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CN117102812A - A method for producing aluminum alloy cold-rolled sheets for new energy vehicle power battery side panels - Google Patents

A method for producing aluminum alloy cold-rolled sheets for new energy vehicle power battery side panels Download PDF

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CN117102812A
CN117102812A CN202311061953.4A CN202311061953A CN117102812A CN 117102812 A CN117102812 A CN 117102812A CN 202311061953 A CN202311061953 A CN 202311061953A CN 117102812 A CN117102812 A CN 117102812A
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rolling
cleaning
percent
aluminum alloy
aluminum
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Inventor
梁新华
黄文辉
黄成安
廖贵朗
何沂桂
韦成强
杨宏宇
覃燕玲
庞凤
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Guangxi Guangtou Liuzhou Aluminum Industry Co ltd
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Guangxi Guangtou Liuzhou Aluminum Industry Co ltd
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Priority to CN202311061953.4A priority Critical patent/CN117102812A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P15/00Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • B21B1/24Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
    • B21B1/26Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process by hot-rolling, e.g. Steckel hot mill
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • B21B1/24Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
    • B21B1/28Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process by cold-rolling, e.g. Steckel cold mill
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B27/00Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
    • B21B27/02Shape or construction of rolls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/46Roll speed or drive motor control
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/004Heating the product
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/02Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
    • B21B45/0269Cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • B21B2001/221Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length by cold-rolling

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Geometry (AREA)
  • Metal Rolling (AREA)

Abstract

The invention discloses a production method of an aluminum alloy cold-rolled sheet for a side plate of a power battery of a new energy automobile, which comprises the following production processes: casting, sawing, milling, homogenizing, hot rolling, cold rolling, cleaning, annealing and finishing; the roller with the roughness of 0.25-0.30 um is used for cold rolling, aluminum ash generated in the rolling process can be reduced, the rolling speed of the finished pass is 150-200 mpm, the oil quantity on the surface of the outlet belt material of the rolling mill (the rolling oil is taken to the outlet of the rolling mill when the roller rotates at a high speed) can be reduced, and the effect of air purging of the outlet can be effectively improved (the time of purging through air per unit length is prolonged), so that the method provided by the invention has the following steps: the production process is short, the production cost is low, and the method is suitable for the production of products with various thicknesses, and has the effect of high surface cleanliness and high dyne value of the aluminum plate.

Description

一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法A method for producing aluminum alloy cold-rolled sheets for new energy vehicle power battery side panels

技术领域Technical field

本发明涉及铝合金板材加工技术领域,具体涉及一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法。The invention relates to the technical field of aluminum alloy plate processing, and specifically relates to a production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side plates.

背景技术Background technique

5083铝合金冷轧板材的常规生产工艺流程为:熔铸→均匀化→锯切→铣面→加热→热轧→冷轧(4道次)→清洗→退火→精整,这种工艺生产的5083铝合金冷轧板材表面铝灰较重,并且只能生产≥1.2mm的板材,对于1.2mm以下的板材需增加一个清洗工序,一个中间退火工序和一个冷轧工序,生产流程长且生产成本高。The conventional production process of 5083 aluminum alloy cold-rolled plates is: casting → homogenization → sawing → milling → heating → hot rolling → cold rolling (4 passes) → cleaning → annealing → finishing. The 5083 produced by this process The surface of aluminum alloy cold-rolled plates is heavy with aluminum ash, and only plates ≥1.2mm can be produced. For plates below 1.2mm, a cleaning process, an intermediate annealing process and a cold-rolling process need to be added. The production process is long and the production cost is high. .

新能源汽车动力电池侧板后续需进行热压绝缘膜处理,对于产品表面洁净度和达因值要求极高(达因值≥38dyne),其力学性能要求为抗拉强度275~350Mpa,屈服强度≥125Mpa,延伸率≥12%,90度折弯不开裂(折弯半径1.0t),成品厚度范围为0.9-1.5mm。The side panels of new energy vehicle power batteries need to be processed with hot-pressed insulating films. The requirements for product surface cleanliness and dyne value are extremely high (dyne value ≥ 38dyne). Its mechanical property requirements are tensile strength 275~350Mpa and yield strength. ≥125Mpa, elongation ≥12%, no cracking when bent at 90 degrees (bending radius 1.0t), finished product thickness range is 0.9-1.5mm.

中国专利(202110477492.3)公开了一种新能源汽车用5083-O态电池壳侧板的制备方法,其工艺流程为:熔铸→均匀化→锯切→铣面→加热→热轧→冷轧→中间退火→冷轧→清洗→退火→精整,并且其成品退火时采用氮气作为保护气氛进行退火,生产工艺流程长且生产成本极高。Chinese patent (202110477492.3) discloses a method for preparing 5083-O battery case side plates for new energy vehicles. The process flow is: casting → homogenization → sawing → milling → heating → hot rolling → cold rolling → intermediate Annealing → cold rolling → cleaning → annealing → finishing, and the finished product is annealed using nitrogen as a protective atmosphere. The production process is long and the production cost is extremely high.

中国专利(202211023842.X)公开了一种电池包铝板的制备方法及电池包铝板,主要生产流程为:熔铸→锯切→铣面→均匀化→热轧→冷轧→清洗→退火→精整,此方法铸锭需进行到435±5℃并保温4小时加515±5℃保温10小时的双级均匀化处理。其热轧坯料厚度为4.0~8.0mm,采用常规冷轧工艺生产需4道次,才能轧至成品厚度,生产时间较长,生产成本较高。另外冷轧轧制道次越多,轧制过程中产生的铝灰与铝板结合越紧密,进而影响清洗后的表面洁净度。其采用PE保护膜的剥离强度为0.35~0.47N/10mm,强度过高,撕掉PE保护膜后铝板表面会有大量残胶,进而导致热压绝缘膜不合格。Chinese patent (202211023842. , this method requires two-stage homogenization treatment in which the ingot is cast at 435±5℃ and kept at 4 hours and at 515±5℃ for 10 hours. The thickness of the hot-rolled billet is 4.0~8.0mm. The conventional cold rolling process requires 4 passes to reach the finished product thickness. The production time is long and the production cost is high. In addition, the more cold rolling passes, the closer the aluminum ash produced during the rolling process will be combined with the aluminum plate, which will affect the surface cleanliness after cleaning. The peel strength of the PE protective film is 0.35~0.47N/10mm, which is too high. After the PE protective film is removed, there will be a large amount of residual glue on the surface of the aluminum plate, which will lead to the failure of the hot-pressed insulation film.

发明内容Contents of the invention

针对现有技术的不足,本发明的目的是提供一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法,通过在气垫式连续热处理炉实施一阶退火,完成后重新卷取并进入箱式退火炉实施二阶退火,最终获得良好表面质量以及均匀、细小晶粒的完全退火状态铝合金薄板。In view of the shortcomings of the existing technology, the purpose of the present invention is to provide a production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side plates, by performing first-stage annealing in an air cushion type continuous heat treatment furnace, and then re-coiling and entering The box annealing furnace implements second-stage annealing, and finally obtains a fully annealed aluminum alloy sheet with good surface quality and uniform and fine grains.

为了实现上述目的,本发明采用的技术方案如下:一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法,所述方法包括如下步骤:熔铸→锯切→铣面→加热→热轧→冷轧→清洗→退火→矫平覆膜;In order to achieve the above object, the technical solution adopted by the present invention is as follows: a production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side panels, which method includes the following steps: casting → sawing → milling → heating → hot rolling →cold rolling→cleaning→annealing→leveling and coating;

所述熔铸步骤中,铝合金化学成分的质量百分数为:Si≤0.10%、Fe≤0.35%、Cu≤0.05%、Mn 0.40~0.50%、Mg 4.20~4.50%、Cr 0.05~0.10%、Zn≤0.15%、Ti≤0.15%、其它杂质元素单个≤0.05%、其它杂质元素合计≤0.15%,其余为Al;In the melting and casting step, the mass percentages of the chemical components of the aluminum alloy are: Si≤0.10%, Fe≤0.35%, Cu≤0.05%, Mn 0.40~0.50%, Mg 4.20~4.50%, Cr 0.05~0.10%, Zn≤ 0.15%, Ti ≤ 0.15%, other impurity elements individually ≤ 0.05%, other impurity elements in total ≤ 0.15%, the rest is Al;

