CN118231406A - Semiconductor device and method for forming the same - Google Patents
Semiconductor device and method for forming the same Download PDFInfo
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- CN118231406A CN118231406A CN202410215879.5A CN202410215879A CN118231406A CN 118231406 A CN118231406 A CN 118231406A CN 202410215879 A CN202410215879 A CN 202410215879A CN 118231406 A CN118231406 A CN 118231406A
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- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- RUFLMLWJRZAWLJ-UHFFFAOYSA-N nickel silicide Chemical compound [Ni]=[Si]=[Ni] RUFLMLWJRZAWLJ-UHFFFAOYSA-N 0.000 description 1
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- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
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- 239000000377 silicon dioxide Substances 0.000 description 1
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Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/80—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs
- H10D84/82—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components
- H10D84/83—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components of only insulated-gate FETs [IGFET]
- H10D84/85—Complementary IGFETs, e.g. CMOS
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/10—Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
- H10D62/117—Shapes of semiconductor bodies
- H10D62/118—Nanostructure semiconductor bodies
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/20—Electrodes characterised by their shapes, relative sizes or dispositions
- H10D64/27—Electrodes not carrying the current to be rectified, amplified, oscillated or switched, e.g. gates
- H10D64/311—Gate electrodes for field-effect devices
- H10D64/411—Gate electrodes for field-effect devices for FETs
- H10D64/511—Gate electrodes for field-effect devices for FETs for IGFETs
- H10D64/517—Gate electrodes for field-effect devices for FETs for IGFETs characterised by the conducting layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
Landscapes
- Insulated Gate Type Field-Effect Transistor (AREA)
Abstract
一种半导体器件,包括在第一栅极堆叠件的背侧上的背侧栅极蚀刻停止层(ESL),其中多个第一纳米结构与背侧栅极ESL重叠。背侧栅极ESL可以包括高k介电材料。半导体器件还包括在第一源极/漏极区之间延伸的多个第一纳米结构和在多个第一纳米结构上方并在第二源极/漏极区之间伸展的多个第二纳米结构。第一栅极堆叠件设置在多个第一纳米结构周围,并且在第一栅极堆叠件上方的第二栅极堆叠件设置于多个第二纳米结构周围。背侧栅极接触件延伸穿过背侧栅极ESL以电耦合到第一栅极堆叠件。本申请的实施例还公开了一种形成半导体器件的方法。
A semiconductor device includes a back gate etch stop layer (ESL) on the back side of a first gate stack, wherein a plurality of first nanostructures overlap the back gate ESL. The back gate ESL may include a high-k dielectric material. The semiconductor device also includes a plurality of first nanostructures extending between first source/drain regions and a plurality of second nanostructures extending above the plurality of first nanostructures and between second source/drain regions. The first gate stack is disposed around the plurality of first nanostructures, and a second gate stack above the first gate stack is disposed around the plurality of second nanostructures. A back gate contact extends through the back gate ESL to electrically couple to the first gate stack. An embodiment of the present application also discloses a method of forming a semiconductor device.
Description
技术领域Technical Field
本申请的实施例涉及半导体器件及其形成方法。Embodiments of the present application relate to semiconductor devices and methods of forming the same.
背景技术Background technique
半导体器件用于各种电子应用,诸如个人电脑、手机、数码相机和其他电子设备。半导体器件通常是通过在半导体衬底上顺序沉积绝缘层或介电层、导电层和半导体层,并使用光刻对各种材料层进行图案化以在其上形成电路组件和元件来制造的。Semiconductor devices are used in a variety of electronic applications, such as personal computers, cell phones, digital cameras, and other electronic devices. Semiconductor devices are typically manufactured by sequentially depositing insulating or dielectric layers, conductive layers, and semiconductor layers on a semiconductor substrate and patterning the various material layers using photolithography to form circuit components and elements thereon.
半导体行业通过不断减小最小部件尺寸,来不断提高各种电子元件(如晶体管、二极管、电阻器、电容器等)的集成密度,从而使更多的元件能够集成到给定的区域中。随着半导体行业进一步朝着增加器件密度、更高性能和更低成本的方向发展,来自制造和设计的挑战导致了堆叠器件配置,诸如包括互补场效应晶体管(CFET)的堆叠晶体管。然而,随着最小部件尺寸的减小,引入了附加的部件。The semiconductor industry continues to increase the integration density of various electronic components (such as transistors, diodes, resistors, capacitors, etc.) by continuously reducing the minimum feature size, so that more components can be integrated into a given area. As the semiconductor industry moves further towards increasing device density, higher performance and lower cost, challenges from manufacturing and design have led to stacked device configurations, such as stacked transistors including complementary field effect transistors (CFETs). However, as the minimum feature size decreases, additional components are introduced.
发明内容Summary of the invention
根据本申请的实施例的一个方面,提供了一种半导体器件,包括:多个第一纳米结构,多个第一纳米结构在第一源极/漏极区之间延伸;多个第二纳米结构,位于多个第一纳米结构上方,多个第二纳米结构在第二源极/漏极区之间延伸;第一栅极堆叠件,围绕多个第一纳米结构;第二栅极堆叠件,位于第一栅极堆叠件上方并且设置在多个第二纳米结构周围;背侧栅极蚀刻停止层,位于第一栅极堆叠件的背侧上,其中,多个第一纳米结构与背侧栅极蚀刻停止层重叠;以及背侧栅极接触件,电耦合到第一栅极堆叠件,其中,背侧栅极接触件延伸穿过背侧栅极蚀刻停止层到达第一栅极堆叠件的背侧。According to one aspect of an embodiment of the present application, a semiconductor device is provided, comprising: a plurality of first nanostructures, the plurality of first nanostructures extending between a first source/drain region; a plurality of second nanostructures, located above the plurality of first nanostructures, the plurality of second nanostructures extending between a second source/drain region; a first gate stack, surrounding the plurality of first nanostructures; a second gate stack, located above the first gate stack and arranged around the plurality of second nanostructures; a back gate etch stop layer, located on the back side of the first gate stack, wherein the plurality of first nanostructures overlap with the back gate etch stop layer; and a back gate contact, electrically coupled to the first gate stack, wherein the back gate contact extends through the back gate etch stop layer to reach the back side of the first gate stack.
根据本申请的实施例的另一个方面,提供了一种半导体器件,包括:器件层,器件层包括:第一晶体管,包括第一栅极堆叠件,其中,第一栅极堆叠件包括第一栅极电介质和第一栅电极;和第二晶体管,与第一晶体管垂直堆叠。半导体器件还包括:第一互连结构,位于器件层的前侧上;栅极蚀刻停止层,位于器件层的背侧上,其中,栅极蚀刻停止层包括高k介电材料;以及栅极接触件,位于器件层的背侧上,其中,栅极接触件延伸穿过栅极蚀刻停止层和第一栅极电介质以接触第一栅电极。According to another aspect of an embodiment of the present application, a semiconductor device is provided, comprising: a device layer, the device layer comprising: a first transistor, comprising a first gate stack, wherein the first gate stack comprises a first gate dielectric and a first gate electrode; and a second transistor, vertically stacked with the first transistor. The semiconductor device also comprises: a first interconnect structure, located on the front side of the device layer; a gate etch stop layer, located on the back side of the device layer, wherein the gate etch stop layer comprises a high-k dielectric material; and a gate contact, located on the back side of the device layer, wherein the gate contact extends through the gate etch stop layer and the first gate dielectric to contact the first gate electrode.
根据本申请的实施例的又一个方面,提供了一种形成半导体器件的方法,包括:在半导体层上方形成第一晶体管和第二晶体管,其中,第一晶体管和第二晶体管垂直堆叠;并且其中,背侧栅极蚀刻停止层设置在第一晶体管的第一栅极结构的背侧和半导体层之间;去除半导体层以暴露背侧栅极蚀刻停止层;在背侧栅极蚀刻停止层上方沉积背侧层间电介质;图案化穿过背侧层间电介质和背侧栅极蚀刻停止层的开口,以暴露第一栅极结构;以及在开口中形成背侧栅极接触件,其中,背侧栅极接触件延伸穿过背侧栅极蚀刻停止层以电连接到第一栅极结构。According to another aspect of an embodiment of the present application, a method for forming a semiconductor device is provided, comprising: forming a first transistor and a second transistor above a semiconductor layer, wherein the first transistor and the second transistor are vertically stacked; and wherein a back gate etch stop layer is disposed between a back side of a first gate structure of the first transistor and the semiconductor layer; removing the semiconductor layer to expose the back gate etch stop layer; depositing a back interlayer dielectric above the back gate etch stop layer; patterning an opening through the back interlayer dielectric and the back gate etch stop layer to expose the first gate structure; and forming a back gate contact in the opening, wherein the back gate contact extends through the back gate etch stop layer to be electrically connected to the first gate structure.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
当接合附图进行阅读时,从以下详细描述可最佳理解本公开的各个方面。应该强调,根据工业中的标准实践,各个部件未按比例绘制并且仅用于说明的目的。实际上,为了清楚的讨论,各个部件的尺寸可以任意地增大或减小。Various aspects of the present disclosure can be best understood from the following detailed description when read in conjunction with the accompanying drawings. It should be emphasized that, in accordance with standard practice in the industry, the various components are not drawn to scale and are only used for illustrative purposes. In fact, for the sake of clarity of discussion, the size of the various components can be arbitrarily increased or reduced.
图1示出了根据一些实施例的示例堆叠晶体管的透视图。FIG. 1 illustrates a perspective view of an example stacked transistor in accordance with some embodiments.
图2A、图2B、图3、图4、图5、图6、图7、图8A、图8B、图9、图10、图11、图12、图13、图14、图15、图16A和图16B是根据一些实施例制造堆叠晶体管的中间阶段的视图。2A, 2B, 3, 4, 5, 6, 7, 8A, 8B, 9, 10, 11, 12, 13, 14, 15, 16A, and 16B are views of intermediate stages in the manufacture of stacked transistors according to some embodiments.
图17、图18、图19、图20、图21、图22、图23、图24A和图24B是根据一些实施例的制造堆叠晶体管的中间阶段的视图。17 , 18 , 19 , 20 , 21 , 22 , 23 , 24A , and 24B are views of intermediate stages in fabricating a stacked transistor in accordance with some embodiments.
具体实施方式Detailed ways
以下公开内容提供了许多用于实现本公开的不同特征不同的实施例或实例。下面描述了组件和布置的具体实施例或实例以简化本公开。当然,这些仅是实例而不旨在限制。例如,在以下描述中,在第二部件上方或者上形成第一部件可以包括第一部件和第二部件直接接触形成的实施例,并且也可以包括在第一部件和第二部件之间可以形成附加的部件,从而使得第一部件和第二部件可以不直接接触的实施例。此外,本公开可以在各个示例中重复参考数字和/或字母。该重复是为了简单和清楚的目的,并且其本身不指示讨论的各个实施例和/或配置之间的关系。The following disclosure provides many different embodiments or examples for realizing different features of the present disclosure. Specific embodiments or examples of components and arrangements are described below to simplify the present disclosure. Of course, these are only examples and are not intended to be limiting. For example, in the following description, forming a first component above or on a second component may include an embodiment in which the first component and the second component are directly contacted, and may also include an embodiment in which an additional component may be formed between the first component and the second component so that the first component and the second component may not be in direct contact. In addition, the present disclosure may repeat reference numbers and/or letters in various examples. This repetition is for the purpose of simplicity and clarity, and does not itself indicate the relationship between the various embodiments and/or configurations discussed.
此外,为了便于描述,本文中可以使用诸如“在…下方”、“在…下面”、“下部”、“在…上面”、“上部”等的间隔关系术语,以描述如图中所示的一个元件或部件与另一元件或部件的关系。除了图中所示的方位外,间隔关系术语旨在包括器件在使用或操作工艺中的不同方位。装置可以以其它方式定位(旋转90度或在其它方位),并且在本文中使用的间隔关系描述符可以同样地作相应地解释。In addition, for ease of description, spacing relation terms such as "below", "beneath", "lower", "above", "upper", etc. may be used herein to describe the relationship of one element or component to another element or component as shown in the figures. The spacing relation terms are intended to encompass different orientations of the device in use or process of operation in addition to the orientation shown in the figures. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spacing relation descriptors used herein should be interpreted accordingly.
提供了诸如CFET的堆叠晶体管及其形成方法。在各种实施例中,堆叠晶体管包括两个垂直堆叠的晶体管,并且栅极蚀刻停止层(ESL)形成在堆叠晶体管的下部栅极堆叠件的背侧上。堆叠晶体管的沟道区可以与栅极ESL重叠。在一些实施例中,栅极ESL可以例如由k值至少为15的高k介电材料制成。A stacked transistor such as a CFET and a method for forming the same are provided. In various embodiments, the stacked transistor includes two vertically stacked transistors, and a gate etch stop layer (ESL) is formed on the back side of a lower gate stack of the stacked transistor. The channel region of the stacked transistor may overlap with the gate ESL. In some embodiments, the gate ESL may be made of a high-k dielectric material having a k value of at least 15, for example.
栅极ESL允许在背侧栅极接触件形成工艺期间在背侧栅接触件与堆叠晶体管的沟道区重叠的位置处将背侧栅极接触件形成至下部栅极堆叠件,而不会损坏沟道区。因此,当形成背侧栅极接触件时,不需要避免与沟道区重叠的位置,从而允许改进的布线灵活性。此外,因为沟道区能够直接与背侧栅极接触件重叠,所以沟道区可以被设计和制造为具有更大的宽度以改进器件速度。例如,通过增加沟道区的宽度,在实施例器件中已经观察到14.4%到19%之间的器件速度改进。结果,各种实施例允许改进的工艺集成、增加的布线灵活性和增加的器件性能。The gate ESL allows the back gate contact to be formed to the lower gate stack at a position where the back gate contact overlaps the channel region of the stacked transistor during the back gate contact formation process without damaging the channel region. Therefore, when forming the back gate contact, there is no need to avoid the position overlapping the channel region, thereby allowing improved wiring flexibility. In addition, because the channel region can directly overlap the back gate contact, the channel region can be designed and manufactured to have a larger width to improve device speed. For example, by increasing the width of the channel region, device speed improvements of between 14.4% and 19% have been observed in embodiment devices. As a result, various embodiments allow for improved process integration, increased wiring flexibility, and increased device performance.
图1示出了根据一些实施例的堆叠晶体管10(包括FET(晶体管)10U和10L)的示例。图1是三维视图,为了便于说明,省略了堆叠晶体管的一些部件。Fig. 1 shows an example of a stacked transistor 10 (including FETs (transistors) 10U and 10L) according to some embodiments. Fig. 1 is a three-dimensional view, and some components of the stacked transistor are omitted for ease of illustration.
堆叠晶体管包括多个垂直堆叠的FET。例如,堆叠晶体管可以包括第一器件类型(例如,n型/p型)的下部纳米结构FET 10L和第二器件类型(例如,p型/n型)的上部纳米结构FET 10U。当堆叠晶体管是CFET时,上部纳米结构FET 10U的第二器件类型与下部纳米结构FET 10L的第一器件类型相反。纳米结构FET 10U和10L包括半导体纳米结构26(包括下部半导体纳米结构26L和上部半导体纳米结构26U),其中半导体纳米结构26用作纳米结构FET的沟道区。下部半导体纳米结构26L用于下部纳米结构FET 10L,上部半导体纳米结构26U用于上部纳米结构FET 10U。在其他实施例中,堆叠晶体管也可以应用于其他类型的晶体管(例如,finFET(鳍式场效应晶体管)等)。The stacked transistor includes a plurality of vertically stacked FETs. For example, the stacked transistor may include a lower nanostructure FET 10L of a first device type (e.g., n-type/p-type) and an upper nanostructure FET 10U of a second device type (e.g., p-type/n-type). When the stacked transistor is a CFET, the second device type of the upper nanostructure FET 10U is opposite to the first device type of the lower nanostructure FET 10L. The nanostructure FETs 10U and 10L include a semiconductor nanostructure 26 (including a lower semiconductor nanostructure 26L and an upper semiconductor nanostructure 26U), wherein the semiconductor nanostructure 26 is used as a channel region of the nanostructure FET. The lower semiconductor nanostructure 26L is used for the lower nanostructure FET 10L, and the upper semiconductor nanostructure 26U is used for the upper nanostructure FET 10U. In other embodiments, the stacked transistor may also be applied to other types of transistors (e.g., finFET (fin field effect transistor), etc.).
栅极电介质78围绕相应的半导体纳米结构26。栅电极80(包括下部栅电极80L和上部栅电极80U)在栅极电介质78上方。源极/漏极区62(包括下部源极/源极区62L和上部源极/漏极区62U)设置在栅极电介质78和对应栅电极80的相对侧上。根据上下文,源极/漏极区62中的每个可以单独地或共同地指代源极或漏极。可以形成隔离部件(未示出)以分离源极/漏极区62中的期望的源极/漏极区和/或栅电极80中的期望的栅电极。The gate dielectric 78 surrounds the corresponding semiconductor nanostructure 26. The gate electrode 80 (including the lower gate electrode 80L and the upper gate electrode 80U) is above the gate dielectric 78. The source/drain region 62 (including the lower source/source region 62L and the upper source/drain region 62U) is disposed on opposite sides of the gate dielectric 78 and the corresponding gate electrode 80. Depending on the context, each of the source/drain regions 62 may be referred to as a source or a drain individually or collectively. Isolation features (not shown) may be formed to separate the desired source/drain region in the source/drain region 62 and/or the desired gate electrode in the gate electrode 80.
