CN1103363C - Super-concentration phosphorus-free bleaching washing liquid - Google Patents
Super-concentration phosphorus-free bleaching washing liquid Download PDFInfo
- Publication number
- CN1103363C CN1103363C CN00111992A CN00111992A CN1103363C CN 1103363 C CN1103363 C CN 1103363C CN 00111992 A CN00111992 A CN 00111992A CN 00111992 A CN00111992 A CN 00111992A CN 1103363 C CN1103363 C CN 1103363C
- Authority
- CN
- China
- Prior art keywords
- super
- present
- bleaching
- washing liquid
- polyoxyethylene ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004061 bleaching Methods 0.000 title claims abstract description 10
- 239000007788 liquid Substances 0.000 title claims abstract description 9
- 238000005406 washing Methods 0.000 title claims description 11
- 230000002087 whitening effect Effects 0.000 claims abstract description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims abstract description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000008367 deionised water Substances 0.000 claims abstract description 5
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 4
- 239000011574 phosphorus Substances 0.000 claims abstract description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 230000003287 optical effect Effects 0.000 claims description 7
- SQAKQVFOMMLRPR-IWGRKNQJSA-N 2-[(e)-2-[4-[4-[(e)-2-(2-sulfophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1\C=C\C1=CC=C(C=2C=CC(\C=C\C=3C(=CC=CC=3)S(O)(=O)=O)=CC=2)C=C1 SQAKQVFOMMLRPR-IWGRKNQJSA-N 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 239000001509 sodium citrate Substances 0.000 claims description 4
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 4
- 229940038773 trisodium citrate Drugs 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 2
- JZRYQZJSTWVBBD-UHFFFAOYSA-N pentaporphyrin i Chemical class N1C(C=C2NC(=CC3=NC(=C4)C=C3)C=C2)=CC=C1C=C1C=CC4=N1 JZRYQZJSTWVBBD-UHFFFAOYSA-N 0.000 claims description 2
- PJANXHGTPQOBST-VAWYXSNFSA-N trans-stilbene Chemical group C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 claims description 2
- 239000007844 bleaching agent Substances 0.000 abstract description 4
- -1 triethanolmine Chemical compound 0.000 abstract description 3
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- 150000002191 fatty alcohols Chemical class 0.000 abstract 2
- 238000009994 optical bleaching Methods 0.000 abstract 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 230000029553 photosynthesis Effects 0.000 abstract 1
- 238000010672 photosynthesis Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 206010023126 Jaundice Diseases 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000009897 hydrogen peroxide bleaching Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229960003010 sodium sulfate Drugs 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The present invention discloses a high-concentrated phosphorus-free color rinsing liquid detergent. The present invention is composed of the raw materials of fatty alcohol polyoxyethylene ether, fatty alcohol polyoxyethylene ether sodium sulfate, triethanolmine, trisodium citrate dihydrate, EDTA-2Na, trimethylene glycol, super whitening agents, optical bleaching agents, perfumery compound and deionized water. The present invention adopts the technology of super whitening agents and optical bleaching, carries out photosynthesis under the existence of sunlight, water and air, removes oxidative dirt, and has the advantages of high concentration, high safety, no pollution, no phosphorus, whitening, bleaching, disinfection and softening.
Description
The present invention relates to washing composition, belong to a kind of pollution-free, photobleaching washing liquid especially.
Existing liquid washing agent kind is a lot, and structure-type and non-structural type are arranged, but to contain STPP (sodium tripolyphosphate), sodium carbonate, alkalescence heavier more, should not wash high-count fabric.Though the not phosphorous and aluminium that has, prescription is simple, and comprehensive scourability is relatively poor, and whitening agent mostly is CCDAS type (derivative of toluylene triazine), and it is poor that fabric is washed the normal obfuscation in back, jaundice, whitening effect.The washing liquid with bleaching function that has, its bleaching mostly are perborate, percarbonate and hydrogen peroxide bleaching system, reach bleaching effect, must have activator to help, and also need to carry out 35 ℃-60 ℃ bath temperature, and be too complicated.
The purpose of this invention is to provide the without phosphorus bleaching washing liquid of a kind of concentrated type, it can have brightens and bleaching effect significantly, and decontamination, sterilizing power are strong, avoid environmental pollution.
The present invention is that following mode realizes, its component concentration is by weight percentage:
Fatty alcohol-polyoxyethylene ether 20%-30% trolamine 1%-5%
Polyoxyethylenated alcohol sodium sulfate 4%-10% Trisodium Citrate 2%-6%
EDTA-2Na 0.1%-2% propylene glycol 0.5%-4%
DSBP whitening agent 0.2%-0.3% BBS optical white 0.1%-0.15%
Essence 0.3%-0.8% deionized water surplus
Described DSBP whitening agent is an a kind of pair of toluylene type white dyes, and described BBS optical white is a kind of blue porphine derivative.