所述加热步骤中,铸锭加热温度为500~520℃,保温时间为2~4小时;In the heating step, the ingot heating temperature is 500-520°C, and the holding time is 2-4 hours;

所述热轧步骤中,采用热连轧机轧制,热轧终轧温度为330~345℃,热轧卷坯厚度为2.5~4.0mm;In the hot rolling step, a hot rolling mill is used for rolling, the final hot rolling temperature is 330-345°C, and the thickness of the hot-rolled coil is 2.5-4.0mm;

所述冷轧步骤中,将热轧卷坯用粗糙度为0.25~0.30μm,机械凸度为0.15~0.20mm的轧辊轧至成品厚度,道次加工率为35~40%,成品道次轧制速度为150~200mpm;In the cold rolling step, the hot-rolled coil is rolled to the finished product thickness using a roller with a roughness of 0.25-0.30 μm and a mechanical crown of 0.15-0.20 mm. The pass processing rate is 35-40%. The finished product is rolled in a pass. The control speed is 150~200mpm;

所述清洗步骤中,铝卷在清洗机进行碱洗和水洗,碱液中游离碱度为0.7~1.5pt,碱液温度为50~60℃;In the cleaning step, the aluminum coil is washed with alkali and water in a cleaning machine. The free alkalinity in the alkali solution is 0.7-1.5pt, and the temperature of the alkali solution is 50-60°C;

所述退火步骤中,铝卷退火温度为320~350℃,保温时间为2~4小时;In the annealing step, the annealing temperature of the aluminum coil is 320-350°C, and the heat preservation time is 2-4 hours;

所述矫平覆膜步骤中,利用横切机将铝卷矫平覆膜后剪切成板材,铝卷塑性变形率为0.1~0.5%,所覆PE膜剥离强度为30~40g/25mm。In the step of leveling and coating, a cross-cutting machine is used to flatten and coat the aluminum coil and cut it into plates. The plastic deformation rate of the aluminum coil is 0.1 to 0.5%, and the peel strength of the covered PE film is 30 to 40g/25mm.

进一步地,所述熔铸步骤中,铝合金化学成分的质量百分数为:Si≤0.10%、Fe≤0.35%、Cu≤0.05%、Mn 0.45~0.50%、Mg 4.30~4.50%、Cr 0.07~0.10%、Zn≤0.15%、Ti≤0.15%、其它杂质元素单个≤0.05%、其它杂质元素合计≤0.15%,其余为Al。Further, in the melting and casting step, the mass percentage of the chemical composition of the aluminum alloy is: Si≤0.10%, Fe≤0.35%, Cu≤0.05%, Mn 0.45~0.50%, Mg 4.30~4.50%, Cr 0.07~0.10% , Zn ≤ 0.15%, Ti ≤ 0.15%, other impurity elements individually ≤ 0.05%, other impurity elements in total ≤ 0.15%, and the rest is Al.

进一步地,所述加热步骤中,铸锭加热温度为510~520℃,保温时间为3~4小时。Further, in the heating step, the ingot heating temperature is 510-520°C, and the heat preservation time is 3-4 hours.

进一步地,所述热轧步骤中,采用热连轧机轧制,热轧终轧温度为335~345℃,热轧卷坯厚度为2.8~4.0mm。Further, in the hot rolling step, a hot rolling mill is used for rolling, the final hot rolling temperature is 335-345°C, and the thickness of the hot-rolled coil is 2.8-4.0 mm.

进一步地,所述冷轧步骤中,将热轧卷坯用粗糙度为0.27~0.30μm,机械凸度为0.18~0.20mm的轧辊轧至成品厚度,道次加工率为36~40%,成品道次轧制速度为160~200mpm。Further, in the cold rolling step, the hot-rolled coil blank is rolled to the finished product thickness using a roll with a roughness of 0.27-0.30 μm and a mechanical crown of 0.18-0.20 mm. The pass processing rate is 36-40%, and the finished product is The rolling speed of each pass is 160~200mpm.

进一步地,所述清洗步骤中,铝卷在清洗机进行碱洗和水洗,碱液中游离碱度为0.8~1.5pt,碱液温度为55~60℃。Further, in the cleaning step, the aluminum coil is subjected to alkali washing and water washing in a cleaning machine. The free alkalinity in the alkali solution is 0.8-1.5pt, and the alkali solution temperature is 55-60°C.

进一步地,所述清洗步骤中,碱洗用碱液中还添加有2~5g/L的碱液清洗加强剂,所述碱液清洗加强剂由以下重量份的组分组成:六偏磷酸钠20~25份、三聚磷酸钠20~25份、岩藻糖8~12份。Further, in the cleaning step, 2 to 5 g/L of alkali cleaning enhancer is added to the alkali cleaning alkali solution. The alkali cleaning enhancer consists of the following components by weight: sodium hexametaphosphate. 20 to 25 parts of sodium tripolyphosphate, 8 to 12 parts of fucose.

进一步地,所述清洗步骤中,碱洗用碱液中还添加有2~5g/L的碱液清洗加强剂,所述碱液清洗加强剂由以下重量份的组分组成:六偏磷酸钠22~25份、三聚磷酸钠23~25份、岩藻糖10~12份。Further, in the cleaning step, 2 to 5 g/L of alkali cleaning enhancer is added to the alkali cleaning alkali solution. The alkali cleaning enhancer consists of the following components by weight: sodium hexametaphosphate. 22 to 25 parts of sodium tripolyphosphate, 23 to 25 parts of sodium tripolyphosphate, and 10 to 12 parts of fucose.

进一步地,所述退火步骤中,铝卷退火温度为330~350℃,保温时间为3~4小时。Further, in the annealing step, the annealing temperature of the aluminum coil is 330-350°C, and the holding time is 3-4 hours.

进一步地,所述矫平覆膜步骤中,利用横切机将铝卷矫平覆膜后剪切成板材,铝卷塑性变形率为0.2~0.5%,所覆PE膜剥离强度为35~40g/25mm。Furthermore, in the step of flattening and coating, a cross-cutting machine is used to flatten and coat the aluminum roll and then cut it into plates. The plastic deformation rate of the aluminum roll is 0.2-0.5%, and the peeling strength of the PE film is 35-40g. /25mm.

本发明一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法,新能源汽车动力电池侧板后续加工工序为冲压落料和折弯,对材料的抗冲压性能要求不高(新能源汽车动力电池壳体须进行深冲成型,对材料的抗冲压性能要求高),铸锭仅需加热至500℃以上保温2~4小时以保证热连轧的顺利生产即可,现有技术主要通过将热轧坯料厚度设计为2.5~4.0mm,同时冷轧用机械凸度为0.15mm的轧辊轧至成品厚度,道次加工率为35~40%,以实现2道次轧至成品厚度,2道次轧至后的铝板表面纹路较粗糙,无法满足产品表面质量要求,而3~4道次轧至成品厚度,轧制道次较多,轧制过程中产生的铝灰与铝板结合紧密,影响清洗后的表面洁净度;本发明用粗糙度为0.25~0.30um的轧辊进行冷轧,可减少轧制过程产生的铝灰,成品道次轧制速度为150~200mpm可减少轧机出口带材的表面带油量(减少轧辊高速转动时将轧制油带到轧机出口处)也能有效提高出口空气吹扫的效果(延长单位长度通过空气吹扫的时间),使得本发明方法具有:生产流程短,生产成本低,适用于各种厚度产品的生产,铝板表面洁净度和达因值高的效果。The present invention is a production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side panels. The subsequent processing steps of the new energy vehicle power battery side panels are stamping blanking and bending, and the requirements for the stamping resistance of the material are not high (new energy The automobile power battery casing must be deep-drawn, which requires high stamping resistance of the material). The ingot only needs to be heated to above 500°C and kept for 2 to 4 hours to ensure the smooth production of hot continuous rolling. The existing technology mainly By designing the thickness of the hot-rolled billet to be 2.5-4.0mm, and simultaneously rolling it to the finished product thickness using a roll with a mechanical crown of 0.15mm for cold rolling, the pass processing rate is 35-40% to achieve 2 passes of rolling to the finished product thickness. The surface texture of the aluminum plate after 2 passes is rough and cannot meet the product surface quality requirements. However, after 3 to 4 passes are rolled to the finished product thickness, there are many rolling passes, and the aluminum ash produced during the rolling process is closely combined with the aluminum plate. , affecting the surface cleanliness after cleaning; the present invention uses rollers with a roughness of 0.25-0.30um for cold rolling, which can reduce the aluminum ash produced during the rolling process. The rolling speed of the finished product pass is 150-200mpm, which can reduce the exit belt of the rolling mill. The amount of oil on the surface of the material (reduces the rolling oil brought to the exit of the rolling mill when the roll rotates at high speed) can also effectively improve the effect of the outlet air purge (extend the time for air purging per unit length), so that the method of the present invention has: The production process is short, the production cost is low, it is suitable for the production of products of various thicknesses, and the surface cleanliness and dyne value of the aluminum plate are high.

本发明一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法,清洗步骤中,碱洗用碱液中还添加特制的碱液清洗加强剂,清洗效果更好,能大幅降低碱液用量,还起到提高板材达因值的作用。The present invention is a production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side panels. In the cleaning step, a special alkali cleaning enhancer is added to the alkali cleaning alkali solution. The cleaning effect is better and the alkali solution can be greatly reduced. The dosage also plays a role in increasing the dyne value of the board.

说明书附图Instructions with pictures

图1为本发明铝灰等级检测判定标准图。Figure 1 is a standard diagram for aluminum gray level detection and determination according to the present invention.

图2为本发明对比例1制备得到的撕膜后的板材图片;板材表面有残胶,表面残胶导致达因值不合格。Figure 2 is a picture of the plate after tearing off the film prepared in Comparative Example 1 of the present invention; there is residual glue on the surface of the plate, and the residual glue on the surface causes the dyne value to be unqualified.

具体实施方式Detailed ways

下面的实施例可以帮助本领域的技术人员更全面地理解本发明,但不可以以任何方式限制本发明。The following examples can help those skilled in the art understand the present invention more comprehensively, but cannot limit the present invention in any way.

本发明一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法,铝灰等级检测方法为:将一张折叠成约50*50mm规格的纸巾夹于手指处,将纸巾放于铝卷表面一侧,向另一侧移动,到达另一侧后沿原路径返回到开始侧,检测的力度以纸巾紧压带材表面为准。观察纸巾上铝灰的分布,比对标准图片对铝粉的严重程度进行判级;铝灰等级检测判定标准如图1所示。The present invention is a production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side panels. The aluminum gray level detection method is: clamp a paper towel folded into a size of about 50*50mm between your fingers, and place the paper towel on the aluminum roll. One side of the surface, move to the other side, and then return to the starting side along the original path after reaching the other side. The strength of the detection is based on the paper towel pressing the surface of the strip. Observe the distribution of aluminum dust on the paper towel, and compare the severity of the aluminum dust with the standard picture; the aluminum dust grade detection and determination standards are shown in Figure 1.

实施例1:Example 1:

本实施例为一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法,包括以下生产流程:熔铸→锯切→铣面→加热→热轧→冷轧→清洗→退火→矫平覆膜。This embodiment is a production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side panels, which includes the following production process: casting → sawing → milling → heating → hot rolling → cold rolling → cleaning → annealing → leveling and coating membrane.

