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CN118813223A - Foam plugging slurry, preparation method of foam plugging slurry, foam plugging slurry system and application - Google Patents

Foam plugging slurry, preparation method of foam plugging slurry, foam plugging slurry system and application Download PDF

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Publication number
CN118813223A
CN118813223A CN202310435016.4A CN202310435016A CN118813223A CN 118813223 A CN118813223 A CN 118813223A CN 202310435016 A CN202310435016 A CN 202310435016A CN 118813223 A CN118813223 A CN 118813223A
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parts
slurry
cement
plugging slurry
foam
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CN118813223B (en
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张晋凯
周仕明
丁士东
初永涛
肖京男
张林海
李鹏程
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China Petroleum and Chemical Corp
Sinopec Petroleum Engineering Technology Research Institute Co Ltd
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China Petroleum and Chemical Corp
Sinopec Petroleum Engineering Technology Research Institute Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/42Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
    • C09K8/426Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells for plugging
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/42Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
    • C09K8/46Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement
    • C09K8/467Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement containing additives for specific purposes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/42Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
    • C09K8/46Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement
    • C09K8/467Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement containing additives for specific purposes
    • C09K8/473Density reducing additives, e.g. for obtaining foamed cement compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00724Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Structural Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to the field of petroleum drilling, and discloses foam plugging slurry, a preparation method of the foam plugging slurry, a foam plugging slurry system and application, wherein the foam plugging slurry comprises the following components: cement-based slurries, foaming agents and nitrogen gas filling; wherein the foaming agent is not more than 5 parts by weight relative to 100 parts by weight of the cement-based slurry; the amount of nitrogen added satisfies that the density of the foam plugging slurry is reduced by 3-30% by volume compared to cement-based slurry. The foam plugging slurry disclosed by the invention can flexibly adjust the density according to the inflation proportion, and is suitable for on-site changeable leakage well conditions.

Description

泡沫堵漏浆及泡沫堵漏浆的制备方法、泡沫堵漏浆体系及 应用Foam plugging slurry, preparation method of foam plugging slurry, foam plugging slurry system and application

技术领域Technical Field

本发明涉及石油钻探领域,具体涉及一种泡沫堵漏浆及泡沫堵漏浆的制备方法、泡沫堵漏浆体系及应用。The invention relates to the field of petroleum drilling, and in particular to a foam plugging slurry, a preparation method of the foam plugging slurry, a foam plugging slurry system and applications.

背景技术Background Art

在石油钻井及固井过程中会经常遇到井漏现象,导致钻井液及其他工作液白白大量漏失到地层中,除此之外进行堵漏和堵漏后的承压也要花费较多的时间,这些都使钻井成本大大增加。Well leakage is often encountered during the oil drilling and cementing process, resulting in a large amount of drilling fluid and other working fluids being lost into the formation. In addition, it takes a long time to plug the leak and withstand the pressure after plugging, which greatly increases the drilling cost.

通常堵漏作业是将含有不同粒径堵漏粒子的一定浓度的堵漏浆泵送至漏失层,通过静置堵漏、憋压堵漏或是随钻堵漏等工艺措施逐步封堵漏失层,当地层漏失速度超过一定规模后(恶性漏失甚至失返),上述堵漏效果就大打折扣,甚至完全不起作用。Usually, the plugging operation is to pump a certain concentration of plugging slurry containing plugging particles of different particle sizes into the leakage layer, and gradually plug the leakage layer through static plugging, pressure-holding plugging or while drilling plugging. When the leakage rate of the local formation exceeds a certain scale (malignant leakage or even loss return), the above plugging effect will be greatly reduced or even completely ineffective.

常规堵漏浆进入地层后,在地层压力的作用下,因密度过大在漏层位置无法停留,在漏层处发生漏失,堵漏失败。为了解决在承压能力较低地层水泥塞留不住的难题,就要尽可能降低水泥塞的密度,一般常规水泥塞受限于减轻材料和入井浆体性能要求,保持浆体具有一定的低密度的同时难以兼顾浆体的各项性能,导致目前入井堵漏水泥浆的密度无法足够低。After conventional plugging slurry enters the formation, it cannot stay at the leaking layer due to its high density under the influence of formation pressure, and leakage occurs at the leaking layer, resulting in plugging failure. In order to solve the problem that cement plugs cannot be retained in formations with low pressure bearing capacity, the density of cement plugs must be reduced as much as possible. Conventional cement plugs are generally limited by the requirements of lightening materials and performance of the slurry entering the well. It is difficult to take into account the various properties of the slurry while maintaining a certain low density of the slurry, resulting in the current density of the cement slurry entering the well not being low enough.

CN103074042A公开了一种钻井液和一种钻井液的制备方法,公开了依靠化学药剂反应的化学发泡法生成氮气泡沫,受混配工艺限制,与其他浆体的配伍性限制,发泡量和稳泡性能也受到限制。CN103074042A discloses a drilling fluid and a method for preparing the drilling fluid, and discloses a chemical foaming method that relies on chemical agent reaction to generate nitrogen foam. The method is limited by the mixing process and the compatibility with other slurries, and the foaming amount and foam stabilization performance are also limited.

因此有必要针对有明显漏失的漏层专门设计一种堵漏浆,配合一定的堵漏工艺来达到良好的封堵效果。Therefore, it is necessary to design a plugging slurry specifically for the leaking layer with obvious leakage, and cooperate with a certain plugging process to achieve a good plugging effect.

发明内容Summary of the invention

本发明的目的是为了克服现有技术存在的常规堵漏浆堵漏效果不理想的问题,提供一种泡沫堵漏浆及泡沫堵漏浆的制备方法、泡沫堵漏浆体系及应用,该泡沫堵漏浆具有气液固三相流,配方简单可靠、使用方便,满足浆体低密度的同时兼顾浆体的各项性能。The purpose of the present invention is to overcome the problem that conventional plugging slurries in the prior art have unsatisfactory plugging effects, and to provide a foam plugging slurry and a preparation method of the foam plugging slurry, a foam plugging slurry system and an application. The foam plugging slurry has a gas-liquid-solid three-phase flow, a simple and reliable formula, and is easy to use. It meets the low density of the slurry while taking into account various properties of the slurry.

