CN1108818A - Gas-diffusion electrode preparation method - Google Patents
Gas-diffusion electrode preparation method Download PDFInfo
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- CN1108818A CN1108818A CN94118458A CN94118458A CN1108818A CN 1108818 A CN1108818 A CN 1108818A CN 94118458 A CN94118458 A CN 94118458A CN 94118458 A CN94118458 A CN 94118458A CN 1108818 A CN1108818 A CN 1108818A
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- 238000009792 diffusion process Methods 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims description 26
- 239000003054 catalyst Substances 0.000 claims abstract description 55
- 238000000034 method Methods 0.000 claims abstract description 38
- 239000003792 electrolyte Substances 0.000 claims abstract description 23
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 11
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 11
- 239000000446 fuel Substances 0.000 claims abstract description 10
- 238000000576 coating method Methods 0.000 claims abstract description 9
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims abstract 3
- 239000012153 distilled water Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- 238000005245 sintering Methods 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000000853 adhesive Substances 0.000 claims description 10
- 230000001070 adhesive effect Effects 0.000 claims description 10
- 239000000243 solution Substances 0.000 claims description 9
- 230000007797 corrosion Effects 0.000 claims description 8
- 238000005260 corrosion Methods 0.000 claims description 8
- 229910000831 Steel Inorganic materials 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 6
- 238000005096 rolling process Methods 0.000 claims description 6
- 239000010959 steel Substances 0.000 claims description 6
- 229960000583 acetic acid Drugs 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 238000005189 flocculation Methods 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 4
- 238000010410 dusting Methods 0.000 claims description 3
- 230000016615 flocculation Effects 0.000 claims description 3
- 229910000510 noble metal Inorganic materials 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 239000001099 ammonium carbonate Substances 0.000 claims description 2
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 238000010924 continuous production Methods 0.000 claims description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-O diethylammonium Chemical compound CC[NH2+]CC HPNMFZURTQLUMO-UHFFFAOYSA-O 0.000 claims description 2
- 239000012065 filter cake Substances 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 239000012362 glacial acetic acid Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 238000005987 sulfurization reaction Methods 0.000 claims description 2
- FBEIPJNQGITEBL-UHFFFAOYSA-J tetrachloroplatinum Chemical compound Cl[Pt](Cl)(Cl)Cl FBEIPJNQGITEBL-UHFFFAOYSA-J 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 239000000463 material Substances 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 4
- 239000011230 binding agent Substances 0.000 abstract 1
- 238000007731 hot pressing Methods 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 2
- 235000011613 Pinus brutia Nutrition 0.000 description 2
- 241000018646 Pinus brutia Species 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 208000028804 PERCHING syndrome Diseases 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 230000000680 avirulence Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229920001600 hydrophobic polymer Polymers 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8828—Coating with slurry or ink
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8892—Impregnation or coating of the catalyst layer, e.g. by an ionomer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8896—Pressing, rolling, calendering
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inert Electrodes (AREA)
Abstract
There is provided a method for preparing the gas diffusion electrode used in fuel cell. Said electrode is comprised of supporting material (i.e. carbon paper), catalyst layer coating on the surface of the supporting material and substrate layer for protecting electrolyte. The first making method is to make the catalyst layer by adding surfactant, hydrophobic high polymer and temporary binder in the catalyst and using conical smear technique. The second making method is to make the catalyst layer by adding hydrophobic high polymer in the catalyst and using roll hot pressing method. The electrolyte protecting layer is comprised of silcon carbide, polytetrafluoroethylene, and polyoxyethylene and the gas diffusion electrode is prepared up by processing the electrolyte on the surface of catalyst layer through the conical smear technique. The solvent of the catalyst is water. Said electrode features high purity of catalyst, high output efficiency and long service period.
Description
Of the present invention be a kind of be electrolyte with acidity or alkaline matter, the chemical energy of fuel gas is directly changed into the preparation method of the sheet gas-diffusion electrode that the fuel cell of electric energy uses.
In the prior art, the gas-diffusion electrode of above-mentioned fuel cell is usually by the electrode supporting thing, the catalyst layer of Fu Gaiing in its surface, and the electrolyte that covers in catalyst layer surface keeps base layer to constitute.The electrode supporting thing is the poroid carbon paper through hydrophobic treatment, contains in the catalyst layer to load on supported catalyst and hydrophobicity carbon fluorine high polymer, and electrolyte keeps matrix to be made up of powdery carborundum or tantalum pentoxide and hydrophobicity carbon fluorine high polymer.When fuel gas was diffused on the electrode, then under the effect of catalyst, fuel gas and electrolyte carried out electrochemical reaction to the course of reaction of fuel cell, thereby chemical energy directly is transformed into electric energy.The delivery efficiency of fuel cell depends primarily on the preparation of gas-diffusion electrode wherein, and at present, the preparation method of kind electrode is existing multiple, but all exists deficiency and drawback separately, has restricted the development and the application of fuel cell.Flocculation process as: silkscreen seal method and when filtering transfer method and all need add thing adjustment such as isopropyl alcohol and prepare catalyst layer, it will influence the effect of catalyst.In addition, these two kinds of methods are the accurate content of noble metal in electrode in the control catalyst all, it is the solvent for preparing in the catalyst layer process that rolling method not only needs with toxic organic compounds such as polyethylene glycol, and the electrode of preparing usually exists tangible crack, thereby directly influences the life cycle of electrode; The cloud chamber method needs with complex apparatus such as thermopnore and vacuum plants with pressing combining of sintering process, and this is very inapplicable in actual fabrication.In addition, directly press sintering process to be easy to damage as yet the electrode of not moulding.
The object of the present invention is to provide two kinds can overcome the prior art defective, pollution-free, thus improve the preparation method that catalyst purity is improved the gas-diffusion electrode of fuel cell delivery efficiency.
Technical program of the present invention lies in: the common technique feature of two kinds of methods that provided is preparations that the catalyst solvent is selected distilled water and catalyst and electrolyte protection body for use.The first method of preparation gas-diffusion electrode is: it is molten in 3.0-10.0 gram distilled water and after stirring that 0.2-0.8 is restrained catalyst, add 0.2-0.8 gram surfactant or be called the resistance flocculant, add temporary adhesive again, after stirring, in catalyst: hydrophobicity high polymer-3: 7-6: 4 ratio adds the hydrophobicity high polymer and stirs with means such as blender or vibration stirrings, whole solution is fully mixed, form the mixed liquor of homogeneous; Then, with above-mentioned mixed liquor with the taper coating method coat equably through hydrophobic treatment poroid carbon paper surface on be on the electrode supporting thing surface, make the content of noble metal in electrode in the catalyst remain on 0.5 milligram/square centimeter, on poroid carbon paper, just formed even component like this and determined that highly≤0.8 millimeter stratiform thing is a catalyst layer; With at room temperature dry 3-4 hour of above-mentioned stratiform thing, in order to prevent to occur minute bubbles on the superficial layer and obtain the surface of good situation, also need control its rate of drying, after treating that it at room temperature parches, for preventing that electrode surface from crackle may occur and being beneficial to surfactant and the temporary adhesive of removing in the catalyst layer, electrode is clipped in wherein with two corrosion resistant plates of identical size and thickness (2 millimeters) and tight with bolt, heating is 10-30 minute in 110 ℃ of-160 ℃ of stoves, remove steel plate then, furnace temperature is risen to 175 ℃-195 ℃ heating 1-2 hour, again furnace temperature is risen to 250 ℃-350 ℃ heating 1-2 hour, at last, with furnace temperature rise to 360 ℃-380 ℃ in nitrogen atmosphere with electrode sintering 20-30 minute, with above-mentioned electrode from stove, take out be chilled to room temperature after, press down at the pressure of 2-3 ton with manual hydraulic press and to get final product in 3-7 minute, then electrolyte is kept matrix to handle on catalyst layer surface.The catalyst of using in the said method is platinum-C catalyst, surfactant is the aqueous acetic acid of the TrltonX-114 of new preparation, the hydrophobicity high polymer is the 60.1%(mass percent) the water-soluble suspension-turbid liquid of polytetrafluoroethylene be Teflon30-N, (Du Pont), temporary adhesive are the 12-18%(mass percent) the polyoxyethylene aqueous solution.The second method of preparation gas-diffusion electrode is the combination