CN117169128A - Multichannel chamber cleaning endpoint monitoring device and method - Google Patents
Multichannel chamber cleaning endpoint monitoring device and method Download PDFInfo
- Publication number
- CN117169128A CN117169128A CN202311314571.8A CN202311314571A CN117169128A CN 117169128 A CN117169128 A CN 117169128A CN 202311314571 A CN202311314571 A CN 202311314571A CN 117169128 A CN117169128 A CN 117169128A
- Authority
- CN
- China
- Prior art keywords
- gas
- chamber
- channel
- cleaning
- endpoint monitoring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
Description
技术领域Technical field
本发明涉及半导体设备技术领域,具体为一种多通道腔室清洁终点监测装置及方法。The invention relates to the technical field of semiconductor equipment, specifically a multi-channel chamber cleaning endpoint monitoring device and method.
背景技术Background technique
薄膜工艺是制造半导体器件的关键技术,它是建立在一层层生长的膜基础之上再结合其它工艺堆积起来的微型“大厦”,掌握更加先进的半导体技术是兴国之要。目前,薄膜生产工艺的腔室清洗受到了一定的限制,腔体的环境受到沉积物厚度、沉积物类型、温度、压力与活性气体等多因素的影响,难以标定一个最佳清洁时间,从而造成膜堆积或过刻蚀现象。腔室清洗不干净或过度清洗,均会很大程度影响晶圆的质量和产量。且由于当前薄膜清洗设备的较单一种类限制,无法清洁涉及到众多的沉积材料类型的薄膜生产工艺。Thin film technology is a key technology for manufacturing semiconductor devices. It is a miniature "building" built on layers of films grown layer by layer and combined with other processes. Mastering more advanced semiconductor technology is the key to rejuvenating the country. At present, the chamber cleaning of the thin film production process is subject to certain restrictions. The environment of the chamber is affected by many factors such as sediment thickness, sediment type, temperature, pressure and active gas. It is difficult to calibrate an optimal cleaning time, resulting in Film accumulation or over-etching phenomenon. Improper or excessive cleaning of the chamber will greatly affect the quality and yield of wafers. And due to the limitation of a single type of current thin film cleaning equipment, it is impossible to clean thin film production processes involving numerous types of deposition materials.
国内外现有的腔室清洁装置有以下三种,包括:There are three types of chamber cleaning devices currently available at home and abroad, including:
第一种,将滤光片放入光路,通过滤光片轮旋转产生入射角,从而进行波长传输。但是该设备结构老化容易出现测试误差,且只用于CVD工艺测试单种气体SIF4。The first is to put the filter into the optical path and rotate the filter wheel to generate the incident angle, thereby transmitting the wavelength. However, the aging structure of this equipment is prone to test errors, and it is only used to test a single gas SIF 4 in the CVD process.
第二种,采用红外吸光度原理将流出物吸光度中的目标气体种类与参考信号进行比较,以计算目标气体种类的浓度。而该设备只用于CVD工艺测试两种气SIF4、CF4,局限性较大。Second, the principle of infrared absorbance is used to compare the target gas species in the effluent absorbance with a reference signal to calculate the concentration of the target gas species. However, this equipment is only used to test two gases SIF 4 and CF 4 in the CVD process, which has great limitations.
第三种,该设备且只用于CVD工艺测试一种SIF4气体,测试气体单一且工艺局限。The third type is that this equipment is only used to test one SIF 4 gas in the CVD process. The test gas is single and the process is limited.
综上所述,上述已有装置存在设备测试系统结构老化、测量气体种类单一、工艺应用范围狭窄和难以识别多种低浓度气体等缺陷,从而限制着半导体薄膜工艺的生产发展进入更高层次水平。To sum up, the above-mentioned existing devices have defects such as aging equipment test system structure, single type of measurement gas, narrow process application range, and difficulty in identifying multiple low-concentration gases, etc., thus limiting the production development of semiconductor thin film processes to a higher level. .
发明内容Contents of the invention
本发明旨在克服现有技术的不足,目的在于提供一种多通道腔室清洁终点监测装置及方法,本装置可以同时监测薄膜腔室清洁中涉及的多种类型的气体,并精准识别低浓度气体及应用于广泛的薄膜工艺范围。The present invention aims to overcome the shortcomings of the existing technology and aims to provide a multi-channel chamber cleaning endpoint monitoring device and method. This device can simultaneously monitor multiple types of gases involved in membrane chamber cleaning and accurately identify low concentrations. gases and are used in a wide range of thin film processes.
为完成上述任务,本发明提供如下技术方案:一种多通道腔室清洁终点监测装置,竖直安装在清洁腔室的前端尾排管道旁侧进行实时气体浓度监测,装置结构包括:In order to accomplish the above tasks, the present invention provides the following technical solution: a multi-channel chamber cleaning endpoint monitoring device, which is installed vertically next to the front end and tail pipe of the cleaning chamber for real-time gas concentration monitoring. The device structure includes:
光源;light source;
气体腔室,所述气体腔室包括柱形腔室本体及垂直设于腔室本体侧的进气管道和出气管道,所述进气管道与出气管道端口为标准NW25法兰接口;Gas chamber, the gas chamber includes a cylindrical chamber body and an air inlet pipe and an air outlet pipe vertically located on the side of the chamber body. The air inlet pipe and air outlet pipe ports are standard NW25 flange interfaces;
探测器,所述探测器包括滤光片和热释电探测元;A detector, which includes a filter and a pyroelectric detection element;
透镜组,所述透镜组包括准直镜和聚焦镜分别设于所述气体腔室两侧,用于对光线进行准直与汇聚并密封气体腔室。The lens group includes a collimating lens and a focusing lens respectively located on both sides of the gas chamber for collimating and converging light and sealing the gas chamber.
优选地,所述光源是宽带远红外光源,其波长范围为2μm至20μm。Preferably, the light source is a broadband far-infrared light source with a wavelength ranging from 2 μm to 20 μm.
优选地,所述光源的光程为600mm。Preferably, the optical path of the light source is 600mm.
