CN1188073A - Method for preparing Fullerenes carbon material and its use in battery electrode material - Google Patents
Method for preparing Fullerenes carbon material and its use in battery electrode material Download PDFInfo
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- CN1188073A CN1188073A CN97105036A CN97105036A CN1188073A CN 1188073 A CN1188073 A CN 1188073A CN 97105036 A CN97105036 A CN 97105036A CN 97105036 A CN97105036 A CN 97105036A CN 1188073 A CN1188073 A CN 1188073A
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- China
- Prior art keywords
- carbon material
- fullerenes
- fullerenes carbon
- carbon
- preparation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 239000003575 carbonaceous material Substances 0.000 title claims abstract description 19
- 229910003472 fullerene Inorganic materials 0.000 title claims abstract description 18
- 239000007772 electrode material Substances 0.000 title claims description 5
- 238000000034 method Methods 0.000 title description 2
- 239000000463 material Substances 0.000 claims abstract description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 239000003345 natural gas Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 5
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 235000009508 confectionery Nutrition 0.000 claims description 6
- 229910052744 lithium Inorganic materials 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 abstract description 3
- 150000003624 transition metals Chemical class 0.000 abstract description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 7
- 239000006229 carbon black Substances 0.000 description 3
- 235000019241 carbon black Nutrition 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000002041 carbon nanotube Substances 0.000 description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 1
- 238000001241 arc-discharge method Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Carbon And Carbon Compounds (AREA)
Abstract
The preparation method of fullerenes carbon material is characterized by using natural gas as raw material, under the condition of Fe, Co and Ni transition metal catalyst and strong cold, using microwave plasma to synthesize fullerenes carbon material with C60 and C70 type cage structure and mixture of nanometer microcarbon tube material. Its yield is high, cost is low, and it can be used to prepare Li-ionic cell negative electrode.
Description
The present invention relates to C
60The manufacturing technology of family's soccerballene carbon materials and little carbon tube material mixture, and the application of this material in Li ionization cell electrode.
Fullerenes carbon material and little carbon tube material are the type materials of finding recent years, because it has special cage shape and cage-like shape structure, make it that special many excellent properties that are different from the existing capability material be arranged.Thereby obtain people's common concern.But, C
60And C
70The acquisition of fullerenes carbon material is difficulty very.Generally obtained by " arc discharge method ", its principle is made electrode for adopting graphite, and the high-temperature gasification that produces through electric arc in inert atmospheres such as argon or helium generates C under strong cold state
60, C
70Deng fullerenes carbon material and CNT (carbon nano-tube).Also useful organic gas is that raw material makes under arc-over and strong cool condition.The subject matter that exists is that yield is extremely low.In addition, the negative material of lithium-ion secondary cell adopts carbon materialses such as carbon black, graphite at present, utilize the function of storage lithium between its interlayer to make battery have recyclability, but the storage lithium amount of this material is big inadequately, makes cell container limited.
The object of the present invention is to provide a kind of preparation method of new fullerenes carbon material, its yield is higher, and cost is lower, and available its prepared Li ionization cell negative pole.
The invention provides a kind of preparation method of fullerenes carbon material, it is characterized in that: be raw material with the Sweet natural gas, reach under strong cold, with the synthetic C of microwave plasma at iron, cobalt, nickel magnesium-yttrium-transition metal catalyzer
60And C
70The mixture of the little carbon tube material of the fullerenes carbon material of cage-like shape structure and nano level.Sweet natural gas is the starting material of the inexpensive greatly carbon materials of resource abundance, amount, and the major ingredient in the Sweet natural gas is hydrocarbon short chain small molecules such as methane.Microwave plasma is handled activating this class short chain molecule and opening hydrocarbon chain in conjunction with having extra high efficient and function.Therefore adopt the microwave plasma method to handle gas material, at first break hydrocarbon marriage chain, adopt rare-earth metal catalysts such as magnesium-yttrium-transition metal catalyzer such as iron, cobalt, nickel or lanthanum again, make the carbochain of splitting be combined into C
60C
70The little carbon tube material of the fullerenes carbon material of cage-like shape structure and nano level.It is a kind of brand-new technology pattern.
With the fullerenes carbon material that above-mentioned preparation method prepares, store metallic lithium, can be used as Li ionization cell electrode materials.
This is because carbon 60 fullerene molecules itself just have the reversibility that discharges and recharges:
Below by embodiment in detail the present invention is described in detail.
