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CN110343556A - Skid-mounted carbon dioxide flooding returns exhaust gas desulfurization dehydration and carbon dioxide recovery system, in accordance - Google Patents

Skid-mounted carbon dioxide flooding returns exhaust gas desulfurization dehydration and carbon dioxide recovery system, in accordance Download PDF

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CN110343556A
CN110343556A CN201910684047.7A CN201910684047A CN110343556A CN 110343556 A CN110343556 A CN 110343556A CN 201910684047 A CN201910684047 A CN 201910684047A CN 110343556 A CN110343556 A CN 110343556A
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gas
carbon dioxide
skid
desulfurization
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CN110343556B (en
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陆诗建
李清方
陆胤君
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Sinopec Oilfield Service Corp
Sinopec Energy and Environmental Engineering Co Ltd
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Sinopec Energy and Environmental Engineering Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/50Carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/103Sulfur containing contaminants

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
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Abstract

本发明提供了一种橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其包括返排气预处理及脱硫橇块、冷干橇块、压缩机进膜橇块、膜分离橇块、二氧化碳增压回注橇块;冷干橇块与返排气预处理及脱硫橇块连通;压缩机进膜橇块与冷干橇块连通;膜分离橇块与压缩机进膜橇块连通;二氧化碳增压回注橇块与膜分离橇块连通;其中,返排气进入返排气预处理及脱硫橇块进行预处理以及脱硫,然后进入冷干橇块,以进行脱水处理,脱水处理后的返排气进入压缩机进膜橇块被增压处理,增压后的返排气进入膜分离橇块中进行气体分离。本发明的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统橇装化设计安装操作方便,便于对气量小的返排气进行处理。

The invention provides a skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system, which comprises a return gas pretreatment and desulfurization skid block, a cold drying skid block, a compressor membrane feeding skid block, a membrane separation skid block, Carbon dioxide pressurization reinjection skid block; cold-drying skid block is connected with return exhaust gas pretreatment and desulfurization skid block; compressor membrane feed block is connected with cold-drying skid block; membrane separation skid block is communicated with compressor film feed block; The carbon dioxide pressurized re-injection skid is connected to the membrane separation skid; wherein, the return exhaust gas enters the return exhaust gas pretreatment and desulfurization skid for pretreatment and desulfurization, and then enters the cold-drying skid for dehydration treatment. The returned exhaust gas enters the compressor and the membrane inlet skid block is pressurized, and the pressurized return exhaust gas enters the membrane separation skid block for gas separation. The skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system of the present invention has a skid-mounted design, is convenient for installation and operation, and facilitates the treatment of the returned exhaust gas with a small amount of gas.

Description

橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统Skid-mounted carbon dioxide drive back exhaust gas desulfurization dehydration and carbon dioxide recovery system

技术领域technical field

本发明涉及二氧化碳回收领域,尤其涉及一种橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统。The invention relates to the field of carbon dioxide recovery, in particular to a skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system.

背景技术Background technique

随着二氧化碳驱三次采油技术的规模化推广,二氧化碳驱采出液地面工艺面临着一些难题:二氧化碳被注入地下后,约有50%~60%被永久封存于地下,剩余的40%~50%则随着油田采出液的返排气溢出。由于二氧化碳驱采出液的返排气含有较多的CO2,二氧化碳驱采出液的返排气不经过必要的处理不能进入集输管网或被点燃,只能直接排放,这既污染了环境,又浪费了天然气、CO2资源,降低了二氧化碳驱油和埋存效果。油田的CO2驱采出液的返排气中CO2回收利用不仅可以保护环境,而且可以利用资源,提高经济效益。合理回收利用CO2驱采出液的返排气资源将是我国未来发展的一个趋势。With the large-scale promotion of CO2 flooding tertiary oil recovery technology, the surface process of CO2 flooding produced fluid faces some difficulties: after carbon dioxide is injected into the ground, about 50% to 60% is permanently stored underground, and the remaining 40% to 50% Then it overflows with the backflow of oilfield produced fluid. Since the blowback gas of the produced liquid from carbon dioxide flooding contains a lot of CO 2 , the blowback gas of the produced liquid from carbon dioxide flooding cannot enter the gathering pipeline network or be ignited without necessary treatment, and can only be discharged directly, which not only pollutes It also wastes natural gas and CO 2 resources, and reduces the effect of carbon dioxide flooding and storage. The recovery and utilization of CO 2 in the return gas of the CO 2 flooding produced fluid in the oil field can not only protect the environment, but also utilize resources and improve economic benefits. It will be a trend of China's future development to rationally recycle and utilize the backflow gas resources of CO 2 flooding produced fluid.

对于单井CO2驱油工程,采出液中返排气气量小,采用传统的胺法脱硫及脱碳投资大、运行成本高,且不经济。For single-well CO 2 flooding projects, the amount of gas returned in the produced fluid is small, and the traditional amine method for desulfurization and decarbonization requires large investment, high operating cost, and is uneconomical.

发明内容SUMMARY OF THE INVENTION

鉴于背景技术中存在的问题,本发明的目的在于提供一种橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其能够将返排气进行处理并将二氧化碳与天然气分离开,从而有效利用天然气,回收二氧化碳,且采用橇装式设计,便于对气量小的返排气进行处理,降低返排气的处理成本。In view of the problems existing in the background technology, the purpose of the present invention is to provide a skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system, which can process the return exhaust gas and separate carbon dioxide from natural gas, thereby effectively utilizing Natural gas, recovering carbon dioxide, and adopting a skid-mounted design, it is convenient to process the return exhaust gas with small gas volume and reduce the processing cost of the return exhaust gas.

为了实现上述目的,本发明提供了一种橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其包括返排气预处理及脱硫橇块、冷干橇块、压缩机进膜橇块、膜分离橇块、二氧化碳增压回注橇块。冷干橇块与返排气预处理及脱硫橇块通过管路连通;压缩机进膜橇块与冷干橇块通过管路连通;膜分离橇块与压缩机进膜橇块通过管路连通;二氧化碳增压回注橇块与膜分离橇块通过管路连通。其中,返排气首先进入返排气预处理及脱硫橇块进行预处理以及脱硫,进行预处理以及脱硫后的返排气进入冷干橇块,以在冷干橇块中进行脱水处理,脱水处理后的返排气进入压缩机进膜橇块,以被增压处理,增压后的返排气进入膜分离橇块中进行气体分离,以将二氧化碳、烃类气体分离,分离的二氧化碳进入二氧化碳增压回注橇块进行增压回注处理,烃类气体作为天然气使用。In order to achieve the above object, the present invention provides a skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system, which includes a return gas pretreatment and desulfurization skid, a cold-drying skid, a compressor film feeding skid, Membrane separation skid block, carbon dioxide pressurized reinjection skid block. The cold-drying skid block is connected with the return gas pretreatment and desulfurization block through pipelines; the compressor membrane inlet skid block and the cold-drying skid block are connected through pipelines; the membrane separation skid block and the compressor film-inlet skid block are connected through pipelines ; The carbon dioxide pressurized reinjection skid block and the membrane separation skid block are communicated through pipelines. Among them, the return exhaust gas first enters the return exhaust gas pretreatment and desulfurization skid for pretreatment and desulfurization, and the return exhaust gas after the pretreatment and desulfurization enters the cold drying skid for dehydration treatment in the cold drying skid. The treated return exhaust gas enters the compressor into the membrane feed block to be pressurized, and the pressurized return exhaust gas enters the membrane separation block for gas separation to separate carbon dioxide and hydrocarbon gases, and the separated carbon dioxide enters The carbon dioxide pressurized re-injection sled is used for pressurized re-injection treatment, and the hydrocarbon gas is used as natural gas.

在一实施例中,返排气预处理及脱硫橇块包括第一气液分离器、第一颗粒过滤器、活性炭塔、至少一级脱硫塔。In one embodiment, the return gas pretreatment and desulfurization skid block includes a first gas-liquid separator, a first particle filter, an activated carbon tower, and at least a first-stage desulfurization tower.

第一气液分离器包括:第一气液分离器入口;第一气液分离器第一出口;第一气液分离器第二出口,用于连通外部排污池。The first gas-liquid separator includes: an inlet of the first gas-liquid separator; a first outlet of the first gas-liquid separator; and a second outlet of the first gas-liquid separator, which is used to communicate with an external sewage tank.

第一颗粒过滤器包括:第一颗粒过滤器入口,连通第一气液分离器第一出口;第一颗粒过滤器第一出口;第一颗粒过滤器第二出口,用于连通外部排污池。The first particle filter includes: a first particle filter inlet, which is connected to the first outlet of the first gas-liquid separator; a first outlet of the first particle filter; and a second outlet of the first particle filter, which is used to communicate with the external sewage tank.

活性炭塔包括:活性炭塔入口,连通第一颗粒过滤器第一出口;活性炭塔第一出口;活性塔塔第二出口,用于连通外部排污池。The activated carbon tower comprises: the inlet of the activated carbon tower, which is connected to the first outlet of the first particle filter; the first outlet of the activated carbon tower; and the second outlet of the activated carbon tower, which is used to communicate with the external sewage pool.

一级脱硫塔包括:一级脱硫塔入口,连通活性炭塔第一出口;一级脱硫塔第一出口,连通冷干橇块;一级脱硫塔第二出口,用于连通外部排污池。The first-stage desulfurization tower includes: the inlet of the first-stage desulfurization tower is connected to the first outlet of the activated carbon tower; the first outlet of the first-stage desulfurization tower is connected to the cold drying skid; the second outlet of the first-stage desulfurization tower is used to connect to the external sewage pool.

其中,返排气经由第一气液分离器入口进入第一气液分离器中进行气液分离并形成分离气和液体,液体经由第一气液分离器第二出口入排污池中;分离气经由第一气液分离器第一出口、第一颗粒过滤器入口进入第一颗粒过滤器中进行过滤,以将分离气中混合的固体杂质颗粒进行初次过滤,过滤出的固体杂质颗粒经由第一颗粒过滤器第二出口排入到排污池中,而过滤后的分离气经由第一颗粒过滤器第一出口、活性炭塔入口进入活性炭塔中进行脱重烃,脱除的重烃经由活性炭塔第二出口排入到排污池中,脱除重烃的分离气至少部分经由活性炭塔第一出口、一级脱硫塔入口进入一级脱硫塔中进行脱硫,脱除的含硫污水经由一级脱硫塔第二出口流入到排污池中,脱硫后的分离气经由脱硫塔第一出口流入到冷干橇块中,以进行下一步操作。Wherein, the return gas enters the first gas-liquid separator through the inlet of the first gas-liquid separator for gas-liquid separation and forms separated gas and liquid, and the liquid enters the sewage tank through the second outlet of the first gas-liquid separator; the separated gas Through the first outlet of the first gas-liquid separator and the inlet of the first particle filter, it enters the first particle filter for filtration, so as to filter the solid impurity particles mixed in the separated gas for the first time, and the filtered solid impurity particles pass through the first particle filter. The second outlet of the particle filter is discharged into the sewage tank, and the filtered separated gas enters the activated carbon tower through the first outlet of the first particle filter and the inlet of the activated carbon tower to remove heavy hydrocarbons, and the removed heavy hydrocarbons pass through the activated carbon tower. The second outlet is discharged into the sewage tank, and the separated gas from the heavy hydrocarbons is at least partially entered into the first-stage desulfurization tower through the first outlet of the activated carbon tower and the inlet of the first-stage desulfurization tower for desulfurization, and the removed sulfur-containing sewage passes through the first-stage desulfurization tower. The second outlet flows into the sewage tank, and the separated gas after desulfurization flows into the cold drying skid block through the first outlet of the desulfurization tower for the next operation.