(1)熔铸:熔铸后铸锭的化学元素质量百分数为(1) Casting: The mass percentage of chemical elements in the ingot after melting and casting is

(2)加热:铸锭加热温度为520℃,保温时间为2小时。(2) Heating: The heating temperature of the ingot is 520°C, and the holding time is 2 hours.

(3)热轧:热连轧机轧制,热轧终轧温度为344℃,热轧卷坯厚度为2.5mm。(3) Hot rolling: hot rolling mill, the final hot rolling temperature is 344°C, and the thickness of the hot rolled coil is 2.5mm.

(4)冷轧:将热轧卷坯用粗糙度为0.25um,机械凸度为0.15mm的轧辊轧至成品厚度0.9mm,轧制道次为2.5-1.5-0.9mm,道次加工率为40%,成品道次轧制速度为200mpm。(4) Cold rolling: Roll the hot-rolled coil with a roll with a roughness of 0.25um and a mechanical crown of 0.15mm to a finished product thickness of 0.9mm. The rolling passes are 2.5-1.5-0.9mm. The processing rate of each pass is 40%, and the rolling speed of the finished product pass is 200mpm.

(5)清洗:铝卷在清洗机进行碱洗和水洗,碱液中游离碱度为0.7pt,碱液温度为50℃。(5) Cleaning: The aluminum coil is washed with alkali and water in a cleaning machine. The free alkalinity in the alkali solution is 0.7pt, and the temperature of the alkali solution is 50°C.

(6)退火:铝卷退火温度为320℃,保温时间为2小时;(6) Annealing: The annealing temperature of the aluminum coil is 320°C, and the holding time is 2 hours;

(7)矫平覆膜:利用横切机将铝卷矫平覆膜后剪切成板材,铝卷塑性变形率为0.49%,所覆PE膜剥离强度为30g/25mm。(7) Leveling and coating: Use a cross-cutting machine to flatten and coat the aluminum coil and cut it into plates. The plastic deformation rate of the aluminum coil is 0.49%, and the peeling strength of the covered PE film is 30g/25mm.

从上表可知,按照本实施例生产的新能源汽车动力电池侧板用铝合金冷轧板材表面洁净度达到1级,撕膜后达因值达到42dyne新能源汽车动力电池侧板用铝合金冷轧板材要求,并且铸锭均热时间为2小时,冷轧轧制道次为2道次,生产时间短,生产成本低。It can be seen from the above table that the surface cleanliness of the aluminum alloy cold-rolled plate for new energy vehicle power battery side panels produced according to this embodiment reaches level 1, and the dyne value after tearing off the film reaches 42dyne. The rolling plate requirements, and the ingot soaking time is 2 hours, and the cold rolling passes are 2 passes, the production time is short, and the production cost is low.

实施例2:Example 2:

本实施例为一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法,包括以下生产流程:熔铸→锯切→铣面→加热→热轧→冷轧→清洗→退火→矫平覆膜。This embodiment is a production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side panels, which includes the following production process: casting → sawing → milling → heating → hot rolling → cold rolling → cleaning → annealing → leveling and coating membrane.

Si≤0.10%、Fe≤0.35%、Cu≤0.05%、Mn 0.40~0.50%、Mg 4.20~4.50%、Cr0.05~0.10%、Zn≤0.15%、Ti≤0.15%Si≤0.10%, Fe≤0.35%, Cu≤0.05%, Mn 0.40~0.50%, Mg 4.20~4.50%, Cr0.05~0.10%, Zn≤0.15%, Ti≤0.15%

(1)熔铸:熔铸后铸锭的化学元素质量百分数为(1) Casting: The mass percentage of chemical elements in the ingot after melting and casting is

(2)加热:铸锭加热温度为500℃,保温时间为4小时。(2) Heating: The heating temperature of the ingot is 500°C, and the holding time is 4 hours.

(3)热轧:热连轧机轧制,热轧终轧温度为332℃,热轧卷坯厚度为4.0mm。(3) Hot rolling: hot rolling mill, the final hot rolling temperature is 332°C, and the thickness of the hot rolled coil is 4.0mm.

(4)冷轧:将热轧卷坯用粗糙度为0.30um,机械凸度为0.20mm的轧辊轧至成品厚度1.5mm,轧制道次为3.5-2.2-1.5mm,道次加工率为37.5~40%,成品道次轧制速度为150mpm。(4) Cold rolling: Roll the hot-rolled coil with a roll with a roughness of 0.30um and a mechanical crown of 0.20mm to a finished product thickness of 1.5mm. The rolling passes are 3.5-2.2-1.5mm. The processing rate of each pass is 37.5~40%, and the rolling speed of the finished product is 150mpm.

(5)清洗:铝卷在清洗机进行碱洗和水洗,碱液中游离碱度为1.5pt,碱液温度为60℃。(5) Cleaning: The aluminum coil is washed with alkali and water in a cleaning machine. The free alkalinity in the alkali solution is 1.5pt, and the alkali solution temperature is 60°C.

(6)退火:铝卷退火温度为350℃,保温时间为4小时;(6) Annealing: The annealing temperature of the aluminum coil is 350°C, and the holding time is 4 hours;

(7)矫平覆膜:利用横切机将铝卷矫平覆膜后剪切成板材,铝卷塑性变形率为0.12%,所覆PE膜剥离强度为40g/25mm。(7) Leveling and coating: Use a cross-cutting machine to flatten and coat the aluminum coil and then cut it into plates. The plastic deformation rate of the aluminum coil is 0.12%, and the peeling strength of the PE film is 40g/25mm.

从上表可知,按照本实施例生产的新能源汽车动力电池侧板用铝合金冷轧板材表面洁净度达到1级,撕膜后达因值达到40dyne新能源汽车动力电池侧板用铝合金冷轧板材要求,并且铸锭均热时间为4小时,冷轧轧制道次为2道次,生产时间短,生产成本低。It can be seen from the above table that the surface cleanliness of the aluminum alloy cold-rolled plate for new energy vehicle power battery side panels produced according to this embodiment reaches level 1, and the dyne value after tearing off the film reaches 40dyne. The rolling plate requirements, and the ingot soaking time is 4 hours, and the cold rolling passes are 2 passes, the production time is short, and the production cost is low.

实施例3:Example 3:

本实施例为一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法,包括以下生产流程:熔铸→锯切→铣面→加热→热轧→冷轧→清洗→退火→矫平覆膜。This embodiment is a production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side panels, which includes the following production process: casting → sawing → milling → heating → hot rolling → cold rolling → cleaning → annealing → leveling and coating membrane.

Si≤0.10%、Fe≤0.35%、Cu≤0.05%、Mn 0.40~0.50%、Mg 4.20~4.50%、Cr0.05~0.10%、Zn≤0.15%、Ti≤0.15%Si≤0.10%, Fe≤0.35%, Cu≤0.05%, Mn 0.40~0.50%, Mg 4.20~4.50%, Cr0.05~0.10%, Zn≤0.15%, Ti≤0.15%

(1)熔铸:熔铸后铸锭的化学元素质量百分数为(1) Casting: The mass percentage of chemical elements in the ingot after melting and casting is

(2)加热:铸锭加热温度为510℃,保温时间为3小时。(2) Heating: The heating temperature of the ingot is 510°C, and the holding time is 3 hours.

(3)热轧:热连轧机轧制,热轧终轧温度为338℃,热轧卷坯厚度为3.0mm。(3) Hot rolling: hot rolling mill, the final hot rolling temperature is 338°C, and the thickness of the hot rolled coil is 3.0mm.

(4)冷轧:将热轧卷坯用粗糙度为0.28um,机械凸度为0.18mm的轧辊轧至成品厚度1.2mm,轧制道次为3.0-1.9-1.2mm,道次加工率为36.7~36.8%,成品道次轧制速度为180mpm。(4) Cold rolling: Roll the hot-rolled coil with a roll with a roughness of 0.28um and a mechanical crown of 0.18mm to a finished product thickness of 1.2mm. The rolling passes are 3.0-1.9-1.2mm. The processing rate of each pass is 36.7~36.8%, and the rolling speed of the finished product is 180mpm.