图1进一步示出了后面附图中使用的参考截面。截面A-A’是平行于堆叠晶体管10的半导体纳米结构26的纵轴、并且在例如堆叠晶体管10的源极/漏极区62之间的电流方向上的垂直截面。截面B-B’是垂直于截面A-A’、并且沿着堆叠晶体管10的栅电极80的纵轴的垂直截面。1 further illustrates reference cross sections used in the following figures. Cross section A-A' is a vertical cross section parallel to the longitudinal axis of the semiconductor nanostructure 26 of the stacked transistor 10 and in the direction of current flow, for example, between the source/drain regions 62 of the stacked transistor 10. Cross section B-B' is a vertical cross section perpendicular to cross section A-A' and along the longitudinal axis of the gate electrode 80 of the stacked transistor 10.
图2A至图16B示出了根据一些实施例的堆叠晶体管(如图1所示)形成过程中的中间阶段的截面图。图2A、图2B、图3和图4显示了一般截面视图。图5显示了类似于图1的透视图。图6、图7、图8A、图9、图10和图16A显示了与图1中的参考截面A-A’类似的截面图。图8B、图11、图12、图13、图14、图15和图16B显示了与图1中的参考截面B-B'类似的截面图。Figures 2A to 16B show cross-sectional views of intermediate stages in the formation of a stacked transistor (as shown in Figure 1) according to some embodiments. Figures 2A, 2B, 3, and 4 show general cross-sectional views. Figure 5 shows a perspective view similar to Figure 1. Figures 6, 7, 8A, 9, 10, and 16A show cross-sectional views similar to reference section A-A' in Figure 1. Figures 8B, 11, 12, 13, 14, 15, and 16B show cross-sectional views similar to reference section BB' in Figure 1.
在图2A和图2B中,分别提供了两个衬底12L和12U。图2A所示为衬底12L,图2B所示为衬底12U。在随后的工艺中,衬底12U可以接合在衬底12L上(见图3)。这样,衬底12L可以被称为下部衬底12L,并且衬底12U也可以被称为上部衬底12U。衬底12L和12U中的每个可以是半导体衬底,诸如体半导体、绝缘体上部半导体(SOI)衬底等,其可以是掺杂(例如,用p型或n型掺杂剂)或未掺杂的。衬底12L和12U可以各自是晶圆,诸如硅晶圆。通常,SOI衬底是在绝缘体层上形成的半导体材料层。绝缘体层可以是例如埋入氧化物(BOX)层、氧化硅层等。绝缘体层被提供在衬底上,通常是硅或玻璃衬底。也可以使用其他衬底,诸如多层或梯度衬底。在一些实施例中,衬底12L和12U的半导体材料可以包括:硅;锗;化合物半导体,包括碳掺杂的硅、砷化镓、磷化镓、磷化铟、砷化铟和/或锑化铟;合金半导体,包括硅锗、砷磷化镓、砷化铝铟、砷化镓铝、砷化镓铟、磷化镓铟和/或砷磷化镓铟;或其组合。在一些实施例中,衬底12L和12U中的每个可以包括嵌入的CMP停止层(未单独示出),例如嵌入(例如,夹在)硅材料层之间的硅锗层。In FIG. 2A and FIG. 2B , two substrates 12L and 12U are provided, respectively. FIG. 2A shows substrate 12L, and FIG. 2B shows substrate 12U. In the subsequent process, substrate 12U can be bonded to substrate 12L (see FIG. 3 ). In this way, substrate 12L can be referred to as lower substrate 12L, and substrate 12U can also be referred to as upper substrate 12U. Each of substrates 12L and 12U can be a semiconductor substrate, such as a bulk semiconductor, a semiconductor on insulator (SOI) substrate, etc., which can be doped (e.g., with p-type or n-type dopants) or undoped. Substrates 12L and 12U can each be a wafer, such as a silicon wafer. Typically, an SOI substrate is a semiconductor material layer formed on an insulator layer. The insulator layer can be, for example, a buried oxide (BOX) layer, a silicon oxide layer, etc. The insulator layer is provided on a substrate, typically a silicon or glass substrate. Other substrates, such as multilayer or gradient substrates, can also be used. In some embodiments, the semiconductor material of substrates 12L and 12U may include: silicon; germanium; compound semiconductors including carbon-doped silicon, gallium arsenide, gallium phosphide, indium phosphide, indium arsenide, and/or indium antimonide; alloy semiconductors including silicon germanium, gallium arsenic phosphide, aluminum indium arsenide, gallium aluminum arsenide, gallium indium arsenide, gallium indium phosphide, and/or gallium indium arsenic phosphide; or combinations thereof. In some embodiments, each of substrates 12L and 12U may include an embedded CMP stop layer (not separately shown), such as a silicon germanium layer embedded (e.g., sandwiched) between silicon material layers.
在上部衬底12U上方形成多层堆叠件14。多层堆叠件14包括交替的伪半导体层14A、14C和半导体层14B。如随后更详细地描述的,伪半导体层14A和14C将被去除,并且半导体层14B将被图案化以形成堆叠晶体管的沟道区。例如,设置在伪半导体层14C上方的半导体层14B可以被图案化以形成堆叠晶体管的第一晶体管的沟道区,并且设置在伪半导体层14C下方的半导体层14可以被图案化以形成堆叠晶体管的第二晶体管的沟道区。A multilayer stack 14 is formed over the upper substrate 12U. The multilayer stack 14 includes alternating dummy semiconductor layers 14A, 14C and semiconductor layers 14B. As described in more detail later, the dummy semiconductor layers 14A and 14C will be removed, and the semiconductor layer 14B will be patterned to form a channel region of a stacked transistor. For example, the semiconductor layer 14B disposed above the dummy semiconductor layer 14C may be patterned to form a channel region of a first transistor of the stacked transistor, and the semiconductor layer 14 disposed below the dummy semiconductor layer 14C may be patterned to form a channel region of a second transistor of the stacked transistor.
伪半导体层14A和14C由从衬底12L和12U的候选半导体材料中选择的第一半导体材料形成。半导体层14B由也从衬底12L和12U的候选半导体材料中选择的一种或多种第二半导体材料形成。伪半导体层14C上方的半导体层14B可以由相同于或不同于伪半导体层14C下方的半导体层14B的半导体材料形成。在一些实施例中,每个半导体层14B由适合于p型器件和n型器件的半导体材料(诸如硅)形成。在一些实施例中,伪半导体层14C上方的半导体层14B由适合于p型器件的半导体材料(诸如锗或硅锗)形成,并且伪半导体层14C下方的半导体层14B由适合于n型器件的半导体材料(诸如硅或碳掺杂硅)形成。在一些实施例中,伪半导体层14C下方的半导体层14B由适合于p型器件的半导体材料(诸如锗或硅锗),并且伪半导体层14C上方的半导体层14B由适合于n型器件的半导体材料(诸如硅或碳掺杂硅)形成。The dummy semiconductor layers 14A and 14C are formed of a first semiconductor material selected from the candidate semiconductor materials of the substrates 12L and 12U. The semiconductor layer 14B is formed of one or more second semiconductor materials also selected from the candidate semiconductor materials of the substrates 12L and 12U. The semiconductor layer 14B above the dummy semiconductor layer 14C may be formed of a semiconductor material that is the same as or different from the semiconductor layer 14B below the dummy semiconductor layer 14C. In some embodiments, each semiconductor layer 14B is formed of a semiconductor material suitable for a p-type device and an n-type device (such as silicon). In some embodiments, the semiconductor layer 14B above the dummy semiconductor layer 14C is formed of a semiconductor material suitable for a p-type device (such as germanium or silicon germanium), and the semiconductor layer 14B below the dummy semiconductor layer 14C is formed of a semiconductor material suitable for an n-type device (such as silicon or carbon-doped silicon). In some embodiments, the semiconductor layer 14B below the dummy semiconductor layer 14C is formed of a semiconductor material suitable for a p-type device (such as germanium or silicon germanium), and the semiconductor layer 14B above the dummy semiconductor layer 14C is formed of a semiconductor material suitable for an n-type device (such as silicon or carbon-doped silicon).
半导体层14B的半导体材料与伪半导体层14A和14C的半导体材料不同,并且相对于伪半导体层14A和14C的半导体材料具有高蚀刻选择性。这样,在随后的处理中,伪半导体层14A和14C的材料可以以比半导体层14B的材料更快的速率被去除。此外,伪半导体层14C的半导体材料相对于伪半导体层14A的半导体材料具有高蚀刻选择性。这样,可以在后续工艺步骤中选择性地去除伪半导体层14C的材料,而不完全去除伪半导体层14A的材料。在一些实施例中,伪半导体层14A由硅锗形成,半导体层14B由硅形成,并且伪半导体14C可以由锗形成、或由锗原子百分比高于伪半导体层14A的硅锗形成。The semiconductor material of semiconductor layer 14B is different from the semiconductor material of dummy semiconductor layers 14A and 14C, and has a high etching selectivity relative to the semiconductor material of dummy semiconductor layers 14A and 14C. In this way, in subsequent processing, the material of dummy semiconductor layers 14A and 14C can be removed at a faster rate than the material of semiconductor layer 14B. In addition, the semiconductor material of dummy semiconductor layer 14C has a high etching selectivity relative to the semiconductor material of dummy semiconductor layer 14A. In this way, the material of dummy semiconductor layer 14C can be selectively removed in subsequent process steps without completely removing the material of dummy semiconductor layer 14A. In some embodiments, dummy semiconductor layer 14A is formed of silicon germanium, semiconductor layer 14B is formed of silicon, and dummy semiconductor 14C can be formed of germanium, or formed of silicon germanium with a higher atomic percentage of germanium than dummy semiconductor layer 14A.
多层堆叠件14被示为包括特定数量的伪半导体层14A、14C和半导体层14B。应当理解,多层堆叠件14可以包括任意数量的伪半导体层14A、14C和/或半导体层14B。多层堆叠件14的每层可通过诸如气相外延(VPE)或分子束外延(MBE)的工艺生长,通过诸如化学气相沉积(CVD)或原子层沉积(ALD)等的工艺沉积。The multilayer stack 14 is shown as including a specific number of dummy semiconductor layers 14A, 14C and semiconductor layers 14B. It should be understood that the multilayer stack 14 may include any number of dummy semiconductor layers 14A, 14C and/or semiconductor layers 14B. Each layer of the multilayer stack 14 may be grown by a process such as vapor phase epitaxy (VPE) or molecular beam epitaxy (MBE), deposited by a process such as chemical vapor deposition (CVD) or atomic layer deposition (ALD), etc.
仍然参考图2B,在多层堆叠件14上方沉积ESL 16。在随后的工艺步骤中,ESL 16可用于控制蚀刻工艺,以在与堆叠晶体管的沟道区重叠的区域中形成背侧栅极接触件(见图10至图16B)。因此,ESL 16也可以被称为栅极ESL或背侧栅极ESL。ESL 16可以由相对于沟道区的材料(例如半导体层14B的材料)和随后形成的栅极堆叠件的材料提供蚀刻选择性的材料形成。例如,ESL 16可以是或包括高k介电材料,诸如氧化铪等。在一些实施例中,ESL 16的k值至少为15,并且ESL 16具有在3nm至6nm范围内的厚度T1。已经观察到,当ESL 16具有上述范围内的k值和厚度时,其适合于形成背侧栅极接触件。例如,当ESL 16的厚度小于3nm时,背侧接触件形成可能会不可接受地损坏器件的其他部件(例如,栅极堆叠件和/或沟道区),并引起泄漏问题。当ESL 16具有大于6nm的厚度时,蚀刻通过可能过于困难和/或冗长,从而使制造工艺复杂化。ESL 16可以通过任何合适的工艺(诸如CVD、ALD等)沉积。Still referring to FIG. 2B , an ESL 16 is deposited over the multilayer stack 14. In subsequent process steps, the ESL 16 may be used to control an etching process to form a backside gate contact in a region overlapping the channel region of the stacked transistor (see FIGS. 10 to 16B ). Therefore, the ESL 16 may also be referred to as a gate ESL or a backside gate ESL. The ESL 16 may be formed of a material that provides etching selectivity relative to the material of the channel region (e.g., the material of the semiconductor layer 14B) and the material of the subsequently formed gate stack. For example, the ESL 16 may be or include a high-k dielectric material such as hafnium oxide. In some embodiments, the k value of the ESL 16 is at least 15, and the ESL 16 has a thickness T 1 in the range of 3 nm to 6 nm. It has been observed that when the ESL 16 has a k value and a thickness in the above range, it is suitable for forming a backside gate contact. For example, when the thickness of ESL 16 is less than 3 nm, backside contact formation may unacceptably damage other components of the device (e.g., gate stack and/or channel region) and cause leakage issues. When ESL 16 has a thickness greater than 6 nm, etching through may be too difficult and/or lengthy, thereby complicating the manufacturing process. ESL 16 may be deposited by any suitable process (such as CVD, ALD, etc.).
在ESL 16上方沉积半导体层20。在一些实施例中,半导体层20由可随后被图案化为半导体鳍的材料(诸如非晶硅)制成。还可以选择半导体层20的厚度T2,使得其足够厚以随后在半导体层20中形成半导体带(也称为半导体鳍)的图案。例如,半导体层20的厚度T2可以是至少100nm。半导体层20可以通过任何合适的工艺(诸如CVD、ALD等)沉积。A semiconductor layer 20 is deposited over ESL 16. In some embodiments, semiconductor layer 20 is made of a material that can be subsequently patterned into semiconductor fins, such as amorphous silicon. The thickness T2 of semiconductor layer 20 can also be selected so that it is thick enough to subsequently form a pattern of semiconductor strips (also referred to as semiconductor fins) in semiconductor layer 20. For example, the thickness T2 of semiconductor layer 20 can be at least 100 nm. Semiconductor layer 20 can be deposited by any suitable process, such as CVD, ALD, etc.
如图2A和图2B所示,接合层18L和18U分别沉积在衬底12L和12U上方。具体地,接合层18L可以沉积在衬底12L上方,并且接合层18U可以沉积在半导体层20上方。接合层18L和18U可以通过任何合适的工艺沉积,诸如物理气相沉积(PVD)、CVD、ALD等。接合层18L和18U可以有助于在后续工艺中将下部衬底12L接合到上部衬底12U(见图3)。接合层18L和18U中的每个可以包括适合于随后的介电对介电接合工艺的绝缘材料。接合层18L和18U的示例材料包括氧化硅(例如,SiO2)、氮化硅、氮氧化硅、碳氮化硅、碳氮氧化硅等。接合层18L的材料组分可以与接合层18U的材料组分相同或不同。在一些实施例中,接合层18L的厚度T3和接合层18U的厚度T4可各自为至少50nm,以提供用于后续接合工艺的足够厚的接合层。厚度T3和T4可以彼此相等或不同。As shown in Figures 2A and 2B, bonding layers 18L and 18U are deposited on substrates 12L and 12U, respectively. Specifically, bonding layer 18L can be deposited on substrate 12L, and bonding layer 18U can be deposited on semiconductor layer 20. Bonding layers 18L and 18U can be deposited by any suitable process, such as physical vapor deposition (PVD), CVD, ALD, etc. Bonding layers 18L and 18U can help to bond lower substrate 12L to upper substrate 12U (see Figure 3) in subsequent processes. Each of bonding layers 18L and 18U can include an insulating material suitable for subsequent dielectric-to-dielectric bonding processes. Example materials of bonding layers 18L and 18U include silicon oxide (e.g., SiO2 ), silicon nitride, silicon oxynitride, silicon carbonitride, silicon carbonitride, etc. The material composition of bonding layer 18L can be the same or different from the material composition of bonding layer 18U. In some embodiments, the thickness T3 of the bonding layer 18L and the thickness T4 of the bonding layer 18U may each be at least 50 nm to provide a sufficiently thick bonding layer for a subsequent bonding process. The thicknesses T3 and T4 may be equal to or different from each other.
在图3中,具有多层堆叠件14、ESL 16和半导体层20的上部衬底12U被翻转并接合到下部衬底12L。接合结构包括:下部衬底12L;在下部衬底12L上方的接合层18L和18U;接合层18L和18U上方的半导体层20、半导体层20上方的ESL 16;ESL 16上方的多层堆叠件14和多层堆叠件14上方的上部衬底12U。具体地,接合层18L和18U可以使用合适的技术接合在一起,诸如介电对介电接合等。在接合之后,下接合层18L和上接合层18U可以统称为接合层18。接合层18可以具有或者可以不具有设置在其中的接合层18L与接合层18U相遇的界面。In FIG3 , the upper substrate 12U having the multilayer stack 14, the ESL 16, and the semiconductor layer 20 is flipped and bonded to the lower substrate 12L. The bonding structure includes: the lower substrate 12L; the bonding layers 18L and 18U above the lower substrate 12L; the semiconductor layer 20 above the bonding layers 18L and 18U, and the ESL 16 above the semiconductor layer 20; the multilayer stack 14 above the ESL 16 and the upper substrate 12U above the multilayer stack 14. Specifically, the bonding layers 18L and 18U can be bonded together using a suitable technique, such as dielectric-to-dielectric bonding, etc. After bonding, the lower bonding layer 18L and the upper bonding layer 18U can be collectively referred to as a bonding layer 18. The bonding layer 18 may or may not have an interface where the bonding layer 18L and the bonding layer 18U meet.
在一些实施例中,介电对介电接合工艺包括对接合层18L和18U中的一个或多个施加表面处理,以在接合层18R和18U的暴露表面形成羟基(OH)。表面处理可以包括等离子体处理,诸如氮(N2)等离子体处理。在等离子体处理之后,表面处理可以还包括清洁工艺,该清洁工艺可以应用于接合层18L和18U中的一个或多个。然后,可以将接合层18U放置在接合层18L上方并与接合层18L对准。然后将两个接合层18L和18U彼此压靠,以启动上部衬底12U与下部衬底12L的预接合。预接合应在室温下进行(例如,在20℃至28℃的范围内)。在预接合之后,可以通过例如将衬底12L和12U加热到300℃至500℃的温度来应用退火工艺。退火工艺触发接合层18L和18U之间共价接合的形成。In some embodiments, the dielectric-to-dielectric bonding process includes applying a surface treatment to one or more of the bonding layers 18L and 18U to form hydroxyl groups (OH) on the exposed surfaces of the bonding layers 18R and 18U. The surface treatment may include a plasma treatment, such as a nitrogen ( N2 ) plasma treatment. After the plasma treatment, the surface treatment may also include a cleaning process, which may be applied to one or more of the bonding layers 18L and 18U. Then, the bonding layer 18U may be placed above the bonding layer 18L and aligned with the bonding layer 18L. The two bonding layers 18L and 18U are then pressed against each other to initiate pre-bonding of the upper substrate 12U with the lower substrate 12L. The pre-bonding should be performed at room temperature (e.g., in the range of 20°C to 28°C). After the pre-bonding, an annealing process may be applied by, for example, heating the substrates 12L and 12U to a temperature of 300°C to 500°C. The annealing process triggers the formation of a covalent bond between the bonding layers 18L and 18U.
在图4中,采用减薄工艺将上部衬底12U的厚度减小到所需厚度,形成半导体层14B’。减薄工艺可以包括研磨工艺、化学机械抛光(CMP)、回蚀刻工艺、其组合等。减薄工艺可以减小上部衬底12U的厚度以匹配每个半导体层14B的厚度。在随后的工艺步骤中,由减薄的上部衬底12U形成的半导体层14B’可以被图案化,以提供用于堆叠晶体管的上部纳米结构FET的纳米结构(例如,沟道区),并且半导体层14B’可以被称为多层堆叠件14的部件。In FIG4 , a thinning process is used to reduce the thickness of the upper substrate 12U to a desired thickness to form a semiconductor layer 14B′. The thinning process may include a grinding process, chemical mechanical polishing (CMP), an etch-back process, a combination thereof, and the like. The thinning process may reduce the thickness of the upper substrate 12U to match the thickness of each semiconductor layer 14B. In subsequent process steps, the semiconductor layer 14B′ formed by the thinned upper substrate 12U may be patterned to provide a nanostructure (e.g., a channel region) of an upper nanostructure FET for a stacked transistor, and the semiconductor layer 14B′ may be referred to as a component of the multilayer stack 14.
在图5中,多层堆叠件14、ESL 16和半导体层20被图案化,以形成从半导体层20向上延伸的半导体带28。在图5和随后的附图中,仅为了便于说明,省略了半导体层20下面的层(例如,接合层18和下部衬底12L)。应当理解,除非另有指示,否则这些层保持在半导体层20下方。每个半导体带28包括半导体带20’(半导体层20的图案化部分)、ESL 16的图案化部分和多层堆叠件22。多层堆叠件22的堆叠部件在下文中被称为纳米结构。具体地,每个多层堆叠件22包括由伪半导体层14A的材料图案化的伪纳米结构24A;由伪半导体层14C的材料图案化的伪纳米结构24B;由伪半导体层14C下面的半导体层14B图案化的下部半导体纳米结构26L(见图4);以及由伪半导体层14C上方的半导体层14B/14B’图案化的上部半导体纳米结构26U(见图4)。伪纳米结构24A和伪纳米结构24B可以进一步统称为伪纳米结构24,并且下部半导体纳米结构26L和上部半导体纳米结构26U可以进一步合称为半导体纳米结构26。In FIG5 , the multilayer stack 14, the ESL 16, and the semiconductor layer 20 are patterned to form semiconductor strips 28 extending upward from the semiconductor layer 20. In FIG5 and subsequent figures, the layers below the semiconductor layer 20 (e.g., the bonding layer 18 and the lower substrate 12L) are omitted for ease of illustration only. It should be understood that these layers remain below the semiconductor layer 20 unless otherwise indicated. Each semiconductor strip 28 includes a semiconductor strip 20′ (a patterned portion of the semiconductor layer 20), a patterned portion of the ESL 16, and a multilayer stack 22. The stacked components of the multilayer stack 22 are hereinafter referred to as nanostructures. Specifically, each multilayer stack 22 includes a pseudo nanostructure 24A patterned by the material of the pseudo semiconductor layer 14A; a pseudo nanostructure 24B patterned by the material of the pseudo semiconductor layer 14C; a lower semiconductor nanostructure 26L patterned by the semiconductor layer 14B below the pseudo semiconductor layer 14C (see FIG. 4 ); and an upper semiconductor nanostructure 26U patterned by the semiconductor layer 14B/14B′ above the pseudo semiconductor layer 14C (see FIG. 4 ). The pseudo nanostructure 24A and the pseudo nanostructure 24B may be further collectively referred to as a pseudo nanostructure 24, and the lower semiconductor nanostructure 26L and the upper semiconductor nanostructure 26U may be further collectively referred to as a semiconductor nanostructure 26.
下部半导体纳米结构26L将为堆叠晶体管的下部纳米结构FET提供沟道区。上部半导体纳米结构26U将为堆叠晶体管的上部纳米结构FET提供沟道区。直接在伪纳米结构24B上方/下方(例如,与伪纳米结构接触)的半导体纳米结构26可以用于隔离,并且可以用作或可以不用作堆叠晶体管的沟道区。伪纳米结构24B随后将被隔离结构替换,该隔离结构可以限定下部纳米结构FET和上部纳米结构FET的边界。The lower semiconductor nanostructure 26L will provide a channel region for the lower nanostructure FET of the stacked transistor. The upper semiconductor nanostructure 26U will provide a channel region for the upper nanostructure FET of the stacked transistor. The semiconductor nanostructure 26 directly above/below the pseudo nanostructure 24B (e.g., in contact with the pseudo nanostructure) can be used for isolation and may or may not be used as a channel region for the stacked transistor. The pseudo nanostructure 24B will then be replaced by an isolation structure that can define the boundary of the lower nanostructure FET and the upper nanostructure FET.
半导体鳍和纳米结构可以通过任何合适的方法图案化。例如,图案化工艺可以包括一个或多个光刻工艺,包括双重图案化或多重图案化工艺。通常,双重图案化或多重图案化工艺将光刻和自对准工艺相接合,从而允许创建具有例如比使用单一直接光刻工艺可获得的节距更小的节距的图案。例如,在一个实施例中,在衬底上形成牺牲层,并使用光刻工艺将其图案化。使用自对准工艺在图案化牺牲层旁边形成间隔件。然后去除牺牲层,然后剩余的间隔件可以用作图案化工艺的蚀刻掩模,以蚀刻第一、第二和第三半导体材料的层以及半导体层20。蚀刻可以通过任何可接受的蚀刻工艺进行,诸如反应离子蚀刻(RIE)、中性束蚀刻(NBE)等,或其组合。蚀刻可以是各向异性的。The semiconductor fins and nanostructures may be patterned by any suitable method. For example, the patterning process may include one or more photolithography processes, including double patterning or multiple patterning processes. Typically, double patterning or multiple patterning processes combine photolithography and self-alignment processes, thereby allowing the creation of patterns having, for example, a pitch smaller than that obtainable using a single direct photolithography process. For example, in one embodiment, a sacrificial layer is formed on a substrate and patterned using a photolithography process. Spacers are formed next to the patterned sacrificial layer using a self-alignment process. The sacrificial layer is then removed, and the remaining spacers can then be used as an etching mask for the patterning process to etch the first, second, and third semiconductor material layers and the semiconductor layer 20. Etching may be performed by any acceptable etching process, such as reactive ion etching (RIE), neutral beam etching (NBE), etc., or a combination thereof. The etching may be anisotropic.
如图5所示,STI区32形成在半导体层20上方和相邻半导体带28之间。STI区32可以包括介电衬垫和在介电衬垫上方的介电材料。介电衬垫和介电材料中的每个可以包括诸如氧化硅的氧化物、诸如氮化硅的氮化物等,或者它们的组合。STI区32的形成可以包括沉积介电层,并执行平坦化工艺,诸如化学机械抛光(CMP)工艺、机械抛光工艺等,以去除介电材料的过量部分。沉积工艺可以包括ALD、高密度等离子体CVD(HDP-CVD)、可流动CVD(FCVD)等,或其组合。在一些实施例中,STI区32包括通过FCVD工艺、随后进行退火工艺形成的氧化硅。然后,介电层被凹陷以限定STI区32。介电层可以凹陷,使得半导体带28(包括多层堆叠件22和ESL 16)的上部比剩余的STI区32突出得更高。As shown in FIG. 5 , STI regions 32 are formed above semiconductor layer 20 and between adjacent semiconductor strips 28. STI regions 32 may include a dielectric liner and a dielectric material above the dielectric liner. Each of the dielectric liner and the dielectric material may include an oxide such as silicon oxide, a nitride such as silicon nitride, or the like, or a combination thereof. The formation of STI regions 32 may include depositing a dielectric layer and performing a planarization process such as a chemical mechanical polishing (CMP) process, a mechanical polishing process, or the like to remove excess portions of the dielectric material. The deposition process may include ALD, high density plasma CVD (HDP-CVD), flowable CVD (FCVD), or the like, or a combination thereof. In some embodiments, STI regions 32 include silicon oxide formed by an FCVD process followed by an annealing process. Then, the dielectric layer is recessed to define STI regions 32. The dielectric layer may be recessed so that the upper portion of semiconductor strip 28 (including multilayer stack 22 and ESL 16) protrudes higher than the remaining STI regions 32.
在形成STI区32之后,可以在半导体带28的上部(比STI区32突出得更高的部分)的侧壁上并沿着该侧壁形成伪栅极堆叠件42。形成伪栅极堆叠件42可以包括在半导体带28上形成伪介电层36。伪介电层36可以由诸如氧化硅、氮化硅、其组合等形成或包括诸如氧化硅、氮化硅、其组合等,并且可以根据可接受的技术沉积或热生长。在伪介电层36上方形成伪栅极层38。伪栅极层38可以例如通过物理气相沉积(PVD)、CVD或其他技术沉积,然后诸如通过CMP工艺平坦化。伪栅极层38的材料是导电的或不导电的,并且可以从包括非晶硅、多晶硅(多晶硅)、多晶硅锗(poly-SiGe)等的组中选择。掩模层40形成在平坦化的伪栅极层38上方,并且可以包括诸如氮化硅、氮氧化硅等材料。接下来,可以通过光刻和蚀刻工艺将掩模层40图案化以形成掩模,然后使用掩模来蚀刻和图案化伪栅极层38,以及可能的伪介电层36。掩模层40、伪栅极层38和伪介电层36的剩余部分形成伪栅极堆叠件42。After forming the STI region 32, a dummy gate stack 42 may be formed on and along the sidewalls of the upper portion of the semiconductor strip 28 (the portion protruding higher than the STI region 32). Forming the dummy gate stack 42 may include forming a dummy dielectric layer 36 on the semiconductor strip 28. The dummy dielectric layer 36 may be formed of or include materials such as silicon oxide, silicon nitride, combinations thereof, and the like, and may be deposited or thermally grown according to acceptable techniques. A dummy gate layer 38 is formed over the dummy dielectric layer 36. The dummy gate layer 38 may be deposited, for example, by physical vapor deposition (PVD), CVD, or other techniques, and then planarized, such as by a CMP process. The material of the dummy gate layer 38 is conductive or non-conductive, and may be selected from a group including amorphous silicon, polycrystalline silicon (poly-Si), polycrystalline silicon germanium (poly-SiGe), and the like. A mask layer 40 is formed over the planarized dummy gate layer 38, and may include materials such as silicon nitride, silicon oxynitride, and the like. Next, mask layer 40 may be patterned by photolithography and etching processes to form a mask, which is then used to etch and pattern dummy gate layer 38, and possibly dummy dielectric layer 36. The remaining portions of mask layer 40, dummy gate layer 38, and dummy dielectric layer 36 form dummy gate stack 42.
在图6中,栅极间隔件44沿着伪栅极堆叠件42的侧壁形成。栅极间隔件44可以通过共形地形成一个或多个介电层并随后各向异性地蚀刻介电层来形成。可应用的介电材料可以包括氧化硅、氮化硅、氮氧化硅、碳氮氧化硅等,其可以通过诸如CVD、ALD等的沉积工艺形成。6, gate spacers 44 are formed along the sidewalls of dummy gate stack 42. Gate spacers 44 may be formed by conformally forming one or more dielectric layers and then anisotropically etching the dielectric layers. Applicable dielectric materials may include silicon oxide, silicon nitride, silicon oxynitride, silicon carbon nitride oxide, etc., which may be formed by deposition processes such as CVD, ALD, etc.
随后,在半导体带28中形成源极/漏极凹陷46。源极/漏极凹陷46通过蚀刻形成,并且可以延伸穿过多层堆叠件22、穿过ESL 16并进入半导体带20’。源极/漏极凹陷46的底表面可以位于隔离区32的顶表面上方、下方或与隔离区32的顶表面齐平的水平处。在蚀刻工艺中,栅极间隔件44和伪栅极堆叠件42掩蔽半导体带28的一些部分。蚀刻可以包括单个蚀刻工艺或多个蚀刻工艺。定时蚀刻工艺可用于在源极/漏极凹陷46达到所需深度时停止对源极/源极凹陷46的蚀刻。Subsequently, source/drain recesses 46 are formed in semiconductor strip 28. Source/drain recesses 46 are formed by etching and may extend through multilayer stack 22, through ESL 16, and into semiconductor strip 20'. The bottom surface of source/drain recess 46 may be located above, below, or at a level flush with the top surface of isolation region 32. During the etching process, gate spacers 44 and dummy gate stack 42 mask portions of semiconductor strip 28. Etching may include a single etching process or multiple etching processes. A timed etching process may be used to stop etching source/source recess 46 when source/drain recess 46 reaches a desired depth.
在图7中,形成内部间隔件54和介电隔离层56。形成内部间隔件54和介电隔离层56可以包括蚀刻工艺,该蚀刻工艺横向蚀刻伪纳米结构24A并去除伪纳米结构24B。蚀刻工艺可以是各向同性的,并且可以对伪纳米结构24的材料是选择性的,使得伪纳米结构24以比半导体纳米结构26更快的速率被蚀刻。蚀刻工艺也可以对伪纳米结构24B的材料是选择性的,使得伪纳米结构24B以比伪纳米结构性24A更快的速率被蚀刻。以这种方式,伪纳米结构24B可以从下部半导体纳米结构26L(共同)和上部半导体纳米结构26U(共同)之间完全去除,而不完全去除伪纳米结构24A。在伪纳米结构24B由具有高锗原子百分比的锗或硅锗形成、伪纳米结构24A由具有低锗原子百分比的硅锗形成、以及半导体纳米结构26由不含锗的硅形成的一些实施例中,蚀刻工艺可包括使用氯气的干蚀刻工艺(利用或不利用等离子体)。由于伪栅极堆叠件42围绕半导体纳米结构26的侧壁周围(见图5),伪栅极堆叠件42可以支撑上部半导体纳米结构26U,使得上部半导体纳米结构26U在去除伪纳米结构24B时不会塌陷。此外,尽管伪纳米结构24A的侧壁被示为在蚀刻之后是直的,但是侧壁可以是凹的或凸的。In FIG. 7 , an internal spacer 54 and a dielectric isolation layer 56 are formed. The formation of the internal spacer 54 and the dielectric isolation layer 56 may include an etching process that laterally etches the pseudo nanostructure 24A and removes the pseudo nanostructure 24B. The etching process may be isotropic and may be selective to the material of the pseudo nanostructure 24, so that the pseudo nanostructure 24 is etched at a faster rate than the semiconductor nanostructure 26. The etching process may also be selective to the material of the pseudo nanostructure 24B, so that the pseudo nanostructure 24B is etched at a faster rate than the pseudo nanostructure 24A. In this way, the pseudo nanostructure 24B may be completely removed from between the lower semiconductor nanostructure 26L (common) and the upper semiconductor nanostructure 26U (common) without completely removing the pseudo nanostructure 24A. In some embodiments where the pseudo nanostructure 24B is formed of germanium or silicon germanium with a high atomic percentage of germanium, the pseudo nanostructure 24A is formed of silicon germanium with a low atomic percentage of germanium, and the semiconductor nanostructure 26 is formed of silicon without germanium, the etching process may include a dry etching process using chlorine gas (with or without plasma). Since the pseudo gate stack 42 surrounds the sidewalls of the semiconductor nanostructure 26 (see FIG. 5 ), the pseudo gate stack 42 can support the upper semiconductor nanostructure 26U so that the upper semiconductor nanostructure 26U does not collapse when the pseudo nanostructure 24B is removed. In addition, although the sidewalls of the pseudo nanostructure 24A are shown as being straight after etching, the sidewalls may be concave or convex.
内部间隔件54形成在凹陷的伪纳米结构24A的侧壁上,并且介电隔离层56形成在上部半导体纳米结构26U(共同)和下部半导体纳米结构26L(共同)之间。如随后更详细地描述的,源极/漏极区将随后形成在源极/漏极凹陷46中,并且伪纳米结构24A将被相应的栅极结构替换。内部间隔件54充当随后形成的源极/漏极区与随后形成的栅极结构之间的隔离部件。此外,内部间隔件54可用于防止后续蚀刻工艺(例如用于形成栅极结构的蚀刻工艺)对后续形成的源极/漏极区的损坏。另一方面,介电隔离层56用于将上部半导体纳米结构26U(共同)与下部半导体纳米结构26L(共同)隔离。此外,中间半导体纳米结构(与介电隔离层56接触的半导体纳米结构26中的半导体纳米结构)和介电隔离层56可以限定下部纳米结构FET和上部纳米结构FET的边界。The internal spacer 54 is formed on the sidewall of the recessed pseudo nanostructure 24A, and the dielectric isolation layer 56 is formed between the upper semiconductor nanostructure 26U (common) and the lower semiconductor nanostructure 26L (common). As described in more detail later, the source/drain region will be subsequently formed in the source/drain recess 46, and the pseudo nanostructure 24A will be replaced by the corresponding gate structure. The internal spacer 54 acts as an isolation component between the subsequently formed source/drain region and the subsequently formed gate structure. In addition, the internal spacer 54 can be used to prevent damage to the subsequently formed source/drain region by a subsequent etching process (e.g., an etching process for forming a gate structure). On the other hand, the dielectric isolation layer 56 is used to isolate the upper semiconductor nanostructure 26U (common) from the lower semiconductor nanostructure 26L (common). In addition, the intermediate semiconductor nanostructure (the semiconductor nanostructure in the semiconductor nanostructure 26 in contact with the dielectric isolation layer 56) and the dielectric isolation layer 56 can define the boundary of the lower nanostructure FET and the upper nanostructure FET.
内部间隔件54和介电隔离层56可以通过在源极/漏极凹陷46中、伪纳米结构24A的侧壁上以及上部半导体纳米结构26U和下部半导体纳米结构26L之间共形地沉积绝缘材料,然后蚀刻绝缘材料来形成。绝缘材料可以是硬介电材料,例如含碳介电材料,诸如碳氮化硅、碳氧化硅、氮氧化硅等。可以使用k值小于约3.5的其他低介电常数(低k)材料。绝缘材料可以通过沉积工艺形成,诸如ALD、CVD等。绝缘材料的蚀刻可以是各向异性的或各向同性的。当蚀刻时,绝缘材料具有保留在伪纳米结构24A的侧壁中的部分(从而形成内部间隔件54),并且具有保留在上部半导体纳米结构26U和下部半导体纳米结构26L之间的部分(由此形成介电隔离层56)。The internal spacer 54 and the dielectric isolation layer 56 can be formed by conformally depositing an insulating material in the source/drain recess 46, on the sidewall of the pseudo nanostructure 24A, and between the upper semiconductor nanostructure 26U and the lower semiconductor nanostructure 26L, and then etching the insulating material. The insulating material can be a hard dielectric material, for example, a carbon-containing dielectric material, such as silicon carbonitride, silicon oxycarbide, silicon oxynitride, etc. Other low dielectric constant (low-k) materials with a k value less than about 3.5 can be used. The insulating material can be formed by a deposition process, such as ALD, CVD, etc. The etching of the insulating material can be anisotropic or isotropic. When etching, the insulating material has a portion that remains in the sidewall of the pseudo nanostructure 24A (thereby forming the internal spacer 54), and has a portion that remains between the upper semiconductor nanostructure 26U and the lower semiconductor nanostructure 26L (thereby forming the dielectric isolation layer 56).
如图7所示,形成下部和上部外延源极/漏极区62L和62U。下部外延源极/漏极区62L形成在源极/漏极凹陷46的下部部分中。下部外延源极/漏极区62L与下部半导体纳米结构26L接触并且不与上部半导体纳米结构26U接触。内部间隔件54将下部外延源极/漏极区62L与伪纳米结构24A电绝缘,伪纳米结构24A将在后续工艺中用替换栅极替换。As shown in FIG7 , lower and upper epitaxial source/drain regions 62L and 62U are formed. Lower epitaxial source/drain region 62L is formed in the lower portion of source/drain recess 46. Lower epitaxial source/drain region 62L contacts lower semiconductor nanostructure 26L and does not contact upper semiconductor nanostructure 26U. Internal spacers 54 electrically insulate lower epitaxial source/drain region 62L from dummy nanostructure 24A, which will be replaced with a replacement gate in a subsequent process.
下部外延源极/漏极区62L是外延生长的,并且具有适合于下部纳米结构FET的器件类型(p型或n型)的导电类型。当下部外延源极/漏极区62L是n型源极/漏极区时,相应的材料可以包括硅或碳掺杂的硅,其掺杂有n型掺杂剂,诸如磷、砷等。当下部外延源极/漏极区62L是p型源极/漏极区时,相应的材料可以包括硅或硅锗,其掺杂有p型掺杂剂,诸如硼、铟等。下部外延源极/漏极区62L可以被原位掺杂,并且可以被或者可以不被注入相应的p型或n型掺杂剂。在下部外延源极/漏极区62L的外延期间,可以掩蔽上部半导体纳米结构26U以防止在上部半导体纳米结构26U上不期望的外延生长。在生长下部外延源极/漏极区62L之后,可以去除上部半导体纳米结构26U上的掩模。The lower epitaxial source/drain region 62L is epitaxially grown and has a conductivity type suitable for the device type (p-type or n-type) of the lower nanostructure FET. When the lower epitaxial source/drain region 62L is an n-type source/drain region, the corresponding material may include silicon or carbon-doped silicon, which is doped with n-type dopants such as phosphorus, arsenic, etc. When the lower epitaxial source/drain region 62L is a p-type source/drain region, the corresponding material may include silicon or silicon germanium, which is doped with p-type dopants such as boron, indium, etc. The lower epitaxial source/drain region 62L may be in-situ doped and may or may not be implanted with the corresponding p-type or n-type dopant. During the epitaxy of the lower epitaxial source/drain region 62L, the upper semiconductor nanostructure 26U may be masked to prevent undesired epitaxial growth on the upper semiconductor nanostructure 26U. After growing the lower epitaxial source/drain regions 62L, the mask on the upper semiconductor nanostructures 26U may be removed.
作为用于形成下部外延源极/漏极区62L的外延工艺的结果,下部外延源极区62L的上表面具有横向向外扩展超过多层堆叠件22的侧壁的小平面。在一些实施例中,在外延工艺完成之后,相邻的下部外延源极/漏极区62L保持分离。在其他实施例中,这些小平面导致同一FET的相邻下部外延源极/漏极区62L合并。As a result of the epitaxial process used to form lower epitaxial source/drain regions 62L, the upper surfaces of lower epitaxial source regions 62L have facets that extend laterally outward beyond the sidewalls of multilayer stack 22. In some embodiments, adjacent lower epitaxial source/drain regions 62L remain separated after the epitaxial process is completed. In other embodiments, these facets cause adjacent lower epitaxial source/drain regions 62L of the same FET to merge.
在下部外延源极/漏极区62L上形成第一接触蚀刻停止层(CESL)66和第一ILD 68。第一CESL 66可以由对第一ILD 68的蚀刻具有高蚀刻选择性的介电材料形成,诸如氮化硅、氧化硅、氮氧化硅等,其可以通过任何合适的沉积工艺形成,诸如CVD、ALD等。第一ILD 68可以由介电材料形成,该介电材料可以通过任何合适的方法沉积,诸如CVD、等离子体增强CVD(PECVD)或FCVD。第一ILD 68的可应用的介电材料可以包括磷硅酸盐玻璃(PSG)、硼硅酸盐玻璃(BSG)、掺硼磷硅酸玻璃(BPSG)、未掺杂硅酸盐玻璃(USG)、氧化硅等。A first contact etch stop layer (CESL) 66 and a first ILD 68 are formed on the lower epitaxial source/drain region 62L. The first CESL 66 may be formed of a dielectric material having a high etch selectivity to the etching of the first ILD 68, such as silicon nitride, silicon oxide, silicon oxynitride, etc., which may be formed by any suitable deposition process, such as CVD, ALD, etc. The first ILD 68 may be formed of a dielectric material, which may be deposited by any suitable method, such as CVD, plasma enhanced CVD (PECVD), or FCVD. Applicable dielectric materials of the first ILD 68 may include phosphosilicate glass (PSG), borosilicate glass (BSG), boron-doped phosphosilicate glass (BPSG), undoped silicate glass (USG), silicon oxide, etc.
形成工艺可包括沉积共形CESL层,沉积用于第一ILD 68的材料,随后进行平坦化工艺,然后进行回蚀刻工艺。在一些实施例中,首先蚀刻第一ILD 68,留下未蚀刻的第一CESL 66。然后执行各向异性蚀刻工艺以去除第一CESL 66的高于凹陷的第一ILD 68的部分。在凹陷之后,暴露出上部半导体纳米结构26U的侧壁。The formation process may include depositing a conformal CESL layer, depositing a material for the first ILD 68, followed by a planarization process, and then an etch-back process. In some embodiments, the first ILD 68 is first etched, leaving the unetched first CESL 66. An anisotropic etching process is then performed to remove the portion of the first CESL 66 that is above the recessed first ILD 68. After the recess, the sidewalls of the upper semiconductor nanostructure 26U are exposed.
然后在源极/漏极凹陷46的上部部分中形成上部外延源极/漏极区62U。上部外延源极/漏极区62U可以从上部半导体纳米结构26U的暴露表面外延生长。上部外延源极/漏极区62U的材料可以从用于形成下部源极/漏极区62L的相同候选材料组中选择,这取决于上部外延源极区62U的期望导电类型。在堆叠晶体管为CFET的实施例中,上部外延源极/漏极区62U的导电类型可与下部外延源极/漏极区62L的导电类型相反。例如,上部外延源极/漏极区62U可以与下部外延源极/漏极区63L相反地掺杂。上部外延源极/漏极区62U可以被原位掺杂,和/或可以用n型或p型掺杂剂注入。相邻的上部源极/漏极区62U可以在外延工艺之后保持分离或者可以合并。An upper epitaxial source/drain region 62U is then formed in the upper portion of the source/drain recess 46. The upper epitaxial source/drain region 62U may be epitaxially grown from the exposed surface of the upper semiconductor nanostructure 26U. The material of the upper epitaxial source/drain region 62U may be selected from the same candidate material group used to form the lower source/drain region 62L, depending on the desired conductivity type of the upper epitaxial source region 62U. In an embodiment where the stacked transistor is a CFET, the conductivity type of the upper epitaxial source/drain region 62U may be opposite to the conductivity type of the lower epitaxial source/drain region 62L. For example, the upper epitaxial source/drain region 62U may be doped opposite to the lower epitaxial source/drain region 63L. The upper epitaxial source/drain region 62U may be doped in situ, and/or may be implanted with n-type or p-type dopants. Adjacent upper source/drain regions 62U may remain separate or may merge after the epitaxial process.
在形成外延源极/漏极区62U之后,形成第二CESL 70和第二ILD 72。材料和形成方法可以分别类似于第一CESL 66和第一ILD 68的材料和形成方式,并且在此不详细讨论。形成工艺可以包括:沉积用于CESL 70和ILD 72的层,并且执行平坦化工艺以去除相应层的过量部分。在平坦化工艺之后,第二ILD72、栅极间隔件44和伪栅极堆叠件42的顶表面共面(在工艺变化内)。平坦化工艺可以去除掩模40,或者不去除硬掩模40。After forming the epitaxial source/drain regions 62U, the second CESL 70 and the second ILD 72 are formed. The materials and the formation methods may be similar to those of the first CESL 66 and the first ILD 68, respectively, and are not discussed in detail herein. The formation process may include depositing layers for the CESL 70 and the ILD 72, and performing a planarization process to remove excess portions of the respective layers. After the planarization process, the top surfaces of the second ILD 72, the gate spacers 44, and the dummy gate stack 42 are coplanar (within process variations). The planarization process may remove the mask 40, or may not remove the hard mask 40.
图8A和图8B示出了用栅极堆叠件90替换伪栅极堆叠件42和伪纳米结构24A的替换栅极工艺的不同截面。图8A示出了沿图1中的参考线A-A’截取的截面图;图8B示出了沿图1的参考线B-B'的截面图。替换栅极工艺包括首先去除伪栅极堆叠件42和伪纳米结构24A的剩余部分。在一个或多个蚀刻工艺中去除伪栅极堆叠件42,使得在栅极间隔件44之间限定凹陷,并且暴露半导体带28的上部部分。然后通过蚀刻去除伪纳米结构24A的剩余部分,使得凹陷在半导体纳米结构26之间延伸。在蚀刻工艺中,伪纳米结构24A以比半导体纳米结构26、介电隔离层56、内部间隔件54和ESL 16更快的速率被蚀刻。蚀刻可以是各向同性的。例如,当伪纳米结构24A由硅锗形成,并且半导体纳米结构26由硅形成时,蚀刻工艺可以包括使用四甲基氢氧化铵(TMAH)、氢氧化铵(NH4OH)等的湿蚀刻工艺。8A and 8B show different cross-sections of a replacement gate process in which the dummy gate stack 42 and the dummy nanostructure 24A are replaced with a gate stack 90. FIG. 8A shows a cross-sectional view taken along reference line A-A' in FIG. 1 ; FIG. 8B shows a cross-sectional view taken along reference line BB' in FIG. 1 . The replacement gate process includes first removing the remaining portions of the dummy gate stack 42 and the dummy nanostructure 24A. The dummy gate stack 42 is removed in one or more etching processes so that a recess is defined between the gate spacers 44 and the upper portion of the semiconductor band 28 is exposed. The remaining portions of the dummy nanostructure 24A are then removed by etching so that the recess extends between the semiconductor nanostructures 26. In the etching process, the dummy nanostructure 24A is etched at a faster rate than the semiconductor nanostructure 26, the dielectric isolation layer 56, the internal spacer 54, and the ESL 16. The etching may be isotropic. For example, when the dummy nanostructure 24A is formed of silicon germanium, and the semiconductor nanostructure 26 is formed of silicon, the etching process may include a wet etching process using tetramethylammonium hydroxide (TMAH), ammonium hydroxide (NH 4 OH), or the like.
然后,将栅极电介质78沉积在栅极间隔件44之间的凹陷中以及暴露的半导体纳米结构26上。栅极电介质78共形地形成在包括半导体纳米结构26和栅极间隔件44的凹陷(去除的伪栅极堆叠件42和伪纳米结构24A)的暴露表面上。在一些实施例中,栅极电介质78围绕半导体纳米结构26的所有(例如,四个)侧面。具体地,栅极电介质78可以形成在半导体带20’的顶表面上;在半导体纳米结构26的顶表面、侧壁和底表面上;以及在栅极间隔件90的侧壁上。栅极电介质78可以包括诸如氧化硅或金属氧化物的氧化物、诸如金属硅酸盐的硅酸盐、其组合、其多层等。栅极电介质78可以包括k值大于约7.0的高介电常数(高k)材料,诸如铪、铝、锆、镧、锰、钡、钛、铅及其组合的金属氧化物或硅酸盐。栅极电介质78的形成方法可以包括分子束沉积(MBD)、ALD、PECVD等,随后进行平坦化工艺(例如CMP)以去除第二ILD72上方的栅极电介质78的部分。尽管示出了单层栅极电介质78,但是栅极电介质78可以包括多层,诸如界面层和上覆的高k介电层。Then, a gate dielectric 78 is deposited in the recesses between the gate spacers 44 and on the exposed semiconductor nanostructures 26. The gate dielectric 78 is conformally formed on the exposed surface of the recess (removed dummy gate stack 42 and dummy nanostructure 24A) including the semiconductor nanostructures 26 and the gate spacers 44. In some embodiments, the gate dielectric 78 surrounds all (e.g., four) sides of the semiconductor nanostructure 26. Specifically, the gate dielectric 78 can be formed on the top surface of the semiconductor strip 20'; on the top surface, sidewalls, and bottom surface of the semiconductor nanostructure 26; and on the sidewalls of the gate spacers 90. The gate dielectric 78 can include an oxide such as silicon oxide or a metal oxide, a silicate such as a metal silicate, a combination thereof, a multilayer thereof, and the like. The gate dielectric 78 can include a high dielectric constant (high-k) material with a k value greater than about 7.0, such as a metal oxide or silicate of hafnium, aluminum, zirconium, lanthanum, manganese, barium, titanium, lead, and a combination thereof. The gate dielectric 78 may be formed by molecular beam deposition (MBD), ALD, PECVD, etc., followed by a planarization process (e.g., CMP) to remove the portion of the gate dielectric 78 above the second ILD 72. Although a single layer of gate dielectric 78 is shown, the gate dielectric 78 may include multiple layers, such as an interfacial layer and an overlying high-k dielectric layer.
下部栅电极80L形成在下部半导体纳米结构26L周围的栅极电介质78上。例如,下部栅电极80L包裹在下部半导体纳米结构26L周围。下部栅电极80L可以由包含以下金属的材料形成:诸如钨、钛、氮化钛、钽、氮化钽、碳化钽、铝、钌、钴、它们的组合、它们的多层等。尽管示出了单层栅电极,但是下部栅电极80L可以包括任意数量的功函数调谐层、任意数量的阻挡层、任意数量的胶层和填充材料。The lower gate electrode 80L is formed on the gate dielectric 78 around the lower semiconductor nanostructure 26L. For example, the lower gate electrode 80L wraps around the lower semiconductor nanostructure 26L. The lower gate electrode 80L can be formed of a material including metals such as tungsten, titanium, titanium nitride, tantalum, tantalum nitride, tantalum carbide, aluminum, ruthenium, cobalt, combinations thereof, multilayers thereof, etc. Although a single-layer gate electrode is shown, the lower gate electrode 80L can include any number of work function tuning layers, any number of barrier layers, any number of glue layers, and filler materials.
下部栅电极80L由适合于下部纳米结构FET的器件类型的材料形成。例如,下部栅电极80L可以包括由适合于下部纳米结构FET的器件类型的材料形成的一个或多个功函数调谐层。在一些实施例中,下部栅电极80L包括n型功函数调谐层,其可以由钛铝、碳化钛铝、钽铝、碳化钽、它们的组合等形成。在一些实施例中,下部栅电极80L包括p型功函数调谐层,其可以由氮化钛、氮化钽、其组合等形成。附加地或可替换地,下部栅电极80L可以包括适用于下部纳米结构FET的器件类型的偶极诱导元素。可接受的偶极诱导元素包括镧、铝、钪、钌、锆、铒、镁、锶及其组合。The lower gate electrode 80L is formed of a material suitable for the device type of the lower nanostructure FET. For example, the lower gate electrode 80L may include one or more work function tuning layers formed of a material suitable for the device type of the lower nanostructure FET. In some embodiments, the lower gate electrode 80L includes an n-type work function tuning layer, which may be formed of titanium aluminum, titanium aluminum carbide, tantalum aluminum, tantalum carbide, combinations thereof, and the like. In some embodiments, the lower gate electrode 80L includes a p-type work function tuning layer, which may be formed of titanium nitride, tantalum nitride, combinations thereof, and the like. Additionally or alternatively, the lower gate electrode 80L may include a dipole-inducing element suitable for the device type of the lower nanostructure FET. Acceptable dipole-inducing elements include lanthanum, aluminum, scandium, ruthenium, zirconium, erbium, magnesium, strontium, and combinations thereof.
下部栅电极80L可以通过共形沉积一个或多个栅电极层并且凹陷栅电极层来形成。可以执行任何可接受的蚀刻工艺,诸如干蚀刻、湿蚀刻等,或其组合,以凹陷栅电极层。蚀刻可以是各向同性的。蚀刻下部栅电极80L可以暴露上部半导体纳米结构26U。The lower gate electrode 80L may be formed by conformally depositing one or more gate electrode layers and recessing the gate electrode layers. Any acceptable etching process, such as dry etching, wet etching, etc., or a combination thereof, may be performed to recess the gate electrode layer. The etching may be isotropic. Etching the lower gate electrode 80L may expose the upper semiconductor nanostructure 26U.
在一些实施例中,隔离层(未明确示出)可以选择性地形成在下部栅电极80L上。隔离层充当下部栅电极80L与随后形成的上部栅电极80U之间的隔离部件。隔离层可以通过共形沉积介电材料(例如,氧化硅、氮化硅、氮氧化硅、碳氮氧化硅及其组合等)并随后使介电材料凹陷以暴露上部半导体纳米结构26U来形成。In some embodiments, an isolation layer (not explicitly shown) may be selectively formed on the lower gate electrode 80L. The isolation layer serves as an isolation member between the lower gate electrode 80L and the subsequently formed upper gate electrode 80U. The isolation layer may be formed by conformally depositing a dielectric material (e.g., silicon oxide, silicon nitride, silicon oxynitride, silicon oxycarbonitride, and combinations thereof, etc.) and then recessing the dielectric material to expose the upper semiconductor nanostructure 26U.
然后,在上述隔离层(如果存在)或下部栅电极80L上形成上部栅电极80U。上部栅电极80U设置在上部半导体纳米结构26U之间。在一些实施例中,上部栅电极80U包裹围绕上部半导体纳米结构26U。上部栅电极80U可以由用于形成下部栅电极80L的相同候选材料和候选工艺形成。上部栅电极80U由适合于上部纳米结构FET的器件类型的材料形成。例如,上部栅电极80U可以包括一个或多个功函数调谐层,功函数调谐层由适合于上部纳米结构FET的器件类型的材料形成。尽管示出了单层栅电极80U,但是上部栅电极80U可以包括任意数量的功函数调谐层、任意数量的阻挡层、任意数量的胶层和填充材料。Then, an upper gate electrode 80U is formed on the above-mentioned isolation layer (if present) or the lower gate electrode 80L. The upper gate electrode 80U is disposed between the upper semiconductor nanostructures 26U. In some embodiments, the upper gate electrode 80U wraps around the upper semiconductor nanostructure 26U. The upper gate electrode 80U can be formed by the same candidate material and candidate process used to form the lower gate electrode 80L. The upper gate electrode 80U is formed of a material suitable for the device type of the upper nanostructure FET. For example, the upper gate electrode 80U may include one or more work function tuning layers, which are formed of a material suitable for the device type of the upper nanostructure FET. Although a single-layer gate electrode 80U is shown, the upper gate electrode 80U may include any number of work function tuning layers, any number of barrier layers, any number of glue layers, and filling materials.
此外,执行去除工艺以使上部栅电极80U和第二ILD72的顶表面齐平。用于形成栅极电介质78的去除工艺可以是与用于形成上部栅电极80U的去除工艺相同的去除工艺。在一些实施例中,可以使用平坦化工艺,诸如化学机械抛光(CMP)、回蚀刻工艺、其组合等。在平坦化工艺之后,上部栅电极80U、栅极电介质78、第二ILD72和栅极间隔件44的顶表面基本共面(在工艺变化内)。栅极电介质78和栅电极80(包括上部栅电极80U和/或下部栅电极80L)的每对可以统称为“栅极结构”90(包括上部栅极结构90U和下部栅极结构90L)。每个栅极结构90沿着半导体纳米结构26的沟道区的三侧(例如,顶表面、侧壁和底表面)延伸(见图1和图8B)。下部栅极结构90L也可以沿着ESL 16的侧壁和/或顶表面以及半导体带20’的侧壁延伸(见图8B)。In addition, a removal process is performed to make the top surfaces of the upper gate electrode 80U and the second ILD 72 flush. The removal process for forming the gate dielectric 78 may be the same removal process as the removal process for forming the upper gate electrode 80U. In some embodiments, a planarization process such as chemical mechanical polishing (CMP), an etch-back process, a combination thereof, etc. may be used. After the planarization process, the top surfaces of the upper gate electrode 80U, the gate dielectric 78, the second ILD 72, and the gate spacer 44 are substantially coplanar (within process variations). Each pair of the gate dielectric 78 and the gate electrode 80 (including the upper gate electrode 80U and/or the lower gate electrode 80L) may be collectively referred to as a "gate structure" 90 (including an upper gate structure 90U and a lower gate structure 90L). Each gate structure 90 extends along three sides (e.g., top surface, sidewall, and bottom surface) of the channel region of the semiconductor nanostructure 26 (see FIGS. 1 and 8B). The lower gate structure 90L may also extend along the sidewalls and/or top surface of the ESL 16 and the sidewalls of the semiconductor strip 20' (see FIG. 8B).
在图9中,金属半导体合金区94和源极/漏极接触件96穿过第二ILD72形成,以电耦合到上部外延源极/漏极区62U和/或下部外延源极/漏极区62L。作为形成源极/漏极接触件96的示例,使用可接受的光刻和蚀刻技术形成穿过第二ILD 72和第二CESL 70的开口。在开口中形成诸如扩散阻挡层、粘合层等的衬垫(未单独示出)以及导电材料。衬垫可以包括钛、氮化钛、钽、氮化钽等。导电材料可以是钴、钨、铜、铜合金、银、金、铝、镍等。可以执行去除工艺以从栅极间隔件44和第二ILD 72的顶表面去除过量材料。剩余的衬垫和导电材料在开口中形成源极/漏极接触件96。在一些实施例中,使用平坦化工艺,诸如CMP、回蚀刻工艺、其组合等。在平坦化工艺之后,栅极间隔件44、第二ILD72和源极/漏极接触件96的顶表面基本共面(在工艺变化内)。In FIG. 9 , a metal semiconductor alloy region 94 and a source/drain contact 96 are formed through the second ILD 72 to electrically couple to the upper epitaxial source/drain region 62U and/or the lower epitaxial source/drain region 62L. As an example of forming the source/drain contact 96, an opening through the second ILD 72 and the second CESL 70 is formed using acceptable photolithography and etching techniques. A liner (not shown separately) such as a diffusion barrier layer, an adhesive layer, etc. and a conductive material are formed in the opening. The liner may include titanium, titanium nitride, tantalum, tantalum nitride, etc. The conductive material may be cobalt, tungsten, copper, copper alloy, silver, gold, aluminum, nickel, etc. A removal process may be performed to remove excess material from the top surface of the gate spacer 44 and the second ILD 72. The remaining liner and conductive material form a source/drain contact 96 in the opening. In some embodiments, a planarization process such as CMP, an etch-back process, a combination thereof, etc. is used. After the planarization process, top surfaces of the gate spacers 44 , the second ILD 72 , and the source/drain contacts 96 are substantially coplanar (within process variations).
可选地,金属半导体合金区94形成在源极/漏极区62和源极/漏电接触件96之间的界面处。金属半导体合金区94可以是由金属硅化物(例如,硅化钛、硅化钴、硅化镍等)形成的硅化物区、由金属锗化物(例如锗化钛、锗化钴、锗化镍等)形成的锗化物区、由金属硅化物和金属锗化物二者形成的锗化硅区等。金属半导体合金区94可以通过在源极/漏极接触件96的开口中沉积金属然后执行热退火工艺而在源极/漏极接触件96的材料之前形成。金属可以是能够与源极/漏极区62的半导体材料(例如,硅、硅锗、锗等)反应以形成低电阻金属半导体合金的任何金属,诸如镍、钴、钛、钽、铂、钨、其他贵金属、其他难熔金属、稀土金属或其合金。可以通过诸如ALD、CVD、PVD等沉积工艺来沉积金属。在热退火工艺之后,可以执行清洁工艺,诸如湿法清洁,以从源极/漏极接触件96的开口去除任何残留金属,例如从金属半导体合金区94的表面去除。然后可以在金属半导体合金区94上形成源极/漏极接触件96的材料。Optionally, a metal semiconductor alloy region 94 is formed at the interface between the source/drain region 62 and the source/drain contact 96. The metal semiconductor alloy region 94 may be a silicide region formed of a metal silicide (e.g., titanium silicide, cobalt silicide, nickel silicide, etc.), a germanide region formed of a metal germanide (e.g., titanium germanide, cobalt germanide, nickel germanide, etc.), a silicon germanide region formed of both a metal silicide and a metal germanide, etc. The metal semiconductor alloy region 94 may be formed before the material of the source/drain contact 96 by depositing a metal in the opening of the source/drain contact 96 and then performing a thermal annealing process. The metal may be any metal that can react with the semiconductor material of the source/drain region 62 (e.g., silicon, silicon germanium, germanium, etc.) to form a low-resistance metal semiconductor alloy, such as nickel, cobalt, titanium, tantalum, platinum, tungsten, other precious metals, other refractory metals, rare earth metals, or alloys thereof. The metal may be deposited by a deposition process such as ALD, CVD, PVD, etc. After the thermal annealing process, a cleaning process, such as a wet clean, may be performed to remove any residual metal from the openings of the source/drain contacts 96, for example, from the surface of the metal semiconductor alloy region 94. The material of the source/drain contacts 96 may then be formed on the metal semiconductor alloy region 94.
然后形成ESL 104和第三ILD 106。在一些实施例中,ESL 104可以包括对第三ILD106的蚀刻具有高蚀刻选择性的介电材料,诸如氧化铝、氮化铝、碳氧化硅等。第三ILD 106可以使用可流动CVD、ALD等形成,并且该材料可以包括PSG、BSG、BPSG、USG等,其可以通过任何合适的方法沉积,诸如CVD、PECVD等。Then, the ESL 104 and the third ILD 106 are formed. In some embodiments, the ESL 104 may include a dielectric material having a high etch selectivity to the etching of the third ILD 106, such as aluminum oxide, aluminum nitride, silicon oxycarbide, etc. The third ILD 106 may be formed using flowable CVD, ALD, etc., and the material may include PSG, BSG, BPSG, USG, etc., which may be deposited by any suitable method, such as CVD, PECVD, etc.
随后,形成栅极接触件108和源极/漏极通孔110,以分别接触上部栅电极80U和源极/漏极接触件96。作为形成栅极接触件108和源极/漏极通孔110的示例,穿过第三ILD 106和ESL 104形成用于栅极接触件108以及源极/漏极通孔110的开口。可以使用可接受的光刻和蚀刻技术来形成开口。在开口中形成诸如扩散阻挡层、粘合层等的衬垫(未单独示出)和导电材料。衬垫可以包括钛、氮化钛、钽、氮化钽等。导电材料可以是钴、钨、铜、铜合金、银、金、铝、镍等。可以执行平坦化工艺,诸如CMP,以从第三ILD 106的顶表面去除过量的材料。剩余的衬垫和导电材料在开口中形成栅极接触件108和源极/漏极通孔110。栅极接触件108和源极/漏极通孔110可以在不同工艺中形成,或者可以在相同工艺中形成。尽管显示为形成在相同的截面中,但是应当理解,栅极接触件108和源极/漏极通孔110中的每个可以形成在不同的截面中,这可以避免接触的短路。Subsequently, a gate contact 108 and a source/drain via 110 are formed to contact the upper gate electrode 80U and the source/drain contact 96, respectively. As an example of forming the gate contact 108 and the source/drain via 110, an opening for the gate contact 108 and the source/drain via 110 is formed through the third ILD 106 and the ESL 104. The opening can be formed using acceptable photolithography and etching techniques. A liner (not shown separately) and a conductive material such as a diffusion barrier layer, an adhesive layer, etc. are formed in the opening. The liner can include titanium, titanium nitride, tantalum, tantalum nitride, etc. The conductive material can be cobalt, tungsten, copper, copper alloy, silver, gold, aluminum, nickel, etc. A planarization process such as CMP can be performed to remove excess material from the top surface of the third ILD 106. The remaining liner and conductive material form a gate contact 108 and a source/drain via 110 in the opening. The gate contact 108 and the source/drain vias 110 may be formed in different processes, or may be formed in the same process. Although shown as being formed in the same cross section, it should be understood that each of the gate contact 108 and the source/drain vias 110 may be formed in different cross sections, which may avoid shorting of the contacts.
在器件层112上形成前侧互连结构114。前侧互连结构114包括介电层116和介电层116中的导电部件118的层。介电层116可以包括由低k介电材料形成的低k介电层。介电层116还可以包括钝化层,钝化层由非低k和致密介电材料形成,例如在低k介电材料上方的未掺杂硅酸盐玻璃(USG)、氧化硅、氮化硅等或其组合。介电层116还可以包括聚合物层。A front side interconnect structure 114 is formed on the device layer 112. The front side interconnect structure 114 includes a dielectric layer 116 and a layer of conductive features 118 in the dielectric layer 116. The dielectric layer 116 may include a low-k dielectric layer formed of a low-k dielectric material. The dielectric layer 116 may also include a passivation layer formed of a non-low-k and dense dielectric material, such as undoped silicate glass (USG), silicon oxide, silicon nitride, etc., or a combination thereof, on top of the low-k dielectric material. The dielectric layer 116 may also include a polymer layer.
导电部件118可以包括导线和通孔,其可以使用镶嵌工艺形成。导电部件118可以包括金属线和金属通孔,金属线和金属通孔包括扩散阻挡层和在扩散阻挡层上的含铜材料。也可以在金属线和通孔上存在铝焊盘并且铝焊盘电连接到金属线和通孔。如将在下面更详细地解释的,可以通过器件层112的背侧(例如,与前侧互连结构114相对的一侧)来形成与下部栅极堆叠件90L和下部源极/漏极区62L的接触件。Conductive component 118 may include conductive lines and vias, which may be formed using a damascene process. Conductive component 118 may include metal lines and metal vias, which include a diffusion barrier layer and a copper-containing material on the diffusion barrier layer. Aluminum pads may also be present on the metal lines and vias and electrically connected to the metal lines and vias. As will be explained in more detail below, contacts to the lower gate stack 90L and the lower source/drain region 62L may be formed through the back side of device layer 112 (e.g., the side opposite to the front side interconnect structure 114).
图10至图16B示出了根据一些实施例的根据下部栅极堆叠件90L和下部源极/漏极区62L形成背侧栅极接触件和源极/漏极接触件的中间步骤的截面图。在图10至图16A中,为了便于说明,省略了器件层112的前侧上超过上栅极堆叠件80U的部件,但应理解,在图10到图16A所示的截面中,ESL 104、第三ILD 106和前侧互连结构114设置在上栅极堆叠件80U下方。参考图10,可以翻转器件的方向。例如,载体衬底(未明确示出)可以通过介电对介电接合而接合到前侧互连结构114,并且器件可以被翻转以暴露器件层112的背侧(器件层112与前侧互连结构112相对的一侧)。然后,可以在器件层112的背侧上执行平坦化工艺。在一些实施例中,平坦化工艺可包括例如CMP和/或回蚀刻工艺的组合。平坦化工艺可以去除下部衬底12L(见图4)、接合层18(见图4),以及半导体层20的未图案化部分。平坦化工艺可以进一步暴露半导体带20’和STI区32。10 to 16B show cross-sectional views of intermediate steps of forming backside gate contacts and source/drain contacts according to the lower gate stack 90L and the lower source/drain region 62L according to some embodiments. In FIG. 10 to FIG. 16A, for ease of illustration, the components on the front side of the device layer 112 that exceed the upper gate stack 80U are omitted, but it should be understood that in the cross-sections shown in FIG. 10 to FIG. 16A, the ESL 104, the third ILD 106, and the front side interconnect structure 114 are disposed below the upper gate stack 80U. Referring to FIG. 10, the direction of the device can be flipped. For example, a carrier substrate (not explicitly shown) can be bonded to the front side interconnect structure 114 by dielectric-to-dielectric bonding, and the device can be flipped to expose the back side of the device layer 112 (the side of the device layer 112 opposite to the front side interconnect structure 112). Then, a planarization process can be performed on the back side of the device layer 112. In some embodiments, the planarization process may include, for example, a combination of CMP and/or etch-back processes. The planarization process may remove the lower substrate 12L (see FIG. 4 ), the bonding layer 18 (see FIG. 4 ), and the unpatterned portion of the semiconductor layer 20. The planarization process may further expose the semiconductor strips 20' and the STI regions 32.
在图11中,执行一个或多个蚀刻工艺以去除半导体带20’和STI区32。去除半导体层20和半导体带20’通过改善随后形成的背侧栅极接触件和/或背侧源极/漏极接触件之间的隔离,有利地改善了电性能。例如,通过去除半导体层20和半导体带20’,可以解决关于通过半导体层20/半导体带20’的背侧接触件短路的问题。此外,可以去除STI区32,从而可以在器件层112的背侧毯覆隔离层。提供毯覆隔离层可以通过去除STI区32的形貌(以及由此产生的界面)来提供改进的膜质量。半导体带20’和STI区32可以通过任何合适的蚀刻工艺以任何顺序去除。在一些实施例中,通过湿蚀刻工艺去除半导体带20’,而通过干蚀刻工艺去除STI区32。在一些实施例中,去除半导体带20’和STI区32暴露出栅极介电层78和ESL16。可选地,在一些实施例中,去除半导体带20’可以使下部源极/漏极区62L部分凹陷至ESL16下方和/或下部栅极堆叠件90L的背侧下方(见图16A)。In FIG. 11 , one or more etching processes are performed to remove the semiconductor strips 20 ′ and the STI regions 32. Removing the semiconductor layer 20 and the semiconductor strips 20 ′ advantageously improves electrical performance by improving the isolation between the subsequently formed backside gate contacts and/or backside source/drain contacts. For example, by removing the semiconductor layer 20 and the semiconductor strips 20 ′, issues regarding shorting of the backside contacts through the semiconductor layer 20/semiconductor strips 20 ′ can be addressed. In addition, the STI regions 32 can be removed so that an isolation layer can be blanketed on the backside of the device layer 112. Providing a blanket isolation layer can provide improved film quality by removing the topography of the STI regions 32 (and the resulting interfaces). The semiconductor strips 20 ′ and the STI regions 32 can be removed in any order by any suitable etching process. In some embodiments, the semiconductor strips 20 ′ are removed by a wet etching process, while the STI regions 32 are removed by a dry etching process. In some embodiments, removing the semiconductor strips 20 ′ and the STI regions 32 exposes the gate dielectric layer 78 and the ESL 16. Optionally, in some embodiments, removal of the semiconductor strip 20' may cause the lower source/drain region 62L to be partially recessed below the ESL 16 and/or below the back side of the lower gate stack 90L (see FIG. 16A ).
在图12中,牺牲层120沉积在器件层112的背侧上方。牺牲层120可以包括通过任何合适的工艺(诸如PVD、CVD、ALD等)沉积的绝缘材料,诸如氧化物等。可以沉积牺牲层120以在随后的平坦化工艺中改善负载和均匀性控制(见图13)。例如,牺牲层120可以覆盖形貌并提供均匀的图案密度,从而减少后续平坦化工艺的总体负担并改善平坦化结果。在一些实施例中,牺牲层120具有在30nm至50nm范围内的厚度T5,已被观察到这充分改善了随后的平坦化工艺。In FIG. 12 , a sacrificial layer 120 is deposited over the back side of the device layer 112. The sacrificial layer 120 may include an insulating material, such as an oxide, deposited by any suitable process, such as PVD, CVD, ALD, etc. The sacrificial layer 120 may be deposited to improve load and uniformity control in a subsequent planarization process (see FIG. 13 ). For example, the sacrificial layer 120 may cover the topography and provide a uniform pattern density, thereby reducing the overall burden of the subsequent planarization process and improving the planarization results. In some embodiments, the sacrificial layer 120 has a thickness T 5 in the range of 30 nm to 50 nm, which has been observed to substantially improve the subsequent planarization process.
在图13中,执行平坦化工艺(例如,CMP工艺等),去除牺牲层120的块体并平坦化器件层112的背侧。平坦化工艺可去除栅极堆叠件90的背侧上的栅极介电层78并暴露ESL 16。在平坦化工艺之后,ESL 16和下部栅电极80L的后表面(例如,背侧表面)可以基本上是齐平的(在工艺变化范围内)。在一些实施例中,例如,可以通过清洁工艺去除平坦化工艺之后的牺牲层120的剩余部分。In FIG13 , a planarization process (e.g., a CMP process, etc.) is performed to remove the bulk of the sacrificial layer 120 and planarize the back side of the device layer 112. The planarization process can remove the gate dielectric layer 78 on the back side of the gate stack 90 and expose the ESL 16. After the planarization process, the rear surface (e.g., backside surface) of the ESL 16 and the lower gate electrode 80L can be substantially flush (within process variation). In some embodiments, for example, the remaining portion of the sacrificial layer 120 after the planarization process can be removed by a cleaning process.
在图14中,在下部栅电极80L和ESL 16的背侧上依次沉积背侧ESL 122、第一背侧ILD 124、背侧ESL 126和第二背侧ILD 128。背侧ESL 122和126可以使用与上述前侧ESL104类似的材料和工艺形成,并且第一和第二背侧ILD 124和128可以使用与如上所述的第三ILD 106类似的材料或工艺形成。在一些实施例中,背侧ESL 122可以进一步沿着ESL 16的侧壁延伸,以覆盖下部源极/漏极区62L的背侧(见图16A)。14 , a backside ESL 122, a first backside ILD 124, a backside ESL 126, and a second backside ILD 128 are sequentially deposited on the backside of the lower gate electrode 80L and the ESL 16. The backside ESLs 122 and 126 may be formed using materials and processes similar to those of the frontside ESL 104 described above, and the first and second backside ILDs 124 and 128 may be formed using materials or processes similar to those of the third ILD 106 described above. In some embodiments, the backside ESL 122 may further extend along the sidewalls of the ESL 16 to cover the backside of the lower source/drain region 62L (see FIG. 16A ).
在一些实施例中,在沉积第一背侧ILD 124和沉积背侧ESL 126之间,形成背侧源极/漏极接触件134和金属半导体合金区136(也称为硅化物区136)(见图16A)。背侧源极/漏极接触件134和金属半导体合金区136可以分别使用与上述源极/漏极接触件96和金属半导体金属合金区94类似的材料和工艺来形成。背侧源极/漏极接触件134可以延伸穿过第一背侧ILD 124和背侧ESL 122,以电耦合到底部源极/漏极区62L的背侧。背侧ESL 122可以为蚀刻开口提供端点控制,该蚀刻开口随后被填充以形成背侧源极/漏极接触件134。In some embodiments, between depositing the first backside ILD 124 and depositing the backside ESL 126, a backside source/drain contact 134 and a metal semiconductor alloy region 136 (also referred to as a silicide region 136) are formed (see FIG. 16A). The backside source/drain contact 134 and the metal semiconductor alloy region 136 can be formed using materials and processes similar to the source/drain contact 96 and the metal semiconductor metal alloy region 94 described above, respectively. The backside source/drain contact 134 can extend through the first backside ILD 124 and the backside ESL 122 to electrically couple to the back side of the bottom source/drain region 62L. The backside ESL 122 can provide endpoint control for the etch opening, which is subsequently filled to form the backside source/drain contact 134.
在图15中,穿过第二背侧ILD 128、背侧ESL 126、第一背侧ILD 124、背侧ESL 122、栅极ESL 16和栅极电介质78图案化背侧栅极接触件开口130以暴露下部栅电极80L。背侧栅极接触件开口130的图案化可以通过光刻和蚀刻工艺的组合来实现。具体地,蚀刻栅极ESL16可以使用蚀刻剂,该蚀刻剂以比下部纳米结构FET的周围部件(例如,下部栅电极80L和/或纳米结构26)更快的速率选择性地蚀刻栅极ESL。例如,可以使用包括NF3、BCl3等的化学蚀刻剂在干蚀刻工艺中蚀刻栅极ESL 16。In FIG15 , a backside gate contact opening 130 is patterned through the second backside ILD 128, the backside ESL 126, the first backside ILD 124, the backside ESL 122, the gate ESL 16, and the gate dielectric 78 to expose the lower gate electrode 80L. The patterning of the backside gate contact opening 130 can be achieved by a combination of photolithography and etching processes. Specifically, etching the gate ESL 16 can use an etchant that selectively etches the gate ESL at a faster rate than the surrounding components of the lower nanostructure FET (e.g., the lower gate electrode 80L and/or the nanostructure 26). For example, a chemical etchant including NF 3 , BCl 3 , etc. can be used to etch the gate ESL 16 in a dry etching process.
背侧栅极接触件开口130可以与纳米结构26重叠并横向对准,纳米结构26在器件层112中提供上部纳米结构FET和下部纳米结构FET的沟道区。栅极ESL 16由合适的材料制成,并且足够厚以允许开口130以精确的端点控制被图案化。例如,栅极ESL 16由高k材料(例如,氧化铪)制成,并且在各种实施例中为至少3nm厚。结果,背侧栅极接触件开口130可以直接与纳米结构26重叠,而不会损坏纳米结构26(例如,通过过蚀刻)。还包括背侧ESL122以进一步改进蚀刻背侧栅极接触件开口130的端点控制。The backside gate contact opening 130 can overlap and laterally align with the nanostructure 26, which provides the channel region of the upper nanostructure FET and the lower nanostructure FET in the device layer 112. The gate ESL 16 is made of a suitable material and is thick enough to allow the opening 130 to be patterned with precise endpoint control. For example, the gate ESL 16 is made of a high-k material (e.g., hafnium oxide) and is at least 3nm thick in various embodiments. As a result, the backside gate contact opening 130 can overlap directly with the nanostructure 26 without damaging the nanostructure 26 (e.g., by overetching). The backside ESL 122 is also included to further improve the endpoint control of etching the backside gate contact opening 130.
因为栅极ESL 16允许背侧栅极接触件开口130直接与纳米结构26重叠,所以在形成背侧栅极接触件时不再需要避免与沟道区(纳米结构26)重叠的位置,从而允许提高布线灵活性。此外,因为为了改进器件速度,纳米结构26可以制成具有较大宽度W1。例如,通过增加沟道区的宽度,在实施例器件中已经观察到14.4%到19%之间的器件速度改进。在一些实施例中,宽度W1大于34nm,诸如在16nm至80nm的范围内,从而实现改进的器件性能。因此,各种实施例允许改进的工艺集成、增加的布线灵活性和增加的器件性能(例如,速度)。Because the gate ESL 16 allows the backside gate contact opening 130 to overlap directly with the nanostructure 26, it is no longer necessary to avoid a position overlapping with the channel region (nanostructure 26) when forming the backside gate contact, thereby allowing for increased wiring flexibility. In addition, because the nanostructure 26 can be made with a larger width W1 in order to improve device speed. For example, by increasing the width of the channel region, device speed improvements of between 14.4% and 19% have been observed in embodiment devices. In some embodiments, the width W1 is greater than 34nm, such as in the range of 16nm to 80nm, thereby achieving improved device performance. Therefore, various embodiments allow for improved process integration, increased wiring flexibility, and increased device performance (e.g., speed).
在图16A和图16B中,形成为分别接触下部栅电极80L和源极/漏极接触件134的背侧栅极接触件132和背侧源极/漏极通孔138。具体地,背侧栅极接触件132可以形成在背侧栅极接触件开口130中并且与纳米结构26重叠。作为形成背侧栅极接触件132的示例,在背侧栅极接触件开口130中形成诸如扩散阻挡层、粘合层等的衬垫(未单独示出)和导电材料。衬垫可以包括钛、氮化钛、钽、氮化钽等。导电材料可以是钴、钨、铜、铜合金、银、金、铝、镍等。可以执行平坦化工艺,诸如CMP,以从第二背侧ILD 128的顶表面去除过量材料。剩余的衬垫和导电材料在背侧栅极接触件开口130中形成背侧栅极接触件132。背侧源极/漏极通孔138可以由与上述源极/漏极通孔110类似的材料和工艺形成。背侧栅极接触件132和背侧源极/漏极通孔138可以在不同工艺中形成,或者可以在相同工艺中形成。尽管显示为形成在相同的截面中,但是应当理解,背侧栅极接触件132和背侧源极/漏极通孔138中的每个可以形成在不同的截面中,这可以避免接触的短路。In FIGS. 16A and 16B , a backside gate contact 132 and a backside source/drain via 138 are formed to contact the lower gate electrode 80L and the source/drain contact 134, respectively. Specifically, the backside gate contact 132 may be formed in the backside gate contact opening 130 and overlap the nanostructure 26. As an example of forming the backside gate contact 132, a liner (not shown separately) such as a diffusion barrier layer, an adhesive layer, etc. and a conductive material are formed in the backside gate contact opening 130. The liner may include titanium, titanium nitride, tantalum, tantalum nitride, etc. The conductive material may be cobalt, tungsten, copper, copper alloy, silver, gold, aluminum, nickel, etc. A planarization process such as CMP may be performed to remove excess material from the top surface of the second backside ILD 128. The remaining liner and conductive material form the backside gate contact 132 in the backside gate contact opening 130. The back side source/drain vias 138 may be formed of similar materials and processes as the source/drain vias 110 described above. The back side gate contact 132 and the back side source/drain vias 138 may be formed in different processes, or may be formed in the same process. Although shown as being formed in the same cross section, it should be understood that each of the back side gate contact 132 and the back side source/drain vias 138 may be formed in different cross sections, which may avoid shorting of the contacts.
图17至图24B示出了根据一些实施例的堆叠晶体管(如图1所示)形成中的中间阶段的截面图。在图17至图24B中,可以在没有上述接合工艺的情况下形成栅极ESL 16(见图2A、图2B和图3)。图17显示了类似于图1的透视图。图18、图19、图20、图21、图22、图23和图24A显示了沿与图1中的参考截面A-A’类似的截面的截面图。图24B显示了与图1中的参考截面B-B'类似的截面图。在图17至图24B中,除非另有说明,否则相同的参考数字表示通过与图2A至图16B中所述相同工艺形成的相同元件。17 to 24B show cross-sectional views of intermediate stages in the formation of a stacked transistor (as shown in FIG. 1 ) according to some embodiments. In FIGS. 17 to 24B , the gate ESL 16 (see FIGS. 2A , 2B , and 3 ) may be formed without the above-described bonding process. FIG. 17 shows a perspective view similar to FIG. 1 . FIGS. 18 , 19 , 20 , 21 , 22 , 23 , and 24A show cross-sectional views along a cross section similar to the reference cross section A-A’ in FIG. 1 . FIG. 24B shows a cross-sectional view similar to the reference cross section B-B’ in FIG. 1 . In FIGS. 17 to 24B , unless otherwise noted, the same reference numerals represent the same elements formed by the same process as described in FIGS. 2A to 16B .
图17示出了半导体衬底12的透视图,其可以由与上述半导体衬底12L和12U相同的材料制成。形成从半导体衬底12向上延伸的半导体带28。每个半导体带28包括半导体带12’(半导体衬底12的图案化部分)和纳米结构的多层堆叠件22’。具体地说,多层堆叠件22’包括伪纳米结构24A、伪纳米结构24B、下部半导体纳米结构26L和上部半导体纳米结构26U。半导体衬底12也可以被称为半导体层。17 shows a perspective view of a semiconductor substrate 12, which may be made of the same material as the semiconductor substrates 12L and 12U described above. Semiconductor strips 28 are formed extending upward from the semiconductor substrate 12. Each semiconductor strip 28 includes a semiconductor strip 12' (a patterned portion of the semiconductor substrate 12) and a multilayer stack 22' of nanostructures. Specifically, the multilayer stack 22' includes a pseudo nanostructure 24A, a pseudo nanostructure 24B, a lower semiconductor nanostructure 26L, and an upper semiconductor nanostructure 26U. The semiconductor substrate 12 may also be referred to as a semiconductor layer.
多层堆叠件22’可以由与多层堆叠件22相同的材料和工艺制成,其中包括附加的伪纳米结构24B作为多层堆叠件22的底层。例如,附加的伪纳米结构24B可以是多层堆叠件22’的最底层,其设置在多层堆叠件22’的上部纳米结构和下面的半导体带12’之间。在随后的工艺步骤中,底部纳米结构24B可以用高k材料替换,以提供栅极ESL(例如,栅极ESL 16,见图23)。底部纳米结构24B可以通过在半导体衬底12上形成伪纳米结构层(具有与上述伪纳米结构层14C类似的材料/工艺),然后将伪纳米结构层图案化作为形成多层堆叠件22’的一部分来形成。因为底部纳米结构24B随后将被高k材料替换以形成背侧栅极ESL,所以底部纳米结构24B的厚度T5可以是至少3nm。以这种方式,得到的栅极ESL至少为3nm厚,这有利地允许栅极ESL在背侧栅极接触件形成期间充分地保护下面的纳米结构26。The multilayer stack 22' can be made of the same materials and processes as the multilayer stack 22, including the additional pseudo nanostructure 24B as the bottom layer of the multilayer stack 22. For example, the additional pseudo nanostructure 24B can be the bottom layer of the multilayer stack 22', which is disposed between the upper nanostructure of the multilayer stack 22' and the semiconductor strip 12' below. In a subsequent process step, the bottom nanostructure 24B can be replaced with a high-k material to provide a gate ESL (e.g., gate ESL 16, see FIG. 23). The bottom nanostructure 24B can be formed by forming a pseudo nanostructure layer (having materials/processes similar to the pseudo nanostructure layer 14C described above) on the semiconductor substrate 12, and then patterning the pseudo nanostructure layer as part of forming the multilayer stack 22'. Because the bottom nanostructure 24B will be subsequently replaced by a high-k material to form a backside gate ESL, the thickness T5 of the bottom nanostructure 24B can be at least 3nm. In this manner, the resulting gate ESL is at least 3 nm thick, which advantageously allows the gate ESL to adequately protect the underlying nanostructures 26 during backside gate contact formation.
如图17所示,STI区32可以形成在半导体带12’之间,并且伪栅极堆叠件42(包括伪介电层36、伪栅极层38和掩模层40)形成在多层堆叠件22’的侧壁上并沿着侧壁形成。STI区32和伪栅极堆叠件42可以由如上所述的类似材料和类似工艺形成。在伪栅极堆叠件42被图案化之后,栅极间隔件44(见图18)可以由与上述材料和工艺类似的材料和工艺形成在伪栅极堆叠件42的侧壁上。As shown in FIG. 17 , STI regions 32 may be formed between semiconductor strips 12 ′, and dummy gate stacks 42 (including dummy dielectric layers 36, dummy gate layers 38, and mask layers 40) may be formed on and along the sidewalls of the multilayer stack 22 ′. STI regions 32 and dummy gate stacks 42 may be formed of similar materials and processes as described above. After dummy gate stacks 42 are patterned, gate spacers 44 (see FIG. 18 ) may be formed on the sidewalls of dummy gate stacks 42 of materials and processes similar to those described above.
在图18中,在伪栅极堆叠件42和多层堆叠件22’上方沉积并图案化掩模层140。掩模层140可以通过例如旋涂工艺沉积在相邻的伪栅极堆叠件42之间。在一些实施例中,掩模层140是光敏层,诸如底部抗反射涂层(BARC)层。掩模层140可通过光刻工艺被图案化,以暴露多层堆叠件22’的第一区22A,同时掩蔽多层堆叠件22’的第二区22B。第一区22A和第二区22B中的每个都设置在伪栅极堆叠件42中的相邻伪栅极堆叠件42之间,并且第一区22B和第二区22B可以交替地设置在半导体衬底12上,其中第二区22中的每个设置于第一区22A中的相邻第一区22A之间。In FIG. 18 , a mask layer 140 is deposited and patterned over the dummy gate stack 42 and the multilayer stack 22 ′. The mask layer 140 may be deposited between adjacent dummy gate stacks 42 by, for example, a spin coating process. In some embodiments, the mask layer 140 is a photosensitive layer, such as a bottom anti-reflective coating (BARC) layer. The mask layer 140 may be patterned by a photolithography process to expose the first region 22A of the multilayer stack 22 ′ while masking the second region 22B of the multilayer stack 22 ′. Each of the first region 22A and the second region 22B is disposed between adjacent dummy gate stacks 42 in the dummy gate stack 42, and the first region 22B and the second region 22B may be alternately disposed on the semiconductor substrate 12, wherein each of the second regions 22 is disposed between adjacent first regions 22A in the first region 22A.
然后,在多层堆叠件22’的第一区22A中形成第一源极/漏极凹陷46A。第一源极/漏极凹陷46A通过蚀刻形成,并且可以延伸穿过多层堆叠件22’并进入半导体带12’。第一源极/漏极凹陷46A的底表面可以位于隔离区32的顶表面上方、下方或与隔离区32顶表面齐平的水平。在蚀刻工艺中,掩模层140、栅极间隔件44和伪栅极堆叠件42掩蔽半导体带28的一些部分。蚀刻可以包括单个蚀刻工艺或多个蚀刻工艺。定时蚀刻工艺可用于在第一源极/漏极凹陷46A达到期望深度时停止对第一源极/漏极凹陷46的蚀刻。在图案化第一源极/漏极凹陷46A之后,可以通过可接受的工艺(例如灰化工艺)去除掩模层140。Then, a first source/drain recess 46A is formed in the first region 22A of the multilayer stack 22'. The first source/drain recess 46A is formed by etching and can extend through the multilayer stack 22' and into the semiconductor strip 12'. The bottom surface of the first source/drain recess 46A can be located above, below, or at a level flush with the top surface of the isolation region 32. During the etching process, the mask layer 140, the gate spacer 44, and the dummy gate stack 42 mask portions of the semiconductor strip 28. The etching can include a single etching process or multiple etching processes. A timed etching process can be used to stop etching the first source/drain recess 46 when the first source/drain recess 46A reaches a desired depth. After patterning the first source/drain recess 46A, the mask layer 140 can be removed by an acceptable process (e.g., an ashing process).
在图19中,进行横向蚀刻工艺,通过第一源极/漏极凹陷46A横向蚀刻伪纳米结构24A和伪纳米结构24B。横向蚀刻工艺可以是各向同性的,并且可以对伪纳米结构24的材料是选择性的,使得伪纳米结构24以比半导体纳米结构26更快的速率被蚀刻。蚀刻工艺也可以对伪纳米结构24B的材料是选择性的,使得伪纳米结构24B以比伪纳米结构性24A更快的速率被蚀刻。以这种方式,伪纳米结构24B可以被横向蚀刻并且凹陷比伪纳米结构24A更大的量。在伪纳米结构24B由具锗或有高锗原子百分比的硅锗形成、伪纳米结构24A由具有低锗原子百分比的硅锗形成、以及半导体纳米结构26由不含锗的硅形成的一些实施例中,蚀刻工艺可包括使用氯气的干蚀刻工艺(利用或不利用等离子体)。横向蚀刻工艺凹陷伪纳米结构24A以形成第一凹陷48A,并且横向蚀刻工艺凹陷伪纳米结构24B以形成具有比第一凹陷48A更大的横向宽度的第二凹陷48B。在一些实施例中,横向蚀刻工艺去除伪纳米结构24A的横向宽度的约50%。尽管伪纳米结构24A的侧壁被示为在蚀刻之后是直的,但是侧壁可以是凹的或凸的。In FIG. 19 , a lateral etching process is performed to laterally etch the pseudo-nanostructure 24A and the pseudo-nanostructure 24B through the first source/drain recess 46A. The lateral etching process may be isotropic and may be selective to the material of the pseudo-nanostructure 24, so that the pseudo-nanostructure 24 is etched at a faster rate than the semiconductor nanostructure 26. The etching process may also be selective to the material of the pseudo-nanostructure 24B, so that the pseudo-nanostructure 24B is etched at a faster rate than the pseudo-nanostructure 24A. In this way, the pseudo-nanostructure 24B may be laterally etched and recessed by a greater amount than the pseudo-nanostructure 24A. In some embodiments where the pseudo-nanostructure 24B is formed of silicon germanium with germanium or a high atomic percentage of germanium, the pseudo-nanostructure 24A is formed of silicon germanium with a low atomic percentage of germanium, and the semiconductor nanostructure 26 is formed of silicon without germanium, the etching process may include a dry etching process (with or without plasma) using chlorine gas. The lateral etching process recesses the pseudo nanostructure 24A to form a first recess 48A, and the lateral etching process recesses the pseudo nanostructure 24B to form a second recess 48B having a larger lateral width than the first recess 48A. In some embodiments, the lateral etching process removes about 50% of the lateral width of the pseudo nanostructure 24A. Although the sidewalls of the pseudo nanostructure 24A are shown as being straight after etching, the sidewalls may be concave or convex.
在图20中,内部间隔件54形成在第一凹陷48A中,高k材料142A和内部间隔件54形成在第二凹陷48B中。形成高k材料142A包括在伪纳米结构24B的侧壁上在第一源极/漏极凹陷46A、第一凹陷48A和第二凹陷48B中共形地沉积高k材料142A,然后蚀刻高k材料。高k材料可以是用于在背侧栅极接触件形成期间保护纳米结构26以及在上部和下部纳米结构26U和26L之间提供足够隔离的任何合适的材料。例如,高k材料142A可以是氧化铪等,并且高k材料142A可以具有至少15的k值。因此,可以在后续工艺中选择性地蚀刻高k材料142A以形成背侧栅极接触件。高k材料142A可以通过沉积工艺形成,诸如ALD、CVD等。高k材料142A的蚀刻可以是各向异性的或各向同性的。当蚀刻时,高k材料142A具有保留在伪纳米结构24B的侧壁中的部分,而高k材料142A的其他部分可以被去除。高k材料142A的蚀刻可以进一步使高k材料142A在伪纳米结构24B的侧壁上凹陷超过纳米结构26的侧壁,使得纳米结构26在蚀刻之后突出高k材料142A的剩余部分。In FIG. 20 , the internal spacer 54 is formed in the first recess 48A, and the high-k material 142A and the internal spacer 54 are formed in the second recess 48B. Forming the high-k material 142A includes conformally depositing the high-k material 142A in the first source/drain recess 46A, the first recess 48A, and the second recess 48B on the sidewalls of the pseudo nanostructure 24B, and then etching the high-k material. The high-k material can be any suitable material for protecting the nanostructure 26 during the formation of the backside gate contact and providing sufficient isolation between the upper and lower nanostructures 26U and 26L. For example, the high-k material 142A can be hafnium oxide, etc., and the high-k material 142A can have a k value of at least 15. Therefore, the high-k material 142A can be selectively etched in a subsequent process to form a backside gate contact. The high-k material 142A can be formed by a deposition process, such as ALD, CVD, etc. The etching of the high-k material 142A can be anisotropic or isotropic. When etching, high-k material 142A has a portion remaining in the sidewall of pseudo nanostructure 24B, while other portions of high-k material 142A may be removed. Etching of high-k material 142A may further cause high-k material 142A to be recessed on the sidewall of pseudo nanostructure 24B beyond the sidewall of nanostructure 26, so that nanostructure 26 protrudes beyond the remaining portion of high-k material 142A after etching.
在沉积和蚀刻高k材料142A之后,在伪纳米结构24A和高k材料142A的暴露侧壁上形成内部间隔件54。内部间隔件54可以由如上所述的类似的材料和类似的工艺形成。内部间隔件54可用于防止随后形成的栅极堆叠件与随后形成的源极/漏极区之间的短路。After depositing and etching the high-k material 142A, an internal spacer 54 is formed on the exposed sidewalls of the pseudo-nanostructure 24A and the high-k material 142A. The internal spacer 54 can be formed of similar materials and similar processes as described above. The internal spacer 54 can be used to prevent short circuits between the subsequently formed gate stack and the subsequently formed source/drain regions.
在图21中,在伪栅极堆叠件42和多层堆叠件22’上方沉积并图案化掩模层144。掩模层144可以通过例如旋涂工艺沉积在相邻的伪栅极堆叠件42之间以及第一源极/漏极区46A中。在一些实施例中,掩模层144是光敏层,诸如BARC层。掩模层144可通过光刻工艺图案化以暴露多层堆叠件22’的第二区22B,同时掩蔽多层堆叠件22’的第一区22A。In FIG. 21 , a mask layer 144 is deposited and patterned over the dummy gate stack 42 and the multilayer stack 22′. The mask layer 144 may be deposited between adjacent dummy gate stacks 42 and in the first source/drain region 46A by, for example, a spin coating process. In some embodiments, the mask layer 144 is a photosensitive layer, such as a BARC layer. The mask layer 144 may be patterned by a photolithography process to expose the second region 22B of the multilayer stack 22′ while masking the first region 22A of the multilayer stack 22′.
然后,在多层堆叠件22’的第二区22B中形成第二源极/漏极凹陷46B。第二源极/漏极凹陷46B是通过蚀刻形成的,并且可以延伸穿过多层堆叠件22’并进入半导体带12’。第二源极/漏极凹陷46B的底表面可以与第一源极/漏极凹陷46A的底表面处于相同的水平(在工艺变化中),并且掩模层144、栅极间隔件44和伪栅极堆叠件42在蚀刻期间掩模半导体带28的一些部分。蚀刻可以包括单个蚀刻工艺或多个蚀刻工艺。定时蚀刻工艺可用于在第二源极/漏极凹陷46B达到期望深度时停止对第二源极/漏极凹陷46B的蚀刻。Then, a second source/drain recess 46B is formed in the second region 22B of the multilayer stack 22'. The second source/drain recess 46B is formed by etching and can extend through the multilayer stack 22' and into the semiconductor strip 12'. The bottom surface of the second source/drain recess 46B can be at the same level as the bottom surface of the first source/drain recess 46A (in process variations), and the mask layer 144, the gate spacer 44, and the dummy gate stack 42 mask some portions of the semiconductor strip 28 during etching. The etching can include a single etching process or multiple etching processes. A timed etching process can be used to stop etching the second source/drain recess 46B when the second source/drain recess 46B reaches a desired depth.
在图22中,进行横向蚀刻工艺,该蚀刻工艺横向蚀刻伪纳米结构24A,并通过第二源极/漏极凹陷46B去除伪纳米结构的剩余部分24B。横向蚀刻工艺可以是各向同性的,并且可以对伪纳米结构24的材料是选择性的,使得伪纳米结构24以比半导体纳米结构26更快的速率被蚀刻。蚀刻工艺也可以对伪纳米结构24B的材料是选择性的,使得伪纳米结构24B以比伪纳米结构性24A更快的速率被蚀刻。以这种方式,可以在不去除伪纳米结构24A的情况下完全去除伪纳米结构24B的剩余部分。在伪纳米结构24B由锗或具有高锗原子百分比的硅锗形成、伪纳米结构24A由具有低锗原子百分比的硅锗形成以及半导体纳米结构26由不含锗的硅形成的一些实施例中,蚀刻工艺可包括使用氯气的干蚀刻工艺(利用或不利用等离子体)。横向蚀刻工艺凹陷伪纳米结构24A以形成第三凹陷50A,并且横向蚀刻工艺去除伪纳米结构24B以形成第四凹陷50B。第四凹陷50B暴露高k材料142A,并且具有比第三凹陷50A更大的横向宽度。尽管伪纳米结构24A的侧壁被示为在蚀刻之后是直的,但是侧壁可以是凹的或凸的。此外,在图22的横向蚀刻工艺期间,掩模144可以掩蔽第一源极/漏极凹陷46A。In FIG. 22 , a lateral etching process is performed, which etches the pseudo nanostructure 24A laterally and removes the remaining portion 24B of the pseudo nanostructure through the second source/drain recess 46B. The lateral etching process may be isotropic and may be selective to the material of the pseudo nanostructure 24, so that the pseudo nanostructure 24 is etched at a faster rate than the semiconductor nanostructure 26. The etching process may also be selective to the material of the pseudo nanostructure 24B, so that the pseudo nanostructure 24B is etched at a faster rate than the pseudo nanostructure 24A. In this way, the remaining portion of the pseudo nanostructure 24B may be completely removed without removing the pseudo nanostructure 24A. In some embodiments in which the pseudo nanostructure 24B is formed of germanium or silicon germanium with a high atomic percentage of germanium, the pseudo nanostructure 24A is formed of silicon germanium with a low atomic percentage of germanium, and the semiconductor nanostructure 26 is formed of silicon without germanium, the etching process may include a dry etching process (with or without plasma) using chlorine gas. The lateral etching process recesses the pseudo nanostructure 24A to form a third recess 50A, and the lateral etching process removes the pseudo nanostructure 24B to form a fourth recess 50B. The fourth recess 50B exposes the high-k material 142A and has a greater lateral width than the third recess 50A. Although the sidewalls of the pseudo nanostructure 24A are shown as being straight after etching, the sidewalls may be concave or convex. In addition, during the lateral etching process of FIG. 22, the mask 144 may mask the first source/drain recess 46A.
在图23中,在第三凹陷50A中形成附加的内部间隔件54,在第四凹陷50B中形成高k材料142B和内部间隔件54。形成高k材料142B包括在高k材料142B的侧壁上在第二源极/漏极凹陷46B、第三凹陷50A和第四凹陷50B中共形地沉积高k材料142B,然后蚀刻高k材料。高k材料142B可以是用于在背侧栅极接触件形成期间保护纳米结构26以及提供上部和下部纳米结构26U和26L之间的隔离的任何合适的材料。例如,高k材料142B可以具有与高k材料142A相同的材料组分。在一些实施例中,界面可以设置在高k材料142A和142B接触的位置。高k材料142B可以通过沉积工艺形成,诸如ALD、CVD等。高k材料142B的蚀刻可以是各向异性的或各向同性的。当蚀刻时,高k材料142B具有保留在高k材料142A的侧壁中的部分,而高k材料142B的其它部分可以被去除。高k材料142B的蚀刻可以进一步使高k材料142B在高k材料142A的侧壁上凹陷超过纳米结构26的侧壁,使得纳米结构26在蚀刻之后突出高k材料142B的剩余部分。In FIG. 23 , an additional internal spacer 54 is formed in the third recess 50A, and a high-k material 142B and the internal spacer 54 are formed in the fourth recess 50B. Forming the high-k material 142B includes conformally depositing the high-k material 142B in the second source/drain recess 46B, the third recess 50A, and the fourth recess 50B on the sidewalls of the high-k material 142B, and then etching the high-k material. The high-k material 142B can be any suitable material for protecting the nanostructure 26 during the formation of the backside gate contact and providing isolation between the upper and lower nanostructures 26U and 26L. For example, the high-k material 142B can have the same material composition as the high-k material 142A. In some embodiments, the interface can be set at a location where the high-k materials 142A and 142B contact. The high-k material 142B can be formed by a deposition process, such as ALD, CVD, etc. The etching of the high-k material 142B can be anisotropic or isotropic. When etching, high-k material 142B has portions remaining in the sidewalls of high-k material 142A, while other portions of high-k material 142B may be removed. Etching of high-k material 142B may further cause high-k material 142B to be recessed on the sidewalls of high-k material 142A beyond the sidewalls of nanostructure 26, such that nanostructure 26 protrudes beyond the remaining portions of high-k material 142B after etching.
在沉积和蚀刻高k材料142B之后,在伪纳米结构24A和高k材料142B的暴露侧壁上形成内部间隔件54。内部间隔件54可以由如上所述的类似的材料和类似的工艺形成。内部间隔件54可用于防止随后形成的栅极堆叠件与随后形成的源极/漏极区之间的短路。随后,可以通过可接受的工艺(例如灰化)去除掩模144。After depositing and etching high-k material 142B, internal spacers 54 are formed on the exposed sidewalls of pseudo nanostructure 24A and high-k material 142B. Internal spacers 54 can be formed of similar materials and similar processes as described above. Internal spacers 54 can be used to prevent short circuits between subsequently formed gate stacks and subsequently formed source/drain regions. Subsequently, mask 144 can be removed by an acceptable process (e.g., ashing).
在各种实施例中,高k材料142A/142B提供背侧栅极ESL 16’并提供介电隔离层56’。具体而言,高k材料142A/142B中的底部材料提供背侧栅极ESL 16’,这允许在与半导体纳米结构26重叠的位置形成背侧栅极接触件(例如,背侧栅极接触件132,见图16A、图16B、图24A和图24B)。以这种方式,当形成背侧栅极接触件时,不再需要避免与沟道区(半导体纳米结构26)重叠的位置,从而允许提高布线灵活性。此外,因为为了改进器件速度,半导体纳米结构26可以制成具有较大宽度W1。因此,各种实施例允许改进的工艺集成、增加的布线灵活性和增加的器件性能(例如,速度)。栅极ESL 16’具有至少3nm的厚度,以便在随后的背侧栅极接触件形成步骤中提供足够的蚀刻控制。此外,ESL 16’可以包括在ESL16’的第一部分(高k材料142A)和ESL 16′的第二部分(高k材料142B)之间的内部垂直界面。In various embodiments, the high-k material 142A/142B provides a backside gate ESL 16' and provides a dielectric isolation layer 56'. Specifically, the bottom material in the high-k material 142A/142B provides a backside gate ESL 16', which allows a backside gate contact (e.g., backside gate contact 132, see Figures 16A, 16B, 24A, and 24B) to be formed at a position overlapping with the semiconductor nanostructure 26. In this way, when forming the backside gate contact, it is no longer necessary to avoid a position overlapping with the channel region (semiconductor nanostructure 26), thereby allowing for improved wiring flexibility. In addition, because the semiconductor nanostructure 26 can be made to have a larger width W1 in order to improve device speed. Therefore, various embodiments allow for improved process integration, increased wiring flexibility, and increased device performance (e.g., speed). The gate ESL 16' has a thickness of at least 3 nm so as to provide sufficient etching control in the subsequent backside gate contact formation step. Furthermore, ESL 16 ′ may include an internal vertical interface between a first portion of ESL 16 ′ (high-k material 142A) and a second portion of ESL 16 ′ (high-k material 142B).
高k材料142A/142B中的顶部材料提供介电隔离层56’,以将上部半导体纳米结构26U(共同)与下部半导体纳米结构26L(共同)隔离。此外,中间半导体纳米结构(与介电隔离层56接触的半导体纳米结构26中的半导体纳米结构)和介电隔离层56可以限定下部纳米结构FET和上部纳米结构FET的边界。在图17至图24B的实施例中,介电隔离层56’具有与栅极ESL 16’相同的材料组分。相反,图2A至图16B的实施方案还包括在上部半导体纳米结构26U和下部半导体纳米结构26B之间的介电隔离层56,但是介电隔离层56具有与栅极ESL 16不同的材料组分。The top material in the high-k material 142A/142B provides a dielectric isolation layer 56' to isolate the upper semiconductor nanostructure 26U (common) from the lower semiconductor nanostructure 26L (common). In addition, the intermediate semiconductor nanostructure (the semiconductor nanostructure in the semiconductor nanostructure 26 that contacts the dielectric isolation layer 56) and the dielectric isolation layer 56 can define the boundary of the lower nanostructure FET and the upper nanostructure FET. In the embodiments of Figures 17 to 24B, the dielectric isolation layer 56' has the same material composition as the gate ESL 16'. In contrast, the embodiments of Figures 2A to 16B also include a dielectric isolation layer 56 between the upper semiconductor nanostructure 26U and the lower semiconductor nanostructure 26B, but the dielectric isolation layer 56 has a different material composition than the gate ESL 16.
随后,进行附加处理以形成堆叠晶体管的源极/漏极区、栅极堆叠件、源极/漏极接触件和栅极接触件,从而获得图24A和图24B的器件。附加处理可以类似于上面在图7至图16B中描述的那些,其中类似的参考数字表示由类似的处理形成的类似的元件,并且为了简洁起见,这里不重复对这些处理的详细描述。如图24A和图24B所示,形成背侧栅极接触件132,其电连接到下部栅极堆叠件90L的背侧。背侧栅极接触件132与纳米结构26重叠,在背侧栅极接触件132的形成过程中,半导体纳米结构26受到栅极ESL 16’的保护。具体地,形成背侧接触件132可以包括使用蚀刻剂蚀刻穿过栅极ESL 16的开口,该蚀刻剂以比下部纳米结构FET的周围部件(例如,下部栅电极80L和/或纳米结构26)更快的速率选择性地蚀刻栅极ESL,以改进蚀刻端点控制。Subsequently, additional processing is performed to form the source/drain regions, gate stacks, source/drain contacts, and gate contacts of the stacked transistor, thereby obtaining the device of Figures 24A and 24B. The additional processing may be similar to those described above in Figures 7 to 16B, where similar reference numbers represent similar elements formed by similar processing, and for the sake of brevity, the detailed description of these processing is not repeated here. As shown in Figures 24A and 24B, a backside gate contact 132 is formed, which is electrically connected to the back side of the lower gate stack 90L. The backside gate contact 132 overlaps the nanostructure 26, and during the formation of the backside gate contact 132, the semiconductor nanostructure 26 is protected by the gate ESL 16'. Specifically, forming the backside contact 132 may include etching an opening through the gate ESL 16 using an etchant that selectively etches the gate ESL at a faster rate than the surrounding components of the lower nanostructure FET (e.g., the lower gate electrode 80L and/or the nanostructure 26) to improve the etching endpoint control.
在各种实施例中,背侧栅极ESL允许在背侧栅极接触件形成工艺期间在背侧栅接触与堆叠晶体管的沟道区重叠的位置处将背侧栅极接触件形成至堆叠晶体管的下部栅极堆叠件,而不会损坏沟道区。因此,当形成背侧栅极接触件时,不再需要避免与沟道区重叠的位置,从而允许改进的布线灵活性。此外,因为沟道区能够直接与背侧栅极接触件重叠,所以沟道区可以具有更大的宽度以提高器件速度。结果,各种实施例允许改进的工艺集成、增加的布线灵活性和增加的器件性能。In various embodiments, the back gate ESL allows a back gate contact to be formed to a lower gate stack of a stacked transistor at a location where the back gate contact overlaps the channel region of the stacked transistor during a back gate contact formation process without damaging the channel region. Thus, when forming the back gate contact, it is no longer necessary to avoid a location that overlaps the channel region, thereby allowing improved routing flexibility. In addition, because the channel region can directly overlap the back gate contact, the channel region can have a larger width to increase device speed. As a result, various embodiments allow for improved process integration, increased routing flexibility, and increased device performance.
根据一些实施例,半导体器件包括:多个第一纳米结构,多个第一纳米结构在第一源极/漏极区之间延伸;多个第二纳米结构,位于多个第一纳米结构上方,多个第二纳米结构在第二源极/漏极区之间延伸;第一栅极堆叠件,围绕多个第一纳米结构;第二栅极堆叠件,位于第一栅极堆叠件上方并且设置在多个第二纳米结构周围;背侧栅极蚀刻停止层(ESL),位于第一栅极堆叠件的背侧上,其中,多个第一纳米结构与背侧栅极ESL重叠;以及背侧栅极接触件,电耦合到第一栅极堆叠件,其中,背侧栅极接触件延伸穿过背侧栅极ESL到达第一栅极堆叠件的背侧。在一些实施例中,背侧栅极ESL由高k介电材料制成。在一些实施例中,背侧栅极ESL包括氧化铪。在一些实施例中,第一栅极堆叠件包括栅极电介质和位于栅极电介质上方的栅电极,并且其中,背侧栅极接触件延伸穿过栅极电介质以接触栅电极。在一些实施例中,背侧栅极ESL的横向表面与栅电极的背侧表面齐平。在一些实施例中,半导体器件还包括位于多个第一纳米结构和多个第二纳米结构之间的介电隔离层,其中,介电隔离层具有与背侧栅极ESL相同的材料组分。在一些实施例中,背侧栅极ESL包括背侧栅极ESL的第一部分和背侧栅极ESL第二部分之间的界面。在一些实施例中,半导体器件还包括位于第一栅极堆叠件和第一源极/漏极区之间的内部间隔件,其中,内部间隔件进一步设置在背侧栅极ESL的侧壁上。在一些实施例中,半导体器件还包括位于多个第一纳米结构和多个第二纳米结构之间的介电隔离层,其中,介电隔离层具有与背侧栅极ESL不同的材料组分。在一些实施例中,背侧栅极ESL的厚度为至少3nm。According to some embodiments, a semiconductor device includes: a plurality of first nanostructures extending between a first source/drain region; a plurality of second nanostructures located above the plurality of first nanostructures, the plurality of second nanostructures extending between the second source/drain region; a first gate stack surrounding the plurality of first nanostructures; a second gate stack located above the first gate stack and disposed around the plurality of second nanostructures; a back gate etch stop layer (ESL) located on a back side of the first gate stack, wherein the plurality of first nanostructures overlap the back gate ESL; and a back gate contact electrically coupled to the first gate stack, wherein the back gate contact extends through the back gate ESL to the back side of the first gate stack. In some embodiments, the back gate ESL is made of a high-k dielectric material. In some embodiments, the back gate ESL includes hafnium oxide. In some embodiments, the first gate stack includes a gate dielectric and a gate electrode located above the gate dielectric, and wherein the back gate contact extends through the gate dielectric to contact the gate electrode. In some embodiments, a lateral surface of the back gate ESL is flush with a back side surface of the gate electrode. In some embodiments, the semiconductor device further includes a dielectric isolation layer between the plurality of first nanostructures and the plurality of second nanostructures, wherein the dielectric isolation layer has the same material composition as the back gate ESL. In some embodiments, the back gate ESL includes an interface between a first portion of the back gate ESL and a second portion of the back gate ESL. In some embodiments, the semiconductor device further includes an internal spacer between the first gate stack and the first source/drain region, wherein the internal spacer is further disposed on a sidewall of the back gate ESL. In some embodiments, the semiconductor device further includes a dielectric isolation layer between the plurality of first nanostructures and the plurality of second nanostructures, wherein the dielectric isolation layer has a different material composition from the back gate ESL. In some embodiments, the thickness of the back gate ESL is at least 3 nm.
根据一些实施例,一种半导体器件包括:器件层,器件层包括:第一晶体管,包括第一栅极堆叠件,其中,第一栅极堆叠件包括第一栅极电介质和第一栅电极;和第二晶体管,与第一晶体管垂直堆叠。半导体器件还包括:第一互连结构,位于器件层的前侧上;栅极蚀刻停止层(ESL),位于器件层的背侧上,其中,栅极ESL包括高k介电材料;以及栅极接触件,位于器件层的背侧上,其中,栅极接触件延伸穿过栅极ESL和第一栅极电介质以接触第一栅电极。在一些实施例中,半导体器件还包括位于器件层的背侧上的附加蚀刻停止层,其中,栅极接触件延伸穿过附加蚀刻停止层,并且其中,附加蚀刻停止层具有与栅极ESL不同的材料组分。在一些实施例中,栅极接触件与第一晶体管的沟道区重叠。在一些实施例中,第一栅极电介质沿着栅极ESL的侧壁延伸。According to some embodiments, a semiconductor device includes: a device layer, the device layer includes: a first transistor, including a first gate stack, wherein the first gate stack includes a first gate dielectric and a first gate electrode; and a second transistor, vertically stacked with the first transistor. The semiconductor device also includes: a first interconnect structure, located on the front side of the device layer; a gate etch stop layer (ESL), located on the back side of the device layer, wherein the gate ESL includes a high-k dielectric material; and a gate contact, located on the back side of the device layer, wherein the gate contact extends through the gate ESL and the first gate dielectric to contact the first gate electrode. In some embodiments, the semiconductor device also includes an additional etch stop layer located on the back side of the device layer, wherein the gate contact extends through the additional etch stop layer, and wherein the additional etch stop layer has a different material composition than the gate ESL. In some embodiments, the gate contact overlaps with a channel region of the first transistor. In some embodiments, the first gate dielectric extends along the sidewalls of the gate ESL.
根据一些实施例,一种方法包括:在半导体层上方形成第一晶体管和第二晶体管,其中,第一晶体管和第二晶体管垂直堆叠;并且其中,背侧栅极蚀刻停止层(ESL)设置在第一晶体管的第一栅极结构的背侧和半导体层之间;去除半导体层以暴露背侧栅极蚀刻停止层;在背侧栅极ESL上方沉积背侧层间电介质(ILD);图案化穿过背侧ILD和背侧栅极ESL的开口,以暴露第一栅极结构;以及在开口中形成背侧栅极接触件,其中,背侧栅极接触件延伸穿过背侧栅极ESL以电连接到第一栅极结构。在一些实施例中,该方法还包括:在第一半导体衬底上方形成多层堆叠件,多层堆叠件包括与第二半导体材料交替布置的第一半导体材料;在多层堆叠件上方沉积高k介电层;将第二半导体衬底接合在多层堆叠件上方;减薄第一半导体衬底;图案化多层堆叠件,其中,图案化多层堆叠件包括由第一半导体材料形成半导体纳米结构以及由第二半导体材料形成伪纳米结构,并且其中,形成第一晶体管包括用第一栅极结构替换伪纳米结构;以及图案化高k介电层以形成背侧栅极ESL。在一些实施例中,该方法还包括:在高k介电层上方形成半导体层,其中,第二半导体衬底通过介电对介电接合直接接合到半导体层。在一些实施例中,该方法还包括:在半导体层上方形成伪半导体材料;在伪半导体材料上方形成多层堆叠件,多层堆叠件包括与第二半导体材料交替布置的第一半导体材料;图案化多层堆叠件和伪半导体材料,其中,图案化多层堆叠件和伪半导体材料包括由伪半导体材料形成第一伪纳米结构、由第一半导体材料形成半导体纳米结构、以及由第二半导体材料形成第二伪纳米结构,并且其中,形成第一晶体管包括用第一栅极结构替换第二伪纳米结构;以及用高k材料替换第一伪纳米结构以形成背侧栅极ESL。在一些实施例中,方法还包括:在去除半导体层之后,在背侧栅极ESL上方沉积附加背侧ESL,其中,背侧ILD沉积在附加背侧ESL上方,并且其中,图案化开口还包括穿过附加背侧ESL来图案化开口。在一些实施例中,背侧栅极接触件与第一晶体管的第一纳米结构和第二晶体管的第二纳米结构重叠。According to some embodiments, a method includes: forming a first transistor and a second transistor above a semiconductor layer, wherein the first transistor and the second transistor are vertically stacked; and wherein a back gate etch stop layer (ESL) is disposed between a back side of a first gate structure of the first transistor and the semiconductor layer; removing the semiconductor layer to expose the back gate etch stop layer; depositing a back interlayer dielectric (ILD) above the back gate ESL; patterning an opening through the back ILD and the back gate ESL to expose the first gate structure; and forming a back gate contact in the opening, wherein the back gate contact extends through the back gate ESL to be electrically connected to the first gate structure. In some embodiments, the method further comprises: forming a multilayer stack over the first semiconductor substrate, the multilayer stack comprising a first semiconductor material arranged alternately with a second semiconductor material; depositing a high-k dielectric layer over the multilayer stack; bonding the second semiconductor substrate over the multilayer stack; thinning the first semiconductor substrate; patterning the multilayer stack, wherein patterning the multilayer stack comprises forming a semiconductor nanostructure from the first semiconductor material and forming a pseudo-nanostructure from the second semiconductor material, and wherein forming the first transistor comprises replacing the pseudo-nanostructure with the first gate structure; and patterning the high-k dielectric layer to form a backside gate ESL. In some embodiments, the method further comprises: forming a semiconductor layer over the high-k dielectric layer, wherein the second semiconductor substrate is directly bonded to the semiconductor layer by dielectric-to-dielectric bonding. In some embodiments, the method further comprises: forming a pseudo-semiconductor material over the semiconductor layer; forming a multilayer stack over the pseudo-semiconductor material, the multilayer stack comprising a first semiconductor material arranged alternately with a second semiconductor material; patterning the multilayer stack and the pseudo-semiconductor material, wherein the patterning of the multilayer stack and the pseudo-semiconductor material comprises forming a first pseudo-nanostructure from the pseudo-semiconductor material, forming a semiconductor nanostructure from the first semiconductor material, and forming a second pseudo-nanostructure from the second semiconductor material, and wherein forming the first transistor comprises replacing the second pseudo-nanostructure with the first gate structure; and replacing the first pseudo-nanostructure with a high-k material to form a back gate ESL. In some embodiments, the method further comprises: depositing an additional backside ESL over the backside gate ESL after removing the semiconductor layer, wherein the backside ILD is deposited over the additional backside ESL, and wherein patterning the opening further comprises patterning the opening through the additional backside ESL. In some embodiments, the backside gate contact overlaps the first nanostructure of the first transistor and the second nanostructure of the second transistor.
上述概述了几个实施例的特征,以便本领域技术人员可以更好地理解本公开的各个方面。本领域技术人员应当理解,他们可以容易地使用本公开作为设计或修改用于实现本文所介绍的实施例的相同目的和/或实现其相同优点的其它过程和结构的基础。本领域技术人员还应当认识到,此类等效结构不背离本公开的精神和范围,并且它们可以在不背离本公开的精神和范围的情况下在本公开中进行各种改变、替换以及改变。The features of several embodiments are summarized above so that those skilled in the art can better understand the various aspects of the present disclosure. Those skilled in the art will appreciate that they can easily use the present disclosure as a basis for designing or modifying other processes and structures for achieving the same purpose and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art will also appreciate that such equivalent structures do not deviate from the spirit and scope of the present disclosure, and that they can make various changes, substitutions, and changes in the present disclosure without departing from the spirit and scope of the present disclosure.
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