第二半导体柱114的顶部内形成PMOS源区后,PMOS区I靠近源区的沟道层中Ge的摩尔百分比大于靠近漏区的沟道层中Ge的摩尔百分比,在半导体领域中,PMOS漏区的电压通常高于源区,因此靠近漏区的沟道层中电场更强,通过使PMOS区I 靠近源区的沟道层中Ge的摩尔百分比较高,有利于提高PMOS晶体管靠近源区的沟道层载流子的迁移率;通过使PMOS区I靠近漏区的沟道层中Ge的摩尔百分比较低,有利于使PMOS区I靠近漏区的沟道层载流子的迁移率较低,从而有利于改善PMOS晶体管靠近漏区的沟道层的热载流子效应以及自发热效应等稳定性问题。By making the mole percentage of Ge in the second semiconductor pillar 114 larger than the mole percentage of Ge in the first semiconductor pillar 113 , a channel layer is subsequently formed in the semiconductor pillar 120 and the first semiconductor pillar 113 in the PMOS region I is formed. After the PMOS drain region is formed in the bottom of the second semiconductor pillar 114 and the PMOS source region is formed in the top of the second semiconductor pillar 114, the mole percentage of Ge in the channel layer near the source region of the PMOS region I is greater than the mole percentage of Ge in the channel layer near the drain region. In the semiconductor field, the voltage of the PMOS drain region is usually higher than that of the source region, so the electric field is stronger in the channel layer near the drain region, by making the PMOS region I The mole percentage of Ge in the channel layer near the source region is higher , it is beneficial to improve the mobility of the carriers in the channel layer of the PMOS transistor close to the source region; by making the mole percentage of Ge in the channel layer of the PMOS region I close to the drain region lower, it is beneficial to make the PMOS region I close to the drain region. The mobility of the carriers in the channel layer is low, which is beneficial to improve the stability problems such as the hot carrier effect and the self-heating effect of the channel layer near the drain region of the PMOS transistor.

所述PMOS区I的基底用于形成PMOS晶体管。The base of the PMOS region I is used to form PMOS transistors.

需要说明的是,本实施例中,所述基底还包括NMOS区II,所述NMOS 区II的基底用于形成NMOS晶体管。It should be noted that, in this embodiment, the substrate further includes an NMOS region II, and the substrate of the NMOS region II is used to form an NMOS transistor.

所述衬底112为后续形成半导体结构提供工艺平台。The substrate 112 provides a process platform for subsequent formation of semiconductor structures.

本实施例中,所述衬底112为硅衬底。在其他实施例中,所述衬底的材料还可以为锗、锗化硅、碳化硅、砷化镓或镓化铟,所述衬底还能够为绝缘体上的硅衬底或者绝缘体上的锗衬底。In this embodiment, the substrate 112 is a silicon substrate. In other embodiments, the material of the substrate may also be germanium, silicon germanium, silicon carbide, gallium arsenide or indium gallium, and the substrate may also be a silicon-on-insulator substrate or germanium-on-insulator substrate.

所述半导体柱120用于形成漏区、源区和沟道层。The semiconductor pillars 120 are used to form drain regions, source regions and channel layers.

所述第一半导体柱113用于形成PMOS和NMOS的漏区以及沟道层。The first semiconductor pillars 113 are used to form drain regions and channel layers of PMOS and NMOS.

本实施例中,所述第一半导体柱113与衬底112为通过对同一半导体材料层刻蚀所得到,第一半导体柱113和衬底112相应为一体结构,所述衬底 112的材料相应也为Si。在其他实施例中,根据实际工艺需求,所述第一半导体柱和衬底的材料还可以不同,而且为进一步提高PMOS晶体管的载流子迁移率,所述第一半导体柱的材料可以为SiGe。In this embodiment, the first semiconductor pillars 113 and the substrate 112 are obtained by etching the same semiconductor material layer, the first semiconductor pillars 113 and the substrate 112 are correspondingly integrated, and the materials of the substrate 112 are corresponding Also Si. In other embodiments, according to actual process requirements, the materials of the first semiconductor pillar and the substrate may be different, and in order to further improve the carrier mobility of the PMOS transistor, the material of the first semiconductor pillar may be SiGe .

本实施例中,所述第一半导体柱113为单层结构。也就是说,所述第一半导体柱113仅包括单个半导体层,可以简化艺流程、降低工艺操作难度。In this embodiment, the first semiconductor pillar 113 is a single-layer structure. That is to say, the first semiconductor pillar 113 only includes a single semiconductor layer, which can simplify the process flow and reduce the difficulty of the process operation.

在其他实施例中,所述第一半导体柱还可以包括依次位于衬底上的多个半导体层,并且,在第一半导体柱中,自远离所述第二半导体柱至靠近第二半导体柱的方向,半导体层中Ge的摩尔百分比逐渐增加,因此,所述第一半导体柱中Ge的摩尔百分比自上而下依次降低,有利于进一步改善PMOS晶体管靠近漏区的沟道层的热载流子效应以及自发热效应等稳定性问题。In other embodiments, the first semiconductor pillar may further include a plurality of semiconductor layers sequentially located on the substrate, and, in the first semiconductor pillar, from the distance from the second semiconductor pillar to the position close to the second semiconductor pillar direction, the mole percentage of Ge in the semiconductor layer gradually increases, therefore, the mole percentage of Ge in the first semiconductor column decreases sequentially from top to bottom, which is beneficial to further improve the hot carrier of the channel layer near the drain region of the PMOS transistor effects and self-heating effects.

所述第二半导体柱114用于形成PMOS源区以及沟道层。The second semiconductor pillars 114 are used to form a PMOS source region and a channel layer.

所述第二半导体柱114的材料为SiGe,SiGe材料能够为PMOS晶体管的沟道层提供压应力作用,从而有利于提高PMOS晶体管的载流子迁移率。The material of the second semiconductor pillar 114 is SiGe, and the SiGe material can provide compressive stress to the channel layer of the PMOS transistor, thereby helping to improve the carrier mobility of the PMOS transistor.

需要说明的是,本实施例中,所述第二半导体柱114包括依次位于第一半导体柱113上的多个半导体层(图未示),并且,在所述第二半导体柱114 中,自靠近所述第一半导体柱113至远离第一半导体柱113的方向,半导体层中Ge的摩尔百分比逐渐增加,因此,所述第二半导体柱114中Ge的摩尔百分比自上而下依次降低,有利于进一步提高PMOS晶体管靠近源区的沟道层载流子的迁移率、以及改善PMOS晶体管靠近漏区的沟道层热载流子效应和自发热效应等稳定性问题。在其他实施例中,所述第二半导体柱还可以仅包括单个半导体层,有利于简化工艺流程。It should be noted that, in this embodiment, the second semiconductor column 114 includes a plurality of semiconductor layers (not shown) sequentially located on the first semiconductor column 113, and in the second semiconductor column 114, the The mole percentage of Ge in the semiconductor layer gradually increases from the direction close to the first semiconductor pillar 113 to the direction away from the first semiconductor pillar 113 . Therefore, the mole percentage of Ge in the second semiconductor pillar 114 decreases sequentially from top to bottom. There are It is beneficial to further improve the mobility of carriers in the channel layer of the PMOS transistor near the source region, and to improve the stability issues such as the hot carrier effect and the self-heating effect of the channel layer of the PMOS transistor near the drain region. In other embodiments, the second semiconductor pillar may also include only a single semiconductor layer, which is beneficial to simplify the process flow.

本实施例中,所述NMOS区I的半导体柱120b包括第一半导体柱113以及位于第一半导体柱113上的第三半导体柱115。In this embodiment, the semiconductor pillar 120 b of the NMOS region I includes a first semiconductor pillar 113 and a third semiconductor pillar 115 located on the first semiconductor pillar 113 .

本实施例中,所述第三半导体柱115和第一半导体柱113的材料相同,所述第三半导体柱115的材料相应也为Si,因此所述NMOS区II的半导体柱 120b的材料为Si,不仅有利于提高工艺兼容性,还有利于提高所述NMOS区 II沟道层的载流子迁移率。In this embodiment, the materials of the third semiconductor pillars 115 and the first semiconductor pillars 113 are the same, and the material of the third semiconductor pillars 115 is correspondingly Si. Therefore, the material of the semiconductor pillars 120b of the NMOS region II is Si. , which is not only beneficial to improve the process compatibility, but also to improve the carrier mobility of the II channel layer in the NMOS region.

具体地,形成所述PMOS区I基底的步骤包括:Specifically, the step of forming the PMOS region I substrate includes:

参考图3,提供第一半导体材料层100,在所述第一半导体材料层100上形成第二半导体材料层110,所述第二半导体材料层110中Ge的摩尔百分比大于所述第一半导体材料层100中Ge的摩尔百分比。Referring to FIG. 3 , a first semiconductor material layer 100 is provided, a second semiconductor material layer 110 is formed on the first semiconductor material layer 100 , and the molar percentage of Ge in the second semiconductor material layer 110 is greater than that of the first semiconductor material The mole percent of Ge in layer 100.

所述第一半导体材料层100用于后续形成衬底112和第一半导体柱113。The first semiconductor material layer 100 is used for the subsequent formation of the substrate 112 and the first semiconductor pillars 113 .

所述第二半导体材料层110用于后续形成第二半导体柱114。The second semiconductor material layer 110 is used for the subsequent formation of the second semiconductor pillars 114 .

本实施例中,在所述第一半导体材料层100上形成第二半导体材料层110 的步骤包括:采用外延生长工艺,在所述第一半导体材料层100上依次生长多个半导体材料膜(图未示),所述多个半导体材料膜作为所述第二半导体材料层110。In this embodiment, the step of forming the second semiconductor material layer 110 on the first semiconductor material layer 100 includes: using an epitaxial growth process to sequentially grow a plurality of semiconductor material films on the first semiconductor material layer 100 (Fig. Not shown), the plurality of semiconductor material films serve as the second semiconductor material layers 110 .

通过外延生长工艺得到的薄膜纯度高、缺陷少,而且有利于得到单晶薄膜,有利于提高所述第二半导体材料层110的形成质量。The thin film obtained by the epitaxial growth process has high purity and few defects, and is favorable for obtaining a single crystal thin film and improving the formation quality of the second semiconductor material layer 110 .