Adopt optical white in the present invention's prescription, and do not adopt chemical bleaching agent in the past, utilization photobleaching technology, but can remove the oxygen dirt that general washing composition is difficult to remove effectively.Adopt three to one compounded technology, make negatively charged ion, nonionogenic tenside reach best synergy.Select the super whitening agent of high environment-friendly type for use, environmentally safe is avoided clothing deepening, flavescence.Prescription is weakly alkaline, is suitable for various fabric washing.The present invention is not phosphorous, have highly enriched, high safety, sterilization, softness, brighten, bleaching, free of contamination advantage.
The embodiment of the invention is as follows:
The invention belongs to a kind of mixed type liquid washing agent, contain the anion-nonionic tensio-active agent, the present invention gets EO3--9 fatty alcohol-polyoxyethylene ether 25% in the weight percentages of components, polyoxyethylenated alcohol sodium sulfate 6%, trolamine 2%, Trisodium Citrate 3%, EDTA-2Na 0.5%, propylene glycol 2%, DSBP whitening agent 0.2%, BBS optical white 0.1%, essence 0.4%, and all the other are deionized water.Preparation method of the present invention is: deionized water is put into container, under constantly stirring, add fatty alcohol-polyoxyethylene ether, polyoxyethylenated alcohol sodium sulfate, trolamine, Trisodium Citrate, EDTA-2Na, propylene glycol successively, heat to back insulation more than 50 ℃, work in-process detect, and add whitening agent, optical white, essence again.
Claims (1)
1. without phosphorus bleaching washing liquid of concentrated type is characterized in that the weight percent of component is:
Fatty alcohol-polyoxyethylene ether 20%-30% trolamine 1%-5%
Polyoxyethylenated alcohol sodium sulfate 4%-10% Trisodium Citrate 2%-6%
EDTA-2Na 0.1%-2% propylene glycol 0.5%-4%
DSBP whitening agent 0.2%-0.3% BBS optical white 0.1%-0.15%
Essence 0.3%-0.8% deionized water surplus
Described DSBP whitening agent is an a kind of pair of toluylene type white dyes, and described BBS optical white is a kind of blue porphine derivative.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN00111992A CN1103363C (en) | 2000-03-13 | 2000-03-13 | Super-concentration phosphorus-free bleaching washing liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN00111992A CN1103363C (en) | 2000-03-13 | 2000-03-13 | Super-concentration phosphorus-free bleaching washing liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1263938A CN1263938A (en) | 2000-08-23 |
| CN1103363C true CN1103363C (en) | 2003-03-19 |
Family
ID=4581888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN00111992A Expired - Fee Related CN1103363C (en) | 2000-03-13 | 2000-03-13 | Super-concentration phosphorus-free bleaching washing liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1103363C (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100366716C (en) * | 2006-04-10 | 2008-02-06 | 中国海洋石油总公司 | Heavy oil cleaning agent |
| CN101058781B (en) * | 2007-05-24 | 2011-08-10 | 朱思聪 | Low-temperature energy-saving emulsifier for industrial washing clothes |
| CN101550379B (en) * | 2009-05-14 | 2011-01-05 | 浙江绿朋环保科技有限公司 | Environment-friendly plant cleaning agent and processing method thereof |
| CN101851564B (en) * | 2010-06-28 | 2013-05-08 | 上海制皂(集团)如皋有限公司 | Laundry detergent used for washing underwear |
| CN103409245A (en) * | 2010-06-30 | 2013-11-27 | 杨红宇 | Concentrated laundry detergent |
| CN101906357A (en) * | 2010-08-12 | 2010-12-08 | 江苏爱特福84股份有限公司 | Textile disinfecting composition and preparation method |
| CN102796626B (en) * | 2012-08-29 | 2019-04-26 | 朱上翔 | A kind of activator washed and rinsed for ionic washer low-temperature energy-saving master |
| CN103146501B (en) * | 2013-03-22 | 2015-02-25 | 于文 | Environment-friendly high-efficiency laundry detergent and preparation method thereof |
| CN103865674A (en) * | 2014-03-18 | 2014-06-18 | 严明东 | Cleaning liquid for bleaching clothes |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1161057A (en) * | 1994-08-30 | 1997-10-01 | 普罗格特-甘布尔公司 | Chelating agents that enhance photobleaching |
| CN1225122A (en) * | 1996-05-17 | 1999-08-04 | 普罗格特-甘布尔公司 | Detergent composition |
-
2000
- 2000-03-13 CN CN00111992A patent/CN1103363C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1161057A (en) * | 1994-08-30 | 1997-10-01 | 普罗格特-甘布尔公司 | Chelating agents that enhance photobleaching |
| CN1225122A (en) * | 1996-05-17 | 1999-08-04 | 普罗格特-甘布尔公司 | Detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1263938A (en) | 2000-08-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |