CN1183186C - Acryl pearlite board and its producing method - Google Patents
Acryl pearlite board and its producing method Download PDFInfo
- Publication number
- CN1183186C CN1183186C CNB021257213A CN02125721A CN1183186C CN 1183186 C CN1183186 C CN 1183186C CN B021257213 A CNB021257213 A CN B021257213A CN 02125721 A CN02125721 A CN 02125721A CN 1183186 C CN1183186 C CN 1183186C
- Authority
- CN
- China
- Prior art keywords
- acryl
- pearlite
- pearlite board
- board
- manufacture method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 229910001562 pearlite Inorganic materials 0.000 title claims abstract description 59
- -1 Acryl Chemical group 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000002002 slurry Substances 0.000 claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 claims abstract description 19
- 238000007711 solidification Methods 0.000 claims abstract description 15
- 230000008023 solidification Effects 0.000 claims abstract description 15
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 10
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 10
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 10
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000008117 stearic acid Substances 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 17
- 239000002994 raw material Substances 0.000 claims description 15
- 238000006116 polymerization reaction Methods 0.000 claims description 11
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 229910000014 Bismuth subcarbonate Inorganic materials 0.000 claims description 3
- 241001005836 Euchloe ausonia Species 0.000 claims description 3
- MGLUJXPJRXTKJM-UHFFFAOYSA-L bismuth subcarbonate Chemical compound O=[Bi]OC(=O)O[Bi]=O MGLUJXPJRXTKJM-UHFFFAOYSA-L 0.000 claims description 3
- 229940036358 bismuth subcarbonate Drugs 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- PPQREHKVAOVYBT-UHFFFAOYSA-H dialuminum;tricarbonate Chemical compound [Al+3].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O PPQREHKVAOVYBT-UHFFFAOYSA-H 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- 210000004243 sweat Anatomy 0.000 claims description 2
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 claims 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 6
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 2
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000012752 auxiliary agent Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Finishing Walls (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention discloses an acryl pearlite board and a manufacturing method thereof. The acryl pearlite board comprises an acryl board layer and a pearlite board layer, and stereo figures are arranged in the acryl pearlite board. The pearlite board is manufactured by polymerizing and solidifying methyl methacrylate, stearic acid, methyl acrylic acid, methyl acrylic acid glycol ester, azobisisobutyronitrile and pearlite color paste and then is clamped in a mould and is injected with acryl board material slurry for solidification and demoulding. The acryl pearlite board which is manufactured by the method is beautiful and is especially suitable for manufacturing sanitary wares and technical products.
Description
Technical field
The present invention relates to a kind of acryl pearlite board and manufacture method thereof, particularly a kind of acryl pearlite board that spatial gauffer decorative pattern is arranged in inside that is combined into by acrylic board and pearlite board, the acryl pearlite board and the manufacture method thereof that are suitable for making sanitary ware, finishing material and artwork.
Background technology
Pearlite board is widely used in fields such as finishing material, handicraft, and pearlite board seems noble elegant because of it has pearliness, and the goods of being made by pearlite board are subjected to people's welcome very much; But existing pearlite board kind is very single, makes its range of application be subjected to certain restriction.
The content of invention
At the single problem of the kind of existing pearlite board product, the object of the present invention is to provide a kind of acryl pearlite board, there is spatial gauffer decorative pattern the inside of this pearlite board, and is very attractive in appearance.
Another object of the present invention is to provide a kind of manufacture method of acryl pearlite board.
The object of the present invention is achieved like this, and acryl pearlite board of the present invention is made of two-layer, and one deck is transparent acrylic board, and another layer is a pearlite board, in the inside of acryl pearlite board, at the bonding surface place of pearlite board and acrylic board spatial gauffer decorative pattern is arranged.