本实施例中,所述第二半导体材料层110的材料为SiGe,因此,所述外延生长工艺采用的气体为SiH4、Si2H6、GeH4和Ge2H6气体。通过控制所述 SiH4、Si2H6气体和所述GeH4、Ge2H6气体的比例,从而能够实现在所述外延生长过程中,不同半导体材料膜中Ge的摩尔百分比的变化。In this embodiment, the material of the second semiconductor material layer 110 is SiGe, therefore, the gases used in the epitaxial growth process are SiH 4 , Si 2 H 6 , GeH 4 and Ge 2 H 6 gases. By controlling the ratios of the SiH 4 and Si 2 H 6 gases and the GeH 4 and Ge 2 H 6 gases, changes in the molar percentage of Ge in different semiconductor material films can be achieved during the epitaxial growth process.

需要说明的是,结合参考图4,本实施例中,形成所述第二半导体材料层110后,所述形成方法还包括:去除所述NMOS区II上的第二半导体材料层 110;在所述NMOS区II的第一半导体材料层100上形成第三半导体材料层 111,所述第三半导体材料层111和第一半导体材料层100的材料相同。It should be noted that, referring to FIG. 4 , in this embodiment, after the second semiconductor material layer 110 is formed, the forming method further includes: removing the second semiconductor material layer 110 on the NMOS region II; A third semiconductor material layer 111 is formed on the first semiconductor material layer 100 in the NMOS region II, and the material of the third semiconductor material layer 111 and the first semiconductor material layer 100 is the same.

所述NMOS区II的第一半导体材料层100和所述第三半导体材料层111 用于形成NMOS区II的衬底112和半导体柱120b。The first semiconductor material layer 100 and the third semiconductor material layer 111 in the NMOS region II are used to form the substrate 112 and the semiconductor pillars 120b in the NMOS region II.

本实施例中,所述第一半导体材料层100的材料为Si,所述第三半导体材料层111的材料相应也为Si,后续形成所述NMOS区II的半导体柱120b 后,有利于提高NMOS晶体管的载流子迁移率。In this embodiment, the material of the first semiconductor material layer 100 is Si, and the material of the third semiconductor material layer 111 is correspondingly Si. After the semiconductor pillars 120b of the NMOS region II are formed subsequently, it is beneficial to improve the NMOS The carrier mobility of the transistor.

本实施例中,采用湿法刻蚀工艺,去除所述NMOS区II上的第二半导体材料层110。In this embodiment, a wet etching process is used to remove the second semiconductor material layer 110 on the NMOS region II.

湿法刻蚀工艺具有较高的刻蚀速率,而且湿法刻蚀工艺对SiGe材料和Si 的刻蚀选择比较高,因此有利于将所述NMOS区II的第二半导体材料层110 完全去除,而且能够降低在去除所述NMOS区II的第二半导体材料层110的过程中对所述第一半导体材料层100的损伤。The wet etching process has a high etching rate, and the wet etching process has a relatively high etching selection for SiGe material and Si, so it is beneficial to completely remove the second semiconductor material layer 110 of the NMOS region II, Moreover, damage to the first semiconductor material layer 100 during the process of removing the second semiconductor material layer 110 of the NMOS region II can be reduced.

为提高所述第三半导体材料层111的薄膜质量以及得到单晶薄膜,本实例中,采用外延生长工艺,在所述第一半导体材料层100上形成第三半导体材料层111。In order to improve the film quality of the third semiconductor material layer 111 and obtain a single crystal film, in this example, an epitaxial growth process is used to form the third semiconductor material layer 111 on the first semiconductor material layer 100 .

结合参考图5,形成所述第二半导体材料层110和第三半导体材料层111 后,依次刻蚀所述第二半导体材料层110和所述第一半导体材料层100,在所述PMOS区I上形成衬底112以及凸出于所述衬底112的半导体柱120a。5 , after the second semiconductor material layer 110 and the third semiconductor material layer 111 are formed, the second semiconductor material layer 110 and the first semiconductor material layer 100 are etched in sequence. In the PMOS region I The substrate 112 and the semiconductor pillars 120a protruding from the substrate 112 are formed thereon.

本实施例中,所述基底还包括NMOS区II,因此,在刻蚀所述第二半导体材料层110和所述第一半导体材料层100的步骤中,还依次刻蚀所述NMOS 区II的第三半导体材料层111和第一半导体材料层100,在所述NMOS区II 上形成衬底112和凸出于所述衬底112的半导体柱120b,所述NMOS区II 的半导体柱120b包括第一半导体柱113以及位于所述第一半导体柱113上的第三半导体柱115。In this embodiment, the substrate further includes the NMOS region II. Therefore, in the step of etching the second semiconductor material layer 110 and the first semiconductor material layer 100, the NMOS region II is also etched in sequence. The third semiconductor material layer 111 and the first semiconductor material layer 100, a substrate 112 and a semiconductor pillar 120b protruding from the substrate 112 are formed on the NMOS region II, and the semiconductor pillar 120b in the NMOS region II includes the first A semiconductor pillar 113 and a third semiconductor pillar 115 located on the first semiconductor pillar 113 .

通过在同一步骤中形成PMOS区I和NMOS区II的衬底112以及凸出于所述衬底112的半导体柱120,有利于提高工艺兼容性和工艺制造效率。By forming the substrate 112 of the PMOS region I and the NMOS region II and the semiconductor pillars 120 protruding from the substrate 112 in the same step, it is beneficial to improve process compatibility and process manufacturing efficiency.

本实施例中,采用干法刻蚀工艺,依次刻蚀所述PMOS区I的第二半导体材料层110和所述第一半导体材料层100、以及NMOS区II的第三半导体材料层111和第一半导体材料层100,形成衬底112和凸出于所述衬底112的半导体柱120。In this embodiment, a dry etching process is used to sequentially etch the second semiconductor material layer 110 and the first semiconductor material layer 100 in the PMOS region I, and the third semiconductor material layer 111 and the first semiconductor material layer 111 in the NMOS region II. A semiconductor material layer 100 forms a substrate 112 and semiconductor pillars 120 protruding from the substrate 112 .

干法刻蚀工艺具有较好的刻蚀剖面控制性,有利于使所述半导体柱120 和衬底112的形貌满足工艺需求。在其他实施例中,根据实际工艺需求,还可以采用湿法刻蚀工艺,或者干法和湿法相结合的工艺刻蚀所述PMOS区的第二半导体材料层和第一半导体材料层、以及NMOS区的第三半导体材料层和第一半导体材料层。The dry etching process has better controllability of the etching profile, which is beneficial to make the topography of the semiconductor pillar 120 and the substrate 112 meet the process requirements. In other embodiments, according to actual process requirements, a wet etching process or a combination of dry and wet processes may also be used to etch the second semiconductor material layer and the first semiconductor material layer in the PMOS region, and The third semiconductor material layer and the first semiconductor material layer of the NMOS region.

需要说明的是,本实施例中,所述第二半导体柱114和所述第三半导体柱115上还形成有缓冲层121(如图5所示)以及位于所述缓冲层121上的硬掩膜层122(如图5所示)。It should be noted that, in this embodiment, a buffer layer 121 (as shown in FIG. 5 ) and a hard mask located on the buffer layer 121 are further formed on the second semiconductor pillar 114 and the third semiconductor pillar 115 . Membrane layer 122 (shown in FIG. 5 ).

所述硬掩膜层122用于作为刻蚀所述第二半导体材料层110、第三半导体材料层111、以及第一半导体材料层111以形成所述衬底112和半导体柱120 的刻蚀掩膜,所述硬掩膜层122还能够在后续工艺制程中保护所述半导体柱120顶部。本实施例中,所述硬掩膜层122的材料为氮化硅。The hard mask layer 122 is used as an etching mask for etching the second semiconductor material layer 110 , the third semiconductor material layer 111 , and the first semiconductor material layer 111 to form the substrate 112 and the semiconductor pillar 120 . The hard mask layer 122 can also protect the tops of the semiconductor pillars 120 in subsequent processes. In this embodiment, the material of the hard mask layer 122 is silicon nitride.

氮化硅材料在受热时应力较大,因此通过在所述硬掩膜层122和所述第二半导体柱114之间、以及所述硬掩膜层122和所述第三半导体柱115之间形成所述缓冲层121的方式,使所述缓冲层121起到应力缓冲的作用,从而提高所述硬掩膜层122和所述第二半导体柱114、硬掩膜层122和第三半导体柱115的粘附性。本实施例中,所述缓冲层121的材料为氧化硅。The silicon nitride material is more stressed when heated, so it passes between the hard mask layer 122 and the second semiconductor pillar 114 and between the hard mask layer 122 and the third semiconductor pillar 115 The way of forming the buffer layer 121 makes the buffer layer 121 play the role of stress buffer, so as to improve the hard mask layer 122 and the second semiconductor pillars 114 , the hard mask layer 122 and the third semiconductor pillars 115 adhesion. In this embodiment, the material of the buffer layer 121 is silicon oxide.

参考图6,在所述PMOS区I第一半导体柱113的底部内形成PMOS漏区125a。Referring to FIG. 6, a PMOS drain region 125a is formed in the bottom of the first semiconductor pillar 113 of the PMOS region I.

本实施例中,所述第二半导体柱114中Ge的摩尔百分比大于第一半导体柱113中Ge的摩尔百分比,因此,后续在所述PMOS区I的半导体柱120a 内形成沟道层后,所述PMOS区I靠近漏区125a的沟道层中Ge的摩尔百分比较小,在半导体领域中,PMOS漏区的电压较高,电场较强,因此有利于降低PMOS晶体管靠近漏区125a的沟道层的载流子迁移率,从而能够降低 PMOS晶体管在漏区125a发生热载流子效应、自发热效应等稳定性问题的概率。In this embodiment, the mole percentage of Ge in the second semiconductor pillar 114 is greater than the mole percentage of Ge in the first semiconductor pillar 113. Therefore, after the channel layer is subsequently formed in the semiconductor pillar 120a of the PMOS region I, the The mole percentage of Ge in the channel layer of the PMOS region I close to the drain region 125a is relatively small. In the semiconductor field, the voltage of the PMOS drain region is higher and the electric field is stronger, so it is beneficial to reduce the channel of the PMOS transistor close to the drain region 125a. The carrier mobility of the layer can be reduced, thereby reducing the probability of stability problems such as hot carrier effect and self-heating effect occurring in the drain region 125a of the PMOS transistor.

