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CN110213979A - Toothbrush - Google Patents

Toothbrush Download PDF

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Publication number
CN110213979A
CN110213979A CN201880008070.8A CN201880008070A CN110213979A CN 110213979 A CN110213979 A CN 110213979A CN 201880008070 A CN201880008070 A CN 201880008070A CN 110213979 A CN110213979 A CN 110213979A
Authority
CN
China
Prior art keywords
toothbrush
toothbrush according
head
spoke
central part
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201880008070.8A
Other languages
Chinese (zh)
Other versions
CN110213979B (en
Inventor
I·巴比克
G·德索萨梅西亚斯
M·法瓦雷托
C·J·米勒
S·佩雷尼克
C·普尔佐尼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever IP Holdings BV
Original Assignee
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever NV filed Critical Unilever NV
Publication of CN110213979A publication Critical patent/CN110213979A/en
Application granted granted Critical
Publication of CN110213979B publication Critical patent/CN110213979B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B9/00Arrangements of the bristles in the brush body
    • A46B9/06Arrangement of mixed bristles or tufts of bristles, e.g. wire, fibre, rubber
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B15/00Other brushes; Brushes with additional arrangements
    • A46B15/0002Arrangements for enhancing monitoring or controlling the brushing process
    • A46B15/0016Arrangements for enhancing monitoring or controlling the brushing process with enhancing means
    • A46B15/0032Arrangements for enhancing monitoring or controlling the brushing process with enhancing means with protrusion for polishing teeth
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B9/00Arrangements of the bristles in the brush body
    • A46B9/02Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
    • A46B9/04Arranged like in or for toothbrushes
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/10For human or animal care
    • A46B2200/1066Toothbrush for cleaning the teeth or dentures

Landscapes

  • Brushes (AREA)

Abstract

The present invention is field of toothbrushes;And more particularly to the toothbrush with the tooth whitening efficacy promoted.It is well known in the art for providing the toothbrush of the whitening benefit in addition to cleaning or polishing benefit.Although the toothbrush of the prior art, which provides, is used for whitening effect, it is still desired for promoting brightening for tooth.Therefore the purpose of the present invention is to provide the dental whitening of promotion or greasiness removal effects.It has been found that when dental whitening element on the head at specific arrangements structure when, can get promoted dental whitening or greasiness removal.