为了实现上述目的,本发明第一方面提供一种泡沫堵漏浆,所述泡沫堵漏浆包括:水泥基浆、泡沫剂和填充的氮气;In order to achieve the above-mentioned object, the first aspect of the present invention provides a foam plugging slurry, wherein the foam plugging slurry comprises: a cement-based slurry, a foaming agent and filled nitrogen;

其中,相对于100重量份的水泥基浆,所述泡沫剂为不大于5重量份;所述填充的氮气以体积量计,加入的氮气量满足所述泡沫堵漏浆的密度相比于水泥基浆下降了3-30%。Among them, relative to 100 parts by weight of cement-based slurry, the foaming agent is no more than 5 parts by weight; the filled nitrogen is calculated by volume, and the amount of nitrogen added satisfies that the density of the foam plugging slurry is reduced by 3-30% compared with the cement-based slurry.

本发明第二方面提供一种泡沫堵漏浆的制备方法,其中,包括以下步骤:A second aspect of the present invention provides a method for preparing a foam plugging slurry, which comprises the following steps:

(1)配制水泥基浆;(1) Prepare cement-based slurry;

(2)向水泥基浆内加入泡沫剂搅拌均匀,得到堵漏浆中间体;(2) adding a foaming agent to the cement-based slurry and stirring evenly to obtain a plugging slurry intermediate;

(3)向堵漏浆中间体充入气体,得到泡沫堵漏浆;(3) injecting gas into the plugging slurry intermediate to obtain foam plugging slurry;

其中,相对于100重量份的水泥基浆,所述泡沫剂为不大于5重量份;Wherein, relative to 100 parts by weight of cement-based slurry, the foaming agent is no more than 5 parts by weight;

优选地,所述填充的氮气以体积量计,加入的氮气量满足所述泡沫堵漏浆的密度相比于水泥基浆下降了3-30%。Preferably, the nitrogen filled is measured by volume, and the amount of nitrogen added is such that the density of the foam plugging slurry is reduced by 3-30% compared with the cement-based slurry.

本发明第三方面提供一种泡沫堵漏浆,所述泡沫堵漏浆由第二方面所述的制备方法制得。The third aspect of the present invention provides a foam plugging slurry, which is prepared by the preparation method described in the second aspect.

本发明第四方面提供一种前述泡沫堵漏浆体系,所述包括第一方面或第三方面所述的泡沫堵漏浆和可选的常规堵漏浆;The fourth aspect of the present invention provides the aforementioned foam plugging slurry system, comprising the foam plugging slurry described in the first aspect or the third aspect and optional conventional plugging slurry;

其中,相对于100重量份的所述泡沫堵漏浆,所述常规堵漏浆为不大于100重量份,优选为10-30重量份。Wherein, relative to 100 parts by weight of the foam plugging slurry, the conventional plugging slurry is no more than 100 parts by weight, preferably 10-30 parts by weight.

本发明第五方面提供一种前述泡沫堵漏浆或者前述的泡沫堵漏浆体系在页岩气井中的应用。A fifth aspect of the present invention provides an application of the aforementioned foam plugging slurry or the aforementioned foam plugging slurry system in a shale gas well.

通过上述技术方案,本发明所取得的有益技术效果如下:Through the above technical solution, the beneficial technical effects achieved by the present invention are as follows:

(1)本发明所述的泡沫堵漏浆根据充气比例能够灵活调节密度,适用于现场多变的漏失井况;(1) The foam plugging slurry of the present invention can flexibly adjust the density according to the inflation ratio, and is suitable for the variable leakage well conditions on site;

(2)本发明所述的泡沫堵漏浆具有独特的可压缩性,更易于进入漏层,堵漏效果优于常规堵漏浆;(2) The foam plugging slurry of the present invention has unique compressibility, is easier to enter the leaking layer, and has a better plugging effect than conventional plugging slurry;

(3)本发明所述的泡沫堵漏浆制备工艺简单,成本低廉。(3) The foam plugging slurry preparation process of the present invention is simple and low-cost.

具体实施方式DETAILED DESCRIPTION

在本文中所披露的范围的端点和任何值都不限于该精确的范围或值,这些范围或值应当理解为包含接近这些范围或值的值。对于数值范围来说,各个范围的端点值之间、各个范围的端点值和单独的点值之间,以及单独的点值之间可以彼此组合而得到一个或多个新的数值范围,这些数值范围应被视为在本文中具体公开。The endpoints and any values of the ranges disclosed in this article are not limited to the precise ranges or values, and these ranges or values should be understood to include values close to these ranges or values. For numerical ranges, the endpoint values of each range, the endpoint values of each range and the individual point values, and the individual point values can be combined with each other to obtain one or more new numerical ranges, which should be considered as specifically disclosed in this article.

本发明第一方面提供一种泡沫堵漏浆,所述泡沫堵漏浆包括:水泥基浆、泡沫剂和填充的氮气;A first aspect of the present invention provides a foam plugging slurry, the foam plugging slurry comprising: a cement-based slurry, a foaming agent and filled nitrogen;

其中,相对于100重量份的水泥基浆,所述泡沫剂为不大于5重量份;所述填充的氮气以体积量计,加入的氮气量满足所述泡沫堵漏浆的密度相比于水泥基浆下降了3-30%。Among them, relative to 100 parts by weight of cement-based slurry, the foaming agent is no more than 5 parts by weight; the filled nitrogen is calculated by volume, and the amount of nitrogen added satisfies that the density of the foam plugging slurry is reduced by 3-30% compared with the cement-based slurry.

根据本发明,优选地,所述填充的氮气以体积量计,加入的氮气量满足所述泡沫堵漏浆的密度相比于水泥基浆下降了5-20%。According to the present invention, preferably, the nitrogen filled is measured by volume, and the amount of nitrogen added is such that the density of the foam plugging slurry is reduced by 5-20% compared with the cement-based slurry.

