Disclosure of Invention
In view of the above, the application provides a method for preparing a household cutter with ultra-long sharpness retention by arc ion plating, which is used for solving the technical problem of poor sharpness retention of the household cutter after coating in the prior art.
The first aspect of the present application provides a method for manufacturing an ultra-long sharpness retention household tool using arc ion plating, the manufacturing method comprising the steps of:
step S1, placing a household cutter matrix in a vacuum chamber of a cathode arc ion plating machine for ion cleaning to obtain a cleaned household cutter matrix;
And S2, controlling a permanent magnetic field mode and an electromagnetic field mode of the cathode arc ion plating machine, applying a vertical target surface magnetic field, a radial magnetic field of a cathode target surface and a tangential magnetic field of a cathode target surface runway perpendicular to the radial magnetic field on a cathode target, and performing arc ion plating on the cleaned household cutter matrix to obtain the household cutter with ultra-long sharpness retention.
Preferably, in step S2, the electromagnetic field mode of the cathodic arc ion plating machine is a waveform parameter for controlling the scanning voltage of the electromagnetic coil in the cathodic arc ion plating machine.
Preferably, the waveform of the electromagnetic coil scanning voltage in the cathodic arc ion plating machine is at least one of triangular wave, square wave or trapezoidal wave and sine wave.
Preferably, the waveform parameters of the scanning voltage are that the frequency range is 1-50 Hz, the duty ratio range is 1-100%, and the corresponding coil voltage range is-50V.
Preferably, in step S2, the permanent magnetic field mode of the cathodic arc ion plating machine is designed to be an arrangement structure of permanent magnets in the cathodic arc ion plating machine.
Preferably, in a first permanent magnetic field mode constructed by the arrangement structure of the permanent magnets in the designed cathodic arc ion plating machine, the cathode bulls-eye is taken as an axis, and the variation range of the vertical target surface magnetic field is-56-96T when the cathode bulls-eye rotates for one circle at intervals of 36 degrees;
In the constructed second permanent magnetic field mode, the cathode bulls-eye is taken as the axis, and the variation range of the vertical target surface magnetic field is-88-56T when the cathode bulls-eye rotates for one circle at intervals of 36 degrees;
In the constructed third permanent magnetic field mode, the cathode bulls-eye is taken as the axis, and the variation range of the magnetic field of the vertical target surface is-79-71T when the cathode bulls-eye rotates for one circle at intervals of 36 degrees;
In the constructed fourth permanent magnetic field mode, the cathode bulls-eye is taken as the axis, and the variation range of the magnetic field of the vertical target surface is 31-116T when the cathode bulls-eye rotates for one circle at intervals of 60 degrees;
In the constructed fifth permanent magnetic field mode, the cathode bulls-eye is taken as the axis, and the change range of the planar magnetic field is 3-116T or-88-44T when the cathode bulls-eye rotates for one circle at intervals of 45 degrees;
in the constructed sixth permanent magnetic field mode, the cathode bulls-eye is taken as the axis, and the change range of the planar magnetic field is-12-62T or-8-44T when the cathode bulls-eye rotates for one circle at intervals of 45 degrees;
in the constructed seventh permanent magnetic field mode, the cathode bulls-eye is taken as the axis, and the change range of the planar magnetic field is-11-51T or 5-54T when the cathode bulls-eye rotates for one circle at intervals of 45 degrees;
In the eighth constructed permanent magnetic field mode, the cathode bulls-eye is taken as the axis, and the change range of the plane magnetic field is-9-82T or-77-57T when the cathode bulls-eye rotates for one circle at intervals of 45 degrees.
Preferably, in step S2, the arc ion plating process includes:
S21, performing arc ion plating by using a metal cathode target of the bonding layer to obtain an ion plating bonding layer;
And S22, performing arc ion plating by using the functional layer metal cathode target to obtain an ion plating functional layer.
Preferably, after the step S21, before the step S22, according to the plating requirement, the method further comprises the step of performing arc ion plating by using the cathode target to obtain an ion plating transition layer.
Preferably, the metal element in the bond layer metal cathode target is selected from nine (e.g., ti, zr, hf, V, nb, ta, cr, mo, W) of three sub-groups (groups IVB, VB, and VIB) of transition metal elements or nitrides thereof (e.g., tiN, crn..and the like) and alloys thereof (e.g., tiAl, alcr..and the like) with individual elements in the third, fourth main groups (e.g., al, si, b..and the like) and nitrides thereof (e.g., tiAlN, cran..and the like) and borides (e.g., tiB 2..and the like).
Preferably, the bonding layer metal cathode target is selected from at least one of a Ti-Al cathode target, a Ti cathode target, a Cr-Al cathode target, and a Cr cathode target.
Preferably, the metal elements in the transition layer and functional layer metal cathode targets are selected from nitrides (e.g., tiN, crn..and the like) or carbonitrides (e.g., tiCN, crcn...and the like) and borides (e.g., tiB 2,HfB2..and the like) composed of nine (e.g., ti, zr, hf, V, nb, ta, cr, mo, W) of the three sub-groups (group IVB, group VB and group VIB) of elements and their third, ternary nitrides (e.g., tiAlN, crAlN, tiSiN...and the like) or carbonitrides (e.g., tiAlCN, crAlCN, tiSiCN...and the like) or quaternary nitrides (e.g., tiAlBN, tiAlSiN, crAlBN, crAlSiN...and the like) or carbonitrides (e.g., tiAlBCN, tiAlSiCN, crAlBCN, crAlSiCN...and the like) or polynitrides (e.g., tiCrAlB, tiCrAlSiN, tiAlSiWN, tiAlSiVN, crAlSiWN, crAlBWN...and the like) or carbonitrides (e.g., tiCrAlBCN, tiCrAlSiCN, tiAlSiWCN, tiAlSiVCN, crAlSiWCN, crAlBWCN...and the like) of individual elements (e.g., al, si, b..and the like) in the fourth main group.
