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CN1173166C - Method and device for measuring double-sided metal waveguide - Google Patents

Method and device for measuring double-sided metal waveguide Download PDF

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CN1173166C
CN1173166C CNB02136611XA CN02136611A CN1173166C CN 1173166 C CN1173166 C CN 1173166C CN B02136611X A CNB02136611X A CN B02136611XA CN 02136611 A CN02136611 A CN 02136611A CN 1173166 C CN1173166 C CN 1173166C
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metal film
thickness
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waveguide
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CN1396445A (en
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曹庄琪
陈洸
沈启舜
李红根
周峰
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Shanghai Jiao Tong University
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Abstract

双面金属波导测量方法及其装置属于物理测量领域。装置由上至下由耦合器件、上层金属膜、待测薄膜层、下层金属膜构成,待测薄膜层和上下层金属膜为双面金属波导结构,上下层金属膜为波导的上下覆盖层,光主要在待测薄膜层中传输。方法如下:在待测薄膜的两面采用蒸镀、溅射或其它方法形成本发明装置;选择激光波长和入射角度及偏振方式;接收并记录从耦合器件底面反射的激光束光强,或从下层金属膜透射出的激光束光强;变化激光入射角度得到光强—入射角度曲线,找出导模吸收峰的共振角度和相应吸收峰的宽度和深度,计算得到薄膜材料的折射率和厚度值。本发明实现了高精确度、大量程、快速实时的测量,装置制造工艺简单、价格低廉、易于操作、小型化。

Figure 02136611

A double-sided metal waveguide measurement method and a device thereof belong to the field of physical measurement. The device is composed of a coupling device, an upper metal film, a thin film layer to be tested, and a lower metal film from top to bottom. The thin film layer to be tested and the upper and lower metal films are double-sided metal waveguide structures, and the upper and lower metal films are the upper and lower covering layers of the waveguide. Light is mainly transmitted in the film layer to be tested. The method is as follows: use vapor deposition, sputtering or other methods to form the device of the present invention on both sides of the film to be tested; select the laser wavelength, incident angle and polarization mode; receive and record the light intensity of the laser beam reflected from the bottom surface of the coupling device, or from the lower layer The light intensity of the laser beam transmitted by the metal film; change the laser incident angle to obtain the light intensity-incident angle curve, find out the resonance angle of the guided mode absorption peak and the width and depth of the corresponding absorption peak, and calculate the refractive index and thickness of the film material . The invention realizes high-precision, large-range, fast and real-time measurement, and the device has simple manufacturing process, low price, easy operation and miniaturization.

Figure 02136611

Description

双面金属波导测量方法及其装置Method and device for measuring double-sided metal waveguide

技术领域technical field

本发明涉及的是一种测量方法及其装置,特别是一种双面金属波导测量方法及其装置,属于物理测量领域。The invention relates to a measuring method and its device, in particular to a double-sided metal waveguide measuring method and its device, belonging to the field of physical measurement.

背景技术Background technique

近二十年来,随着激光技术特别是集成光电子学技术的发展,材料光学特性和厚度的测量以及光波导表征技术的研究和应用取得了长足的进步。其中,双波长法已经进入实用,对它的报道也较多。经文献检索发现,美国专利号为5034617,专利名称为:测量薄膜厚度和折射率的方法及装置,该专利提出了一种测量光学薄膜厚度的方法,该方法中,先选用某一波长λ1的激光光束入射到镀了光学薄膜的衬底材料上,然后观察反射光强,测量并记录反射光强极小点的入射角度,θ1和θ2,然后更换入射激光的波长λ2,再测得一个反射光强极小的角度θ3,然后把这五个数据代入公式即可计算得到待测薄膜的厚度和折射率。该方法能对薄膜的厚度以及折射率等光学特性进行测量,但由于在这种结构中,通过调整入射激光的光波长来得到第三个角度值,不可避免的带来了一定的色散,从而严重影响了测量结果的精度。另外报道较多的是一种棱镜耦合测量结构。激光通过耦合棱镜入射到镀了光学薄膜的衬底材料上,然后观察反射光强,测量并记录反射光强极小点的入射角度,θ1和θ2,然后更换耦合棱镜,再测得一个反射光强极小的角度θ3,然后把这五个数据代入公式即可计算得到待测薄膜的厚度和折射率。这种方法的好处是避免了双波长法带来的色散,但是,棱镜与待测薄膜之间的距离难以准确调节,而这又将对耦合效率产生极大的影响,导致两次耦合的效率不同,从而影响测量结果的精度。而且,为了能将光从棱镜中耦合到薄膜材料中,该方法要求待测材料的折射率要小于其耦合棱镜的折射率,极大的限制了该方法适用的测量范围。In the past two decades, with the development of laser technology, especially the development of integrated optoelectronics technology, the measurement of optical properties and thickness of materials and the research and application of optical waveguide characterization technology have made great progress. Among them, the dual-wavelength method has been put into practice, and there are many reports on it. After literature search, it is found that the U.S. Patent No. 5034617, the patent name is: method and device for measuring film thickness and refractive index. This patent proposes a method for measuring optical film thickness. In this method, a certain wavelength λ 1 is first selected. The laser beam is incident on the substrate material coated with optical film, then observe the reflected light intensity, measure and record the incident angles of the minimum point of reflected light intensity, θ 1 and θ 2 , then change the wavelength λ 2 of the incident laser light, and then Measure an angle θ 3 where the reflected light intensity is extremely small, and then substitute these five data into the formula to calculate the thickness and refractive index of the film to be tested. This method can measure the optical properties such as the thickness and refractive index of the film, but in this structure, the third angle value is obtained by adjusting the light wavelength of the incident laser, which inevitably brings a certain amount of dispersion, thus Seriously affect the accuracy of the measurement results. Another reported more is a prism coupling measurement structure. The laser is incident on the substrate material coated with optical film through the coupling prism, then observe the reflected light intensity, measure and record the incident angle of the minimum point of reflected light intensity, θ 1 and θ 2 , then replace the coupling prism, and measure a The angle θ 3 at which the reflected light intensity is extremely small, and then these five data are substituted into the formula to calculate the thickness and refractive index of the film to be tested. The advantage of this method is that it avoids the dispersion caused by the dual-wavelength method. However, the distance between the prism and the film to be measured is difficult to adjust accurately, which in turn will have a great impact on the coupling efficiency, resulting in the efficiency of the two couplings. different, thus affecting the accuracy of the measurement results. Moreover, in order to couple the light from the prism to the thin film material, this method requires that the refractive index of the material to be measured should be smaller than that of the coupling prism, which greatly limits the applicable measurement range of this method.

发明内容Contents of the invention

本发明针对现有技术的不足和缺陷,提供一种双面金属波导测量方法及其装置,使其适用于各种波长的激光,测量仪器小型化,操作简单,制造工艺简单、价格低廉,能对光学材料(包括薄膜以及体材料)的厚度和折射率、双折射系数、各向异性等以及光波导的传输损耗和导模模序数等参数进行精确测量和表征,薄膜材料的厚度从微米量级到毫米量级都能够实现精确的测量,并可在没有耦合器件的情况下实现直接耦合。Aiming at the deficiencies and defects of the prior art, the present invention provides a double-sided metal waveguide measurement method and its device, which are applicable to lasers of various wavelengths, the measuring instrument is miniaturized, the operation is simple, the manufacturing process is simple, and the price is low. Accurately measure and characterize the thickness, refractive index, birefringence coefficient, anisotropy, etc. of optical materials (including thin films and bulk materials), as well as the transmission loss of optical waveguides and the number of guided mode modes. The thickness of thin film materials is measured from microns Accurate measurements can be achieved from the level of 1 to 1000 mm, and direct coupling can be achieved without coupling devices.

本发明的技术方案是这样实现的,本发明装置由上至下由耦合器件、上层金属膜、待测薄膜层、下层金属膜构成,上层金属膜、待测薄膜层和下层金属膜为双面金属波导结构,上下层金属膜为波导的上下覆盖层,光主要在待测薄膜层中传输。The technical scheme of the present invention is realized in this way, the device of the present invention is made up of coupling device, upper layer metal film, test film layer, lower layer metal film from top to bottom, upper layer metal film, test film layer and lower layer metal film are double-sided The metal waveguide structure, the upper and lower metal films are the upper and lower covering layers of the waveguide, and the light is mainly transmitted in the thin film layer to be tested.

耦合器件采用高折射率棱镜(n>1.5)、光栅和耦合波导等器件,或不用耦合器件,进行空气直接耦合,棱镜的形状可根据实际需要选择等边、或等腰、或柱面、或球面或其它常见或特殊形状。The coupling device adopts high refractive index prism (n>1.5), grating, coupling waveguide and other devices, or directly couples air without coupling device. The shape of the prism can be equilateral, or isosceles, or cylindrical, or Spherical or other common or special shapes.

上层金属膜和下层金属膜一般可选用对工作波长吸收较小的金属,金属介电常数ε=εr+iεi与工作波长有关,且该层金属膜的厚度应严格控制使入射光与导波的耦合最为有效。上层金属膜的厚度在20nm-80nm之间。下层金属膜的厚度可根据测量方式确定,采用反射光测量方式时,应大于100nm;而采用透射光测量方式时,一般应小于30nm。金属种类可选择银、金、铝、铜等在光频范围内介电常数虚部较小的金属,一般要求其介电常数实部εr≤-10,介电常数虚部εi≤5.0。The upper metal film and the lower metal film can generally be selected from metals that absorb less at the working wavelength. The metal dielectric constant ε=ε r +iε i is related to the working wavelength, and the thickness of the metal film should be strictly controlled so that the incident light and the guide Coupling of waves is most effective. The thickness of the upper metal film is between 20nm-80nm. The thickness of the lower metal film can be determined according to the measurement method. When the reflected light measurement method is used, it should be greater than 100nm; when the transmitted light measurement method is used, it should generally be less than 30nm. The metal type can choose silver, gold, aluminum, copper and other metals with small imaginary part of dielectric constant in the optical frequency range. Generally, the real part of the dielectric constant ε r ≤ -10, and the imaginary part of the dielectric constant ε i ≤ 5.0 .

待测薄膜层的厚度在0.5μm-1000μm之间,厚度必须确保能承载三个以上的导波共振模式,其折射率在1.0-2.3之间,待测薄膜层处于波导结构的传输层,导波光就在待测薄膜层里传输,因此,待测薄膜的折射率等性质将最直接的影响导波光的传输性质,有效的提高了测量效率和精度。The thickness of the film layer to be tested is between 0.5 μm and 1000 μm. The thickness must ensure that it can carry more than three guided wave resonance modes, and its refractive index is between 1.0 and 2.3. The film layer to be tested is in the transmission layer of the waveguide structure. The wave light is transmitted in the film layer to be tested. Therefore, the refractive index and other properties of the film to be tested will most directly affect the transmission properties of the guided wave light, which effectively improves the measurement efficiency and accuracy.

本发明方法基于上述测量装置,用一种全新的思路实现了薄膜的折射率等光学特性和厚度的精确测量,并能对波导材料的各项参数进行表征,具体步骤如下:Based on the above-mentioned measuring device, the method of the present invention realizes the precise measurement of the optical properties and thickness of the film such as the refractive index with a brand-new idea, and can characterize various parameters of the waveguide material. The specific steps are as follows:

第一步:在待测薄膜的两面采用蒸镀、溅射或其他方法形成本发明装置双面金属波导结构,其结构为“耦合器件-上层金属膜-待测薄膜层-下层金属膜”的四层结构;Step 1: Form the double-sided metal waveguide structure of the device of the present invention by evaporation, sputtering or other methods on both sides of the film to be tested, and its structure is "coupling device-upper metal film-test film layer-lower metal film" four-tier structure;

第二步:选择合适的激光波长和入射角度以及偏振方式,选用激光作为光源,工作波长可在可见和红外光频范围内选择,从激光器输出的激光束入射到耦合器件上,要求入射角度在0到90度间变化时能激发多个共振吸收峰,偏振方式可根据测量要求选定,既可以选择横磁波(TM模),也可选择横电波(TE模);The second step: choose the appropriate laser wavelength, incident angle and polarization mode, choose the laser as the light source, the working wavelength can be selected in the visible and infrared frequency range, the laser beam output from the laser is incident on the coupling device, the incident angle is required Multiple resonant absorption peaks can be excited when changing from 0 to 90 degrees, and the polarization mode can be selected according to the measurement requirements, either transverse magnetic wave (TM mode) or transverse electric wave (TE mode);

第三步:在耦合器件的另一侧利用光强测量装置接收并记录从耦合器件底面反射的激光束光强,或从底面方向接收并记录从下层金属膜透射出的激光束光强;Step 3: Use a light intensity measuring device on the other side of the coupling device to receive and record the light intensity of the laser beam reflected from the bottom surface of the coupling device, or receive and record the light intensity of the laser beam transmitted from the lower metal film from the direction of the bottom surface;

第四步:在0到90度范围内连续变化激光入射角度,并同期记录其反射(透射)光强,形成反射(透射)光强—入射角度曲线,在曲线上找出导模吸收峰的共振角度和相应的吸收峰宽度和深度,然后,根据双面金属波导的特征公式,可以通过计算得到薄膜材料的折射率和厚度的精确值。Step 4: Continuously change the incident angle of the laser in the range of 0 to 90 degrees, and record the reflected (transmitted) light intensity at the same time to form a reflected (transmitted) light intensity-incident angle curve, and find out the value of the guided mode absorption peak on the curve The resonance angle and the corresponding absorption peak width and depth, then, according to the characteristic formula of the double-sided metal waveguide, can be calculated to obtain the precise values of the refractive index and thickness of the thin film material.

以下对本发明方法作进一步描述:The inventive method is further described below:

①利用双面金属波导的ATR(衰减全反射)导模吸收峰对于波导介质的折射率等光学特性非常敏感且有一一对应的特性,和反射(透射)光强随激光入射角度变化的曲线,将薄膜厚度和折射率等光学特性的测量以及波导参数的表征,转化为对反射光强随入射角度变化曲线的测量;①Using the ATR (attenuated total reflection) guided mode absorption peak of the double-sided metal waveguide is very sensitive to the optical properties such as the refractive index of the waveguide medium and has a one-to-one correspondence, and the curve of the reflection (transmission) light intensity changing with the laser incident angle , transforming the measurement of optical properties such as film thickness and refractive index and the characterization of waveguide parameters into the measurement of the curve of reflected light intensity versus incident angle;

②利用双面金属波导的ATR导模吸收峰对于波导介质的折射率等光学特性非常敏感且一一对应的特性,选择ATR导模区作为工作区;② Using the ATR guided mode absorption peak of the double-sided metal waveguide is very sensitive to the optical properties such as the refractive index of the waveguide medium and has one-to-one correspondence, the ATR guided mode area is selected as the working area;

③工作点即入射角度选择在ATR吸收峰高阶模区、低阶模区和表面模区,包括在一个器件中使用多个工作点同时工作及使用透射光进行测量的情况;③ The working point, that is, the incident angle is selected in the high-order mode area, low-order mode area and surface mode area of the ATR absorption peak, including the case of using multiple operating points in one device to work simultaneously and using transmitted light for measurement;

④利用双面金属波导TE和TM模分离的特点,在对光偏振敏感的薄膜进行测量时,只用横电(TE)或横磁(TM)模光信号作为入射光,并用另一模式的光作为参考光,可以实现双光束计测,通过光信号的比对,有效的消除光源带来的噪音;④Using the characteristics of double-sided metal waveguide TE and TM mode separation, when measuring thin films sensitive to light polarization, only the transverse electric (TE) or transverse magnetic (TM) mode optical signal is used as the incident light, and the other mode Light is used as a reference light, which can realize double-beam measurement, and through the comparison of optical signals, the noise caused by the light source can be effectively eliminated;

⑤利用双面金属波导能承载多个模式的特点(通常三个以上),可以同时对待测薄膜的厚度进行测量,从而提高测量精度和实用性。⑤Using the characteristic that the double-sided metal waveguide can carry multiple modes (usually more than three), the thickness of the film to be tested can be measured at the same time, thereby improving the measurement accuracy and practicability.

在本发明方法中,双面金属波导中ATR导模吸收峰的角度、深度和宽度等特征随薄膜的折射率、厚度等特性变化非常敏感且一一对应,利用这些参数结合波导特性公式对薄膜的折射率和厚度进行精确的测量,其实质是将薄膜的折射率和厚度等特性转化为与之一一对应的双面金属波导的导模吸收峰的各项参数,从而实现对薄膜折射率和厚度的精确测量。In the method of the present invention, the characteristics such as the angle, depth and width of the ATR guided mode absorption peak in the double-sided metal waveguide are very sensitive and one-to-one corresponding to the characteristics such as the refractive index and thickness of the film. The precise measurement of the refractive index and thickness of the film is essentially to convert the characteristics of the film’s refractive index and thickness into the parameters of the guided mode absorption peak of the double-sided metal waveguide corresponding to each other, so as to realize the measurement of the film’s refractive index. and accurate measurement of thickness.

本发明同现有的通过棱镜耦合对薄膜的光学特性和厚度进行测量的技术相比,具有以下优点:Compared with the existing technology of measuring the optical properties and thickness of the film through prism coupling, the present invention has the following advantages:

测量量程大,精度高。利用本方法,对薄膜材料的折射率的测量在极限条件下可以达到0.5%左右,在正常工作条件下可以达到0.2%或更高,对薄膜厚度的测量精度在极限条件下可以达到0.3%左右,正常工作区可以达到0.1%或更高。相比通常的棱镜耦合测量技术而言,其厚度的测量量程可以扩展到从0.5个微米到1个毫米的量级。折射率的测量如果采用空气耦合的方式也突破了以往的要求薄膜材料的折射率要低于耦合棱镜折射率的限制。Large measuring range and high precision. Using this method, the measurement of the refractive index of the film material can reach about 0.5% under the limit condition, and can reach 0.2% or higher under the normal working condition, and the measurement accuracy of the film thickness can reach about 0.3% under the limit condition , the normal working area can reach 0.1% or higher. Compared with the usual prism coupling measurement technology, the measurement range of its thickness can be extended to the order of magnitude from 0.5 micron to 1 mm. If the measurement of the refractive index adopts the air coupling method, it also breaks through the previous limitation that the refractive index of the thin film material should be lower than that of the coupling prism.

方法简单,测量效率高。对薄膜的折射率和厚度的测量一次完成,无需更多步骤。The method is simple and the measurement efficiency is high. The measurement of the refractive index and thickness of the film is done in one pass, no further steps are required.

制备简单、成本低廉。利用双面金属波导的特性,可以省略耦合器件,采用空气直接耦合的方式进行测量,减少了测量部件,降低了测量成本。The preparation is simple and the cost is low. Utilizing the characteristics of the double-sided metal waveguide, the coupling device can be omitted, and the air direct coupling method can be used for measurement, which reduces the measurement components and reduces the measurement cost.

制成的仪器具有小型化、易于携带等特点。按照本项技术制成的器件,体积很小,方便携带、安装,对测量环境的要求不高。The manufactured instrument has the characteristics of miniaturization and easy portability. The devices made according to this technology are small in size, easy to carry and install, and have low requirements on the measurement environment.

适用范围广。在通常的测量方法中,需要对待测薄膜的性质做出诸多限制,妨碍了测量方法的广泛应用。而在本项技术中,对薄膜的折射率、厚度都没有提出很多的要求,故而能够在一个更为广泛的领域中得到应用。Wide range of applications. In the usual measurement methods, many restrictions need to be made on the properties of the film to be measured, which hinders the wide application of the measurement method. However, in this technology, there are not many requirements on the refractive index and thickness of the film, so it can be applied in a wider field.

测量周期短,可以实现实时监测。本薄膜厚度和折射率及其它光学性质测量方法的反应时间主要取决于光强探测器的响应时间,因而能实现快速甚至实时测量。The measurement cycle is short and real-time monitoring can be realized. The response time of the film thickness and refractive index and other optical property measurement methods mainly depends on the response time of the light intensity detector, so fast and even real-time measurement can be realized.

可以对光偏振敏感的薄膜利用偏振光进行测量。在对光偏振敏感的薄膜进行测量时,可只用横电波(TE模)或横磁波(TM模)光信号作为入射光,并用另一模式的光作为参考光,可以实现双光束计测,通过光信号的比对,有效的消除光源带来的噪音。Films that are sensitive to light polarization can be measured with polarized light. When measuring a thin film sensitive to light polarization, only the transverse electric wave (TE mode) or transverse magnetic wave (TM mode) optical signal can be used as the incident light, and the light of the other mode can be used as the reference light to realize the double-beam measurement. Through the comparison of optical signals, the noise caused by the light source can be effectively eliminated.

本发明具有实质性特点和显著进步,本发明方法可以广泛应用于多种薄膜的光学特性和厚度的测量、光波导参数的表征等等方面,尤其是可以同时对薄膜折射率和厚度这两组参量进行测量,利用此项技术,可以实现高精确度、大量程、快速实时的测量,同时保证仪器具有制造工艺简单、价格低廉、易于操作、小型化、便于携带等高技术性能。The present invention has substantive features and significant progress. The method of the present invention can be widely used in the measurement of optical properties and thickness of various films, the characterization of optical waveguide parameters, etc., especially the two groups of film refractive index and thickness can be simultaneously analyzed. Using this technology, high-precision, large-range, fast and real-time measurement can be achieved, while ensuring that the instrument has high-tech performances such as simple manufacturing process, low price, easy operation, miniaturization, and portability.

附图说明Description of drawings

图1本发明结构示意图Fig. 1 structural representation of the present invention

具体实施方式Detailed ways

如图1所示,本发明装置由上至下由耦合器件1、上层金属膜2、待测薄膜层3、下层金属膜4构成,上层金属膜2、待测薄膜层3和下层金属膜4为双面金属波导结构,上层金属膜2、下层金属膜4为波导的上下覆盖层,光主要在待测薄膜层3中传输。As shown in Figure 1, the device of the present invention consists of a coupling device 1, an upper metal film 2, a thin film layer 3 to be tested, and a lower metal film 4 from top to bottom. It is a double-sided metal waveguide structure, the upper metal film 2 and the lower metal film 4 are the upper and lower covering layers of the waveguide, and the light is mainly transmitted in the thin film layer 3 to be tested.

耦合器件1可采用高折射率棱镜(n>1.5)、光栅和耦合波导等器件,或进行空气直接耦合。在待测薄膜的两面采用蒸镀、溅射或其他方法形成双面金属波导结构,上层金属膜2和下层金属膜4选用对工作波长吸收较小的金属,金属介电常数ε=εr+iεi与工作波长有关,且该金属膜的厚度应严格控制使入射光与导波的耦合最为有效。上层金属膜的厚度在20nm-80nm之间。下层金属膜的厚度根据测量方式确定,采用反射光测量方式时,应大于100nm;而采用透射光测量方式时,一般应小于30nm。金属种类为银、金、铝、铜等在光频范围内介电常数虚部较小的金属,其介电常数实部εr≤-10,介电常数虚部εi≤5.0。The coupling device 1 can use high refractive index prisms (n>1.5), gratings, coupling waveguides and other devices, or direct air coupling. A double-sided metal waveguide structure is formed on both sides of the film to be tested by evaporation, sputtering or other methods. The upper metal film 2 and the lower metal film 4 are selected from metals that absorb less at the working wavelength. The metal dielectric constant ε = ε r + iε i is related to the working wavelength, and the thickness of the metal film should be strictly controlled to make the coupling of the incident light and the guided wave most effective. The thickness of the upper metal film is between 20nm-80nm. The thickness of the lower metal film is determined according to the measurement method. When the reflected light measurement method is used, it should be greater than 100nm; when the transmitted light measurement method is used, it should generally be less than 30nm. The metal types are silver, gold, aluminum, copper and other metals with small imaginary part of dielectric constant in the optical frequency range, the real part of dielectric constant ε r ≤ -10, and the imaginary part of dielectric constant ε i ≤ 5.0.