在一实施例中,返排气预处理及脱硫橇块还包括二级脱硫塔,二级脱硫塔包括:二级脱硫塔入口,连通活性炭塔第一出口、一级脱硫塔第一出口;二级脱硫塔第一出口,连通冷干橇块;二级脱硫塔第二出口,用于连通外部排污池。其中,经由活性炭塔第一出口排出的分离气至少部分经由二级脱硫塔入口进入二级脱硫塔中进行脱硫处理,且经由一级脱硫塔第一出口排出的分离气经由二级脱硫塔入口再次进入到二级脱硫塔中进行二次脱硫,脱硫后的分离气经由二级脱硫塔第一出口流入到冷干橇块中,而二级脱硫塔脱除的含硫污水经由二级脱硫塔第二出口流入到排污池中。In one embodiment, the return gas pretreatment and desulfurization skid further includes a secondary desulfurization tower, and the secondary desulfurization tower includes: an inlet of the secondary desulfurization tower, which is connected to the first outlet of the activated carbon tower and the first outlet of the primary desulfurization tower; two The first outlet of the first-stage desulfurization tower is connected to the cold-drying skid block; the second outlet of the second-stage desulfurization tower is used to connect to the external sewage pool. Wherein, at least part of the separated gas discharged through the first outlet of the activated carbon tower enters the secondary desulfurization tower through the inlet of the secondary desulfurization tower for desulfurization treatment, and the separated gas discharged through the first outlet of the primary desulfurization tower passes through the inlet of the secondary desulfurization tower again. Enter into the secondary desulfurization tower for secondary desulfurization, the separated gas after desulfurization flows into the cold drying skid through the first outlet of the secondary desulfurization tower, and the sulfur-containing sewage removed by the secondary desulfurization tower passes through the second desulfurization tower. The second outlet flows into the sewage pool.

在一实施例中,返排气预处理及脱硫橇块还包括:切断阀,设置于第一气液分离器入口的上游管路上,用于控制第一气液分离器入口的上游管路的打开与闭合。In one embodiment, the return gas pretreatment and desulfurization skid block further includes: a shut-off valve, which is arranged on the upstream pipeline of the inlet of the first gas-liquid separator, and is used to control the flow of the upstream pipeline of the inlet of the first gas-liquid separator. Open and closed.

在一实施例中,冷干橇块包括冷干机、第二气液分离器和第二颗粒过滤器。In one embodiment, the refrigerated drying skid includes a refrigerated dryer, a second gas-liquid separator, and a second particle filter.

冷干机包括:冷干机入口,连通一级脱硫塔第一出口、二级脱硫塔第一出口;冷干机第一出口;冷干机第二出口,用于连通外部排污池。The refrigerating machine includes: an inlet of the refrigerating machine, which is connected to the first outlet of the primary desulfurization tower and the first outlet of the secondary desulfurizing tower; the first outlet of the refrigerating machine;

第二气液分离器包括:第二气液分离器入口,连通冷干机第一出口;第二气液分离器第一出口;第二气液分离器第二出口,用于连通外部排污池。The second gas-liquid separator includes: the inlet of the second gas-liquid separator, which is connected to the first outlet of the refrigerating machine; the first outlet of the second gas-liquid separator; and the second outlet of the second gas-liquid separator, which is used to communicate with the external sewage tank .

第二颗粒过滤器包括:第二颗粒过滤器入口,连通第二气液分离器第一出口;第二颗粒过滤器第一出口,连通压缩机进膜橇块;第二颗粒过滤器第二出口,用于连通外部排污池。The second particulate filter includes: an inlet of the second particulate filter, which is connected to the first outlet of the second gas-liquid separator; a first outlet of the second particulate filter, which is connected to the compressor feeding membrane block; the second outlet of the second particulate filter , used to connect the external sewage pool.

其中,经由一级脱硫塔和二级脱硫塔排出的脱硫后的分离气经由冷干机入口进入冷干机中进行脱水处理,脱水后的分离气经由冷干机第一出口、第二气液分离器入口进入第二气液分离器中进行气液分离,分离出的气体经由第二气液分离器第一出口、第二颗粒过滤器入口进入第二颗粒过滤器中,以进一步脱除气体中的固体杂质颗粒,被脱除的固体杂质颗粒排出到排污池中,经由第二颗粒过滤器过滤后的气体经由第二颗粒过滤器第一出口流入到压缩机进膜橇块中进行进一步操作。Wherein, the desulfurized separated gas discharged from the primary desulfurization tower and the secondary desulfurization tower enters the cold dryer through the inlet of the cold dryer for dehydration treatment, and the dehydrated separated gas passes through the first outlet of the cold dryer and the second gas-liquid The inlet of the separator enters the second gas-liquid separator for gas-liquid separation, and the separated gas enters the second particle filter through the first outlet of the second gas-liquid separator and the inlet of the second particle filter to further remove the gas The solid impurity particles in the filter are discharged into the sewage tank, and the gas filtered by the second particle filter flows into the compressor membrane feeder block through the first outlet of the second particle filter for further operation. .

在一实施例中,压缩机进膜橇块包括第一压缩机。第一压缩机包括:第一压缩机入口,连通第二颗粒过滤器第一出口;第一压缩机第一出口;第一压缩机第二出口,用于连外部通排污池。其中,经由第二颗粒过滤器第一出口排出的气体经由第一压缩机入口进入到第一压缩机中,气体被第一压缩机压缩增压,然后经由第一压缩机第一出口进入到膜分离橇块中进行进一步操作。In one embodiment, the compressor feed skid includes a first compressor. The first compressor includes: the first compressor inlet, which is connected to the first outlet of the second particle filter; the first outlet of the first compressor; and the second outlet of the first compressor, which is used for connecting to the external sewage tank. Wherein, the gas discharged through the first outlet of the second particulate filter enters the first compressor through the first compressor inlet, the gas is compressed and pressurized by the first compressor, and then enters the membrane through the first outlet of the first compressor Separate sleds for further operations.

在一实施例中,膜分离橇块包括过滤器组件、电加热器、一级膜管、二级膜管。In one embodiment, the membrane separation skid includes a filter assembly, an electric heater, a primary membrane tube, and a secondary membrane tube.

过滤器组件包括第三颗粒过滤器和第四颗粒过滤器,第三颗粒过滤器和第四颗粒过滤器依次设置在第一压缩机第一出口的下游。第三颗粒过滤器包括:第三颗粒过滤器入口,连通第一压缩机第一出口;第三颗粒过滤器第一出口;第三颗粒过滤器第二出口,用于连通外部排污池。第四颗粒过滤器包括:第四颗粒过滤器入口,连通第三颗粒过滤器第一出口;第四颗粒过滤器第一出口;第四颗粒过滤器第二出口,用于连通外部排污池。The filter assembly includes a third particulate filter and a fourth particulate filter disposed in sequence downstream of the first outlet of the first compressor. The third particle filter includes: an inlet of the third particle filter, which is connected to the first outlet of the first compressor; a first outlet of the third particle filter; and a second outlet of the third particle filter, which is used to communicate with the external sewage tank. The fourth particle filter includes: a fourth particle filter inlet, which is connected to the first outlet of the third particle filter; a first outlet of the fourth particle filter; and a second outlet of the fourth particle filter, which is used to communicate with the external sewage tank.

电加热器包括:电加热器入口,连通第四颗粒过滤器出口;电加热器出口。The electric heater includes: an inlet of the electric heater, which is communicated with an outlet of the fourth particle filter; and an outlet of the electric heater.

一级膜管包括:一级膜管入口,连通电加热器出口;一级膜管低压出口,连通第一压缩机入口;一级膜管高压出口。The primary membrane tube comprises: the inlet of the primary membrane tube, which is connected to the outlet of the electric heater; the low pressure outlet of the primary membrane tube, which is communicated with the inlet of the first compressor; and the high pressure outlet of the primary membrane tube.

二级膜管包括:二级膜管入口,连通一级膜管高压出口;二级膜管低压出口,连通二氧化碳增压回注橇块;二级膜管高压出口,用于连通外部天然气管道。The secondary membrane tube includes: the inlet of the secondary membrane tube, which is connected to the high-pressure outlet of the primary membrane tube; the low-pressure outlet of the secondary membrane tube, which is connected to the carbon dioxide pressurized reinjection skid block; and the high-pressure outlet of the secondary membrane tube, which is used to communicate with the external natural gas pipeline.

其中,经由第一压缩机第一出口排出的增压气体依次进入到第三颗粒过滤器和第四颗粒过滤器中进行过滤,过滤后的气体经由电加热器入口进入到电加热器中进行气化处理,然后经由电加热器出口排出,排出的气体首先进行一级膜管进行初次分离处理,然后进入到二级膜管进行二次分离并将气体中的二氧化碳与烃类气体分离开,分离出的二氧化碳经由二级膜管低压出口进入到二氧化碳增压回注橇块;分离出的烃类气体直接进入外部天然气管道。Among them, the pressurized gas discharged through the first outlet of the first compressor enters the third particle filter and the fourth particle filter in turn for filtration, and the filtered gas enters the electric heater through the inlet of the electric heater for gasification. Chemical treatment, and then discharged through the outlet of the electric heater. The discharged gas first undergoes primary separation treatment in the primary membrane tube, and then enters the secondary membrane tube for secondary separation and separates carbon dioxide and hydrocarbon gases in the gas. The outgoing carbon dioxide enters the carbon dioxide pressurization and reinjection skid through the low-pressure outlet of the secondary membrane tube; the separated hydrocarbon gas directly enters the external natural gas pipeline.

在一实施例中,膜分离橇块还包括第二气体分析仪,其中,一级膜管低压出口、一级膜管高压出口、二级膜管低压出口、二级膜管高压出口分别连通于第二气体分析仪。In one embodiment, the membrane separation skid block further includes a second gas analyzer, wherein the primary membrane tube low pressure outlet, the primary membrane tube high pressure outlet, the secondary membrane tube low pressure outlet, and the secondary membrane tube high pressure outlet are respectively connected to Second gas analyzer.

在一实施例中,压缩机进膜橇块设置为两个;对应地,膜分离橇块设置为两个,各膜分离橇块与两个压缩机进膜橇块分别连通,且各膜分离橇块与二氧化碳增压回注橇块连通。In one embodiment, the number of compressor membrane feeding skids is set to two; correspondingly, the number of membrane separation skids is set to two, each membrane separation skid is connected to the two compressor membrane feeding skids respectively, and each membrane is separated. The skid is in communication with the carbon dioxide pressurized reinjection skid.

在一实施例中,二氧化碳增压回注橇块包括第二压缩机,第二压缩机包括:第二压缩机入口;第二压缩机第一出口,用于将二氧化碳排出;第二压缩机第二出口,用于连通外部排污池。其中,经由各膜分离橇块的二级膜管的二级膜管低压出口分离出来的气体从第二压缩机入口进入到第二压缩机进行压缩,压缩后二氧化碳经由第二压缩机第一出口排出,以进行下一步处理。In one embodiment, the carbon dioxide booster re-injection block includes a second compressor, and the second compressor includes: a second compressor inlet; a first outlet of the second compressor for discharging carbon dioxide; The second outlet is used to connect the external sewage pool. Wherein, the gas separated from the low-pressure outlet of the secondary membrane tube of the secondary membrane tube of each membrane separation block enters the second compressor for compression from the inlet of the second compressor, and the compressed carbon dioxide passes through the first outlet of the second compressor. Drain for further processing.