Preferably, the transition layer and the functional layer metal cathode targets are at least one selected from Ti-Al-Si cathode targets, ti-B cathode targets, ti cathode targets, cr-Al-B cathode targets, ti-Al cathode targets, cr-Al cathode targets and Cr cathode targets.
Preferably, in step S1, the home tool base is a home tool base made of martensitic stainless steel.
Preferably, the martensitic stainless steel material is selected from martensitic chromium steel material or martensitic chromium nickel steel material.
Preferably, in the process of arc ion plating, the working current of the cathode target arc discharge ranges from 20 to 450A, the negative bias voltage ranges from not more than 200V, the working pressure ranges from 0.2 Pa to 10Pa, the working temperature ranges from 100 ℃ to 550 ℃, and the working pressure comprises nitrogen partial pressure, argon partial pressure, hydrogen partial pressure and the like.
Preferably, in the ion cleaning process, the range of the negative bias is not more than a specific value between 0 and 500v, the range of the arc target working current is a specific value between 50 and 400 amperes, the range of the working air pressure is a specific value between 0.2 and 10pa, the working temperature is a certain temperature not more than 550 ℃, the working air pressure comprises argon partial pressure and/or hydrogen partial pressure, and the hydrogen partial pressure is continuously changed or fixed at a certain value between not more than 50%.
Compared with the prior art, the method for preparing the household cutter with the ultra-long sharpness retention by using the arc ion plating provided by the application at least comprises the following beneficial effects:
1. In the method for preparing the ultra-long sharpness maintaining household cutter, the tangential magnetic field of the planar runway is introduced into the target surface, the tangential magnetic field of the planar runway is perpendicular to the radial magnetic field of the planar runway, and the tangential magnetic field of the planar runway and the radial magnetic field of the planar form the planar magnetic field of the target surface, so that the control of the arc spot on the target surface of the cathode is enhanced, the stability and the movement speed of the arc spot are accelerated, the temperature of the target surface is reduced, the metal liquid drops sprayed out from the arc spot are reduced and deposited on the film of the cutter, and the sharpness maintaining capability (TCC) of the household cutter after ion film plating is improved.
2. In the method for preparing the household cutter with ultra-long sharpness retention, the position where the vertical magnetic field component Bn of the target surface is equal to 0 is closer to the target, the arcing point of the arc spot is closer to the target, the arcing probability from the cathode target to one half of the edge of the cathode target is higher, the movement track radius of the arc spot can be wider, the arc spot cannot be limited to the edge of the target surface, the target surface is etched more uniformly, and the utilization rate of the cathode target is improved.
Detailed Description
The application provides a method for preparing a household cutter with ultra-long sharpness retention by using arc ion plating, which is used for solving the technical problem of poor sharpness retention of the household cutter after film plating in the prior art.
The following description of the embodiments of the present application will be made apparent and complete in conjunction with the accompanying drawings, in which it is evident that the embodiments described are some, but not all embodiments of the present application. All other embodiments, which can be made by those skilled in the art based on the embodiments of the application without making any inventive effort, are intended to be within the scope of the application.
Example 1
The embodiment 1 of the application provides a method for preparing a household cutter with ultra-long sharpness retention by using arc ion plating, which comprises the steps of pretreatment of the household cutter, ion etching and cleaning of the household cutter and arc ion plating of the household cutter.
The household cutter pretreatment step comprises the steps of preparing a household cutter with a machined and cut edge, and applying ultrasonic waves to clean the household cutter.
And (3) carrying out ion etching cleaning on the household cutter, namely hanging the ultrasonically cleaned household cutter on a rotating frame, putting the rotating frame into a vacuum chamber of an ion plating machine, vacuumizing to 5 multiplied by 10 -3 Pa, heating to a certain temperature of not more than 550 ℃, selecting a correct negative bias parameter, regulating the negative bias to a certain specific value of not more than 500V, switching on an arc source special for an etching device to control a certain specific value of 50-400 amperes of working current, regulating the flow of argon and hydrogen in a gas mixer, controlling the working pressure of the vacuum chamber to a certain specific value of 0.2-10 Pa, continuously changing or fixing the partial pressure of the hydrogen to a certain value, and carrying out ion etching on the household cutter for a certain specific time length of 30-120 minutes to obtain the cleaned household cutter matrix.
The steps of the household cutter arc ion plating comprise:
Turning off a power supply of an ion etching system, selecting a Ti-Al cathode target, introducing nitrogen, controlling the working pressure to be a certain specific value between 0.1 and 10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn on the Ti-Al cathode target, a radial magnetic field Bt on a Ti-Al cathode target plane and an arc runway tangential magnetic field Br perpendicular to the radial magnetic field on the Ti-Al cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V as shown in figure 2, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating for a certain specific time length between 30 and 60 minutes on a household cutter to obtain a plating bonding layer on the surface of the household cutter;
Then selecting a Ti-Si cathode target, introducing nitrogen, controlling the working pressure to be a certain specific value between 0.5 and 5 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn, a radial magnetic field Bt on a Ti-Si cathode target plane and an arc track tangential magnetic field Br perpendicular to the radial magnetic field on the Ti-Si cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V as shown in a figure 2, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating on a household cutter for a certain specific time length between 30 and 120 minutes to obtain an ion plating transition layer on the surface of the household cutter;
Next, selecting a Ti-B cathode target, introducing argon, controlling the working pressure to be a certain specific value between 0.5 and 5 Pa, applying a vertical magnetic field Bn on the Ti-B cathode target, a radial magnetic field Bt on a Ti-B cathode target plane and an arc spot runway tangential magnetic field Br on the Ti-B cathode target plane, which is perpendicular to the radial magnetic field, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V, switching on an ion plating arc source, controlling the working current to be a certain specific value between 50 and 400 Pa, and performing arc ion plating on a household cutter for a certain specific time length between 30 and 120 minutes to obtain an ion plating functional layer plated on the surface of the household cutter;
In the embodiment, the permanent magnetic field mode of the cathode arc ion plating machine is realized by controlling the permanent magnet structure, namely, the arrangement structure of the permanent magnets in the cathode arc ion plating machine is designed, so that the distribution state of the magnetic field intensity of the permanent magnetic field mode constructed by the permanent magnet arrangement structure is obviously different from that of the target surface magnetic field constructed by the traditional double-ring permanent magnet as shown in any one of figures 3-10, the distribution state of the magnetic field intensity of the vertical target surface and the magnetic field intensity of the parallel target surface are obviously different from those of the magnetic field constructed by the traditional double-ring permanent magnet, the electromagnetic field mode is realized by controlling the waveform of the scanning voltage of an electromagnetic coil, the waveform of the scanning voltage is at least one of triangular wave, square wave, trapezoidal wave or sine wave, the frequency is 1-50 Hz, the duty ratio range is 50-100%, and the corresponding coil voltage range is-50V.
According to the embodiment, by controlling the energy of the coating ions and the size of the metal liquid drops, the increase of the angle of the cutting edge caused by ion bombardment sputtering in the ion cleaning and coating processes and the increase of the angle of the cutting edge caused by the film deposition rate of the cutting edge changed by the sharp angle effect generated by the negative bias at the cutting edge in the deposition process are reduced, so that the damage to the cutting edge of the household cutter caused by etching cleaning and coating by using a cathodic arc ion plating technology is avoided as much as possible, and the prepared household cutter with ultra-long sharpness maintaining power (ICP) is 113mm and sharpness maintaining power (TCC) is 2325.7mm.
Example 2
Embodiment 2 of the application provides a method for preparing a household cutter with ultra-long sharpness retention by using arc ion plating, which comprises the steps of pretreatment of the household cutter, ion etching and cleaning of the household cutter and arc ion plating of the household cutter.
The household cutter pretreatment step comprises the steps of preparing a household cutter with a machined and cut edge, and applying ultrasonic waves to clean the household cutter.
And (3) carrying out ion etching cleaning on the household cutter, namely hanging the ultrasonically cleaned household cutter on a rotating frame, putting the rotating frame into a vacuum chamber of an ion plating machine, vacuumizing to 5 multiplied by 10 -3 Pa, heating to a certain temperature of not more than 550 ℃, selecting a correct negative bias parameter, regulating the negative bias to a certain specific value of not more than 500V, switching on an arc source special for an etching device to control a certain specific value of 50-400A of working current, regulating the flow of argon and hydrogen in a gas mixer, controlling the working pressure of the vacuum chamber to a certain specific value of 0.2-10 Pa, continuously changing or fixing the partial pressure of hydrogen to a certain value, and carrying out ion etching on the household cutter for a certain specific time length of 30-120 minutes to obtain the cleaned household cutter matrix.
The steps of the household cutter arc ion plating comprise:
Turning off a power supply of an ion etching system, selecting a Cr-Al cathode target, introducing nitrogen, controlling the working pressure to be a certain specific value between 0.1 and 10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn on the Cr-Al cathode target, a radial magnetic field Bt on a Cr-Al cathode target plane and an arc runway tangential magnetic field Br perpendicular to the radial magnetic field on the Cr-Al cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating for a certain specific time length between 30 and 60 minutes on a household cutter to obtain a plating bonding layer on the surface of the household cutter;
And then selecting a Cr-Al-B cathode target, introducing argon, controlling the working pressure to be a specific value between 1 and 10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn on the Cr-Al-B cathode target, a radial magnetic field Bt on a Cr-Al-B cathode target plane and an arc runway tangential magnetic field Br perpendicular to the radial magnetic field on the Cr-Al-B cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a specific value not more than 200V as shown in a drawing 2, switching on an ion plating arc source, controlling a specific value between 50 and 400A of working current, and performing arc ion plating on a household cutter for a specific time length between 30 and 120 minutes to obtain the household cutter with an ion plating functional layer on the surface of the household cutter.
In the embodiment, the permanent magnetic field mode of the cathode arc ion plating machine is selected by controlling the permanent magnet arrangement structure, namely, the permanent magnet arrangement structure in the cathode arc ion plating machine is designed, so that the distribution state of the magnetic field intensity of the permanent magnetic field mode constructed by the permanent magnet arrangement structure is obviously different from that of the target surface magnetic field constructed by the traditional double-ring permanent magnet as shown in any one of figures 3-10, and the electromagnetic field mode is realized by controlling the waveform of the electromagnetic coil scanning voltage, wherein the waveform of the scanning voltage is at least one of triangular wave, square wave, trapezoidal wave or sine wave, the frequency is 5-40 Hz, the duty ratio range is 50-100%, and the corresponding coil voltage range is-40V.
According to the embodiment, by controlling the energy of the coating ions and the size of the metal liquid drops, the increase of the angle of the cutting edge caused by ion bombardment sputtering in the ion cleaning and coating processes and the increase of the angle of the cutting edge caused by the film deposition rate of the cutting edge changed by the sharp angle effect generated by the negative bias at the cutting edge in the deposition process are reduced, so that the damage to the cutting edge of the household cutter caused by etching cleaning and coating by using a cathodic arc ion plating technology is avoided as much as possible, and the initial sharpness (ICP) and sharpness retention (TCC) of the prepared household cutter with ultra-long sharpness retention are above 100mm and above 2000 mm.