具体地,采用离子注入工艺,在所述PMOS区I第一半导体柱113的底部内形成PMOS区漏区125a。Specifically, using an ion implantation process, a PMOS region drain region 125a is formed in the bottom of the first semiconductor pillar 113 of the PMOS region I.

本实施例中,所述基底还包括NMOS区II,因此,在所述PMOS区I第一半导体柱113的底部内形成PMOS漏区125a的步骤包括:在所述NMOS 区II的基底上形成保护层(图未示),仅露出PMOS区I的基底;对所述PMOS 区I的第一半导体柱113底部进行第一离子掺杂处理,形成PMOS区漏区125a;形成PMOS区I漏区125a之后,去除所述NMOS区II基底上的保护层。In this embodiment, the substrate further includes the NMOS region II, therefore, the step of forming the PMOS drain region 125a in the bottom of the first semiconductor pillar 113 of the PMOS region I includes: forming a protection on the substrate of the NMOS region II layer (not shown), only the substrate of the PMOS region I is exposed; the first ion doping treatment is performed on the bottom of the first semiconductor pillar 113 of the PMOS region I to form the PMOS region drain region 125a; the PMOS region I drain region 125a is formed After that, the protective layer on the substrate of the NMOS region II is removed.

本实施例中,形成所述PMOS漏区125a之后,所述形成方法还包括:在所述NMOS区II第一半导体柱113的底部内形成NMOS漏区125b。In this embodiment, after the PMOS drain region 125a is formed, the forming method further includes: forming an NMOS drain region 125b in the bottom of the first semiconductor pillar 113 in the NMOS region II.

具体地,形成所述NMOS漏区125b的步骤包括:在所述PMOS区I的基底上形成保护层,仅露出所述NMOS区II的基底;对所述NMOS区II的第一半导体柱113底部进行第二离子掺杂处理,形成NMOS漏区125b;形成所述NMOS漏区125b之后,去除所述PMOS区I基底上的保护层。在其他实施例中,也可以在形成NMOS漏区之后,形成PMOS漏区。Specifically, the step of forming the NMOS drain region 125b includes: forming a protective layer on the substrate of the PMOS region I, exposing only the substrate of the NMOS region II; A second ion doping treatment is performed to form an NMOS drain region 125b; after the NMOS drain region 125b is formed, the protective layer on the substrate of the PMOS region I is removed. In other embodiments, the PMOS drain region may also be formed after the NMOS drain region is formed.

所述第一离子掺杂处理用于形成PMOS漏区125a,因此第一离子掺杂处理的掺杂离子为P型离子,其中,所述P型离子为B离子、Ga离子或In离子;所述第二离子掺杂处理用于形成NMOS漏区125b,因此第二离子掺杂处理的掺杂离子为N型离子,其中,所述N型离子为P离子、As离子或Sb离子。The first ion doping treatment is used to form the PMOS drain region 125a, so the doping ions in the first ion doping treatment are P-type ions, wherein the P-type ions are B ions, Ga ions or In ions; The second ion doping treatment is used to form the NMOS drain region 125b, so the doping ions in the second ion doping treatment are N-type ions, wherein the N-type ions are P ions, As ions or Sb ions.

需要说明的是,在所述PMOS区I第一半导体柱113的底部内形成PMOS 漏区125a、以及在所述NMOS区II第一半导体柱113的底部内形成NMOS 漏区125b的过程中,所述衬底112也暴露在工艺环境中,因此所述离子也会掺杂到部分所述衬底112内从而使所述PMOS漏区125a、以及NMOS漏区 125b还形成于部分所述衬底112内。而且,通过使所述PMOS漏区125a、以及NMOS漏区125b还形成于部分所述衬底112内,还有利于降低后续形成与所述PMOS漏区125a、以及NMOS漏区125b电连接的漏区接触孔插塞的工艺难度,提高工艺兼容性。It should be noted that, in the process of forming the PMOS drain region 125a in the bottom of the first semiconductor pillar 113 in the PMOS region I, and forming the NMOS drain region 125b in the bottom of the first semiconductor pillar 113 in the NMOS region II, the The substrate 112 is also exposed to the process environment, so the ions are also doped into part of the substrate 112 so that the PMOS drain region 125a and the NMOS drain region 125b are also formed in part of the substrate 112 Inside. In addition, by forming the PMOS drain region 125a and the NMOS drain region 125b in part of the substrate 112, it is also beneficial to reduce the drain that is electrically connected to the PMOS drain region 125a and the NMOS drain region 125b in the subsequent formation. The process difficulty of the contact hole plug in the area is improved, and the process compatibility is improved.

还需要说明的是,参考图7,本实施例中,形成所述PMOS漏区125a后,所述形成方法还包括:在所述半导体柱120露出的衬底112上形成第一隔离层130,所述第一隔离层130包围部分所述PMOS漏区125a。It should also be noted that, referring to FIG. 7 , in this embodiment, after the PMOS drain region 125 a is formed, the forming method further includes: forming a first isolation layer 130 on the substrate 112 exposed by the semiconductor pillar 120 , The first isolation layer 130 surrounds part of the PMOS drain region 125a.

所述第一隔离层130用于对相邻器件起到隔离作用,后续形成包围所述半导体柱120的栅极结构后,所述第一隔离层130还用于隔离所述衬底112 和所述栅极结构。The first isolation layer 130 is used for isolating adjacent devices, and after the gate structure surrounding the semiconductor pillar 120 is subsequently formed, the first isolation layer 130 is also used for isolating the substrate 112 from all other devices. the gate structure.

本实施例中,所述第一隔离层130的材料为氧化硅。氧化硅是工艺常用、成本较低的介电材料,且具有较高的工艺兼容性,有利于降低形成所述第一隔离层130的工艺难度和工艺成本;此外,氧化硅的介电常数较小,还有利于提高所述第一隔离层130用于隔离相邻器件、以及隔离所述衬底112和栅极结构的作用。在其他实施例中,所述第一隔离层的材料还可以为氮化硅、氮氧化硅等其他绝缘材料。In this embodiment, the material of the first isolation layer 130 is silicon oxide. Silicon oxide is a commonly used and low-cost dielectric material, and has high process compatibility, which is beneficial to reduce the process difficulty and process cost of forming the first isolation layer 130; in addition, the dielectric constant of silicon oxide is relatively high. It is also beneficial to improve the function of the first isolation layer 130 for isolating adjacent devices and isolating the substrate 112 and the gate structure. In other embodiments, the material of the first isolation layer may also be other insulating materials such as silicon nitride and silicon oxynitride.

本实施例中,所述基底还包括NMOS区II,因此,形成第一隔离层130 的步骤中,所述第一隔离层130还包围部分所述NMOS漏区125b。In this embodiment, the substrate further includes the NMOS region II. Therefore, in the step of forming the first isolation layer 130 , the first isolation layer 130 also surrounds part of the NMOS drain region 125b.

具体地,形成所述第一隔离层130的步骤包括:在所述半导体柱120露出的衬底112上形成第一隔离膜(图未示),所述第一隔离膜包围所述半导体柱120;回刻蚀所述第一隔离膜,剩余第一隔离膜作为所述第一隔离层130。Specifically, the step of forming the first isolation layer 130 includes: forming a first isolation film (not shown) on the exposed substrate 112 of the semiconductor pillars 120 , the first isolation film surrounding the semiconductor pillars 120 ; Etch back the first isolation film, and the remaining first isolation film is used as the first isolation layer 130 .

本实施例中,所述第一隔离层130包围部分所述PMOS漏区125a,露出部分所述第一半导体柱113,从而使后续所述PMOS区I的栅极结构能够覆盖所述第一半导体柱113和第二半导体柱114的交界处,使所述PMOS区I的沟道层能够跨越所述第二半导体柱114和第一半导体柱113,从而所述PMOS 区I靠近所述漏区125a的沟道层中Ge的摩尔百分比较低。In this embodiment, the first isolation layer 130 surrounds part of the PMOS drain region 125a and exposes part of the first semiconductor pillar 113, so that the gate structure of the subsequent PMOS region I can cover the first semiconductor At the junction of the pillar 113 and the second semiconductor pillar 114, the channel layer of the PMOS region I can span the second semiconductor pillar 114 and the first semiconductor pillar 113, so that the PMOS region I is close to the drain region 125a The mole percentage of Ge in the channel layer is lower.

参考图8,形成所述PMOS漏区125a后,形成包围所述半导体柱120的栅极结构140,所述PMOS区I的栅极结构140覆盖所述第一半导体柱113和第二半导体柱114的交界处且露出所述第二半导体柱114的顶部,被所述栅极结构140覆盖的所述半导体柱120作为沟道层(图未示)。具体地,所述栅极结构140形成在所述第一隔离层130上。Referring to FIG. 8 , after the PMOS drain region 125a is formed, a gate structure 140 surrounding the semiconductor pillar 120 is formed, and the gate structure 140 of the PMOS region I covers the first semiconductor pillar 113 and the second semiconductor pillar 114 The junction of the second semiconductor pillar 114 is exposed and the top of the second semiconductor pillar 114 is exposed, and the semiconductor pillar 120 covered by the gate structure 140 serves as a channel layer (not shown). Specifically, the gate structure 140 is formed on the first isolation layer 130 .

本实施例中,所述栅极结构140为全包围栅结构且覆盖第一半导体柱113 和第二半导体柱114的交界处,因此PMOS区I的沟道层能够跨越第二半导体柱114和第一半导体柱113,PMOS区I靠近所述漏区125a的沟道层中Ge 的摩尔百分比较低,从而有利于改善PMOS晶体管漏区125a附近的热载流子效应、自发热效应等稳定性问题;后续在第二半导体柱114顶部内形成PMOS 源区后,PMOS区I靠近源区的沟道层中Ge的摩尔百分比较高,有利于提高PMOS晶体管的载流子迁移率。In this embodiment, the gate structure 140 is a fully surrounding gate structure and covers the junction of the first semiconductor pillar 113 and the second semiconductor pillar 114, so the channel layer of the PMOS region I can span the second semiconductor pillar 114 and the second semiconductor pillar 114. A semiconductor pillar 113, the molar percentage of Ge in the channel layer of the PMOS region I close to the drain region 125a is relatively low, thereby helping to improve stability problems such as hot carrier effect and self-heating effect near the drain region 125a of the PMOS transistor; After the PMOS source region is subsequently formed in the top of the second semiconductor pillar 114, the molar percentage of Ge in the channel layer of the PMOS region I close to the source region is higher, which is beneficial to improve the carrier mobility of the PMOS transistor.