本发明的有益效果如下:The beneficial effects of the present invention are as follows:

在根据本发明的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统中,二氧化碳驱返排气通过返排气预处理及脱硫橇块、冷干橇块、压缩机进膜橇块、膜分离橇块、二氧化碳增压回注橇块处理,形成了对返排气进行预处理、脱硫、冷干脱水、增压、膜法脱碳步骤,有效地将返排气中的二氧化碳和烃类气体(天然气)进行分离和提取,使得返排气中的二氧化碳得到了回收和有效利用,避免了直接排放大气中而污染环境,提取的天然气用于燃料燃烧,防止了能源的浪费;此外,本发明的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统橇装化、模块化设计使得系统简单、安装操作方便,便于对气量小的返排气进行处理,降低了对返排气的处理成本。In the skid-mounted carbon dioxide drive back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to the present invention, the carbon dioxide drive back exhaust gas passes through the return exhaust gas pretreatment and desulfurization The separation skid and carbon dioxide pressurization and reinjection skid treatment form the steps of pretreatment, desulfurization, cold-drying dehydration, pressurization, and membrane decarburization for the return gas, which effectively removes carbon dioxide and hydrocarbons in the return gas. The gas (natural gas) is separated and extracted, so that the carbon dioxide in the return gas can be recovered and effectively used, avoiding direct emission into the atmosphere and polluting the environment, and the extracted natural gas is used for fuel combustion to prevent the waste of energy; in addition, this The skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system of the invention has a skid-mounted and modular design, which makes the system simple, easy to install and operate, facilitates the treatment of the return exhaust gas with a small amount of gas, and reduces the treatment of the return exhaust gas. cost.

附图说明Description of drawings

图1是根据本发明的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统。FIG. 1 is a skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to the present invention.

其中,附图标记说明如下:Among them, the reference numerals are described as follows:

A返排气预处理及脱硫橇块 20A第一压缩机入口A return exhaust gas pretreatment and desulfurization skid block 20A first compressor inlet

11第一气液分离器 20B1第一压缩机第一出口11 The first gas-liquid separator 20B1 The first outlet of the first compressor

11A第一气液分离器入口 20B2第一压缩机第二出口11A first gas-liquid separator inlet 20B2 first compressor second outlet

11B1第一气液分离器第一出口 D膜分离橇块11B1 The first outlet of the first gas-liquid separator D membrane separation skid

21过滤器组件 21 Filter components

11B2第一气液分离器第二出口 211第三颗粒过滤器11B2 The second outlet of the first gas-liquid separator 211 The third particle filter

211A第三颗粒过滤器入口 211A Third Particulate Filter Inlet

12第一颗粒过滤器12 First particle filter

12A第一颗粒过滤器入口 211B1第三颗粒过滤器第一出口12A First particle filter inlet 211B1 Third particle filter first outlet

12B1第一颗粒过滤器第一出口12B1 1st particle filter 1st outlet

211B2第三颗粒过滤器第二出口 211B2 third particle filter second outlet

12B2第一颗粒过滤器第二出口12B2 First particle filter second outlet

212第四颗粒过滤器 212 Fourth Particulate Filter

13一级脱硫塔 212A第四颗粒过滤器入口13 First stage desulfurization tower 212A fourth particle filter inlet

13A一级脱硫塔入口13A primary desulfurization tower inlet

13B1一级脱硫塔第一出口 212B1第四颗粒过滤器第一出口13B1 The first outlet of the first stage desulfurization tower 212B1 The first outlet of the fourth particle filter

13B2一级脱硫塔第二出口The second outlet of 13B2 first-stage desulfurization tower

14二级脱硫塔 212B2第四颗粒过滤器第二出口14 Secondary desulfurization tower 212B2 The second outlet of the fourth particle filter

14A二级脱硫塔入口14A secondary desulfurization tower inlet

14B1二级脱硫塔第一出口 22电加热器14B1 The first outlet of the secondary desulfurization tower 22 Electric heater

14B2二级脱硫塔第二出口 22A电加热器入口14B2 secondary desulfurization tower second outlet 22A electric heater inlet

15流量计 22B电加热器出口15 flow meter 22B electric heater outlet

B冷干橇块 23一级膜管B cold drying skid block 23 primary film tube

16冷干机 23A一级膜管入口16 Refrigeration dryer 23A first-stage membrane tube inlet

16A冷干机入口 23B1一级膜管低压出口16A cold dryer inlet 23B1 first-stage membrane tube low pressure outlet

16B1冷干机第一出口 23B2一级膜管高压出口16B1 The first outlet of the refrigerated dryer 23B2 The high pressure outlet of the first-stage membrane tube

16B2冷干机第二出口 24二级膜管16B2 Second outlet of refrigerated dryer 24 Secondary membrane tube

17第二气液分离器 24A二级膜管入口17 Second gas-liquid separator 24A secondary membrane tube inlet

17A第二气液分离器入口 24B1二级膜管低压出口17A second gas-liquid separator inlet 24B1 second stage membrane tube low pressure outlet

17B1第二气液分离器第一出口 24B2二级膜管高压出口17B1 The first outlet of the second gas-liquid separator 24B2 The high pressure outlet of the secondary membrane tube

25第二气体分析仪 25 Second Gas Analyzer

17B2第二气液分离器第二出口 E二氧化碳增压回注橇块17B2 The second outlet of the second gas-liquid separator E carbon dioxide pressurized reinjection skid

26第二压缩机 26 Second compressor

18第二颗粒过滤器 26A第二压缩机入口18 Second Particulate Filter 26A Second Compressor Inlet

18A第二颗粒过滤器入口 26B1第二压缩机第一出口18A Second Particulate Filter Inlet 26B1 Second Compressor First Outlet

18B1第二颗粒过滤器第一出口 26B2第二压缩机第二出口18B1 The first outlet of the second particle filter 26B2 The second outlet of the second compressor

27活性炭塔 27 Activated carbon tower

18B2第二颗粒过滤器第二出口 27A活性炭塔入口18B2 second particle filter second outlet 27A activated carbon tower inlet

27B1活性炭塔第一出口 27B1 activated carbon tower first outlet

19第一气体分析仪 27B2活性塔塔第二出口19 The first gas analyzer 27B2 The second outlet of the active tower

C压缩机进膜橇块 28切断阀C compressor film feed block 28 shut-off valve

20第一压缩机20 First compressor

具体实施方式Detailed ways

参照图1,根据本发明的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统包括返排气预处理及脱硫橇块A、冷干橇块B、压缩机进膜橇块C、膜分离橇块D、二氧化碳增压回注橇块E。冷干橇块B与返排气预处理及脱硫橇块A通过管路连通;压缩机进膜橇块C与冷干橇块B通过管路连通;膜分离橇块D与压缩机进膜橇块C通过管路连通;二氧化碳增压回注橇块E与膜分离橇块D通过管路连通;其中,返排气首先进入返排气预处理及脱硫橇块A进行预处理以及脱硫,进行预处理以及脱硫后的返排气进入冷干橇块B,以在冷干橇块B中进行脱水处理,脱水处理后的返排气进入压缩机进膜橇块C,以被增压处理,增压后的返排气进入膜分离橇块D中进行气体分离,以将二氧化碳、烃类气体分离,分离的二氧化碳进入二氧化碳增压回注橇块E进行增压回注处理,烃类气体作为天然气使用。在一实施例中,返排气来自二氧化碳驱采油井井口三相分离器(未示出)的顶部出口。Referring to Fig. 1, the skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to the present invention includes a return gas pretreatment and desulfurization skid block A, a cold-drying skid block B, a compressor film feeding skid block C, and a membrane separation block. Skid block D, carbon dioxide pressurized reinjection skid block E. The cold-drying skid block B is connected with the return gas pretreatment and desulfurization block A through pipelines; the compressor membrane inlet skid block C is connected with the cold-drying skid block B through pipelines; the membrane separation skid block D is connected with the compressor membrane entry skid Block C is connected through pipelines; carbon dioxide pressurized reinjection skid block E and membrane separation skid block D are connected through pipelines; wherein, the return exhaust gas first enters the return exhaust gas pretreatment and desulfurization skid block A for pretreatment and desulfurization, and then The return exhaust gas after pretreatment and desulfurization enters the cold-drying block B for dehydration treatment in the cold-drying block B, and the return exhaust gas after the dehydration treatment enters the compressor feeding block C to be pressurized. The pressurized return exhaust gas enters the membrane separation skid D for gas separation to separate carbon dioxide and hydrocarbon gases, and the separated carbon dioxide enters the carbon dioxide pressurized reinjection skid E for pressurization and reinjection treatment, and the hydrocarbon gas is used as the natural gas use. In one embodiment, the blowback gas comes from the top outlet of a three-phase separator (not shown) at the wellhead of a carbon dioxide flooding well.

需要说明的是,橇块即为橇装化设备,就是将设备(下文所述的气液分离器、颗粒分离器、压缩机、脱硫塔等)、管道、阀门、仪表等集中组装于一个钢结构底座上,成为一个整体设备,能够单独、完全、准确地实现某种功能。橇块的制造、组装都可以在工厂内进行,预制完毕后运输至现场安装。It should be noted that the skid block is the skid-mounted equipment, which is to assemble equipment (gas-liquid separator, particle separator, compressor, desulfurization tower, etc.), pipelines, valves, instruments, etc. On the structural base, it becomes a whole device, which can realize a certain function independently, completely and accurately. The manufacture and assembly of the skid blocks can be carried out in the factory, and after prefabrication, they are transported to the site for installation.

在根据本发明的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统中,二氧化碳驱返排气通过返排气预处理及脱硫橇块A、冷干橇块B、压缩机进膜橇块C、膜分离橇块D、二氧化碳增压回注橇块E处理,形成了对返排气进行预处理、脱硫、冷干脱水、增压、膜法脱碳步骤,有效地将返排气中的二氧化碳和烃类气体(天然气)进行分离和提取,使得返排气中的二氧化碳得到了回收和有效利用,避免了直接排放大气中而污染环境,提取的天然气用于燃料燃烧,防止了能源的浪费;此外,相对于传统的现场安装设备需要经过设备采购、现场安装和调试等环节,本发明的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统橇装化、模块化设计使得系统简单、安装操作方便,只需要在橇块之间进行安装调试,降低了现场施工费用,大大减少了返排气处理过程所涉及的工程现场施工作业工程量,且橇块化的设计在系统出现问题时,仅需针对对应的橇块进行维修调试便可,无需对整个系统进行检测维修,提高了系统运动的稳定性、可靠性,便于系统的维护管理,降低了设备的运行成本;再者,当返排气来自于单井CO2驱油工程时,返排气的气量小,若采用传统的胺法脱硫及脱碳投资大、运行成本高,且不经济,本发明的橇块式的系统便于对气量小的返排气进行处理,由此降低了返排气的处理成本。In the skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to the present invention, the carbon dioxide drive-back exhaust gas passes through the return exhaust gas pretreatment and desulfurization skid block A, the cold drying block B, and the compressor feeding into the film block. C. Membrane separation skid D, carbon dioxide pressurized reinjection skid E treatment, forming the steps of pretreatment, desulfurization, cold-drying dehydration, pressurization, and membrane decarburization for the return exhaust gas, which effectively displaces the return exhaust gas. The carbon dioxide and hydrocarbon gas (natural gas) are separated and extracted, so that the carbon dioxide in the return gas can be recovered and effectively used, avoiding direct emission into the atmosphere and polluting the environment, and the extracted natural gas is used for fuel combustion, preventing energy consumption. waste; in addition, compared with the traditional on-site installation equipment that needs to go through equipment procurement, on-site installation and debugging, the skid-mounted carbon dioxide repulsion exhaust gas desulfurization dehydration and carbon dioxide recovery system of the present invention is skid-mounted and modularized design makes the system simple , Easy installation and operation, only need to install and debug between the skid blocks, which reduces the construction cost on site, greatly reduces the amount of construction work involved in the process of returning and exhausting, and the design of the skid blocks has problems in the system. When it is installed, it is only necessary to carry out maintenance and debugging for the corresponding skid block, without the need for inspection and maintenance of the entire system, which improves the stability and reliability of the system movement, facilitates the maintenance and management of the system, and reduces the operating cost of the equipment; moreover, When the blowback gas comes from a single-well CO 2 flooding project, the gas volume of the blowback gas is small. If the traditional amine method is used for desulfurization and decarbonization, the investment is large, the operation cost is high, and it is not economical. The system facilitates the treatment of the return exhaust gas with a small amount of air, thereby reducing the treatment cost of the return exhaust gas.

