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CN111005261A - Preparation method of high-temperature-resistant glassine release paper - Google Patents

Preparation method of high-temperature-resistant glassine release paper Download PDF

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Publication number
CN111005261A
CN111005261A CN201911232304.XA CN201911232304A CN111005261A CN 111005261 A CN111005261 A CN 111005261A CN 201911232304 A CN201911232304 A CN 201911232304A CN 111005261 A CN111005261 A CN 111005261A
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CN
China
Prior art keywords
paper
glassine
temperature resistant
release paper
modified polyester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911232304.XA
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Chinese (zh)
Inventor
安斌昌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Shuangguan New Material Technology Co Ltd
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Jiangsu Shuangguan New Material Technology Co Ltd
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Priority to CN201911232304.XA priority Critical patent/CN111005261A/en
Publication of CN111005261A publication Critical patent/CN111005261A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/001Release paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/02Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the Fourdrinier type
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/02Chemical or chemomechanical or chemothermomechanical pulp
    • D21H11/06Sulfite or bisulfite pulp
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/20Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/24Polyesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04Physical treatment, e.g. heating, irradiating
    • D21H25/06Physical treatment, e.g. heating, irradiating of impregnated or coated paper

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paper (AREA)

Abstract

The invention discloses a preparation method of high-temperature resistant glassine release paper, which comprises the steps of adopting fast-growing pine as a paper pulp raw material, adding modified polyester fibers with the length of 1-5mm, mixing, papermaking and paper forming to obtain glassine paper, then carrying out corona pretreatment, coating a layer of mixed release agent on the surface of the paper, and carrying out high-temperature drying to obtain the high-temperature resistant glassine release paper. According to the high-temperature resistant glassine release paper disclosed by the invention, the magnesium carbonate modified polyester fiber is added into the paper, and the alumina is added into the mixed release agent, so that the obtained high-temperature resistant release paper can still have very good temperature resistance at the temperature of more than 500 ℃. In the invention, magnesium carbonate is added in the preparation process of the modified polyester fiber, and can react with alumina in the mixed release agent on the surface of graphene oxide to form a small amount of mixed oxide with a spinel structure, so that the glassine release paper has very good high-temperature resistance and dimensional stability.