在本发明中,气体体积受温度和压力控制,而该温度和压力又是由每口井的漏层段最高温度和漏失压力决定,所以需要氮气的体积为使得原水泥基浆密度下降3-30%(漏层段最高温度和漏失压力下)所需要的充氮量,优选原水泥基浆密度下降5-20%,据此温度和压力下所需氮气量,通过真实氮气状态方程反推出地面充氮设备的充氮量(一般称为施工充氮量)。In the present invention, the gas volume is controlled by temperature and pressure, and the temperature and pressure are determined by the maximum temperature and leakage pressure of the leaking layer section of each well. Therefore, the required volume of nitrogen is the amount of nitrogen required to reduce the density of the original cement-based slurry by 3-30% (under the maximum temperature and leakage pressure of the leaking layer section), and preferably the density of the original cement-based slurry is reduced by 5-20%. Based on the required amount of nitrogen at this temperature and pressure, the nitrogen charging amount of the ground nitrogen charging equipment (generally referred to as the construction nitrogen charging amount) is inversely deduced through the real nitrogen state equation.

本发明中,例如设定水泥基浆的密度为1.88g/cm3,漏层段最高温度为90℃,井漏失压力为35MPa,此温度和压力下水泥基浆密度降低3%-30%所需要的氮气充入体积为0.03-0.53份体积(以水泥基浆体积为基准),据此温压下所需充氮量,根据真实氮气状态方程反推得到地面充氮体积为7-124份体积(以水泥基浆体积为基准)。即得到相对于单位体积量的水泥基浆,地面充氮设备需要的施工充氮量为7-124体积份(以水泥基浆体积为基准),从而能够得到本发明需要的泡沫堵漏浆。In the present invention, for example, the density of cement slurry is set to 1.88g/ cm3 , the maximum temperature of the leaking layer is 90℃, and the well loss pressure is 35MPa. The nitrogen filling volume required to reduce the density of cement slurry by 3%-30% at this temperature and pressure is 0.03-0.53 parts by volume (based on the volume of cement slurry). Based on the required nitrogen filling amount under this temperature and pressure, the ground nitrogen filling volume is reversed according to the real nitrogen state equation to obtain 7-124 parts by volume (based on the volume of cement slurry). That is, relative to the unit volume of cement slurry, the construction nitrogen filling amount required by the ground nitrogen filling equipment is 7-124 parts by volume (based on the volume of cement slurry), so that the foam plugging slurry required by the present invention can be obtained.

根据本发明,所述泡沫剂为2-3重量份,所述泡沫剂为阴离子类表面活性剂发泡剂,优选选自十二烷基苯磺酸钠、α-烯烃磺酸盐、α-磺基脂肪酸甲酯和N-油酰基N-甲基牛磺酸钠中的至少一种。According to the present invention, the foaming agent is 2-3 parts by weight, and the foaming agent is an anionic surfactant foaming agent, preferably selected from at least one of sodium dodecylbenzene sulfonate, α-olefin sulfonate, α-sulfo fatty acid methyl ester and sodium N-oleoyl N-methyl taurate.

在本发明一些具体实施方式中,所述泡沫剂是起发泡和稳泡作用,所述泡沫剂在机械作用力引入气体的情况下,能有效降低液体表面张力,发泡倍数高、泡沫稳定性好,可长时间不消泡,泡沫细腻,与使用介质的相容性好。In some specific embodiments of the present invention, the foaming agent plays a role in foaming and stabilizing foam. When the foaming agent introduces gas by mechanical force, it can effectively reduce the surface tension of the liquid, has a high foaming multiple, good foam stability, can last for a long time without defoaming, has fine foam, and has good compatibility with the medium used.

本发明中,相较于采用化学药剂发泡,难以控制发泡量和发泡均匀程度,发泡多会破坏基浆的力学性能,发泡少不能满足发泡需求,本发明采用机械作用物理发泡,可以灵活应对不同应用条件。In the present invention, compared with the use of chemical agents for foaming, it is difficult to control the amount of foaming and the uniformity of foaming. Excessive foaming will destroy the mechanical properties of the base slurry, and insufficient foaming cannot meet the foaming requirements. The present invention uses mechanical physical foaming, which can flexibly respond to different application conditions.

根据本发明,所述水泥基浆以重量份计包括:水泥100份、降失水剂1-10份、缓凝剂0-3份、早强剂0-5份、增稠剂0-0.2份、水30-70份。According to the present invention, the cement-based slurry comprises, by weight: 100 parts of cement, 1-10 parts of fluid loss reducer, 0-3 parts of retarder, 0-5 parts of early strength agent, 0-0.2 parts of thickener, and 30-70 parts of water.

根据本发明,优选地,所述水泥基浆以重量份计包括:水泥100份、降失水剂3-8份、缓凝剂0.1-2份、早强剂0.25-1份、增稠剂0.05-0.1份、水35-60份。According to the present invention, preferably, the cement-based slurry comprises, by weight: 100 parts of cement, 3-8 parts of fluid loss reducer, 0.1-2 parts of retarder, 0.25-1 parts of early strength agent, 0.05-0.1 parts of thickener, and 35-60 parts of water.

本发明中,优选地,所述泡沫堵漏浆的密度为1.2-1.7g/cm3In the present invention, preferably, the density of the foam plugging slurry is 1.2-1.7 g/cm 3 .

本发明中,所述水泥为纯水泥和/或掺混有密度减轻材料的低密度灰。对掺混的密度减轻材料没有特别限定,可以为本领域中常规的密度减轻材料,优选地,选自漂珠、空心玻璃微珠、微硅和粉煤灰中的至少一种。In the present invention, the cement is pure cement and/or low-density ash mixed with density reducing materials. The mixed density reducing materials are not particularly limited and can be conventional density reducing materials in the art, preferably, at least one selected from floating beads, hollow glass microspheres, microsilica and fly ash.

本发明中,所述降失水剂为乳液类降失水剂和/或水溶性高分子聚合物降失水剂。采用上述降失水剂能够控制水泥浆中液相向渗透性边界滤失,从而保持水泥浆适当水灰比。In the present invention, the fluid loss agent is an emulsion fluid loss agent and/or a water-soluble high molecular polymer fluid loss agent. The use of the above fluid loss agent can control the loss of the liquid phase to the permeability boundary in the cement slurry, thereby maintaining an appropriate water-cement ratio of the cement slurry.

