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CN111011874A - Natural biodegradable composite edible tubular product and preparation method thereof - Google Patents

Natural biodegradable composite edible tubular product and preparation method thereof Download PDF

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Publication number
CN111011874A
CN111011874A CN202010005012.9A CN202010005012A CN111011874A CN 111011874 A CN111011874 A CN 111011874A CN 202010005012 A CN202010005012 A CN 202010005012A CN 111011874 A CN111011874 A CN 111011874A
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Prior art keywords
edible
parts
grade
organic
powder
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谭卓华
黄炜岚
谭晓露
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Guangzhou Lvhui New Material Research Institute Co ltd
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Guangzhou Lvhui New Material Research Institute Co ltd
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Priority to CN202010005012.9A priority Critical patent/CN111011874A/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L35/00Foods or foodstuffs not provided for in groups A23L5/00 - A23L33/00; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G21/00Table-ware
    • A47G21/18Drinking straws or the like

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  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Wrappers (AREA)

Abstract

The invention relates to a natural biodegradable composite edible tubular product and a preparation method thereof, belonging to the technical field of biodegradable edible tubular products; the tube-shaped product is prepared from natural edible substances, edible auxiliary materials, deionized water, an edible-grade functional additive, an edible-grade quality improver, an edible-grade preservative, an edible-grade color-adjusting powder, an edible-grade plasticizer and an edible-grade flavoring agent; the preparation method adopts an extrusion process method of a tubular product production line, changes a forming die and a cutting knife in the tubular product production line according to the diameter, the length and the requirements of the product, and produces various straws, cotton sticks, stirring sticks, chopsticks and the like in a large scale. The basic form is kept when the hot drink is used for 3 to 4 hours and the hot drink is used for 30 to 40 minutes; the tubular product can be composted at home and degraded in the ocean, and can be completely naturally decomposed in a short time even if being discarded in any ecological environment, and the tubular product can fall into mud and be ground into dust; the adopted raw materials have rich sources, low cost, simple process and low production cost.

Description

Natural biodegradable composite edible tubular product and preparation method thereof
Technical Field
The invention relates to an edible tubular product and a preparation method thereof, in particular to a naturally biodegradable composite edible tubular product and a preparation method thereof, belonging to the technical field of biodegradable edible tubular products.
Background
With the development of the catering industry and the prevalence of disposable beverage straws, the disposable straw is more and more popular in use, and at present, the plastic straw has better flexibility, beauty, cheapness, strong durability and the like than the paper straw, so the paper straw is replaced by the colorful plastic straw and occupies almost all the application space of straw materials. Plastic straws are the most widely used straw products at present. The common disposable straws on the market are processed by plastics, most of the straws are made of Polyethylene (PE) or polypropylene (PP) as production raw materials or a few of straws are made of resin powder or PPT raw materials and chemical raw materials, and the straws have the defects that the straws are difficult to overcome:
⒈ the manufacturing process is added with various additives, which has certain toxic and side effects on human body, the straw is in direct contact with human mouth, which can affect human health, moreover, if the straw is used to suck hot beverage, the plastic straw can release toxic and harmful or carcinogenic substances, which can cause great harm to human body, the plastic straw is not easy to decompose after use, the combustion can generate a large amount of toxic and harmful gas, which can pollute the atmosphere, moreover, some children like to bite the straw, which is very unsafe and unhygienic;
⒉ since plastic is not easy to dissolve, many straws on the market are likely to be made of recycled waste plastic, and generate toxic substances to harm health when exposed to high temperature, or are made of inferior plastic or recycled plastic, and pigments may be used to cover impurities, and the color is more colorful, so the potential safety hazard is larger;
⒊ Plastic straws are not eyeful in resource recycling system and are easy to be discarded at will, people drink beverages with straws which are an indispensable daily life article in people's daily life, but the plastic straws have no biodegradability and can not be decomposed in nature, and the straws become garbage which is not easy to be disposed after drinking, and the straws have serious pollution to the environment, are a main white pollution source, the pollution degree of the straws is second to plastic bags, and a large amount of waste straws can become a burden that the global environment can not be easily erased, and the straws have too small volume and can not be recycled, and the straws can not be disposed in a proper way, such as burning but polluting air, and most of straw garbage finally flows into rivers or oceans to become plastic wastes which affect ecology, and finally can enter into animals and human bodies through food chains, thereby causing great threat and damage to life health.
With the development of petrochemical industry, a large number of plastic products are used in the food packaging industry. Plastic products such as polyethylene, polypropylene, polyvinyl chloride and the like are difficult to degrade after being discarded, and cause serious pollution to the environment; in particular, carcinogenic substances such as VOC and plasticizers easily pollute food and affect the health of human bodies. The call for plastic inhibition of European countries is higher, for example, a few countries such as the United kingdom have started to legislatively inhibit the application of plastics in certain packaging fields, 8 months in 2018, and Chilean becomes the first country of the south America which can completely inhibit plastic;
in recent years, the circulation of plastic straws is forbidden by a plurality of large catering enterprises at home and abroad, and at present, the use of disposable plastic products is limited or even forbidden by the national and urban plans of some Europe and America, so that the enterprises are under pressure; the Jutou Xingbuck announced in the global coffee chain store completely banned the use of plastic straws in 2.8 ten thousand shops under the flag before the end of 2020, and the Seattle city of the Seattle headquarters forbids restaurants and coffee shops from 7 months and 1 day, so that offenders can pay penalty. In response to an action against the disposable plastic product; starbucks have also called for, because plastic straws can cause pollution to the sea, it is desirable that families do not use plastic straws which cannot be degraded;
the european union prohibits the use of plastic straws in member countries, while companies such as mcdonald (mcdonald are developing biodegradable straws and cups with integrated lids), teiagou and paulika have promised to stop using plastic straws step by step; many large companies in the food and beverage industry have promised to eliminate the use of plastic straws in the past year, as they are adapted to the desires and legislative changes of consumers;
accordingly, those skilled in the art have also proposed a number of environmentally friendly straw technologies.
At present, plastic straw substitutes exist on the market:
⒈ paper straw
For example, patent CN204363641U proposes a paper straw, wherein the straw body is made of paper, and a plurality of ring patterns are indented on one end of the straw, so that one end of the straw can be properly bent, and the straw is degradable and reduces environmental pressure due to the paper body; however:
① the environmental pollution is relatively large when paper is made, more environmental resources are consumed in the post-treatment stage, meanwhile, a large amount of wood resources are consumed, the forest area on the earth is increasingly reduced, and the environmental pressure is increased invisibly;
②, the paper is not waterproof, and chemical waterproof products need to be added, so that the potential safety hazard is great;
③ paper straws will "dissolve" or collapse;
④ the straw has high cost of raw materials and no cost advantage;
⒉ straw for plant and rice straw
For example, patent CN108342932A discloses a method for preparing a degradable straw beverage straw, which comprises mixing straw, food gum, glutinous rice flour and resin powder according to the weight ratio of 6.5: 2: putting the mixture into a stirrer according to the proportion of 1:0.5, and adding a waterproof agent for stirring; the mixed materials are placed into a die and then molded to form the degradable straw, and the finished product obtained by the method has certain hardness, better flexibility, good plasticity, water resistance and light straw fragrance, and is environment-friendly and safe in production and use; however:
① the preparation process is relatively complex, and the time of compost degradation is as long as 120 days, which is not favorable for wide popularization;
② break easily, and its own flavor can penetrate into the beverage;
③ the straw has high raw material collection cost and no cost advantage;
⒊ Metal straw
The metal suction pipe conducts heat, is easy to scratch and scald, has no cost advantage, consumes a large amount of metal resources, and consumes more environmental resources in a post-processing stage;
⒋ degradable straw made of polylactic acid
The environment-friendly biological material is prepared from a novel bio-based and renewable biodegradable material, has good biodegradability, can be completely degraded by microorganisms in the nature under specific conditions after being used, finally generates carbon dioxide and water, does not pollute the environment, is very favorable for protecting the environment, is a well-known environment-friendly material, and is very stable; however:
① its thermal stability is bad, the degradable straw products including polylactic acid in the market at present, the heat resistance is bad, only can be used as cold drink straw, it can be used in the condition of low temperature;
② the straw has high cost of raw materials and no cost advantage;
③ need commercial compost degradation
The common degradable plastics are 60 ℃ according to the industrial compost standard, 25 ℃ or lower for home composting, the temperature can not be reached, the temperature and the humidity are not easy to control, basically, the degradable plastics can not be degraded in the natural environment, a commercial composting facility is needed, and no related facility exists at home; if the composting environment is not sufficient, the method is also changed into pollution;
⒌ edible environmental protection straw
The prior edible environment-friendly straw is usually prepared by taking starch, sugar or plant fiber as main raw materials, and chemical additives are added, but the straw is prepared by the following steps:
①, the straw has poor flexibility, no high temperature resistance, low mechanical strength, insufficient waterproof performance and poor taste, and can soften and decompose quickly after being absorbed by liquid, usually the phenomenon of softening, cracking or pasting can occur within about 10min, especially when the straw is applied to hot drinks, the straw is easy to absorb water and soften, even dissolve, and can not be used continuously, thus limiting the popularization and application;
② short shelf life;
③ the formulation and preparation process are complicated;
④ the straw has high cost of raw materials and no cost advantage.
Therefore, most of the environment-friendly straws appearing in the market are considered, and the environment-friendly straws cannot meet the requirements of safety, sanitation, convenience, environmental protection, low cost and the like. The research is still in the starting stage because of poor performance, insufficient mechanical strength, poor water resistance, poor antibacterial property, easy cracking, difficult long-term packaging, storage and use, high manufacturing cost, poor experience, serious operation pollution or high raw material cost and the like. Or other reasons, the popularization is not high in the broad-spectrum. At present, the method is not suitable for wide application.
In conclusion, although the harm of the plastic straw is known all over the world, the replaceable material is rare, the production process of the replaceable material is complex, and the preparation cost is high, so that the further popularization and use of the plastic straw are restricted; to date, little has been done commercially on a large scale or commercially in practice.
With the continuous development of society, environmental protection is more and more emphasized, and the search for a safe, convenient, sanitary, environment-friendly and low-cost straw becomes a technical problem which needs to be solved urgently by technicians in the field, but from the major trend of global environmental protection, the edible environment-friendly straw is adopted to replace the traditional plastic products to become a new development trend, the related scientific discussion cannot be stopped, and the future development value of the straw is worthy of affirmation. The edible straw with excellent performance and natural biodegradability is certainly and more emphasized and applied by people, and has wide market prospect in research, development and application in China.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a natural biodegradable composite edible tubular product which comprises the following components in parts by weight: the edible tubular product is a tubular product which can be eaten by people; various tastes can be selected according to different tastes and preferences of individuals; preparing colorful colors according to different preferences of individual colors; when the normal temperature water beverage is used for 3-4 hours, the hot beverage is used for 30-40 minutes, the basic form is kept, and the beverage can resist 100 ℃ boiled water for 3-8 minutes; after being used, the feed can feed livestock, saves grain and solves the pollution problem.
In order to achieve the purpose, the invention adopts the technical scheme that:
a natural biodegradable composite edible tubular product is prepared from the following raw materials in parts by weight: 70-90 parts of natural edible substance, 10-25 parts of edible auxiliary material, 10-25 parts of deionized water, 6-10 parts of edible functional additive, 2.2-7 parts of edible quality improver, 0.2-1 part of edible preservative, 3-5 parts of edible color-adjusting powder, 1-6 parts of edible plasticizer and 1-5 parts of edible flavoring agent.
The natural edible substance is one or a mixture of two of organic rice, organic brown rice, organic millet, organic black rice, organic oat rice, organic barley and organic wheat.
The edible auxiliary material is a mixture of two or more of dried red fruit fiber, day lily fiber, spinach fiber, Chinese toon and Chinese cabbage fiber, celery fiber, bracken fiber, dried bamboo shoot fiber, pine mushroom fiber, lettuce fiber, pumpkin fiber, green bean fiber, soybean sprout fiber, organic corn starch, organic wheat starch, organic potato starch, organic cassava starch, organic sweet potato starch, organic pre-gelatinized wheat starch, phosphate starch, gellan gum and pectin.
The food-grade functional additive is a compound mixture of two or more than two of acid-modified chitosan, casein and grain alcohol-soluble protein compositions; the cereal prolamin is kafirin, wheat gliadin, hordein, zein and secalin; the cereal prolamin composition is prepared by adding 70% ethanol solution into cereal prolamin at a ratio of 1: 8, heating in water bath to 80 deg.C, and stirring at 300r/min for 20 min.
The food grade quality improver is a mixture of two or more of calcium chloride, sodium trimetaphosphate, citric acid, acetic acid, lactic acid, malic acid, soybean polysaccharide, lecithin, molecular distillation monoglyceride and diacetyl tartaric acid monoglyceride (diglyceride).
The food grade preservative is one or a mixture of two of nisin, natamycin, polylysine and ethyl p-hydroxybenzoate.
The food-grade toning powder is one or a mixture of two of strawberry powder, grape powder, sweet potato powder, green tea powder, taro powder, carrot powder, orange powder, mango powder, beet powder, purple sweet potato snowflake powder, pumpkin powder, pineapple powder and spinach powder.
The edible plasticizer is one or a mixture of two of organic sunflower oil, organic peanut oil, organic rapeseed oil, organic soybean oil, polyethylene glycol, glycerol and sorbitol.
The food-grade flavoring agent is one or two of laurel leaf, cortex Cinnamomi Japonici, pericarpium Citri Tangerinae, fructus Foeniculi, lemon leaf, herba Menthae, herb Hierochloes Adoratae, fructus Amomi rotundus, herba Thymi vulgaris, herba Rosmarini officinalis, Lavender, herba Salvia officinalis, Glycyrrhrizae radix, fructus Punicae Granati, herba Cymbopogonis Citrari, xylitol, maltitol, and trehalose.
A preparation method of a naturally biodegradable composite edible tubular product comprises the following steps:
①, weighing and mixing 2.2-7 parts of food-grade quality improver, 6-10 parts of food-grade functional additive, adding 70-90 parts of natural edible substance, 10-25 parts of edible auxiliary material, 10-25 parts of deionized water, 0.2-1 part of food-grade preservative, 3-5 parts of food-grade toner, 1-6 parts of food-grade plasticizer and 1-5 parts of food-grade flavoring agent, and adding into a high-speed mixer to mix and stir uniformly;
② the raw material mixture of step ① is processed by vacuum feeding machine in the production line of tubular product, through ripening → extrusion → traction → cooling → cutting → drying → sterilization → packaging → a natural biological degradation compound edible tubular product is obtained, according to the diameter, length and requirement of the product, the production line of tubular product is changed into forming mould and cutting knife, the scale processing production is widely applied to various straws, cotton sticks, stirring sticks, coffee sticks, ice cream sticks, chopsticks, etc. which are in direct contact with daily drink or food.
The invention has the beneficial effects that:
1. the edible tubular product can be degraded in the ocean within 90 days, and even if the edible tubular product flows into the ocean, the edible tubular product cannot cause damage which is difficult to estimate on the ocean;
2. the fertilizer has strong compostability, can be used as food residue for household composting treatment, is degraded within 15-25 days, and can be used as plant nutrient after composting;
3. after anaerobic digestion treatment, the biomass fuel is generated, and the zero pollution and zero plastic are realized, and meanwhile, waste materials can be changed into valuable materials;
4. even if the ecological environment is abandoned, the natural decomposition can be realized within 60 days;
5. the shelf life under the condition of no unsealing is as long as 24 months, and the requirement of the shelf life of food can be met;
6. the adopted raw materials have rich sources and low cost;
7. the process is simple and the production cost is low;
8. can be used for producing various straws, cotton sticks, stirring sticks, coffee sticks, ice cream sticks, chopsticks and the like which are widely applied to direct contact with daily drinks or foods.
The principle of the action and the production method of each component is as follows:
(1) the composite edible tubular product uses natural edible substance and edible auxiliary material as main raw materials for molding, the flexible and toughening effect of the composite edible tubular product is improved by using the edible auxiliary material with toughness, the strength and resilience are increased, the density is increased after freeze drying to improve the waterproofness of the composite edible tubular product, and the structural stability and the diameter of the composite edible tubular product are kept within a set range and the surface smoothness of the product during extrusion;
(2) the composite edible tubular product adopts edible-grade functional additives:
a. the acid-modified chitosan is slightly soluble in water and hardly soluble in ethanol; the natural polymer has the advantages that the tensile strength, the water resistance and the bursting strength can be enhanced, the natural polymer is not easy to break during processing, the excellent performances such as the biological functionality, the compatibility, the safety, the microbial degradability and the like of the natural polymer are widely concerned by various industries, and the application research in various fields such as medicine, food, chemical engineering, metal extraction and recovery, biochemistry and biomedical engineering and the like is greatly advanced;
b. casein and grain alcohol soluble protein are high-quality edible protein materials, and have a large amount of hydrophobic amino acid, so that the casein and grain alcohol soluble protein have unique characteristics such as good film forming property, biodegradability, high toughness, elasticity, hydrophobicity and biocompatibility; the surface properties are mainly influenced by the composition, distribution and folding mode of amino acids, and the hydrodynamic properties are more easily restricted by the physical shape and size of the protein; such as hordein, has water insolubility, rheological property, extensibility, expansibility, film-forming property, gelatination property and the like; zein has the characteristics of solubility, film-forming property, cohesiveness, oxidation resistance, oil resistance, water retention, gelation and the like; the water holding capacity of hordein is relatively poor, but the oil holding capacity is good, and the emulsification and emulsification stability are comparable to those of soybean protein isolate; the wheat gliadin has excellent viscoelasticity, ductility and film forming property; the kafirin has the characteristics of good elasticity, formability, high toughness, oil retention property, water retention property and the like; the proteins are resistant to digestion and have unique self-assembly capacity and good affinity to hydrophobic bioactive substances;
c. aiming at the influence of different physicochemical properties of various raw materials in the food-grade functional additive, the invention firstly adopts the compound application of the acid modified chitosan, casein and grain alcohol soluble protein composition to make up the defect of single use;
① the price cost of the acid modified chitosan and casein is relatively low, and the filling and adding of the acid modified chitosan and casein compounds can reduce the addition amount of the grain alcohol soluble protein compound with relatively high price cost of the raw materials, and greatly save the cost of the terminal product on the premise of not influencing the application function of the terminal product;
② has water insolubility, good film forming property, oxidation resistance, emulsibility, ductility, high toughness, elasticity, oil retention, water resistance, heat resistance, grease resistance, oxygen isolation, fresh keeping, ultraviolet ray resistance, biocompatibility, biodegradability and the like, and has certain bacteriostasis, thereby prolonging the service time, expanding the application range and having wide application prospect in food;
(3) the preparation method of the composite edible tubular product adopts an extrusion process method of a tubular product production line, and the production line comprises a feeding system, a curing device, an extruding device, a drying device, a cooling device, a transmission device, a cutting device, a control system and the like; according to the diameter, length and requirements of the product, a forming die and a cutting knife are changed on a tubular product production line, and various straws, cotton sticks, stirring sticks, coffee sticks, ice cream sticks, chopsticks and the like are produced in a large scale;
the working principle is as follows: the material enters curing equipment and extrusion equipment, and the screw spirally pushes the material to form axial flow. Due to the mechanical friction between the screw and the material, between the material and the machine barrel and inside the material, the material is strongly extruded, stirred and sheared, and as a result, the material is further refined and homogenized; along with the gradual increase of the pressure, the temperature is correspondingly increased, and the physical properties of the materials are changed under the conditions of high temperature, high pressure and high shear; the powder is changed into paste, protein is denatured, the cellulose is partially degraded and refined, pathogenic bacteria are killed, the sanitation index is improved, and toxic components are inactivated; when the pasty material is sprayed out of the die hole, the material is cured, dehydrated and cooled under the action of strong pressure difference, the product has high quality and hardness, good surface smoothness, better palatability and flavor, and improved taste and use experience;
(4) the composite edible tubular product adopts raw materials with rich sources and low cost:
a. the natural crop is compounded, is odorless and nontoxic, is harmless to human bodies, and has high safety; the product is a tube-shaped product which can be eaten by people after being used, can be eaten together with packaged food, and has the excellent characteristics of no pollution to the food and the like;
b. the product contains abundant vitamins, has high nutritive value and low calorie, and can provide body energy after being eaten;
c. the feed additive does not contain mammal animal components, and does not have the fear of common infectious diseases of people and livestock such as mad cow disease, foot and mouth disease and the like;
d. is made of halal authentication raw materials without religious distinction;
e. various tastes can be selected according to different tastes and preferences of individuals;
f. aiming at different preferences of individual colors, the colors are colorful;
(5) the composite edible tubular product can be used for 3-4 hours in normal-temperature water beverage and 30-40 minutes in hot beverage, keeps the basic shape and can resist 100 ℃ boiled water for 3-8 minutes;
(6) the composite edible tubular product can be used for feeding livestock, and can solve pollution problem while saving food.
Detailed Description
The present invention is further illustrated in detail by the following examples, which are provided only for illustrating the present invention and are not intended to limit the scope of the present invention.
Example 1
A naturally biodegradable composite edible tubular product is prepared from the following raw materials in parts by weight: 90 parts of natural edible substance organic rice, 5 parts of edible auxiliary material dried fructus crataegi fibers, 5 parts of organic corn starch, 20 parts of deionized water, 5 parts of an edible-grade functional additive kafirin composition, 5 parts of acid-modified chitosan, 2 parts of an edible-grade quality modifier soybean polysaccharide, 5 parts of lactic acid, 1 part of an edible-grade preservative natamycin, 5 parts of an edible-grade toner strawberry powder, 6 parts of an edible-grade plasticizer organic sunflower oil and 5 parts of an edible-grade flavoring agent laurel leaf;
a preparation method of a naturally biodegradable composite edible tubular product comprises the following steps:
⑴ weighing the above materials at a certain weight ratio, adding edible quality modifier, edible functional additive, dissolving, adding natural edible substance, edible auxiliary material, deionized water, edible antiseptic, edible color adjusting powder, edible plasticizer, and edible flavoring agent, and mixing in a high-speed mixer;
⑵, the raw material mixture of step ⑴ is processed by curing → extrusion → traction → cooling → cutting → drying → sterilization → packaging → a natural biodegradable composite edible straw is obtained on the production line of tubular products by a vacuum feeding machine.
Example 2
A naturally biodegradable composite edible tubular product is prepared from the following raw materials in parts by weight: 70 parts of natural edible organic brown rice, 15 parts of edible auxiliary material organic wheat starch, 10 parts of day lily fibers, 10 parts of deionized water, 4 parts of edible functional additive acid-modified chitosan, 6 parts of zein composition, 4 parts of edible quality modifier citric acid, 1 part of soybean polysaccharide, 0.3 part of edible preservative ethyl p-hydroxybenzoate, 3 parts of edible toner grape powder, 1 part of edible plasticizer organic peanut oil and 1 part of edible flavoring agent cinnamon;
a preparation method of a naturally biodegradable composite edible tubular product comprises the following steps:
⑴ weighing the above materials at a certain weight ratio, adding edible quality modifier, edible functional additive, dissolving, adding natural edible substance, edible auxiliary material, deionized water, edible antiseptic, edible color adjusting powder, edible plasticizer, and edible flavoring agent, and mixing in a high-speed mixer;
⑵, the raw material mixture of step ⑴ is processed by curing → extrusion → traction → cooling → cutting → drying → sterilization → packaging → a natural biodegradable composite edible toothpick is obtained on the production line of tubular products by a vacuum feeding machine.
Example 3
A naturally biodegradable composite edible tubular product is prepared from the following raw materials in parts by weight: 75 parts of natural edible organic black rice, 10 parts of edible auxiliary material spinach fiber, 10 parts of phosphate starch, 15 parts of deionized water, 3 parts of edible functional additive acid-modified chitosan, 7 parts of wheat prolamin composition, 3 parts of edible quality modifier malic acid, 0.2 part of diacetyl tartaric acid mono (di) glyceride, 0.2 part of edible preservative nisin, 3.5 parts of edible color-mixing pink potato powder, 1.5 parts of edible plasticizer organic rapeseed oil and 1.5 parts of edible flavoring agent cinnamon;
a preparation method of a naturally biodegradable composite edible tubular product comprises the following steps:
⑴ weighing the above materials at a certain weight ratio, adding edible quality modifier, edible functional additive, dissolving, adding natural edible substance, edible auxiliary material, deionized water, edible antiseptic, edible color adjusting powder, edible plasticizer, and edible flavoring agent, and mixing in a high-speed mixer;
⑵, the raw material mixture of step ⑴ is processed by curing → extruding → drawing → cooling → cutting → drying → sterilizing → packaging → obtaining the natural biodegradable composite edible cotton stick in the production line of tubular products by a vacuum feeding machine.
Example 4
A naturally biodegradable composite edible tubular product is prepared from the following raw materials in parts by weight: 80 parts of natural edible substance organic millet, 5 parts of edible auxiliary material gellan gum, 10 parts of Chinese toon and Chinese cabbage fibers, 12 parts of deionized water, 8 parts of an edible-grade functional additive hordein composition, 2 parts of acid-modified chitosan, 2 parts of an edible-grade quality improver acetic acid, 0.2 part of calcium chloride, 0.5 part of an edible-grade preservative polylysine, 4 parts of edible-grade color-adjusting green tea powder, 4 parts of an edible-grade plasticizer organic soybean oil and 3 parts of an edible-grade flavoring agent fennel;
a preparation method of a naturally biodegradable composite edible tubular product comprises the following steps:
⑴ weighing the above materials at a certain weight ratio, adding edible quality modifier, edible functional additive, dissolving, adding natural edible substance, edible auxiliary material, deionized water, edible antiseptic, edible color adjusting powder, edible plasticizer, and edible flavoring agent, and mixing in a high-speed mixer;
⑵, the raw material mixture of step ⑴ is processed by curing → extrusion → traction → cooling → cutting → drying → sterilization → packaging → a natural biodegradable composite edible stirring rod is obtained on the production line of tubular products by a vacuum feeding machine.
Example 5
A naturally biodegradable composite edible tubular product is prepared from the following raw materials in parts by weight: 85 parts of natural edible substance organic oat rice, 5 parts of edible auxiliary material celery fiber, 5 parts of pectin, 15 parts of deionized water, 3 parts of edible functional additive casein, 3 parts of kafirin composition, 0.2 part of edible quality modifier calcium chloride, 3 parts of acetic acid, 0.4 part of edible preservative nisin, 4.5 parts of edible color-adjusting yam powder, 5 parts of edible plasticizer polyethylene glycol and 4.5 parts of edible flavoring agent lemon leaf;
a preparation method of a naturally biodegradable composite edible tubular product comprises the following steps:
⑴ weighing the above materials at a certain weight ratio, adding edible quality modifier, edible functional additive, dissolving, adding natural edible substance, edible auxiliary material, deionized water, edible antiseptic, edible color adjusting powder, edible plasticizer, and edible flavoring agent, and mixing in a high-speed mixer;
⑵, the raw material mixture of step ⑴ is processed by curing → extrusion → traction → cooling → cutting → drying → sterilization → packaging → a natural biodegradable composite edible chopsticks is obtained on the production line of tubular products by a vacuum feeding machine.
Example 6
A naturally biodegradable composite edible tubular product is prepared from the following raw materials in parts by weight: 80 parts of natural edible substance organic barley, 10 parts of edible auxiliary material bracken fiber, 15 parts of organic wheat starch, 20 parts of deionized water, 5 parts of edible-grade functional additive casein, 5 parts of zein composition, 5 parts of edible-grade quality modifier lactic acid, 0.3 part of sodium trimetaphosphate, 0.8 part of edible-grade preservative natamycin, 4 parts of edible-grade color-adjusting carrot powder, 3 parts of edible-grade plasticizer glycerol and 4 parts of edible-grade flavoring agent mint;
a preparation method of a naturally biodegradable composite edible tubular product comprises the following steps:
⑴ weighing the above materials at a certain weight ratio, adding edible quality modifier, edible functional additive, dissolving, adding natural edible substance, edible auxiliary material, deionized water, edible antiseptic, edible color adjusting powder, edible plasticizer, and edible flavoring agent, and mixing in a high-speed mixer;
⑵, the raw material mixture of step ⑴ is processed by curing → extruding → drawing → cooling → cutting → drying → sterilizing → packaging → obtaining the natural biodegradable composite edible coffee stick in the production line of tubular products by a vacuum feeding machine.
Example 7
A naturally biodegradable composite edible tubular product is prepared from the following raw materials in parts by weight: 90 parts of natural edible substance organic wheat, 9 parts of edible auxiliary material dried bamboo shoot fiber, 9 parts of organic potato starch, 25 parts of deionized water, 4 parts of edible-grade functional additive casein, 6 parts of wheat prolamin composition, 4 parts of edible-grade quality modifier citric acid, 1 part of lecithin, 0.7 part of edible-grade preservative polylysine, 5 parts of edible-grade color-adjusting orange powder, 5.5 parts of edible-grade plasticizer sorbitol and 5 parts of edible-grade flavoring agent vanilla;
a preparation method of a naturally biodegradable composite edible tubular product comprises the following steps:
⑴ weighing the above materials at a certain weight ratio, adding edible quality modifier, edible functional additive, dissolving, adding natural edible substance, edible auxiliary material, deionized water, edible antiseptic, edible color adjusting powder, edible plasticizer, and edible flavoring agent, and mixing in a high-speed mixer;
⑵, the raw material mixture of step ⑴ is processed by curing → extrusion → traction → cooling → cutting → drying → sterilization → packaging → a natural biodegradable composite edible straw is obtained on the production line of tubular products by a vacuum feeding machine.
Example 8
A naturally biodegradable composite edible tubular product is prepared from the following raw materials in parts by weight: 75 parts of natural edible substance organic rice, 10 parts of edible auxiliary material pine mushroom fiber, 10 parts of organic cassava starch, 18 parts of deionized water, 3 parts of edible-grade functional additive casein, 7 parts of hordein composition, 3 parts of edible-grade quality modifier malic acid, 0.2 part of molecular distillation monoglyceride, 0.4 part of edible-grade preservative ethyl p-hydroxybenzoate, 3.5 parts of edible-grade color-adjusting mango powder, 2.5 parts of edible-grade plasticizer and 2.5 parts of edible-grade flavoring agent cardamom;
⑴ weighing the above materials at a certain weight ratio, adding edible quality modifier, edible functional additive, dissolving, adding natural edible substance, edible auxiliary material, deionized water, edible antiseptic, edible color adjusting powder, edible plasticizer, and edible flavoring agent, and mixing in a high-speed mixer;
⑵, the raw material mixture of step ⑴ is processed by curing → extruding → drawing → cooling → cutting → drying → sterilizing → packaging → obtaining the natural biodegradable composite edible cotton stick in the production line of tubular products by a vacuum feeding machine.
Example 9
A naturally biodegradable composite edible tubular product is prepared from the following raw materials in parts by weight: 70 parts of natural edible substance organic millet, 12 parts of edible auxiliary material lettuce fiber, 12 parts of organic cassava starch, 16 parts of deionized water, 2 parts of edible functional additive casein, 8 parts of rye alcohol soluble protein composition, 2 parts of edible quality modifier citric acid, 0.3 part of diacetyl tartaric acid mono (di) glyceride, 0.2 part of edible preservative nisin, 3 parts of edible color-adjusting beet powder, 1.5 parts of edible plasticizer organic sunflower oil and 2 parts of edible flavoring agent thyme;
a preparation method of a naturally biodegradable composite edible tubular product comprises the following steps:
⑴ weighing the above materials at a certain weight ratio, adding edible quality modifier, edible functional additive, dissolving, adding natural edible substance, edible auxiliary material, deionized water, edible antiseptic, edible color adjusting powder, edible plasticizer, and edible flavoring agent, and mixing in a high-speed mixer;
⑵, the raw material mixture of step ⑴ is processed by curing → extruding → drawing → cooling → cutting → drying → sterilizing → packaging → obtaining the natural biodegradable composite edible ice cream stick on the production line of tubular products by a vacuum feeding machine.
Performance test result of naturally biodegradable composite edible tubular product
Figure 757504DEST_PATH_IMAGE002
All the foregoing descriptions of specific exemplary embodiments of the present invention are presented for purposes of illustration and description. It is not intended to limit the invention to the precise form disclosed, and obviously many modifications and variations are possible in light of the above teaching. The exemplary embodiments were chosen and described in order to explain certain principles of the invention and its practical application to enable one skilled in the art to make and use various exemplary embodiments of the invention and various alternatives and modifications as are suited to the particular use contemplated. Or the equivalent substitution is made for some technical characteristics; the modifications, substitutions and other conceivable alternative means are within the scope of the present invention, and do not depart from the spirit and scope of the technical solutions of the embodiments of the present invention.

Claims (10)

1. A natural biodegradable composite edible tubular product is characterized in that: the feed is prepared from the following raw materials in parts by weight: 70-90 parts of natural edible substance, 10-25 parts of edible auxiliary material, 10-25 parts of deionized water, 6-10 parts of edible functional additive, 2.2-7 parts of edible quality improver, 0.2-1 part of edible preservative, 3-5 parts of edible color-adjusting powder, 1-6 parts of edible plasticizer and 1-5 parts of edible flavoring agent.
2. The naturally biodegradable, edible composite tube according to claim 1, wherein: the natural edible substance is one or a mixture of two of organic rice, organic brown rice, organic millet, organic black rice, organic oat rice, organic barley and organic wheat.
3. The naturally biodegradable, edible composite tube according to claim 1, wherein: the edible auxiliary material is a mixture of two or more of dried red fruit fiber, day lily fiber, spinach fiber, Chinese toon and Chinese cabbage fiber, celery fiber, bracken fiber, dried bamboo shoot fiber, pine mushroom fiber, lettuce fiber, pumpkin fiber, green bean fiber, soybean sprout fiber, organic corn starch, organic wheat starch, organic potato starch, organic cassava starch, organic sweet potato starch, organic pre-gelatinized wheat starch, phosphate starch, gellan gum and pectin.
4. The naturally biodegradable, edible composite tube according to claim 1, wherein: the food-grade functional additive is a compound mixture of two or more than two of acid-modified chitosan, casein and grain alcohol-soluble protein compositions; the cereal prolamin is kafirin, wheat gliadin, hordein, zein and secalin; the cereal prolamin composition is prepared by adding 70% ethanol solution into cereal prolamin at a ratio of 1: 8, heating in water bath to 80 deg.C, and stirring at 300r/min for 20 min.
5. The naturally biodegradable, edible composite tube according to claim 1, wherein: the food grade quality improver is a mixture of two or more of calcium chloride, sodium trimetaphosphate, citric acid, acetic acid, lactic acid, malic acid, soybean polysaccharide, lecithin, molecular distillation monoglyceride and diacetyl tartaric acid monoglyceride (diglyceride).
6. The edible composite tube product of claim 1, wherein the food grade preservative is one or a mixture of two of nisin, natamycin, polylysine and ethyl p-hydroxybenzoate.
7. The tube of claim 1, wherein the food-grade color-adjusting powder is one or a mixture of strawberry powder, grape powder, sweet potato powder, green tea powder, taro powder, carrot powder, orange powder, mango powder, beet powder, purple sweet potato snow powder, pumpkin powder, pineapple powder and spinach powder.
8. The edible composite naturally biodegradable tube as set forth in claim 1, wherein the edible plasticizer is one or a mixture of two of organic sunflower oil, organic peanut oil, organic rapeseed oil, organic soybean oil, polyethylene glycol, glycerol and sorbitol.
9. The naturally biodegradable, edible composite tube according to claim 1, wherein: the food-grade flavoring agent is one or two of laurel leaf, cortex Cinnamomi Japonici, pericarpium Citri Tangerinae, fructus Foeniculi, lemon leaf, herba Menthae, herb Hierochloes Adoratae, fructus Amomi rotundus, herba Thymi vulgaris, herba Rosmarini officinalis, Lavender, herba Salvia officinalis, Glycyrrhrizae radix, fructus Punicae Granati, herba Cymbopogonis Citrari, xylitol, maltitol, and trehalose.
10. A preparation method of a naturally biodegradable composite edible tubular product is characterized by comprising the following steps: the method comprises the following steps:
①, weighing and mixing 2.2-7 parts of food-grade quality improver, 6-10 parts of food-grade functional additive, adding 70-90 parts of natural edible substance, 10-25 parts of edible auxiliary material, 10-25 parts of deionized water, 0.2-1 part of food-grade preservative, 3-5 parts of food-grade toner, 1-6 parts of food-grade plasticizer and 1-5 parts of food-grade flavoring agent, and adding into a high-speed mixer to mix and stir uniformly;
② making the raw material mixture from step ① into a tube product production line by vacuum feeding machine, curing → extruding → drawing → cooling → cutting → drying → sterilizing → packaging → getting a natural biological degradation compound edible tube product, changing the forming mould and cutting knife in the tube product production line according to the diameter, length and requirement of the product, and producing various suction tubes, cotton sticks, stirring sticks, coffee sticks, ice cream sticks and chopsticks which are contacted with daily drinks or food directly in large scale.
CN202010005012.9A 2020-01-03 2020-01-03 Natural biodegradable composite edible tubular product and preparation method thereof Pending CN111011874A (en)

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CN111875853A (en) * 2020-08-18 2020-11-03 施竣元 Degradable environment-friendly straw and preparation method thereof
CN111944325A (en) * 2020-09-01 2020-11-17 四川农业大学 A kind of preparation method of degradable soybean dietary fiber straw
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CN111728455A (en) * 2020-07-02 2020-10-02 凌源绿缘食品科技有限公司 Process and formula for processing plant hollow pipe
CN111875853A (en) * 2020-08-18 2020-11-03 施竣元 Degradable environment-friendly straw and preparation method thereof
CN111875853B (en) * 2020-08-18 2022-03-04 施竣元 Degradable environment-friendly straw and preparation method thereof
CN111944325A (en) * 2020-09-01 2020-11-17 四川农业大学 A kind of preparation method of degradable soybean dietary fiber straw
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CN116530639A (en) * 2023-04-07 2023-08-04 安徽诚宇新材料科技有限公司 Environment-friendly edible straw and manufacturing process thereof
WO2025072291A1 (en) * 2023-09-27 2025-04-03 Kalykos Llc Zein coated or impregnated paper straws and related tubular articles
TWI914061B (en) 2024-06-20 2026-02-01 王賢明 Manufacturing method of cotton swab with tea leaf mixture and biodegradable materials

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