优选地,所述气体腔室内表面经过平滑打磨,粗糙度小于0.2μm。Preferably, the inner surface of the gas chamber is smoothly polished, with a roughness of less than 0.2 μm.
优选地,所述探测器为双通道、四通道或八通道类型。Preferably, the detector is of dual-channel, four-channel or eight-channel type.
一种多通道腔室清洁终点监测方法,通过一种多通道腔室清洁终点监测装置,包括如下步骤:A multi-channel chamber cleaning end point monitoring method, through a multi-channel chamber cleaning end point monitoring device, includes the following steps:
步骤1:将所述装置竖直安装在目标工艺机台清洁腔室的前端尾排管道旁侧,打开电源开关;Step 1: Install the device vertically next to the front and rear pipes of the cleaning chamber of the target process machine, and turn on the power switch;
步骤2:清除(purge)所述气体腔室中的细小颗粒杂质和残留气体;Step 2: Purge the fine particle impurities and residual gas in the gas chamber;
步骤3:将清洁腔室中的待测气体通入所述气体腔室;Step 3: Pass the gas to be measured in the clean chamber into the gas chamber;
步骤4:所述光源工作产生红外光线经所述准直镜准直光路后穿过待测气体;Step 4: The infrared light generated by the operation of the light source passes through the gas to be measured after being collimated by the collimating lens and passing through the light path;
步骤5:所述探测器实时监测并收集经气体吸收后气体腔室接收端光线的光强变化,通过GUI界面输出气体浓度--时间曲线图,从零点上升至稳定区间再降至预设的气体浓度终点监测极小值即为清洁终点。Step 5: The detector monitors and collects in real time the light intensity changes of the light at the receiving end of the gas chamber after gas absorption, and outputs the gas concentration-time curve through the GUI interface, rising from zero to the stable range and then falling to the preset value. The minimum value of gas concentration endpoint monitoring is the cleaning endpoint.
优选地,所述步骤1中的应用工艺为CVD、PVD或SEG中任一种。Preferably, the application process in step 1 is any one of CVD, PVD or SEG.
优选地,所述步骤3中待测气体为SIF4、CF4、WF6、TiF4、CuF2、AlF2、CoF2和TaF5中的一种或几种。Preferably, the gas to be measured in step 3 is one or more of SIF 4 , CF 4 , WF 6 , TiF 4 , CuF 2 , AlF 2 , CoF 2 and TaF 5 .
优选地,所述步骤5中的实时监测是一种动态检测方法,通过嵌入式算法在考虑各种漂移情况下实现多通道气体浓度的精确计算,所述漂移情况包括温度、压力、膜厚和气流速度因素。Preferably, the real-time monitoring in step 5 is a dynamic detection method that uses an embedded algorithm to achieve accurate calculation of multi-channel gas concentration taking into account various drift conditions, including temperature, pressure, film thickness and Air velocity factor.
优选地,步骤5中气体浓度终点监测极小值设定范围为1.0*10-6-50.0*10-6VOL。Preferably, the gas concentration end point monitoring minimum value setting range in step 5 is 1.0*10 -6 -50.0*10 -6 VOL.
由于采用上述技术方案,本发明与现有技术相比所具有的积极效果在于:Due to the adoption of the above technical solution, the positive effects of the present invention compared with the prior art are:
(1)本发明装置安装简单便捷,易操作。(1) The device of the present invention is simple and convenient to install and easy to operate.
(2)气体管道为耐特气腐蚀材料且气体腔室内表面经平滑打磨以最小化气体吸收,因而可以精确地识别各低浓度气体。(2) The gas pipeline is made of special gas corrosion-resistant material and the inner surface of the gas chamber is smoothly polished to minimize gas absorption, so each low-concentration gas can be accurately identified.
(3)本发明能够实现同时监测多达七种气体的实时浓度值,对于腔体清洁终点的反馈能够对腔室起到很好的保护作用。(3) The present invention can monitor the real-time concentration values of up to seven gases at the same time, and the feedback on the end point of chamber cleaning can play a very good protective role in the chamber.
(4)本发明扩展了清洁终点监测在CVD、PVD和SEG工艺中的应用,能够有效提高腔室清洁效率并带来薄膜工艺领域生产水平的提升。(4) The present invention expands the application of cleaning endpoint monitoring in CVD, PVD and SEG processes, can effectively improve chamber cleaning efficiency and improve production levels in the field of thin film processes.
因此,本发明具有安装使用简单便捷、精确识别低浓度气体、多种类气体监测及可应用工艺范围广的特点。Therefore, the present invention has the characteristics of simple and convenient installation and use, accurate identification of low-concentration gases, monitoring of multiple types of gases, and a wide range of applicable processes.
附图说明Description of drawings
图1为本发明提供的多通道腔室清洁方法流程图;Figure 1 is a flow chart of the multi-channel chamber cleaning method provided by the present invention;
图2为本发明明实施例一的清洁终点探测装置的结构示意图;Figure 2 is a schematic structural diagram of a cleaning end point detection device according to Embodiment 1 of the present invention;
图3为本发明施例一的清洁终点探测装置的工作曲线图;Figure 3 is a working curve diagram of the cleaning end point detection device according to Embodiment 1 of the present invention;
图4为本发明实施例二的清洁终点探测装置的结构示意图;Figure 4 is a schematic structural diagram of a cleaning end point detection device according to Embodiment 2 of the present invention;
图5为本发明实施例二的清洁终点探测装置探测图形的结构示意图;Figure 5 is a schematic structural diagram of the detection pattern of the cleaning end point detection device in Embodiment 2 of the present invention;
图6为本发明实施例三的清洁终点探测装置的结构示意图;Figure 6 is a schematic structural diagram of a cleaning end point detection device according to Embodiment 3 of the present invention;
图7为本发明施例三的清洁终点探测装置探测图形的结构示意图。Figure 7 is a schematic structural diagram of the detection pattern of the cleaning end point detection device in Embodiment 3 of the present invention.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, of the embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts fall within the scope of protection of the present invention.
