CN1171547C - Processing method for reducing benzo [ a ] pyrene content in cigarette smoke - Google Patents
Processing method for reducing benzo [ a ] pyrene content in cigarette smoke Download PDFInfo
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- CN1171547C CN1171547C CNB031488323A CN03148832A CN1171547C CN 1171547 C CN1171547 C CN 1171547C CN B031488323 A CNB031488323 A CN B031488323A CN 03148832 A CN03148832 A CN 03148832A CN 1171547 C CN1171547 C CN 1171547C
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- Prior art keywords
- gamma
- cigarette
- benzo
- cigarette smoke
- pyrene
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- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 45
- FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 239000000779 smoke Substances 0.000 title claims abstract description 17
- 238000003672 processing method Methods 0.000 title claims abstract description 7
- 230000005251 gamma ray Effects 0.000 claims abstract description 27
- 230000005855 radiation Effects 0.000 claims abstract description 13
- GUTLYIVDDKVIGB-OUBTZVSYSA-N Cobalt-60 Chemical compound [60Co] GUTLYIVDDKVIGB-OUBTZVSYSA-N 0.000 claims abstract description 7
- BUGBHKTXTAQXES-AHCXROLUSA-N Selenium-75 Chemical compound [75Se] BUGBHKTXTAQXES-AHCXROLUSA-N 0.000 claims abstract description 4
- TVFDJXOCXUVLDH-RNFDNDRNSA-N cesium-137 Chemical compound [137Cs] TVFDJXOCXUVLDH-RNFDNDRNSA-N 0.000 claims abstract description 4
- GKOZUEZYRPOHIO-IGMARMGPSA-N iridium-192 Chemical compound [192Ir] GKOZUEZYRPOHIO-IGMARMGPSA-N 0.000 claims abstract description 4
- 235000019505 tobacco product Nutrition 0.000 claims description 9
- 230000009467 reduction Effects 0.000 claims description 6
- 238000000034 method Methods 0.000 abstract description 8
- 230000000391 smoking effect Effects 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 3
- 239000011269 tar Substances 0.000 description 11
- 241000208125 Nicotiana Species 0.000 description 9
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 7
- 239000000523 sample Substances 0.000 description 7
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 6
- 229960002715 nicotine Drugs 0.000 description 6
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 4
- 238000004868 gas analysis Methods 0.000 description 4
- 238000004817 gas chromatography Methods 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 238000012544 monitoring process Methods 0.000 description 4
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 4
- 150000001720 carbohydrates Chemical class 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000013068 control sample Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000005284 excitation Effects 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000005605 benzo group Chemical group 0.000 description 2
- 239000003183 carcinogenic agent Substances 0.000 description 2
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000002285 radioactive effect Effects 0.000 description 2
- MGTMTTGZMPDIQS-UHFFFAOYSA-N 6-Hydroxybenzo[a]pyrene Chemical compound C1=C2C(O)=C(C=CC=C3)C3=C(C=C3)C2=C2C3=CC=CC2=C1 MGTMTTGZMPDIQS-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- LPQOADBMXVRBNX-UHFFFAOYSA-N ac1ldcw0 Chemical compound Cl.C1CN(C)CCN1C1=C(F)C=C2C(=O)C(C(O)=O)=CN3CCSC1=C32 LPQOADBMXVRBNX-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011285 coke tar Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000033444 hydroxylation Effects 0.000 description 1
- 238000005805 hydroxylation reaction Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 231100000586 procarcinogen Toxicity 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The invention relates to a processing method for reducing benzo [ a ] pyrene content in cigarette smoke, which is characterized in that finished cigarettes or box-packed cigarettes are placed in a gamma-ray radiation area for gamma-ray radiation, the adopted gamma-ray radiation source is isotope cobalt-60 or cesium-137 or iridium-192 or selenium-75, the radiation dose is 4KGy-40KGy, and the benzo [ a ] pyrene content in the cigarette smoke can be reduced by 12-70%, and the smoking quality of the cigarettes processed by the method is basically not influenced; in addition, the finished cigarette can be effectively prevented from mildewing in the storage process through gamma ray irradiation.
Description
Technical field
The present invention relates to reduce the technology of harmful components in the cigarette smoke, particularly a kind of treatment technology that can effectively reduce benzo in the finished product cigarette smoke [a] pyrene content.
Background technology
Along with improving constantly and progress of science and technology of living standards of the people, smoking is to extremely social concerns of health affected.At present, tobacco science and technology tentatively discloses, harmful components in the coke tar in cigarette, it is one of main matter of harm health of smokers, contain multiple carcinogenic substance and short cancer thing in the tar, for example well-known carcinogen benzo [a] pyrene, its procarcinogen therefore one is exactly: benzo [a] pyrene is at first at 6 hydroxylations, form 6-hydroxy benzo [a] pyrene (it can form covalent compound with nucleic acid), further be oxidized to 6-oxygen benzo [a] pyrene free radical again, this free radical can be attacked human DNA and form bond, thereby causes canceration.In a word, reducing tar content, improve the smoking security and be subjected to the tobacco business common concern always, also is one of urgent problem in the current cigarette industry development.
In recent years, tobacco business is from cigarette process technology aspect both at home and abroad, by improving air permeance for cigarette paper, adopting the filter tip with different structure, the technology such as dilution, expanded cut tobacco stem and reconstituted tobacoo, adding medicinal herb components of punching, reduce tar content in cigarette, some gratifying achievements have been obtained, but the tar content of the cigarette of Chu Shouing is still generally higher in the market.
Along with deepening continuously of " smoking is with healthy " problem, development low tar, low harm cigarette are the only ways of whole world tobacco business.
Summary of the invention
Purpose of the present invention just provides the treatment technology of benzo [a] pyrene content in a kind of technology reduction finished product cigarette smoke simple, with low cost.
The present invention has finished goal of the invention by following technical scheme is provided:
The tobacco product (cigarette props up or cigarettes) that the cigarette machine is produced, after the packing, with hanging the hang-up tobacco bale, be placed in the gamma-ray irradiation district, with radio isotope cobalt-60, caesium-137, iridium-192 or selenium-75 is gamma-ray radiation source, the loading of source amount is 300,000 Curie to 150, ten thousand Curie, and the dosage of irradiation is at 4KGy-40KGy (1KGy=1000Gy).Tobacco product adopts and utilizes the gas chromatography instrument behind gamma-ray irradiation---and select ion monitoring method (SIM) to measure the content of benzo [a] pyrene in the cigarette smoke.Compare sample with the Cigarette that does not pass through gamma-ray irradiation, carry out flue gas analysis and suction evaluation.
The gamma-ray irradiation device that the present invention adopts is made of gamma-rays radioactive source, source storage well, source frame, hoisting mechanism, transfer system, control system, safety interlock system.
The processing method of benzo [a] pyrene content in a kind of reduction cigarette smoke of the present invention can make benzo in the cigarette smoke [a] pyrene content decline 12-70%, and the sucking quality of cigarette is unaffected substantially; In addition, gamma-ray irradiation can also prevent going mouldy in the finished cigarettes storage process effectively.
The gamma-rays that the present invention adopts, its frequency is 3 * 10
12～3 * 10
15MHz, gamma-ray photon energy is up to 1.1732MeV, and therefore, gamma-rays can make generation ionization of most organic matter molecule or chemical bond disconnect.When the gamma-ray irradiation finished cigarettes, cigarette props up the presoma of middle benzo [a] pyrene, accept to become unstable after the gamma-rays photon energy as the electronics in the components such as protein, carbohydrate, cellulose, electronics will transit to the high level track from the low-lying level track, cause atom to be excited state, when excitation energy is higher than molecular ionization potential, the then molecule generation ionization of protein, carbohydrate, cellulose etc.; In addition, molecular excitation can be converted into the chemical bond vibrational energy again, when this vibrational energy surpasses chemical bond energy, be in the covalent bond fracture of molecule of the protein, carbohydrate, cellulose etc. of excitation state, generate little molecule free radical, a nearly step is converted into materials such as amino acid, monose, thereby reaches the purpose that reduces benzo [a] pyrene content in the finished product cigarette smoke.
The ray that gamma-rays sends from atomic nucleus inside when being the decay of radio isotopes such as cobalt-60, caesium-137, iridium-192 or selenium-75.It is widely used in fields such as radioactive breeding, food fresh keeping, disposable use medical article sterilizing, radiographic inspection, radiation chemistry, material composition analysis, customs's container detections, has brought huge benefit to the mankind; In addition, can not produced artificial radioactivity, non-residual toxicity behind the irradiation by the article of gamma-ray irradiation.1997, the International Atomic Energy Agency and the World Health Organization announced that jointly the high dose radiation that surpasses 10KGy (Gy is the abbreviation of Gray, irradiation unit) also is safe, and these conclusions have greatly promoted the development of irradiation industry, are now generally accepted in the world.
The specific embodiment
Further specify the present invention by the following examples.
Embodiment 1
With tar content is that 15mg, nicotine content are 200 of the tobacco products of 1.2mg, is divided into ten bags, with hanging the hang-up tobacco bale, be placed in the gamma-ray irradiation district, with radio isotope cobalt-60 is gamma-ray radiation source, and the loading of source amount is 300,000 Curie, and the dosage of irradiation is 4KGy (1KGy=1000Gy).Tobacco product utilizes gas chromatography instrument-selection ion monitoring method (SIM) to measure the content of benzo [a] pyrene in the cigarette smoke behind gamma-ray irradiation.Compare sample with the Cigarette that does not pass through gamma-ray irradiation, carry out flue gas analysis and suction evaluation.The results are shown in following table.
| Project | The control sample detected value | Sample detection value of the present invention | Reduced rate (%) |
| Benzo [a] pyrene | 15.37 nanogram/ | 13.56 nanogram/ | 11.78 |
| Nicotine | 1.2 milligram/ | 1.1 milligram/ | 8.3 |
| Tar content | 15 milligrams/ | 14.5 milligram/ | 3.3 |
| Suck evaluation | Suck the taste no change | ||
Embodiment 2
With tar content is that 12mg, nicotine content are 200 of the tobacco products of 1.0mg, is divided into five bags, with hanging the hang-up tobacco bale, be placed in the gamma-ray irradiation district, with radio isotope cobalt-60 is gamma-ray radiation source, and the loading of source amount is 1,000,000 Curie, and the dosage of irradiation is 20KGy.Tobacco product utilizes gas chromatography instrument-selection ion monitoring method to measure the content of benzo [a] pyrene in the cigarette smoke behind gamma-ray irradiation.Compare sample with the Cigarette that does not pass through gamma-ray irradiation.Carry out flue gas analysis and suction evaluation.The results are shown in following table.
| Project | The control sample detected value | Sample detection value of the present invention | Reduced rate (%) |
| Benzo [a] pyrene | 11.28 nanogram/ | 8.54 nanogram/ | 24.29 |
| Nicotine | 1.0 milligram/ | 0.8 milligram/ | 20.00 |
| Tar content | 12 milligrams/ | 10 milligrams/ | 16.67 |
| Suck evaluation | Suck taste and do not have noticeable variation | ||
Embodiment 3
With tar content is that 15mg, nicotine content are 200 of the tobacco products of 1.2mg, is divided into four bags, with hanging the hang-up tobacco bale, be placed in the gamma-ray irradiation district, with radio isotope cobalt-60 is gamma-ray radiation source, and the loading of source amount is 1,500,000 Curie, and the dosage of irradiation is 40KGy.Tobacco product is behind gamma-ray irradiation. and utilize gas chromatography instrument-selection ion monitoring method to measure the content of benzo [a] pyrene in the cigarette smoke.Compare sample with the Cigarette that does not pass through gamma-ray irradiation, carry out flue gas analysis and suction evaluation.The results are shown in following table.
| Project | The control sample detected value | Sample detection value of the present invention | Reduced rate (%) |
| Benzo [a] pyrene | 15.37 nanogram/ | 4.76 nanogram/ | 69.03 |
| Nicotine | 1.2 milligram/ | 0.5 milligram/ | 58.33 |
| Tar content | 15 milligrams/ | 8 milligrams/ | 46.67 |
| Suck evaluation | Sucking taste has certain variation, and excitant obviously diminishes | ||
Claims (3)
1, the processing method of benzo [a] pyrene content in a kind of reduction cigarette smoke is characterized in that finished cigarettes or box-packed cigarette are placed the gamma-rays radiation area, carries out gamma-ray irradiation.
2, the processing method of benzo [a] pyrene content in a kind of reduction cigarette smoke according to claim 1, it is characterized in that: the gamma-ray radiation source of employing is isotopes of cobalt-60 or caesium-137 or iridium-192 or selenium-75, and dose of radiation is 4KGy-40KGy.
3, the processing method of benzo [a] pyrene content in a kind of reduction cigarette smoke according to claim 1 is characterized in that: said tobacco product is to prop up or cigarettes through the cigarette after the cigarette machine cigarette.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031488323A CN1171547C (en) | 2003-06-13 | 2003-06-13 | Processing method for reducing benzo [ a ] pyrene content in cigarette smoke |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031488323A CN1171547C (en) | 2003-06-13 | 2003-06-13 | Processing method for reducing benzo [ a ] pyrene content in cigarette smoke |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1486643A CN1486643A (en) | 2004-04-07 |
| CN1171547C true CN1171547C (en) | 2004-10-20 |
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ID=34156284
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031488323A Expired - Fee Related CN1171547C (en) | 2003-06-13 | 2003-06-13 | Processing method for reducing benzo [ a ] pyrene content in cigarette smoke |
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| Country | Link |
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| CN (1) | CN1171547C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102578701A (en) * | 2012-02-21 | 2012-07-18 | 河南省科学院同位素研究所有限责任公司 | Method for reducing polyaromatic hydrocarbon content in tar of cigarette smoke |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102578697A (en) * | 2011-12-20 | 2012-07-18 | 江苏省农业科学院 | Irradiation degradation method for tobacco-specific nitrosamines in cigarette |
| CN102726828B (en) * | 2012-06-27 | 2013-05-01 | 广州华大生物科技有限公司 | Radiation control method for tobacco and tobacco products based on mathematical model guide |
| CN104013098A (en) * | 2013-11-21 | 2014-09-03 | 白云 | Handling device and method for reducing toxic and harmful substances in tobacco |
| CN104351945B (en) * | 2014-10-17 | 2016-01-20 | 云南中烟工业有限责任公司 | A kind of method and apparatus reducing benzo [a] pyrene precursor compound in pipe tobacco |
| CN105029695B (en) * | 2015-06-10 | 2018-11-13 | 云南中烟工业有限责任公司 | A method of using high energy electron beam modifying cigarette cellulose acetate filter stick |
| CN110214971B (en) * | 2019-07-11 | 2021-12-17 | 中国烟草总公司郑州烟草研究院 | Method for improving sensory quality of inferior tobacco leaves |
-
2003
- 2003-06-13 CN CNB031488323A patent/CN1171547C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102578701A (en) * | 2012-02-21 | 2012-07-18 | 河南省科学院同位素研究所有限责任公司 | Method for reducing polyaromatic hydrocarbon content in tar of cigarette smoke |
| CN102578701B (en) * | 2012-02-21 | 2013-07-10 | 河南省科学院同位素研究所有限责任公司 | Method for reducing polyaromatic hydrocarbon content in tar of cigarette smoke |
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| Publication number | Publication date |
|---|---|
| CN1486643A (en) | 2004-04-07 |
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