Example 3
Embodiment 3 of the application provides a method for preparing a household cutter with ultra-long sharpness retention by using arc ion plating, which comprises the steps of pretreatment of the household cutter, ion etching and cleaning of the household cutter and arc ion plating of the household cutter.
The household cutter pretreatment step comprises the steps of preparing a household cutter with a machined and cut edge, and applying ultrasonic waves to clean the household cutter.
And (3) carrying out ion etching cleaning on the household cutter, namely hanging the ultrasonically cleaned household cutter on a rotating frame, putting the rotating frame into a vacuum chamber of an ion plating machine, vacuumizing to 5 multiplied by 10 -3 Pa, heating to a certain temperature of not more than 550 ℃, selecting a correct negative bias parameter, regulating the negative bias to a certain specific value of not more than 500V, switching on an arc source special for an etching device to control a certain specific value of 50-400A of working current, regulating the flow of argon and hydrogen in a gas mixer, controlling the working pressure of the vacuum chamber to a certain specific value of 0.2-10 Pa, continuously changing or fixing the partial pressure of hydrogen to a certain value, and carrying out ion etching on the household cutter for a certain specific time length of 30-120 minutes to obtain the cleaned household cutter matrix.
The steps of the household cutter arc ion plating comprise:
Turning off a power supply of an ion etching system, selecting a Ti-Al cathode target, introducing nitrogen, controlling the working pressure to be a certain specific value between 0.1 and 10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn on the Ti-Al cathode target, a radial magnetic field Bt on a Ti-Al cathode target plane and an arc runway tangential magnetic field Br perpendicular to the radial magnetic field on the Ti-Al cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V as shown in figure 2, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating for a certain specific time length between 30 and 60 minutes on a household cutter to obtain a plating bonding layer on the surface of the household cutter;
Then selecting a Ti-Si cathode target, introducing nitrogen, controlling the working pressure to be a certain specific value between 0.5 and 5 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn, a radial magnetic field Bt on a Ti-Si cathode target plane and an arc track tangential magnetic field Br perpendicular to the radial magnetic field on the Ti-Si cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating for a certain specific time length between 30 and 120 minutes on a household cutter to obtain the household cutter with an ion plating functional layer on the surface of the household cutter, thereby obtaining the household cutter with ultra-long sharpness retention;
In the embodiment, the permanent magnetic field mode of the cathode arc ion plating machine is selected by controlling the permanent magnet arrangement structure, namely, the permanent magnet arrangement structure in the cathode arc ion plating machine is designed, so that the waveform curve of the intensity of the permanent magnetic field mode magnetic field constructed by the permanent magnet arrangement structure is shown in any one of figures 3-10, the distribution states of the intensity of the vertical target surface magnetic field and the intensity of the parallel target surface magnetic field are obviously different from those of the target surface magnetic field constructed by the traditional double-ring permanent magnet, the electromagnetic field mode is realized by controlling the waveform of the electromagnetic coil scanning voltage, the scanning waveform is at least one of triangular wave, square wave trapezoidal wave or sine wave, the frequency is 1-40 Hz, the duty ratio range is 50-100%, and the corresponding coil voltage range is-40-50V.
According to the embodiment, by controlling the energy of the coating ions and the size of the metal liquid drops, the increase of the angle of the cutting edge caused by ion bombardment sputtering in the ion cleaning and coating processes and the increase of the angle of the cutting edge caused by the film deposition rate of the cutting edge changed by the sharp angle effect generated by the negative bias at the cutting edge in the deposition process are reduced, so that the damage to the cutting edge of the household cutter caused by etching cleaning and coating by using a cathodic arc ion plating technology is avoided as much as possible, and the initial sharpness (ICP) and sharpness retention (TCC) of the prepared household cutter with ultra-long sharpness retention are above 100mm and above 1500 mm.
Example 4
Embodiment 4 of the application provides a method for preparing a household cutter with ultra-long sharpness retention by using arc ion plating, which comprises the steps of pretreatment of the household cutter, ion etching and cleaning of the household cutter and arc ion plating of the household cutter.
The household cutter pretreatment step comprises the steps of preparing a household cutter with a machined and cut edge, and applying ultrasonic waves to clean the household cutter.
And (3) carrying out ion etching cleaning on the household cutter, namely hanging the ultrasonically cleaned household cutter on a rotating frame, putting the rotating frame into a vacuum chamber of an ion plating machine, vacuumizing to 5 multiplied by 10 -3 Pa, heating to a certain temperature of not more than 550 ℃, selecting a correct negative bias parameter, regulating the negative bias to a certain specific value of not more than 500V, switching on an arc source special for an etching device to control a certain specific value of 50-400A of working current, regulating the flow of argon and hydrogen in a gas mixer, controlling the working pressure of the vacuum chamber to a certain specific value of 0.5-10 Pa, continuously changing or fixing the partial pressure of hydrogen to a certain value of not more than 100%, and carrying out ion etching on the household cutter for a certain specific time length of 30-120 minutes to obtain the cleaned household cutter matrix.