需要说明的是:It should be noted:
本发明的说明书和权利要求书以及本发明实施例附图中的术语“第一”、“第二”和“第三”(如果存在)等,仅是用于区别不同对象,而非用于描述特定的顺序;The terms "first", "second" and "third" (if present) in the description and claims of the present invention and the drawings of the embodiments of the present invention are only used to distinguish different objects, rather than to describe a specific sequence;
此外,术语“包括”以及它们的任何变形,意图在于覆盖不排他的包含,例如,包含了一系列步骤或单元的过程、方法、系统、产品或设备没有限定于已列出的步骤或单元,而是可选地还包括没有列出的步骤或单元,或可选地还包括对于这些过程、方法、产品或设备固有的其它步骤或单元。In addition, the term "comprising" and any variations thereof are intended to cover non-exclusive inclusions, for example, a process, method, system, product or device that includes a series of steps or units and is not limited to the listed steps or units. Rather, steps or elements not listed may optionally be included, or other steps or elements inherent to the process, method, product or apparatus may optionally be included.
需要理解的是:What needs to be understood is:
在本发明实施例的描述中,术语“上”、“下”、“顶部”、“底部”等指示性方位或位置用词,仅为基于本发明实施例附图所示的方位或位置关系,是为了便于描述本发明的实施例和简化说明,而不是指示或暗示所述的装置或元件必须具有的特定方位、特定的方位构造和操作,因此,不能理解为是对本发明的限制。In the description of the embodiments of the present invention, the terms "upper", "lower", "top", "bottom" and other indicative orientation or position words are only based on the orientation or positional relationships shown in the drawings of the embodiments of the present invention. , is for the convenience of describing the embodiments of the present invention and simplifying the description, but does not indicate or imply the specific orientation, specific orientation configuration and operation that the described device or element must have, and therefore cannot be understood as a limitation of the present invention.
在本发明中,除非另有明确的规定和限定,术语“安装”、“连接”、“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接或活动连接,亦可是成为一体;可以是直接连接,也可以是通过中间媒介的间接连接,可以是两个元件内部的连通或两个元件的相互作用关系,除非另有明确的限定,对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本发明中的具体含义。In the present invention, unless otherwise clearly stated and limited, the terms "installation", "connection", "fixing" and other terms should be understood in a broad sense. For example, it can be a fixed connection, a detachable connection or a movable connection. It can also be integrated into one body; it can be a direct connection or an indirect connection through an intermediate medium; it can be an internal connection between two elements or an interactive relationship between two elements. Unless otherwise clearly limited, for those of ordinary skill in the art Personnel may understand the specific meanings of the above terms in the present invention according to specific circumstances.
还需要说明的是:What also needs to be explained is:
以下的具体实施例可以相互结合,对于其中相同或相似的概念或过程可能在某些实施例中不再赘述。The following specific embodiments may be combined with each other, and the same or similar concepts or processes may not be described again in some embodiments.
下面,以具体的实施例对本发明的技术方案进行详细说明。Below, the technical solution of the present invention is described in detail with specific embodiments.
实施例1Example 1
本实施例1中提供了一种双通道腔室清洁终点监测装置,如图2所示,竖直安装在清洁腔室前端尾排管道的旁侧进行实时气体浓度监测,包括:Embodiment 1 provides a dual-channel chamber cleaning endpoint monitoring device, as shown in Figure 2, which is installed vertically on the side of the tail pipe at the front end of the cleaning chamber for real-time gas concentration monitoring, including:
光源1;light source 1;
气体腔室2,所述气体腔室2包括柱形腔室本体21及垂直设于腔室本体并与之连通的进气管道22和出气管道23,所述进气管道23与出气管道23端口为标准NW25法兰接口;Gas chamber 2. The gas chamber 2 includes a cylindrical chamber body 21 and an air inlet pipe 22 and a gas outlet pipe 23 that are vertically arranged on the chamber body and connected thereto. The air inlet pipe 23 and the gas outlet pipe 23 have two ports. It is a standard NW25 flange interface;
探测器3,所述探测器包括滤光片31、31和热释电探测元35、36;Detector 3, the detector includes optical filters 31, 31 and pyroelectric detection elements 35, 36;
透镜组,所述透镜组包括准直镜12和聚焦镜26分别设于所述气体腔室2两侧,用于对光线进行准直与汇聚并密封气体腔室2。The lens group includes a collimating lens 12 and a focusing lens 26 respectively located on both sides of the gas chamber 2 for collimating and converging light and sealing the gas chamber 2 .
具体的,光源1是宽带远红外光源,其波长范围为2μm至20μm。Specifically, the light source 1 is a broadband far-infrared light source with a wavelength ranging from 2 μm to 20 μm.
具体的,光源1的光程为600mm。Specifically, the optical path of light source 1 is 600mm.
具体的,气体腔室2为耐特气腐蚀材料且内表面经过平滑打磨,粗糙度小于0.2μm。Specifically, the gas chamber 2 is made of special gas corrosion-resistant material and the inner surface is smoothly polished with a roughness of less than 0.2 μm.
具体的,探测器3为双通道类型。Specifically, detector 3 is a dual-channel type.
本实施例还提供了一种双通道腔室清洁终点监测方法,如图1所示,利用上述一种双通道腔室清洁终点监测装置,包括如下步骤:This embodiment also provides a dual-channel chamber cleaning endpoint monitoring method. As shown in Figure 1, the above-mentioned dual-channel chamber cleaning endpoint monitoring device includes the following steps:
步骤1:将所述装置竖直安装在目标工艺机台清洁腔室的前端尾排管道旁侧,打开电源开关;Step 1: Install the device vertically next to the front and rear pipes of the cleaning chamber of the target process machine, and turn on the power switch;
步骤2:清除(purge)所述气体腔室中的细小颗粒杂质和残留气体;Step 2: Purge the fine particle impurities and residual gas in the gas chamber;
步骤3:将清洁腔室中的待测气体通入所述气体腔室;Step 3: Pass the gas to be measured in the clean chamber into the gas chamber;
步骤4:所述光源工作产生红外光线经所述准直镜准直光路后穿过待测气体;Step 4: The infrared light generated by the operation of the light source passes through the gas to be measured after being collimated by the collimating lens and passing through the light path;
步骤5:所述探测器实时监测并收集经气体吸收后气体腔室接收端光线的光强变化,通过GUI界面输出气体浓度--时间曲线图,从零点上升至稳定区间再降至预设的气体浓度终点监测极小值即为清洁终点。Step 5: The detector monitors and collects in real time the light intensity changes of the light at the receiving end of the gas chamber after gas absorption, and outputs the gas concentration-time curve through the GUI interface, rising from zero to the stable range and then falling to the preset value. The minimum value of gas concentration endpoint monitoring is the cleaning endpoint.
具体的,所述步骤3中的应用工艺为SEG。Specifically, the application process in step 3 is SEG.
具体的,所述步骤4中待测气体为SIF424。Specifically, the gas to be measured in step 4 is SIF 4 24.
具体的,所述步骤5中的实时监测是一种动态检测方法,通过嵌入式算法在考虑各种漂移情况下实现双通道气体浓度的精确计算,漂移情况包括温度、压力、膜厚和气流速度因素。Specifically, the real-time monitoring in step 5 is a dynamic detection method that uses an embedded algorithm to achieve accurate calculation of dual-channel gas concentration taking into account various drift conditions, including temperature, pressure, film thickness and air flow velocity. factor.
具体的,所述步骤5中预设的气体浓度终点监测极小值为10.0*10-6VOL。Specifically, the minimum value for gas concentration endpoint monitoring preset in step 5 is 10.0*10 -6 VOL.
图2表示本实施例1的工作过程为:待测气体SIF424由进气管道22进入气体腔室2的柱形腔室本体21(通过出气管道23排出),光源1工作发出红外光线11,经准直镜12准直后形成平行光线13,穿过柱形腔室本体21中的SiF424气体,平行光线13经过气体吸收后发生光强变化,被吸收后光线25经过聚焦镜26汇聚,到达滤光片31(参照通道窗口)和滤光片32,经滤波选择后的透射光线33、34分别到达热释电探测元35、36,再经嵌入式算法计算后在GUI界面输出SiF4气体浓度(c)--时间(t)曲线图(如图3所示),首先从零点上升至稳定区间,t1时到达所设定的气体浓度终点监测极小值10*10-6VOL,t1即为清洁终点。Figure 2 shows the working process of this embodiment 1: the gas SIF 4 24 to be measured enters the cylindrical chamber body 21 of the gas chamber 2 through the air inlet pipe 22 (and is discharged through the gas outlet pipe 23), and the light source 1 works to emit infrared light 11 , after being collimated by the collimating mirror 12, a parallel light 13 is formed, which passes through the SiF 4 24 gas in the cylindrical chamber body 21. The parallel light 13 changes in light intensity after being absorbed by the gas. After being absorbed, the light 25 passes through the focusing mirror 26 Converge and reach the filter 31 (reference channel window) and filter 32. The filtered and selected transmitted light 33 and 34 reach the pyroelectric detection units 35 and 36 respectively, and are then calculated by the embedded algorithm and output on the GUI interface. SiF 4 gas concentration (c) - time (t) curve (as shown in Figure 3), first rises from zero to the stable range, and reaches the set gas concentration endpoint monitoring minimum value 10*10-6VOL at t1 , t1 is the cleaning end point.
本实施提供的一种双通道腔室清洁终点监测方法拓展了在薄膜领域SEG工艺的应用,实时监测SIF4气体浓度并感知SEG腔室清洁终点,精准的清洁终点监测对于SEG腔室能够起到很好的保护作用,提升SEG腔室清洁效率及薄膜工艺生产效率。本实施例表现出了良好的积极效果,由于气体管道为耐特气腐蚀材料且内表面经过平滑打磨,因而可以可以最小化全体腔室壁对SIF424气体的吸收,且嵌入式算法在考虑温度、压力、膜厚和气流速度各种漂移情况下实现了双通道气体(SIF4气体通道和参照通道)浓度的精确计算,并扩展了腔室清洁终点监测在SEG工艺中的应用。This implementation provides a dual-channel chamber cleaning endpoint monitoring method that expands the application of SEG technology in the thin film field. It monitors the SIF 4 gas concentration in real time and senses the SEG chamber cleaning endpoint. Accurate cleaning endpoint monitoring can play a role in the SEG chamber. It has a very good protective effect and improves SEG chamber cleaning efficiency and thin film process production efficiency. This embodiment shows a good positive effect. Since the gas pipeline is made of special gas corrosion-resistant material and the inner surface is smoothly polished, the absorption of SIF 4 24 gas by the entire chamber wall can be minimized, and the embedded algorithm is taking into account It achieves accurate calculation of the concentration of dual-channel gas (SIF 4 gas channel and reference channel) under various drift conditions of temperature, pressure, film thickness and gas flow rate, and expands the application of chamber cleaning end-point monitoring in the SEG process.
实施例2Example 2
本实施例中提供了一种四通道腔室清洁终点监测装置,如图4所示,竖直安装在清洁腔室前端尾排管道的旁侧进行实时气体浓度监测,包括:This embodiment provides a four-channel chamber cleaning endpoint monitoring device, as shown in Figure 4, which is installed vertically next to the tail pipe at the front end of the cleaning chamber for real-time gas concentration monitoring, including:
光源10;light source 10;
气体腔室20,所述气体腔室20包括柱形腔室本体210及垂直设于腔室本体并与之连通的进气管道220和出气管道230,所述进气管道与出气管道端口为标准NW25法兰接口;Gas chamber 20. The gas chamber 20 includes a cylindrical chamber body 210 and an air inlet pipe 220 and a gas outlet pipe 230 that are vertically provided on the chamber body and connected thereto. The ports of the gas inlet pipe and the gas outlet pipe are standard NW25 flange interface;
探测器30,所述探测器包括滤光片310、320、330、340和热释电探测元350、360、370、380;Detector 30, the detector includes optical filters 310, 320, 330, 340 and pyroelectric detection elements 350, 360, 370, 380;
透镜组,所述透镜组包括准直镜120和聚焦镜280分别设于所述气体腔室20两侧,用于对光线进行准直与汇聚并密封气体腔室20。The lens group includes a collimating lens 120 and a focusing lens 280 respectively located on both sides of the gas chamber 20 for collimating and converging light and sealing the gas chamber 20 .
具体的,光源10是宽带远红外光源,其波长范围为2μm至20μm。Specifically, the light source 10 is a broadband far-infrared light source with a wavelength ranging from 2 μm to 20 μm.
具体的,光源10的光程为600mm。Specifically, the optical path of the light source 10 is 600mm.
具体的,气体腔室20为耐特气腐蚀材料且内表面经过平滑打磨,粗糙度小于0.2μm。Specifically, the gas chamber 20 is made of special gas corrosion-resistant material and the inner surface is smoothly polished with a roughness of less than 0.2 μm.
具体的,探测器30为四通道类型。Specifically, the detector 30 is a four-channel type.
本实施例还提供了一种四通道腔室清洁终点监测方法,如图1所示,利用上述一种四通道腔室清洁终点监测装置,包括如下步骤:This embodiment also provides a four-channel chamber cleaning endpoint monitoring method. As shown in Figure 1, the above-mentioned four-channel chamber cleaning endpoint monitoring device includes the following steps:
步骤1:将所述装置竖直安装在目标工艺机台清洁腔室的前端尾排管道旁侧,打开电源开关;Step 1: Install the device vertically next to the front and rear pipes of the cleaning chamber of the target process machine, and turn on the power switch;
步骤2:清除(purge)所述气体腔室中的细小颗粒杂质和残留气体;Step 2: Purge the fine particle impurities and residual gas in the gas chamber;
步骤3:将清洁腔室中的待测气体通入所述气体腔室;Step 3: Pass the gas to be measured in the clean chamber into the gas chamber;
步骤4:所述光源工作产生红外光线经所述准直镜准直光路后穿过待测气体;Step 4: The infrared light generated by the operation of the light source passes through the gas to be measured after being collimated by the collimating lens and passing through the light path;
步骤5:所述探测器实时监测并收集经气体吸收后气体腔室接收端光线的光强变化,通过GUI界面输出气体浓度--时间曲线图,从零点上升至稳定区间再降至预设的气体浓度终点监测极小值即为清洁终点。Step 5: The detector monitors and collects in real time the light intensity changes of the light at the receiving end of the gas chamber after gas absorption, and outputs the gas concentration-time curve through the GUI interface, rising from zero to the stable range and then falling to the preset value. The minimum value of gas concentration endpoint monitoring is the cleaning endpoint.
具体的,所述步骤3中的应用工艺为CVD。Specifically, the application process in step 3 is CVD.
具体的,所述步骤4中待测气体为SIF4240、CF4250和WF6260。Specifically, the gases to be measured in step 4 are SIF 4 240, CF 4 250 and WF 6 260.
具体的,所述步骤5中的实时监测是一种动态检测方法,通过嵌入式算法在考虑各种漂移情况下实现四通道气体浓度的精确计算,漂移情况包括温度、压力、膜厚和气流速度因素。Specifically, the real-time monitoring in step 5 is a dynamic detection method that uses an embedded algorithm to accurately calculate the gas concentration of the four channels while considering various drift conditions, including temperature, pressure, film thickness and air flow velocity. factor.
具体的,所述步骤5中气体浓度终点监测极小值设定为30.0*10-6VOL。Specifically, the minimum value for gas concentration endpoint monitoring in step 5 is set to 30.0*10 -6 VOL.
图4表示本实施例工作过程为:待测气体SIF4240、CF4250和WF6260由进气管道220进入气体腔室20的柱形腔室本体210(通过出气管道230排出),光源10工作发出红外光线110,经准直镜120准直后形成平行光线130,穿过柱形腔室本体210中的SIF4240、CF4250和WF6260气体,平行光线130经过气体吸收后发生光强变化,被吸收后光线270经过聚焦镜280汇聚,到达滤光片310(参照通道窗口)和滤光片320、330、340,经滤波选择后的透射光线311、321、331、341分别到达热释电探测元350、360、370、380,再经嵌入式算法计算后在GUI界面输出SIF4230、CF4240和WF6250气体浓度(c)--时间(t)曲线图(如图5所示),首先从零点上升至稳定区间,t1(WF6260)、t2(CF4250)、t3(SIF4240)时分别到达所设定的气体浓度终点监测极小值30*10-6VOL,t3即为清洁终点。Figure 4 shows the working process of this embodiment as follows: the gases SIF 4 240, CF 4 250 and WF 6 260 to be measured enter the cylindrical chamber body 210 of the gas chamber 20 through the air inlet pipe 220 (discharged through the gas outlet pipe 230), the light source 10 works to emit infrared light 110, which is collimated by the collimating mirror 120 to form parallel light 130, which passes through the SIF 4 240, CF 4 250 and WF 6 260 gases in the cylindrical chamber body 210. The parallel light 130 is absorbed by the gas. The light intensity changes. After being absorbed, the light 270 converges through the focusing lens 280 and reaches the filter 310 (refer to the channel window) and the filters 320, 330, 340. The filtered and selected transmitted light 311, 321, 331, 341 Reach the pyroelectric detection units 350, 360, 370, and 380 respectively, and then calculate the SIF 4 230, CF 4 240, and WF 6 250 gas concentration (c)-time (t) curves on the GUI interface after calculation by the embedded algorithm. (As shown in Figure 5), first rise from zero to the stable range, and reach the set gas concentration endpoint monitoring minimum value at t1 (WF 6 260), t2 (CF 4 250), and t3 (SIF 4 240) respectively. 30*10 -6 VOL, t3 is the cleaning end point.
本实施提供的一种四通道腔室清洁终点监测方法,相对实施例1有效提升了监测气体种类、数量,实时监测SIF4230、CF4240和WF6250气体浓度并感知CVD腔室清洁终点,精准的清洁终点监测对于CVD腔室能够起到很好的保护作用,提升CVD腔室清洁效率及薄膜工艺生产效率。本实施例表现出了良好的积极效果,由于气体管道为耐特气腐蚀材料且内表面经过平滑打磨,因而可以最小化全体腔室壁对SIF4240、CF4250和WF6260气体的吸收,且嵌入式算法在考虑温度、压力、膜厚和气流速度各种漂移情况下实现了四通道气体(SIF4、CF4、WF6气体通道和参照通道)浓度的精确计算,以防止过度清洗损坏腔室壁。This implementation provides a four-channel chamber cleaning endpoint monitoring method that effectively improves the monitoring gas type and quantity compared to Embodiment 1, monitors SIF 4 230, CF 4 240, and WF 6 250 gas concentrations in real time and senses the CVD chamber cleaning endpoint. , accurate cleaning endpoint monitoring can play a very good role in protecting the CVD chamber and improve the cleaning efficiency of the CVD chamber and the production efficiency of the thin film process. This embodiment shows a good positive effect. Since the gas pipeline is made of special gas corrosion-resistant material and the inner surface is smoothly polished, the absorption of SIF 4 240, CF 4 250 and WF 6 260 gases by the entire chamber wall can be minimized. , and the embedded algorithm achieves accurate calculation of the concentration of the four-channel gas (SIF 4 , CF 4 , WF 6 gas channel and reference channel) taking into account various drifts in temperature, pressure, film thickness and gas flow velocity to prevent excessive cleaning Damage to chamber walls.
实施例3Example 3
本实施例中提供了一种八通道腔室清洁终点监测装置,如图6所示,竖直安装在清洁腔室前端尾排管道的旁侧进行实时气体浓度监测,包括:This embodiment provides an eight-channel chamber cleaning endpoint monitoring device, as shown in Figure 6, which is installed vertically next to the tail pipe at the front end of the cleaning chamber for real-time gas concentration monitoring, including:
光源100;light source 100;
气体腔室200,所述气体腔室2包括柱形腔室本体2100及垂直设于腔室本体并与之连通的进气管道2200和出气管道2300,所述进气管道与出气管道端口为标准NW25法兰接口;Gas chamber 200. The gas chamber 2 includes a cylindrical chamber body 2100 and an air inlet pipe 2200 and a gas outlet pipe 2300 that are vertically provided on the chamber body and connected with it. The ports of the gas inlet pipe and the gas outlet pipe are standard NW25 flange interface;
探测器300,所述探测器包括滤光片3100、3200、3300、3400、3500、3700和3800和热释电探测元3900、4000、4100、4200、4300、4400、4500、4600;Detector 300, which includes optical filters 3100, 3200, 3300, 3400, 3500, 3700 and 3800 and pyroelectric detection elements 3900, 4000, 4100, 4200, 4300, 4400, 4500 and 4600;
透镜组,所述透镜组包括准直镜120和聚焦镜3000分别设于所述气体腔室200两侧,用于对光线进行准直与汇聚并密封气体腔室200。The lens group includes a collimating lens 120 and a focusing lens 3000 respectively located on both sides of the gas chamber 200 for collimating and converging light and sealing the gas chamber 200 .
具体的,光源100是宽带远红外光源,其波长范围为2μm至20μm。Specifically, the light source 100 is a broadband far-infrared light source with a wavelength ranging from 2 μm to 20 μm.
具体的,光源100的光程为600mm。Specifically, the optical path of the light source 100 is 600mm.
具体的,气体腔室200为耐特气腐蚀材料且内表面经过平滑打磨,粗糙度小于0.2μm。Specifically, the gas chamber 200 is made of special gas corrosion-resistant material and the inner surface is smoothly polished with a roughness of less than 0.2 μm.
具体的,探测器300为八通道类型。Specifically, the detector 300 is an eight-channel type.
本实施例还提供了一种八通道腔室清洁终点监测方法,如图1所示,利用上述一种八通道腔室清洁终点监测装置,包括如下步骤:This embodiment also provides an eight-channel chamber cleaning endpoint monitoring method. As shown in Figure 1, the above-mentioned eight-channel chamber cleaning endpoint monitoring device includes the following steps:
步骤1:将所述装置竖直安装在目标工艺机台清洁腔室的前端尾排管道旁侧,打开电源开关;Step 1: Install the device vertically next to the front and rear pipes of the cleaning chamber of the target process machine, and turn on the power switch;
步骤2:清除(purge)所述气体腔室中的细小颗粒杂质和残留气体;Step 2: Purge the fine particle impurities and residual gas in the gas chamber;
步骤3:将清洁腔室中的待测气体通入所述气体腔室;Step 3: Pass the gas to be measured in the clean chamber into the gas chamber;
步骤4:所述光源工作产生红外光线经所述准直镜准直光路后穿过待测气体;Step 4: The infrared light generated by the operation of the light source passes through the gas to be measured after being collimated by the collimating lens and passing through the light path;
步骤5:所述探测器实时监测并收集经气体吸收后气体腔室接收端光线的光强变化,通过GUI界面输出气体浓度--时间曲线图,从零点上升至稳定区间再降至预设的气体浓度终点监测极小值即为清洁终点。Step 5: The detector monitors and collects in real time the light intensity changes of the light at the receiving end of the gas chamber after gas absorption, and outputs the gas concentration-time curve through the GUI interface, rising from zero to the stable range and then falling to the preset value. The minimum value of gas concentration endpoint monitoring is the cleaning endpoint.
具体的,所述步骤3中的应用工艺为PVD。Specifically, the application process in step 3 is PVD.
具体的,所述步骤4中待测气体为SIF42400、WF62500、TiF42600、CuF22700、AlF22800和CoF22900。Specifically, the gases to be measured in step 4 are SIF 4 2400, WF 6 2500, TiF 4 2600, CuF 2 2700, AlF 2 2800 and CoF 2 2900.