需要说明的是,来自于二氧化碳驱采油井井口三相分离器顶部出口的返排气主要以甲烷等烃类为主,常含有硫化氢等酸性物质,硫化物有腐蚀作用,在后续的返排气输送过程中容易造成管道的腐蚀和堵塞,此外,返排气中若混有硫化物,在对返排气采用膜法分离二氧化碳时,硫化物的存在将导致膜管无法分离出二氧化碳,再者,硫化氢有毒有害,国家规定的天然气标准中硫化氢含量应小于一定值(20mg/Nm3),因此由于以上原因,返排气需要脱硫处理;此外,返排气中还含有油田化学药剂、颗粒物质等许多液体和固体杂质,这些液体或固体杂质对后续的采用膜法脱碳时对膜(一级膜管和二级膜管)的性能将产生严重的不利影响,因此,在采用膜法脱碳前需要先对返排气进行预处理、脱水和脱除固体杂质等操作。It should be noted that the blowback gas from the top outlet of the three-phase separator at the wellhead of the carbon dioxide flooding well is mainly composed of hydrocarbons such as methane, and often contains acidic substances such as hydrogen sulfide. In the process of gas transportation, it is easy to cause corrosion and blockage of the pipeline. In addition, if there is sulfide mixed in the return exhaust gas, when the membrane method is used to separate carbon dioxide from the return exhaust gas, the existence of sulfide will cause the membrane tube to be unable to separate carbon dioxide. However, hydrogen sulfide is toxic and harmful, and the content of hydrogen sulfide in the natural gas standard stipulated by the state should be less than a certain value (20mg/Nm3). Therefore, due to the above reasons, the return gas needs desulfurization treatment; in addition, the return gas also contains oilfield chemicals, Many liquid and solid impurities such as particulate matter, these liquid or solid impurities will have a serious adverse effect on the performance of the membrane (first-stage membrane tube and second-stage membrane tube) during subsequent decarburization by membrane method. Before the decarburization method, the return gas needs to be pretreated, dehydrated, and solid impurities removed.

返排气预处理及脱硫橇块A包括第一气液分离器11、第一颗粒过滤器12、活性炭塔27、至少一级脱硫塔。The return gas pretreatment and desulfurization skid block A includes a first gas-liquid separator 11, a first particle filter 12, an activated carbon tower 27, and at least one-stage desulfurization tower.

第一气液分离器11包括:第一气液分离器入口11A;第一气液分离器第一出口11B1;第一气液分离器第二出口11B2,用于连通外部排污池。The first gas-liquid separator 11 includes: an inlet 11A of the first gas-liquid separator; a first outlet 11B1 of the first gas-liquid separator; and a second outlet 11B2 of the first gas-liquid separator for communicating with an external sewage tank.

第一颗粒过滤器12包括第一颗粒过滤器入口12A,连通第一气液分离器第一出口11B1;第一颗粒过滤器第一出口12B1;第一颗粒过滤器第二出口12B2,用于连通外部排污池。The first particle filter 12 includes a first particle filter inlet 12A, which communicates with a first outlet 11B1 of the first gas-liquid separator; a first outlet 12B1 of the first particle filter; and a second outlet 12B2 of the first particle filter, which communicates with External sewage pool.

活性炭塔27包括:活性炭塔入口27A,连通第一颗粒过滤器第一出口12B1;活性炭塔第一出口27B1;活性塔塔第二出口27B2,用于连通外部排污池。The activated carbon tower 27 includes: an activated carbon tower inlet 27A, which is connected to the first outlet 12B1 of the first particle filter; a first activated carbon tower outlet 27B1;

一级脱硫塔13包括:一级脱硫塔入口13A,连通活性炭塔第一出口27B1;一级脱硫塔第一出口13B1,连通冷干橇块B;一级脱硫塔第二出口13B2,用于连通外部排污池。The first-stage desulfurization tower 13 includes: the first-stage desulfurization tower inlet 13A, which is connected to the first outlet 27B1 of the activated carbon tower; the first-stage desulfurization tower's first outlet 13B1 is connected to the cold drying block B; External sewage pool.

其中,返排气经由第一气液分离器入口11A进入第一气液分离器11中进行气液分离并形成分离气和液体(污水和油),液体经由第一气液分离器第二出口11B2流入排污池中;分离气经由第一气液分离器第一出口11B1、第一颗粒过滤器入口12A进入第一颗粒过滤器12中进行过滤,以将分离气中混合的固体杂质颗粒进行初次过滤,过滤出的固体杂质颗粒经由第一颗粒过滤器第二出口12B2排入到排污池中,而过滤后的分离气经由第一颗粒过滤器第一出口12B1、活性炭塔入口27A进入活性炭塔27中进行脱重烃,脱除的重烃经由活性炭塔第二出口27B2排入到排污池中,脱除重烃的分离气至少部分经由活性炭塔第一出口27B1、一级脱硫塔入口13A进入一级脱硫塔13中进行脱硫,脱除的含硫污水经由一级脱硫塔第二出口13B2流入到排污池中,脱硫后的分离气经由脱硫塔第一出口13B1流入到冷干橇块B中,以进行下一步操作。The return gas enters the first gas-liquid separator 11 through the first gas-liquid separator inlet 11A for gas-liquid separation and forms separated gas and liquid (sewage and oil), and the liquid passes through the second outlet of the first gas-liquid separator 11B2 flows into the sewage tank; the separated gas enters the first particle filter 12 through the first outlet 11B1 of the first gas-liquid separator and the first particle filter inlet 12A for filtration, so as to filter the solid impurity particles mixed in the separated gas for the first time. Filtration, the filtered solid impurity particles are discharged into the sewage tank through the second outlet 12B2 of the first particle filter, and the filtered separated gas enters the activated carbon tower 27 through the first outlet 12B1 of the first particle filter and the activated carbon tower inlet 27A. The heavy hydrocarbons removed are discharged into the sewage tank through the second outlet 27B2 of the activated carbon tower, and the separated gas from the heavy hydrocarbons is at least partially removed through the first outlet 27B1 of the activated carbon tower and the inlet 13A of the primary desulfurization tower. Desulfurization is carried out in the first stage desulfurization tower 13, the removed sulfur-containing sewage flows into the sewage tank through the second outlet 13B2 of the first stage desulfurization tower, and the separated gas after desulfurization flows into the cold drying skid block B through the first outlet 13B1 of the desulfurization tower, to proceed to the next step.

第一气液分离器11的设置有效地将返排气中的化学药剂、至少部分重烃类等液体进行初步分离,而第一颗粒过滤器12有效地将返排气中混入的固体杂质颗粒进行首次过滤;一级脱硫塔13能够将返排气中的硫化氢等硫化物进行脱除。第一气液分离器11、第一颗粒过滤器12、活性炭塔27以及一级脱硫塔13实现了对返排气进行预处理,便于返排气后续采用膜分离法脱除二氧化碳。The setting of the first gas-liquid separator 11 effectively performs preliminary separation of chemicals, at least part of heavy hydrocarbons and other liquids in the return gas, while the first particulate filter 12 effectively removes the solid impurity particles mixed in the return gas. The first filtration is carried out; the first-stage desulfurization tower 13 can remove sulfides such as hydrogen sulfide in the return gas. The first gas-liquid separator 11, the first particle filter 12, the activated carbon tower 27 and the first-stage desulfurization tower 13 realize the pretreatment of the return gas, which is convenient for subsequent removal of carbon dioxide by membrane separation.

优选地,在一实施例中,返排气预处理及脱硫橇块A还包括二级脱硫塔14,二级脱硫塔14包括:二级脱硫塔入口14A,连通活性炭塔第一出口27B1、一级脱硫塔第一出口13B1;二级脱硫塔第一出口14B1,连通冷干橇块B;二级脱硫塔第二出口14B2,用于连通外部排污池。Preferably, in one embodiment, the return gas pretreatment and desulfurization skid block A further includes a secondary desulfurization tower 14, and the secondary desulfurization tower 14 includes: an inlet 14A of the secondary desulfurization tower, which is connected to the first outlet 27B1 of the activated carbon tower, a The first outlet 13B1 of the secondary desulfurization tower; the first outlet 14B1 of the secondary desulfurization tower is connected to the cold drying skid block B; the second outlet of the secondary desulfurization tower 14B2 is used to connect to the external sewage pool.

其中,经由活性炭塔第一出口27B1排出的分离气至少部分经由二级脱硫塔入口14A进入二级脱硫塔14中进行脱硫处理,且经由一级脱硫塔第一出口13B1排出的分离气经由二级脱硫塔入口14A再次进入到二级脱硫塔14中进行二次脱硫,脱硫后的分离气经由二级脱硫塔第一出口14B1流入到冷干橇块B中,而二级脱硫塔14脱除的含硫污水经由二级脱硫塔第二出口14B2流入到排污池中。在一实施例中,一级脱硫塔13和二级脱硫塔14内分别装有大硫容羟基氧化铁脱硫剂,二级脱硫塔14的设置能够保证对返排气进行充分脱除硫化物等酸性气体,且二级脱硫塔14的二级脱硫塔入口14A连通活性炭塔第一出口27B1,与一级脱硫塔13为并联关系,提高了脱硫效率;此外,二级脱硫塔14的二级脱硫塔入口14A还连通于一级脱硫塔第一出口13B1,使得经由活性炭塔第一出口27B1排出的分离气依次经过两次脱硫,使得分离气脱硫充分彻底。Wherein, at least part of the separated gas discharged through the first outlet 27B1 of the activated carbon tower enters the secondary desulfurization tower 14 through the secondary desulfurization tower inlet 14A for desulfurization treatment, and the separated gas discharged through the first outlet 13B1 of the primary desulfurization tower passes through the secondary desulfurization tower. The desulfurization tower inlet 14A enters the secondary desulfurization tower 14 again for secondary desulfurization, and the desulphurized separated gas flows into the cold drying skid B through the first outlet 14B1 of the secondary desulfurization tower, while the desulphurized gas removed by the secondary desulfurization tower 14. The sulfur-containing sewage flows into the sewage tank through the second outlet 14B2 of the secondary desulfurization tower. In one embodiment, the primary desulfurization tower 13 and the secondary desulfurization tower 14 are respectively equipped with a large sulfur-capacity ferric oxyhydroxide desulfurizing agent, and the setting of the secondary desulfurization tower 14 can ensure that the return exhaust gas is fully removed sulfide, etc. acid gas, and the secondary desulfurization tower inlet 14A of the secondary desulfurization tower 14 is connected to the first outlet 27B1 of the activated carbon tower, and is in a parallel relationship with the primary desulfurization tower 13, which improves the desulfurization efficiency; in addition, the secondary desulfurization of the secondary desulfurization tower 14 The tower inlet 14A is also connected to the first outlet 13B1 of the primary desulfurization tower, so that the separated gas discharged through the first outlet 27B1 of the activated carbon tower undergoes two successive desulfurizations, so that the desulfurization of the separated gas is sufficiently complete.