需要说明的是,本实施例中,NMOS区II的栅极结构140还覆盖第一半导体柱113和第三半导体柱115的交界处且露出第三半导体柱115的顶部。It should be noted that, in this embodiment, the gate structure 140 of the NMOS region II also covers the junction of the first semiconductor pillar 113 and the third semiconductor pillar 115 and exposes the top of the third semiconductor pillar 115 .

所述栅极结构140露出第二半导体柱114和第三半导体柱115顶部,从而后续能够在所述第二半导体柱114的顶部内形成PMOS源区、以及在所述第三半导体柱115的顶部内形成NMOS源区。The gate structure 140 exposes the tops of the second semiconductor pillars 114 and the third semiconductor pillars 115 , so that a PMOS source region can be subsequently formed in the tops of the second semiconductor pillars 114 and the tops of the third semiconductor pillars 115 An NMOS source region is formed inside.

本实施例中,所述栅极结构140为金属栅结构,所述栅极结构140包括包围半导体柱120的栅氧化层131、包围栅氧化层131的栅介质层132以及包围栅介质层132的栅电极层133。In this embodiment, the gate structure 140 is a metal gate structure, and the gate structure 140 includes a gate oxide layer 131 surrounding the semiconductor pillar 120 , a gate dielectric layer 132 surrounding the gate oxide layer 131 , and a gate dielectric layer 132 surrounding the gate dielectric layer 132 . The gate electrode layer 133 .

本实施例中,栅氧化层131覆盖第一隔离层130露出的半导体柱120表面。In this embodiment, the gate oxide layer 131 covers the surface of the semiconductor pillar 120 exposed by the first isolation layer 130 .

本实施例中,所述栅氧化层131的材料为氧化硅。在其他实施例中,所述栅氧化层的材料还可以为氮氧化硅。In this embodiment, the material of the gate oxide layer 131 is silicon oxide. In other embodiments, the material of the gate oxide layer may also be silicon oxynitride.

本实施例中,所述栅介质层132的材料为高k介质材料;其中,高k介质材料是指相对介电常数大于氧化硅相对介电常数的介电材料。具体地,所述栅介质层132的材料为HfO2。在其他实施例中,所述栅介质层的材料还可以选自ZrO2、HfSiO、HfSiON、HfTaO、HfTiO、HfZrO或Al2O3等。In this embodiment, the material of the gate dielectric layer 132 is a high-k dielectric material, wherein the high-k dielectric material refers to a dielectric material with a relative permittivity greater than that of silicon oxide. Specifically, the material of the gate dielectric layer 132 is HfO 2 . In other embodiments, the material of the gate dielectric layer may also be selected from ZrO 2 , HfSiO, HfSiON, HfTaO, HfTiO, HfZrO, Al 2 O 3 and the like.

需要说明的是,本实施例中,所述栅介质层132还位于所述第一隔离层 130和栅极结构140之间,是由于栅介质层132与第一隔离层130均为绝缘材料,不会影响晶体管的性能,而且有利于简化工艺流程。在其他实施例中,还可以去除位于所述第一隔离层和所述栅极结构之间的栅介质层。It should be noted that, in this embodiment, the gate dielectric layer 132 is also located between the first isolation layer 130 and the gate structure 140 because the gate dielectric layer 132 and the first isolation layer 130 are both insulating materials. It does not affect the performance of the transistor and helps to simplify the process flow. In other embodiments, the gate dielectric layer between the first isolation layer and the gate structure may also be removed.

所述栅电极层133的材料为Al、Cu、Ag、Au、Pt、Ni、Ti或W。本实施例中,所述栅电极层133的材料为W。The material of the gate electrode layer 133 is Al, Cu, Ag, Au, Pt, Ni, Ti or W. In this embodiment, the material of the gate electrode layer 133 is W.

在其他实施例中,所述栅极结构还可以多晶硅栅极结构。相应地,所述栅极结构包括栅氧化层以及包围所述栅氧化层的栅极层。In other embodiments, the gate structure may also be a polysilicon gate structure. Correspondingly, the gate structure includes a gate oxide layer and a gate layer surrounding the gate oxide layer.

需要说明的是,本实施例中,所述半导体柱120的顶部还形成有硬掩膜层122(如图7所示)和缓冲层121(如图7所示),因此,在形成所述第一隔离层130之后,形成所述栅极结构140之前,所述形成方法还包括:去除所述硬掩膜层122和缓冲层121,露出所述半导体柱120表面。It should be noted that, in this embodiment, a hard mask layer 122 (as shown in FIG. 7 ) and a buffer layer 121 (as shown in FIG. 7 ) are also formed on top of the semiconductor pillars 120 . After the first isolation layer 130 and before the gate structure 140 is formed, the forming method further includes: removing the hard mask layer 122 and the buffer layer 121 to expose the surface of the semiconductor pillar 120 .

继续参考图8,形成所述栅极结构140后,在所述第二半导体柱114的顶部内形成PMOS源区145a。Continuing to refer to FIG. 8 , after the gate structure 140 is formed, a PMOS source region 145 a is formed in the top of the second semiconductor pillar 114 .

本实施例中,所述PMOS区I靠近所述源区145a的沟道层中Ge的摩尔百分比大于靠近所述漏区125a的沟道层中Ge的摩尔百分比,因此,所述 PMOS区I靠近所述源区145a的沟道层的载流子迁移率较高,从而提升了 PMOS晶体管的电学性能。In this embodiment, the mole percentage of Ge in the channel layer of the PMOS region I close to the source region 145a is greater than the mole percentage of Ge in the channel layer close to the drain region 125a. Therefore, the PMOS region I is close to The carrier mobility of the channel layer of the source region 145a is relatively high, thereby improving the electrical performance of the PMOS transistor.

具体地,采用离子注入工艺,在所述第二半导体柱114的顶部内形成PMOS源区145a。Specifically, a PMOS source region 145 a is formed in the top of the second semiconductor pillar 114 by using an ion implantation process.

本实施例中,所述基底还包括NMOS区II,因此在第二半导体柱114顶部内形成PMOS源区145a的步骤包括:形成覆盖NMOS区II栅极结构140 和第三半导体柱115顶部的保护层(图未示),仅露出PMOS区I第二半导体柱114顶部;对PMOS区I第二半导体柱114顶部进行第三离子掺杂处理,形成PMOS源区145a;形成PMOS区源区145a后,去除NMOS区II的保护层。In this embodiment, the substrate further includes the NMOS region II, so the step of forming the PMOS source region 145a in the top of the second semiconductor pillar 114 includes: forming a protection covering the gate structure 140 of the NMOS region II and the top of the third semiconductor pillar 115 layer (not shown), only the top of the second semiconductor pillar 114 in the PMOS region I is exposed; the third ion doping treatment is performed on the top of the second semiconductor pillar 114 in the PMOS region I to form the PMOS source region 145a; after the PMOS region source region 145a is formed , remove the protective layer of the NMOS region II.

需要说明的是,本实施例中,在形成PMOS源区145a之后,所述形成方法还包括:在所述第三半导体柱115的顶部内形成NMOS源区145b。It should be noted that, in this embodiment, after the PMOS source region 145a is formed, the forming method further includes: forming an NMOS source region 145b in the top of the third semiconductor pillar 115 .

具体地,形成NMOS源区145b的步骤包括:形成覆盖所述PMOS区I 栅极结构140和第二半导体柱114顶部的保护层(图未示),仅露出所述NMOS 区II的第三半导体柱115顶部;对所述NMOS区II的第三半导体柱115顶部进行第四离子掺杂处理,形成NMOS源区145b;形成NMOS源区145b之后,去除PMOS区I的保护层。在其他实施例中,也可以在形成NMOS区的源区之后,形成PMOS区的源区。Specifically, the step of forming the NMOS source region 145b includes: forming a protective layer (not shown) covering the gate structure 140 of the PMOS region I and the top of the second semiconductor pillar 114, and only exposing the third semiconductor of the NMOS region II The top of the pillar 115; the fourth ion doping treatment is performed on the top of the third semiconductor pillar 115 in the NMOS region II to form the NMOS source region 145b; after the NMOS source region 145b is formed, the protective layer of the PMOS region I is removed. In other embodiments, the source region of the PMOS region may also be formed after the source region of the NMOS region is formed.

所述第三离子掺杂处理与第一离子掺杂处理的掺杂离子相同,因此,所述第三离子掺杂处理的掺杂离子也为P型离子,其中,所述P型离子为B离子、Ga离子或In离子;所述第四离子掺杂处理与第二离子掺杂处理的掺杂离子相同,因此,所述第四离子掺杂处理的掺杂离子为N型离子,其中,所述 N型离子为P离子、As离子或Sb离子。The doping ions of the third ion doping treatment are the same as the doping ions of the first ion doping treatment, therefore, the doping ions of the third ion doping treatment are also P-type ions, wherein the P-type ions are B ions, Ga ions or In ions; the doping ions of the fourth ion doping treatment are the same as the doping ions of the second ion doping treatment, therefore, the doping ions of the fourth ion doping treatment are N-type ions, wherein, The N-type ions are P ions, As ions or Sb ions.

结合参考图9,需要说明的是,形成所述PMOS源区145a后,所述形成方法还包括:形成包围所述PMOS源区145a的第二隔离层150,所述第二隔离层150位于所述栅极结构140上且覆盖所述半导体柱120顶部。With reference to FIG. 9 , it should be noted that, after forming the PMOS source region 145a, the forming method further includes: forming a second isolation layer 150 surrounding the PMOS source region 145a, and the second isolation layer 150 is located at the on the gate structure 140 and covering the top of the semiconductor pillar 120 .