本发明中,所述乳液类降失水剂为胶乳体系降失水剂和/或树脂体系降失水剂,所述水溶性高分子聚合物降失水剂选自纤维素及其衍生物、丙烯酰胺及其衍生物和聚乙烯醇类降失水剂中的至少一种。优选地,所述降失水剂为丙烯酰胺和/或2-丙烯酰胺基-2-甲基丙磺酸。In the present invention, the emulsion fluid loss agent is a latex system fluid loss agent and/or a resin system fluid loss agent, and the water-soluble polymer fluid loss agent is at least one selected from cellulose and its derivatives, acrylamide and its derivatives, and polyvinyl alcohol fluid loss agents. Preferably, the fluid loss agent is acrylamide and/or 2-acrylamido-2-methylpropanesulfonic acid.

本发明中,所述早强剂选自电解质无机盐类早强剂、水溶性有机聚合物类早强剂和有机化合物与无机盐复合类早强剂中的至少一种。本发明中,所述电解质无机盐类早强剂选自硫酸盐、硫酸复盐、硝酸盐、亚硝酸盐和氯盐中的至少一种,所述水溶性有机聚合物类早强剂选自三乙醇胺、甲酸盐、乙酸盐和丙酸盐中的至少一种。采用上述早强剂能加速混凝土早期强度发展。In the present invention, the early strength agent is selected from at least one of electrolyte inorganic salt early strength agent, water-soluble organic polymer early strength agent and organic compound and inorganic salt composite early strength agent. In the present invention, the electrolyte inorganic salt early strength agent is selected from at least one of sulfate, sulfate complex salt, nitrate, nitrite and chloride, and the water-soluble organic polymer early strength agent is selected from at least one of triethanolamine, formates, acetates and propionates. The use of the above early strength agent can accelerate the development of early strength of concrete.

本发明中,优选地,所述早强剂为硝酸钠和/或三乙醇胺。In the present invention, preferably, the early strength agent is sodium nitrate and/or triethanolamine.

本发明中,对增稠剂的种类没有特别限定,可以为本领域中常规的增稠剂,例如选自无机增稠剂、纤维素类增稠剂、天然高分子及其衍生物类增稠剂、合成高分子聚合物类增稠剂和络合型有机金属化合物类增稠剂中的至少一种。采用上述增稠剂能够提高水泥浆体系黏稠度。In the present invention, there is no particular limitation on the type of thickener, and the thickener may be any conventional thickener in the art, such as at least one selected from inorganic thickeners, cellulose thickeners, natural polymer thickeners and their derivatives, synthetic polymer thickeners, and complex organic metal compound thickeners. The above thickeners can improve the viscosity of the cement slurry system.

本发明中,所述无机增稠剂选自有机膨润土、硅藻土、凹凸棒土和硅凝胶中的至少一种;优选地,所述纤维素类增稠剂选自甲基纤维素、羟丙基甲基纤维素和羟乙基纤维素中的至少一种;优选地,所述天然高分子及其衍生物类增稠剂选自淀粉、明胶、干酪素、瓜尔胶、黄原胶和大豆蛋白胶中的至少一种;优选地,所述合成高分子聚合物类增稠剂选自聚丙烯酰胺、聚乙烯醇和聚丙烯酸中的至少一种;优选地,所述络合型有机金属化合物类增稠剂为氨基醇络合型钛酸酯。In the present invention, the inorganic thickener is selected from at least one of organic bentonite, diatomaceous earth, attapulgite and silica gel; preferably, the cellulose thickener is selected from at least one of methyl cellulose, hydroxypropyl methyl cellulose and hydroxyethyl cellulose; preferably, the natural polymer and its derivative thickener is selected from at least one of starch, gelatin, casein, guar gum, xanthan gum and soy protein gum; preferably, the synthetic polymer thickener is selected from at least one of polyacrylamide, polyvinyl alcohol and polyacrylic acid; preferably, the complex organic metal compound thickener is amino alcohol complex titanate.

本发明中,所述缓凝剂选自羟基羧酸、氨基羧酸及其盐、多元醇及其衍生物、葡萄糖、蔗糖及其衍生物、糖蜜及其衍生物、磷酸盐、偏磷酸盐类、硼砂和氟硅酸钠中的至少一种,对所述缓凝剂的状态没有特别限定,可以为液相或固相,采用上述缓凝剂能够降低水泥水化速度和水化热、延长凝结时间。In the present invention, the retarder is selected from at least one of hydroxycarboxylic acids, aminocarboxylic acids and salts thereof, polyols and derivatives thereof, glucose, sucrose and derivatives thereof, molasses and derivatives thereof, phosphates, metaphosphates, borax and sodium fluorosilicate. The state of the retarder is not particularly limited and may be liquid or solid. The use of the retarder can reduce the cement hydration rate and hydration heat and prolong the setting time.

本发明中,所述水为不含明显矿物质,且不影响混合后水泥浆各项基本性能的通常的井水、河水、江水和雨水等。In the present invention, the water is common well water, river water, river water, rain water, etc. which does not contain obvious minerals and does not affect the basic properties of the cement slurry after mixing.

根据本发明,对所述搅拌速度没有特别限定,本领域技术人员可以根据需要进行适应性选择,优选地,搅拌速度为5-1000rpm,优选为100-500rpm,在上述搅拌速度下可以实现泡沫堵漏浆的均匀混合。According to the present invention, there is no particular limitation on the stirring speed, and those skilled in the art can make an adaptive selection according to needs. Preferably, the stirring speed is 5-1000 rpm, preferably 100-500 rpm. At the above stirring speed, uniform mixing of the foam plugging slurry can be achieved.

本发明开发出一种特殊的泡沫堵漏浆,即在常规密度及低密度水泥基浆的基础上,加入泡沫剂并在机械作用下充入一定比例氮气,进一步降低浆体密度,形成泡沫均匀的泡沫堵漏浆,以此达到在承压能力较低地层打堵漏水泥塞(堵漏水泥浆)基本不漏失,保证打塞堵漏的成功率。The present invention develops a special foam plugging slurry, that is, on the basis of conventional density and low-density cement-based slurry, a foaming agent is added and a certain proportion of nitrogen is filled under mechanical action to further reduce the slurry density and form a foam plugging slurry with uniform foam, so as to achieve the goal of basically no leakage when plugging cement plugs (plugging cement slurry) in strata with low pressure bearing capacity, thereby ensuring the success rate of plugging.