Description

Preparation method of high-temperature-resistant glassine release paper
Technical Field
The invention relates to the technical field of release paper, in particular to a preparation method of high-temperature resistant glassine release paper.
Background
The high-temperature resistant release paper can be used for manufacturing synthetic leather, artificial leather and the like with different temperature requirements. The domestic research on the high-temperature resistant release paper starts in 1980, but the high-temperature resistant performance is not high, and other performances of the paper sheet are not ideal. If the current domestic and foreign release paper is treated at the same constant temperature of 200 ℃ for the same time, the result shows that the domestic and foreign release paper has good stripping performance, the surface of the domestic and foreign release paper is not damaged after the same stripping times, the heat resistance of the domestic and foreign release paper is good, and the strength of the paper sheet is superior to that of the domestic release paper.
The Chinese invention patent CN102587192A discloses a preparation method of high temperature resistant glassine release paper, which comprises the steps of adding an inorganic high temperature resistant auxiliary agent into slurry, and then coating a high temperature resistant reinforcing agent, an organic high temperature resistant auxiliary agent and a release agent on the surface of paper, wherein the release paper has good temperature resistance at 180-200 ℃, has heat-resistant dimensional stability, does not contain expensive mineral fiber substances, and has low cost and good temperature resistance effect. But the high temperature resistance of the release paper needs to be further improved, so that the application of the high temperature resistant glassine release paper is further expanded.
Disclosure of Invention
Based on the technical problems in the background art, the invention provides a preparation method of high-temperature resistant glassine release paper.
The technical scheme of the invention is as follows:
a preparation method of high-temperature resistant glassine release paper comprises the following steps:
A. directly chipping fast-growing pine without peeling, then cooking and pulping by a sulfite method, carrying out DQP three-section totally chlorine-free bleaching and washing to obtain electronic grade pulp with the whiteness reaching 78-86%, pulping to 42-48 DEG SR by adopting a pulping machine under the pulp concentration of 1.5-3%, and wet weight of the pulp is 6-9 g;
B. slurry preparation: adding modified polyester fibers into the slurry prepared in the step A, and mixing the slurry in a slurry mixing pool;
C. manufacturing paper: using white water to wash and dilute until the concentration reaches 0.8-1.0%, and then carrying out papermaking on a fourdrinier paper machine to obtain a wet paper web;
D. paper forming: preparing glassine base paper through a pressing part, a front drying part, sizing, a rear drying part, press polishing, reeling and slitting;
E. coating: carrying out corona pretreatment on the glassine base paper, then coating the mixed release agent on the glassine base paper, and then drying for 45-60s under the conditions of 250-280 ℃ to obtain the high-temperature resistant glassine release paper.
Preferably, the modified polyester fiber is: the modified polyester fiber of magnesium carbonate is added in the preparation process.
More preferably, the particle size of the magnesium carbonate is 1-20 μm; the mass ratio of the magnesium carbonate to the polyester chip is 1: (80-200).
Further preferably, the length of the modified polyester fiber is 1-5 mm.
Preferably, the thickness of the raw raffinose paper is 100-130g/m2
Preferably, the mixed release agent comprises the following components: food grade methyl silicone oil, graphene oxide, aluminum oxide and palm oil.
Preferably, the mixed release agent consists of the following components in percentage by weight: 15-25% of food-grade methyl silicone oil, 0.05-0.12% of graphene oxide, 3-8% of aluminum oxide and the balance of palm oil.
Preferably, the coating weight of the mixed release agent is 0.5-1.2g/m2
The invention has the advantages that: the preparation method of the high-temperature resistant glassine release paper comprises the steps of adopting fast-growing pine as a paper pulp raw material, adding modified polyester fiber with the length of 1-5mm, mixing, making paper, forming paper to obtain glassine base paper, performing corona pretreatment, coating a layer of mixed release agent on the surface of the base paper, and drying at the temperature of 250-280 ℃ for 45-60 seconds to obtain the high-temperature resistant glassine release paper. According to the high-temperature resistant glassine release paper disclosed by the invention, the magnesium carbonate modified polyester fiber is added into the paper, and the alumina is added into the mixed release agent, so that the obtained high-temperature resistant release paper can still have very good temperature resistance at the temperature of more than 500 ℃.
In the invention, magnesium carbonate is added in the preparation process of the modified polyester fiber, the magnesium carbonate on the surface of the fiber is rapidly decomposed into carbon dioxide and magnesium oxide at the high temperature of 1000 ℃, the surface of the polyester fiber is unsmooth and remarkable in concave-convex feeling, and then the magnesium oxide reacts with alumina in the mixed release agent on the surface of graphene oxide at the temperature of 250-280 ℃ to form a small amount of mixed oxide with a spinel structure, wherein the mixed oxide has very good high temperature resistance, and the glassine release paper has very good high temperature resistance and very good dimensional stability under the protection of the mixed oxide.