返排气预处理及脱硫橇块A还包括切断阀28,设置于第一气液分离器入口11A的上游管路上,用于控制第一气液分离器入口11A的上游管路的打开与闭合。当出现来自三相分离器顶部出口的返排气流量过大等其它紧急情况时,切断阀28能够及时关闭第一气液分离器入口11A的上游管路,保护系统的安全性。The return gas pretreatment and desulfurization skid block A also includes a shut-off valve 28, which is arranged on the upstream pipeline of the first gas-liquid separator inlet 11A, and is used to control the opening and closing of the upstream pipeline of the first gas-liquid separator inlet 11A . When other emergencies such as excessive return exhaust flow from the top outlet of the three-phase separator occur, the shut-off valve 28 can close the upstream pipeline of the first gas-liquid separator inlet 11A in time to protect the safety of the system.

返排气预处理及脱硫橇块A还包括流量计15,设置于第一颗粒过滤器12与活性炭塔27之间的管路上,用于监测经由第一颗粒过滤器第一出口12B1流出的分离气的流量。流量计15用于计量进入一级脱硫塔13和二级脱硫塔14的分离气的流量,防止流量过大而使得分离气脱硫不彻底。The return gas pretreatment and desulfurization skid block A also includes a flow meter 15, which is arranged on the pipeline between the first particulate filter 12 and the activated carbon tower 27, and is used to monitor the separation flowing out through the first outlet 12B1 of the first particulate filter. air flow. The flow meter 15 is used to measure the flow rate of the separated gas entering the primary desulfurization tower 13 and the secondary desulfurization tower 14, so as to prevent the flow rate from being too large and causing incomplete desulfurization of the separated gas.

第一气液分离器11、第一颗粒过滤器12、活性炭塔27、一级脱硫塔13、二级脱硫塔14、流量计15、切断阀28橇装制成返排气预处理及脱硫橇块A,这一橇装化设计仅需将各部分(第一气液分离器11、第一颗粒过滤器12、活性炭27、一级脱硫塔13、二级脱硫塔14、流量计15、切断阀28、管路等)在工厂中完成组装形成一体式设备,然后运输到生产现场进行使用即可,简化了返排气分离二氧化碳与天然气所需的设备的结构复杂程度,降低了安装成本,此外,返排气预处理及脱硫橇块A便于维护管理。The first gas-liquid separator 11, the first particle filter 12, the activated carbon tower 27, the first-stage desulfurization tower 13, the second-stage desulfurization tower 14, the flow meter 15, and the cut-off valve 28 are skid-mounted to make a return gas pretreatment and desulfurization skid Block A, this skid-mounted design only needs to disconnect each part (the first gas-liquid separator 11, the first particle filter 12, the activated carbon 27, the primary desulfurization tower 13, the secondary desulfurization tower 14, the flow meter 15, the cut-off Valves 28, pipelines, etc.) are assembled in the factory to form an integrated device, and then transported to the production site for use, which simplifies the structural complexity of the equipment required for the separation of carbon dioxide and natural gas from the return gas, and reduces the installation cost. In addition, the return gas pretreatment and desulfurization skid block A is convenient for maintenance and management.

冷干橇块B包括冷干机16、第二气液分离器17和第二颗粒过滤器18。The cold-drying skid B includes a cold-drying machine 16 , a second gas-liquid separator 17 and a second particle filter 18 .

冷干机16包括:冷干机入口16A,连通一级脱硫塔第一出口13B1、二级脱硫塔第一出口14B1;冷干机第一出口16B1;冷干机第二出口16B2,用于连通外部排污池。The refrigerating machine 16 includes: an inlet 16A of the refrigerating machine, which is connected to the first outlet 13B1 of the primary desulfurization tower and the first outlet 14B1 of the secondary desulfurizing tower; the first outlet 16B1 of the refrigerating machine; External sewage pool.

第二气液分离器17包括:第二气液分离器入口17A,连通冷干机第一出口16B1;第二气液分离器第一出口17B1;第二气液分离器第二出口17B2,用于连通外部排污池。The second gas-liquid separator 17 includes: the inlet 17A of the second gas-liquid separator, which is connected to the first outlet 16B1 of the refrigerating machine; the first outlet 17B1 of the second gas-liquid separator; and the second outlet 17B2 of the second gas-liquid separator, which is connected with It is connected to the external sewage pool.

第二颗粒过滤器18包括:第二颗粒过滤器入口18A,连通第二气液分离器第一出口17B1;第二颗粒过滤器第一出口18B1,连通压缩机进膜橇块C;第二颗粒过滤器第二出口18B2,用于连通外部排污池。The second particle filter 18 includes: the second particle filter inlet 18A, which is connected to the first outlet 17B1 of the second gas-liquid separator; the first outlet 18B1 of the second particle filter, which is connected to the compressor inlet block C; the second particle filter The second outlet 18B2 of the filter is used to communicate with the external sewage pool.

其中,经由一级脱硫塔13和二级脱硫塔14排出的脱硫后的分离气经由冷干机入口16A进入冷干机16中进行冷干脱水处理,脱水后的分离气(脱水后的分离气仍会携带部分小液滴)经由冷干机第一出口16B1、第二气液分离器入口17A进入第二气液分离器17中进行气液分离,分离出的气体经由第二气液分离器第一出口17B1、第二颗粒过滤器入口18A进入第二颗粒过滤器18中,以进一步脱除气体中的固体杂质颗粒,被脱除的固体杂质颗粒排出到排污池中,经由第二颗粒过滤器18过滤后的气体经由第二颗粒过滤器第一出口18B1流入到压缩机进膜橇块C中进行进一步操作。Wherein, the desulfurized separated gas discharged through the primary desulfurization tower 13 and the secondary desulfurization tower 14 enters the refrigerated dryer 16 through the inlet 16A of the refrigerated dryer for refrigerating and dehydration treatment, and the dehydrated separated gas (the dehydrated separated gas still carry some small droplets) into the second gas-liquid separator 17 through the first outlet 16B1 of the freeze dryer and the second gas-liquid separator inlet 17A for gas-liquid separation, and the separated gas passes through the second gas-liquid separator The first outlet 17B1 and the second particle filter inlet 18A enter the second particle filter 18 to further remove solid impurity particles in the gas, and the removed solid impurity particles are discharged into the sewage tank, and pass through the second particle filter. The gas filtered by the filter 18 flows into the compressor feed block C through the first outlet 18B1 of the second particle filter for further operation.

需要说明的是,返排气中的水含量会严重增加下文所述的一级膜管23和二级膜管24中的膜的负荷,严重影响膜的选择性及渗透性,而冷干机16用于对脱硫后的分离气进行进一步脱水,分离气在冷干机16的作用下,分离气中携带的水蒸气会凝结并转化为小液滴,小液滴进入外部排污池中,冷干机16的设置进一步脱除了分离气中所含有的水,提高了下文所述的膜管的分离效率,同时降低了分离气的露点,可以保证分离气在进入膜分离橇块D时不产生冷凝液体;此外,第二颗粒过滤器18的设置能够起到对进入膜分离橇块D的气体进行脱除固体颗粒杂质的作用,预防进入膜管的气体携带固体颗粒而影响膜管的分离性能。It should be noted that the water content in the return gas will seriously increase the load of the membranes in the primary membrane tube 23 and the secondary membrane tube 24 described below, which will seriously affect the selectivity and permeability of the membrane. 16 is used to further dehydrate the desulfurized separated gas. Under the action of the cooling dryer 16, the water vapor carried in the separated gas will be condensed and converted into small droplets, and the small droplets will enter the external sewage tank and cool down. The setting of the dryer 16 further removes the water contained in the separation gas, improves the separation efficiency of the membrane tube described below, and at the same time reduces the dew point of the separation gas, which can ensure that the separation gas does not generate when entering the membrane separation skid D. condensate liquid; in addition, the setting of the second particle filter 18 can play a role in removing solid particle impurities from the gas entering the membrane separation skid D, preventing the gas entering the membrane tube from carrying solid particles and affecting the separation performance of the membrane tube .

冷干橇块B还包括第一气体分析仪19,设置于二级脱硫塔第二出口14B2与冷干机16之间,用于检测从二级脱硫塔第一出口14B1、一级脱硫塔第一出口13B1排出的气体中硫化物的含量。第一气体分析仪19能够有效地监测经由一级脱硫塔第一出口13B1和二级脱硫塔第一出口14B1出口排出的分离气所含硫化氢的含量,从而保证硫化氢等硫化物降至所需要求。The cold-drying skid block B also includes a first gas analyzer 19, which is arranged between the second outlet 14B2 of the secondary desulfurization tower and the refrigerating machine 16, and is used to detect the gas from the first outlet 14B1 of the secondary desulfurization tower and the second outlet of the primary desulfurization tower 14B2. The content of sulfide in the gas discharged from an outlet 13B1. The first gas analyzer 19 can effectively monitor the content of hydrogen sulfide contained in the separated gas discharged through the first outlet 13B1 of the primary desulfurization tower and the first outlet 14B1 of the secondary desulfurization tower, thereby ensuring that sulfides such as hydrogen sulfide are reduced to all levels. need to ask.

冷干机16、第二气液分离器17、第二颗粒过滤器18、第一气体分析仪19橇装制成冷干橇块B,这一橇装化设计仅需将各部分(冷干机16、第二气液分离器17、第二颗粒过滤器18、第一气体分析仪19、管路等)在工厂中完成组装形成一体式设备,然后运输到生产现场进行使用即可,简化了返排气分离二氧化碳与天然气所需的设备的结构复杂程度,降低了安装成本,此外,冷干橇块B便于维护管理,降低了后期维护管理的成本。The refrigerated dryer 16, the second gas-liquid separator 17, the second particle filter 18, and the first gas analyzer 19 are skid-mounted to form the refrigerated drying skid block B. This skid-mounted design only needs to 16, the second gas-liquid separator 17, the second particle filter 18, the first gas analyzer 19, pipelines, etc.) are assembled in the factory to form an integrated device, and then transported to the production site for use, simplifying The structure complexity of the equipment required to separate carbon dioxide and natural gas from the return gas is reduced, and the installation cost is reduced. In addition, the cold-drying skid B is convenient for maintenance and management, which reduces the cost of later maintenance and management.

压缩机进膜橇块C包括第一压缩机20。The compressor feed block C includes a first compressor 20 .

第一压缩机20包括:第一压缩机入口20A,连通第二颗粒过滤器第一出口18B1;第一压缩机第一出口20B1;第一压缩机第二出口20B2,用于连外部通排污池。The first compressor 20 includes: a first compressor inlet 20A, which is connected to the first outlet 18B1 of the second particle filter; a first compressor first outlet 20B1; .

其中,经由第二颗粒过滤器第一出口18B1排出的气体经由第一压缩机入口20A进入到第一压缩机20中,气体被第一压缩机20压缩增压,然后经由第一压缩机第一出口20B1进入到膜分离橇块D中进行进一步操作。Wherein, the gas discharged through the first outlet 18B1 of the second particulate filter enters the first compressor 20 through the first compressor inlet 20A, the gas is compressed and pressurized by the first compressor 20, and then passes through the first compressor 20A. Outlet 20B1 enters into membrane separation skid D for further operations.