所述第二隔离层150用于为后续形成接触孔以及与所述PMOS源区145a 电连接的接触孔插塞提供工艺平台,所述第二隔离层150还用于隔离相邻器件。The second isolation layer 150 is used to provide a process platform for the subsequent formation of contact holes and contact hole plugs electrically connected to the PMOS source region 145a, and the second isolation layer 150 is also used to isolate adjacent devices.

本实施例中,所述基底还包括NMOS区II,因此,形成所述第二隔离层 150的步骤中,所述第二隔离层150还包围所述NMOS源区145b。In this embodiment, the substrate further includes an NMOS region II. Therefore, in the step of forming the second isolation layer 150, the second isolation layer 150 also surrounds the NMOS source region 145b.

本实施例中,为提高工艺兼容性,所述第二隔离层150和所述第一隔离层130的材料相同,所述第二隔离层150的材料相应为氧化硅。在其他实施例中,所述第二隔离层的材料还可以为氮化硅、氮氧化硅等其他绝缘材料。In this embodiment, in order to improve process compatibility, the material of the second isolation layer 150 and the first isolation layer 130 are the same, and the material of the second isolation layer 150 is correspondingly silicon oxide. In other embodiments, the material of the second isolation layer may also be other insulating materials such as silicon nitride and silicon oxynitride.

需要说明的是,结合参考图8,所述栅氧化层131覆盖所述第一隔离层 130露出的半导体柱120表面,因此,在对所述第二半导体柱114的顶部进行第三离子掺杂处理以形成PMOS区源区145a、对第三半导体柱115的顶部进行第四离子掺杂处理以形成NMOS源区145b的过程中,所述离子也会掺杂到栅极结构140露出的栅氧化层131内。为降低对半导体结构电学性能的影响,而且,为后续形成与PMOS源区145a电连接的接触孔插塞,本实施例中,在形成所述源PMOS源区145a后,形成所述第二隔离层150之前,所述形成方法还包括:去除所述栅电极层133露出的栅氧化层131。It should be noted that, referring to FIG. 8 , the gate oxide layer 131 covers the surface of the semiconductor pillar 120 exposed by the first isolation layer 130 , therefore, a third ion doping is performed on the top of the second semiconductor pillar 114 During the process of forming the PMOS source region 145a and the fourth ion doping process on the top of the third semiconductor pillar 115 to form the NMOS source region 145b, the ions are also doped into the gate oxide exposed by the gate structure 140. within layer 131. In order to reduce the influence on the electrical performance of the semiconductor structure, and to subsequently form a contact hole plug electrically connected to the PMOS source region 145a, in this embodiment, the second isolation is formed after the source PMOS source region 145a is formed. Before the layer 150 , the forming method further includes: removing the gate oxide layer 131 exposed by the gate electrode layer 133 .

本实施例中,采用干法刻蚀工艺,去除所述栅电极层133露出的栅氧化层131。In this embodiment, a dry etching process is used to remove the gate oxide layer 131 exposed by the gate electrode layer 133 .

采用干法刻蚀工艺时可以调节偏置电压以调整横向刻蚀的量,从而能够在去除所述半导体柱120顶部的栅氧化层131的同时,也能去除所述栅电极层133露出的半导体柱120侧壁上的栅氧化层131。When the dry etching process is used, the bias voltage can be adjusted to adjust the amount of lateral etching, so that the gate oxide layer 131 on the top of the semiconductor pillar 120 can be removed, and the semiconductor exposed by the gate electrode layer 133 can also be removed. The gate oxide layer 131 on the sidewall of the pillar 120 .

继续参考图9,形成所述第二隔离层150后,刻蚀所述PMOS源区145a 顶部的第二隔离层150,在所述第二隔离层150内形成接触孔(图未示),所述接触孔露出所述PMOS源区145a顶部;在所述接触孔内形成接触孔插塞 160。Continuing to refer to FIG. 9 , after the second isolation layer 150 is formed, the second isolation layer 150 on top of the PMOS source region 145 a is etched, and a contact hole (not shown) is formed in the second isolation layer 150 . The contact hole exposes the top of the PMOS source region 145a; a contact hole plug 160 is formed in the contact hole.

所述接触孔用于为形成所述接触孔插塞160提供空间位置。The contact hole is used to provide a space for forming the contact hole plug 160 .

本实施例中,所述基底还包括NMOS区II,因此,刻蚀所述PMOS源区 145a顶部的第二隔离层150的步骤中,还刻蚀NMOS源区145b顶部的第二隔离层150,也就是说,所述接触孔还位于NMOS区II的第二隔离层150内。In this embodiment, the substrate further includes the NMOS region II. Therefore, in the step of etching the second isolation layer 150 on the top of the PMOS source region 145a, the second isolation layer 150 on the top of the NMOS source region 145b is also etched. That is to say, the contact hole is also located in the second isolation layer 150 of the NMOS region II.

所述接触孔插塞160用于与PMOS源区145a电连接。本实施例中,所述接触孔插塞160还形成在NMOS区II的接触孔内,所述接触孔插塞160还与所述NMOS源区145b电连接。The contact hole plug 160 is used for electrical connection with the PMOS source region 145a. In this embodiment, the contact hole plug 160 is further formed in the contact hole of the NMOS region II, and the contact hole plug 160 is also electrically connected to the NMOS source region 145b.

本实施例中,所述接触孔插塞160的材料为钨。在其他实施例中,所述接触孔插塞的材料还可以为金属氮化物、氮化钛和氮化铊中的一种或几种。In this embodiment, the material of the contact hole plug 160 is tungsten. In other embodiments, the material of the contact hole plug may also be one or more of metal nitride, titanium nitride and thallium nitride.

需要说明的是,形成所述接触孔后,在所述接触孔内形成接触孔插塞160 之前,所述形成方法还包括:在所述接触孔露出的PMOS源区145a和NMOS 源区145b表面形成硅化物层155。It should be noted that, after forming the contact hole and before forming the contact hole plug 160 in the contact hole, the forming method further includes: the surfaces of the PMOS source region 145a and the NMOS source region 145b exposed in the contact hole A silicide layer 155 is formed.

所述硅化物层155位于所述接触孔露出的PMOS源区145a和NMOS源区145b表面,在形成与PMOS源区145a和NMOS源区145b电连接的接触孔插塞160时,有利于减小PMOS源区145a与接触孔插塞160、以及所述 NMOS源区145b与接触孔插塞160的接触电阻。The silicide layer 155 is located on the surface of the PMOS source region 145a and the NMOS source region 145b exposed by the contact hole, and is beneficial to reduce the size of the contact hole plug 160 that is electrically connected to the PMOS source region 145a and the NMOS source region 145b. The contact resistance between the PMOS source region 145 a and the contact hole plug 160 , and the NMOS source region 145 b and the contact hole plug 160 .

本实施例中,所述硅化物层155的材料可以为TiSi、NiSi或CoSi等。In this embodiment, the material of the silicide layer 155 may be TiSi, NiSi, or CoSi, or the like.

相应的,本发明还提供一种半导体结构。参考图9,示出了本发明半导体结构一实施例的结构示意图。Correspondingly, the present invention also provides a semiconductor structure. Referring to FIG. 9 , a schematic structural diagram of an embodiment of the semiconductor structure of the present invention is shown.

所述半导体结构包括:基底,包括PMOS区I,所述基底包括衬底112以及凸出于所述衬底112的半导体柱120,所述PMOS区I的半导体柱120a包括第一半导体柱113以及位于所述第一半导体柱113上的第二半导体柱114,所述第二半导体柱114中Ge的摩尔百分比大于所述第一半导体柱113中Ge 的摩尔百分比;PMOS漏区125a,位于所述PMOS区I第一半导体柱113的底部内;栅极结构140,包围所述半导体柱120,所述栅极结构140覆盖所述第一半导体柱113和第二半导体柱114的交界处且露出所述第二半导体柱114 的顶部,被所述栅极结构140覆盖的所述半导体柱120作为沟道层(图未示); PMOS源区145a,位于所述第二半导体柱114的顶部内。The semiconductor structure includes: a base including a PMOS region I, the base including a substrate 112 and a semiconductor pillar 120 protruding from the substrate 112, the semiconductor pillar 120a of the PMOS region I including a first semiconductor pillar 113 and The second semiconductor pillar 114 located on the first semiconductor pillar 113, the mole percentage of Ge in the second semiconductor pillar 114 is greater than the mole percentage of Ge in the first semiconductor pillar 113; the PMOS drain region 125a, located in the In the bottom of the first semiconductor pillar 113 in the PMOS region I; the gate structure 140 surrounds the semiconductor pillar 120, the gate structure 140 covers the junction of the first semiconductor pillar 113 and the second semiconductor pillar 114 and exposes the On the top of the second semiconductor pillar 114 , the semiconductor pillar 120 covered by the gate structure 140 serves as a channel layer (not shown); the PMOS source region 145 a is located in the top of the second semiconductor pillar 114 .

在半导体领域中,PMOS漏区145a的电压通常高于源区125a,漏区145a 附近的电场更强,通过使所述第二半导体柱114中Ge的摩尔百分比大于所述第一半导体柱113中Ge的摩尔百分比,使所述PMOS区I靠近源区145a的沟道层中Ge的摩尔百分比大于靠近漏区125a的沟道层中Ge的摩尔百分比,所述PMOS区I靠近源区145a的沟道层中Ge的摩尔百分比较高,有利于提高PMOS晶体管靠近源区145a的沟道层载流子的迁移率,从而提升PMOS 晶体管的电学性能;所述PMOS区I靠近漏区125a的沟道层中Ge的摩尔百分比较低,有利于使PMOS区I靠近漏区125a的沟道层载流子的迁移率较低,从而有利于改善PMOS晶体管漏区125a附近的热载流子效应以及自发热效应等稳定性问题,进而提升了半导体结构的电学性能。In the semiconductor field, the voltage of the PMOS drain region 145a is generally higher than that of the source region 125a, and the electric field near the drain region 145a is stronger. By making the mole percentage of Ge in the second semiconductor pillar 114 larger than that in the first semiconductor pillar 113 The mole percentage of Ge is such that the mole percentage of Ge in the channel layer near the source region 145a of the PMOS region I is greater than the mole percentage of Ge in the channel layer near the drain region 125a, and the PMOS region I is near the channel of the source region 145a. The higher molar percentage of Ge in the channel layer is beneficial to improve the mobility of carriers in the channel layer of the PMOS transistor close to the source region 145a, thereby improving the electrical performance of the PMOS transistor; the PMOS region I is close to the channel of the drain region 125a The lower molar percentage of Ge in the layer is beneficial to lower the mobility of carriers in the channel layer of the PMOS region I close to the drain region 125a, thereby helping to improve the hot carrier effect and spontaneous flow near the drain region 125a of the PMOS transistor Thermal effects and other stability problems, thereby improving the electrical properties of the semiconductor structure.

