CN1180685A - Long-lasting special compound fertilizer and manufacturing technonoly thereof - Google Patents
Long-lasting special compound fertilizer and manufacturing technonoly thereof Download PDFInfo
- Publication number
- CN1180685A CN1180685A CN96119508A CN96119508A CN1180685A CN 1180685 A CN1180685 A CN 1180685A CN 96119508 A CN96119508 A CN 96119508A CN 96119508 A CN96119508 A CN 96119508A CN 1180685 A CN1180685 A CN 1180685A
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- long
- composite fertilizer
- production technique
- ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 52
- 150000001875 compounds Chemical class 0.000 title claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 23
- 230000005923 long-lasting effect Effects 0.000 title 1
- 239000002131 composite material Substances 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 27
- 239000000618 nitrogen fertilizer Substances 0.000 claims description 27
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 230000003389 potentiating effect Effects 0.000 claims description 12
- 229910021529 ammonia Inorganic materials 0.000 claims description 9
- 239000012747 synergistic agent Substances 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 6
- 239000002601 urease inhibitor Substances 0.000 claims description 6
- 229940090496 Urease inhibitor Drugs 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- 210000003608 fece Anatomy 0.000 claims description 3
- 239000010871 livestock manure Substances 0.000 claims description 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 2
- 239000004254 Ammonium phosphate Substances 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 claims description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 239000002367 phosphate rock Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 241000208125 Nicotiana Species 0.000 description 3
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 240000008042 Zea mays Species 0.000 description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 3
- IEPIYXWWJPPIEM-UHFFFAOYSA-N benzene-1,3-diol;benzene-1,4-diol Chemical compound OC1=CC=C(O)C=C1.OC1=CC=CC(O)=C1 IEPIYXWWJPPIEM-UHFFFAOYSA-N 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 235000005822 corn Nutrition 0.000 description 3
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014075 nitrogen utilization Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 235000006180 nutrition needs Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Chemical group 0.000 description 1
- 239000011591 potassium Chemical group 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011573 trace mineral Chemical group 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G1/00—Mixtures of fertilisers belonging individually to different subclasses of C05
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
A long-acting compound fertilizer features that 0.2-0.8 wt.% N fertilizer synergist is added to it for elongating its active period by 100-150 days and increasing the utilization rate of N by 15-20% .Its advantages are increasing yield saving fertilizer and saving labour.
Description
What the present invention relates to is a kind of compound manure and manufacturing process thereof, a kind of specifically long-acting specific composite fertilizer material and manufacturing process thereof.
Production at present and the compound fertilizer special that uses, mostly being nitrogen, phosphorus, potassium and trace element forms, some has also added organic materials and bacteria agent, wherein nitrogenous fertilizer mostly is urea and liquefied ammonia, because the fertilizer efficiency period of nitrogenous fertilizer short (40~60 days) is at the bottom of the utilization ratio (about 35%), so in crop growth, later stage also will repeatedly impose nitrogenous fertilizer in order to satisfy the required nitrogen nutrition of crop growth.
The present invention be directed to above-mentioned existing problems, it is long to propose a kind of fertilizer efficiency period, long-acting specific composite fertilizer that utilization ratio is high and manufacturing process thereof.
Nitrogen fertilizer potentiating agent is a kind of auxiliary agent that improves the nitrogen fertilizer efficiency, divides two kinds of nitrification inhibitor and urease inhibitors, and it can improve the utilization ratio of nitrogenous fertilizer effectively, prolongs its fertilizer efficiency period, makes agricultural reach volume increase, increases income, economizes fertilizer, saving of labor's net effect.Present existing technology is that nitrogen fertilizer potentiating agent and nitrogenous fertilizer are used, or makes long-acting nitrogen fertilizer such as long-acting carbamide and long-term efficiency bicarbonate ammonium etc., also never has nitrogen fertilizer potentiating agent is added precedent in the composite fertilizer special.Feature of the present invention is the nitrogen fertilizer potentiating agent that adds its nitrogenous fertilizer weight 0.2~0.8% in composite fertilizer special, nitrogenous fertilizer comprises: urea, liquefied ammonia, sulphur ammonium, ammonium nitrate, ammonium chloride etc., nitrogen fertilizer potentiating agent comprises: urease inhibitor hydroquinone (Resorcinol) and nitrification inhibitor Dyhard RU 100 (Dicyanodiamide) etc.The production technique of the long-acting specific composite fertilizer of above-mentioned formation has two kinds: 1. granulating method production technique: with powdery base fertilizer and synergistic agent (or making powdery) is raw material, heat by humidification, granulation in rotary drum or garden dish machine, the long-acting specific composite fertilizer that contains synergistic agent is made in the drying moulding.This method is fit in the production, the middle-size and small-size producer of lower concentration product.2. slurry process production technique: be a kind of compound manure production technique that combines with ammonium phosphate fertilizers, earlier with phosphoric acid and ammonia or sulfuric acid ground phosphate rock and ammonia generation slip, add other base fertilizers and synergistic agent again, granulating and forming is produced long-acting specific composite fertilizer then.This technology is fit to produce the large and medium-sized enterprise of middle and high concentration product.
The characteristics of long-acting specific composite fertilizer are: owing to added synergistic agent in the composite fertilizer special, can make the fertilizer efficiency period of composite fertilizer special extend to 100~150 days, nitrogen utilization efficiency improves 15~20%, the fertile process of confession of composite fertilizer special and the regulation of fertilizer requirement of crop are coordinated substantially, better met the nutritional needs of three breeding times of crop, reached volume increase, increase income, economize fertilizer, saving of labor's net effect.Particularly to overlay film, exempt to intertill, new agricultural technology that inconvenience such as rice field fish culture is topdressed, played irreplaceable vital role, solved the crucial difficult problem that these technology inconvenience are topdressed, make these new technologies bring into play its effect of increasing production better.
This technology is suitable for various composite fertilizer specials such as cotton, corn, wheat, tobacco, fruit tree, vegetables etc., composite fertilizer special can be by adding nitrogen fertilizer potentiating agent, make corresponding long-acting specific composite fertilizer, its production technique can only be done a small amount of investment and change and can go into operation on the basis of original production composite fertilizer special.
Example 1 cotton long-acting specific composite fertilizer granulating method production technique
Nitrogen fertilizer potentiating agent is that the part by weight of nitrogenous fertilizer in urease inhibitor hydroquinone (Resorcinol) and the composite fertilizer special is 0.3% adding, burden process in its production technique adds quinhydrones with this ratio, stir then, make the cotton long-acting specific composite fertilizer that adds synergistic agent through granulation, drying forming.
Example 2. corn long-acting specific composite fertilizer slurry process production technique
Nitrogen fertilizer potentiating agent is that the part by weight of nitrogenous fertilizer in nitrification inhibitor Dyhard RU 100 (Dicyanodiamide) and the composite fertilizer special is 0.6% adding, generate slip with phosphoric acid and ammonia earlier, add Dyhard RU 100 and other material fertilizers more according to the above ratio, granulating and forming is made the corn long-acting specific composite fertilizer that adds synergistic agent then.
Example 3 wheat long-acting specific composite fertilizer granulating method production technique
Nitrogen fertilizer potentiating agent is that the part by weight of nitrogenous fertilizer in urease inhibitor hydroquinone (Resorcinol) and the composite fertilizer special is 0.2% adding, add quinhydrones at the burden process of producing with aforementioned proportion, right stirs, and the granulation drying forming is made the wheat long-acting specific composite fertilizer that adds synergistic agent.
Example 4 tobacco long-acting specific composite fertilizer slurry process production technique
Nitrogen fertilizer potentiating agent is that the part by weight of nitrogenous fertilizer in nitrification inhibitor Dyhard RU 100 (Dicyanodiamide) and the composite fertilizer special is 0.7% adding.Earlier make slip with phosphoric acid and ammonia, add Dyhard RU 100 and other material fertilizers more according to the above ratio, the tobacco long-acting specific composite fertilizer that adds Dyhard RU 100 is made in granulation then.
Use urease inhibitor hydroquinone and nitrification inhibitor Dyhard RU 100 respectively, adopt different ratios and production technique can produce the long-acting specific composite fertilizer of various crops such as beet, fruit tree and vegetables.
Claims (2)
1. long-acting specific composite fertilizer is characterized in that:
A. the nitrogen fertilizer potentiating agent that in composite fertilizer special, adds its nitrogenous fertilizer weight 0.2~0.8%;
B. nitrogenous fertilizer comprises: urea, liquefied ammonia, sulphur ammonium, ammonium nitrate, ammonium chloride etc., nitrogen fertilizer potentiating agent comprises: urease inhibitor hydroquinone and nitrification inhibitor Dyhard RU 100.
2. method of producing above-mentioned composite fertilizer is characterized in that:
A. granulating method production technique: with powdery base fertilizer and synergistic agent is raw material, by humidification heating, granulation in rotary drum or garden dish machine, drying moulding;
B. slurry process production technique: be a kind of compound manure production technique that combines with ammonium phosphate fertilizers, with phosphoric acid and ammonia or sulfuric acid ground phosphate rock and ammonia generation slip, add other base fertilizers and synergistic agent again, then granulating and forming earlier.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96119508A CN1180685A (en) | 1996-10-25 | 1996-10-25 | Long-lasting special compound fertilizer and manufacturing technonoly thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96119508A CN1180685A (en) | 1996-10-25 | 1996-10-25 | Long-lasting special compound fertilizer and manufacturing technonoly thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1180685A true CN1180685A (en) | 1998-05-06 |
Family
ID=5125759
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96119508A Pending CN1180685A (en) | 1996-10-25 | 1996-10-25 | Long-lasting special compound fertilizer and manufacturing technonoly thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1180685A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101121615B (en) * | 2006-08-10 | 2010-05-26 | 河北天人化工股份有限公司 | Disposable corn composite fertilizer and producing technique thereof |
| CN101412643B (en) * | 2007-10-19 | 2011-03-16 | 中国科学院沈阳应用生态研究所 | Use of long-acting compound fertilizer in licorice planting |
| CN101723731B (en) * | 2009-02-25 | 2012-04-04 | 山东三方化工集团有限公司 | Environment-friendly long-acting compound fertilizer and preparation method thereof |
| CN102417427A (en) * | 2011-09-08 | 2012-04-18 | 河南心连心化肥有限公司 | Polyaspartic acid slow release compound fertilizer and production method thereof |
| CN102875238A (en) * | 2012-10-19 | 2013-01-16 | 新疆农业科学院土壤肥料与农业节水研究所 | Whole-process combined drip irrigation fertilizer for fruit trees |
| CN103254007A (en) * | 2013-05-17 | 2013-08-21 | 湖南省土壤肥料研究所 | Special additional fertilizer for tobacco with function of improving effect of nitrogen fertilizer and use method thereof |
| CN107721777A (en) * | 2016-08-12 | 2018-02-23 | 江苏省地矿复合肥厂 | A kind of urea ammonia enzyme Synergistic composite fertilizer |
| US10501383B2 (en) | 2014-10-31 | 2019-12-10 | Koch Agronomic Services, Llc | Nitrification inhibitor compositions and methods of making thereof |
-
1996
- 1996-10-25 CN CN96119508A patent/CN1180685A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101121615B (en) * | 2006-08-10 | 2010-05-26 | 河北天人化工股份有限公司 | Disposable corn composite fertilizer and producing technique thereof |
| CN101412643B (en) * | 2007-10-19 | 2011-03-16 | 中国科学院沈阳应用生态研究所 | Use of long-acting compound fertilizer in licorice planting |
| CN101723731B (en) * | 2009-02-25 | 2012-04-04 | 山东三方化工集团有限公司 | Environment-friendly long-acting compound fertilizer and preparation method thereof |
| CN102417427A (en) * | 2011-09-08 | 2012-04-18 | 河南心连心化肥有限公司 | Polyaspartic acid slow release compound fertilizer and production method thereof |
| CN102875238A (en) * | 2012-10-19 | 2013-01-16 | 新疆农业科学院土壤肥料与农业节水研究所 | Whole-process combined drip irrigation fertilizer for fruit trees |
| CN103254007A (en) * | 2013-05-17 | 2013-08-21 | 湖南省土壤肥料研究所 | Special additional fertilizer for tobacco with function of improving effect of nitrogen fertilizer and use method thereof |
| CN103254007B (en) * | 2013-05-17 | 2015-04-08 | 湖南省土壤肥料研究所 | Special additional fertilizer for tobacco with function of improving effect of nitrogen fertilizer and use method thereof |
| US10501383B2 (en) | 2014-10-31 | 2019-12-10 | Koch Agronomic Services, Llc | Nitrification inhibitor compositions and methods of making thereof |
| CN107721777A (en) * | 2016-08-12 | 2018-02-23 | 江苏省地矿复合肥厂 | A kind of urea ammonia enzyme Synergistic composite fertilizer |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |