CN110438819A - A kind of solid hyperchromic preparation method - Google Patents
A kind of solid hyperchromic preparation method Download PDFInfo
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- CN110438819A CN110438819A CN201910737726.6A CN201910737726A CN110438819A CN 110438819 A CN110438819 A CN 110438819A CN 201910737726 A CN201910737726 A CN 201910737726A CN 110438819 A CN110438819 A CN 110438819A
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- Prior art keywords
- hyperchromic
- solid
- preparation
- fibre cloth
- carrier fibre
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- 230000000215 hyperchromic effect Effects 0.000 title claims abstract description 78
- 239000007787 solid Substances 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000000835 fiber Substances 0.000 claims abstract description 75
- 239000004744 fabric Substances 0.000 claims abstract description 69
- 239000007788 liquid Substances 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000001035 drying Methods 0.000 claims abstract description 16
- 238000007761 roller coating Methods 0.000 claims abstract description 16
- 239000000853 adhesive Substances 0.000 claims abstract description 12
- 230000001070 adhesive effect Effects 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 12
- 230000008569 process Effects 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 230000006855 networking Effects 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- -1 polypropylene Polymers 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 12
- 239000000975 dye Substances 0.000 claims description 11
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 5
- 239000000987 azo dye Substances 0.000 claims description 4
- 241000234435 Lilium Species 0.000 claims description 3
- 229920005749 polyurethane resin Polymers 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 239000004677 Nylon Substances 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 229920002521 macromolecule Polymers 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 229920001778 nylon Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 238000005562 fading Methods 0.000 abstract description 5
- 238000005406 washing Methods 0.000 description 15
- 125000002091 cationic group Chemical group 0.000 description 12
- 229920001296 polysiloxane Polymers 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 7
- 229920000178 Acrylic resin Polymers 0.000 description 6
- 239000004925 Acrylic resin Substances 0.000 description 6
- 239000003599 detergent Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 238000005282 brightening Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000002242 deionisation method Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 229910052747 lanthanoid Inorganic materials 0.000 description 2
- 150000002602 lanthanoids Chemical class 0.000 description 2
- 238000004900 laundering Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 239000008118 PEG 6000 Substances 0.000 description 1
- 229920002584 Polyethylene Glycol 6000 Polymers 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920000344 molecularly imprinted polymer Polymers 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/02—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/28—Preparing azo dyes on the material
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of hyperchromic preparation methods of solid, are related to the hyperchromic technical field of fabric.Be characterized in that: a kind of solid hyperchromic preparation method includes the following steps: step 1, and hyperchromic liquid prepares: toner and adhesive being dissolved in deionized water, adjusting pH is 3.5-9, and auxiliary agent is added, is uniformly mixed, obtains hyperchromic liquid；Step 2, carrier fibre cloth prepare: fibrous raw material is obtained carrier fibre cloth by fiber opening, combing networking and water jet process；Step 3, roller coating: by the way of roller coating by hyperchromic liquid be rolled onto carrier fibre cloth one side or it is two-sided on；Drying: step 4 passes through carrier fibre cloth drying forming to get arriving solid hyperchromic under the conditions of 80-120 DEG C of temperature.Solid hyperchromic prepared by the present invention has the advantages that prevent clothing color fading and dimmed.
Description
Technical field
The present invention relates to the hyperchromic technical fields of fabric, more specifically, it relates to a kind of solid hyperchromic preparation method.
Background technique
In daily life, clothing is repeatedly washed, and will lead to its lighter or dimmed, and current effective solution is
Brightening agent or black detergent are added in laundering process, help somewhat to assign fabric sheen and are prevented
Deep-colour fabric colour fading shoals.
Above-mentioned brightening agent and black detergent needs are separately added in laundry water during clothes washing, not only
It is more troublesome, and using effect is bad, clothing still has dimmed situation of fading after repeatedly washing.