Detailed Description
Example 1
A preparation method of high-temperature resistant glassine release paper comprises the following steps:
A. directly chipping fast-growing pine without peeling, then cooking and pulping by a sulfite method, carrying out DQP three-section totally chlorine-free bleaching and washing to obtain electronic grade pulp with whiteness reaching 84%, pulping to 45 DEG SR at the pulp concentration of 2.7% by using a pulping machine, and wet weight of the pulp is 7.2 g;
B. slurry preparation: adding modified polyester fibers into the slurry prepared in the step A, and mixing the slurry in a slurry mixing pool;
C. manufacturing paper: diluting the white water pulp until the concentration reaches 0.95%, and then carrying out papermaking on a fourdrinier paper machine to obtain a wet paper web;
D. paper forming: preparing glassine base paper through a pressing part, a front drying part, sizing, a rear drying part, press polishing, reeling and slitting;
E. coating: carrying out corona pretreatment on glassine paper, then coating the mixed release agent on glassine paper, and then drying for 50s at 275 ℃ to obtain the high-temperature-resistant glassine release paper.
The modified polyester fiber is as follows: the modified polyester fiber of magnesium carbonate is added in the preparation process.
The particle size of the magnesium carbonate is 1-20 mu m; the mass ratio of the magnesium carbonate to the polyester chip is 1: 120.
the length of the modified polyester fiber is 2-4 mm.
The thickness of the raffinose base paper is 115g/m2
The mixed release agent comprises the following components in percentage by weight: 18% of food-grade methyl silicone oil, 0.08% of graphene oxide, 5.5% of aluminum oxide and the balance of palm oil.
The coating weight of the mixed release agent is 1.0g/m2
Example 2
A preparation method of high-temperature resistant glassine release paper comprises the following steps:
A. directly chipping fast-growing pine without peeling, then cooking and pulping by a sulfite method, carrying out DQP three-section totally chlorine-free bleaching and washing to obtain electronic grade pulp with the whiteness reaching 86%, pulping to 48 DEG SR at the pulp concentration of 1.5% by using a pulping machine, and wet weight of the pulp is 6 g;
B. slurry preparation: adding modified polyester fibers into the slurry prepared in the step A, and mixing the slurry in a slurry mixing pool;
C. manufacturing paper: diluting the white water pulp until the concentration reaches 1.0%, and then carrying out papermaking on a fourdrinier paper machine to obtain a wet paper web;
D. paper forming: preparing glassine base paper through a pressing part, a front drying part, sizing, a rear drying part, press polishing, reeling and slitting;
E. coating: carrying out corona pretreatment on glassine paper, then coating the mixed release agent on glassine paper, and then drying for 60s at 250 ℃ to obtain the high-temperature-resistant glassine release paper.
The modified polyester fiber is as follows: the modified polyester fiber of magnesium carbonate is added in the preparation process.
The particle size of the magnesium carbonate is 1-20 mu m; the mass ratio of the magnesium carbonate to the polyester chip is 1: 200.
the length of the modified polyester fiber is 1-3 mm.
The thickness of the raffinose base paper is 130g/m2
The mixed release agent comprises the following components in percentage by weight: 25% of food-grade methyl silicone oil, 0.05% of graphene oxide, 8% of aluminum oxide and the balance of palm oil.
The coating weight of the mixed release agent is 1.2g/m2
Example 3
A preparation method of high-temperature resistant glassine release paper comprises the following steps:
A. directly chipping fast-growing pine without peeling, then cooking and pulping by a sulfite method, carrying out DQP three-section totally chlorine-free bleaching and washing to obtain electronic grade pulp with the whiteness reaching 78%, pulping to 42 DEG SR at the pulp concentration of 3% by a pulping machine, and wet weight of the pulp is 9 g;
B. slurry preparation: adding modified polyester fibers into the slurry prepared in the step A, and mixing the slurry in a slurry mixing pool;
C. manufacturing paper: diluting the white water pulp until the concentration reaches 0.8%, and then carrying out papermaking on a fourdrinier paper machine to obtain a wet paper web;
D. paper forming: preparing glassine base paper through a pressing part, a front drying part, sizing, a rear drying part, press polishing, reeling and slitting;
E. coating: carrying out corona pretreatment on glassine paper, then coating the mixed release agent on glassine paper, and then drying for 45s at 280 ℃ to obtain the high-temperature-resistant glassine release paper.
The modified polyester fiber is as follows: the modified polyester fiber of magnesium carbonate is added in the preparation process.
The particle size of the magnesium carbonate is 1-20 mu m; the mass ratio of the magnesium carbonate to the polyester chip is 1: 80.
the length of the modified polyester fiber is 3-5 mm.
The thickness of the lancine base paper is 100g/m2
The mixed release agent comprises the following components in percentage by weight: 15% of food-grade methyl silicone oil, 0.12% of graphene oxide, 3% of aluminum oxide and the balance of palm oil.
The coating weight of the mixed release agent is 0.5g/m2
The glassine release paper of examples 1 to 3 was baked at 550 ℃ for 15min, taken out and cooled at room temperature, and the dimensional stability of the release paper was tested.
Example 1 Example 2 Example 3
Rate of change in size% 1.22 1.14 1.34
From the above test data, it can be known that the high temperature resistant glassine release paper of the present invention has very good dimensional stability at 550 ℃.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (9)