具体的,所述步骤5中的实时监测是一种动态检测方法,通过嵌入式算法在考虑各种漂移情况下实现八通道气体浓度的精确计算,漂移情况包括温度、压力、膜厚和气流速度因素。Specifically, the real-time monitoring in step 5 is a dynamic detection method that uses embedded algorithms to achieve accurate calculation of eight-channel gas concentrations while considering various drift conditions, including temperature, pressure, film thickness and air flow velocity. factor.
具体的,所述步骤5中气体浓度终点监测极小值设定为50.0*10-6VOL。Specifically, the minimum value for gas concentration endpoint monitoring in step 5 is set to 50.0*10 -6 VOL.
图5表示本实施例工作过程为:待测气体SIF42300、WF62400、TiF42500、CuF22600、AlF22700和CoF22800由进气管道2200进入气体腔室200的柱形腔室本体2100(通过出气管道2300排出),光源100工作发出红外光线1100,经准直镜1200准直后形成平行光线1300,穿过柱形腔室本体2100中的SIF42400、WF62500、TiF42600、CuF22700、AlF22800和CoF22900气体,平行光线1300经过气体吸收后发生光强变化,被吸收后光线3000经过聚焦镜3001汇聚,到达滤光片3100(参照通道窗口)和滤光片3200、3300、3400、3500、3600、3700、3800,经滤波选择后的透射光线3101,3201,3301,3401,3501,3601,3701,3801分别到达热释电探测元3900、4000、4100、4200、4300、4400、4500、4600,再经嵌入式算法计算后在GUI界面输出SIF42400、WF62500、TiF42600、CuF22700、AlF22800和CoF22900气体浓度(c)--时间(t)曲线图(如图7所示),首先从零点上升至稳定区间,t1(AlF22800)、t2(CoF22900)、t3(TiF42600)、t4(WF62500)、t5(CuF22700)、t6(SIF42400)时分别到达所设定的气体浓度终点监测极小值30*10-6VOL,t6即为清洁终点。Figure 5 shows the working process of this embodiment as follows: the gases to be measured SIF 4 2300, WF 6 2400, TiF 4 2500, CuF 2 2600, AlF 2 2700 and CoF 2 2800 enter the cylindrical cavity of the gas chamber 200 through the air inlet pipe 2200 The chamber body 2100 (exhausted through the air outlet pipe 2300), the light source 100 works to emit infrared light 1100, which is collimated by the collimating mirror 1200 to form parallel light 1300, which passes through the SIF 4 2400, WF 6 2500, and TiF 4 2600, CuF 2 2700, AlF 2 2800 and CoF 2 2900 gases, the parallel light 1300 changes in light intensity after being absorbed by the gas. After being absorbed, the light 3000 converges through the focusing mirror 3001 and reaches the filter 3100 (refer to the channel window) and filters 3200, 3300, 3400, 3500, 3600, 3700, 3800. After filtering and selecting, the transmitted light 3101, 3201, 3301, 3401, 3501, 3601, 3701, 3801 reaches the pyroelectric detection units 3900 and 4000 respectively. , 4100, 4200, 4300, 4400, 4500, 4600, and then calculated by the embedded algorithm and output SIF 4 2400, WF 6 2500, TiF 4 2600, CuF 2 2700, AlF 2 2800 and CoF 2 2900 gas concentrations in the GUI interface ( c)--Time (t) curve (shown in Figure 7), first rises from zero to the stable range, t1 (AlF 2 2800), t2 (CoF 2 2900), t3 (TiF 4 2600), t4 (WF 6 2500), t5 (CuF 2 2700), and t6 (SIF 4 2400) respectively reach the set gas concentration endpoint monitoring minimum value 30*10 -6 VOL, and t6 is the cleaning endpoint.
本实施提供的一种八通道腔室清洁终点监测方法,相对实施例1和实施例2更大程度的提升了监测气体种类、数量并扩展了在薄膜领域PVD工艺的应用,实时监测SIF42400、WF62500、TiF42600、CuF22700、AlF22800和CoF22900气体浓度并感知SEG腔室清洁终点,精准的清洁终点监测对于PVD腔室能够起到很好的保护作用,提升PVD腔室清洁效率及薄膜工艺生产效率。本实施例3表现出了良好的积极效果,由于气体管道为耐特气腐蚀材料且内表面经过平滑打磨,因而可以可以最小化全体腔室壁对SIF42400、WF62500、TiF42600、CuF22700、AlF22800和CoF22900气体的吸收,且嵌入式算法在考虑温度、压力、膜厚和气流速度各种漂移情况下实现了八通道气体(SIF4、WF6、TiF4、CuF2、AlF2和CoF2气体通道和参照通道)浓度的精确计算,并扩展了腔室清洁终点监测在PVD工艺中的应用。This implementation provides an eight-channel chamber cleaning endpoint monitoring method. Compared with Embodiment 1 and 2, it improves the type and quantity of monitored gases to a greater extent and expands the application of PVD technology in the field of thin films. It monitors SIF 4 2400 in real time. , WF 6 2500, TiF 4 2600, CuF 2 2700, AlF 2 2800 and CoF 2 2900 gas concentrations and sense the cleaning endpoint of the SEG chamber. Accurate cleaning endpoint monitoring can play a very good protective role in the PVD chamber and improve PVD Chamber cleaning efficiency and film process production efficiency. This embodiment 3 shows good positive effects. Since the gas pipeline is made of special gas corrosion-resistant material and the inner surface is smoothly polished, the impact of the entire chamber wall on SIF 4 2400, WF 6 2500, TiF 4 2600, The absorption of CuF 2 2700, AlF 2 2800 and CoF 2 2900 gases, and the embedded algorithm realizes eight-channel gases (SIF 4 , WF 6 , TiF 4 , Accurate calculation of CuF 2 , AlF 2 and CoF 2 gas channel and reference channel) concentrations, and expands the application of chamber cleaning endpoint monitoring in PVD processes.
在上述说明书的描述过程中:In the description process of the above manual:
术语“本实施例”、“本发明实施例”、“如……所示”、“进一步的”、“进一步改进的技术分方案”等的描述,意指该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中,在本说明书中,对上述术语的示意性表述不是必须针对相同的实施例或示例,而且,描述的具体特征、结构、材料或者特点等可以在任意一个或者多个实施例或示例中以合适的方式结合或组合;Descriptions of the terms "this embodiment", "embodiments of the present invention", "as shown in...", "further", "further improved technical sub-solutions", etc., mean the specific features described in the embodiment or example , structures, materials or features are included in at least one embodiment or example of the present invention. In this specification, the schematic expressions of the above terms are not necessarily directed to the same embodiment or example, and the specific features, structures, Materials or features may be combined or combined in a suitable manner in any one or more embodiments or examples;
此外,在不产生矛盾的前提下,本领域的普通技术人员可以将本说明书中描述的不同实施例或示例以及不同实施例或示例的特征进行结合或组合。In addition, those of ordinary skill in the art may combine or combine different embodiments or examples and features of different embodiments or examples described in this specification, provided that no contradiction occurs.
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, those of ordinary skill in the art will understand that various changes, modifications, and substitutions can be made to these embodiments without departing from the principles and spirit of the invention. and modifications, the scope of the invention is defined by the appended claims and their equivalents.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311314571.8A CN117169128A (en) | 2023-10-11 | 2023-10-11 | Multichannel chamber cleaning endpoint monitoring device and method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311314571.8A CN117169128A (en) | 2023-10-11 | 2023-10-11 | Multichannel chamber cleaning endpoint monitoring device and method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN117169128A true CN117169128A (en) | 2023-12-05 |
Family
ID=88941452
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202311314571.8A Pending CN117169128A (en) | 2023-10-11 | 2023-10-11 | Multichannel chamber cleaning endpoint monitoring device and method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN117169128A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN121237703A (en) * | 2025-12-03 | 2025-12-30 | 上海车仪田科技有限公司 | Method and system for judging cleaning end point of semiconductor process chamber |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060107973A1 (en) * | 2004-10-12 | 2006-05-25 | Samuel Leung | Endpoint detector and particle monitor |
| CN1804114A (en) * | 2004-08-25 | 2006-07-19 | 东京毅力科创株式会社 | Thin film forming device and cleaning method thereof |
| US20120186604A1 (en) * | 2011-01-20 | 2012-07-26 | Kabushiki Kaisha Toshiba | Semiconductor manufacturing apparatus and cleaning method thereof |
| CN116559105A (en) * | 2023-07-06 | 2023-08-08 | 国科大杭州高等研究院 | Linearization readout circuit system based on gas infrared spectrum detection technology |
| CN220932759U (en) * | 2023-10-11 | 2024-05-10 | 上海车仪田科技有限公司 | Multichannel cavity cleaning endpoint monitoring device |
-
2023
- 2023-10-11 CN CN202311314571.8A patent/CN117169128A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1804114A (en) * | 2004-08-25 | 2006-07-19 | 东京毅力科创株式会社 | Thin film forming device and cleaning method thereof |
| US20060107973A1 (en) * | 2004-10-12 | 2006-05-25 | Samuel Leung | Endpoint detector and particle monitor |
| US20120186604A1 (en) * | 2011-01-20 | 2012-07-26 | Kabushiki Kaisha Toshiba | Semiconductor manufacturing apparatus and cleaning method thereof |
| CN116559105A (en) * | 2023-07-06 | 2023-08-08 | 国科大杭州高等研究院 | Linearization readout circuit system based on gas infrared spectrum detection technology |
| CN220932759U (en) * | 2023-10-11 | 2024-05-10 | 上海车仪田科技有限公司 | Multichannel cavity cleaning endpoint monitoring device |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN121237703A (en) * | 2025-12-03 | 2025-12-30 | 上海车仪田科技有限公司 | Method and system for judging cleaning end point of semiconductor process chamber |
| CN121237703B (en) * | 2025-12-03 | 2026-02-10 | 上海车仪田科技有限公司 | A method and system for determining the cleaning endpoint of a semiconductor process chamber. |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI240600B (en) | Apparatus and method for use of optical system with a plasma processing system | |
| US7351976B2 (en) | Monitoring system comprising infrared thermopile detector | |
| US7723685B2 (en) | Monitoring system comprising infrared thermopile detector | |
| US6344151B1 (en) | Gas purge protection of sensors and windows in a gas phase processing reactor | |
| US8009938B2 (en) | Advanced process sensing and control using near infrared spectral reflectometry | |
| JP4456224B2 (en) | Method and apparatus for monitoring the processing status of a semiconductor device manufacturing process | |
| US20240079220A1 (en) | Optical absorption sensor for semiconductor processing | |
| TW201930863A (en) | In-situ chamber clean end point detection systems and methods using computer vision systems | |
| CN117169128A (en) | Multichannel chamber cleaning endpoint monitoring device and method | |
| TW202018810A (en) | Normal-incidence in-situ process monitor sensor | |
| CN220932759U (en) | Multichannel cavity cleaning endpoint monitoring device | |
| TWI842930B (en) | Methods for detection using optical emission spectroscopy | |
| CN103866260B (en) | Coating method, coating device and coating generation system | |
| CN117102156A (en) | A kind of graphite boat dry cleaning device and cleaning method | |
| JP3191076B2 (en) | Dry etching apparatus and dry etching method | |
| KR101871809B1 (en) | apparatus for monitoring gas and plasma process equipment including the same | |
| JP7617914B2 (en) | Gas delivery systems and methods | |
| KR20250012642A (en) | In-situ integrated wafer parameter detection system | |
| US12014902B2 (en) | System and method of cleaning process chamber components | |
| TW202224799A (en) | Method for controlling consumption of cleaning gas in processing chamber and processing system | |
| US20250118603A1 (en) | Improved optical access for spectroscopic monitoring of semiconductor processes | |
| US12422357B2 (en) | Chamber moisture control using narrow optical filters measuring emission lines | |
| KR200489281Y1 (en) | Contamination sensor for process gas line | |
| US20130055818A1 (en) | Pressure control in continuous plasma deposition processes | |
| JPS6389684A (en) | Detection of end point of cleaning |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |