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CN1173471A - Method for forming pattern on surface of crystal or optical glass - Google Patents

Method for forming pattern on surface of crystal or optical glass Download PDF

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Publication number
CN1173471A
CN1173471A CN 96106437 CN96106437A CN1173471A CN 1173471 A CN1173471 A CN 1173471A CN 96106437 CN96106437 CN 96106437 CN 96106437 A CN96106437 A CN 96106437A CN 1173471 A CN1173471 A CN 1173471A
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pattern
light
crystal
glue
substrate
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Chinese (zh)
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简英彬
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Individual
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00Other surface treatment of glass not in the form of fibres or filaments
    • C03C23/0005Other surface treatment of glass not in the form of fibres or filaments by irradiation
    • C03C23/002Other surface treatment of glass not in the form of fibres or filaments by irradiation by ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001General methods for coating; Devices therefor
    • C03C17/002General methods for coating; Devices therefor for flat glass, e.g. float glass

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Printing Methods (AREA)

Abstract

The invention discloses a method for forming patterns on the surface of crystal or optical glass, which comprises coating a layer of uniform and thin ultraviolet glue between the pattern substrate printed with patterns and the surface of a transparent material matrix as a pattern transfer medium, irradiating the pattern with ultraviolet light for a proper time to dry and fix the pattern, stripping the pattern from the pattern substrate, and enabling the ultraviolet glue layer to be firmly adhered on the surface of the transparent material matrix, thereby forming delicate and beautiful patterns on the surface of the transparent material matrix just like full-color printing paper. The invention can also glue the transparent material base body with transfer printing pattern with the main body of another article to form the composition with transparent characteristic pattern between the gluing interlayers.

Description

Surface at crystal or opticglass forms method of patterning
The present invention relates to form method of patterning at article surface, be particularly related on the surface of crystal or opticglass and form method of patterning, especially refer to the medium of a kind of mat ultraviolet light glue as pattern transfer, make between the surface of light transmissive material matrix or interlayer, form one attractive in appearance and have a pattern of light transmission features, the method that can promote the attractive in appearance of finished product and be worth.
Crystal promptly has the appellation of " ice in thousand " or " Bodhisattva stone ", visible ancients' valuing it from ancient times; And because quartzy or its analogue has refrangible light, texture is penetrating, and can form as the dazzling surface as the diamond, so often be made into meticulous artwork, orndments or jewellery with oneself, and equally with jade, emerald, the contour value jewelry of gold and silver be carried out classical collection and spread; And crystal is processed to artwork, orndments then promptly has far away from China Chinese Tang period, find its trace in some artifacts that are unearthed of Chang Kecong, therefore there has been the history in two over thousands of years in it in China, it is one of Chinese tratitional technology, they often are made into the simple crystal ball of moulding, quartzy post, article such as Amethyst Geode, there are some then to be engraved as complicated moulding as the figure of buddha, beads, bracelet (bracelet), the orndments of lucky pendant or even animal shape, especially to modern age, progressive growth in the living standard because of society, people are increased the demand benefit of these class article, and examine the quartzy article of this class closely with more harsh aesthetic standard, therefore Crystal ornaments now such as nothing are looked for and will be difficult to satisfy the popular demand of consumption.
And be this demand form that adapts on the market now, the production dealer of each quartzy artwork racks one's brains invariably, seeking breakthrough, seek for and to create the finished product of trying to be different is consumed masses with attraction favor, yet as everyone knows, since quartzy material hard, be easy to cracked characteristic, make its processing that high degree of difficulty be arranged, therefore this also hindered the attempt of quartzy product diversification; At present general on the market common quartzy artwork, no matter its material is artificial synthetic half lead water crystalline substance, full lead water crystalline substance, natural regeneration (system again) crystal or the finished product of pure natural mineral crystal, generally approximately can be distinguished into following two kinds of product form: one is combined into the product of different appearance for mat cutting, outside Quartz lamp decoration, quartzy vase, wineglass, imitative animal appearance and various special solid geometry patterns etc. (and this non-this patent category is so will not deeply inquire into) are arranged still; Another kind then is in being conceived to form various decorations at crystal surface, reach by the see-through of crystal and to beautify the effect of viewing and admiring, these article are as artwork or the souvenir presents such as ornaments, necklace weight, key circle, Wen Zhen, lucky pendants of engraving or paste the impression line at crystal surface.
For above-mentioned these existing technology, be to do following brief introduction explanation at crystal surface formation pattern:
(1) surface pastes method: be in advance after stamping pattern on resin film or the paper, printed patterns on the direct clip paper, overlay on the crystal base surface or its Jie is put centre at these two quartzy matrixes with solid, the mat solid is folded mutually, pressurization, the gummed of heating is one, just like the used technology of present widely used so-called gummed decorative glass board, but this working method not only needs skilled bonding technique, and substrate (being paper or resin film) for printed patterns, the selection of printing coatings (China ink) all has extremely many restrictions, just enables to obtain required careful color glaze pattern picture satisfactorily and does not have the product of finishing that bubble generates; In addition, because of the substrate of these printed patterns has specific thickness, the material of these substrates is not as the stable material quality of quartzy matrix, so the former one side of finished product Chang Yinqi printed patterns substrate is exposed in the air, with the passing of time unavoidably be subjected to daylight or atmospheric oxidation and the color of colored drawing pattern is changed or fade, and this open is damaged again when being stain the back wiping easily; And the latter has middle resin film or the facial tissue that is printed on color glaze colored drawing or grain pattern with two quartzy matrix folder Jie, thickness because of this interlayer substrate, so common periphery at its joint, need remake special border seal processing just can be practical, otherwise its middle film or facial tissue are changed by room temperature and humidity very easily and peel off, and are not enough to the permanent classical collection purposes as the pendulum decorations.
(2) surface printing method: be mat printing screen plate or ink-jet application, the pattern decorative pattern directly is printed on the crystal base surface, though this kind surface working does not have paper to transplant in gluing the trace of crystal surface and comparatively attractive in appearance, but direct printing-ink on quartzy matrix, easily cause the printing ink skewness and have the printing position to be difficult to the aligned puzzlement again, inferior very difficult breakthrough is adopted two or more colors or is done more accurate complicated patterns printing; Again, the shortcoming of the maximum of this printing is, hard and the lattice dense structure smooth surface because of quartzy material, so be printed in the printing ink of crystal surface the actual problem that is difficult to overcome that is difficult for inking, dried fixed is arranged, so the easy scratch of the pattern of its finished product, (gently scraped promptly by hard thing can drop) comes off, and this surface printing method can only find expression in literal and simple lines decorative pattern usually, makes the finished product outward appearance dullness of formation stiff, does not meet now the attractive in appearance careful requirement to Crystal ornaments.In addition, above-mentioned these two kinds of technology have more a common shortcoming, and to be the color glaze colored drawing pattern go to constitute by color glaze color, coating or printing ink or its mixture of light tight body, can't represent the penetrating brilliance of quartzy article, exquisitely carved characteristics, this also is that this method is shown the major cause that is extensively adopted by senior Crystal ornaments.
(3) method is engraved on the surface: be directly to sandblast at crystal surface to handle or come the crystal surface piercing with ultrasound, radium-shine (laser), the shortcoming that this method does not have above-mentioned two kinds of crystal surfaces to handle, and generally speaking the piercing position is as long as under the situation that not be infected with by dirt, the figure line that it represents does not come off constancy shape yet, the depth because of piercing changes again, in the penetrating characteristic of crystal, can present and have gradation sense slightly, and obtain another kind of effect attractive in appearance; Yet this piercing processing mode adds man-hour at the figure line of making small area, can only show its pattern decorative pattern with atomized surface effect, and can't go up different colours and come colored drawing to handle characteristics with showing pattern, therefore the careful property of figure line that is presented is subjected to great restriction; In addition, because of quartzy material surface is subjected to the result of powerful se, piercing, make the figure ornament or the rag that machine produce the irregular coarse burr of spination and cause flaw in periphery regular meeting; In addition, its lines of figure ornament that this method forms are thick and stiff, promptly can't show for complicated a little figure ornament; Again, as materials such as mineral crystals then is to ponder shaping by cutting substantially, because of often containing inclusion, the crack that is unsuitable for cutting or chasing processing in extreme hardness and this class raw ore, and idol is made up of different crystallizations such as presenting nature aberration, Bai Jing, citrine, amethyst, rose crystalline substance, a crystalline substance, powder crystal in a mineral crystal material, is subjected to bigger restriction so make in the selection of chasing pattern; Moreover, calculate with tooling cost, sandblast or radium-shine, ultrasound processing charges is to be these 5~10 times of aforesaid surface printing methods at least, for the surface pastes 50~100 times of method, can't roll over mass production again and fall cost, therefore the dealer is perplexed endlessly.
(4) electroplating surface method: based on the shortcoming of above-mentioned prior art, be have advanced person of the same trade or business promptly Austria (AUSTRIA) (the D.SWAROVSKI ﹠amp of rope Laski company; CO.,), stretch to spread out from aforesaid " surface printing method " and improved and propose a kind of technology that forms the minute surface figure ornament in crystal surface, be to do monochrome or two color printing at crystal surface earlier, and then with the top layer vacuum plating on printing surface with the setting of these printed patterns, and cause as strong reflection (reflective) effect as the mirror; This technology pastes method than above-mentioned surface really or the progress of surface printing method is a lot, the pattern of this formation is had be difficult for stained, come off and become advantages such as (moving back) look, but this pipoint technique and complicated manufacturing course make the degree of difficulty thereby the increase of its processing, and because the machinery equipment of a whole set of process for processing is huge, complicated and expensive, again because of being only applicable to do single specification, the production of the product that quantity is huge, so it is obviously also improper for the present market status that focuses on a small amount of various artwork, again, the manufacturing enterprise that all belongs to middle and small scale with respect to exhausted most quartzy artwork manufacturer now, so the highly difficult technology of this vacuum plating and expensive machinery equipment, and do not meet the rate of return on investment of general manufacturer, so being unmanned follow-up, present quartzy artwork production industry adopts.In addition,, desire also to make it to become not light-permeable though the surface with figure ornament of the formed quartzy article of technology has the reflection of the cleaning of minute surface in accordance with the law, and the original exquisitely carved characteristics of the quartzy article that detracted.
Because the above-mentioned existing every shortcoming that forms the technology of pattern at crystal surface, gram is difficult repeatly through further investigation for the inventor, and then a kind of innovation fully is provided form the method for figure ornament at crystal surface, make in simple operation technology and can form attractive in appearance, careful printed patterns and come the benefit aesthetic feeling of brilliant artwork of surging, and be able to cheap cost and manufacture a finished product apace at quartzy article surface or interlayer.
Main purpose of the present invention is providing a kind of surface in quartzy or its analogue to form method of patterning, the pattern of crystal surface that Using such method is formed at is meticulous, attractive in appearance just as the full-color pattern that is printed in above the paper, not only pattern kind, color are unrestricted, and formed patterned layer has the characteristic of transmit light, and it is mashed honorable to make beautiful, exquisitely carved pattern and quartzy finished product shine, more increase gem mutually.
An of the present invention purpose is to provide a kind of surface at quartzy or its analogue to form method of patterning, it does not need coating or the ink printing or the bonding technique of height, only the existing printing technology of mat directly on a kind of polynary ester synthetic paper the printshop need figure, mat ultraviolet light glue is needed on the surface of quartzy matrix with it again, therefore it is very easy that it makes processing, the finished product success ratio is very big, and the hard firm difficult drop-off of patterned layer that forms.
Another object of the present invention is for providing a kind of technology that any surface with material of light transmission forms pattern attractive in appearance that is widely used in, be that mat is in being coated with the medium of the even and thin ultraviolet light glue of one deck as pattern transfer on the pattern substrate that is printed on pattern and between the surface of light transmissive material matrix, this layer of mat ultraviolet light glue is shone and dried fixed by the time of ultraviolet light source appropriateness again, with pattern from the pattern strippable substrate, and this ultraviolet light glue-line is firmly covered in the surface of light transmissive material matrix, thereby form thin layer decorative pattern attractive in appearance on the surface of light transmissive material matrix.
A further object of the present invention is that a kind of method that forms the quartzy artwork with light transmission decorative pattern between surface or knitting layer is provided, this method is for being that the medium transfer printing is formed at crystal surface by the pattern that will be printed on the polynary ester combination board with ultraviolet light glue, or again should the surface form figuratum crystal and another quartzy gummed and pattern is formalized between two quartzy gummed interlayers, make quartzy finished product indistinct beautiful pattern that shows light-permeable in it is glittering and translucent, and benefit increases its attractive in appearance and value, reach increase quartzy artwork with similar as agate, beautiful, the competitive capacity of jasper ornaments such as emerald, and the purpose of expansion product demand.
Below the advantage that invention will be further ex-plained with reference to the appended drawings:
Fig. 1 is for showing the work flow block diagram of the inventive method.
Used herein to material comprise three kinds: pattern substrate, quartzy matrix and offset medium.
Wherein, pattern substrate refers to be printed with the polynary ester synthetic paper (POLYESTER PAPER is commonly called as and tears not waste paper, hereinafter to be referred as P.P paper) of required pattern.
Here the quartzy matrix of indication is a kind ofly to ponder and have a smooth and smooth surface at least through preparatory processing; In general, this crystal matrix preferably is laminar, and it simultaneously is the plane, and another side be the best for tool convex globoidal person slightly; And its material extensively be defined as comprise various mineral crystals, regeneration crystal, synthetic quartz (being crystal glass), generally glass or all kinds of material hard, have jewel, jasper and a spar than light-transmissive.
Offset medium of the present invention refers to a kind of ultraviolet light glue (Ultraviolet Curing Adhesive is commonly called as UV glue, hereinafter to be referred as UV glue) of low viscosity.
Also using in the present invention a kind of ultraviolet projection machine (being commonly called as the UV machine), is to be used to provide ultraviolet light source (hereinafter to be referred as the UV light source) to make ultraviolet light gelling fixed as offset medium. ◎ forms the method for pattern in the surface of quartzy or its analog:
Mentioned method is the making that reaches achievement at quartzy telogenesis shape figure ornament: A, selected pattern and this pattern substrate by following operating process (as shown in Figure 1):
The pattern of indication, its kind, kenel, color are unrestricted, as long as can utilize printing technology be printed on the specified paper all can, that is pattern can be selected for use full color, the elaborate composition or has gold stamping special pattern (sign or letter symbol).
After determining required pattern, the making of this pattern is identical with general printing technology commonly used substantially, its maximum difference is and pattern must be printed on the P.P paper, and the pattern after this printing must treat that it just can be used as pattern substrate required for the present invention after air-dry fully.
Can not be too thin as pattern substrate P.P paper, because behind ultraviolet light irradiation, understanding the relation of Yin Wendu rising, too thin P.P paper makes P.P paper slight deformation, and the planarization that influences drawing causes the shift defect of pattern transferring, and after tested at 200pb/cm 2Above P.P paper can meet the requirements.
Above-mentioned pattern drying process, find according to inventor's test-results many times, still can not use after above-mentioned pattern finishes printing at once, must wait printing-ink on the P.P paper to be dried to and to a certain degree can use, and this general use about time more than one month of natural air drying.
In addition, need in addition on literal or sign, to do gold stamping processing, then can use then in finishing printing the gold stamping again pattern on P.P paper of individual week of one of back as pattern itself.
The careful selection board of the gold stamping need of pattern when most orange cold foil meets liquid state UV glue, promptly can produce the chemical transformation that melts erosion in the short period of time, thereby destroys the attractive in appearance of pattern, adopts so the orange cold foil of class is not suitable for the present invention.B, quartzy matrix are from the process of pattern substrate pattern transferring: the coating of a. offset medium:
Desiring on pattern substrate got the figure scope or in the desire pattern transferring surface of quartzy matrix, is coated with one deck UV glue equably, and generally speaking being somebody's turn to do glue-line is as thin as a wafer between 0.01mm~0.03mm.
The selection of UV glue: the employed UV glue of this flow process, after the inventor makes tens of kinds of different UV colloid property testings, the most suitable with the UV glue that adopts the numbering 401 that numbering 4303 that German DELO company produces or U.S. DYMAX company produce, and its viscosity is about about 50~150 (CPS) (23 ℃ in Brookfield viscometer).
Necessary extreme care in this coating process, glue on the coated face of pattern substrate or quartzy matrix can not have any bubble to produce or impurity (especially granulous) mixes, because have the place of bubble point or impurity will cause this place's pattern can't transfer printing success, and cause the flaw of quartzy product.
The excessive coating of UV glue causes glue-line too thick, and under specific ultraviolet illumination and irradiation time, can producing glue-line, to solidify the typing degree not enough, then makes pattern transfer imperfect.B. the set up procedure of pattern transferring:
The smooth-flat-surface of quartzy matrix is placed in desire pattern transferring place on the pattern substrate, and should pay attention to placing skill this moment especially, avoids producing bubble or mix impurity between bonding surface, otherwise should the place can cause the defective that pattern can't the transfer printing success.The typing of figure is got in c, transfer printing:
With ultraviolet light source by quartzy matrix top, the bonding surface of quartzy matrix and pattern substrate is implemented the irradiation time of appropriateness, make the UV glue-line little by little solidify typing, and the one side of this UV glue film is pasted the surface that is glued at quartzy matrix with the jail, and another side then is needed on pattern on this layer UV glue film from peeling off on the pattern substrate because of the printing ink (or gold stamping) of stinging the pattern on the corrosion figure case substrate.
During above-mentioned irradiation operation, its light source must be the vertical irradiation state, could control effectively irradiation light quantity, and the situation generation of any relative displacement must not be arranged between quartzy matrix and the pattern substrate between the light period, fails to avoid pattern transferring.
" the appropriate irradiation time " of this program is usually below one minute, more than the five seconds, and this " appropriate irradiation time " will be because of the transmittance of the material of the UV glue kind selected for use, coating glue-line thickness degree or quartzy matrix and light illumination strong and weak different, and time-histories length is different, and " the appropriate irradiation time " of several common used materials of experiment test is listed as follows: test conditions: fixed UV light source: 350-400mw/cm 2(INTENSITYMILLIWATTS/SQUARED CENTIMETERS)
UV glue: U.S. DYMAX company produces, numbering 401, and viscosity is 50~150 (CPS) (23 ℃ in Brookfield viscometers)
Irradiation vertical range: 4cm
Material thickness: 6cm
Material size (pattern transferring area): diameter 2.5cm
Material category Optimal irradiation time (second)
Natural regeneration crystal ????11±1.0
Mineral crystal ????12±1.0
Flint glass (32%PbO) ????21±1.5
Opticglass (white glass) ????24±2.0
Blue or green light glass (common) ????30±2.5
The tolerance error degree of " appropriate irradiation time " in this process is minimum, and its occupy epochmaking key in getting the figure success or not, when irradiation time too in short-term, the not dried as yet fixed of glue-line then will make the partial graph China ink transfer printing successfully cause pattern defect, and it is of a specified duration excessively to work as irradiation time, the improper cellulosic of getting on the P.P paper of stinging of glue-line causes ugly vestige first, it clears up difficult and time-consuming increase production cost again, second glue-line will influence the attractive in appearance of global pattern because of the dendritic crackle of internal stress generation tree.
The light and shade colour system kind of the thickness of the printing-ink of pattern or printing ink has partly influence to the transfer printing success or not, and promptly thicker or printing ink is dead color when being when printing-ink, and is big to the tolerance error value of UV light source irradiation time.
This pattern transferring is to be attached on the UV glue-line that solidifies typing, and this glue-line also is the surface that closely is covered on quartzy matrix, again because of this UV glue-line that solidifies typing has suitable hardness and the wear-resistant intensity that falls from the sky or outer space, so the crystal base surface difficult drop-off of pattern transferring or scrape damage.◎ has the constituent of light transmission pattern at the glue press interlayer;
The surface of finishing according to preceding method has the quartzy matrix of figure ornament, also can further process and with the main body gummed of other article, form and have the ornament or the artwork of pattern sandwich.
The article of this indication be meant any have a smooth flat and foot may with the article of the surface gummed with figure ornament of this crystal matrix, do not limit material or moulding, can be as the light-permeable material of crystal, opticglass etc. that what also can be metal reaches nonmetallic as non-light transmittance materials such as jade, potteries as silver, copper, alloy etc.
And the cementing agent that this step adopted can be to appoint to close the cementing agent with transparent characteristic, for example: various Resin adhesives, AB glue, Instant cement or UV glue etc.
Wherein, when adopting UV glue to be cementing agent, its operating method is as follows: the desire cemented surface in main body of articles applies UV glue, the surface with figure ornament with the quartzy matrix of complete pattern transferring is placed in this cemented surface again, by UV light source irradiation appropriate time, make this finish combination in conjunction with glue-line solidifies typing fully.
When the quartzy matrix behind this pattern transferring and another main body of articles gummed, between the light period, cemented surface is produced improperly and change if any slight sliding phenomenon, and the flaw on the formation product pattern.
The employed UV glue of this step is to be the higher UV glue of a kind of viscosity, uses stronger the consolidating of acquisition and closes effect and be enough to fill up small gap between cemented surface, and avoid producing internal stress between cementing layer, causes the dendroid slight crack.
Learn according to test at present,, meet the requirement of this step most with German DELO company's numbering 4473 or U.S. DYMAX company numbering 424, the above UV glue of about 1000 (CPS) of viscosity (23 ℃ in Brookfield viscometer).
In sum as can be known, the present invention is that the figure ornament that will be printed in fully on the pattern substrate is transplanted totally in the middle of the interlayer of crystal base surface or composition product, the pattern of this formation has the characteristic of sky, that is light can penetrate pattern image and reach semi-transparent effect of looking.So, the pattern of product can change because of the figure viewed from behind light and shade at putting position place different viewpoints, and in the middle of this product is moving, can make the reflection change of reflection of the mystery of figure ornament because of the variation of background, this kind uniqueness makes it compare distinct visual experience with product at the same level on the market.
Another characteristic of the present invention is that the pattern that forms can represent the effect with stereoscopic vision, especially when selecting the planoconvex quartz plate as the quartzy matrix of pattern transferring, produced finished product visually has more the spatial image effect, the arc screen of somewhat similar televisor, the colour picture effect that is represented during still frame is the same.
A characteristic more of the present invention is as selecting the planoconvex quartz plate of two same specifications, the pattern sandwich of produced composition product, figure ornament image definition when the front is seen, figure ornament image theme was also identical when the back side was seen, sharpness is also just the same, just exchanges mutually about the vision order, often make us stunned after a time-division do not go out the side for positive, and the side is a reverse side, and this uniqueness is never to have for present product at the same level on the market.
Another characteristic of the present invention be whole processing and manufacturing program one gas drink, fast simple, and can independentization (product at the same level must send outside relevant dealer's processing as: wire mark, sandblast, ultrasound piercing etc. comes and goes time-consuming, and transport in the way and the clashing and breaking consumption during the processing, this is all indirectly attributable expense).Thereby can save production cost in large quantities, and the also suitable a small amount of various Production Flow Chart of its not only suitable mass production, therefore have high commercial competition ability, more further masses are generally consumed in Jiahui.
In addition, it is to be the extremely easy operator scheme of a cover that the present invention has demonstrated its manufacturing operation flow process, even complete unfamiliar operating personnel, in very short time, after suitable explanation and actual rehearsal skill, can put into production at once, and at most only carry out the irradiation time of twice UV when producing, and all within one minute, can finish at every turn, so production rate is fast, the mass production of can standardizing.
The above is about technical conceive of the present invention, enumerates three embodiment below, and the feature of manufacture method of the present invention and finished product is done more detailed explanation:
In embodiments of the present invention, at first get be printed in have " Kun Ding seashore " on the P.P paper, " pheasant " reach the pattern substrate each (shown in annex one) of " silk tree illawarra mountain pine snow building " multi color pattern, forms required gold stamping part in addition on these patterns; And these pattern areas that print on P.P paper are: " Kun Ding seashore " is the figure of diameter more than 2.5 centimeters, and " pheasant " is the figure of diameter more than 3.5 centimeters, and " silk tree illawarra mountain pine snow building " is the figure of diameter more than 7 centimeters.The A example is provided with pure natural crystal necklace, the retainer of " Kun Ding seashore " pattern:
Two of the pure natural quartz plates of preparation water white transparency plano-convex shape, specification is identical to be 2.5 centimeters of diameters, thickness is all 0.6 centimeter, get wherein a slice natural water wafer, smear the thin UV glue of one deck (US-built DYMAX numbering 401 in the smooth flat place of quartz plate, color~water white transparency after the curing, viscosity is 50~150 (CPS) (23 ℃ in Brookfield viscometers), be positioned over P.P paper then and be printed on the picture of " Kun Ding seashore ", use the UV light source to provide intensity 350~400mw/cm 2The UV light source, and the vertical range of maintenance UV light source and P.P paper is 4 centimeters (shown in annexes two), shine and remove the UV light source after 12 ± 1 seconds, slowly dial from P.P paper, then " Kun Ding seashore " multi color pattern and gold stamping part are transplanted on the solidifying and setting UV glue film that is embedded on the quartzy plane fully, and the complete quartzy plane (shown in annex three) that is pasted on of this UV glue film.Smear UV glue (German DELO company numbering 4473 again, solidify back~water white transparency, viscosity is about 8000 (CPS) (23 ℃ in Brookfield viscometer) on the quartz plate of another sheet same size, the quartzy storing of two pure naturals glued together together, get the UV light source of above-mentioned use, make about 5.5 centimeters of the vertical range (shown in annex four) of UV light source and two gummed quartz plate belows, irradiation time is removed the UV light source after 15 ± 1 seconds, so promptly finish the work flow of present embodiment; Can tumble in nickel plating or gold-plated metal edges in the finished figure periphery afterwards, add that necklace then becomes natural crystal necklace, as change into and add that retainer then becomes mineral crystal retainer (shown in annex five).B example, pattern are the quartzy Wen Zhen of " pheasant ":
Prepare a colourless natural reuse water wafer that is the plano-convex shape, specification is 0.8 centimeter of 3.5 centimeters thickness of diameter, preparing in addition to ponder leaded synthetic quartzy one that finishes via cutting, is smooth flat about 3.8 centimeters at tool one diameter on the volume of its geometric form; On the smooth flat of natural water wafer, smear UV glue (the German DELO company numbering 4303 of thin layer, color~water white transparency after the curing, viscosity is about 50~150 (CPS) (23 ℃ in Brookfield viscometer), be placed in then on the picture that is printed on " pheasant " on the P.P paper, and use the UV light source of A example to operate identical flow process, just irradiation time wherein is modified to 18 ± 1.5 seconds; Vertical irradiation distance with synthetic quartzy gummed changes 10.5 centimeters into then, and irradiation time changes 22 ± 2 seconds into, promptly finishes the processing work flow of present embodiment; Add packing then is the quartzy literary composition town finished product (shown in annex six) with pattern of " pheasant " (font is gold stamping) afterwards.The C example, have the opticglass ornaments of " silk tree illawarra mountain pine snow building " figure line:
Preparing two of the colouless optical glasses of same size, is that plano-convex shape, diameter are that 7 centimeters, thickness are 0.9 centimeter; The process of its transfer printing on P.P paper " silk tree illawarra mountain pine snow building " pattern and to glue together process mutually identical with the A example, but change employing intensity 1000mw/cm into 2The UV light source, the UV glue that pattern transferring and two optical mirror slips gummed use is all U.S. DYMAX company numbering 401, and the vertical range of UV light source and P.P paper is 10 centimeters, irradiation time 24 ± 2 seconds during its pattern transferring, and the below vertical range of UV light source and optical glass sheet is 11 centimeters, irradiation time 30 ± 2.5 seconds during two combinations.It forms product can engrave the tin limit in the circumference coating, places tin system to engrave pedestal, promptly becomes opticglass ornaments (shown in annex seven), and pattern is gold stamping for " silk tree illawarra mountain pine snow building " has font.
Clearly; the present invention can just can realize the above technical conceive that discloses by the method for some ordinary skills; therefore after poring over above-mentioned patent description; all can use wherein each technical conceive to be spread out to stretch and cause various change kenel; or replace with equivalent and to reach identical technical conceive and special efficacy; therefore; all have any modification relevant of the present invention or a change of being done under identical creation spirit, all must be included in the category that the invention is intended to protect.
Annex one is the reference photo of the style of the used pattern substrate of the present invention;
Annex two is the present invention gets the graphic operation stage in transfer printing reference photos;
To be the present invention get that graphic operation is finished and reference photo that UV glue film is peeled off from P.P paper in transfer printing with annex three;
Annex four is quartzy matrix and reference photos of the operational phase that another quartz plate interlayer glues together that surface of the present invention has pattern;
Annex five is reference photos of the finished product of A embodiment of the present invention;
Annex six is reference photos of the finished product of B embodiment of the present invention;
Annex seven is reference photos of the finished product of C embodiment of the present invention.

Claims (5)

1、一种于水晶或光学玻璃的表面形成图案的方法,是在被加工物表面形成具透明状的薄层装饰图案,其特征在于包含:1. A method for forming a pattern on the surface of crystal or optical glass, which is to form a transparent thin-layer decorative pattern on the surface of the processed object, which is characterized in that it comprises: 以印刷技术将图案印制在多元酯合成纸上并待其完全风干之后而使用的图样基板;A pattern substrate that is used to print patterns on polyester synthetic paper by printing technology and wait until it is completely air-dried; 取具有适合形成图案的加工表面的透光材料基体;Taking a light-transmitting material substrate with a processed surface suitable for forming a pattern; 将图样基板的图案面与透光材料基体的加工表面二者相互叠合,并于该叠合面之间均匀涂布一层厚度约在0.01~0.03mm之间、粘稠度约在50~150(CPS)(Brookfield粘度计23℃)左右的紫外光线胶作为图案转印的介质层;Lay the pattern surface of the pattern substrate and the processed surface of the light-transmitting material substrate together, and evenly coat a layer between the superimposed surfaces with a thickness of about 0.01-0.03mm and a viscosity of about 50- About 150 (CPS) (Brookfield viscometer 23°C) ultraviolet light glue is used as the medium layer for pattern transfer; 以紫外线光源对该层涂布的介质层实施例适度的照射时间,使其干固定型;The moderate irradiation time of the medium layer embodiment coated with ultraviolet light source is used to make it dry and fixed; 再将图案基板自透光材料基体的加工表面剥离,使该具有图案的介质层稳固地停留在该透光材料基体的加工表面。Then the patterned substrate is peeled off from the processed surface of the light-transmitting material base, so that the patterned medium layer stays firmly on the processed surface of the light-transmitting material base. 2、如权利要求1所述的于水晶或光学玻璃的表面形成图案的方法,其特征在于:该介质层受紫外线光源的适度照射时间是因选用的紫外光线胶种类、涂布胶层厚薄度或水晶基体的材质的透光率以及光源照度的强弱不同,而时程长短有别,但一般在五秒钟以上、六十秒钟以下。2. The method for forming patterns on the surface of crystal or optical glass as claimed in claim 1, characterized in that: the moderate irradiation time of the medium layer by the ultraviolet light source is due to the type of ultraviolet light glue selected and the thickness of the coating glue layer. Or the light transmittance of the material of the crystal substrate and the strength of the light source are different, and the length of the time course is different, but generally it is more than five seconds and less than sixty seconds. 3、一种于水晶或光学玻璃的胶合夹层间形成透光性图案的方法,其特征在于包含:3. A method for forming a translucent pattern between glued interlayers of crystal or optical glass, characterized in that it comprises: 以印刷技术将图案印制在多元酯合成纸上并待其完全风干之后而使用的图样基板;A pattern substrate that is used to print patterns on polyester synthetic paper by printing technology and wait until it is completely air-dried; 取具有适合形成图案的加工表面的透光材料基体;Taking a light-transmitting material substrate with a processed surface suitable for forming a pattern; 将图样基板的图案面与透光材料基体的加工表面二者相互叠合,并于该叠合面之间均匀涂布一层厚度约在0.01~0.03mm之间、粘稠度约在50~150(CPS)(Brookfield粘度计23℃)左右的紫外光线胶作为图案转印的介质层;Lay the pattern surface of the pattern substrate and the processed surface of the light-transmitting material substrate together, and evenly coat a layer between the superimposed surfaces with a thickness of about 0.01-0.03mm and a viscosity of about 50- About 150 (CPS) (Brookfield viscometer 23°C) ultraviolet light glue is used as the medium layer for pattern transfer; 以紫外线光源对该层涂布的介质层实施适度的照射时间,使其干固定型;Apply a moderate irradiation time to the medium layer coated with an ultraviolet light source to make it dry and fixed; 将图样基板自透光材料基体的加工表面剥离,使该具有图案的介质层稳固地停留在该透光材料基体的加工表面;peeling off the patterned substrate from the processed surface of the light-transmitting material substrate, so that the patterned dielectric layer stays firmly on the processed surface of the light-transmitting material substrate; 取一具有一个平整的加工表面并与上述透光材料基体的加工表面对称的欲胶合体;Take a body to be bonded which has a flat processed surface and is symmetrical to the processed surface of the above-mentioned light-transmitting material matrix; 将该透光材料基体的加工表面与所述的欲胶合体的加工表面二者相互叠合,并于该叠合面之间均匀涂布一层稀薄且粘稠度约在1000(CPS)(Brookfield粘度计23℃)以上的紫外光线胶作为胶合层;The processed surface of the light-transmitting material substrate and the processed surface of the body to be glued are superimposed on each other, and a thin layer with a viscosity of about 1000 (CPS) is evenly coated between the superimposed surfaces. Brookfield viscometer (23°C) above ultraviolet light glue as the glue layer; 以紫外线光源对该胶合层实施适度的照射时间使其固着,从而于该胶合层呈现具有透空性特色图案的成品。The adhesive layer is irradiated with an ultraviolet light source for a moderate time to fix it, so that the finished product with a characteristic pattern of air permeability is presented on the adhesive layer. 4、如权利要求3所述的于水晶或光学玻璃的胶合夹层间形成透光性图案的方法,其特征在于:所述的欲胶合体是为如水晶、光学玻璃等的可透光性材料。4. The method for forming a light-transmitting pattern between glued interlayers of crystal or optical glass as claimed in claim 3, characterized in that: said body to be glued is a light-transmitting material such as crystal or optical glass . 5、如权利要求3所述的于水晶或光学玻璃的胶合夹层间形成透光性图案的方法,其特征在于:所述的欲胶合体是为金属的如银、铜、合金等及非金属的如玉石、陶瓷等非透光性材料。5. The method for forming light-transmitting patterns between the glued interlayers of crystal or optical glass as claimed in claim 3, characterized in that: said objects to be glued are metals such as silver, copper, alloys, etc. and non-metallic Non-translucent materials such as jade and ceramics.
CN 96106437 1996-08-13 1996-08-13 Method for forming pattern on surface of crystal or optical glass Pending CN1173471A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102152698A (en) * 2011-05-16 2011-08-17 王春林 Crystal glass pen container
CN102259542A (en) * 2011-05-18 2011-11-30 王春林 Crystal glass pen case
CN102771970A (en) * 2012-08-09 2012-11-14 邓民 Titanium decorating process on precious stone
CN103496282A (en) * 2013-10-22 2014-01-08 丁小彬 Technology for manufacturing jade digital image and video product
CN104844015A (en) * 2015-04-27 2015-08-19 欧阳宣 Manufacturing process for glass with micro-nano structure
CN105034669A (en) * 2015-07-27 2015-11-11 东莞市昆顺树脂制品有限公司 Glass transfer process
CN109263263A (en) * 2018-10-19 2019-01-25 兴科电子(东莞)有限公司 A kind of technique forming stone pattern effect on film
CN114851761A (en) * 2022-06-02 2022-08-05 四川南谷文化传播有限公司 A kind of method utilizing polymethyl methacrylate to prepare spar image

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102152698A (en) * 2011-05-16 2011-08-17 王春林 Crystal glass pen container
CN102259542A (en) * 2011-05-18 2011-11-30 王春林 Crystal glass pen case
CN102259542B (en) * 2011-05-18 2015-05-13 王春林 Crystal glass pen case
CN102771970A (en) * 2012-08-09 2012-11-14 邓民 Titanium decorating process on precious stone
CN103496282A (en) * 2013-10-22 2014-01-08 丁小彬 Technology for manufacturing jade digital image and video product
CN104844015A (en) * 2015-04-27 2015-08-19 欧阳宣 Manufacturing process for glass with micro-nano structure
CN105034669A (en) * 2015-07-27 2015-11-11 东莞市昆顺树脂制品有限公司 Glass transfer process
CN109263263A (en) * 2018-10-19 2019-01-25 兴科电子(东莞)有限公司 A kind of technique forming stone pattern effect on film
CN114851761A (en) * 2022-06-02 2022-08-05 四川南谷文化传播有限公司 A kind of method utilizing polymethyl methacrylate to prepare spar image

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