Description

Toothbrush
Technical field
The present invention is field of toothbrushes;And more particularly, to the toothbrush with improved tooth whitening efficacy.
Background technique
In recent years, because consumer is for the boosting of both charming smiles in health and appearance demand, dental whitening, which becomes, to be increased One of long oral care branch the most quick.In fact, for most people, the appearance of tooth is very important, And it is possibly formed into any discoloration on tooth or spot all will affect the aesthetic quality of tooth.The color of tooth is solid by tooth There is color to obtain the discoloration in film or the existing combined effect of exogenous spot with enamel is possibly formed into.Tooth it is intrinsic Color is mainly determined by lower layer's dentine through the color attribute that relatively translucent outer adamantine layer is projected.Exogenous spot Be particularly formed in tooth less easily for brush teeth and these regions that the abrasive action of toothpaste is touched on.In addition, exogenous Spot often by smoking, rich in dark pigment food (for example, red wine) diet intake and such as chlorohexidene certain cationics Or the use of the multivalent metal salt of such as tin and iron etc promotes.
It is well known in the art for providing the toothbrush of the whitening benefit in addition to cleaning or polishing benefit.
WO03/015575 (Unilever) is disclosed with the toothbrush for radially extending rubber cleaning element.WO11093874 (Colgate) toothbrush that polishing component is dispersed in Y shape bristle is disclosed.WO 01/21036 (Unilever) discloses packet The toothbrush of handle and head is included, the head includes upright bristles and at least one upright polishing of teeth element, which is characterized in that tooth Polishing element is resilient wall type component form and connects with bristle side.
WO2008/103598 discloses a kind of oral care implement or toothbrush, the oral care implement or toothbrush include Head and the tooth cleaning components for enhancing cleaning of teeth and brightening.Tooth cleaning components have the pedestal for being connected to head.Pedestal With the concave surface form for being in the distal region towards head, so that the tooth powder for being applied to head is adapted to the distal region towards head Guidance.Distal region of the protrusion from concave surface towards head extends.Head may include along head longitudinal axis aligned in general it is more A concave surface, and protrusion extends from curved surface.
WO04/026075 (Unilever) discloses a kind of toothbrush, and the toothbrush includes longitudinal elasticity component, longitudinal elasticity Component includes the perlite for brightening.
Although the toothbrush of the prior art, which provides, is used for whitening benefit, it is still desired for promoting brightening for tooth.
Correspondingly, the object of the present invention is to provide the dental whitening of promotion or greasiness removal effects.
Other purpose is, provides a kind of toothbrush, and the toothbrush has effects that the dental whitening or greasiness removal promoted Benefit is removed with sufficient polishing and plaque.
Unexpectedly, it was found that when dental whitening element on the head at specific arrangements structure when, can get promoted Dental whitening or greasiness removal.
Summary of the invention
Correspondingly, the present invention provides a kind of toothbrush, the toothbrush includes handle (1) and head (2), and the head includes bristle With the dental whitening element (3) for being resilient wall type component form, which is characterized in that the dental whitening element has along head Central part (4) and cup that longitudinal axis extends enclose at least one lateral part (5) of the end of (cup) central part, wherein The lateral part (5) forming is there are two spoke or the lateral part is starlike is formed at least three spoke (6).
In another aspect, the present invention provides the purposes for improved oral hygiene of toothbrush according to the present invention.
From described in detail below and appended claims are read, these and other aspects, features and advantages is general to this field Logical technical staff will become obvious.To avoid doubt, any feature of one aspect of the present invention is for use in the present invention In any other aspect.Word " comprising " be intended to indicate "comprising" but be not necessarily " by ... form " or " by ... constitute ". In other words, cited step or option are without exhaustive.It is noted that the example provided in being described below is intended to explain the present invention, It is not intended that the present invention is limited to these examples itself.Similarly, all percentage is all weight/weight percent, unless In addition it indicates.Other than in operation and comparative example, or there are other clear indications, otherwise in the specification All numbers of the quantity of the material of Indicator Reaction or condition, the physical property of material and/or purposes are it will be understood that at word is modified with Language " about ".The digital scope stated in the form of " from x to y " is interpreted as including x and y.When in the form of " from x to y " description for When multiple preferred scopes of special characteristic, it is understood that all ranges for combining different endpoints are also considered.
Specific embodiment
The present invention relates to provide promoted brighten or the toothbrush of greasiness removal effect.Toothbrush of the invention also provides adequately Polishing and plaque remove benefit.
Preferably, toothbrush is manual toothbrush.Preferably, the shape of tooth head is general rectangular.
Dental whitening element
Dental whitening element is resilient wall type component form.Wall type component is preferably made of soft enough material to provide The whitening benefit of tooth, and it is therefore preferable that the wall type component by having between 5 and 80, preferably from 15 to 50 The material of Xiao A hardness is made.
As dental whitening element is along dental surface brushing during scrub, brightens element and whitening benefit is provided.Due to tooth Tooth brightens the wall-like structure and its elasticity composition of element, therefore dental whitening element being capable of flexible deformation.
Dental whitening element is presented as the thin slice being inserted between the bristle of toothbrush.Dental whitening element is preferably by thermoplastic Property elastomer (TPE) is made.
Thermoplastic elastomer (TPE) is made of polymer material such as block copolymer.Preferred block copolymer includes styrene (for example, Styrene Ethylene styrene or styrene butadiene styrene), polyolefin are (for example, polypropylene/ethylene The modified system's (that is, synthetic rubber) of propane diamine), polyamide (for example, polyamide (2 or polyamide 6), polyester (for example, polyester ester or Polyether ester), polyurethane (for example, polyester polyurethane, polyethers or polyester-polyurethane).
It is also preferred that brightening element includes perlite particle.
It is contemplated that brightening element can be die cut or be molded production by any conventional method.However, the such knot of production The preferred method of structure will pass through injection moulding.The material of wall type component can be attached to head toothbrushes in any way, either Pass through chemical means, mechanical means or both.
In the case where being not intended to theoretical limited, it is believed that, dental whitening element, which has, is against tooth for the resistance of toothpaste particle On advantage.When toothbrush is stowed against the flat surfaces of tooth, these particles be would be held in contact.In addition, toothbrush In bristle have the advantages that for toothpaste particle to be carried in interdental seam or narrow gap, thus whitening benefit and cleaning are provided The combination of benefit.Dental whitening element of the invention has central part and at least one lateral part.Preferably, dental whitening The central part (4) of element (3) is extended continuously along the longitudinal axis of head (2).
Central part and lateral part, which are preferably separated from each other and do not combine at any point, forms individual unit.
The central part of dental whitening element is extended continuously preferably along the longitudinal axis of head.Central part preferably has 10mm to 15mm, more preferably 10mm to 13mm, the straight length of still more preferably 10mm to 12mm.
In the case where distance, the i.e. development length that central part extends up to the length greater than head is greater than head length, center Part may need to be bent with some form.This can be gentle bending, but its can also with serpentine, sine curve or word The form of shape is bent.
Development length should not the straight length of the shortest distance with centered between the end of part obscure.
Preferably, the linear form of central part.
Dental whitening element preferably has a central part.
Dental whitening element of the invention have preferably cup enclose/in a manner of cup-shaped around central part end at least One lateral part.
Preferably, there are two lateral parts that cup encloses each end of central part.
Lateral part preferably shapes the end for enclosing central part so as to cup.Preferably, lateral part have V-arrangement, U-shaped or The end of central part is enclosed with cup in U-V shape region.
Preferably, the end that there is lateral part V-arrangement region central part is enclosed with cup.Lateral part can be because of lateral part V-arrangement and formed there are two spoke;Or lateral part can be it is star-shaped, have at least three spoke, preferably 3 spokes.Respectively Spoke can have identical or different length.The length of spoke can from 1mm to 7mm, preferably 2mm to 6mm, more preferably 3mm Change to 6mm.Spoke can be straight also at tip or be bent outwardly.
Toothbrush according to the present invention can be made of any material conventional use of in this field.
Correspondingly, the handle of brush and head can be by polyolefin (for example, polypropylene and polyethylene), polyamide (for example, nylon) It is molded as with polyester (for example, poly terephthalic acid).Other suitable material includes polymethyl methacrylate, polyethylene propylene Nitrile and cellulose esters, such as cellulose propionate.
The bristle of brush can be made by being suitable for flexible material used in oral hygiene.Generally, it is suitable for the material of bristle Polyamide (for example, nylon) or polyester (for example, polybutylene terephthalate (PBT)).
In second aspect, the present invention is provided to the use for improved oral hygiene of toothbrush according to the present invention On the way.
Attached drawing
The embodiment of toothbrush according to the present invention is described with reference to the drawings herein.Fig. 1 shows toothbrush according to the present invention Schematic diagram.In Fig. 1, toothbrush includes head (2) and handle (1).Head has dental whitening element (3), dental whitening element tool There are (5) two parts of central part (4) and lateral part.Lateral part has spoke (6).Brushing cluster (7) are also shown in head.
Fig. 2 shows the comparing results of 3 kinds of toothbrushes of example 3.Blue color (first column) indicates tooth according to the present invention Brush, green color (Article 3 column) indicates the whole edge toothbrush of Oral B flat-top and red color (Article 2 column) indicates Signal toothbrush.
The present invention will be illustrated by following non-limiting example now.
Example
Example 1: toothbrush according to the present invention is in the effect for brightening aspect
In this example, it compares toothbrush according to the present invention and is gone out with the famous market of whitening effect and with brand name Signal The existing toothbrush (White System Ex, Italy, 2016) sold.
Equipment:
Equipment used in the example is as follows:
Dismembyator, gravel paper;
WIRA scrubbing unit;
Color difference meter Minolta CR321 (Minolta Camera Co., Ltd, Japan), under CIE L*a*b* mode.
Spot process:
According to Stookey GA, Burkhard TA, Schemehorn B R.in vitro removal of stain Cleaning is assessed described in 1982 61:1236-1239 of with dentifrices J Dent Res.Greasiness removal percentage Than being provided by following equation:
L*Brushed: the L* value after brushing time
L*Stained: the L* value under the conditions of baseline spot
L*Pumiced: the L* value after finally being polished using preventive treatment
Test product:
Code Test product
A The Signal White System toothbrush of Unilever
B Toothbrush according to the present invention
Toothbrush according to the present invention used in the example has following specification: head
Design:
Bristle shears profile: multilayer (has power end)
Material
Anchor:
Metal alloy (nickel silver electric wire)
Supplier-Berkenhoff
Grade-nickeline NS 12
Fibril:
Nylon 6/12
Supplier: DuPont/STP
Grade: PA6.12 fibril
+
Nylon 6/12
Supplier: BBC-tbc
Grade: charcoal fibril
Cluster figure:
As shown in figure 1
Fibril slide calliper rule & fibril color:
Modify size:
Highly: higher cluster=12.5 ± 0.5mm
Lower cluster=10.5 ± 0.5mm
Thin slice=10.5 ± 0.2mm
As a result:
In this study, toothbrush A and B are tested using experimental design matrix, it is ensured that the bristle of test is randomly assigned scrubbing In 4 slots of machine.As a result it is summarised in table 1.Data statistic analysis is carried out via JMP 11 (statistical software from SAS).Benefit Expansion comparison is tested with Tukey-Kramer HSD, to assess whether the difference between product is statistical significant.
Table 1 shows the mean value of greasiness removal percentage, with for each test product relative standard deviation value and Standard error value.
Table 1
The mean value of (*) different letters significant difference under the conditions of 95% confidence level (p < 0.05).
Above table shows in greasiness removal effect or brightens the statistical discrepancy of aspect discovery.It can be seen that according to this The toothbrush of invention outperforms Signal toothbrush.
Example 2: effect of the toothbrush according to the present invention in terms of plaque removal
In this example, the existing toothbrush for comparing toothbrush according to the present invention and being sold in the market with brand name Signal, To remain in the quantity of the plaque in interdental spaces after round scrub is mobile by measuring and evaluate cleaning performance.
Equipment:
Equipment used in the example is as follows:
Scrubbing unit: with line mode and the combination that intersects brush mode, it is tested in observe that it is approximately substantial circular Brushing motion.
Tooth model:
Using the coloured dental plate that seam is made and extended in parallel including four of polyurethane, to simulate front tooth and mill in mouth Interdental spaces between tooth.Full of paste group seam show as 4mm width leukorrhea;After scrub, the clean seam in part shows The leukorrhea reduced out for width.Analysis only considers two center seams.
Equipment for measuring plaque removal: spectrophotometer measurement whiteness is utilized, wherein for empty seam, full seam With " L " in the seam record L*a*b* color system after scrub.
Artificial plaque:
The soft white paste group of synthesis of the seam filled with simulation mankind's plaque physical property on tooth model.
In the seam that paste group is dispersed on dental plate (plate) using palette knife, and extra paste will be rolled into a ball in dental plate It is applied on surface.
Test process:
Toothbrush is immersed in water 5 minutes to soften bristle.Then by head toothbrushes vertically in the grasping list of grooming machine So that cluster is not compressed during storing and after putting in member.Full dental plate and empty dental plate are measured using chromascope Value.Six groups of measurements (for each each three groups of measurements of seam: intermediate one group and each one group of every side) has been carried out in two center seams, And it calculates average.The tooth dental plate for being provisioned with plaque filling is placed in special container, and saliva addition is whole at covering A dental plate.Container is seated in machine holder.By weight, apply 190 grams of load on brush head, and allows to scrub Machine runs 30 total travels (150 two-passes of frequency/minute).Then using distilled water carefully denture care bed to remove desalivation Residue, and dental plate is taken out from container.Plaque removal is assessed in a manner of photometering by stitching, such as full value with As empty value is done.Denture care bed, and the load for applying 275 grams for same brush head performs an analysis again.
The percentage of plaque removal is determined using following equation:
Test product:
Code Test product
A The Signal toothbrush of Unilever
B Toothbrush according to the present invention
Toothbrush according to the present invention used in the example has and identical specification in example 1.
As a result:
In this study, toothbrush A and B are tested for plaque removal.
Table 2 shows the mean value of plaque removal percentage, with the relative standard deviation value for each test product.
Table 2
Above table shows that test product statistics is equal.It can be seen that toothbrush performance according to the present invention is similar to Signal toothbrush.
Example 3: effect of the toothbrush according to the present invention in terms of polishing
In this example, the existing tooth sold to toothbrush according to the present invention frequently and in the market with brand name Oral B Brush, to evaluate the wear intensity of toothbrush according to the present invention.
Test product:
Test product
A The Signal toothbrush of Unilever
B Toothbrush according to the present invention
C The whole edge of Oral B flat-top
Used material:
Scrubbing unit
Black acrylic ceramic tile
Sheen vancometer 155/SO
Test process:
Using the miniature vancometer of Sheen with the gloss value of 60o/60o (incidence/measurement) every block of ceramic tile of angle measurement. For every block of ceramic tile, original gloss measurement is carried out, then so that organic glass surface is become low and deep using sand paper, and measure again Gloss value.This provides the minimum and maximum gloss value of ceramic tile, is then calculated according to the minimum and maximum gloss value Glossiness percentage.
Slurry is by following preparation:
1 part of toothpaste (Signal responsive type toothpaste)
1 part of water
1 part of SCMC dilution
Deposited 10g or more slurry is applied on every part of sample, and scrubs ceramic tile.It goes in 200,1000,3000 and 5000 scrubs Glossiness measurement is carried out after journey.
As a result:
In this study, toothbrush A, B and C are tested for wear intensity.
Fig. 2 shows the results of different time points.Generally, it is inferred that toothbrush according to the present invention (in Fig. 2 by Blue color marking) it is better than the whole edge type toothbrush (being indicated in Fig. 2 by green color) of Oral B flat-top on polishing action, and in table Existing aspect statistics is similar to Signal toothbrush (being indicated in Fig. 2 by red color).

