CN1181880A - Herbicide series composition for rice seedling field and direct seeding field - Google Patents
Herbicide series composition for rice seedling field and direct seeding field Download PDFInfo
- Publication number
- CN1181880A CN1181880A CN 96118409 CN96118409A CN1181880A CN 1181880 A CN1181880 A CN 1181880A CN 96118409 CN96118409 CN 96118409 CN 96118409 A CN96118409 A CN 96118409A CN 1181880 A CN1181880 A CN 1181880A
- Authority
- CN
- China
- Prior art keywords
- fenclorim
- herbicides
- acetochlor
- described composition
- composition series
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 239000004009 herbicide Substances 0.000 title claims abstract description 22
- 235000007164 Oryza sativa Nutrition 0.000 title claims abstract description 16
- 235000009566 rice Nutrition 0.000 title claims abstract description 16
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 10
- 238000010899 nucleation Methods 0.000 title claims abstract description 6
- 240000007594 Oryza sativa Species 0.000 title claims 2
- NRFQZTCQAYEXEE-UHFFFAOYSA-N Fenclorim Chemical compound ClC1=CC(Cl)=NC(C=2C=CC=CC=2)=N1 NRFQZTCQAYEXEE-UHFFFAOYSA-N 0.000 claims abstract description 42
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 claims abstract description 23
- -1 metazasulfuron Chemical compound 0.000 claims abstract description 11
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- 239000000375 suspending agent Substances 0.000 claims abstract description 11
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 239000006184 cosolvent Substances 0.000 claims abstract description 7
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 16
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 13
- 229910052708 sodium Inorganic materials 0.000 claims description 13
- VXMNDQDDWDDKOQ-UHFFFAOYSA-N Pyrazosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N(N=CC=2C(O)=O)C)=N1 VXMNDQDDWDDKOQ-UHFFFAOYSA-N 0.000 claims description 10
- 239000005476 Bentazone Substances 0.000 claims description 9
- ZOMSMJKLGFBRBS-UHFFFAOYSA-N bentazone Chemical compound C1=CC=C2NS(=O)(=O)N(C(C)C)C(=O)C2=C1 ZOMSMJKLGFBRBS-UHFFFAOYSA-N 0.000 claims description 9
- CNBGNNVCVSKAQZ-UHFFFAOYSA-N benzidamine Natural products C12=CC=CC=C2C(OCCCN(C)C)=NN1CC1=CC=CC=C1 CNBGNNVCVSKAQZ-UHFFFAOYSA-N 0.000 claims description 9
- ZDXMLEQEMNLCQG-UHFFFAOYSA-N sulfometuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=CC(C)=N1 ZDXMLEQEMNLCQG-UHFFFAOYSA-N 0.000 claims description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 5
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 4
- 210000000481 breast Anatomy 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 4
- 239000000741 silica gel Substances 0.000 claims description 4
- 229910002027 silica gel Inorganic materials 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexyloxide Natural products O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 2
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 claims description 2
- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 claims description 2
- 244000215068 Acacia senegal Species 0.000 claims description 2
- 229920001817 Agar Polymers 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 229920000084 Gum arabic Polymers 0.000 claims description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000205 acacia gum Substances 0.000 claims description 2
- 235000010489 acacia gum Nutrition 0.000 claims description 2
- 239000008272 agar Substances 0.000 claims description 2
- 235000010419 agar Nutrition 0.000 claims description 2
- 235000010443 alginic acid Nutrition 0.000 claims description 2
- 229920000615 alginic acid Polymers 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 2
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 claims description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 238000009313 farming Methods 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 239000011507 gypsum plaster Substances 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 2
- 239000010451 perlite Substances 0.000 claims description 2
- 235000019362 perlite Nutrition 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229920000136 polysorbate Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 2
- 229940096992 potassium oleate Drugs 0.000 claims description 2
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- 150000004945 aromatic hydrocarbons Chemical group 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 241000220324 Pyrus Species 0.000 claims 1
- 239000004113 Sepiolite Substances 0.000 claims 1