The steps of the household cutter arc ion plating comprise:
Turning off a power supply of an ion etching system, selecting a Cr-Al cathode target, introducing nitrogen, controlling the working pressure to be a certain specific value between 0.1 and 10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn on the Cr-Al cathode target, a radial magnetic field Bt on a Cr-Al cathode target plane and an arc runway tangential magnetic field Br perpendicular to the radial magnetic field on the Cr-Al cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating for a certain specific time length between 30 and 60 minutes on a household cutter to obtain a plating bonding layer on the surface of the household cutter;
then selecting a Ti-Si cathode target, introducing nitrogen, controlling the working pressure to be a certain specific value between 0.5 and 5 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn, a radial magnetic field Bt on a Ti-Si cathode target plane and an arc track tangential magnetic field Br perpendicular to the radial magnetic field on the Ti-Si cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V as shown in a figure 2, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating on a household cutter for a certain specific time length between 30 and 120 minutes to obtain an ion plating transition layer on the surface of the household cutter;
And then selecting a Ti-Si cathode target, introducing nitrogen and acetylene, controlling the partial pressure of the acetylene gas to be a specific value within a range of not more than 50% or continuously changing, controlling the working pressure to be a specific value within a range of 1-10 Pa, applying a vertical magnetic field Bn on the Ti-Si cathode target, a radial magnetic field Bt on a Ti-Si cathode target plane and an arc runway tangential magnetic field Br perpendicular to the radial magnetic field on the Ti-Si cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a specific value within a range of not more than 200V, switching on an ion plating arc source, controlling the specific value within a range of 50-400A of working current, performing arc ion plating for a specific time length within a range of 30-120 Pa on the household cutter, and obtaining the household cutter with an ion plating functional layer Ti-Si-C-N on the surface of the household cutter.
In the embodiment, the permanent magnetic field mode of the cathode arc ion plating machine is selected by controlling the permanent magnet structure, namely, the permanent magnet arrangement structure in the cathode arc ion plating machine is designed, so that the permanent magnetic field mode magnetic field intensity waveform curve constructed by the permanent magnet arrangement structure is shown in any one of figures 3-10, the distribution states of the vertical target surface magnetic field intensity and the parallel target surface magnetic field intensity are obviously different from those of the target surface magnetic field constructed by the traditional double-ring permanent magnet, the electromagnetic field mode is realized by controlling the waveform of the electromagnetic coil scanning voltage, the waveform of the scanning voltage is selected from at least one of triangular wave, square wave, trapezoidal wave or sine wave, the frequency is 5-50 Hz, the duty ratio range is 50-100%, and the corresponding coil voltage range is-50-40V.
According to the embodiment, by controlling the energy of the coating ions and the size of the metal liquid drops, the increase of the angle of the cutting edge caused by ion bombardment sputtering in the ion cleaning and coating processes and the increase of the angle of the cutting edge caused by the film deposition rate of the cutting edge changed by the sharp angle effect generated by the negative bias at the cutting edge in the deposition process are reduced, so that the damage to the cutting edge of the household cutter caused by etching cleaning and coating by using a cathodic arc ion plating technology is avoided as much as possible, and the initial sharpness (ICP) and sharpness retention (TCC) of the prepared household cutter with ultra-long sharpness retention are above 100mm and above 1500 mm.
Example 5
Embodiment 5 of the application provides a method for preparing a household cutter with ultra-long sharpness retention by using arc ion plating, which comprises the steps of pretreatment of the household cutter, ion etching and cleaning of the household cutter and arc ion plating of the household cutter.
The household cutter pretreatment step comprises the steps of preparing a household cutter with a machined and cut edge, and applying ultrasonic waves to clean the household cutter.
And (3) carrying out ion etching cleaning on the household cutter, namely hanging the ultrasonically cleaned household cutter on a rotating frame, putting the rotating frame into a vacuum chamber of an ion plating machine, vacuumizing to 5 multiplied by 10 -3 Pa, heating to a certain temperature of not more than 550 ℃, selecting a correct negative bias parameter, adjusting the negative bias to a certain specific value of not more than 500V, switching on an arc source special for an etching device to control a certain specific value of 50-400 amperes of working current, adjusting the flow of argon and hydrogen in a gas mixer, controlling the working pressure of the vacuum chamber to a certain specific value of 0.2-10 Pa, and carrying out ion etching on the household cutter for a certain specific time length of 30-120 minutes to obtain the cleaned household cutter matrix.
The steps of the household cutter arc ion plating comprise:
Turning off a power supply of an ion etching system, selecting a Cr-Al cathode target, introducing nitrogen, controlling the working pressure to be a certain specific value between 0.1 and 10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn on the Cr-Al cathode target, a radial magnetic field Bt on a Cr-Al cathode target plane and an arc runway tangential magnetic field Br perpendicular to the radial magnetic field on the Cr-Al cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating for a certain specific time length between 30 and 60 minutes on a household cutter to obtain a plating bonding layer on the surface of the household cutter;
Then selecting a Cr-Al-Si cathode target, introducing nitrogen, controlling the working pressure to be a certain specific value between 1 and 10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn on the Cr-Al-Si cathode target, a radial magnetic field Bt on a Cr-Al-Si cathode target plane and an arc runway tangential magnetic field Br perpendicular to the radial magnetic field on the Cr-Al-Si cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V as shown in figure 2, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating for a certain specific time length between 30 and 120 minutes on a household cutter to obtain the household cutter with the ion plating functional layer Cr-Al-Si-N on the surface of the household cutter, thereby obtaining the super-length sharpness maintaining household cutter.
In the embodiment, the permanent magnetic field mode of the cathode arc ion plating machine is selected by controlling the permanent magnet structure, namely, the permanent magnet arrangement structure in the cathode arc ion plating machine is designed, so that the permanent magnetic field mode magnetic field intensity waveform curve constructed by the permanent magnet arrangement structure is shown in any one of figures 3-10, the distribution states of the vertical target surface magnetic field intensity and the parallel target surface magnetic field intensity are obviously different from those of the target surface magnetic field constructed by the traditional double-ring permanent magnet, the electromagnetic field mode is realized by controlling the waveform of the electromagnetic coil scanning voltage, the waveform of the scanning voltage is selected from at least one of triangular wave, square wave, trapezoidal wave or sine wave, the frequency is 2-50 Hz, the duty ratio range is 50-100%, and the corresponding coil voltage range is-45V.
According to the embodiment, by controlling the energy of the coating ions and the size of the metal liquid drops, the increase of the angle of the cutting edge caused by ion bombardment sputtering in the ion cleaning and coating processes and the increase of the angle of the cutting edge caused by the film deposition rate of the cutting edge changed by the sharp angle effect generated by the negative bias at the cutting edge in the deposition process are reduced, so that the damage to the cutting edge of the household cutter caused by etching cleaning and coating by using a cathodic arc ion plating technology is avoided as much as possible, and the initial sharpness (ICP) and sharpness retention (TCC) of the prepared household cutter with ultra-long sharpness retention are above 100mm and above 2000 mm.
Example 6
Embodiment 6 of the application provides a method for preparing a household cutter with ultra-long sharpness retention by using arc ion plating, which comprises the steps of pretreatment of the household cutter, ion etching and cleaning of the household cutter and arc ion plating of the household cutter.
The household cutter pretreatment step comprises the steps of preparing a household cutter with a machined and cut edge, and applying ultrasonic waves to clean the household cutter.
And (3) carrying out ion etching cleaning on the household cutter, namely hanging the ultrasonically cleaned household cutter on a rotating frame, putting the rotating frame into a vacuum chamber of an ion plating machine, vacuumizing to 5 multiplied by 10 -3 Pa, heating to a certain temperature of not more than 550 ℃, selecting a correct negative bias parameter, regulating the negative bias to a certain specific value of not more than 500V, switching on an arc source special for an etching device to control a certain specific value of 50-400A of working current, regulating the flow of argon and hydrogen in a gas mixer, controlling the working pressure of the vacuum chamber to a certain specific value of 0.2-10 Pa, continuously changing or fixing the partial pressure of hydrogen to a certain value, and carrying out ion etching on the household cutter for a certain specific time length of 30-120 minutes to obtain the cleaned household cutter matrix.
The steps of the household cutter arc ion plating comprise:
Turning off a power supply of an ion etching system, selecting a Ti cathode target, introducing nitrogen, controlling the working pressure to be a certain specific value between 0.1 and 10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn on the Ti cathode target, a radial magnetic field Bt on a Ti cathode target plane and an arc runway tangential magnetic field Br perpendicular to the radial magnetic field on the Ti cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating for a certain specific time length between 30 and 60 minutes on a household cutter to obtain a plating bonding layer on the surface of the household cutter;
Then selecting a Ti-Al cathode target, introducing nitrogen, controlling the working pressure to be a specific value between 1 and 10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn on the Ti-Al cathode target, a radial magnetic field Bt on a Ti-Al cathode target plane and an arc track tangential magnetic field Br perpendicular to the radial magnetic field on the Ti-Al cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a specific value not more than 200V, switching on an ion plating arc source, controlling the specific value between 50 and 400A of working current, and performing arc ion plating for a specific time length between 30 and 120 minutes on a household cutter to obtain the household cutter with the ultra-long sharpness retention.
In the embodiment, the permanent magnetic field mode of the cathode arc ion plating machine is selected by controlling the permanent magnet structure, namely, the permanent magnet arrangement structure in the cathode arc ion plating machine is designed, the distribution state of the vertical target surface magnetic field intensity and the parallel target surface magnetic field intensity is obviously different from the target surface magnetic field constructed by the traditional double-ring permanent magnet, so that the waveform curve of the permanent magnetic field mode magnetic field intensity constructed by the permanent magnet arrangement structure is shown as any drawing in figures 3-10, the distribution state of the vertical target surface magnetic field intensity and the parallel target surface magnetic field intensity is obviously different from the target surface magnetic field constructed by the traditional double-ring permanent magnet, the electromagnetic field mode is realized by controlling the waveform of the electromagnetic coil scanning voltage, the waveform of the scanning voltage is selected from at least one of triangular wave, square wave, trapezoidal wave or sine wave, the frequency is 5-50 Hz, the duty ratio range is 50-100%, and the corresponding coil voltage range is-40-45V.
According to the embodiment, by controlling the energy of the coating ions and the size of the metal liquid drops, the increase of the angle of the cutting edge caused by ion bombardment sputtering in the ion cleaning and coating processes and the increase of the angle of the cutting edge caused by the film deposition rate of the cutting edge changed by the sharp angle effect generated by the negative bias at the cutting edge in the deposition process are reduced, so that the damage to the cutting edge of the household cutter caused by etching cleaning and coating by using a cathodic arc ion plating technology is avoided as much as possible, and the initial sharpness (ICP) and sharpness retention (TCC) of the prepared household cutter with ultra-long sharpness retention are above 100mm and above 1500 mm.
Example 7
Embodiment 7 of the application provides a method for preparing a household cutter with ultra-long sharpness retention by using arc ion plating, which comprises the steps of pretreatment of the household cutter, ion etching and cleaning of the household cutter and arc ion plating of the household cutter.
The household cutter pretreatment step comprises the steps of preparing a household cutter with a machined and cut edge, and applying ultrasonic waves to clean the household cutter.
And (3) carrying out ion etching cleaning on the household cutter, namely hanging the ultrasonically cleaned household cutter on a rotating frame, putting the rotating frame into a vacuum chamber of an ion plating machine, vacuumizing to 5 multiplied by 10 -3 Pa, heating to a certain temperature of not more than 550 ℃, selecting a correct negative bias parameter, regulating the negative bias to a certain specific value of not more than 500V, switching on an arc source special for an etching device to control a certain specific value of 50-400A of working current, regulating the flow of argon and hydrogen in a gas mixer, controlling the working pressure of the vacuum chamber to a certain specific value of 0.5-10 Pa, continuously changing or fixing the partial pressure of hydrogen to a certain value, and carrying out ion etching on the household cutter for a certain specific time length of 30-120 minutes to obtain the cleaned household cutter matrix.
The steps of the household cutter arc ion plating comprise:
Turning off a power supply of an ion etching system, selecting a Ti cathode target, introducing argon, controlling the working pressure to be a certain specific value between 0.1 and 10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn on the Ti cathode target, a radial magnetic field Bt on a Ti cathode target plane and an arc runway tangential magnetic field Br perpendicular to the radial magnetic field on the Ti cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating for a certain specific time length between 30 and 60 minutes on a household cutter to obtain a plating bonding layer on the surface of the household cutter;
then selecting a Ti cathode target, introducing nitrogen, controlling the working pressure to be a certain specific value between 0.5 and 5 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn, a radial magnetic field Bt on a Ti cathode target plane and an arc track tangential magnetic field Br perpendicular to the radial magnetic field on the Ti cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating for a certain specific time length between 30 and 120 minutes on a household cutter to obtain an ion plating transition layer Ti-N plated on the surface of the household cutter;
And then selecting a Ti cathode target, introducing nitrogen and acetylene, wherein the partial pressure of the acetylene gas is in a certain specific value or continuously changes within a range of not more than 50%, controlling the working pressure to be in a certain specific value within 1-10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn, a radial magnetic field Bt on a Ti cathode target plane and an arc spot runway tangential magnetic field Br perpendicular to the radial magnetic field on the Ti cathode target plane on the Ti cathode target, selecting a correct negative bias parameter, regulating the negative bias to be in a certain specific value within a range of not more than 200V as shown in a figure 2, switching on an ion plating arc source, controlling the working current to be in a certain specific value within a range of 50-400 Pa, and performing arc ion plating for a certain specific time length within 30-120 minutes on a household cutter to obtain the household cutter with an ion plating functional layer Ti-C-N on the surface of the household cutter, thereby obtaining the household cutter with ultra-sharpness maintaining force.
In the embodiment, the permanent magnetic field mode of the cathode arc ion plating machine is selected by controlling the permanent magnet structure, namely, the permanent magnet arrangement structure in the cathode arc ion plating machine is designed, so that the permanent magnetic field mode magnetic field intensity waveform curve constructed by the permanent magnet arrangement structure is shown in any one of figures 3-10, the distribution states of the vertical target surface magnetic field intensity and the parallel target surface magnetic field intensity are obviously different from those of the target surface magnetic field constructed by the traditional double-ring permanent magnet, the electromagnetic field mode is realized by controlling the waveform of the electromagnetic coil scanning voltage, the waveform of the scanning voltage is selected from at least one of triangular wave, square wave, trapezoidal wave or sine wave, the frequency is 2-40 Hz, the duty ratio range is 50-100%, and the corresponding coil voltage range is-40-45V.
According to the embodiment, by controlling the energy of the coating ions and the size of the metal liquid drops, the increase of the angle of the cutting edge caused by ion bombardment sputtering in the ion cleaning and coating processes and the increase of the angle of the cutting edge caused by the film deposition rate of the cutting edge changed by the sharp angle effect generated by the negative bias at the cutting edge in the deposition process are reduced, so that the damage to the cutting edge of the household cutter caused by etching cleaning and coating by using a cathodic arc ion plating technology is avoided as much as possible, and the initial sharpness (ICP) and sharpness retention (TCC) of the prepared household cutter with ultra-long sharpness retention are above 100mm and above 1500 mm.
Example 8
Embodiment 8 of the application provides a method for preparing a household cutter with ultra-long sharpness retention by using arc ion plating, which comprises the steps of pretreatment of the household cutter, ion etching and cleaning of the household cutter and arc ion plating of the household cutter.
The household cutter pretreatment step comprises the steps of preparing a household cutter with a machined and cut edge, and applying ultrasonic waves to clean the household cutter.
And (3) carrying out ion etching cleaning on the household cutter, namely hanging the ultrasonically cleaned household cutter on a rotating frame, putting the rotating frame into a vacuum chamber of an ion plating machine, vacuumizing to 5 multiplied by 10 -3 Pa, heating to a certain temperature of not more than 550 ℃, selecting a correct negative bias parameter, regulating the negative bias to a certain specific value of not more than 500V, switching on an arc source special for an etching device to control a certain specific value of 50-400A of working current, regulating the flow of argon and hydrogen in a gas mixer, controlling the working pressure of the vacuum chamber to a certain specific value of 0.5-10 Pa, continuously changing or fixing the partial pressure of hydrogen to a certain value, and carrying out ion etching on the household cutter for a certain specific time length of 30-120 minutes to obtain the cleaned household cutter matrix.