所述PMOS区I的基底用于形成PMOS晶体管。需要说明的是,本实施例中,所述基底还包括NMOS区II,NMOS区II的基底用于形成NMOS晶体管。The base of the PMOS region I is used to form PMOS transistors. It should be noted that, in this embodiment, the substrate further includes an NMOS region II, and the substrate of the NMOS region II is used to form an NMOS transistor.

本实施例中,所述NMOS区II的半导体柱120b包括第一半导体柱113 以及位于所述第一半导体柱113上的第三半导体柱115。In this embodiment, the semiconductor pillar 120 b of the NMOS region II includes a first semiconductor pillar 113 and a third semiconductor pillar 115 located on the first semiconductor pillar 113 .

所述半导体结构还包括:NMOS漏区125b,位于所述NMOS区II第一半导体柱113的底部内;NMOS源区145b,位于所述第三半导体柱115的顶部内。The semiconductor structure further includes: an NMOS drain region 125b located in the bottom of the first semiconductor pillar 113 of the NMOS region II; and an NMOS source region 145b located in the top of the third semiconductor pillar 115 .

所述衬底112为半导体结构的形成提供工艺平台。The substrate 112 provides a process platform for the formation of semiconductor structures.

本实施例中,所述衬底112为硅衬底。在其他实施例中,所述衬底的材料还可以为锗、锗化硅、碳化硅、砷化镓或镓化铟,所述衬底还能够为绝缘体上的硅衬底或者绝缘体上的锗衬底。In this embodiment, the substrate 112 is a silicon substrate. In other embodiments, the material of the substrate may also be germanium, silicon germanium, silicon carbide, gallium arsenide or indium gallium, and the substrate may also be a silicon-on-insulator substrate or germanium-on-insulator substrate.

所述PMOS区I半导体柱120a用于形成所述PMOS漏区125a、源区145a 和沟道层。The PMOS region I semiconductor pillar 120a is used to form the PMOS drain region 125a, the source region 145a and the channel layer.

本实施例中,所述PMOS区I的半导体柱120a包括第一半导体柱113以及位于所述第一半导体柱113上的第二半导体柱114,所述第二半导体柱114 中Ge的摩尔百分比大于所述第一半导体柱113中Ge的摩尔百分比。In this embodiment, the semiconductor pillar 120a of the PMOS region I includes a first semiconductor pillar 113 and a second semiconductor pillar 114 located on the first semiconductor pillar 113, and the mole percentage of Ge in the second semiconductor pillar 114 is greater than The mole percentage of Ge in the first semiconductor pillars 113 .

所述PMOS区I的第一半导体柱113用于形成PMOS漏区125a和沟道层,所述NMOS区II的第一半导体柱113用于形成NMOS漏区125b和沟道层。The first semiconductor pillars 113 of the PMOS region I are used to form the PMOS drain region 125a and the channel layer, and the first semiconductor pillars 113 of the NMOS region II are used to form the NMOS drain region 125b and the channel layer.

本实施例中,所述第一半导体柱113与衬底112通过对同一半导体材料层刻蚀所得到,所述第一半导体柱113和衬底112相应为一体结构,所述衬底112的材料相应也为Si,在其他实施例中,根据实际工艺需求,所述第一半导体柱和衬底的材料还可以不同,而且为进一步提高PMOS晶体管的载流子迁移率,所述第一半导体柱的材料可以为SiGe。In this embodiment, the first semiconductor pillars 113 and the substrate 112 are obtained by etching the same semiconductor material layer. Correspondingly, it is also Si. In other embodiments, according to actual process requirements, the materials of the first semiconductor column and the substrate may also be different, and in order to further improve the carrier mobility of the PMOS transistor, the first semiconductor column The material can be SiGe.

本实施例中,所述第一半导体柱113为单层结构,即所述第一半导体柱113仅包括单个半导体层(图未示),可以简化艺流程、降低工艺操作难度。在其他实施例中,所述第一半导体柱还可以包括依次位于所述衬底上的多个半导体层,并且,在所述第一半导体柱中,自远离所述第二半导体柱至靠近所述第二半导体柱的方向,半导体层中Ge的摩尔百分比逐渐增加,因此,所述第一半导体柱中Ge的摩尔百分比自上而下依次降低,有利于进一步改善PMOS晶体管靠近漏区的沟道层的热载流子效应以及自发热效应等稳定性问题。In this embodiment, the first semiconductor column 113 is a single-layer structure, that is, the first semiconductor column 113 only includes a single semiconductor layer (not shown), which can simplify the process flow and reduce the difficulty of the process operation. In other embodiments, the first semiconductor pillar may further include a plurality of semiconductor layers sequentially located on the substrate, and, in the first semiconductor pillar, from far from the second semiconductor pillar to close to the In the direction of the second semiconductor column, the mole percentage of Ge in the semiconductor layer gradually increases. Therefore, the mole percentage of Ge in the first semiconductor column decreases sequentially from top to bottom, which is beneficial to further improve the channel of the PMOS transistor near the drain region. Stability issues such as the hot carrier effect of the layer and the self-heating effect.

所述第二半导体柱114用于形成PMOS源区145a以及沟道层。The second semiconductor pillar 114 is used to form the PMOS source region 145a and the channel layer.

所述第二半导体柱114的材料为SiGe,SiGe材料能够为PMOS晶体管的沟道层提供压应力作用,从而有利于提高PMOS晶体管的载流子迁移率。The material of the second semiconductor pillar 114 is SiGe, and the SiGe material can provide compressive stress to the channel layer of the PMOS transistor, thereby helping to improve the carrier mobility of the PMOS transistor.

需要说明的是,本实施例中,所述第二半导体柱114包括依次位于所述第一半导体柱113上的多个半导体层,并且,在所述第二半导体柱114中,自靠近所述第一半导体柱113至远离所述第一半导体柱113的方向,半导体层中Ge的摩尔百分比逐渐增加,因此,所述第二半导体柱114中Ge的摩尔百分比自上而下依次降低,有利于进一步提高PMOS晶体管靠近源区145a的沟道层载流子的迁移率、以及改善PMOS晶体管靠近漏区125a的沟道层热载流子效应和自发热效应等稳定性问题。在其他实施例中,所述第二半导体柱还可以仅包括单个半导体层,有利于简化工艺流程。It should be noted that, in this embodiment, the second semiconductor pillar 114 includes a plurality of semiconductor layers sequentially located on the first semiconductor pillar 113 , and in the second semiconductor pillar 114 , the From the first semiconductor pillar 113 to the direction away from the first semiconductor pillar 113 , the mole percentage of Ge in the semiconductor layer gradually increases. Therefore, the mole percentage of Ge in the second semiconductor pillar 114 decreases sequentially from top to bottom, which is beneficial to The mobility of carriers in the channel layer of the PMOS transistor near the source region 145a is further improved, and the stability problems such as hot carrier effect and self-heating effect of the channel layer of the PMOS transistor near the drain region 125a are improved. In other embodiments, the second semiconductor pillar may also include only a single semiconductor layer, which is beneficial to simplify the process flow.

本实施例中,所述第三半导体柱115和第一半导体柱113的材料相同,第三半导体柱115的材料相应也为Si,因此NMOS区II的半导体柱120b的材料为Si,有利于提高工艺兼容性、以及NMOS晶体管沟道层的载流子迁移率。In this embodiment, the material of the third semiconductor pillar 115 and the first semiconductor pillar 113 are the same, and the material of the third semiconductor pillar 115 is correspondingly Si. Therefore, the material of the semiconductor pillar 120b in the NMOS region II is Si, which is beneficial to improve the Process compatibility, and carrier mobility of the NMOS transistor channel layer.

所述PMOS漏区125a中掺杂有P型离子,其中,所述P型离子为B离子、Ga离子或In离子;所述NMOS漏区125b中掺杂有N型离子,其中,所述N型离子为P离子、As离子或Sb离子。The PMOS drain region 125a is doped with P-type ions, wherein the P-type ions are B ions, Ga ions or In ions; the NMOS drain region 125b is doped with N-type ions, wherein the N-type ions are Type ions are P ions, As ions or Sb ions.

需要说明的是,所述PMOS漏区125a、以及NMOS漏区125b通过对所述第一半导体柱113的底部进行离子掺杂形成,在所述离子掺杂的过程中,所述衬底112也暴露在工艺环境中,因此所述离子也会掺杂到部分所述衬底112内从而使所述PMOS漏区125a、以及NMOS漏区125b还位于部分所述衬底112内。而且,通过使所述PMOS漏区125a、以及NMOS漏区125b还位于部分所述衬底112内,有利于降低后续形成与所述PMOS漏区125a、以及NMOS漏区125b电连接的漏区接触孔插塞的工艺难度,提高工艺兼容性。It should be noted that the PMOS drain region 125a and the NMOS drain region 125b are formed by ion doping the bottom of the first semiconductor pillar 113. During the ion doping process, the substrate 112 is also Exposed to the process environment, the ions are also doped into part of the substrate 112 so that the PMOS drain region 125a and the NMOS drain region 125b are also located in part of the substrate 112 . Moreover, by making the PMOS drain region 125a and the NMOS drain region 125b also located in part of the substrate 112, it is beneficial to reduce the subsequent formation of drain contacts electrically connected to the PMOS drain region 125a and the NMOS drain region 125b. The process difficulty of the hole plug is improved, and the process compatibility is improved.

还需要说明的是,本实施例中,所述半导体结构还包括:第一隔离层130,位于所述衬底112和所述栅极结构140之间且包围部分所述PMOS漏区125a。It should also be noted that, in this embodiment, the semiconductor structure further includes: a first isolation layer 130 located between the substrate 112 and the gate structure 140 and surrounding a part of the PMOS drain region 125a.