The manufacture method of this acryl pearlite board comprises the steps:
(1) preparation of raw material, the raw material of pearlite board is made of carrier, auxiliary agent and pearly-lustre mill base, its carrier is the raw material of acrylic board, it is methyl methacrylate, auxiliary agent comprises stearic acid, methacrylic acid, methacrylic acid glycol ester, Diisopropyl azodicarboxylate, and above-mentioned materials mixes by following weight proportion
Methyl methacrylate 75%-95%
Stearic acid 0.1%-10%
Methacrylic acid 0.1%-5%
Methacrylic acid glycol ester 0.1%-5%
Diisopropyl azodicarboxylate 0.1%-5%
Pearly-lustre mill base 0.3%-20%
B, above-mentioned raw materials is added reactor, polymerization under 20-90 ℃ of temperature, to its denseness be 10%-20%;
C, above-mentioned slurry is injected mould, sealing is positioned in 30-72 ℃ the hot water, carries out initial solidification, and carrying out not with vibrator to it therebetween, intermittent control shaking to initial solidification finishes;
D, mould is positioned over carries out the high temperature later stage in 80-120 ℃ the hot setting equipment and solidified 10-90 minute
E, mould cool off under normal temperature environment, and the demoulding makes pearlite board;
F, the pearlite board after the demoulding is clipped on the mould, good seal around the mould only keeps a charging bole;
G, will be under 40 ℃ of-90 ℃ of temperature the polymeric denseness be that the transparent acrylic slurry of 10%-20%% injects mould, make it evenly to be covered in the pearlite board surface, then charging bole is sealed, be positioned in 40 ℃-70 ℃ the hot water and solidify the demoulding.
The preferable weight proportion of the raw material of pearlite board is:
Methyl methacrylate 88.35%
Stearic acid 1%
Methacrylic acid 0.2%
Methacrylic acid glycol ester 0.3%
Diisopropyl azodicarboxylate 0.15%
Pearly-lustre mill base 10%
Above-mentioned pearly-lustre mill base is one or more in pearl white, titanium dioxide, Aluminum Carbonate Basic, Bismuth Subcarbonate and the photochromic slurry of acid zincic acid lead sweat.
The preferable polymerization temperature of above-mentioned pearlite board raw material in still is 30-85 ℃, and preferred 80 ℃, its preferable denseness is 15%.
Above-mentioned initial solidification temperature preferred range is 50-65 ℃, preferred 60 ℃.
The preferred temperature of above-mentioned hot setting is 100-105 ℃, and the preferable hot setting time is 10-90 minute.
The preferable polymerization temperature of above-mentioned acrylic slurry is 80 ℃, and the preferable denseness of acrylic slurry is 15%, and the preferable solidification value of acrylic slurry is 60 ℃.
Adopt the acryl pearlite board of aforesaid method production to be made of two-layer, one side is transparent acrylic layer, from this simultaneously, pearly-lustre color solid decorative pattern is arranged in acryl pearlite board, is wavy, and the same gloss of pearl is arranged.This acryl pearlite board be fit to be made sanitary ware, handicraft and finishing material very much, the goods noble quality that is made by this material, attractive in appearance.
Embodiment
The utility model is described in further detail in conjunction with specific embodiments for following machine.In an embodiment, the polymkeric substance denseness adopts the QWC-9040 consistometer of Shenyang instrument institute production to measure.
Embodiment 1
Carrier, auxiliary agent and pearlite slurry raw material are mixed by following weight proportion, wherein, methyl methacrylate 88.35%, stearic acid 1%, methacrylic acid 0.2%, methacrylic acid glycol ester 0.3%, Diisopropyl azodicarboxylate 0.15%, pearl white 10% after above-mentioned raw materials mixed, carries out polyreaction under 80 ℃ of temperature, to its denseness be 15%, inject mould then, put into 60 ℃ of hot water and carry out initial solidification, not intermittent control shaking.Solidify the back that finishes and under 102 ℃ of temperature, carried out hot setting 30 minutes.The cooling back demoulding at normal temperatures then.