1. The preparation method of the high-temperature resistant glassine release paper is characterized by comprising the following steps:
A. directly chipping fast-growing pine without peeling, then cooking and pulping by a sulfite method, carrying out DQP three-section totally chlorine-free bleaching and washing to obtain electronic grade pulp with the whiteness reaching 78-86%, pulping to 42-48 DEG SR by adopting a pulping machine under the pulp concentration of 1.5-3%, and wet weight of the pulp is 6-9 g;
B. slurry preparation: adding modified polyester fibers into the slurry prepared in the step A, and mixing the slurry in a slurry mixing pool;
C. manufacturing paper: using white water to wash and dilute until the concentration reaches 0.8-1.0%, and then carrying out papermaking on a fourdrinier paper machine to obtain a wet paper web;
D. paper forming: preparing glassine base paper through a pressing part, a front drying part, sizing, a rear drying part, press polishing, reeling and slitting;
E. coating: carrying out corona pretreatment on the glassine base paper, then coating the mixed release agent on the glassine base paper, and then drying for 45-60s under the conditions of 250-280 ℃ to obtain the high-temperature resistant glassine release paper.
2. The method for preparing the high-temperature resistant glassine release paper according to claim 1, wherein the modified polyester fiber is: the modified polyester fiber of magnesium carbonate is added in the preparation process.
3. The method for preparing high temperature resistant glassine release paper according to claim 2, wherein the magnesium carbonate has a particle size of 1-20 μm; the mass ratio of the magnesium carbonate to the polyester chip is 1: (80-200).
4. The method for preparing the high temperature resistant glassine release paper according to claim 2, wherein the length of the modified polyester fiber is 1-5 mm.
5. The method for preparing high temperature resistant glassine release paper as claimed in claim 1, wherein the thickness of the glassine paper is 100-130g/m2
6. The method for preparing the high-temperature resistant glassine release paper according to claim 1, wherein the mixed release agent comprises the following components: food grade methyl silicone oil, graphene oxide, aluminum oxide and palm oil.
7. The method for preparing the high-temperature resistant glassine release paper according to claim 6, wherein the mixed release agent comprises the following components in percentage by weight: 15-25% of food-grade methyl silicone oil, 0.05-0.12% of graphene oxide, 3-8% of aluminum oxide and the balance of palm oil.
8. The method for preparing the high temperature resistant glassine release paper according to claim 1, wherein the amount of the mixed release agent is 0.5-1.2g/m2
9. The method for preparing the high temperature resistant glassine release paper according to claim 1, comprising the steps of:
A. directly chipping fast-growing pine without peeling, then cooking and pulping by a sulfite method, carrying out DQP three-section totally chlorine-free bleaching and washing to obtain electronic grade pulp with the whiteness reaching 86%, pulping to 48 DEG SR at the pulp concentration of 1.5% by using a pulping machine, and wet weight of the pulp is 6 g;
B. slurry preparation: adding modified polyester fibers into the slurry prepared in the step A, and mixing the slurry in a slurry mixing pool;
C. manufacturing paper: diluting the white water pulp until the concentration reaches 1.0%, and then carrying out papermaking on a fourdrinier paper machine to obtain a wet paper web;
D. paper forming: preparing glassine base paper through a pressing part, a front drying part, sizing, a rear drying part, press polishing, reeling and slitting;
E. coating: carrying out corona pretreatment on glassine paper, then coating the mixed release agent on glassine paper, and then drying for 60s at 250 ℃ to obtain high-temperature-resistant glassine release paper;
the modified polyester fiber is as follows: adding magnesium carbonate modified polyester fiber in the preparation process;
the particle size of the magnesium carbonate is 1-20 mu m; the mass ratio of the magnesium carbonate to the polyester chip is 1: 200 of a carrier;
the length of the modified polyester fiber is 1-3 mm;
the thickness of the raffinose base paper is 130g/m2
The mixed release agent comprises the following components in percentage by weight: 25% of food-grade methyl silicone oil, 0.05% of graphene oxide, 8% of aluminum oxide and the balance of palm oil;
the coating weight of the mixed release agent is 1.2g/m2
CN201911232304.XA 2019-12-05 2019-12-05 Preparation method of high-temperature-resistant glassine release paper Pending CN111005261A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201911232304.XA CN111005261A (en) 2019-12-05 2019-12-05 Preparation method of high-temperature-resistant glassine release paper

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113550063A (en) * 2021-07-14 2021-10-26 台州市黄岩喜金擦纱有限公司 Manufacturing process of packing paper of melt direct spinning strong polyester filament yarn
CN114108361A (en) * 2021-11-23 2022-03-01 仙鹤股份有限公司 Production and processing technology of breathable antibacterial silicone oil paper
CN118727511A (en) * 2024-07-03 2024-10-01 浙江哲丰新材料有限公司 Glassine paper and its production process

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113550063A (en) * 2021-07-14 2021-10-26 台州市黄岩喜金擦纱有限公司 Manufacturing process of packing paper of melt direct spinning strong polyester filament yarn
CN113550063B (en) * 2021-07-14 2022-08-19 台州市黄岩喜金擦纱有限公司 Manufacturing process of packing paper of melt direct spinning strong polyester filament yarn
CN114108361A (en) * 2021-11-23 2022-03-01 仙鹤股份有限公司 Production and processing technology of breathable antibacterial silicone oil paper
CN118727511A (en) * 2024-07-03 2024-10-01 浙江哲丰新材料有限公司 Glassine paper and its production process

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Application publication date: 20200414