The steps of the household cutter arc ion plating comprise:
Turning off a power supply of an ion etching system, selecting a Cr cathode target, introducing argon, controlling the working pressure to be a certain specific value between 0.1 and 10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn on the Cr cathode target, a radial magnetic field Bt on a Cr cathode target plane and an arc runway tangential magnetic field Br on the Cr cathode target plane, which is perpendicular to the radial magnetic field, selecting a correct negative bias parameter, adjusting the negative bias to be a certain specific value not more than 200V, switching on an ion plating arc source, controlling a certain specific value between 50 and 400A of working current, and performing arc ion plating for a certain specific time length between 30 and 60 minutes on a household cutter to obtain a plating bonding layer on the surface of the household cutter;
Then selecting a Cr cathode target, introducing nitrogen, controlling the working pressure to be a specific value between 0.5 and 5 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn on the Cr cathode target, a radial magnetic field Bt on a Cr cathode target plane and an arc track tangential magnetic field Br perpendicular to the radial magnetic field on the Cr cathode target plane, selecting a correct negative bias parameter, adjusting the negative bias to be a specific value not more than 200V, switching on an ion plating arc source, controlling a specific value between 50 and 400A of working current, and performing arc ion plating for a specific time length between 30 and 120 minutes on a household cutter to obtain an ion plating transition layer Cr-N plated on the surface of the household cutter, wherein the negative bias parameter is shown in the figure 2;
Then selecting a Cr cathode target, introducing nitrogen and acetylene, controlling the partial pressure of the acetylene gas to be a specific value within a range of not more than 50% or continuously changing, controlling the working pressure to be a specific value within a range of 1-10 Pa, selecting a permanent magnetic field mode and an electromagnetic field mode of a cathode arc ion plating machine, applying a vertical magnetic field Bn, a radial magnetic field Bt on a Cr cathode target plane and an arc spot runway tangential magnetic field Br perpendicular to the radial magnetic field on the Cr cathode target plane on the Cr cathode target, selecting a correct negative bias parameter, regulating the negative bias to be a specific value within a range of not more than 200V as shown in a figure 2, switching on an ion plating arc source, controlling the working current to be a specific value within a range of 50-400 Pa, and performing arc ion plating for a specific time length of 30-120 min on a household cutter to obtain the household cutter with an ion plating functional layer Cr-C-N on the surface of the household cutter, thereby obtaining the household cutter with ultra-sharpness retention.
In the embodiment, the permanent magnetic field mode of the cathode arc ion plating machine is selected by controlling the permanent magnet structure, namely, the permanent magnet arrangement structure in the cathode arc ion plating machine is designed, so that the waveform curve of the intensity of the permanent magnetic field mode magnetic field constructed by the permanent magnet arrangement structure is shown in any one of figures 3-10, the distribution states of the intensity of the vertical target surface magnetic field and the intensity of the parallel target surface magnetic field are obviously different from those of the target surface magnetic field constructed by the traditional double-ring permanent magnet, the electromagnetic field mode is realized by controlling the waveform of the electromagnetic coil scanning voltage, the waveform of the scanning voltage is at least one of triangular wave, square wave trapezoidal wave or sine wave, the frequency is 2-50 Hz, the duty ratio range is 50-100%, and the corresponding coil voltage range is-45-50V.
According to the embodiment, by controlling the energy of the coating ions and the size of the metal liquid drops, the increase of the angle of the cutting edge caused by ion bombardment sputtering in the ion cleaning and coating processes and the increase of the angle of the cutting edge caused by the film deposition rate of the cutting edge changed by the sharp angle effect generated by the negative bias at the cutting edge in the deposition process are reduced, so that the damage to the cutting edge of the household cutter caused by etching cleaning and coating by using a cathodic arc ion plating technology is avoided as much as possible, and the initial sharpness (ICP) and sharpness retention (TCC) of the prepared household cutter with ultra-long sharpness retention are above 100mm and above 1500 mm.
Experimental example 1
The performance test of the ultra-long sharpness maintaining household cutter and the ultrasonic-cleaned household cutter provided in the embodiment 1 is carried out according to the EN ISO 8442-5.2005 standard of European Union, and the test results are shown in fig. 12 and 13.
As is apparent from comparing the attached drawings 12 and 13, the initial sharpness (ICP) of the cutter which is not subjected to arc ion plating is 129.4mm, but the sharpness maintaining force (TCC) is only 934.5mm, while the initial sharpness (ICP) of the cutter is slightly reduced, but the sharpness maintaining force (TCC) of the household cutter is multiplied to 2325.7mm, the sharpness maintaining force is improved by 249%, and as shown in the attached drawings 11, the arc spots of the target surface are regular and approximately circular, the preparation method provided by the embodiment 1 of the application enhances the control of the arc spots on the target surface of the cathode by introducing a planar runway tangential magnetic field on the target surface of the cathode, so that the stability of the arc spots is improved, arc extinction is difficult, the movement speed of the arc spots is faster, the target surface temperature is lower, a large number of high-temperature points are difficult to appear on the target surface, metal drops sprayed out from the arc spots are reduced and deposited on a film plating film, the large particle pollution of the film layer of the household cutter by plasma is reduced, and thus the sharpness maintaining force (TCC) of the household cutter is improved, and the arc spots of the cutter is not attenuated by the conventional magnetic field of the arc machine, as shown in the attached drawings 1, and the arc surface of the arc surface has a sharp magnetic field is generally perpendicular to the arc surface of the arc surface.
Meanwhile, as shown in figures 3-10, particularly in figure 3, the position where the vertical magnetic field component Bn is equal to 0 is about 4-5cm, so that the arcing point of the arc spot is easier to approach the target center, the radius of the motion track of the arc spot can be wider, the arc spot cannot be limited to the edge of the target surface, the target surface is etched more uniformly, and the utilization rate of the cathode target is improved.
Although the present application has been described in detail with reference to the foregoing embodiments, those skilled in the art will understand that the technical solutions described in the foregoing embodiments may be modified or some or all of the technical features may be equivalently replaced, and these modifications or replacements do not depart from the spirit of the technical solutions of the embodiments of the present application.