待测薄膜层3的厚度在0.5μm~1000μm之间,厚度必须能承载三个以上的导波共振模式,其折射率在1.0~2.3之间,待测薄膜层3处于波导结构的传输层,导波光就在待测薄膜层3里传输。The thickness of the film layer 3 to be tested is between 0.5 μm and 1000 μm, the thickness must be able to carry more than three guided wave resonance modes, and its refractive index is between 1.0 and 2.3. The film layer 3 to be tested is in the transmission layer of the waveguide structure. The waveguide light is transmitted in the film layer 3 to be tested.

结合本发明的内容,提供以下三个实施例:In conjunction with the content of the present invention, the following three embodiments are provided:

实施例一:Embodiment one:

第一步:耦合器件1选用高折射率等边三角棱镜(n=1.5),在棱镜的底面和衬底材料上采用溅射方法镀上金属膜层,然后将两膜层拼合,并在其间留有空气薄层,形成双面金属波导结构,上层金属膜2厚度为34nm,待测薄膜3为空气,厚度的真实值为5μm,折射率真实值为1.0(介电系数为1.0),下层金属膜4厚度为300nm,金属采用金(690.0nm波长下ε=-14.4+i1.22);The first step: the coupling device 1 selects a high-refractive-index equilateral triangular prism (n=1.5), adopts the sputtering method to plate a metal film layer on the bottom surface of the prism and the substrate material, and then puts the two film layers together, and in between A thin layer of air is left to form a double-sided metal waveguide structure. The thickness of the upper metal film 2 is 34nm, the film 3 to be tested is air, the actual value of the thickness is 5μm, and the actual value of the refractive index is 1.0 (dielectric coefficient is 1.0). The metal film 4 has a thickness of 300nm, and the metal is gold (ε=-14.4+i1.22 at a wavelength of 690.0nm);

第二步:选用入射激光5波长为690.0nm,入射光为横磁波(TM模),入射角度7在0到90度之间扫描;The second step: select the incident laser 5 with a wavelength of 690.0nm, the incident light is a transverse magnetic wave (TM mode), and the incident angle 7 is scanned between 0 and 90 degrees;

第三步:在棱镜的另一侧接收并测量从棱镜底面反射的激光束6光强,反射光强极小值即为共振吸收峰,记录所激发的相邻三个共振吸收峰的角度,得:Step 3: Receive and measure the light intensity of the laser beam 6 reflected from the bottom surface of the prism on the other side of the prism. The minimum value of the reflected light intensity is the resonant absorption peak, and record the angles of the three adjacent resonant absorption peaks excited. have to:

θ1=22.83度  θ2=18.22度  θ3=11.63度θ 1 = 22.83 degrees θ 2 = 18.22 degrees θ 3 = 11.63 degrees

将以上数据代入双面金属薄导的特性方程,Substituting the above data into the characteristic equation of the double-sided metal thin conductor,

2π*sqrt(e1-N1 2)*d/λ=m*π+2*arctan((e1*sqrt(N1 2-e2))/(e2*sqrt(e1-N1 2)));2π*sqrt(e 1 -N 1 2 )*d/λ=m*π+2*arctan((e 1 *sqrt(N 1 2 -e 2 ))/(e 2 *sqrt(e 1 -N 1 2 )));

2*π*sqrt(e1-N2 2)*d/λ=(m+1)*π+2*arctan((e1*sqrt(N2 2-e2))/(e2*sqrt(e1-N2 2)));2*π*sqrt(e 1 -N 2 2 )*d/λ=(m+1)*π+2*arctan((e 1 *sqrt(N 2 2 -e 2 ))/(e 2 *sqrt (e 1 -N 2 2 )));

2*π*sqrt(e1-N3 2)*d/λ=(m+2)*π+2*arctan((e1*sqrt(N3 2-e2))/(e2*sqrt(e1-N3 2)));2*π*sqrt(e 1 -N 3 2 )*d/λ=(m+2)*π+2*arctan((e 1 *sqrt(N 3 2 -e 2 ))/(e 2 *sqrt (e 1 -N 3 2 )));

其中:Ni=n*sinθi,e2=-14.4+1.22i(金属层的介电系数),n=1.5(耦合器件1折射率),λ=0.69(入射激光5波长),m为模式阶数,是一个正整数,d为待测薄膜3的厚度,e1为待测薄膜3的介电系数。Wherein: N i =n*sinθ i , e 2 =-14.4+1.22i (dielectric coefficient of metal layer), n=1.5 (refractive index of coupling device 1), λ=0.69 (wavelength of incident laser 5), m is The mode order is a positive integer, d is the thickness of the film 3 to be tested, and e 1 is the dielectric coefficient of the film 3 to be tested.

解此联立方程组,得:Solving this system of simultaneous equations, we get:

e1=1.0021212    与真实值之间偏差为0.2%,The deviation between e 1 =1.0021212 and the true value is 0.2%,

d=5.00414133μm与真实值之间偏差为0.08%;The deviation between d=5.00414133μm and the true value is 0.08%;

m=12.0m=12.0

计算表明对待测薄膜3样品的介电系数(折射率的平方)检测可以达到0.2%的精度,对薄膜厚度的检测可以达到0.08%的精度。The calculation shows that the detection of the dielectric coefficient (the square of the refractive index) of the film 3 sample to be tested can reach an accuracy of 0.2%, and the detection of the film thickness can reach an accuracy of 0.08%.

实施例二:Embodiment two:

第一步:耦合器件1选用高折射率等边金红石棱镜(n=2.8),在待测薄膜的两面采用溅射方法形成双面金属波导结构,上层金属膜2厚度为48nm,待测薄膜3为铌酸锂,厚度的真实值为0.5μm,折射率真实值为2.22(介电系数为4.9284),下层金属膜4厚度为300nm。金属采用银(560.0nm波长下ε=-12.0+i0.4)。The first step: the coupling device 1 selects a high refractive index equilateral rutile prism (n=2.8), and adopts sputtering method to form a double-sided metal waveguide structure on both sides of the film to be tested. The thickness of the upper metal film 2 is 48nm, and the film to be tested 3 It is lithium niobate, the actual value of the thickness is 0.5 μm, the actual value of the refractive index is 2.22 (dielectric coefficient is 4.9284), and the thickness of the lower metal film 4 is 300 nm. The metal is silver (ε=-12.0+i0.4 at a wavelength of 560.0 nm).

第二步:选用入射激光波5长为560.0nm,入射光为横磁波(TM模),入射角度7在0到90度之间扫描;The second step: select the incident laser wavelength 5 to be 560.0nm, the incident light is a transverse magnetic wave (TM mode), and the incident angle 7 is scanned between 0 and 90 degrees;

第三步:在棱镜的另一侧接收并测量从棱镜底面反射的激光束6光强,反射光强极小值即为共振吸收峰,记录所激发的相邻三个共振吸收峰的角度,得:Step 3: Receive and measure the light intensity of the laser beam 6 reflected from the bottom surface of the prism on the other side of the prism. The minimum value of the reflected light intensity is the resonant absorption peak, and record the angles of the three adjacent resonant absorption peaks excited. have to:

θ1=48.76度   θ2=38.51度   θ3=19.47度θ 1 = 48.76 degrees θ 2 = 38.51 degrees θ 3 = 19.47 degrees

将以上数据代入双面金属薄导的特性方程,Substituting the above data into the characteristic equation of the double-sided metal thin conductor,

2π*sqrt(e1-N1 2)*d/λ=m*π+2*arctan((e1*sqrt(N1 2-e2))/(e2*sqrt(e1-N1 2)));2π*sqrt(e 1 -N 1 2 )*d/λ=m*π+2*arctan((e 1 *sqrt(N 1 2 -e 2 ))/(e 2 *sqrt(e 1 -N 1 2 )));

2*π*sqrt(e1-N2 2)*d/λ=(m+1)*π+2*arctan((e1*sqrt(N2 2-e2))/(e2*sqrt(e1-N2 2)));2*π*sqrt(e 1 -N 2 2 )*d/λ=(m+1)*π+2*arctan((e 1 *sqrt(N 2 2 -e 2 ))/(e 2 *sqrt (e 1 -N 2 2 )));

2*π*sqrt(e1-N3 2)*d/λ=(m+2)*π+2*arctan((e1*sqrt(N3 2-e2))/(e2*sqrt(e1-N3 2));2*π*sqrt(e 1 -N 3 2 )*d/λ=(m+2)*π+2*arctan((e 1 *sqrt(N 3 2 -e 2 ))/(e 2 *sqrt (e 1 -N 3 2 ));

其中:Ni=n*sinθi,e2=-12.0+0.4i(金属层的介电系数),n=2.8(耦合器件1折射率),λ=0.56(入射激光5波长),m为模式阶数,是一个正整数,d为待测薄膜3的厚度,e1为待测薄膜3的介电系数。Wherein: N i =n*sinθ i , e 2 =-12.0+0.4i (dielectric coefficient of metal layer), n=2.8 (refractive index of coupling device 1), λ=0.56 (wavelength of incident laser 5), m is The mode order is a positive integer, d is the thickness of the film 3 to be tested, and e 1 is the dielectric coefficient of the film 3 to be tested.

解此联立方程组,得:Solving this system of simultaneous equations, we get:

e1=4.93331422   与真实值之间偏差为0.1%,The deviation between e 1 =4.93331422 and the true value is 0.1%,

d=0.501123276μm与真实值之间偏差为0.224%;The deviation between d=0.501123276μm and the true value is 0.224%;

m=2.0m=2.0

计算表明对待测薄膜3样品的介电系数(折射率的平方)检测可以达到0.1%的精度,对薄膜厚度的检测可以达到0.224%的精度。The calculation shows that the detection of the dielectric coefficient (the square of the refractive index) of the film 3 sample to be tested can reach an accuracy of 0.1%, and the detection of the film thickness can reach an accuracy of 0.224%.

实施例三:Embodiment three:

第一步:本例不采用耦合器件1,而使用空气直接耦合的方法激发导模(n=1.0),在待测薄膜的两面采用溅射方法形成双面金属波导结构,上层金属膜2厚度为34nm,待测薄膜3厚度的真实值为1000μm,折射率真实值为1.673(介电系数为2.8),下层金属膜4厚度为300nm,金属采用金(890.0nm波长下ε=-34.5+i2.47)。Step 1: This example does not use the coupling device 1, but uses the air direct coupling method to excite the guided mode (n=1.0), and uses the sputtering method to form a double-sided metal waveguide structure on both sides of the film to be tested, and the thickness of the upper metal film 2 34nm, the real value of the thickness of the film 3 to be measured is 1000 μm, the real value of the refractive index is 1.673 (dielectric coefficient is 2.8), the thickness of the lower metal film 4 is 300nm, and the metal adopts gold (ε=-34.5+i under the wavelength of 890.0nm .47).

第二步:选用入射激光5波长为890.0nm,入射光为横磁波(TM模),入射角度7在0到90度之间扫描;The second step: select the wavelength of the incident laser 5 to be 890.0nm, the incident light is a transverse magnetic wave (TM mode), and the incident angle 7 is scanned between 0 and 90 degrees;

第三步:在棱镜的另一侧接收并测量从棱镜底面反射的激光束6光强,反射光强极小值即为共振吸收峰,因为在此实例中,待测薄膜3的厚度较大,所以激发的模式很多,相邻模式之间的距离很小,因此选取从零度开始的第一、第四、第七个模式来计算,记录所选取的三个共振吸收峰的角度,得:Step 3: Receive and measure the light intensity of the laser beam 6 reflected from the bottom surface of the prism on the other side of the prism. The minimum value of the reflected light intensity is the resonant absorption peak, because in this example, the thickness of the film 3 to be tested is relatively large , so there are many excited modes, and the distance between adjacent modes is very small, so the first, fourth and seventh modes starting from zero are selected for calculation, and the angles of the three selected resonant absorption peaks are recorded to obtain:

θ1=5.625度    θ2=4.114度    θ3=1.494度θ 1 = 5.625 degrees θ 2 = 4.114 degrees θ 3 = 1.494 degrees

将以上数据代入双面金属薄导的特性方程,Substituting the above data into the characteristic equation of the double-sided metal thin conductor,

2π*sqrt(e1-N1 2)*d/λ=m*π+2*arctan((e1*sqrt(N1 2-e2))/(e2*sqrt(e1-N1 2)));2π*sqrt(e 1 -N 1 2 )*d/λ=m*π+2*arctan((e 1 *sqrt(N 1 2 -e 2 ))/(e 2 *sqrt(e 1 -N 1 2 )));

2*π*sqrt(e1-N2 2)*d/λ=(m+3)*π+2*arctan((e1*sqrt(N2 2-e2)/(e2*sqrt(e1-N2 2)));2*π*sqrt(e 1 -N 2 2 )*d/λ=(m+3)*π+2*arctan((e 1 *sqrt(N 2 2 -e 2 )/(e 2 *sqrt( e 1 -N 2 2 )));

2*π*sqrt(e1-N3 2)*d/λ=(m+6)*π+2*arctan((e1*sqrt(N3 2-e2))/(e2*sqrt(e1-N3 2)));2*π*sqrt(e 1 -N 3 2 )*d/λ=(m+6)*π+2*arctan((e 1 *sqrt(N 3 2 -e 2 ))/(e 2 *sqrt (e 1 -N 3 2 )));

其中:Ni=n*sinθi,e2=-34.5+2.47i(金属层的介电系数),n=1.0(空气折射率),λ=0.89(入射激光5波长),m为模式阶数,是一个正整数,本实例中会很大,d为待测薄膜3的厚度,e1为待测薄膜3的介电系数。Where: N i =n*sinθ i , e 2 =-34.5+2.47i (dielectric coefficient of metal layer), n=1.0 (refractive index of air), λ=0.89 (5 wavelengths of incident laser light), m is the mode order Number, is a positive integer, can be very big in this instance, d is the thickness of the film 3 to be measured, and e1 is the dielectric coefficient of the film 3 to be measured.

解此联立方程组,得:Solving this system of simultaneous equations, we get:

e1=2.7842007    与真实值之间偏差为0.57%,The deviation between e 1 =2.7842007 and the true value is 0.57%,

d=997.162568μm与真实值之间偏差为0.28%;The deviation between d=997.162568μm and the true value is 0.28%;

m=3732m=3732

计算表明对待测薄膜3样品的介电系数(折射率的平方)检测可以达到0.57%的精度,对薄膜厚度的检测可以达到0.28%的精度。The calculation shows that the detection of the dielectric coefficient (the square of the refractive index) of the film 3 sample to be tested can reach an accuracy of 0.57%, and the detection of the film thickness can reach an accuracy of 0.28%.

Claims (3)

1、一种双面金属波导测量装置,其特征在于,采用高折射率棱镜n>1.5、光栅和耦合波导器件,或进行空气直接耦合作为耦合器件(1);采用对工作波长吸收较小的金属,种类为银、金、铝、铜,在光频范围内介电常数虚部较小的金属,其介电常数实部εr≤-10,介电常数虚部εi≤5.0来制作上层金属膜(2)和下层金属膜(4),且上层金属膜(2)的厚度在20nm~80nm之间,下层金属膜(4)的厚度根据测量方式确定,采用反射光测量方式时,大于100nm,采用透射光测量方式时,小于30nm;待测薄膜层(3)的厚度在0.5μm~1000μm之间,厚度必须承载三个以上的导波共振模式,其折射率在1.0~2.3之间;测量装置由上至下由耦合器件(1)、上层金属膜(2)、待测薄膜层(3)、下层金属膜(4)构成,其中,上层金属膜(2)、待测薄膜层(3)和下层金属膜(4)为双面金属波导结构,上层金属膜(2)、下层金属膜(4)为波导的上下覆盖层,待测薄膜层(3)处于波导结构的传输层,导波光在待测薄膜层(3)里传输。1. A double-sided metal waveguide measuring device, characterized in that it adopts a high refractive index prism n>1.5, a grating and a coupling waveguide device, or directly couples air as the coupling device (1); Metals, such as silver, gold, aluminum, copper, and metals with a small imaginary part of the dielectric constant in the optical frequency range, the real part of the dielectric constant ε r ≤ -10, and the imaginary part of the dielectric constant ε i ≤ 5.0 to produce The upper metal film (2) and the lower metal film (4), and the thickness of the upper metal film (2) is between 20nm and 80nm, and the thickness of the lower metal film (4) is determined according to the measurement method. When the reflected light measurement method is used, greater than 100nm, and less than 30nm when the transmitted light measurement method is used; the thickness of the film layer (3) to be measured is between 0.5 μm and 1000 μm, and the thickness must carry more than three guided wave resonance modes, and its refractive index is between 1.0 and 2.3 Between; the measuring device consists of a coupling device (1), an upper metal film (2), a thin film to be tested (3) and a lower metal film (4) from top to bottom, wherein the upper metal film (2), the thin film to be tested The layer (3) and the lower metal film (4) are double-sided metal waveguide structures, the upper metal film (2) and the lower metal film (4) are the upper and lower covering layers of the waveguide, and the film layer (3) to be tested is in the transmission of the waveguide structure. layer, the guided light is transmitted in the film layer (3) to be tested. 2、一种双面金属波导测量方法,其特征在于,具体步骤如下:2. A double-sided metal waveguide measurement method, characterized in that the specific steps are as follows: 第一步:在待测薄膜的两面用蒸镀、溅射方法,形成双面金属波导结构:采用高折射率棱镜n>1.5、光栅和耦合波导器件,或进行空气直接耦合作为耦合器件(1);采用对工作波长吸收较小的金属,种类为银、金、铝、铜,在光频范围内介电常数虚部较小的金属,其介电常数实部εr≤-10,介电常数虚部εr≤5.0来制作上层金属膜(2)和下层金属膜(4),且上层金属膜(2)的厚度在20nm~80nm之间,下层金属膜(4)的厚度根据测量方式确定,采用反射光测量方式时,大于100nm,采用透射光测量方式时,小于30nm;待测薄膜层(3)的厚度在0.5μm~1000μm之间,厚度必须承载三个以上的导波共振模式,其折射率在1.0~2.3之间;测量装置由上至下由耦合器件(1)、上层金属膜(2)、待测薄膜层(3)、下层金属膜(4)构成,其中,上层金属膜(2)、待测薄膜层(3)和下层金属膜(4)为双面金属波导结构,上层金属膜(2)、下层金属膜(4)为波导的上下覆盖层,待测薄膜层(3)处于波导结构的传输层,导波光在待测薄膜层(3)里传输;Step 1: Use evaporation and sputtering methods on both sides of the film to be tested to form a double-sided metal waveguide structure: use a high refractive index prism n>1.5, a grating and a coupling waveguide device, or perform air direct coupling as a coupling device (1 ); use metals that absorb less at the working wavelength, such as silver, gold, aluminum, copper, metals with a small imaginary part of the dielectric constant in the optical frequency range, and the real part of the dielectric constant ε r ≤ -10, the dielectric constant The imaginary part of the electrical constant ε r ≤ 5.0 to make the upper metal film (2) and the lower metal film (4), and the thickness of the upper metal film (2) is between 20nm and 80nm, the thickness of the lower metal film (4) according to the measurement The method is determined, when the reflected light measurement method is used, it is greater than 100nm, and when the transmitted light measurement method is used, it is less than 30nm; the thickness of the film layer (3) to be measured is between 0.5μm and 1000μm, and the thickness must bear more than three guided wave resonances Mode, whose refractive index is between 1.0 and 2.3; the measuring device consists of a coupling device (1), an upper metal film (2), a thin film layer to be measured (3), and a lower metal film (4) from top to bottom, wherein, The upper metal film (2), the film layer to be tested (3) and the lower metal film (4) are double-sided metal waveguide structures, the upper metal film (2) and the lower metal film (4) are the upper and lower covering layers of the waveguide, and the metal film to be tested The thin film layer (3) is in the transmission layer of the waveguide structure, and the guided wave light is transmitted in the thin film layer (3) to be tested; 第二步:选择合适的激光波长和入射角度以及偏振方式,用激光作为光源,工作波长可在可见和红外光频范围内选择,从激光器(8)输出的激光束(5)以一定的入射角度(7)入射到耦合器件(1)上,入射角度(7)激发多个共振吸收峰,偏振方式为TM模入射,或TE模入射;The second step: choose the appropriate laser wavelength, incident angle and polarization mode, use laser as the light source, the working wavelength can be selected in the visible and infrared light frequency range, the laser beam (5) output from the laser (8) with a certain incident The angle (7) is incident on the coupling device (1), the incident angle (7) excites multiple resonant absorption peaks, and the polarization mode is incident in TM mode or incident in TE mode; 第三步:在耦合器件的另一侧利用光强测量装置(9)接收并记录从耦合器件底面反射的激光束(6)光强,或从底面方向接收并记录从下层金属膜透射出的激光束光强;Step 3: Use the light intensity measuring device (9) on the other side of the coupling device to receive and record the light intensity of the laser beam (6) reflected from the bottom surface of the coupling device, or receive and record the light intensity transmitted from the lower metal film from the direction of the bottom surface laser beam intensity; 第四步:在0到90度范围内连续变化激光入射角度(7),并同期记录其反射透射光强,形成反射透射光强-入射角度曲线,在曲线上找出导模吸收峰的共振角度和相应的吸收峰宽度和深度,通过计算得到薄膜材料的折射率和厚度的精确值。Step 4: Continuously change the laser incident angle (7) within the range of 0 to 90 degrees, and record its reflection and transmission light intensity at the same time to form a reflection and transmission light intensity-incident angle curve, and find the resonance of the guided mode absorption peak on the curve Angles and corresponding absorption peak widths and depths are calculated to obtain accurate values of the refractive index and thickness of the thin film material. 3、根据权利要求2所述的这种双面金属波导测量方法,其特征是以下对本发明方法作进一步描述:3. The double-sided metal waveguide measurement method according to claim 2, characterized in that the method of the present invention is further described as follows: 将薄膜厚度和折射率光学特性的测量以及波导参数的表征,转化为对反射光强随入射角度变化曲线的测量;Transform the measurement of film thickness and refractive index optical properties and the characterization of waveguide parameters into the measurement of the curve of reflected light intensity versus incident angle; 选择衰减全反射导模区作为工作区;Select the attenuated total reflection guided mode area as the working area; 工作点即入射角度(7)选择在衰减全反射吸收峰高阶模区、低阶模区和表面模区,包括在一个器件中使用多个工作点同时工作及使用透射光进行测量的情况;The working point, that is, the incident angle (7) is selected in the high-order mode area, low-order mode area and surface mode area of the attenuated total reflection absorption peak, including the case of using multiple operating points to work simultaneously in a device and using transmitted light for measurement; 在对光偏振敏感的薄膜进行测量时,只用横电TE或横磁TM模光信号作为入射光,并用另一模式的光作为参考光,实现双光束计测;When measuring thin films sensitive to light polarization, only the transverse electric TE or transverse magnetic TM mode optical signal is used as the incident light, and the other mode of light is used as the reference light to realize double-beam measurement; 双面金属波导承载多个模式,同时对待测薄膜(3)厚度和折射率进行测量。The double-sided metal waveguide carries multiple modes, and the thickness and refractive index of the film (3) to be tested are measured simultaneously.
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