It is, therefore, desirable to provide a kind of new scheme solves the above problems.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of solid hyperchromic preparation method,
It has the advantages that prevent clothing color fading and dimmed.
To achieve the above object one, the present invention provides the following technical scheme that
A kind of solid hyperchromic preparation method, includes the following steps:
Step 1, hyperchromic liquid prepare: toner and adhesive is dissolved in deionized water, adjusting pH is 3.5-9, and auxiliary agent is added,
It is uniformly mixed, obtains hyperchromic liquid；
Step 2, carrier fibre cloth prepare: fibrous raw material is obtained carrier fibre by fiber opening, combing networking and water jet process
Wei Bu；
Step 3, roller coating: by the way of roller coating by hyperchromic liquid be rolled onto carrier fibre cloth one side or it is two-sided on；
Step 4, drying: by carrier fibre cloth drying forming to get to solid hyperchromic under the conditions of 80-120 DEG C of temperature.
By using above-mentioned technical proposal, aiming at the problem that black clothing fades, black washing is all made of in technology at present
Agent is added in laundry water, but this black detergent using effect is bad, and not can guarantee can also after clothing repeatedly washs
Enough colour-fast and dimmed, the present invention is bright-coloured or black clothing for color by using toner, can be good at by
Clothing is captured, so that clothing is still able to maintain bright-coloured and colour-fast dimmed after repeatedly washing.
Solid of the invention hyperchromic uses carrier fibre cloth, and toner, adhesive and auxiliary agent are rolled onto carrier fibre
On cloth, when use, solid hyperchromic is mixed with clothing directly and is added in laundry water, toner is from carrier fibre
It discharges and is attached on clothing in cloth, it is gorgeous to achieve the effect that clothing increases black increasing, so that clothing is also not susceptible to by repeatedly washing
It fades and dimmed situation, carrier fibre cloth is small in size, lighter weight, and being easy to transport and travel carries, and use is more convenient.
Further preferably, the toner is black dyes, and the black dyes uses azo dyes.
By using above-mentioned technical proposal, azo dyes is suitable for cellulosics, so that fabric color is bright-coloured, after effect
Fugitive color is not dimmed.
Further preferably, the toner uses cationic silicones high molecular polymer.
By using above-mentioned technical proposal, cationic silicones Molecularly Imprinted Polymer serves as a kind of increasing in laundering process
The effect of deep agent changes the reflectivity to light, thus increasing deep base by forming one layer of hydrophobic film on clothes fiber surface
It can achieve the effect that repair fabric color on plinth.
Further preferably, described adhesive is using one in acrylic resin, polyurethane resin and polyvinyl acetate
Kind is a variety of.
By using above-mentioned technical proposal, the presence of adhesive can avoid occurring when carrier fibre bending or deformation hyperchromic
Agent obscission avoids the toner to fall off from being transferred to user on hand, and can enable clothing is as much as possible to capture
Toner, and capture more stable after toner, adhesive uses more group polyfunctional group structures, on the fabric resistance to
Washing property is preferable, and after tens washings, fabric is still able to maintain good color properties.
Further preferably, the carrier fibre cloth uses Fypro, polyester fiber or polypropylene fibre.
By using above-mentioned technical proposal, carrier fibre cloth obtains spunlace non-woven cloth by water jet process, and fiber is mutual
It being intertwined, fibre web is reinforced and has certain strength, and using synthetic fibers, raw material sources are extensive, and it is cheap, it can
Production cost is substantially reduced, furthermore synthetic fibers are easier to discharge the toner in hyperchromic liquid.
Further preferably, the auxiliary agent includes surfactant, and the surfactant uses Gemini surface-active
Agent or polyethylene glycol.
By using above-mentioned technical proposal, Gemini surface active can reduce the surface tension of toner and adhesive,
The two compatibility is improved, and more stable dispersion is in deionized water.Polyethylene glycol is nonionic surfactant, stability
Height is added in hyperchromic liquid, the stop that may make toner effectively stable on the fabric so that clothing is by repeatedly washing it
Not fugitive color and dimmed afterwards.
Further preferably, 8-12 parts of rare earth compound is additionally added in the hyperchromic liquid.
By using above-mentioned technical proposal, rare earth compound contains 15 kinds of elements of group of the lanthanides in the periodic table of chemical element, and
Closely related yttrium and scandium element, rare earth element can be modified fiber with group of the lanthanides, so that limit extruding, structural relaxation,
Activation and complexing are carried out to dirt on fiber, it is made to be cleaved to form complex compound with the spot containing elements such as N, O, S, it is dilute
After soil dispersion is dealt into washing water, capillary effect can be improved, so that fabrics feel soft, improves appearance of fabrics, improve plant
Whiteness, to increase deep Zeng Yan.
Further preferably, according to the mass fraction, the toner dosage is 12-15 parts, and described adhesive dosage is 5-
10 parts, the auxiliary dosage is 1-10 parts, and the carrier fibre cloth dosage is 45-50 parts.
Further preferably, the carrier fibre cloth with a thickness of 0.4-1mm.
By using above-mentioned technical proposal, the thickness control of carrier fibre cloth is between 0.4-1mm, thinner thickness, a side
Face can reduce production cost, and on the other hand relatively thin carrier fibre cloth is relatively soft, be conducive to the producer and user grabs, and subtract
Inner wrapping space.
Further preferably, the carrier fibre cloth uses lily spunlace non-woven cloth.
By using above-mentioned technical proposal, using lily carrier fibre cloth, in use, dark is hyperchromic
Agent is discharged from carrier fibre cloth, and the carrier fibre cloth for losing toner restores white, a kind of to user from sense organ
The good feeling of using effect.
In conclusion compared with prior art, the invention has the following advantages:
(1) directly that solid is hyperchromic when use by the way that toner, adhesive and auxiliary agent to be rolled on carrier fibre cloth
Piece and clothing, which are mixed, to be added in laundry water, and toner is discharged from carrier fibre cloth and is attached on clothing, reaches clothing
Object increases the gorgeous effect of black increasing, so that clothing is also not susceptible to fade and dimmed situation, carrier fibre cloth body by repeatedly washing
Small, the lighter weight of product, being easy to transport and travel carries, and use is more convenient；
(2) by using toner, it is bright-coloured or black clothing for color, can be good at being captured by clothing,
So that clothing is still able to maintain bright-coloured and colour-fast dimmed after repeatedly washing；
(3) carrier fibre cloth of the invention uses spunlace non-woven cloth, and fiber therein is wound mutually, so that original fiber netting gear
There are certain strength and complete structure, feel is preferable, is easy to grab, and when in use, and toner is easier to from carrier fibre
It is discharged in cloth, so that solid hyperchromic can sufficiently use.
Detailed description of the invention
The preparation method flow chart that Fig. 1 is solid hyperchromic in the present invention.
Specific embodiment
With reference to the accompanying drawings and examples.
Embodiment 1: a kind of solid hyperchromic, acquisition is made by the steps:
Step 1, hyperchromic liquid prepare: 12 parts of cationic silicones high molecular polymers and 5 parts of acrylic resins are dissolved in deionization
In water, pH=7 is adjusted, 1 part of Gemini surface active and 8 parts of rare earth compounds is added, is uniformly mixed, obtains hyperchromic
Liquid；
Step 2, carrier fibre cloth prepare: by 45 parts of Fypro raw materials by fiber opening, combing networking and water jet process
Obtain the carrier fibre cloth with a thickness of 0.6mm；
Roller coating: hyperchromic liquid is rolled onto the one side of carrier fibre cloth by step 3 by the way of roller coating；
Step 4, drying: by carrier fibre cloth drying forming to get to solid hyperchromic under the conditions of 100 DEG C of temperature；
In the present embodiment, cationic silicones high molecular polymer uses the VIvo brand deep-dyeing agent of U.S. P&G company production；
Gemini surface active uses the surfactant of Jining Hua Kai resin Co., Ltd production.
Embodiment 2-6: a kind of solid hyperchromic, difference from example 1 is that, each component and its corresponding quality
Number is as shown in table 1.
Each component and its mass fraction in 1 embodiment 2-6 of table
Embodiment 7: a kind of solid hyperchromic, acquisition is made by the steps:
Step 1, hyperchromic liquid prepare: 12 parts of black dyes and 5 parts of acrylic resins is dissolved in deionized water, pH=7 is adjusted,
1 part of Gemini surface active and 8 parts of rare earth compounds is added, is uniformly mixed, obtains hyperchromic liquid；
Step 2, carrier fibre cloth prepare: by 45 parts of Fypro raw materials by fiber opening, combing networking and water jet process
Obtain the carrier fibre cloth with a thickness of 0.6mm；
Roller coating: hyperchromic liquid is rolled onto the one side of carrier fibre cloth by step 3 by the way of roller coating；
Step 4, drying: by carrier fibre cloth drying forming to get to solid hyperchromic under the conditions of 100 DEG C of temperature；
In the present embodiment, black dyes uses the azo dyes of Longgang District of Shenzhen City Lai Ang dyestuff firm production；The surface Gemini
Activating agent uses the surfactant of Jining Hua Kai resin Co., Ltd production.
Embodiment 8: a kind of solid hyperchromic, acquisition is made by the steps:
Step 1, hyperchromic liquid prepare: 12 parts of cationic silicones high molecular polymers, 2.5 parts of acrylic resins and 2.5 parts are poly-
Urethane resin is dissolved in deionized water, adjusts pH=7,1 part of Gemini surface active and 8 parts of rare earth compounds is added, and is stirred
It is uniformly mixed, obtains hyperchromic liquid；
Step 2, carrier fibre cloth prepare: by 45 parts of Fypro raw materials by fiber opening, combing networking and water jet process
Obtain the carrier fibre cloth with a thickness of 0.6mm；
Roller coating: hyperchromic liquid is rolled onto the one side of carrier fibre cloth by step 3 by the way of roller coating；
Step 4, drying: by carrier fibre cloth drying forming to get to solid hyperchromic under the conditions of 100 DEG C of temperature；
In the present embodiment, cationic silicones high molecular polymer uses the VIvo brand deep-dyeing agent of U.S. P&G company production；
Gemini surface active uses the surfactant of Jining Hua Kai resin Co., Ltd production.
Embodiment 9: a kind of solid hyperchromic, acquisition is made by the steps:
Step 1, hyperchromic liquid prepare: by 12 parts of cationic silicones high molecular polymers, 2 parts of acrylic resins, 2 parts of polyurethane
Resin and 2 parts of polyvinyl acetate are dissolved in deionized water, adjust pH=7,1 part of Gemini surface active is added and 8 parts dilute
Earth compounds are uniformly mixed, and obtain hyperchromic liquid；
Step 2, carrier fibre cloth prepare: by 45 parts of Fypro raw materials by fiber opening, combing networking and water jet process
Obtain the carrier fibre cloth with a thickness of 0.6mm；
Roller coating: hyperchromic liquid is rolled onto the one side of carrier fibre cloth by step 3 by the way of roller coating；
Step 4, drying: by carrier fibre cloth drying forming to get to solid hyperchromic under the conditions of 100 DEG C of temperature；
In the present embodiment, cationic silicones high molecular polymer uses the VIvo brand deep-dyeing agent of U.S. P&G company production；
Gemini surface active uses the surfactant of Jining Hua Kai resin Co., Ltd production.
Embodiment 10: a kind of solid hyperchromic, acquisition is made by the steps:
Step 1, hyperchromic liquid prepare: 12 parts of cationic silicones high molecular polymers and 5 parts of acrylic resins are dissolved in deionization
In water, pH=7 is adjusted, 1 part of polyethylene glycol and 8 parts of rare earth compounds is added, is uniformly mixed, obtains hyperchromic liquid；
Step 2, carrier fibre cloth prepare: by 45 parts of Fypro raw materials by fiber opening, combing networking and water jet process
Obtain the carrier fibre cloth with a thickness of 0.6mm；
Roller coating: hyperchromic liquid is rolled onto the one side of carrier fibre cloth by step 3 by the way of roller coating；
Step 4, drying: by carrier fibre cloth drying forming to get to solid hyperchromic under the conditions of 100 DEG C of temperature；
In the present embodiment, cationic silicones high molecular polymer uses the VIvo brand deep-dyeing agent of U.S. P&G company production；It is poly-
Ethylene glycol uses the molecular weight of the model PEG-6000 of Jiangsu Hai'an Petrochemical Plant for the polyethylene glycol of 5500-7000.
Embodiment 1: a kind of solid hyperchromic preparation method the difference is that, does not add with 1 institute of embodiment in hyperchromic liquid
Enter cationic silicones high molecular polymer.
Embodiment 2: a kind of solid hyperchromic preparation method the difference is that, does not add with 1 institute of embodiment in hyperchromic liquid
Enter polyethylene glycol.
Embodiment 3: a kind of solid hyperchromic preparation method the difference is that, does not add with 1 institute of embodiment in hyperchromic liquid
Enter rare earth compound.
Performance test
Using commercially available 13 sets of black pure cotton knitted fabric clothes common, respectively experimental group 1-10 and control group 1-3, using Tide
Laundry detergents are washed, and respectively mix solid made from embodiment 1-10 hyperchromic with clothing in experimental group 1-10, respectively
Solid made from comparative example 1-3 hyperchromic is mixed with clothing in control group 1-3.In this experiment, using automatic washing machine pair
Clothing is machine-washed, and every group of equal repeated washing of clothing and is dried 20 times.
2 the performance test results of table
| Test item | Cleaning 5 times | Cleaning 10 times | Cleaning 20 times |
| Experimental group 1 | Color is deeper, does not fade | Color is deeper, does not fade | Color is deeper, slight to fade |
| Experimental group 2 | Color is deeper, does not fade | Color is deeper, does not fade | Color is deeper, slight to fade |
| Experimental group 3 | Color is deeper, does not fade | Color is deeper, does not fade | Color is deeper, slight to fade |
| Experimental group 4 | Color is deeper, does not fade | Color is deeper, does not fade | Color is deeper, slight to fade |
| Experimental group 5 | Color is deeper, does not fade | Color is deeper, does not fade | Color is deeper, slight to fade |
| Experimental group 6 | Color is deeper, does not fade | Color is deeper, does not fade | Color is deeper, slight to fade |
| Experimental group 7 | Color is deeper, does not fade | Color is deeper, does not fade | Color is deeper, slight to fade |
| Experimental group 8 | Color is deeper, does not fade | Color is deeper, does not fade | Color is deeper, slight to fade |
| Experimental group 9 | Color is deeper, does not fade | Color is deeper, does not fade | Color is deeper, slight to fade |
| Experimental group 10 | Color is deeper, does not fade | Color is deeper, does not fade | Color is deeper, slight to fade |
| Control group 1 | Color is deeper, does not fade | Clothing slightly fades, dimmed | Clothing fades seriously, lighter |
| Control group 2 | Color is deeper, does not fade | Clothing slightly fades, dimmed | Clothing slightly fades, dimmed |
| Control group 3 | Color is deeper, does not fade | Clothing slightly fades, dimmed | Clothing slightly fades, dimmed |
By test result in table 2 it is found that can obviously prevent clothing color fading and dimmed using obtained hyperchromic of the solid of the present invention,
It is wherein not added with the control group 1 of cationic silicones high molecular polymer and fades after washing 20 times more serious, and do not add
The control group 2 of addition polymerization ethylene glycol and the control group 3 of rare earth compound is not added with after washing 20 times, clothing slightly fades and becomes
Secretly.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art
Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of solid hyperchromic preparation method, which comprises the steps of:
Step 1, hyperchromic liquid prepare: toner and adhesive is dissolved in deionized water, adjusting pH is 3.5-9, and auxiliary agent is added,
It is uniformly mixed, obtains hyperchromic liquid；
Step 2, carrier fibre cloth prepare: fibrous raw material is obtained carrier fibre by fiber opening, combing networking and water jet process
Wei Bu；
Step 3, roller coating: by the way of roller coating by hyperchromic liquid be rolled onto carrier fibre cloth one side or it is two-sided on；
Step 4, drying: by carrier fibre cloth drying forming to get to solid hyperchromic under the conditions of 80-120 DEG C of temperature.
2. solid hyperchromic preparation method according to claim 1, which is characterized in that the toner is black dye
Material, the black dyes use azo dyes.
3. solid hyperchromic preparation method according to claim 1, which is characterized in that the toner is using cation
Organosilicon macromolecule polymer.
4. solid hyperchromic preparation method according to claim 1, which is characterized in that described adhesive uses acrylic acid
One of resin, polyurethane resin and polyvinyl acetate are a variety of.
5. solid hyperchromic preparation method according to claim 1, which is characterized in that the carrier fibre cloth is using poly-
Nylon, polyester fiber or polypropylene fibre.
6. solid hyperchromic preparation method according to claim 1, which is characterized in that the auxiliary agent includes surface-active
Agent, the surfactant use Gemini surface active or polyethylene glycol.
7. solid hyperchromic preparation method according to claim 1, which is characterized in that be additionally added in the hyperchromic liquid
8-12 parts of rare earth compound.
8. solid hyperchromic preparation method according to claim 1, which is characterized in that according to the mass fraction, the increasing
Toner dosage is 12-15 parts, and described adhesive dosage is 5-10 parts, and the auxiliary dosage is 1-10 parts, the carrier fibre cloth
Dosage is 45-50 parts.
9. solid hyperchromic preparation method according to claim 1, which is characterized in that the thickness of the carrier fibre cloth
For 0.4-1mm.
10. solid hyperchromic preparation method according to claim 1, which is characterized in that the carrier fibre cloth uses
Lily spunlace non-woven cloth.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4077890A (en) * | 1973-02-23 | 1978-03-07 | Graham Barker | Composition for treating fabrics, method for making and using the same |
| US20030207630A1 (en) * | 1995-12-19 | 2003-11-06 | Newlund Laboratories, Inc. | Method of making a laundry detergent article containing detergent formulations |
| US20070042923A1 (en) * | 2005-07-08 | 2007-02-22 | Akos Jankura | Laundry cleaning delivery system |
| CN102408950A (en) * | 2011-09-28 | 2012-04-11 | 宋子奎 | Colored textile hyperchromic washing agent and its preparation method |
-
2019
- 2019-08-12 CN CN201910737726.6A patent/CN110438819A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4077890A (en) * | 1973-02-23 | 1978-03-07 | Graham Barker | Composition for treating fabrics, method for making and using the same |
| US20030207630A1 (en) * | 1995-12-19 | 2003-11-06 | Newlund Laboratories, Inc. | Method of making a laundry detergent article containing detergent formulations |
| US20070042923A1 (en) * | 2005-07-08 | 2007-02-22 | Akos Jankura | Laundry cleaning delivery system |
| CN102408950A (en) * | 2011-09-28 | 2012-04-11 | 宋子奎 | Colored textile hyperchromic washing agent and its preparation method |
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Application publication date: 20191112 |