- 239000012752 auxiliary agent Substances 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 125000002243 cyclohexanonyl group Chemical group *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 claims 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 claims 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 claims 1
- 150000002191 fatty alcohols Chemical class 0.000 claims 1
- 235000021017 pears Nutrition 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 229910052624 sepiolite Inorganic materials 0.000 claims 1
- 235000019355 sepiolite Nutrition 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 230000008961 swelling Effects 0.000 claims 1
- 241000209094 Oryza Species 0.000 abstract description 14
- 241000196324 Embryophyta Species 0.000 abstract description 7
- WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 abstract 4
- FZMKKCQHDROFNI-UHFFFAOYSA-N sulfometuron Chemical compound CC1=CC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 FZMKKCQHDROFNI-UHFFFAOYSA-N 0.000 abstract 2
- 231100000674 Phytotoxicity Toxicity 0.000 abstract 1
- BGNQYGRXEXDAIQ-UHFFFAOYSA-N Pyrazosulfuron-ethyl Chemical group C1=NN(C)C(S(=O)(=O)NC(=O)NC=2N=C(OC)C=C(OC)N=2)=C1C(=O)OCC BGNQYGRXEXDAIQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- DEDOPGXGGQYYMW-UHFFFAOYSA-N molinate Chemical compound CCSC(=O)N1CCCCCC1 DEDOPGXGGQYYMW-UHFFFAOYSA-N 0.000 description 2
- FFSSWMQPCJRCRV-UHFFFAOYSA-N quinclorac Chemical compound ClC1=CN=C2C(C(=O)O)=C(Cl)C=CC2=C1 FFSSWMQPCJRCRV-UHFFFAOYSA-N 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
- 241001504664 Crossocheilus latius Species 0.000 description 1
- 244000285790 Cyperus iria Species 0.000 description 1
- 244000150195 Cyperus longus Species 0.000 description 1
- 235000018109 Cyperus longus Nutrition 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 244000058871 Echinochloa crus-galli Species 0.000 description 1
- 241000234642 Festuca Species 0.000 description 1
- 241000254158 Lampyridae Species 0.000 description 1
- 240000007038 Lindernia dubia Species 0.000 description 1
- 241000091577 Mexicana Species 0.000 description 1
- 240000000178 Monochoria vaginalis Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 241000756999 Potamogetonaceae Species 0.000 description 1
- QHTQREMOGMZHJV-UHFFFAOYSA-N Thiobencarb Chemical compound CCN(CC)C(=O)SCC1=CC=C(Cl)C=C1 QHTQREMOGMZHJV-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- HKPHPIREJKHECO-UHFFFAOYSA-N butachlor Chemical compound CCCCOCN(C(=O)CCl)C1=C(CC)C=CC=C1CC HKPHPIREJKHECO-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a series herbicide composition for rice seedling fields and direct seeding fields, which comprises pyrazosulfuron-ethyl, acetochlor and fenclorim, metazasulfuron, metolachlor and fenclorim, * sulfometuron, acetochlor and fenclorim, * sulfometuron, metolachlor and fenclorim, methoxone, acetochlor and fenclorim, methoxone, fenclorim, metolachlor, fenclorim, acetochlor and fenclorim, and metolachlor and fenclorim. And mixing with proper solvent, cosolvent, carrier, surfactant, etc. to prepare emulsion, wettable powder and suspending agent. The herbicide composition is directly used for preventing and controlling weeds in rice seedling fields or direct seeding fields, can effectively control the harm of various weeds by applying the herbicide composition once, is safe to crops due to the addition of the fenclorim, and cannot generate phytotoxicity.
Description
The present invention relates to rice seedling bed and live field chemical herbicide composition series, particularly pyrazosulfuron,
Sulfometuron Methyl, methoxone (sodium), bentazone, Acetochlor, isopropyl methoxalamine, fenclorim make up mutually, are equipped with appropriate solvent, cosolvent, carrier, surfactant and are mixed with missible oil, wetting powder, suspending agent.
China is large agricultural country, and paddy rice is one of crops of China's cultivated area maximum, and for the high yield, the stable yields that guarantee paddy rice, country has carried out the input of each side, and especially science and technology applies.Paddy rice often suffers the harm of various weeds in vegetative period, and these weeds have very strong vitality, with rice seedling contention nutrition, moisture content, sunlight, growing space etc., has a strong impact on growing of rice seedling, causes rice yield to descend or total crop failure.At present, developed country has developed numerous efficient, wide spectrums, herbicide for paddy field that selectivity is strong in succession, as molinate, quinclorac, careless jinx etc., many complex preparations are also arranged, composite with butachlor, quinclorac, molinate, benthiocarb respectively as: benzyl ethyl methyl, but, temporarily do not obtain large tracts of land and promote the use of because these preparation use costs are higher.