本发明第二方面提供一种泡沫堵漏浆的制备方法,其中,包括以下步骤:A second aspect of the present invention provides a method for preparing a foam plugging slurry, which comprises the following steps:

(1)配制水泥基浆;(1) Prepare cement-based slurry;

(2)向水泥基浆内加入泡沫剂搅拌均匀,得到堵漏浆中间体;(2) adding a foaming agent to the cement-based slurry and stirring evenly to obtain a plugging slurry intermediate;

(3)向堵漏浆中间体充入氮气,得到泡沫堵漏浆;(3) filling nitrogen into the plugging slurry intermediate to obtain foam plugging slurry;

其中,相对于100重量份的水泥基浆,所述泡沫剂为不大于5重量份;Wherein, relative to 100 parts by weight of cement-based slurry, the foaming agent is no more than 5 parts by weight;

优选地,充入的氮气以体积量计,满足所述泡沫堵漏浆的密度相比于未加入氮气时下降了3-30%。Preferably, the nitrogen gas charged is calculated on a volume basis to ensure that the density of the foam plugging slurry decreases by 3-30% compared to when no nitrogen gas is added.

在一些具体实施方式中,根据真实气体状态方程近似计算气体密度或根据已发表的气体不同温度压力下的实验数据表查表得到。例如在温度T1和压力P1下,气体密度为D1,水泥基浆密度为C1,那么每单位体积水泥基浆在该温度压力下充入n单位体积气体并掺混均匀,形成均匀的气液固三相流泡沫堵漏浆的密度近似为F1(T1,P1)=(n×D1+C1)/(n+1),随着n增大,充入的气体量增多,泡沫堵漏浆密度越低。In some specific embodiments, the gas density is approximately calculated according to the real gas state equation or obtained by looking up the table based on the published experimental data table of gas at different temperatures and pressures. For example, at temperature T1 and pressure P1, the gas density is D1, and the cement-based slurry density is C1. Then, each unit volume of cement-based slurry is filled with n unit volumes of gas at this temperature and pressure and mixed evenly to form a uniform gas-liquid-solid three-phase flow foam plugging slurry. The density is approximately F1(T1, P1) = (n×D1+C1)/(n+1). As n increases, the amount of gas filled increases, and the density of the foam plugging slurry is lower.

在本发明一些具体实施方式中,步骤(3)中所述充氮的过程包括:In some specific embodiments of the present invention, the nitrogen filling process in step (3) comprises:

(3-1)模拟推算:根据在漏层段最高温度和漏失压力下,向所述堵漏浆中间体(可以是满足本发明前述组成,但量较少的样品液)充入一定体积的氮气,得到泡沫堵漏浆,所述泡沫堵漏浆的密度相比水泥基浆密度降低3-30%,优选为5-20%,即泡沫堵漏浆密度数值为水泥基浆密度数值的70-97%,优选为80-95%,形成的泡沫堵漏浆的密度近似满足以下关系:F(T,P)=(n×D+C)/(n+1)。例如在漏层段最高温度T1和漏失压力P1下,氮气密度为D1,水泥基浆密度为C1,那么所述水泥基浆在该温度压力下充入n单位体积氮气并掺混均匀,得到泡沫堵漏浆,泡沫堵漏浆密度数值为基液密度数值的70-97%,优选为80-95%,据此得到漏层段最高温度和漏失压力下所需氮气量,再根据真实氮气状态方程反推地面(地面环境下,温度和地面压力)所需的充氮量,获得即施工充氮量;(3-1) Simulation calculation: Under the highest temperature and leakage pressure of the leaking layer, a certain volume of nitrogen is charged into the plugging slurry intermediate (which can be a sample liquid that meets the aforementioned composition of the present invention but has a smaller amount) to obtain a foam plugging slurry. The density of the foam plugging slurry is reduced by 3-30%, preferably 5-20%, compared with the density of the cement-based slurry. That is, the density of the foam plugging slurry is 70-97%, preferably 80-95% of the density of the cement-based slurry. The density of the formed foam plugging slurry approximately satisfies the following relationship: F(T,P)=(n×D+C)/(n+1). For example, at the highest temperature T1 and leakage pressure P1 of the leaking layer, the nitrogen density is D1, and the cement-based slurry density is C1. Then, the cement-based slurry is filled with n unit volumes of nitrogen at this temperature and pressure and mixed evenly to obtain a foam plugging slurry. The density of the foam plugging slurry is 70-97% of the density of the base liquid, preferably 80-95%. Based on this, the required amount of nitrogen at the highest temperature and leakage pressure of the leaking layer is obtained, and then the required nitrogen filling amount on the ground (temperature and ground pressure under the ground environment) is reversed according to the real nitrogen state equation to obtain the construction nitrogen filling amount;

(3-2)应用专门的充氮设备,按照上面获得的施工充氮量,向所述堵漏浆中间体中充入氮气(用量满足相对应于所述堵漏浆中间体所需要的施工充氮量),得到泡沫堵漏浆。(3-2) Using a special nitrogen filling device, nitrogen is filled into the plugging slurry intermediate according to the construction nitrogen filling amount obtained above (the amount used meets the construction nitrogen filling amount required for the plugging slurry intermediate), to obtain foam plugging slurry.

不同温度和压力下,氮气的密度是不一样的,可根据真实气体状态方程近似计算氮气密度或根据已发表的氮气不同温度压力下的实验数据表查表得到。The density of nitrogen is different at different temperatures and pressures. It can be approximately calculated based on the real gas state equation or obtained by looking up the published experimental data table of nitrogen at different temperatures and pressures.

根据本发明,优选地,相对于100重量份的水泥基浆,所述泡沫剂为2-3重量份。According to the present invention, preferably, the foaming agent is 2-3 parts by weight relative to 100 parts by weight of the cement-based slurry.

根据本发明,优选地,充入的氮气以体积量计,满足所述泡沫堵漏浆的密度相比于未加入氮气时下降了5-20%。According to the present invention, preferably, the nitrogen gas charged is calculated on a volume basis to satisfy that the density of the foam plugging slurry is reduced by 5-20% compared to when no nitrogen gas is added.

根据本发明,步骤(1)中所述水泥基浆以重量份计包括::水泥100份、降失水剂1-10份、缓凝剂0-3份、早强剂0-5份、增稠剂0-0.2份、水30-70份。进一步地,所述水泥基浆以重量份计包括::水泥100份、降失水剂3-8份、缓凝剂0.1-2份、早强剂0.25-1份、增稠剂0.05-0.1份、水35-60份。According to the present invention, the cement-based slurry in step (1) comprises, by weight: 100 parts of cement, 1-10 parts of fluid loss agent, 0-3 parts of retarder, 0-5 parts of early strength agent, 0-0.2 parts of thickener, and 30-70 parts of water. Further, the cement-based slurry comprises, by weight: 100 parts of cement, 3-8 parts of fluid loss agent, 0.1-2 parts of retarder, 0.25-1 parts of early strength agent, 0.05-0.1 parts of thickener, and 35-60 parts of water.

在一些实施方式中,步骤(1)所述水泥基浆配制完成后,在漏层深度处最高温度和漏失压力下进行水泥基浆的各项性能评价,包括冷热浆流变(冷、热浆六速流变仪尾转数值≥10)、API失水(30min失水量<100mL),稠化曲线(曲线正常,满足井下泵送至漏层处的安全时间及施工状况)及抗压强度(漏层段最低温度和漏失压力下养护48h后抗压强度>3MPa),若水泥基浆满足上述性能,则符合进一步配制泡沫堵漏浆要求。In some embodiments, after the cement-based slurry described in step (1) is prepared, various properties of the cement-based slurry are evaluated at the highest temperature and leakage pressure at the depth of the leaking layer, including cold and hot slurry rheology (cold and hot slurry six-speed rheometer tail turn value ≥ 10), API water loss (30min water loss <100mL), thickening curve (the curve is normal, meeting the safety time and construction conditions for downhole pumping to the leaking layer) and compressive strength (compressive strength >3MPa after curing for 48h at the lowest temperature and leakage pressure of the leaking layer). If the cement-based slurry meets the above properties, it meets the requirements for further preparation of foam plugging slurry.

在一些实施方式中,根据漏失层位地层承压能力,配制能够覆盖漏失层位厚度的一定体积、一定密度的水泥浆(要求井筒内漏层处泡沫堵漏浆密度足够低,在此处的浆体压力与此处地层漏失压力相当,使得这段水泥浆能够停留住候凝并起强度,否则水泥浆会在漏层处发生漏失,会全部漏失掉或部分漏失掉而造成堵漏失败),再配合一定的注水泥浆工艺泵送至漏失地层位置候凝24-72h,待水泥浆彻底稠化起强度后,就形成了与地层胶结的具有一定强度的水泥塞,此时水泥塞彻底封堵并密封了原漏失地层的孔、缝及洞等类型的漏失通道,再下钻扫掉该段井筒内的水泥塞,该段漏层的井壁就得到了水泥固化的强化处理,能够极大程度缓解或消除该段漏层的漏失状况,使正常钻进能够得以继续。In some embodiments, according to the bearing capacity of the formation of the leakage layer, a certain volume and density of cement slurry that can cover the thickness of the leakage layer is prepared (the density of the foam plugging slurry at the leakage layer in the wellbore is required to be low enough, and the slurry pressure at this place is equivalent to the leakage pressure of the formation at this place, so that this section of cement slurry can stay and wait for solidification and strength, otherwise the cement slurry will leak at the leakage layer, and will be completely lost or partially lost, causing plugging failure), and then combined with a certain cement slurry injection process, it is pumped to the leakage formation position and waited for solidification for 24-72 hours. After the cement slurry is completely thickened and strengthened, a cement plug with a certain strength bonded to the formation is formed. At this time, the cement plug completely blocks and seals the leakage channels such as holes, cracks and holes in the original leakage formation. Then, the cement plug in this section of the wellbore is swept away by drilling, and the wall of the leakage layer in this section is strengthened by cement solidification, which can greatly alleviate or eliminate the leakage of the leakage layer, so that normal drilling can continue.

本发明第三方面提供一种泡沫堵漏浆,所述泡沫堵漏浆由第二方面所述的制备方法制得。The third aspect of the present invention provides a foam plugging slurry, which is prepared by the preparation method described in the second aspect.

本发明第四方面提供一种前述泡沫堵漏浆体系,所述包括第一方面或第三方面所述的泡沫堵漏浆和可选的常规堵漏浆;The fourth aspect of the present invention provides the aforementioned foam plugging slurry system, comprising the foam plugging slurry described in the first aspect or the third aspect and optional conventional plugging slurry;

其中,相对于100重量份的所述泡沫堵漏浆,所述常规堵漏浆为不大于100重量份,优选为10-30重量份。Wherein, relative to 100 parts by weight of the foam plugging slurry, the conventional plugging slurry is no more than 100 parts by weight, preferably 10-30 parts by weight.

本发明中,采用所述泡沫堵漏浆与常规堵漏浆混合,可以进一步提升泡沫堵漏浆的堵漏性能,在承压能力较低地层打堵漏水泥塞(堵漏水泥浆)基本不漏失,保证打塞堵漏的成功率。In the present invention, the foam plugging slurry is mixed with conventional plugging slurry to further improve the plugging performance of the foam plugging slurry. There is basically no leakage when plugging cement plugs (plugging cement slurry) in formations with low pressure bearing capacity, thereby ensuring the success rate of plugging.

本发明第五方面提供一种前述泡沫堵漏浆或者前述泡沫堵漏浆体系在页岩气井中的应用。A fifth aspect of the present invention provides an application of the aforementioned foam plugging slurry or the aforementioned foam plugging slurry system in a shale gas well.

以下将通过实施例和对比例对本发明进行详细描述。以下实施例和对比例中未注明具体条件者,按照常规条件或制造商建议的条件进行。所用试剂或仪器未注明生产厂商者,均为可以通过市购途径获得的常规或定制产品。The present invention will be described in detail below through examples and comparative examples. In the following examples and comparative examples, if no specific conditions are specified, the experiments were carried out under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used, if the manufacturer is not specified, are all conventional or customized products that can be obtained through commercial channels.

实施例1Example 1

(1)设置漏层段最高温度90℃和上覆压力35MPa,按照重量份为水泥100份、降失水剂3份、缓凝剂2份、早强剂0.25份、增稠剂0.05份、水50份的比例配制水泥基浆,水泥密度1.88g/cm3,具体配方见表1;(1) The maximum temperature of the leaking layer section is set at 90°C and the overburden pressure is 35 MPa. The cement-based slurry is prepared according to the weight ratio of 100 parts of cement, 3 parts of fluid loss reducer, 2 parts of retarder, 0.25 parts of early strength agent, 0.05 parts of thickener, and 50 parts of water. The cement density is 1.88 g/cm 3 . The specific formula is shown in Table 1;

(2)向水泥基浆内加入重量份3份的泡沫剂以100rpm的速度搅拌3min,得到堵漏浆中间体;(2) adding 3 parts by weight of a foaming agent to the cement-based slurry and stirring at a speed of 100 rpm for 3 minutes to obtain a plugging slurry intermediate;

(3)假设地面充氮设备向堵漏浆中间体充入是基浆体积50倍的氮气,得到泡沫堵漏浆(1个大气压,20℃),此密度的泡沫堵漏浆在该漏层段叠加上部所有压力后与本漏层段地层漏失压力相当。(3) Assume that the ground nitrogen filling equipment fills the plugging slurry intermediate with nitrogen 50 times the volume of the base slurry to obtain foam plugging slurry (1 atmosphere, 20°C). The foam plugging slurry of this density is equivalent to the formation loss pressure of this leaking layer after superimposing all the upper pressures on this leaking layer.

实施例2Example 2

按照实施例1的步骤制备泡沫堵漏浆,具体配方见表1。The foam plugging slurry was prepared according to the steps of Example 1. The specific formula is shown in Table 1.

实施例3Example 3

按照实施例1的步骤制备泡沫堵漏浆,具体配方见表1。The foam plugging slurry was prepared according to the steps of Example 1. The specific formula is shown in Table 1.

实施例4Example 4

按照实施例1的步骤制备泡沫堵漏浆,具体配方见表1。The foam plugging slurry was prepared according to the steps of Example 1. The specific formula is shown in Table 1.

实施例5Example 5

按照实施例1的步骤制备泡沫堵漏浆,具体配方见表1。The foam plugging slurry was prepared according to the steps of Example 1. The specific formula is shown in Table 1.

表1Table 1

对比例1Comparative Example 1

按照实施例1的设定条件和步骤制备泡沫堵漏浆,区别在于,未充气体,具体配方见表2。The foam plugging slurry was prepared according to the set conditions and steps of Example 1, except that no gas was added. The specific formula is shown in Table 2.

对比例2Comparative Example 2

按照实施例1的设定条件和步骤制备泡沫堵漏浆,具体配方见表2。The foam plugging slurry was prepared according to the set conditions and steps of Example 1. The specific formula is shown in Table 2.

对比例3Comparative Example 3

按照实施例1的设定条件和步骤制备泡沫堵漏浆,区别在于,未加泡沫剂,具体配方见表2。The foam plugging slurry was prepared according to the set conditions and steps of Example 1, except that no foaming agent was added. The specific formula is shown in Table 2.

对比例4Comparative Example 4

按照实施例1的设定条件和步骤制备泡沫堵漏浆,区别在于,未加缓凝剂,具体配方见表2。The foam plugging slurry was prepared according to the set conditions and steps of Example 1, except that no retarder was added. The specific formula is shown in Table 2.

对比例5Comparative Example 5

按照实施例1的步骤制备泡沫堵漏浆,区别在于,未加降失水剂,具体配方见表2。The foam plugging slurry was prepared according to the steps of Example 1, except that no fluid loss agent was added. The specific formula is shown in Table 2.

表2Table 2

测试例1Test Example 1

测试实施例和对比例的水泥基浆的各项性能指标,结果如表3所示。冷热浆流变采用六速旋转黏度计对冷热浆进行读取;The various performance indicators of the cement-based slurries of the embodiments and comparative examples were tested, and the results are shown in Table 3. The rheology of the cold and hot slurries was read using a six-speed rotary viscometer;

API失水采用高温高压失水仪按照API标准进行失水测量;API water loss is measured using a high temperature and high pressure water loss instrument in accordance with API standards;

稠化曲线采用增压稠化仪按照业内常规做法获取;The thickening curve is obtained using a pressurized thickening instrument according to the conventional practice in the industry;

抗压强度采用压力测试机对养护48h的水泥试块进行抗压强度测试。The compressive strength was tested on cement specimens cured for 48 hours using a pressure testing machine.

表3Table 3

测试例2Test Example 2

对实施例和对比例的泡沫堵漏浆的性能参数测定结果如表4所示。The performance parameter measurement results of the foam plugging slurry of the embodiment and the comparative example are shown in Table 4.

表4Table 4

从表4中可以看出,实施例1和实施例2的泡沫堵漏浆,水泥基浆性能满足井下泵送至漏层处的安全时间及施工状况,漏层处的泡沫堵漏浆为均匀泡状流且无漏失,且气泡稳定分布无游离,浆体稳定性好,较对比例的泡沫堵漏浆堵漏效果好。It can be seen from Table 4 that the foam plugging slurry of Example 1 and Example 2, the cement-based slurry performance meets the safety time and construction conditions of downhole pumping to the leaking layer, the foam plugging slurry at the leaking layer is a uniform bubbling flow without leakage, and the bubbles are stably distributed without free, the slurry stability is good, and the plugging effect is better than that of the foam plugging slurry of the comparative example.

测试例3Test Example 3

测试实施例1和实施例2的泡沫堵漏浆的堵漏性能,结果如表5所示。The plugging performance of the foam plugging slurry of Example 1 and Example 2 was tested, and the results are shown in Table 5.

表5Table 5

从表5中可以看出,采用本发明实施例1和实施例2的泡沫堵漏浆,在重庆南川页岩气工区现场,应用本发明的泡沫堵漏浆的配方及制备方法,前期常规堵漏方案的堵漏效果不理想,最后采用泡沫堵漏浆封堵漏层,封堵效果显著,且一次堵漏成功,节省大量堵漏成本。As can be seen from Table 5, the foam plugging slurry of Example 1 and Example 2 of the present invention was used. At the Chongqing Nanchuan shale gas field, the formula and preparation method of the foam plugging slurry of the present invention were applied. The plugging effect of the conventional plugging scheme in the early stage was not ideal. Finally, the foam plugging slurry was used to plug the leaking layer, and the plugging effect was significant. The plugging was successful in one time, saving a lot of plugging costs.

以上详细描述了本发明的优选实施方式,但是,本发明并不限于此。在本发明的技术构思范围内,可以对本发明的技术方案进行多种简单变型,包括各个技术特征以任何其它的合适方式进行组合,这些简单变型和组合同样应当视为本发明所公开的内容,均属于本发明的保护范围。The preferred embodiments of the present invention are described in detail above, but the present invention is not limited thereto. Within the technical concept of the present invention, the technical solution of the present invention can be subjected to a variety of simple modifications, including the combination of various technical features in any other suitable manner, and these simple modifications and combinations should also be regarded as the contents disclosed by the present invention and belong to the protection scope of the present invention.

Claims (10)

1. A foam plugging slurry, wherein the foam plugging slurry comprises: cement-based slurries, foaming agents and nitrogen gas filling;
Wherein the foaming agent is not more than 5 parts by weight relative to 100 parts by weight of the cement-based slurry; the amount of nitrogen added satisfies that the density of the foam plugging slurry is reduced by 3-30% by volume compared to cement-based slurry.
2. The foam plugging slurry of claim 1 wherein the foaming agent is 2-3 parts by weight;
Preferably, the amount of nitrogen added is such that the density of the foam plugging slurry is reduced by 5-20% by volume compared to the cement-based slurry.
3. The foam plugging slurry of claim 1 or 2, wherein the cement-based slurry comprises, in parts by weight: 100 parts of cement, 1-10 parts of a fluid loss agent, 0-3 parts of a retarder, 0-5 parts of an early strength agent, 0-0.2 part of a thickener and 30-70 parts of water;
preferably, the cement-based slurry comprises, in parts by weight: 100 parts of cement, 3-8 parts of filtrate reducer, 0.1-2 parts of retarder, 0.25-1 part of early strength agent, 0.05-0.1 part of thickener and 35-60 parts of water.
4. The preparation method of the foam leak-stopping slurry is characterized by comprising the following steps of:
(1) Preparing cement-based slurry;
(2) Adding a foaming agent into the cement-based slurry, and uniformly stirring to obtain a leakage blocking slurry intermediate;
(3) Filling nitrogen into the middle of the plugging slurry to obtain foam plugging slurry;
wherein the foaming agent is not more than 5 parts by weight relative to 100 parts by weight of the cement-based slurry;
Preferably, the amount of nitrogen added is such that the density of the foam plugging slurry is reduced by 3-30% by volume compared to the cement-based slurry.
5. The preparation method according to claim 4, wherein the cement-based slurry in step (1) comprises, in parts by weight: 100 parts of cement, 1-10 parts of a fluid loss agent, 0-3 parts of a retarder, 0-5 parts of an early strength agent, 0-0.2 part of a thickener and 30-70 parts of water;
preferably, the cement-based slurry comprises, in parts by weight: 100 parts of cement, 3-8 parts of filtrate reducer, 0.1-2 parts of retarder, 0.25-1 part of early strength agent, 0.05-0.1 part of thickener and 35-60 parts of water.
6. The production method according to claim 4 or 5, wherein the foaming agent is2 to 3 parts by weight relative to 100 parts by weight of the cement-based slurry;
preferably, the amount of nitrogen added is such that the density of the foamed plugging slurry is reduced by 5-20% by volume compared to the cement-based slurry;
Preferably, the foaming agent in the step (2) is a surfactant foaming agent, preferably at least one selected from sodium dodecyl benzene sulfonate, alpha-olefin sulfonate, alpha-sulfo fatty acid methyl ester and sodium N-oleoyl-N-methyl taurate;
preferably, the stirring speed is 50-1000rpm, preferably 100-500rpm.
7. The preparation method according to any one of claims 4 to 6, wherein the fluid loss additive is an emulsion fluid loss additive and/or a water-soluble high polymer fluid loss additive;
preferably, the early strength agent is at least one selected from electrolyte inorganic salt early strength agents, water-soluble organic polymer early strength agents and organic compound and inorganic salt composite early strength agents.
8. A foam plugging slurry prepared by the preparation method of any one of claims 4-7.
9. A foamed plugging slurry system, characterized in that the system comprises the foamed plugging slurry of any one of claims 1-3, 8 and optionally a conventional plugging slurry;
wherein the conventional plugging slurry is not more than 100 parts by weight, preferably 10 to 30 parts by weight, relative to 100 parts by weight of the foam plugging slurry.
10. Use of the foamed plugging slurry of any one of claims 1-3, 8 or the foamed plugging slurry system of claim 9 in a shale gas well.
CN202310435016.4A 2023-04-21 2023-04-21 Foam plugging slurry, preparation method of foam plugging slurry, foam plugging slurry system and application Active CN118813223B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103525387A (en) * 2013-09-29 2014-01-22 中国石油大学(华东) Foam cement slurry system and composition
CN104946220A (en) * 2015-06-12 2015-09-30 天津中油渤星工程科技有限公司 Early strength foam cement slurry for well cementation
CN109514739A (en) * 2017-09-18 2019-03-26 中国石油化工股份有限公司 A kind of foam slurry cementing equipment and method
US20190218445A1 (en) * 2018-01-17 2019-07-18 Bj Services, Llc Cement Slurries for Well Bores

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103525387A (en) * 2013-09-29 2014-01-22 中国石油大学(华东) Foam cement slurry system and composition
CN104946220A (en) * 2015-06-12 2015-09-30 天津中油渤星工程科技有限公司 Early strength foam cement slurry for well cementation
CN109514739A (en) * 2017-09-18 2019-03-26 中国石油化工股份有限公司 A kind of foam slurry cementing equipment and method
US20190218445A1 (en) * 2018-01-17 2019-07-18 Bj Services, Llc Cement Slurries for Well Bores

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