Embodiment 1
With the Sweet natural gas is raw material, under iron, cobalt, nickel magnesium-yttrium-transition metal catalyzer and strong cool condition, with the synthetic C of microwave plasma
60And C
70The mixture of the little carbon tube material of the fullerenes carbon material of cage-like shape structure and nano level.
Example 2
With the fullerenes carbon material that embodiment 1 described preparation method prepares, store metallic lithium, as Li ionization cell electrode materials.
Claims (2)
1. the preparation method of a fullerenes carbon material is characterized in that: be raw material with the Sweet natural gas, under iron, cobalt, nickel magnesium-yttrium-transition metal catalyzer and strong cool condition, with the synthetic C of microwave plasma
60And C
70The mixture of the little carbon tube material of the fullerenes carbon material of cage-like shape structure and nano level.
2. the fullerenes carbon material of preparing with the described preparation method of claim 1 is stored metallic lithium, as Li ionization cell electrode materials.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97105036A CN1188073A (en) | 1997-01-17 | 1997-01-17 | Method for preparing Fullerenes carbon material and its use in battery electrode material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97105036A CN1188073A (en) | 1997-01-17 | 1997-01-17 | Method for preparing Fullerenes carbon material and its use in battery electrode material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1188073A true CN1188073A (en) | 1998-07-22 |
Family
ID=5167598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97105036A Pending CN1188073A (en) | 1997-01-17 | 1997-01-17 | Method for preparing Fullerenes carbon material and its use in battery electrode material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1188073A (en) |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1333478C (en) * | 2002-10-04 | 2007-08-22 | 三菱化学株式会社 | Negative electrode material for lithium secondary battery, negative electrode using same, and lithium secondary battery |
| CN1747218B (en) * | 2004-09-03 | 2010-06-09 | 香港科技大学 | Lithium ion battery combined with carbon nano-structure material |
| CN101891183A (en) * | 2010-07-15 | 2010-11-24 | 山西大同大学 | A method for preparing carbon nanotubes using biological products as catalyst precursors |
| CN102231925A (en) * | 2011-05-20 | 2011-11-02 | 中国科学院化学研究所 | A method for improving the yield of C60/C70 fullerenes prepared by arc discharge method |
| CN108529597A (en) * | 2018-04-24 | 2018-09-14 | 常州天鸽环保科技有限公司 | The preparation method of fullerene/graphene hetero-junctions of fluorine modification |
| CN111584864A (en) * | 2019-02-22 | 2020-08-25 | 叶小剑 | A kind of carbon nanotube fullerene battery and preparation method thereof |
| US11590568B2 (en) | 2019-12-19 | 2023-02-28 | 6K Inc. | Process for producing spheroidized powder from feedstock materials |
| US11633785B2 (en) | 2019-04-30 | 2023-04-25 | 6K Inc. | Mechanically alloyed powder feedstock |
| US11717886B2 (en) | 2019-11-18 | 2023-08-08 | 6K Inc. | Unique feedstocks for spherical powders and methods of manufacturing |
| US11839919B2 (en) | 2015-12-16 | 2023-12-12 | 6K Inc. | Spheroidal dehydrogenated metals and metal alloy particles |
| US11855278B2 (en) | 2020-06-25 | 2023-12-26 | 6K, Inc. | Microcomposite alloy structure |
| US11919071B2 (en) | 2020-10-30 | 2024-03-05 | 6K Inc. | Systems and methods for synthesis of spheroidized metal powders |
| US11963287B2 (en) | 2020-09-24 | 2024-04-16 | 6K Inc. | Systems, devices, and methods for starting plasma |
| US12040162B2 (en) | 2022-06-09 | 2024-07-16 | 6K Inc. | Plasma apparatus and methods for processing feed material utilizing an upstream swirl module and composite gas flows |
| US12042861B2 (en) | 2021-03-31 | 2024-07-23 | 6K Inc. | Systems and methods for additive manufacturing of metal nitride ceramics |
| US12094688B2 (en) | 2022-08-25 | 2024-09-17 | 6K Inc. | Plasma apparatus and methods for processing feed material utilizing a powder ingress preventor (PIP) |
| US12195338B2 (en) | 2022-12-15 | 2025-01-14 | 6K Inc. | Systems, methods, and device for pyrolysis of methane in a microwave plasma for hydrogen and structured carbon powder production |
| US12214420B2 (en) | 2015-12-16 | 2025-02-04 | 6K Inc. | Spheroidal titanium metallic powders with custom microstructures |
| US12261023B2 (en) | 2022-05-23 | 2025-03-25 | 6K Inc. | Microwave plasma apparatus and methods for processing materials using an interior liner |
| CN119852336A (en) * | 2023-10-18 | 2025-04-18 | 溧阳天目先导电池材料科技有限公司 | Silicon-carbon negative electrode material, preparation method and application thereof in lithium ion battery |
| US12311447B2 (en) | 2018-06-19 | 2025-05-27 | 6K Inc. | Process for producing spheroidized powder from feedstock materials |
| US12406829B2 (en) | 2021-01-11 | 2025-09-02 | 6K Inc. | Methods and systems for reclamation of Li-ion cathode materials using microwave plasma processing |
-
1997
- 1997-01-17 CN CN97105036A patent/CN1188073A/en active Pending
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1333478C (en) * | 2002-10-04 | 2007-08-22 | 三菱化学株式会社 | Negative electrode material for lithium secondary battery, negative electrode using same, and lithium secondary battery |
| CN1747218B (en) * | 2004-09-03 | 2010-06-09 | 香港科技大学 | Lithium ion battery combined with carbon nano-structure material |
| CN101891183B (en) * | 2010-07-15 | 2012-07-04 | 山西大同大学 | Method for preparing carbon nano-tubes by using biological product as catalyst precursor |
| CN101891183A (en) * | 2010-07-15 | 2010-11-24 | 山西大同大学 | A method for preparing carbon nanotubes using biological products as catalyst precursors |
| CN102231925A (en) * | 2011-05-20 | 2011-11-02 | 中国科学院化学研究所 | A method for improving the yield of C60/C70 fullerenes prepared by arc discharge method |
| US11839919B2 (en) | 2015-12-16 | 2023-12-12 | 6K Inc. | Spheroidal dehydrogenated metals and metal alloy particles |
| US12214420B2 (en) | 2015-12-16 | 2025-02-04 | 6K Inc. | Spheroidal titanium metallic powders with custom microstructures |
| CN108529597A (en) * | 2018-04-24 | 2018-09-14 | 常州天鸽环保科技有限公司 | The preparation method of fullerene/graphene hetero-junctions of fluorine modification |
| US12311447B2 (en) | 2018-06-19 | 2025-05-27 | 6K Inc. | Process for producing spheroidized powder from feedstock materials |
| CN111584864A (en) * | 2019-02-22 | 2020-08-25 | 叶小剑 | A kind of carbon nanotube fullerene battery and preparation method thereof |
| US11633785B2 (en) | 2019-04-30 | 2023-04-25 | 6K Inc. | Mechanically alloyed powder feedstock |
| US11717886B2 (en) | 2019-11-18 | 2023-08-08 | 6K Inc. | Unique feedstocks for spherical powders and methods of manufacturing |
| US11590568B2 (en) | 2019-12-19 | 2023-02-28 | 6K Inc. | Process for producing spheroidized powder from feedstock materials |
| US11855278B2 (en) | 2020-06-25 | 2023-12-26 | 6K, Inc. | Microcomposite alloy structure |
| US12176529B2 (en) | 2020-06-25 | 2024-12-24 | 6K Inc. | Microcomposite alloy structure |
| US11963287B2 (en) | 2020-09-24 | 2024-04-16 | 6K Inc. | Systems, devices, and methods for starting plasma |
| US11919071B2 (en) | 2020-10-30 | 2024-03-05 | 6K Inc. | Systems and methods for synthesis of spheroidized metal powders |
| US12406829B2 (en) | 2021-01-11 | 2025-09-02 | 6K Inc. | Methods and systems for reclamation of Li-ion cathode materials using microwave plasma processing |
| US12042861B2 (en) | 2021-03-31 | 2024-07-23 | 6K Inc. | Systems and methods for additive manufacturing of metal nitride ceramics |
| US12261023B2 (en) | 2022-05-23 | 2025-03-25 | 6K Inc. | Microwave plasma apparatus and methods for processing materials using an interior liner |
| US12040162B2 (en) | 2022-06-09 | 2024-07-16 | 6K Inc. | Plasma apparatus and methods for processing feed material utilizing an upstream swirl module and composite gas flows |
| US12094688B2 (en) | 2022-08-25 | 2024-09-17 | 6K Inc. | Plasma apparatus and methods for processing feed material utilizing a powder ingress preventor (PIP) |
| US12195338B2 (en) | 2022-12-15 | 2025-01-14 | 6K Inc. | Systems, methods, and device for pyrolysis of methane in a microwave plasma for hydrogen and structured carbon powder production |
| CN119852336A (en) * | 2023-10-18 | 2025-04-18 | 溧阳天目先导电池材料科技有限公司 | Silicon-carbon negative electrode material, preparation method and application thereof in lithium ion battery |
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