of rolling method and pressure sintering, promptly floccular catalyst and hydrophobic polymer are distributed on the surface of poroid carbon paper equably with rolling method, under the help of sark, abandon the adding of surfactant and provisional superpolymer adhesive with pressure sintering again.The detailed process of this method is as follows: at first, it is molten in 2.5-5.5 gram distilled water and after stirring that 0.25-0.55 is restrained catalyst, add 0.25-0.45 gram hydrophobicity high polymer, make their direct generation flocculations and form thick floccule, then with above-mentioned floccule with rolling method be distributed to equably through hydrophobic treatment poroid carbon paper surface on, be on the electrode supporting thing surface, on poroid carbon paper surface, just formed so evenly, component is determined, highly≤0.8 millimeter stratiform thing is a catalyst layer, simultaneously, will be with dusting cover as a kind of low boiling of sark, volatile inorganic powder is evenly dispersed on the corrosion resistant plate, above-mentioned still moist catalyst layer is lain on the sark, put the corrosion resistant plate of an onesize and thickness above again, with the electrode that is clipped in the middle together with steel plate with bolt tight after, place the stove of 120 ℃ of-180 ℃ of temperature to heat 10-20 minute, from stove, take out the back pine then and remove bolt, remove steel plate, take out electrode gently, again electrode is placed on separately in the stove of 350 ℃ of-380 ℃ of temperature, in nitrogen atmosphere, sintering 15-30 minute, again electrode is taken out from stove and be chilled to room temperature, pressed to 2-7 minute at 2-4 ton pressure with manual hydraulic press, then electrolyte is kept matrix to handle on the surface of catalyst layer.In addition, the electrode of the humidity of the last catalyst layer of firm covering is the available heat press also, under sark helps, makes finished product in hot press.The catalyst of using in the said method is platinum-C catalyst, and the hydrophobicity high polymer is the 60.1%(mass percent) (Teflon 30-N, DuPont), sark is carbonic hydroammonium or ammonium carbonate to the water-soluble suspension-turbid liquid of polytetrafluoroethylene.
The preparation process of the catalyst-platinum-C catalyst that relates in above-mentioned two kinds of methods is: 10-20 gram sulfuration XC-72 type carbon black is molten in the 300-500 ml distilled water that contains 0.5-1.5 gram glacial acetic acid, and in the continuous process that stirs, add the 80-120 milliliter platinum tetrachloride solution that contains 25-35 milliliter diethyl ammonium, then will be as the 10-15 gram of reducing agent, the 3%-7%(mass percent) formic acid solution adds gradually, simultaneously heter temperature is raised to 70 ℃-100 ℃, and kept 20-40 minute, be chilled to room temperature more gradually, the gained slurries are filtered and constantly wash with hot distilled water, till chloride ion is cleaned substantially, then with filter cake in 95 ℃ of baking ovens after dry 16 hours, wear into fine powder with grinder again, contain the 7%-12%(mass percent in the gained catalyst) platinum.
The electrolyte that covers at the electrode surface of described two kinds of methods preparation keeps the preparation method of base layer to be: be 98 with mass ratio in distilled water: 2-90: 10 carborundum and polytetrafluoroethylene mix, form the solution of homogeneous, add 5%-7%(mass percent again as temporary adhesive) the polyoxyethylene aqueous solution, be distributed to this mixed liquor on the surface of gas-diffusion electrode with the taper coating method, treat that it is at room temperature after the drying, in 150 ℃ of-200 ℃ of stoves, heated 10-30 minute earlier, in 250 ℃ of-350 ℃ of stoves sintering 15-30 minute again, temporary adhesive is removed in heating, on the gas-diffusion electrode surface, just formed≤electrolyte of 0.2 millimeter thin layer keeps matrix.
Gas-diffusion electrode with two kinds of preparation methods provided by the invention, use distilled water as the solvent in the catalyst layer preparation process, avirulence, free from environmental pollution, finished product can be removed the interpolation foreign material more up hill and dale, especially the pressure sintering of rolling, the interpolation foreign material have just been avoided during preparation, simplify the preparation method, shortened manufacturing cycle, reduced preparation cost, the electrode of making has kept the original purity of catalyst, make it to have good catalytic activity and low resistance, the catalyst of electrode and electrolyte keep matrix to use the ad hoc approach inseparable with electrode preparation to prepare with electrode, have improved its performance.With the gas-diffusion electrode of method preparation provided by the invention, make fuel cell have long life cycle and higher delivery efficiency, thereby have very high industrial value.
The present invention has following embodiment.
Embodiment 1: 0.50 gram platinum-C catalyst is molten in 5.50 gram distilled water, the aqueous acetic acid and 0.56 that adds the Trlton X-114 of the new preparation of 0.5 gram restrains 60.1% the water-soluble suspension-turbid liquid of polytetrafluoroethylene, after stirring, add 7.0 grams, 18% polyoxyethylene aqueous solution again, after treating that this mixed liquor stirs, with the taper coating method mixed liquor is coated equably on the poroid carbon paper surface of crossing through hydrophobic treatment, after treating that it at room temperature parches, tight by bolt electrode with corrosion resistant plate, heating is 20 minutes in 140 ℃ of stoves, remove steel plate then, furnace temperature is risen to 185 ℃ of heating 2 hours, again furnace temperature is risen to 300 ℃ of heating 1 hour, at last, furnace temperature is risen to 370 ℃, in nitrogen atmosphere with electrode sintering 25 minutes, with electrode from stove, take out be chilled to room temperature after, pressed down 5 minutes with the pressure of manual hydraulic press at the 2-3 ton.On above-mentioned electrode surface, coat again≤electrolyte of 0.2 millimeter thin layer keeps matrix, the gas-diffusion electrode that gets final product finally.Electrolyte keeps the preparation example of matrix as follows: in distilled water 95: 5 carborundum and polytetrafluoroethylene mixed, form the solution of homogeneous, add 5%-7% polyoxyethylene aqueous solution again, this mixed liquor is distributed to the surface of gas-diffusion electrode with the taper coating method, thereby form electrolyte and keep the matrix thin layer, treat that it is at room temperature after the drying, in 185 ℃ of stoves, heated 20 minutes earlier, to remove polyethylene glycol oxide, be that sintering got final product in 25 minutes in 300 ℃ of stoves in temperature then as temporary adhesive.
Embodiment 2: 0.34 gram platinum-C catalyst is molten in 3.5 gram distilled water, add the water-soluble suspension-turbid liquid of 0.37 gram 60.1% polytetrafluoroethylene after stirring again, after stirring fast, make platinum-C catalyst and polytetrafluoroethylene generation flocculation and form flocculent aggregate, this flocculate is moved on on the poroid carbon paper surface of crossing through hydrophobic treatment (its area is 10.0 * 7.0 square centimeters), and it is flocculate is smooth in the carbon paper surface treatment with the plane perching knife, with the round rubber roller flocculate is planished again, simultaneously, with dusting cover carbonic hydroammonium being evenly dispersed in size is on 15 * 10 * 2 centimetres of inorganic sarks of the lip-deep powdery of corrosion resistant plate, put a corrosion resistant plate above again, tight with bolt, be placed in 150 ℃ of stoves and heated 15-20 minute, after heating finished, pine went bolt to take out electrode gently, again electrode is put into 370 ℃ of stoves, sintering is 25 minutes in nitrogen atmosphere, with electrode from stove, take out wait to be chilled to room temperature after, pressed down 5 minutes at 2-3 ton pressure with manual hydraulic press.Electrolyte keeps the preparation of matrix and handles with embodiment 1.
Claims (6)
1, use in a kind of fuel cell by the electrode supporting thing, cover the preparation method that its lip-deep catalyst layer and electrolyte keep the gas-diffusion electrode of base layer formation, it is characterized in that: it is molten in 3.0-10.0 gram distilled water and after stirring at first 0.2-0.8 to be restrained catalyst, add 0.2-0.8 gram surfactant, add temporary adhesive again, after stirring, in catalyst: hydrophobicity high polymer=3: 7-6: 4 ratio adds the hydrophobicity high polymer and stirs whole solution is fully mixed, form the mixed liquor of homogeneous, then above-mentioned mixed liquor is coated on the process carbon paper surface of hydrophobic treatment equably with the taper coating method, make the content of noble metal in electrode in the catalyst reach 0.5 milligram/square centimeter, form the stratiform thing of height≤0.8 millimeter on poroid carbon paper surface, with at room temperature dry 3-4 hour of above-mentioned stratiform thing, after parching, be clipped in electrode wherein and fix tight with corrosion resistant plate, heating is 10-30 minute in 110 ℃ of-160 ℃ of stoves, remove steel plate, furnace temperature is risen to 175 ℃-195 ℃ heating 1-2 hour, again furnace temperature is risen to 250 ℃-350 ℃ heating 1-2 hour, at last, furnace temperature is risen to 360 ℃-380 ℃, in nitrogen atmosphere with electrode sintering 20-30 minute, pressed down 3-7 minute at 2-3 ton pressure after above-mentioned electrode is chilled to room temperature, the electrolyte of coating in its surface then keeps base layer to get final product.
2, the method for claim 1, it is characterized in that: the catalyst of using in the said method is platinum-C catalyst, surfactant is the aqueous acetic acid of the Trlton X-114 of new preparation, the hydrophobicity high polymer is the 60.1%(mass percent) the water-soluble suspension-turbid liquid of polytetrafluoroethylene, temporary adhesive is the 12%-18%(mass percent) the polyoxyethylene aqueous solution.
3, use in a kind of fuel cell by the electrode supporting thing, cover the preparation method that its lip-deep catalyst layer and electrolyte keep the gas-diffusion electrode of base layer formation, it is characterized in that: at first, it is molten in 2.5-5.5 gram distilled water and after stirring that 0.25-0.55 is restrained catalyst, add 0.25-0.45 gram hydrophobicity high polymer, make their direct generation flocculations and form thick floccule, then above-mentioned floccule is distributed to through on the poroid carbon paper surface of hydrophobic treatment equably with rolling method, form the stratiform thing of height≤0.8 millimeter, simultaneously, with dusting cover sark is evenly dispersed on the corrosion resistant plate, above-mentioned still moist electrode is lain on the sark, put a block plate above again, fixing tight, place the stove of 120 ℃ of-180 ℃ of temperature to heat 10-20 minute, remove steel plate then, take out electrode gently, again electrode is placed on separately in the stove of 350 ℃ of-380 ℃ of temperature, in nitrogen atmosphere sintering 15-30 minute, again electrode is taken out to room temperature from stove, pressed down 2-7 minute at 2-4 ton pressure, the electrolyte of coating in its surface then keeps base layer to get final product.
4, method as claimed in claim 3 is characterized in that: the catalyst of using in the said method is platinum-C catalyst, and the hydrophobicity high polymer is the 60.1%(mass percent) the water-soluble suspension-turbid liquid of polytetrafluoroethylene, sark is carbonic hydroammonium or ammonium carbonate.
5, as claim 1 or 3 described methods, it is characterized in that: electrolyte keeps being prepared as of base layer in described two kinds of methods, be 98 with mass ratio in distilled water: 2-90: 10 carborundum and polytetrafluoroethylene mix, form the solution of homogeneous, add the 5%-7%(mass percent again) the polyoxyethylene aqueous solution, be distributed to this mixed liquor on the surface of gas-diffusion electrode with the taper coating method, treat that it is at room temperature after the drying, in 150 ℃ of-200 ℃ of stoves, heated 10-30 minute earlier, in 250 ℃ of-350 ℃ of stoves sintering 15-30 minute again, temporary adhesive is removed in heating, and the electrolyte that just forms≤0.2 millimeter on the gas-diffusion electrode surface keeps base layer.
6, as claim 2 or 4 described methods, it is characterized in that: being prepared as of the platinum-C catalyst in the said method, 10-20 gram sulfuration XC-72 type carbon black is molten in the distilled water of the 300-500 milliliter that contains 0.5-1.5 gram glacial acetic acid, and in the continuous process that stirs, add the 80-120 milliliter platinum tetrachloride solution that contains 25-35 milliliter diethyl ammonium, then 10-15 is restrained the 3%-7%(mass percent) formic acid solution add gradually, simultaneously heter temperature is elevated to 70 ℃-100 ℃, and kept 20-40 minute, be chilled to room temperature more gradually, the gained slurries are filtered and constantly wash with hot distilled water, till chloride ion is cleaned substantially, then filter cake after dry 16 hours, is worn into fine powder in 95 ℃ of baking ovens.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94118458A CN1067808C (en) | 1994-12-05 | 1994-12-05 | Gas-diffusion electrode preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94118458A CN1067808C (en) | 1994-12-05 | 1994-12-05 | Gas-diffusion electrode preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1108818A true CN1108818A (en) | 1995-09-20 |
| CN1067808C CN1067808C (en) | 2001-06-27 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94118458A Expired - Fee Related CN1067808C (en) | 1994-12-05 | 1994-12-05 | Gas-diffusion electrode preparation method |
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| Country | Link |
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| CN (1) | CN1067808C (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006000156A1 (en) * | 2004-06-23 | 2006-01-05 | Byd Company Limited | Gas diffusion electodes and membrane electrode assemblies for proton exchange membrane fuel cells |
| CN1302985C (en) * | 2002-01-11 | 2007-03-07 | 御国色素株式会社 | Carbonaceous materials and dispersions containing carbonaceous materials |
| CN1327563C (en) * | 2002-04-03 | 2007-07-18 | 3M创新有限公司 | Lamination apparatus and methods |
| CN101421438B (en) * | 2006-04-12 | 2012-10-31 | 德诺拉工业有限公司 | Gas Diffusion Electrodes for Electrolyte Percolation Cells |
| WO2014037828A1 (en) * | 2012-09-06 | 2014-03-13 | Basf Se | Gas-diffusion electrodes for metal-oxygen cells and the production of said electrodes |
| US9012346B2 (en) | 2010-11-04 | 2015-04-21 | GM Global Technology Operations LLC | Wet lamination process for reducing mud cracking in fuel cell components |
| US9419286B2 (en) | 2011-01-13 | 2016-08-16 | GM Global Technology Operations LLC | Wet lamination process for reducing mud cracking in fuel cell components |
| CN106328956A (en) * | 2016-09-06 | 2017-01-11 | 江苏大学 | Preparation method and application of high-temperature membrane fuel cell gas diffusion electrode |
| US9647274B2 (en) | 2008-01-11 | 2017-05-09 | GM Global Technology Operations LLC | Method of making a proton exchange membrane using a gas diffusion electrode as a substrate |
| US9722269B2 (en) | 2008-01-11 | 2017-08-01 | GM Global Technology Operations LLC | Reinforced electrode assembly |
| US9780399B2 (en) | 2008-01-11 | 2017-10-03 | GM Global Technology Operations LLC | Electrode assembly with integrated reinforcement layer |
| CN112687897A (en) * | 2020-12-29 | 2021-04-20 | 长沙迅洋新材料科技有限公司 | Consolidation preparation method of waterproof breathable layer material for magnesium metal air battery |
| CN113632265A (en) * | 2019-04-09 | 2021-11-09 | 凸版印刷株式会社 | Membrane electrode assembly and solid polymer fuel cell |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039506A (en) * | 1989-07-23 | 1990-02-07 | 厦门大学 | Water deficiency type gas diffusion porous electrode |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1302985C (en) * | 2002-01-11 | 2007-03-07 | 御国色素株式会社 | Carbonaceous materials and dispersions containing carbonaceous materials |
| CN1327563C (en) * | 2002-04-03 | 2007-07-18 | 3M创新有限公司 | Lamination apparatus and methods |
| WO2006000156A1 (en) * | 2004-06-23 | 2006-01-05 | Byd Company Limited | Gas diffusion electodes and membrane electrode assemblies for proton exchange membrane fuel cells |
| CN101421438B (en) * | 2006-04-12 | 2012-10-31 | 德诺拉工业有限公司 | Gas Diffusion Electrodes for Electrolyte Percolation Cells |
| US9722269B2 (en) | 2008-01-11 | 2017-08-01 | GM Global Technology Operations LLC | Reinforced electrode assembly |
| US9647274B2 (en) | 2008-01-11 | 2017-05-09 | GM Global Technology Operations LLC | Method of making a proton exchange membrane using a gas diffusion electrode as a substrate |
| US9780399B2 (en) | 2008-01-11 | 2017-10-03 | GM Global Technology Operations LLC | Electrode assembly with integrated reinforcement layer |
| US9899685B2 (en) | 2008-01-11 | 2018-02-20 | GM Global Technology Operations LLC | Method of making a proton exchange membrane using a gas diffusion electrode as a substrate |
| US9012346B2 (en) | 2010-11-04 | 2015-04-21 | GM Global Technology Operations LLC | Wet lamination process for reducing mud cracking in fuel cell components |
| US9419286B2 (en) | 2011-01-13 | 2016-08-16 | GM Global Technology Operations LLC | Wet lamination process for reducing mud cracking in fuel cell components |
| WO2014037828A1 (en) * | 2012-09-06 | 2014-03-13 | Basf Se | Gas-diffusion electrodes for metal-oxygen cells and the production of said electrodes |
| CN106328956A (en) * | 2016-09-06 | 2017-01-11 | 江苏大学 | Preparation method and application of high-temperature membrane fuel cell gas diffusion electrode |
| CN113632265A (en) * | 2019-04-09 | 2021-11-09 | 凸版印刷株式会社 | Membrane electrode assembly and solid polymer fuel cell |
| CN113632265B (en) * | 2019-04-09 | 2024-05-14 | 凸版印刷株式会社 | Membrane electrode assembly and solid polymer fuel cell |
| CN112687897A (en) * | 2020-12-29 | 2021-04-20 | 长沙迅洋新材料科技有限公司 | Consolidation preparation method of waterproof breathable layer material for magnesium metal air battery |
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