Claims (13)

1. a kind of toothbrush, including handle (1) and head (2), the head includes bristle and the tooth increasing for being resilient wall type component form White element (3), which is characterized in that the dental whitening element has the central part extended along the longitudinal axis of the head (4) and cup enclose the central part end at least one lateral part (5), wherein the lateral part (5) is configured to have There are two spoke or the lateral part be it is star-shaped, there are at least three spoke (6).
2. toothbrush according to claim 1, wherein the central part (4) of the dental whitening element (3) is along the head (2) longitudinal axis is extended continuously.
3. toothbrush according to any one of the preceding claims, wherein the central part (4) and the lateral part (5) it is separated from each other.
4. toothbrush according to any one of the preceding claims, wherein the central part (4) has 10mm to 15mm's Straight length.
5. toothbrush according to any one of the preceding claims, wherein the lateral part (5) has V-arrangement, U-shaped or U-V The end of the central part is enclosed in the region of shape with cup.
6. toothbrush according to any one of the preceding claims, wherein the lateral part (5) be V-arrangement, tool there are two Spoke or the lateral part be it is star-shaped, have at least three spoke (6).
7. toothbrush according to any one of the preceding claims, wherein each spoke (6) has identical or different length.
8. toothbrush according to any one of the preceding claims, wherein the length of the spoke (6) is 1mm to 7mm.
9. toothbrush according to any one of the preceding claims, wherein the spoke (6) is straight or curved.
10. toothbrush according to any one of the preceding claims, wherein the dental whitening element (3) has in one Center portion point (4).
11. toothbrush according to any one of the preceding claims, wherein the dental whitening element (3) is presented as thin slice.
12. toothbrush according to any one of the preceding claims, wherein the dental whitening element (3) includes perlite.
13. a kind of purposes for being used to improve oral hygiene of toothbrush according to any one of the preceding claims.
CN201880008070.8A 2017-01-23 2018-01-17 Tooth brush Expired - Fee Related CN110213979B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP17152544.7 2017-01-23
EP17152544 2017-01-23
PCT/EP2018/051132 WO2018134270A1 (en) 2017-01-23 2018-01-17 A toothbrush

Publications (2)

Publication Number Publication Date
CN110213979A true CN110213979A (en) 2019-09-06
CN110213979B CN110213979B (en) 2022-04-26

Family

ID=57868125

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880008070.8A Expired - Fee Related CN110213979B (en) 2017-01-23 2018-01-17 Tooth brush

Country Status (3)

Country Link
EP (1) EP3570703B1 (en)
CN (1) CN110213979B (en)
WO (1) WO2018134270A1 (en)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1211963A1 (en) * 1999-09-17 2002-06-12 Unilever N.V. Toothbrush
WO2003015575A1 (en) * 2001-08-14 2003-02-27 Unilever N.V. Electric toothbrush
CN1407865A (en) * 1999-10-08 2003-04-02 高露洁-棕榄公司 Toothbrush having bristle pattern providing enhanced cleaning
WO2004026075A1 (en) * 2002-09-20 2004-04-01 Unilever N.V. Brush device
CN1674808A (en) * 2002-08-09 2005-09-28 高露洁-棕榄公司 toothbrush
US7089621B2 (en) * 2002-09-20 2006-08-15 Colgate-Palmolive Company Toothbrush
WO2008103598A1 (en) * 2007-02-23 2008-08-28 Colgate-Palmolive Company Oral care implement
WO2011093874A1 (en) * 2010-01-29 2011-08-04 Colgate-Palmolive Company Oral care implement
WO2016105359A1 (en) * 2014-12-23 2016-06-30 Colgate-Palmolive Company Oral care implement

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1211963A1 (en) * 1999-09-17 2002-06-12 Unilever N.V. Toothbrush
US20020124337A1 (en) * 1999-09-17 2002-09-12 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Toothbrush
CN1374840A (en) * 1999-09-17 2002-10-16 荷兰联合利华有限公司 Tooth brush
CN1407865A (en) * 1999-10-08 2003-04-02 高露洁-棕榄公司 Toothbrush having bristle pattern providing enhanced cleaning
WO2003015575A1 (en) * 2001-08-14 2003-02-27 Unilever N.V. Electric toothbrush
CN1674808A (en) * 2002-08-09 2005-09-28 高露洁-棕榄公司 toothbrush
WO2004026075A1 (en) * 2002-09-20 2004-04-01 Unilever N.V. Brush device
US7089621B2 (en) * 2002-09-20 2006-08-15 Colgate-Palmolive Company Toothbrush
WO2008103598A1 (en) * 2007-02-23 2008-08-28 Colgate-Palmolive Company Oral care implement
WO2011093874A1 (en) * 2010-01-29 2011-08-04 Colgate-Palmolive Company Oral care implement
WO2016105359A1 (en) * 2014-12-23 2016-06-30 Colgate-Palmolive Company Oral care implement

Also Published As

Publication number Publication date
EP3570703B1 (en) 2024-10-16
EP3570703A1 (en) 2019-11-27
WO2018134270A1 (en) 2018-07-26
CN110213979B (en) 2022-04-26
BR112019010950A2 (en) 2019-10-01

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Applicant before: Unilever Nederland B.V.

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Granted publication date: 20220426