The purpose of this invention is to provide rice seedling bed and live field chemical weed control composition series, effective ingredient have pyrazosulfuron,
Sulfometuron Methyl, methoxone sodium, bentazone, Acetochlor, isopropyl methoxalamine, antipoison fenclorim by different combinations, are equipped with appropriate solvent, cosolvent, carrier, surfactant and are made into missible oil, wetting powder and suspending agent.
The present invention and task are done in such a way that rice seedling bed and direct seeding fields herbicidal series of products composition active ingredient (structural formula sees Table one), and each combination is: the phonetic iodine of pyrrole swells+Acetochlor+fenclorim; Pyrazosulfuron+isopropyl methoxalamine+fenclorim,
Sulfometuron Methyl+Acetochlor+fenclorim;
Sulfometuron Methyl ten isopropyl methoxalamines+fenclorim; Methoxone (sodium)+Acetochlor+fenclorim; Methoxone (sodium)+isopropyl methoxalamine+fenclorim; Acetochlor+fenclorim; Isopropyl methoxalamine+fenclorim.Add suitable surfactant, solvent, cosolvent or carrier, effective ingredient 5～60% (m/m), surfactant 5～20% (m/m), other components 5～20% (m/m).Surfactant used in the present invention is anionic, nonionic or their mixed type, and neopelex (calcium), lauryl sodium sulfate, potassium oleate (sodium), dioctyl sodium sulfosuccinate, nekal, alkyl polyoxyethylene ether sulfonate, peregal, No. 100, farming breast, No. 10, peaceful breast, BY, agricultural emulsifier NO, No. 1600, tween, sorbitol polyoxyethylene ether, trivial amber, sodium lignin sulfonate (calcium), NNO, BX, LS are arranged.When the present invention was missible oil, selected solvent was benzene,toluene,xylene or their mixture, and selected cosolvent can be selected methyl alcohol, ethanol, cyclohexanone, dimethyl formamide, dioxane, the inferior stone roller of dimethyl, ethyl acetate, naphthalene, methyl naphthalene for use.When the present invention was wetting powder, selected carrier was kaolin, white carbon, precipitated calcium carbonate, bentonite, atlapulgite, talcum powder, the plaster of paris, diatomite, chalky soil, potter's clay, montmorillonite, clay, and fineness is greater than 325 orders; When the present invention is suspending agent, continuous phase is water, selected tackifier are xanthans, the basic sodium cellulosate of carboxylic first (second), methylcellulose, polyvinyl alcohol, polyvinylpyrrolidone during the preparation suspending agent, soluble starch and derivative thereof, gum Arabic, gelatin, algin, agar, silica gel etc., employed viscosity stabiliser can be selected white carbon, diatomite, silica gel, bentonite, precipitated calcium carbonate, perlite, talcum powder for use, the optional spent glycol of antifreezing agent, propane diols, glycerine, polyethylene glycol, urea.
The present invention is mainly used in rice seedling bed or live field prevents and treats weeds such as barnyard grass grass, Monochoria vaginalis, pondweed, mexicana, Procumbent Falsepimpernel, fescue, difformed galingale herb, Herba Cyperi Glomerati, cyperus iria, firefly Lin.The present invention is to rice safety, and broad weed-killing spectrum, a drug make the harm that can effectively control all kinds of weeds.Owing in each preparation, added the antipoison fenclorim,, can not produce poisoning therefore to crop safety.The present invention is with low cost, can reduce drug cost.
Below the invention will be further described in conjunction with the embodiments:
Embodiment 1-10
With fenclorim respectively with pyrazosulfuron,
Sulfometuron Methyl, methoxone, bentazone, Acetochlor, different third methylamine are effective ingredient, are mixed with missible oil in the presence of solvent, cosolvent surfactant, and it is as follows to fill a prescription:
Embodiment 1-10
Embodiment 11-20
With fenclorim respectively with pyrazosulfuron,
Sulfometuron Methyl, methoxone (sodium), bentazone, Acetochlor, different third methylamine are effective ingredient, add carrier, and surfactant etc. through comminution by gas stream, mix, and are mixed with wetting powder, and it is as follows to fill a prescription:
Embodiment 11-20
Embodiment 21-30
With fenclorim respectively with pyrazosulfuron,
Sulfometuron Methyl, methoxone (sodium), bentazone, Acetochlor, different third methylamine are effective ingredient, add entry, surfactant, tackifier, viscosity stabiliser, antifreezing agent, and through ball milling, sand milling, homogeneous is mixed with suspending agent, and it is as follows to fill a prescription:
The preparation suspending agent, it is as follows to fill a prescription:
Embodiment 21-30
Claims (17)
1, rice seedling bed and direct seeding fields herbicidal composition series is characterized in that the effective ingredient composition is pyrazosulfuron+Acetochlor+fenclorim; Pyrazosulfuron+isopropyl methoxalamine+fenclorim;
Sulfometuron Methyl+Acetochlor ten fenclorims;
Ethyl methyl+isopropyl methoxalamine+fenclorim; Methoxone+Acetochlor+fenclorim; Methoxone+isopropyl methoxalamine ten fenclorims; Bentazone+Acetochlor+fenclorim; Bentazone+isopropyl methoxalamine+fenclorim; Acetochlor+fenclorim; Isopropyl methoxalamine+fenclorim is equipped with appropriate solvent, cosolvent, carrier, surfactant in each combination, is mixed with missible oil, wetting powder, suspending agent
2, according to the described serial herbicide compound of claim 1, the quality proportioning that it is characterized in that pyrazosulfuron+Acetochlor+fenclorim is 1: (1～48): (1～40), best proportioning are 1: (2～25): (2～30)
3, according to the described composition series of herbicides of claim 1, the quality proportioning that it is characterized in that pyrazosulfuron+isopropyl methoxalamine+fenclorim is 1: (0.5～50): (0.5～50), best proportioning are 1: (2～20): (2～20)
4, according to the described composition series of herbicides of claim 1, it is characterized in that
The quality proportioning of ethyl methyl+Acetochlor+fenclorim is 1: (1～48): (1～40), best proportioning are 1: (2～25): (2～30)
5, according to the described composition series of herbicides of claim 1, it is characterized in that
The quality proportioning 1 of Sulfometuron Methyl+isopropyl methoxalamine+fenclorim: (0.5～50): (0.5～50), best proportioning are 1: (2～20): (2～20)
6, according to the described composition series of herbicides of claim 1, it is characterized in that the quality proportioning at bentazone+Acetochlor+fenclorim is 100: (1～80): (1～80), best proportioning are 100: (3～60): (3～60)
7, according to the described composition series of herbicides of claim 1, it is characterized in that the quality proportioning at bentazone+isopropyl methoxalamine+fenclorim is 100: (1～80): (1～80), best proportioning are 100: (3～60): (3～60)
8, according to the described composition series of herbicides of claim 1, the quality proportioning that it is characterized in that 2 first, 4 chlorine (sodium)+Acetochlor+fenclorim is 100: (1～100): (1～100), best proportioning are 1: (5～50): (5～50)
9, according to the described composition series of herbicides of claim 1, the quality proportioning that it is characterized in that 2 first, 4 chlorine (sodium)+isopropyl methoxalamine+fenclorim is 100: (1～100): (1～100), best proportioning are 1: (5～50): (5～50)
10, according to the described composition series of herbicides of claim 1, the quality proportioning that it is characterized in that Acetochlor+fenclorim is 100: (1～100), best proportioning are 100: (10～50)
11, according to the described composition series of herbicides of claim 1, the quality proportioning that it is characterized in that isopropyl methoxalamine+fenclorim is 100: (1～100), best proportioning are 100: (10～50)
12, according to the described composition series of herbicides of claim l, solvent for use is aromatic hydrocarbon, heavy aromatic hydrocarbon, fatty alcohol when it is characterized in that preparing missible oil, and institute just auxiliary agent is cyclohexanone, dimethyl formamide, dioxane, dimethyl sulfoxide (DMSO), ethyl acetate, naphthalene, methyl naphthalene
13, according to the described composition series of herbicides of claim 1, it is characterized in that preparing the used sanction body of wetting powder is kaolin, swelling scholar, atlapulgite, sepiolite, white carbon, diatomite, precipitated calcium carbonate, talcum powder, the plaster of paris, chalky soil, potter's clay, montmorillonite, clay
14, according to the described composition series of herbicides of claim 1, it is characterized in that employed surfactant can select anionic for use, nonionic, or their mixed type, dodecyl benzene sulfonate, trivial amber, lauryl sodium sulfate, potassium oleate (sodium), this quality sodium sulfonate (calcium), NNO, BX, LS, dioctyl sodium sulfosuccinate, nekal, alkyl polyoxyethylene ether phosphate, No. 100, farming breast, No. 10, peaceful breast, By, agricultural emulsifier NO, No. 1600, tween are arranged, by pears alcohol APEO, 0204C, 0206B etc.
15, according to the described composition series of herbicides of claim 1, it is characterized in that preparing the selected tackifier of suspending agent is xanthans, the basic cellulose of carboxylic first (second) (sodium), methylcellulose, polyvinyl alcohol, polyvinylpyrrolidone, soluble starch and derivative thereof, gum Arabic, gelatin, algin, agar, silica gel etc.
16, according to the described composition series of herbicides of claim 1, it is characterized in that preparing the selected viscosity stabiliser of suspending agent is white carbon, diatomite, silica gel, bentonite, precipitated calcium carbonate, perlite, talcum powder
17, according to the described composition series of herbicides of claim 1, it is characterized in that preparing the selected antifreezing agent of suspending agent is ethylene glycol, propane diols, glycerine, polyethylene glycol, urea.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96118409 CN1181880A (en) | 1996-11-12 | 1996-11-12 | Herbicide series composition for rice seedling field and direct seeding field |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96118409 CN1181880A (en) | 1996-11-12 | 1996-11-12 | Herbicide series composition for rice seedling field and direct seeding field |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1181880A true CN1181880A (en) | 1998-05-20 |
Family
ID=5125070
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 96118409 Pending CN1181880A (en) | 1996-11-12 | 1996-11-12 | Herbicide series composition for rice seedling field and direct seeding field |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1181880A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1061215C (en) * | 1998-06-20 | 2001-01-31 | 吴应多 | Compound herbicide for paddy field |
| CN102524302A (en) * | 2012-01-08 | 2012-07-04 | 庄晓曦 | Rice seed soaking agent and using method thereof |
| CN102626083A (en) * | 2012-03-22 | 2012-08-08 | 中国水稻研究所 | Herbicide resistant regulator for safe growth of rice |
| CN101282648B (en) * | 2005-09-12 | 2013-05-29 | 先正达参股股份有限公司 | Water-suspendable agricultural chemical composition |
| TWI405537B (en) * | 2005-02-04 | 2013-08-21 | Syngenta Participations Ag | Process for the control of undesired plant growth in rice |
| US11071296B2 (en) | 2014-12-22 | 2021-07-27 | Mitsui Agriscience International S.A./N.V. | Liquid sulfonylurea-containing herbicidal compositions |
| US11464225B2 (en) | 2016-06-21 | 2022-10-11 | Battelle Uk Limited | Liquid sulfonylurea- and li-salt containing herbicidal compositions |
| EP4591712A1 (en) * | 2024-01-23 | 2025-07-30 | Adama Agan Ltd. | Method of treating rice |
-
1996
- 1996-11-12 CN CN 96118409 patent/CN1181880A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1061215C (en) * | 1998-06-20 | 2001-01-31 | 吴应多 | Compound herbicide for paddy field |
| TWI405537B (en) * | 2005-02-04 | 2013-08-21 | Syngenta Participations Ag | Process for the control of undesired plant growth in rice |
| CN101282648B (en) * | 2005-09-12 | 2013-05-29 | 先正达参股股份有限公司 | Water-suspendable agricultural chemical composition |
| CN102524302A (en) * | 2012-01-08 | 2012-07-04 | 庄晓曦 | Rice seed soaking agent and using method thereof |
| CN102626083A (en) * | 2012-03-22 | 2012-08-08 | 中国水稻研究所 | Herbicide resistant regulator for safe growth of rice |
| US11071296B2 (en) | 2014-12-22 | 2021-07-27 | Mitsui Agriscience International S.A./N.V. | Liquid sulfonylurea-containing herbicidal compositions |
| US12268209B2 (en) | 2014-12-22 | 2025-04-08 | Mitsui Agriscience International S.A./N.V. | Liquid sulfonylurea-containing herbicidal compositions |
| US11464225B2 (en) | 2016-06-21 | 2022-10-11 | Battelle Uk Limited | Liquid sulfonylurea- and li-salt containing herbicidal compositions |
| US12364261B2 (en) | 2016-06-21 | 2025-07-22 | Battelle Uk Limited | Liquid sulfonylurea- and Li-salt containing herbicidal compositions |
| EP4591712A1 (en) * | 2024-01-23 | 2025-07-30 | Adama Agan Ltd. | Method of treating rice |
| WO2025158281A1 (en) * | 2024-01-23 | 2025-07-31 | Adama Agan Ltd. | Method of treating rice |
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