To make pearlite board with aforesaid method and stand in admittedly in the mould, will use folder sign indicating number and seal gum good seal around the mould, the centre keeps a charging bole.The denseness that will aggregate under 80 ℃ of conditions is that 15% transparent acrylic slurry injects mould and evenly covers whole pearlite board surface until slurry, with mould mouth good seal, place 60 ℃ of hot water to solidify, cooling then, the demoulding, promptly make an acryl pearlite board.
Embodiment 2
Pearlite board raw material weight proportioning is: methyl methacrylate 75%, stearic acid 10%, methacrylic acid 0.1%, methacrylic acid glycol ester 0.3%, Diisopropyl azodicarboxylate 5%, titanium dioxide 9.6% after above-mentioned raw materials mixed, carries out polyreaction under 90 ℃ of temperature, to denseness be 15%, inject mould then, put into 30 ℃ of hot water and carry out initial solidification, not intermittent control shaking.Solidify the back that finishes and under 80 ℃ of temperature, carried out hot setting 90 minutes.The cooling back demoulding at normal temperatures then.
Pearlite board is sandwiched mould, and as process as described in the embodiment 1, the denseness that polymerization under 90 ℃ of conditions is obtained is that 20% acrylic slurry injects mould, carries out a series of cure and demolds under 70 ℃ of conditions.
Embodiment 3
Entire making process is as described in the embodiment 1, and different is that its raw material weight proportioning is: methyl methacrylate 82%, stearic acid 5%, methacrylic acid 5%, methacrylic acid glycol ester 5%, Diisopropyl azodicarboxylate 2%, Bismuth Subcarbonate 1%.Polymerization temperature is 40 ℃, and the slurry consistency that obtains is 10%, and the initial solidification temperature is 70 ℃, 35 minutes set times; The hot setting temperature is 100 ℃.The polymerization temperature of acrylic slurry is 60 ℃, and denseness is 10%, and solidification value is 70 ℃.
Embodiment 4
Entire making process is as described in the embodiment 1, and different is that its raw material weight proportioning is: methyl methacrylate 75%, stearic acid 1%, methacrylic acid 2%, methacrylic acid glycol ester 2%, Diisopropyl azodicarboxylate 5%, acid zincic acid lead 20%.Polymerization temperature is 60 ℃, and the slurry consistency that obtains is 20%, and the initial solidification temperature is 60 ℃, 50 minutes set times; The hot setting temperature is 93 ℃.The polymerization temperature of acrylic slurry is 70 ℃, and denseness is 16%, and solidification value is 60 ℃.
Claims (10)
1, a kind of acryl pearlite board is characterized in that: acryl pearlite board is made of transparent acryl layer and pearlite layer, and there is spatial gauffer decorative pattern at the bonding surface place of pearlite layer and acryl layer.
2, the manufacture method of acryl pearlite board as claimed in claim 1 is characterized in that, this manufacture method comprises the steps:
A, pearlite board raw material mix blending by following weight percentage
Methyl methacrylate 75%-95%
Stearic acid 0.1%-10%
Methacrylic acid 0.1%-5%
Methacrylic acid glycol ester 0.1%-5%
Diisopropyl azodicarboxylate 0.1%-5%
Pearly-lustre mill base 0.3%-20%
B, above-mentioned raw materials is added reactor, polymerization under 20-90 ℃ of temperature, to denseness be 10%-20%;
C, above-mentioned slurry is injected mould, sealing is positioned in 30-72 ℃ the hot water carries out initial solidification, and carrying out not with vibrator to it therebetween, intermittent control shaking to initial solidification finishes;
D, mould is positioned over carries out the high temperature later stage in 80-120 ℃ the hot setting equipment and solidify, the time is 10-90 minute;
E, mould cool off under normal temperature environment, and the demoulding makes pearlite board;
F, the pearlite board after the demoulding is clipped on the mould, good seal around the mould only keeps a charging bole;
G, will be under 40 ℃ of-90 ℃ of temperature the polymeric denseness be that the transparent acrylic slurry of 10%-20% injects mould, make it evenly to be covered in the pearlite board surface, then charging bole is sealed, be positioned in 40 ℃-70 ℃ the hot water and solidify the demoulding.
3, the manufacture method of acryl pearlite board as claimed in claim 2 is characterized in that: the raw material weight umber proportioning of pearlite board is:
Methyl methacrylate 88.35%
Stearic acid 1%
Methacrylic acid 0.2%
Methacrylic acid glycol ester 0.3%
Diisopropyl azodicarboxylate 0.15%
Pearly-lustre mill base 10%
4, the manufacture method of acryl pearlite board as claimed in claim 2 is characterized in that: above-mentioned pearly-lustre mill base is one or more in pearl white, titanium dioxide, Aluminum Carbonate Basic, Bismuth Subcarbonate and the photochromic slurry of acid zincic acid lead sweat.
5, the manufacture method of acryl pearlite board as claimed in claim 2 is characterized in that: the polymerization temperature among the above-mentioned step b is 80 ℃.
6, the manufacture method of acryl pearlite board as claimed in claim 2 is characterized in that: the initial solidification hot water temperature among the above-mentioned step c is 60 ℃.
7, the manufacture method of acryl pearlite board as claimed in claim 2 is characterized in that: the hot setting temperature in the above-mentioned steps d is 100-105 ℃.
8, the manufacture method of acryl pearlite board as claimed in claim 2 is characterized in that: the polymerization temperature of the acrylic slurry in the above-mentioned step g is 80 ℃.
9, the manufacture method of acryl pearlite board as claimed in claim 2 is characterized in that: the denseness of the acrylic slurry in the above-mentioned step g is 15%.
10, the manufacture method of acryl pearlite board as claimed in claim 2 is characterized in that: the solidification value of the acrylic slurry in the above-mentioned step g is 60 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021257213A CN1183186C (en) | 2002-08-14 | 2002-08-14 | Acryl pearlite board and its producing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021257213A CN1183186C (en) | 2002-08-14 | 2002-08-14 | Acryl pearlite board and its producing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1392181A CN1392181A (en) | 2003-01-22 |
| CN1183186C true CN1183186C (en) | 2005-01-05 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021257213A Expired - Fee Related CN1183186C (en) | 2002-08-14 | 2002-08-14 | Acryl pearlite board and its producing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1183186C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103286954A (en) * | 2013-06-09 | 2013-09-11 | 平湖市中正塑板有限公司 | Production process of acrylic composite board |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103802263B (en) * | 2012-11-06 | 2016-03-23 | 珠海格力电器股份有限公司 | household appliance panel and manufacturing method thereof |
| CN105504627B (en) * | 2016-01-12 | 2017-10-13 | 陈礼根 | Raw material and its manufacture method for preparing three-dimensional pattern pearly-lustre decorative panel |
| CN106543620A (en) * | 2016-11-09 | 2017-03-29 | 安徽新胜塑料科技有限公司 | A kind of preparation method for making the acrylic board of sanitary apparatus |
| CN106565914A (en) * | 2016-11-09 | 2017-04-19 | 安徽新胜塑料科技有限公司 | Preparation method for pouring acrylic plate for lampshade plate |
| CN116001482A (en) * | 2022-12-07 | 2023-04-25 | 固安县朝阳生物科技有限公司 | Making process of dark flowers |
| CN115972721B (en) * | 2023-02-03 | 2024-08-27 | 厦门九牧研发有限公司 | Antibacterial acrylic plate and preparation method and application thereof |
-
2002
- 2002-08-14 CN CNB021257213A patent/CN1183186C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103286954A (en) * | 2013-06-09 | 2013-09-11 | 平湖市中正塑板有限公司 | Production process of acrylic composite board |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1392181A (en) | 2003-01-22 |
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