所述第一隔离层130用于对相邻器件起到隔离作用,所述第一隔离层130 还用于隔离所述衬底112和所述栅极结构140。The first isolation layer 130 is used to isolate adjacent devices, and the first isolation layer 130 is also used to isolate the substrate 112 and the gate structure 140 .

本实施例中,所述第一隔离层130的材料为氧化硅。氧化硅是工艺常用、成本较低的介电材料,且具有较高的工艺兼容性,有利于降低第一隔离层130 的形成难度和工艺成本;此外,氧化硅的介电常数较小,还有利于提高第一隔离层130用于隔离相邻器件、隔离衬底112和栅极结构140的作用。在其他实施例中,所述第一隔离层的材料还可以为氮化硅、氮氧化硅等其他绝缘材料。In this embodiment, the material of the first isolation layer 130 is silicon oxide. Silicon oxide is a commonly used and low-cost dielectric material, and has high process compatibility, which is beneficial to reduce the difficulty of forming the first isolation layer 130 and the process cost; It is beneficial to improve the function of the first isolation layer 130 for isolating adjacent devices, isolating the substrate 112 and the gate structure 140 . In other embodiments, the material of the first isolation layer may also be other insulating materials such as silicon nitride and silicon oxynitride.

本实施例中,所述基底还包括NMOS区II,因此,所述第一隔离层130 相应还包围部分所述NMOS漏区125b。In this embodiment, the substrate further includes an NMOS region II, and accordingly, the first isolation layer 130 also surrounds a part of the NMOS drain region 125b accordingly.

本实施例中,所述第一隔离层130包围部分所述PMOS漏区125a,露出部分所述第一半导体柱113,从而使所述PMOS区I的栅极结构能够覆盖所述第一半导体柱113和第二半导体柱114的交界处,因此所述PMOS区I的沟道层能够跨越所述第二半导体柱114和第一半导体柱113以使所述PMOS区I 靠近所述漏区125a的沟道层中Ge的摩尔百分比较低。In this embodiment, the first isolation layer 130 surrounds part of the PMOS drain region 125a and exposes part of the first semiconductor pillar 113, so that the gate structure of the PMOS region I can cover the first semiconductor pillar 113 and the junction of the second semiconductor pillar 114, so the channel layer of the PMOS region I can span the second semiconductor pillar 114 and the first semiconductor pillar 113 so that the PMOS region I is close to the drain region 125a The mole percentage of Ge in the channel layer is low.

本实施例中,所述栅极结构140为全包围栅结构,且覆盖第一半导体柱 113和第二半导体柱114的交界处,因此所述PMOS区I的沟道层能够跨越第二半导体柱114和第一半导体柱113,所述PMOS区I靠近漏区125a的沟道层中Ge的摩尔百分比较低,从而有利于改善PMOS晶体管漏区125a附近的热载流子效应、自发热效应等稳定性问题;所述PMOS区I靠近源区145a的沟道层中Ge的摩尔百分比较高,有利于提高PMOS晶体管的载流子迁移率。In this embodiment, the gate structure 140 is a fully surrounding gate structure and covers the junction of the first semiconductor pillar 113 and the second semiconductor pillar 114, so the channel layer of the PMOS region I can span the second semiconductor pillar 114 and the first semiconductor pillar 113, the molar percentage of Ge in the channel layer of the PMOS region I near the drain region 125a is relatively low, thereby helping to improve the stability of the hot carrier effect and the self-heating effect near the drain region 125a of the PMOS transistor The PMOS region I has a higher molar percentage of Ge in the channel layer close to the source region 145a, which is beneficial to improve the carrier mobility of the PMOS transistor.

需要说明的是,本实施例中,NMOS区II的栅极结构140还覆盖所述第一半导体柱113和第三半导体柱115的交界处且露出第三半导体柱115的顶部。It should be noted that, in this embodiment, the gate structure 140 of the NMOS region II also covers the junction of the first semiconductor pillar 113 and the third semiconductor pillar 115 and exposes the top of the third semiconductor pillar 115 .

所述栅极结构140露出所述第二半导体柱114和所述第三半导体柱115 顶部,从而使所述PMOS源区145a能够形成在所述第二半导体柱114的顶部内、使所述NMOS源区145b能够形成在所述第三半导体柱115的顶部内。The gate structure 140 exposes the top of the second semiconductor pillar 114 and the third semiconductor pillar 115 so that the PMOS source region 145a can be formed in the top of the second semiconductor pillar 114, enabling the NMOS The source region 145b can be formed in the top of the third semiconductor pillar 115 .

本实施例中,所述栅极结构140为金属栅结构,所述栅极结构140包括包围所述半导体柱120的栅氧化层131、包围所述栅氧化层131的栅介质层 132以及包围所述栅介质层132的栅电极层133。In this embodiment, the gate structure 140 is a metal gate structure, and the gate structure 140 includes a gate oxide layer 131 surrounding the semiconductor pillar 120 , a gate dielectric layer 132 surrounding the gate oxide layer 131 , and a gate dielectric layer 132 surrounding the gate oxide layer 131 . The gate electrode layer 133 of the gate dielectric layer 132 is described.

本实施例中,所述栅氧化层131的材料为氧化硅。在其他实施例中,所述栅氧化层的材料还可以为氮氧化硅。In this embodiment, the material of the gate oxide layer 131 is silicon oxide. In other embodiments, the material of the gate oxide layer may also be silicon oxynitride.

本实施例中,所述栅介质层132的材料为高k介质材料;其中,高k介质材料是指相对介电常数大于氧化硅相对介电常数的介电材料。具体地,所述栅介质层132的材料为HfO2。在其他实施例中,所述栅介质层的材料还可以选自ZrO2、HfSiO、HfSiON、HfTaO、HfTiO、HfZrO或Al2O3等。In this embodiment, the material of the gate dielectric layer 132 is a high-k dielectric material, wherein the high-k dielectric material refers to a dielectric material with a relative permittivity greater than that of silicon oxide. Specifically, the material of the gate dielectric layer 132 is HfO 2 . In other embodiments, the material of the gate dielectric layer may also be selected from ZrO 2 , HfSiO, HfSiON, HfTaO, HfTiO, HfZrO, Al 2 O 3 and the like.

本实施例中,所述栅介质层132还位于所述第一隔离层130和所述栅极结构140之间,是由于栅介质层132与第一隔离层130均为绝缘材料,不会影响晶体管的性能,而且有利于简化工艺流程。在其他实施例中,所述栅介质层还可以仅位于所述栅氧化层和栅电极层之间。In this embodiment, the gate dielectric layer 132 is also located between the first isolation layer 130 and the gate structure 140 , because the gate dielectric layer 132 and the first isolation layer 130 are both insulating materials, which will not affect the performance of transistors, and is conducive to simplifying the process flow. In other embodiments, the gate dielectric layer may only be located between the gate oxide layer and the gate electrode layer.

所述栅电极层133的材料为Al、Cu、Ag、Au、Pt、Ni、Ti或W。本实施例中,所述栅电极层133的材料为W。The material of the gate electrode layer 133 is Al, Cu, Ag, Au, Pt, Ni, Ti or W. In this embodiment, the material of the gate electrode layer 133 is W.

在其他实施例中,所述栅极结构还可以多晶硅栅极结构。相应地,所述栅极结构包括栅氧化层以及包围所述栅氧化层的栅极层。In other embodiments, the gate structure may also be a polysilicon gate structure. Correspondingly, the gate structure includes a gate oxide layer and a gate layer surrounding the gate oxide layer.

本实施例中,所述PMOS源区145a位于所述第二半导体柱114顶部内,所述NMOS源区145b位于所述第三半导体柱115顶部内。In this embodiment, the PMOS source region 145 a is located in the top of the second semiconductor pillar 114 , and the NMOS source region 145 b is located in the top of the third semiconductor pillar 115 .

所述PMOS源区145a中和漏区125a中的掺杂离子相同,所述PMOS源区145b中和漏区125b的掺杂离子相同,所述PMOS源区145a和所述NMOS 源区145b中的掺杂离子具体可参考前述对PMOS漏区125a和NMOS漏区125b的掺杂离子的描述,在此不再赘述。The doped ions in the PMOS source region 145a and the drain region 125a are the same, the doping ions in the PMOS source region 145b and the drain region 125b are the same, and the doped ions in the PMOS source region 145a and the NMOS source region 145b are the same. For details of the doping ions, reference may be made to the foregoing description of the doping ions in the PMOS drain region 125a and the NMOS drain region 125b, which will not be repeated here.

还需要说明的是,所述半导体结构还包括:第二隔离层150,包围所述 PMOS源区145a,所述第二隔离层150位于栅极结构140上且第二隔离层150 顶部高于半导体柱120顶部;接触孔插塞160,位于所述第二隔离层150内且与PMOS源区145a电连接。It should also be noted that the semiconductor structure further includes: a second isolation layer 150 surrounding the PMOS source region 145a, the second isolation layer 150 is located on the gate structure 140 and the top of the second isolation layer 150 is higher than the semiconductor The top of the pillar 120; the contact hole plug 160, located in the second isolation layer 150 and electrically connected to the PMOS source region 145a.

所述第二隔离层150用于为接触孔插塞160的形成提供工艺平台,且所述第二隔离层150还用于隔离相邻器件。The second isolation layer 150 is used to provide a process platform for forming the contact hole plug 160, and the second isolation layer 150 is also used to isolate adjacent devices.

本实施例中,所述基底还包括NMOS区II,因此,所述第二隔离层150 还包围所述NMOS源区145b。In this embodiment, the substrate further includes an NMOS region II, therefore, the second isolation layer 150 also surrounds the NMOS source region 145b.

本实施例中,为提高工艺兼容性,所述第二隔离层150和所述第一隔离层130的材料相同,所述第二隔离层150的材料相应为氧化硅。在其他实施例中,所述第二隔离层的材料还可以为氮化硅、氮氧化硅等其他绝缘材料。In this embodiment, in order to improve process compatibility, the material of the second isolation layer 150 and the first isolation layer 130 are the same, and the material of the second isolation layer 150 is correspondingly silicon oxide. In other embodiments, the material of the second isolation layer may also be other insulating materials such as silicon nitride and silicon oxynitride.

所述接触孔插塞160与PMOS源区145a电连接。相应地,所述接触孔插塞160还位于所述NMOS区II的第二隔离层150内,且所述接触孔插塞160 还与所述NMOS源区145b电连接。The contact hole plug 160 is electrically connected to the PMOS source region 145a. Correspondingly, the contact hole plug 160 is also located in the second isolation layer 150 of the NMOS region II, and the contact hole plug 160 is also electrically connected to the NMOS source region 145b.

本实施例中,所述接触孔插塞160的材料为钨。在其他实施例中,所述接触孔插塞的材料还可以为金属氮化物、氮化钛和氮化铊中的一种或几种。In this embodiment, the material of the contact hole plug 160 is tungsten. In other embodiments, the material of the contact hole plug may also be one or more of metal nitride, titanium nitride and thallium nitride.

此外,本实施例中,所述半导体结构还包括:硅化物层155,位于PMOS 源区145a和接触孔插塞160、以及NMOS源区145b和接触孔插塞160之间。In addition, in this embodiment, the semiconductor structure further includes: a silicide layer 155 located between the PMOS source region 145 a and the contact hole plug 160 and the NMOS source region 145 b and the contact hole plug 160 .

所述硅化物层155用于减小所述PMOS源区145a与所述接触孔插塞 160、以及所述NMOS源区145b与所述接触孔插塞160的接触电阻。The silicide layer 155 is used to reduce the contact resistance between the PMOS source region 145a and the contact hole plug 160 , and the NMOS source region 145b and the contact hole plug 160 .

本实施例中,所述硅化物层155的材料可以为TiSi、NiSi或CoSi等。In this embodiment, the material of the silicide layer 155 may be TiSi, NiSi, or CoSi, or the like.

所述半导体结构可以采用前述实施例所述的形成方法所形成,也可以采用其他形成方法所形成。对本实施例所述半导体结构的具体描述,可参考前述实施例中的相应描述,本实施例在此不再赘述。The semiconductor structure may be formed by the formation method described in the foregoing embodiments, or may be formed by other formation methods. For the specific description of the semiconductor structure in this embodiment, reference may be made to the corresponding descriptions in the foregoing embodiments, which will not be repeated in this embodiment.

虽然本发明披露如上,但本发明并非限定于此。任何本领域技术人员,在不脱离本发明的精神和范围内,均可作各种更动与修改,因此本发明的保护范围应当以权利要求所限定的范围为准。Although the present invention is disclosed above, the present invention is not limited thereto. Any person skilled in the art can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention should be based on the scope defined by the claims.

Claims (20)

1. A method of forming a semiconductor structure, comprising:
forming a base, wherein the base comprises a PMOS (P-channel metal oxide semiconductor) region, the base comprises a substrate and a semiconductor column protruding out of the substrate, the semiconductor column of the PMOS region comprises a first semiconductor column and a second semiconductor column positioned on the first semiconductor column, and the mole percentage of Ge in the second semiconductor column is greater than that in the first semiconductor column;
forming a PMOS drain region in the bottom of the first semiconductor pillar in the PMOS region;
after the PMOS drain region is formed, a grid structure surrounding the semiconductor column is formed, the grid structure of the PMOS region covers the junction of the first semiconductor column and the second semiconductor column and exposes the top of the second semiconductor column, and the semiconductor column covered by the grid structure is used as a channel layer;
and forming a PMOS source region in the top of the second semiconductor column after the gate structure is formed, wherein in the PMOS region, the molar percentage of Ge in the channel layer close to the source region is greater than that in the channel layer close to the drain region.
2. The method of forming a semiconductor structure according to claim 1, wherein the second semiconductor pillar includes a plurality of semiconductor layers sequentially located on the first semiconductor pillar, and wherein, in the second semiconductor pillar, a molar percentage of Ge in a semiconductor layer gradually increases from a direction close to the first semiconductor pillar to a direction away from the first semiconductor pillar.
3. The method of claim 1 or 2, wherein the first semiconductor pillar comprises a plurality of semiconductor layers sequentially located on the substrate, and wherein a molar percentage of Ge in a semiconductor layer in the first semiconductor pillar gradually increases from a direction away from the second semiconductor pillar to a direction closer to the second semiconductor pillar.
4. The method of forming a semiconductor structure according to claim 1, wherein a material of the first semiconductor pillar is Si or SiGe.
5. The method of forming a semiconductor structure according to claim 1, wherein a material of the second semiconductor pillar is SiGe.
6. The method of forming a semiconductor structure of claim 1, wherein forming the PMOS region base comprises: providing a first semiconductor material layer, and forming a second semiconductor material layer on the first semiconductor material layer, wherein the mole percentage of Ge in the second semiconductor material layer is greater than that in the first semiconductor material layer;
and sequentially etching the second semiconductor material layer and the first semiconductor material layer, and forming a substrate and a semiconductor column protruding out of the substrate on the PMOS region.
7. The method for forming a semiconductor structure according to claim 6, wherein the second semiconductor material layer and the first semiconductor material layer are sequentially etched by a dry etching process.
8. The method of claim 6, wherein the process of forming the second layer of semiconductor material on the first layer of semiconductor material is an epitaxial growth process.
9. The method of claim 8, wherein the second semiconductor material layer is SiGe, and the epitaxial growth process uses SiH as a gas 4 、Si 2 H 6 、GeH 4 And Ge 2 H 6 A gas.
10. The method of forming a semiconductor structure of claim 6, wherein the substrate further comprises an NMOS region;
the step of forming the NMOS region substrate comprises the following steps: after the second semiconductor material layer is formed, removing the second semiconductor material layer on the NMOS area; forming a third semiconductor material layer on the first semiconductor material layer of the NMOS region, wherein the third semiconductor material layer and the first semiconductor material layer are made of the same material;
in the process of etching the second semiconductor material layer and the first semiconductor material layer of the PMOS region, sequentially etching the third semiconductor material layer and the first semiconductor material layer of the NMOS region, and forming the substrate and a semiconductor column protruding from the substrate on the NMOS region, wherein the semiconductor column of the NMOS region comprises the first semiconductor column and a third semiconductor column positioned on the first semiconductor column;
forming an NMOS drain region in the bottom of the first semiconductor pillar of the NMOS region;
in the step of forming the gate structure, the gate structure also covers the boundary of the first semiconductor pillar and the third semiconductor pillar and exposes the top of the third semiconductor pillar;
after the gate structure is formed, the forming method further comprises: and forming an NMOS source region in the top of the third semiconductor column.
11. The method of forming a semiconductor structure of claim 1, wherein after forming the PMOS drain region and before forming the gate structure, the method further comprises: forming a first isolation layer on the substrate exposed out of the semiconductor pillar, wherein the first isolation layer surrounds part of the PMOS drain region;
in the step of forming a gate structure surrounding the semiconductor pillar, the gate structure is formed on the first isolation layer.
12. The method of forming a semiconductor structure of claim 1, wherein the method of forming further comprises, after forming the PMOS source region: forming a second isolation layer surrounding the PMOS source region, wherein the second isolation layer is positioned on the grid structure and covers the top of the semiconductor column;
etching the second isolation layer on the top of the PMOS source region, and forming a contact hole in the second isolation layer, wherein the contact hole exposes the top of the PMOS source region;
and forming a contact hole plug in the contact hole.
13. A semiconductor structure, comprising:
the semiconductor pillar of the PMOS region comprises a first semiconductor pillar and a second semiconductor pillar positioned on the first semiconductor pillar, and the mole percentage of Ge in the second semiconductor pillar is greater than that in the first semiconductor pillar;
a PMOS drain region located within a bottom of the PMOS region first semiconductor pillar;
the grid structure surrounds the semiconductor pillar, covers the junction of the first semiconductor pillar and the second semiconductor pillar and exposes the top of the second semiconductor pillar, and the semiconductor pillar covered by the grid structure is used as a channel layer;
a PMOS source region located within a top portion of the second semiconductor pillar; and in the PMOS region, the mole percentage of Ge in the channel layer close to the source region is larger than that in the channel layer close to the drain region.
14. The semiconductor structure of claim 13, wherein the second semiconductor pillar comprises a plurality of semiconductor layers sequentially located on the first semiconductor pillar, and wherein a mole percentage of Ge in a semiconductor layer gradually increases in the second semiconductor pillar from near the first semiconductor pillar to far away from the first semiconductor pillar.
15. The semiconductor structure of claim 13 or 14, wherein the first semiconductor pillar comprises a plurality of semiconductor layers sequentially located on the substrate, and wherein a molar percentage of Ge in a semiconductor layer gradually increases in the first semiconductor pillar from a direction away from the second semiconductor pillar to a direction closer to the second semiconductor pillar.
16. The semiconductor structure of claim 13, wherein the material of the first semiconductor pillar is Si or SiGe.
17. The semiconductor structure of claim 13, wherein the material of the second semiconductor pillar is SiGe.
18. The semiconductor structure of claim 13, wherein the substrate further comprises an NMOS region;
the semiconductor pillar of the NMOS region comprises a first semiconductor pillar and a third semiconductor pillar positioned on the first semiconductor pillar, and the third semiconductor pillar and the first semiconductor pillar are made of the same material;
the gate structure also covers the intersection of the first semiconductor pillar and a third semiconductor pillar and exposes the top of the third semiconductor pillar;
the semiconductor structure further includes: an NMOS drain region located within a bottom of the NMOS region first semiconductor pillar; an NMOS source region located within a top portion of the third semiconductor pillar.
19. The semiconductor structure of claim 13, wherein the semiconductor structure further comprises: and the first isolation layer is positioned between the substrate and the gate structure and surrounds part of the PMOS drain region.
20. The semiconductor structure of claim 13, wherein the semiconductor structure further comprises: the second isolation layer surrounds the PMOS source region, is positioned on the grid structure and has the top higher than the top of the semiconductor column;
and the contact hole plug is positioned in the second isolation layer and is electrically connected with the PMOS source region.
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CN104134697A (en) * 2014-08-11 2014-11-05 北京大学 Asymmetric Schottky source drain transistor and preparing method thereof
CN105810720A (en) * 2015-01-16 2016-07-27 台湾积体电路制造股份有限公司 Inducing local strain in vertical nanowire transistors

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