需要说明的是,进膜(下文所述的一级膜管23和二级膜管24)前的气体需要带有一定的压力,而第一压缩机20的设置能够对经由第二颗粒过滤器第一出口18B1排出的气体进行增压,保证气体在进膜前带有所要求的压力,保证膜分离橇块D分离出符合标准的天然气。同样地,压缩机进膜橇块C的设计简化了返排气分离二氧化碳与天然气所需的设备的结构复杂程度,降低了安装成本,同时降低了后期维护管理的成本。It should be noted that the gas before entering the membrane (the first-stage membrane tube 23 and the second-stage membrane tube 24 described below) needs to have a certain pressure, and the setting of the first compressor 20 can prevent the gas passing through the second particle filter The gas discharged from the first outlet 18B1 is pressurized to ensure that the gas has the required pressure before entering the membrane, so that the membrane separation skid D can separate natural gas that meets the standard. Similarly, the design of the compressor membrane feed block C simplifies the structural complexity of the equipment required for the separation of carbon dioxide and natural gas from the return gas, reduces the installation cost, and at the same time reduces the cost of subsequent maintenance and management.

膜分离橇块D包括过滤器组件21、电加热器22、一级膜管23、二级膜管24。The membrane separation block D includes a filter assembly 21 , an electric heater 22 , a primary membrane tube 23 and a secondary membrane tube 24 .

过滤器组件21包括第三颗粒过滤器211和第四颗粒过滤器212,第三颗粒过滤器211和第四颗粒过滤器212依次设置在第一压缩机第一出口20B1的下游。The filter assembly 21 includes a third particulate filter 211 and a fourth particulate filter 212, which are sequentially disposed downstream of the first outlet 20B1 of the first compressor.

第三颗粒过滤器211包括:第三颗粒过滤器入口211A,连通第一压缩机第一出口20B1;第三颗粒过滤器第一出口211B1;第三颗粒过滤器第二出口211B2,用于连通外部排污池。The third particulate filter 211 includes: a third particulate filter inlet 211A, which communicates with the first compressor first outlet 20B1; a third particulate filter first outlet 211B1; and a third particulate filter second outlet 211B2, which communicates with the outside Sewage pool.

第四颗粒过滤器212包括:第四颗粒过滤器入口212A,连通第三颗粒过滤器第一出口211B1;第四颗粒过滤器第一出口212B1;第四颗粒过滤器第二出口212B2,用于连通外部排污池。如上文所述,气体中若携带固体颗粒杂质,将会对膜分离橇块D的性能产生不利影响,严重影响膜分离效果,而第三颗粒过滤器211和第四颗粒过滤器212二者的双重过滤作用能够有效地对气体中混入的固体颗粒杂质进行脱除,防止进膜前的气体携带固体杂质颗粒,保证下文所述的一级膜管23和二级膜管24的分离效果和效率。The fourth particle filter 212 includes: a fourth particle filter inlet 212A, which communicates with the third particle filter first outlet 211B1; the fourth particle filter first outlet 212B1; and the fourth particle filter second outlet 212B2, which communicates with External sewage pool. As mentioned above, if the gas carries solid particle impurities, it will adversely affect the performance of the membrane separation skid D, which will seriously affect the membrane separation effect. The double filtration effect can effectively remove the solid particle impurities mixed in the gas, prevent the gas before entering the membrane from carrying solid impurity particles, and ensure the separation effect and efficiency of the primary membrane tube 23 and the secondary membrane tube 24 described below. .

电加热器22包括:电加热器入口22A,连通第四颗粒过滤器第一出口212B1;电加热器出口22B。同样地,进膜前的气体若含有水汽等液体,也对会膜管中的膜的分离性能产生影响,而加热器22的设置将进膜前的气体进行加热,以将气体中携带的液滴转换为气态,同时使气体保持足够高的温度,防止气体进入膜管后产生冷凝液体,保证了膜管的分离效果。The electric heater 22 includes: an electric heater inlet 22A, which communicates with the first outlet 212B1 of the fourth particulate filter; and an electric heater outlet 22B. Similarly, if the gas before entering the membrane contains liquid such as water vapor, it will also affect the separation performance of the membrane in the membrane tube, and the setting of the heater 22 will heat the gas before entering the membrane to remove the liquid carried in the gas. The droplet is converted into a gaseous state, and at the same time, the temperature of the gas is kept high enough to prevent the condensation of liquid after the gas enters the membrane tube, which ensures the separation effect of the membrane tube.

一级膜管23包括:一级膜管入口23A,连通电加热器出口22B;一级膜管低压出口23B1,连通第一压缩机入口20A;一级膜管高压出口23B2。The primary membrane tube 23 includes: the primary membrane tube inlet 23A, which communicates with the electric heater outlet 22B; the primary membrane tube low pressure outlet 23B1, which communicates with the first compressor inlet 20A; the primary membrane tube high pressure outlet 23B2.

二级膜管24包括:二级膜管入口24A,连通一级膜管高压出口23B2;二级膜管低压出口24B1,连通二氧化碳增压回注橇块E;二级膜管高压出口24B2,用于连通外部天然气管道。The secondary membrane tube 24 includes: the inlet 24A of the secondary membrane tube, which is connected to the high-pressure outlet 23B2 of the primary membrane tube; the low-pressure outlet of the secondary membrane tube 24B1 is connected to the carbon dioxide pressurized reinjection skid block E; the high-pressure outlet of the secondary membrane tube 24B2 is connected to for connection to external natural gas pipelines.

其中,经由第一压缩机第一出口20B1排出的增压气体依次进入到第三颗粒过滤器211和第四颗粒过滤器212中进行过滤,过滤后的气体经由电加热器入口23A进入到电加热器22中进行汽化处理,然后经由电加热器出口22B排出,排出的气体首先进行一级膜管23进行初次分离处理,然后进入到二级膜管24进行二次分离并将混合气体中的二氧化碳与烃类气体分离开,分离开的二氧化碳经由二级膜管低压出口24B1进入到二氧化碳增压回注橇块E;分离开的烃类气体直接进入外部天然气管道。The pressurized gas discharged through the first outlet 20B1 of the first compressor enters the third particulate filter 211 and the fourth particulate filter 212 for filtration in sequence, and the filtered gas enters the electric heater through the electric heater inlet 23A. Vaporization treatment is carried out in the device 22, and then it is discharged through the electric heater outlet 22B. The discharged gas is first subjected to the primary membrane tube 23 for primary separation treatment, and then enters the secondary membrane tube 24 for secondary separation and the carbon dioxide in the mixed gas. Separated from the hydrocarbon gas, the separated carbon dioxide enters the carbon dioxide pressurization reinjection block E through the low-pressure outlet 24B1 of the secondary membrane tube; the separated hydrocarbon gas directly enters the external natural gas pipeline.

一级膜管23对混合气进行初次分离过滤,一级膜管低压出口23B1排出的二氧化碳混有一部分甲烷等烃类气体,因此,一级膜管低压出口23B1连通第一压缩机入口20A,从而将含有烃类气体的二氧化碳进行重新压缩增压以再次进入膜分离橇块D再次进行过滤,减少了天然气的浪费,同时提高了天然气的提取量;一级膜管高压出口23B2排出的天然气混有一部分二氧化碳,天然气纯度未能达到天然气使用标准,因此,需要进一步分离过滤,因此含有二氧化碳的天然气经由一级膜管高压出口23B2流入到二级膜管24中进行进一步分离,而经由二级膜管24的作用,含有二氧化碳的天然气分离为二氧化碳和使用标准的天然气,二氧化碳经由二级膜管低压出口24B1流入到二氧化碳回注橇块E进行回注,二级膜管高压出口24B2排出的符合使用标准的天然气流入到外部天然气管道中,一级膜管23与二级膜管24的双重过滤作用对天然气进行了充分的过滤和提取,防止了天然气的浪费,同时有效地回收二氧化碳,减少了环境污染。The first-stage membrane tube 23 separates and filters the mixed gas for the first time, and the carbon dioxide discharged from the low-pressure outlet 23B1 of the first-stage membrane tube is mixed with a part of hydrocarbon gases such as methane. Therefore, the low-pressure outlet 23B1 of the first-stage membrane tube is connected to the first compressor inlet 20A, thereby The carbon dioxide containing hydrocarbon gas is recompressed and pressurized to enter the membrane separation block D again for filtration, which reduces the waste of natural gas and improves the extraction of natural gas; the natural gas discharged from the high-pressure outlet 23B2 of the first-stage membrane tube is mixed with A part of carbon dioxide, the purity of natural gas fails to meet the natural gas use standard, therefore, further separation and filtration are required, so the natural gas containing carbon dioxide flows into the secondary membrane tube 24 through the high pressure outlet 23B2 of the primary membrane tube for further separation, and passes through the secondary membrane tube. 24, the natural gas containing carbon dioxide is separated into carbon dioxide and standard natural gas. The carbon dioxide flows into the carbon dioxide reinjection block E through the low-pressure outlet 24B1 of the secondary membrane tube for re-injection. The natural gas flows into the external natural gas pipeline. The double filtration effect of the primary membrane tube 23 and the secondary membrane tube 24 fully filters and extracts the natural gas, preventing the waste of natural gas, and at the same time effectively recovering carbon dioxide and reducing environmental pollution. .

膜分离橇块D还包括第二气体分析仪25,其中,一级膜管低压出口23B1、一级膜管高压出口23B2、二级膜管低压出口24B1、二级膜管高压出口24B2分别连通于第二气体分析仪25。The membrane separation block D also includes a second gas analyzer 25, wherein the primary membrane tube low pressure outlet 23B1, the primary membrane tube high pressure outlet 23B2, the secondary membrane tube low pressure outlet 24B1, and the secondary membrane tube high pressure outlet 24B2 are respectively connected to The second gas analyzer 25 .

同理,过滤器组件21、电加热器22、一级膜管23、二级膜管24、第二气体分析仪25橇装制成膜分离橇块D,这一橇装化设计仅需将各部分(过滤器组件21、电加热器22、一级膜管23、二级膜管24、第二气体分析仪25、管路等)在工厂中完成组装形成一体式设备,然后运输到生产现场与其他橇块连接进行使用即可,简化了返排气分离二氧化碳与天然气所需的设备的结构复杂程度,降低了安装成本,此外,膜分离橇块D出现问题时仅需对这一橇块单独进行维护管理即可,降低了系统的维护管理的成本。Similarly, the filter assembly 21, the electric heater 22, the primary membrane tube 23, the secondary membrane tube 24, and the second gas analyzer 25 are skid-mounted to form the membrane separation skid D. This skid-mounted design only requires the Each part (filter assembly 21, electric heater 22, primary membrane tube 23, secondary membrane tube 24, second gas analyzer 25, piping, etc.) is assembled in the factory to form an integrated device, and then transported to production It can be used by connecting with other skid blocks on site, which simplifies the structural complexity of the equipment required for the separation of carbon dioxide and natural gas by the return gas, and reduces the installation cost. The block can be maintained and managed independently, which reduces the cost of system maintenance and management.

在一实施例中,压缩机进膜橇块C设置为两个;对应地,膜分离橇块D设置为两个,各膜分离橇块D与两个压缩机进膜橇块C分别连通,且各膜分离橇块D与二氧化碳增压回注橇块E连通。这一设计使得经由第二颗粒过滤器第一出口18B1排出的气体进入两个压缩机进膜橇块C中,然后再进入两个膜分离橇块D中进行二氧化碳与天然气的分离,提高了返排气分离二氧化碳与天然气的分离效率。In one embodiment, the number of compressor membrane feeding skid blocks C is set to two; correspondingly, the number of membrane separation skid blocks D is set to two, and each membrane separation skid block D is communicated with two compressor membrane feeding skid blocks C respectively, And each membrane separation skid block D is in communication with the carbon dioxide pressurized reinjection skid block E. This design allows the gas discharged through the first outlet 18B1 of the second particulate filter to enter the two compressors and enter the membrane block C, and then enter the two membrane separation blocks D for the separation of carbon dioxide and natural gas, which improves the return rate. Separation efficiency of carbon dioxide and natural gas from exhaust gas.

二氧化碳增压回注橇块E包括第二压缩机26,第二压缩机26包括:第二压缩机入口26A;第二压缩机第一出口26B1,用于将二氧化碳排出;第二压缩机第二出口26B2,用于连通外部排污池;其中,经由各膜分离橇块D的二级膜管24的二级膜管低压出口24B1分离出来的气体从第二压缩机入口26A进入到第二压缩机26进行压缩,压缩后二氧化碳经由第二压缩机第一出口26B1排出,然后回注到地下,这一过程有效地回收了二氧化碳,使得二氧化碳再次被利用,降低了二氧化碳驱油田采出液所额外消耗二氧化碳的量,降低了成本,同时防止了二氧化碳排放到大气而污染环境。The carbon dioxide booster reinjection block E includes a second compressor 26, the second compressor 26 includes: a second compressor inlet 26A; a second compressor first outlet 26B1 for discharging carbon dioxide; the second compressor second The outlet 26B2 is used to communicate with the external sewage tank; wherein, the gas separated from the secondary membrane tube low-pressure outlet 24B1 of the secondary membrane tube 24 of each membrane separation block D enters the second compressor from the second compressor inlet 26A 26 is compressed, and the compressed carbon dioxide is discharged through the first outlet 26B1 of the second compressor, and then injected back into the ground. This process effectively recovers the carbon dioxide, so that the carbon dioxide can be used again, reducing the extra consumption of the produced fluid in the oilfield by carbon dioxide flooding. The amount of carbon dioxide reduces costs, while preventing carbon dioxide from being emitted into the atmosphere and polluting the environment.

Claims (10)

1.一种橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其特征在于,1. a skid-mounted carbon dioxide drive back exhaust gas desulfurization dehydration and carbon dioxide recovery system, is characterized in that, 包括返排气预处理及脱硫橇块(A)、冷干橇块(B)、压缩机进膜橇块(C)、膜分离橇块(D)、二氧化碳增压回注橇块(E);Including back exhaust gas pretreatment and desulfurization skid block (A), cold drying skid block (B), compressor membrane feeding skid block (C), membrane separation skid block (D), carbon dioxide booster reinjection skid block (E) ; 冷干橇块(B)与返排气预处理及脱硫橇块(A)通过管路连通;The cold-drying skid block (B) is connected with the return exhaust gas pretreatment and desulfurization skid block (A) through a pipeline; 压缩机进膜橇块(C)与冷干橇块(B)通过管路连通;The compressor film feeding block (C) is communicated with the cold drying block (B) through a pipeline; 膜分离橇块(D)与压缩机进膜橇块(C)通过管路连通;The membrane separation block (D) is communicated with the compressor membrane feed block (C) through a pipeline; 二氧化碳增压回注橇块(E)与膜分离橇块(D)通过管路连通;The carbon dioxide pressurized reinjection block (E) is communicated with the membrane separation block (D) through a pipeline; 其中,返排气首先进入返排气预处理及脱硫橇块(A)进行预处理以及脱硫,进行预处理以及脱硫后的返排气进入冷干橇块(B),以在冷干橇块(B)中进行脱水处理,脱水处理后的返排气进入压缩机进膜橇块(C),以被增压处理,增压后的返排气进入膜分离橇块(D)中进行气体分离,以将二氧化碳、烃类气体分离,分离的二氧化碳进入二氧化碳增压回注橇块(E)进行增压回注处理,烃类气体作为天然气使用。Among them, the return exhaust gas first enters the return exhaust gas pretreatment and desulfurization block (A) for pretreatment and desulfurization, and the return exhaust gas after pretreatment and desulfurization enters the cold drying block (B) to be used in the cold drying block (B). The dehydration treatment is carried out in (B), the return gas after the dehydration treatment enters the compressor membrane feed block (C) to be pressurized, and the pressurized return gas enters the membrane separation block (D) for gas Separation to separate carbon dioxide and hydrocarbon gas, the separated carbon dioxide enters the carbon dioxide pressurized reinjection sled (E) for pressurized reinjection treatment, and the hydrocarbon gas is used as natural gas. 2.根据权利要求1所述的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其特征在于,2. the skid-mounted carbon dioxide drive back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to claim 1, is characterized in that, 返排气预处理及脱硫橇块(A)包括第一气液分离器(11)、第一颗粒过滤器(12)、活性炭塔(27)、至少一级脱硫塔;The return gas pretreatment and desulfurization skid block (A) includes a first gas-liquid separator (11), a first particle filter (12), an activated carbon tower (27), and at least one-stage desulfurization tower; 第一气液分离器(11)包括:The first gas-liquid separator (11) includes: 第一气液分离器入口(11A);the first gas-liquid separator inlet (11A); 第一气液分离器第一出口(11B1);the first outlet (11B1) of the first gas-liquid separator; 第一气液分离器第二出口(11B2),用于连通外部排污池;The second outlet (11B2) of the first gas-liquid separator is used to communicate with the external sewage tank; 第一颗粒过滤器(12)包括:The first particulate filter (12) includes: 第一颗粒过滤器入口(12A),连通第一气液分离器第一出口(11B1);The first particle filter inlet (12A) is connected to the first outlet (11B1) of the first gas-liquid separator; 第一颗粒过滤器第一出口(12B1);the first outlet of the first particle filter (12B1); 第一颗粒过滤器第二出口(12B2),用于连通外部排污池;The second outlet (12B2) of the first particle filter is used to communicate with the external sewage tank; 活性炭塔(27)包括:The activated carbon tower (27) includes: 活性炭塔入口(27A),连通第一颗粒过滤器第一出口(12B1);The activated carbon tower inlet (27A) is connected to the first outlet (12B1) of the first particle filter; 活性炭塔第一出口(27B1);The first outlet of activated carbon tower (27B1); 活性塔塔第二出口(27B2),用于连通外部排污池;The second outlet (27B2) of the active tower is used to communicate with the external sewage pool; 一级脱硫塔(13)包括:The primary desulfurization tower (13) includes: 一级脱硫塔入口(13A),连通活性炭塔第一出口(27B1);The inlet (13A) of the primary desulfurization tower is connected to the first outlet (27B1) of the activated carbon tower; 一级脱硫塔第一出口(13B1),连通冷干橇块(B);The first outlet (13B1) of the first-stage desulfurization tower is connected to the cold-drying skid block (B); 一级脱硫塔第二出口(13B2),用于连通外部排污池;The second outlet (13B2) of the primary desulfurization tower is used to communicate with the external sewage pool; 其中,返排气经由第一气液分离器入口(11A)进入第一气液分离器(11)中进行气液分离并形成分离气和液体,液体经由第一气液分离器第二出口(11B2)流入排污池中;分离气经由第一气液分离器第一出口(11B1)、第一颗粒过滤器入口(12A)进入第一颗粒过滤器(12)中进行过滤,以将分离气中混合的固体杂质颗粒进行初次过滤,过滤出的固体杂质颗粒经由第一颗粒过滤器第二出口(12B2)排入到排污池中,而过滤后的分离气经由第一颗粒过滤器第一出口(12B1)、活性炭塔入口(27A)进入活性炭塔(27)中进行脱重烃,脱除的重烃经由活性炭塔第二出口(27B2)排入到排污池中,脱除重烃的分离气至少部分经由活性炭塔第一出口(27B1)、一级脱硫塔入口(13A)进入一级脱硫塔(13)中进行脱硫,脱除的含硫污水经由一级脱硫塔第二出口(13B2)流入到排污池中,脱硫后的分离气经由脱硫塔第一出口(13B1)流入到冷干橇块(B)中,以进行下一步操作。Wherein, the return gas enters the first gas-liquid separator (11) through the first gas-liquid separator inlet (11A) for gas-liquid separation and forms separated gas and liquid, and the liquid passes through the second outlet of the first gas-liquid separator (11A). 11B2) flows into the sewage tank; the separated gas enters the first particle filter (12) through the first outlet (11B1) of the first gas-liquid separator and the first particle filter inlet (12A) for filtration, so that the separated gas is filtered. The mixed solid impurity particles are first filtered, the filtered solid impurity particles are discharged into the sewage tank through the second outlet (12B2) of the first particle filter, and the filtered separated gas is passed through the first outlet of the first particle filter (12B2). 12B1), the activated carbon tower inlet (27A) enters the activated carbon tower (27) to remove heavy hydrocarbons, and the removed heavy hydrocarbons are discharged into the sewage tank through the second outlet of the activated carbon tower (27B2), and the separated gas for removing heavy hydrocarbons is at least Part of it enters the first-stage desulfurization tower (13) through the first outlet (27B1) of the activated carbon tower and the first-stage desulfurization tower inlet (13A) for desulfurization, and the removed sulfur-containing sewage flows into the first-stage desulfurization tower through the second outlet (13B2). In the sewage tank, the separated gas after desulfurization flows into the cold drying skid (B) through the first outlet (13B1) of the desulfurization tower for the next operation. 3.根据权利要求2所述的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其特征在于,3. The skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to claim 2, is characterized in that, 返排气预处理及脱硫橇块(A)还包括二级脱硫塔(14),The return gas pretreatment and desulfurization skid block (A) also includes a secondary desulfurization tower (14), 二级脱硫塔(14)包括:The secondary desulfurization tower (14) includes: 二级脱硫塔入口(14A),连通活性炭塔第一出口(27B1)、一级脱硫塔第一出口(13B1);The inlet (14A) of the secondary desulfurization tower is connected to the first outlet (27B1) of the activated carbon tower and the first outlet (13B1) of the primary desulfurization tower; 二级脱硫塔第一出口(14B1),连通冷干橇块(B);The first outlet (14B1) of the secondary desulfurization tower is connected to the cold drying skid (B); 二级脱硫塔第二出口(14B2),用于连通外部排污池;The second outlet (14B2) of the secondary desulfurization tower is used to communicate with the external sewage pool; 其中,经由活性炭塔第一出口(27B1)排出的分离气至少部分经由二级脱硫塔入口(14A)进入二级脱硫塔(14)中进行脱硫处理,且经由一级脱硫塔第一出口(13B1)排出的分离气经由二级脱硫塔入口(14A)再次进入到二级脱硫塔(14)中进行二次脱硫,脱硫后的分离气经由二级脱硫塔第一出口(14B1)流入到冷干橇块(B)中,而二级脱硫塔(14)脱除的含硫污水经由二级脱硫塔第二出口(14B2)流入到排污池中。Wherein, at least part of the separated gas discharged through the first outlet of the activated carbon tower (27B1) enters the secondary desulfurization tower (14) through the inlet of the secondary desulfurization tower (14A) for desulfurization treatment, and passes through the first outlet of the first desulfurization tower (13B1). ) discharged separated gas is re-entered into the secondary desulfurization tower (14) through the secondary desulfurization tower inlet (14A) for secondary desulfurization, and the desulfurized separated gas flows into the cold drying through the first outlet (14B1) of the secondary desulfurization tower In the skid block (B), the sulfur-containing sewage removed by the secondary desulfurization tower (14) flows into the sewage pool through the second outlet (14B2) of the secondary desulfurization tower. 4.根据权利要求2所述的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其特征在于,4. the skid-mounted carbon dioxide drive back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to claim 2, is characterized in that, 返排气预处理及脱硫橇块(A)还包括:切断阀(28),设置于第一气液分离器入口(11A)的上游管路上,用于控制第一气液分离器入口(11A)的上游管路的打开与闭合。The return gas pretreatment and desulfurization skid block (A) further comprises: a shut-off valve (28), which is arranged on the upstream pipeline of the first gas-liquid separator inlet (11A) and is used to control the first gas-liquid separator inlet (11A). ) opening and closing of the upstream pipeline. 5.根据权利要求3所述的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其特征在于,5. The skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to claim 3 is characterized in that, 冷干橇块(B)包括冷干机(16)、第二气液分离器(17)和第二颗粒过滤器(18),The cold-drying skid block (B) includes a cold-drying machine (16), a second gas-liquid separator (17) and a second particle filter (18), 冷干机(16)包括:The freeze dryer (16) includes: 冷干机入口(16A),连通一级脱硫塔第一出口(13B1)、二级脱硫塔第一出口(14B1);The inlet (16A) of the refrigeration dryer is connected to the first outlet (13B1) of the primary desulfurization tower and the first outlet (14B1) of the secondary desulfurization tower; 冷干机第一出口(16B1);The first outlet of the refrigerating machine (16B1); 冷干机第二出口(16B2),用于连通外部排污池;The second outlet (16B2) of the refrigerating machine is used to communicate with the external sewage pool; 第二气液分离器(17)包括:The second gas-liquid separator (17) includes: 第二气液分离器入口(17A),连通冷干机第一出口(16B1);The inlet (17A) of the second gas-liquid separator is connected to the first outlet (16B1) of the refrigerating machine; 第二气液分离器第一出口(17B1);The first outlet of the second gas-liquid separator (17B1); 第二气液分离器第二出口(17B2),用于连通外部排污池;The second outlet (17B2) of the second gas-liquid separator is used to communicate with the external sewage tank; 第二颗粒过滤器(18)包括:The second particulate filter (18) includes: 第二颗粒过滤器入口(18A),连通第二气液分离器第一出口(17B1);The second particle filter inlet (18A) communicates with the first outlet (17B1) of the second gas-liquid separator; 第二颗粒过滤器第一出口(18B1),连通压缩机进膜橇块(C);The first outlet (18B1) of the second particle filter is communicated with the compressor inlet block (C); 第二颗粒过滤器第二出口(18B2),用于连通外部排污池;The second outlet (18B2) of the second particle filter is used to communicate with the external sewage pool; 其中,经由一级脱硫塔(13)和二级脱硫塔(14)排出的脱硫后的分离气经由冷干机入口(16A)进入冷干机(16)中进行冷干脱水处理,脱水后的分离气经由冷干机第一出口(16B1)、第二气液分离器入口(17A)进入第二气液分离器(17)中进行气液分离,分离出的气体经由第二气液分离器第一出口(17B1)、第二颗粒过滤器入口(18A)进入第二颗粒过滤器(18)中,以进一步脱除气体中的固体杂质颗粒,被脱除的固体杂质颗粒排出到排污池中,经由第二颗粒过滤器(18)过滤后的气体经由第二颗粒过滤器第一出口(18B1)流入到压缩机进膜橇块(C)中进行进一步操作。Wherein, the desulfurized separated gas discharged from the primary desulfurization tower (13) and the secondary desulfurization tower (14) enters the refrigerated dryer (16) through the refrigerated dryer inlet (16A) for refrigerated dehydration treatment, and the dehydrated The separated gas enters the second gas-liquid separator (17) through the first outlet (16B1) of the cold dryer and the second gas-liquid separator inlet (17A) for gas-liquid separation, and the separated gas passes through the second gas-liquid separator The first outlet (17B1) and the second particle filter inlet (18A) enter the second particle filter (18) to further remove solid impurity particles in the gas, and the removed solid impurity particles are discharged into the sewage tank , the gas filtered by the second particle filter (18) flows into the compressor feed block (C) through the first outlet (18B1) of the second particle filter for further operation. 6.根据权利要求5所述的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其特征在于,6. The skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to claim 5 is characterized in that, 压缩机进膜橇块(C)包括第一压缩机(20),The compressor film feed block (C) includes a first compressor (20), 第一压缩机(20)包括:The first compressor (20) includes: 第一压缩机入口(20A),连通第二颗粒过滤器第一出口(18B1);The first compressor inlet (20A) is connected to the first outlet (18B1) of the second particulate filter; 第一压缩机第一出口(20B1);a first compressor first outlet (20B1); 第一压缩机第二出口(20B2),用于连外部通排污池;The second outlet (20B2) of the first compressor is used to communicate with the external sewage pool; 其中,经由第二颗粒过滤器第一出口(18B1)排出的气体经由第一压缩机入口(20A)进入到第一压缩机(20)中,气体被第一压缩机(20)压缩增压,然后经由第一压缩机第一出口(20B1)进入到膜分离橇块(D)中进行进一步操作。Wherein, the gas discharged through the first outlet (18B1) of the second particulate filter enters the first compressor (20) through the first compressor inlet (20A), and the gas is compressed and pressurized by the first compressor (20), It then enters the membrane separation skid (D) via the first compressor first outlet (20B1) for further operation. 7.根据权利要求6所述的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其特征在于,7. The skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to claim 6, characterized in that, 膜分离橇块(D)包括过滤器组件(21)、电加热器(22)、一级膜管(23)、二级膜管(24);The membrane separation block (D) comprises a filter assembly (21), an electric heater (22), a primary membrane tube (23), and a secondary membrane tube (24); 过滤器组件(21)包括第三颗粒过滤器(211)和第四颗粒过滤器(212),第三颗粒过滤器(211)和第四颗粒过滤器(212)依次设置在第一压缩机第一出口(20B1)的下游,The filter assembly (21) includes a third particle filter (211) and a fourth particle filter (212), and the third particle filter (211) and the fourth particle filter (212) are sequentially arranged on the first compressor. Downstream of an outlet (20B1), 第三颗粒过滤器(211)包括:The third particulate filter (211) includes: 第三颗粒过滤器入口(211A),连通第一压缩机第一出口(20B1);The third particle filter inlet (211A) communicates with the first compressor first outlet (20B1); 第三颗粒过滤器第一出口(211B1);The first outlet of the third particle filter (211B1); 第三颗粒过滤器第二出口(211B2),用于连通外部排污池;The second outlet (211B2) of the third particle filter is used to communicate with the external sewage pool; 第四颗粒过滤器(212)包括:The fourth particulate filter (212) includes: 第四颗粒过滤器入口(212A),连通第三颗粒过滤器第一出口(211B1);The fourth particle filter inlet (212A) is connected to the third particle filter first outlet (211B1); 第四颗粒过滤器第一出口(212B1);The fourth particle filter first outlet (212B1); 第四颗粒过滤器第二出口(212B2),用于连通外部排污池;The second outlet (212B2) of the fourth particle filter is used to communicate with the external sewage pool; 电加热器(22)包括:The electric heater (22) includes: 电加热器入口(22A),连通第四颗粒过滤器第一出口(212B1);The electric heater inlet (22A) communicates with the first outlet (212B1) of the fourth particulate filter; 电加热器出口(22B);Electric heater outlet (22B); 一级膜管(23)包括:The primary membrane tube (23) includes: 一级膜管入口(23A),连通电加热器出口(22B);The first-stage membrane tube inlet (23A) is connected to the electric heater outlet (22B); 一级膜管低压出口(23B1),连通第一压缩机入口(20A);The first-stage membrane tube low-pressure outlet (23B1) is connected to the first compressor inlet (20A); 一级膜管高压出口(23B2);The high pressure outlet of the first-stage membrane tube (23B2); 二级膜管(24)包括:The secondary membrane tube (24) includes: 二级膜管入口(24A),连通一级膜管高压出口(23B2);The inlet (24A) of the secondary membrane tube is connected to the high pressure outlet (23B2) of the primary membrane tube; 二级膜管低压出口(24B1),连通二氧化碳增压回注橇块(E);The low-pressure outlet (24B1) of the secondary membrane tube is connected to the carbon dioxide pressurized reinjection block (E); 二级膜管高压出口(24B2),用于连通外部天然气管道;Secondary membrane tube high pressure outlet (24B2), used to connect external natural gas pipelines; 其中,经由第一压缩机第一出口(20B1)排出的增压气体依次进入到第三颗粒过滤器(211)和第四颗粒过滤器(212)中进行过滤,过滤后的气体经由电加热器入口(23A)进入到电加热器(22)中进行气化处理,然后经由电加热器出口(22B)排出,排出的气体首先进行一级膜管(23)进行初次分离处理,然后进入到二级膜管(24)进行二次分离并将气体中的二氧化碳与烃类气体分离开,分离出的二氧化碳经由二级膜管低压出口(24B1)进入到二氧化碳增压回注橇块(E);分离出的烃类气体直接进入外部天然气管道。The pressurized gas discharged through the first outlet (20B1) of the first compressor enters the third particle filter (211) and the fourth particle filter (212) for filtration in turn, and the filtered gas passes through the electric heater. The inlet (23A) enters the electric heater (22) for gasification treatment, and then is discharged through the electric heater outlet (22B). The secondary membrane tube (24) performs secondary separation and separates the carbon dioxide in the gas from the hydrocarbon gas, and the separated carbon dioxide enters the carbon dioxide pressurization reinjection block (E) through the secondary membrane tube low-pressure outlet (24B1); The separated hydrocarbon gas goes directly to the external natural gas pipeline. 8.根据权利要求7所述的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其特征在于,8. The skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to claim 7, characterized in that, 膜分离橇块(D)还包括第二气体分析仪(25),The membrane separation skid (D) further comprises a second gas analyzer (25), 其中,一级膜管低压出口(23B1)、一级膜管高压出口(23B2)、二级膜管低压出口(24B1)、二级膜管高压出口(24B2)分别连通于第二气体分析仪(25)。Among them, the low-pressure outlet of the primary membrane tube (23B1), the high-pressure outlet of the primary membrane tube (23B2), the low-pressure outlet of the secondary membrane tube (24B1), and the high-pressure outlet of the secondary membrane tube (24B2) are respectively connected to the second gas analyzer ( 25). 9.根据权利要求8所述的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其特征在于,9. The skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to claim 8, characterized in that, 压缩机进膜橇块(C)设置为两个;对应地,膜分离橇块(D)设置为两个,各膜分离橇块(D)与两个压缩机进膜橇块(C)分别连通,且各膜分离橇块(D)与二氧化碳增压回注橇块(E)连通。The number of compressor membrane feed sleds (C) is set to two; correspondingly, the number of membrane separation sleds (D) is set to two, and each membrane separation sled (D) and the two compressor membrane feed sleds (C) are respectively communication, and each membrane separation block (D) communicates with the carbon dioxide pressurization reinjection block (E). 10.根据权利要求9所述的橇装式二氧化碳驱返排气脱硫脱水与二氧化碳回收系统,其特征在于,10. The skid-mounted carbon dioxide drive-back exhaust gas desulfurization dehydration and carbon dioxide recovery system according to claim 9, characterized in that: 二氧化碳增压回注橇块(E)包括第二压缩机(26),第二压缩机(26)包括:The carbon dioxide booster reinjection skid (E) includes a second compressor (26), the second compressor (26) including: 第二压缩机入口(26A);second compressor inlet (26A); 第二压缩机第一出口(26B1),用于将二氧化碳排出;The second compressor first outlet (26B1) is used to discharge carbon dioxide; 第二压缩机第二出口(26B2),用于连通外部排污池;The second outlet (26B2) of the second compressor is used to communicate with the external sewage pool; 其中,经由各膜分离橇块(D)的二级膜管(24)的二级膜管低压出口(24B1)分离出来的气体从第二压缩机入口(26A)进入到第二压缩机(26)进行压缩,压缩后二氧化碳经由第二压缩机第一出口(26B1)排出,以进行下一步处理。Wherein, the gas separated from the secondary membrane tube low pressure outlet (24B1) of the secondary membrane tube (24) of each membrane separation block (D) enters the second compressor (26A) from the second compressor inlet (26A) ) is compressed, and the compressed carbon dioxide is discharged through the first outlet (26B1) of the second compressor for further processing.
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