CN1110372C - Precious metal and non-ferrous metal sulfide ore compound flotation agent - Google Patents
Precious metal and non-ferrous metal sulfide ore compound flotation agent Download PDFInfo
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- CN1110372C CN1110372C CN 99113384 CN99113384A CN1110372C CN 1110372 C CN1110372 C CN 1110372C CN 99113384 CN99113384 CN 99113384 CN 99113384 A CN99113384 A CN 99113384A CN 1110372 C CN1110372 C CN 1110372C
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- Prior art keywords
- floatating
- ore
- gold
- copper
- mineral
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Links
- 229910052976 metal sulfide Inorganic materials 0.000 title claims abstract description 11
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title description 2
- 150000001875 compounds Chemical class 0.000 title 1
- 239000008396 flotation agent Substances 0.000 title 1
- 239000010970 precious metal Substances 0.000 title 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 12
- 229910000510 noble metal Inorganic materials 0.000 claims abstract description 12
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 12
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 10
- 239000002131 composite material Substances 0.000 claims description 31
- 239000000126 substance Substances 0.000 claims description 30
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 25
- 239000011707 mineral Substances 0.000 claims description 25
- -1 thiocarbamic acid ester Chemical class 0.000 claims description 11
- 125000003118 aryl group Chemical group 0.000 claims description 9
- 238000005188 flotation Methods 0.000 abstract description 12
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 2
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 abstract 1
- 239000010692 aromatic oil Substances 0.000 abstract 1
- 239000010931 gold Substances 0.000 description 30
- 229910052737 gold Inorganic materials 0.000 description 27
- 239000003814 drug Substances 0.000 description 26
- 239000010949 copper Substances 0.000 description 23
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 22
- 239000012141 concentrate Substances 0.000 description 21
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 20
- 229910052802 copper Inorganic materials 0.000 description 20
- 239000003795 chemical substances by application Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 13
- 238000007667 floating Methods 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 229910052683 pyrite Inorganic materials 0.000 description 12
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 12
- 239000011028 pyrite Substances 0.000 description 12
- 238000011084 recovery Methods 0.000 description 11
- 230000008569 process Effects 0.000 description 9
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 8
- TUZCOAQWCRRVIP-UHFFFAOYSA-N butoxymethanedithioic acid Chemical compound CCCCOC(S)=S TUZCOAQWCRRVIP-UHFFFAOYSA-N 0.000 description 8
- 229910052951 chalcopyrite Inorganic materials 0.000 description 8
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 8
- 229910052709 silver Inorganic materials 0.000 description 8
- 239000004332 silver Substances 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000004088 foaming agent Substances 0.000 description 6
- 150000002343 gold Chemical class 0.000 description 5
- 239000011133 lead Substances 0.000 description 5
- 239000012991 xanthate Substances 0.000 description 5
- 229910001254 electrum Inorganic materials 0.000 description 4
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 4
- XXOYNJXVWVNOOJ-UHFFFAOYSA-N fenuron Chemical compound CN(C)C(=O)NC1=CC=CC=C1 XXOYNJXVWVNOOJ-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000031068 symbiosis, encompassing mutualism through parasitism Effects 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-O butylazanium Chemical compound CCCC[NH3+] HQABUPZFAYXKJW-UHFFFAOYSA-O 0.000 description 2
- 229910001779 copper mineral Inorganic materials 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 235000011888 snacks Nutrition 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical compound [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 description 2
- 229940126680 traditional chinese medicines Drugs 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- FWLHAQYOFMQTHQ-UHFFFAOYSA-N 2-N-[8-[[8-(4-aminoanilino)-10-phenylphenazin-10-ium-2-yl]amino]-10-phenylphenazin-10-ium-2-yl]-8-N,10-diphenylphenazin-10-ium-2,8-diamine hydroxy-oxido-dioxochromium Chemical compound O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.Nc1ccc(Nc2ccc3nc4ccc(Nc5ccc6nc7ccc(Nc8ccc9nc%10ccc(Nc%11ccccc%11)cc%10[n+](-c%10ccccc%10)c9c8)cc7[n+](-c7ccccc7)c6c5)cc4[n+](-c4ccccc4)c3c2)cc1 FWLHAQYOFMQTHQ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910017518 Cu Zn Inorganic materials 0.000 description 1
- 229910017752 Cu-Zn Inorganic materials 0.000 description 1
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- 229910017943 Cu—Zn Inorganic materials 0.000 description 1
- 241000784726 Lycaena thetis Species 0.000 description 1
- 206010033307 Overweight Diseases 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- QRJOYPHTNNOAOJ-UHFFFAOYSA-N copper gold Chemical compound [Cu].[Au] QRJOYPHTNNOAOJ-UHFFFAOYSA-N 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- 229960004643 cupric oxide Drugs 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 235000021321 essential mineral Nutrition 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 238000009291 froth flotation Methods 0.000 description 1
- 229910052949 galena Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- JQJCSZOEVBFDKO-UHFFFAOYSA-N lead zinc Chemical class [Zn].[Pb] JQJCSZOEVBFDKO-UHFFFAOYSA-N 0.000 description 1
- XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052960 marcasite Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 229910052961 molybdenite Inorganic materials 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- CMGLSTYFWSQNEC-UHFFFAOYSA-N o-ethyl n-ethylcarbamothioate Chemical class CCNC(=S)OCC CMGLSTYFWSQNEC-UHFFFAOYSA-N 0.000 description 1
- 235000020825 overweight Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052954 pentlandite Inorganic materials 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052655 plagioclase feldspar Inorganic materials 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 229910052611 pyroxene Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 229910001739 silver mineral Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910052569 sulfide mineral Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention belongs to the field of flotation reagents for noble metal and nonferrous metal sulphide ores, and comprises the following components: 30 to 60 percent of dialkyl dithiophosphate, 8 to 14 percent of dialkyl thiocarbamate, 8 to 24 percent of mixed fatty alcohol, 4 to 8 percent of aromatic oil, 0 to 30 percent of sodium carboxymethylcellulose, and 15 to 36 percent of water.
Description
The invention belongs to noble metal and non-ferro metals floatation medicament, particularly a kind of noble metal and nonferrous metal sulfide mineral composite chemical for floatating.
Past is emphasized the medicament classification in order to grasp the characteristic of a certain floating agent more, and best a kind of medicament only has single performance, and promptly collecting agent can not have foaming characteristic, and foaming agent can not have collecting, so that choose to the ill in floatation process.But, the floating agent functional requirement is also constantly being improved along with the development of floatation process technology and Study on mechanism.One medicament is multi-functional to be not to be infeasible.
Before and after the sixties, the former Soviet Union promptly begins one's study and uses combination medicament, and its method is the same category medicament with different alkyl, that is to say that alkyl carbon atoms counts difference and the identical collecting agent of active group structure, combine as the alkyl xanthate that carbon number is different, make single medicine type and use.Can add snack made with traditional Chinese medicines at one according to the flotation flowsheet difference, also can add in the different snack made with traditional Chinese medicines that adds in different flotation stage, its floatation indicators all is better than single medicament.
Some patent of the seventies and ore dressing plant are released again and the application mix medicament, and it is to be mixed into a kind of medicament with the different collecting agent of active group structure.Then use xanthogen formate as certain ore dressing plant of Chile and sneak into mineral oil and select copper, reach the reduction reagent cost, improve the purpose of copper recovery as collecting agent.Certain patent is then made collectors application with sneaking into aromatic amine in the xanthogen formate, and the floatation indicators in the example all is better than the floatation indicators of single application xanthogen formate.Also early there is the method for floating that uses multiple collecting agent in floatation process simultaneously in China, as using xanthate and black powder to select non-ferrous metals such as copper, lead, zinc simultaneously, select molybdenite etc. with kerosene and xanthate, just they add respectively in use, rather than just make single medicament with the certain proportion allotment before use together.
The object of the present invention is to provide that a kind of consumption is little, cost is low, that medicament adds system is easy, has multiple flotation function, can improve the composite chemical for floatating of the noble metal and the non-ferrous metal rate of recovery in the froth flotation process effectively.
Technical solution of the present invention can realize according to following mode:
A kind of noble metal and nonferrous metal sulfide mineral composite chemical for floatating is characterized in that: contain:
Dialkyl dithiophosphate 30%-60%
Dialkyl thiocarbamic acid ester 8%-30%
Mixed fatty alcohol 8%-24%
Aromatic naphtha 4%-8%
Sodium carboxymethylcellulose 0%-14%
Water 15%-36%
All percentages are percetage by weight.
It is easy that the present invention has in use that consumption is little, cost is low, medicament adds system, to the metal recovery index good improvement can be arranged.In floatation process, have multiple function, can bubble and can collecting, and have the cooperative effect of selection, activation, inhibition, anti-sludge interference etc. simultaneously.Also might from polymetallic ore, reclaim multiple valuable metal in actual applications.
Describe the specific embodiment of the present invention below in detail:
1, composite drug of the present invention is by dialkyl dithiophosphate (I), dialkyl thiocarbamic acid ester (II), and mixed fatty alcohol (III), aromatic naphtha (IV), sodium carboxymethylcellulose compositions such as (V) is formed.
2, the chemical constitution of various components is among the present invention:
R=C in the formula
4H
9Alkyl Me=K, Na or NH
4
R=C in the formula
3H
7Isoalkyl R '=CH
3Or C
2H
5Alkyl III R-OH
R=C in the formula
9-13Alkyl
R in the V formula
1, R
2, R
3=C
0-4 N=450-550 in the formula
3, the composition (weight %) of the various compositions of the present invention in composite drug
Dialkyl dithiophosphate 30%-60%
Dialkyl thiocarbamic acid ester 8%-30%
Mixed fatty alcohol 8%-24%
Aromatic naphtha 4%-8%
Sodium carboxymethylcellulose 0%-14%
All percentages of water 15%-36% are percetage by weight.
The present invention at first added sodium carboxymethylcellulose in the entry by said ratio in when preparation, and with the water heating more than 60 ℃, stir, make sodium carboxymethylcellulose molten entirely, add other component by said ratio then, continue to stir, dissolve mutually to each component; Be product after leaving standstill, precipitate, filtering.The composite drug that the present invention's processing obtains is mobile brownish red transparency liquid, and water soluble is easy to disperse in ore pulp.Stable chemical performance, non-stimulated smell, non-corrosiveness, non-inflammable thing, but pollution abatement are improved the ore dressing plant operating environment, store in the cool, do not have mass change for a long time.The little water that overweights of proportion, d20 is 1.015-1.045, and freezing point is low, and first condensation point is＜-12 ℃.
Embodiment 1:
Noble metal and nonferrous metal sulfide mineral composite chemical for floatating, contain:
Dialkyl dithiophosphate 32%
Dialkyl thiocarbamic acid ester 18.5%
Mixed fatty alcohol 11.5%
Aromatic naphtha 8.0%
Sodium carboxymethylcellulose 0%
Water 30% all percentages are percetage by weight.
Utilize this medicament to carry out beneficiation test to being exposed to the sun certain gold mine.This gold mine ore is many metallic gold of quartz vein type copper mine stone.The major metal mineral are chalcopyrite, pyrite, magnetic iron ore, zincblende and marcasite.The valuable element that can reclaim for ore dressing is Jin Hetong, and gold is mainly rusty gold and electrum in the ore, and copper is chalcopyrite.Gold mineral mainly originates between quartzy gangue and the particle based on middle particulate.The rusty gold relative amount is 74.22%, and metallographic is to content 25.78% in the electrum.Distributive law among the Jin Zaitong is 27.74%, and the distributive law 53.97% in gangue, the distributive law in copper and gangue are 18.29%.
Amalgamate---golden copper is reclaimed in flotation in this gold mine production procedure employing, and floating product is a copper-bearing gold concentrate.
Test is that pulp density 30% carries out under the situation of pH values of pulp=8 at fixing mog-200 order 70%.Comparative test result shows that the kind that former medicament adds is many, and consumption is bigger, causes the flotation concentrate productive rate big, poor selectivity, and concentrate grade is on the low side.Adopt this composite chemical for floatating only with 80 gram/tons, the concentrate copper grade improves 5.55%, and gold grade improves 37.51 gram/tons, and copper recovery improves 6.70% simultaneously, and gold recovery improves 854%.From the flotation phenomenon, mineral floating speed is fast, and foam is not sticking, easy operating.As seen this composite chemical for floatating collecting ability is strong, and selectivity is good, is highly profitable to improving golden copper concentrate grade.Table 1 as a result:
The table 1 medicament condition mineral productive rate grade rate of recovery, (%) gram/ton, (%) copper, (%) gold, No. 152 oil of (gram/ton) copper gold butyl xanthate 70 butyl ammonium aerofloat 20 concentrate, 2.52 10.97 65.00 84.39 67.80 ethyl thiourethanes 40 composite chemical for floatating 80 concentrate 1.82 16.52 102.51 91.07 76.34
Comprehensive various technical indicator relatively can be reached a conclusion: this composite chemical for floatating selectivity is strong, and foaming characteristic is good, and consumption is few, and effect is remarkable.
Embodiment 2:
Noble metal and nonferrous metal sulfide mineral composite chemical for floatating, contain:
Dialkyl dithiophosphate 32.1%
Dialkyl thiocarbamic acid ester 8.5%
Mixed fatty alcohol 23.3%
Aromatic naphtha 4%
Sodium carboxymethylcellulose 0%
Water 32.1% all percentages are percetage by weight.
Utilize this medicament that west of Liaoning gold mine has been carried out beneficiation test.Pyrite type that this gold mine ore belongs to auriferous quartz vein---pyrite and carbonate---.Major metal mineral yellow iron ore, chalcopyrite, electrum and rusty gold.Electrum and rusty gold are mainly composed and are existed in pyrite and the chalcopyrite, and pyrite content is higher.Gold content is 3.58 gram/tons in the raw ore, and silver is 26.67 gram/tons, and sulphur is 28%, and copper is 0.52%.
Test is carried out under the prerequisite that does not change on-the-spot technological process, mog, pulp density.Adopt thick three essences two to sweep flow process, mog-200 order is between 57～62%.Compare test with the The field medicament.On-the-spot medicament is butyl xanthate consumption 60 gram/tons, 2# oil consumption 40 gram/tons.This composite chemical for floatating consumption is 50 gram/tons.Result of the test sees Table 2:
The table 2 regime of agent mineral productive rate grade rate of recovery, (%) gram/ton, (%) Cu, (%) Au, (gram/ton) Cu Au butyl xanthate 60 concentrate 6.00 7.06 46.32 78.59 75.412# oil 40 composite floating chemicals 50 concentrate 5.72 8.30 50.00 82.82 76.44
The result shows that concerning this gold mine, this composite chemical for floatating can substitute butyl xanthate fully, and this additive amount of medicament can save 1/3～1/2.Show to such an extent that flotation speed is fast in the floatation process, frothing capacity is good, the characteristics that selectivity is strong, and every index all must be improved.
Embodiment 3:
Noble metal and nonferrous metal sulfide mineral composite chemical for floatating, contain:
Dialkyl dithiophosphate 32%
Dialkyl thiocarbamic acid ester 18.5%
Mixed fatty alcohol 11.5%
Aromatic naphtha 8%
Sodium carboxymethylcellulose 0%
Water 30% all percentages are percetage by weight.
Utilize this medicament that the Henan gold mine has been carried out beneficiation test.This ore belongs to gold-containing sulfurating mineral type ore, and the major metal mineral are chalcopyrite, pyrite, rusty gold, native silver.Rusty gold and sulfide mineral symbiosis are close, main and copper mineral symbiosis also with the pyrite symbiosis, golden many embeddings cloth is in the pyrite crack and pyrite and chalcopyrite intergranular.
Gold content is 4.81 gram/tons in the raw ore, copper 0.363%, sulphur 6.45%.
In the metalliferous mineral, sulfide accounts for 15%, and wherein 13.3% is pyrite.85.12% is sulphide ore in the copper mineral, and 14.88% is cupric oxide.
Amalgamate---floatation is adopted in this gold mine production procedure, and product is Gold Concentrate under Normal Pressure and copper concentrate.Thin 200 orders 60% of ore grinding.The alkalescence ore pulp.It is identical with applied component among the embodiment 1 that this tests used composite floating chemical component, uses this floating agent and the auxilliary 2# oil that adds, and uses fourth level xanthate comparative test result such as table 3:
Table 3
The regime of agent mineral productive rate grade rate of recovery
(gram/ton) be Au (gram/ton) Au (%) butyl xanthate 80 concentrate 3.20 33.00 58.672# oil 40 composite floating chemicals 35 concentrate 2.53 42.00 59.362# oil 30 (%)
The result shows: replace fourth level xanthate with composite chemical for floatating, reduce dosing greatly, with the addition of less than 1/2, but obtain the Gold Concentrate under Normal Pressure grade and the Gold Concentrate under Normal Pressure rate of recovery, all be significantly improved.
Embodiment 4:
Noble metal and nonferrous metal sulfide mineral composite chemical for floatating, contain:
Dialkyl dithiophosphate 58.3%
Dialkyl thiocarbamic acid ester 8.8%
Mixed fatty alcohol 8.8%
Aromatic naphtha 7.4%
Sodium carboxymethylcellulose 0%
Water 16.7% all percentages are percetage by weight.
Utilize this medicament that the plumbous zinc ore in the west of Liaoning has been carried out beneficiation test.This lead zinc ore belongs to argentiferous multi-metal complex sulfide ore.The major metal mineral have pyrite, zincblende, galena, chalcopyrite.Silver mineral is freibergite, argentite, dark red silver ore and native silver etc.
Desire recovery valuable metal content is in the ore: silver 160 gram/tons, lead 1.90%, zinc 2.39%, copper 0.32%.
Use this composite chemical for floatating the valuable metal enrichment result in this ore has been made contrast test.Condition is to be added with to adjust agent CaO, Na before choosing
2S, ZnSO
4Mog-200 order 75% through one roughing and once purging selection, obtains the Ag-Cu-Zn mixed crude concentrate.Result of the test is listed in table 4.Sequence number 1,2,3,4 in the table, is to add different collecting agents and the plumbous bulk concentrate floatation indicators of the resulting silver-bearing copper of foaming agent respectively.
Table 4 sequence number is pounced on and is received the agent productive rate grade rate of recovery (%)
(gram/ton) be Ag (g/t) Cu (%) Pb (%) Ag Cu Pb1 25# black powder 40 9.70 1234.6 1.96 16.3 72.64 72.05 83.74 (%)
Foaming agent 02 aniline black powder 40 16.20 753.7 1.27 10.7 75.87 75.42 86.38
Terpenic oil 153 butyl ammonium aerofloats 40 13.20 1029.3 1.63 12.38 77.46 77.98 87.05
Foaming agent 04 composite floating chemical 40 13.80 1011.2 1.71 12.55 81.56 84.56 88.93
Foaming agent 0
The result shows that what sequence number 4 was used is that this composite chemical for floatating effect is best, and the silver-bearing copper lead minerals is had tangible enrichment advantage.Show that also this composite chemical for floatating has special effective function to silver-bearing copper lead.
Embodiment 5:
Noble metal and nonferrous metal sulfide mineral composite chemical for floatating, contain:
Dialkyl dithiophosphate 35.4%
Dialkyl thiocarbamic acid ester 12.4%
Mixed fatty alcohol 9.7%
Aromatic naphtha 4.4%
Sodium carboxymethylcellulose 2.7%
Water 35.4% all percentages are percetage by weight.
Utilize this medicament that the Jilin nickel minerals has been carried out this nickel minerals mineral deposit of beneficiation test and be the ultrabasic rock body, belong to copper nickel, essential mineral has pentlandite, magnetic iron ore, chalcopyrite, pyrite, violarite and capillose.Based on coarse grain embedding cloth, be easy to monomer dissociation mostly.Gangue has plagioclase, talcum, pyroxene etc.The ore dressing field in process of production, in order to adjust the acid-base value of ore pulp, suppress gangue and anti-sludge and disturb, optimize the optional atmosphere of valuable metal, the adjustment agent of interpolation has sodium carbonate, ammonium sulfate, lime, CMC etc., and pounce on the receipts agent with butyl xanthate and C-125, the on-the-spot use observed, because the C-125 performance is stable inadequately, mass change often arranged, shortage directly influences flotation effect to the antijamming capability of ore pulp.Therefore, adopt this composite chemical for floatating, replaced C-125.
Do not add foaming agent and carry out floating operation, small-sized flotation comparative test result is listed as table 5:
Table 5 regime of agent mineral productive rate grades (%) productive rates (%) (gram/ton) are Cu Ni Cu Ni butyl xanthate bulk concentrate 11.92 2.311 8.933 86.19 79.19C-125 140 butyl xanthate bulk concentrates 19.66 2.768 8.986 90.49 84.22 composite floating chemicals 130 (%)
The result shows: replace C-125 with this composite chemical for floatating, addition is low, and its floatation indicators is obtained positive effect.Copper, the nickel productive rate of copper, nickel grade and the bulk concentrate of the bulk concentrate that obtains with the composite chemical for floatating flotation all is better than using the flotation data of C-125.
Claims (1)
1, a kind of noble metal and nonferrous metal sulfide mineral composite chemical for floatating is characterized in that: contain:
Dialkyl dithiophosphate 30%-60%
Dialkyl thiocarbamic acid ester 8%-30%
Mixed fatty alcohol 8%-24%
Aromatic naphtha 4%-8%
Sodium carboxymethylcellulose 0%-14%
All percentages of water 15%-36% are percetage by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99113384 CN1110372C (en) | 1999-10-29 | 1999-10-29 | Precious metal and non-ferrous metal sulfide ore compound flotation agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99113384 CN1110372C (en) | 1999-10-29 | 1999-10-29 | Precious metal and non-ferrous metal sulfide ore compound flotation agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1294032A CN1294032A (en) | 2001-05-09 |
| CN1110372C true CN1110372C (en) | 2003-06-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99113384 Expired - Fee Related CN1110372C (en) | 1999-10-29 | 1999-10-29 | Precious metal and non-ferrous metal sulfide ore compound flotation agent |
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| CN (1) | CN1110372C (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PE20081058A1 (en) * | 2002-08-03 | 2008-09-04 | Clariant Produkte Deutschland | PROCESS FOR THE FLOTATION OF MINES OF THE SULFIDE TYPE |
| CN102600986A (en) * | 2011-12-21 | 2012-07-25 | 西北矿冶研究院 | Efficient copper-nickel polymetallic sulphide ore beneficiation reagent |
| CN102716809B (en) * | 2012-05-30 | 2013-07-03 | 西北矿冶研究院 | Copper-nickel sulfide ore collecting agent |
| CN102744157A (en) * | 2012-07-18 | 2012-10-24 | 铁岭选矿药剂有限公司 | Composite copper ore collector |
| CN103447155B (en) * | 2013-08-23 | 2015-07-22 | 西北矿冶研究院 | A kind of beneficiation method of blue chalcocite and pyrite and its collector |
| CN103657867B (en) * | 2013-12-03 | 2016-02-17 | 安徽朝山新材料股份有限公司 | A kind of flotation agent and preparation method thereof selecting gold from Copper sulfide ore containing gold |
| CN106492993A (en) * | 2016-10-30 | 2017-03-15 | 长春黄金研究院 | Suppress the composite restrainer of particulate silicate gangue |
| CN107138287B (en) * | 2017-07-07 | 2020-03-24 | 沈阳有色金属研究院 | Sulfide ore flotation combined collecting agent and application |
| CN117206085B (en) * | 2023-11-07 | 2024-03-08 | 矿冶科技集团有限公司 | High-selectivity molybdenite flotation collector, and preparation method and application thereof |
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1999
- 1999-10-29 CN CN 99113384 patent/CN1110372C/en not_active Expired - Fee Related
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| CN1294032A (en) | 2001-05-09 |
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