(5)清洗:铝卷在清洗机进行碱洗和水洗,碱液中游离碱度为1.0pt,碱液温度为55℃。(5) Cleaning: The aluminum coil is washed with alkali and water in a cleaning machine. The free alkalinity in the alkali solution is 1.0pt, and the alkali solution temperature is 55°C.

(6)退火:铝卷退火温度为330℃,保温时间为3小时;(6) Annealing: The annealing temperature of the aluminum coil is 330°C, and the holding time is 3 hours;

(7)矫平覆膜:利用横切机将铝卷矫平覆膜后剪切成板材,铝卷塑性变形率为0.24%,所覆PE膜剥离强度为35g/25mm。(7) Leveling and coating: Use a cross-cutting machine to flatten and coat the aluminum coil and then cut it into plates. The plastic deformation rate of the aluminum coil is 0.24%, and the peeling strength of the covered PE film is 35g/25mm.

从上表可知,按照本实施例生产的新能源汽车动力电池侧板用铝合金冷轧板材表面洁净度达到1级,撕膜后达因值达到41dyne新能源汽车动力电池侧板用铝合金冷轧板材要求,并且铸锭均热时间为3小时,冷轧轧制道次为2道次,生产时间短,生产成本低。It can be seen from the above table that the surface cleanliness of the aluminum alloy cold-rolled plate for new energy vehicle power battery side panels produced according to this embodiment reaches level 1, and the dyne value after tearing off the film reaches 41dyne. The rolling plate requirements, and the ingot soaking time is 3 hours, and the cold rolling passes are 2 passes, the production time is short, and the production cost is low.

实施例4:Example 4:

本实施例为一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法,包括以下生产流程:熔铸→锯切→铣面→加热→热轧→冷轧→清洗→退火→矫平覆膜。This embodiment is a production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side panels, which includes the following production process: casting → sawing → milling → heating → hot rolling → cold rolling → cleaning → annealing → leveling and coating membrane.

(1)熔铸:熔铸后铸锭的化学元素质量百分数为(1) Casting: The mass percentage of chemical elements in the ingot after melting and casting is

(2)加热:铸锭加热温度为520℃,保温时间为2小时。(2) Heating: The heating temperature of the ingot is 520°C, and the holding time is 2 hours.

(3)热轧:热连轧机轧制,热轧终轧温度为344℃,热轧卷坯厚度为2.5mm。(3) Hot rolling: hot rolling mill, the final hot rolling temperature is 344°C, and the thickness of the hot rolled coil is 2.5mm.

(4)冷轧:将热轧卷坯用粗糙度为0.25um,机械凸度为0.15mm的轧辊轧至成品厚度0.9mm,轧制道次为2.5-1.5-0.9mm,道次加工率为40%,成品道次轧制速度为200mpm。(4) Cold rolling: Roll the hot-rolled coil with a roll with a roughness of 0.25um and a mechanical crown of 0.15mm to a finished product thickness of 0.9mm. The rolling passes are 2.5-1.5-0.9mm. The processing rate of each pass is 40%, and the rolling speed of the finished product pass is 200mpm.

(5)清洗:铝卷在清洗机进行碱洗和水洗,碱液中游离碱度为0.7pt,碱液温度为50℃;碱洗用碱液中还添加有2g/L的碱液清洗加强剂,所述碱液清洗加强剂由以下重量份的组分组成:六偏磷酸钠20份、三聚磷酸钠20份、岩藻糖8份。(5) Cleaning: The aluminum coil is subjected to alkali cleaning and water washing in a cleaning machine. The free alkalinity in the alkali solution is 0.7pt, and the alkali solution temperature is 50°C; 2g/L alkali solution is added to the alkali cleaning solution to strengthen cleaning. The alkali cleaning enhancer is composed of the following components by weight: 20 parts of sodium hexametaphosphate, 20 parts of sodium tripolyphosphate, and 8 parts of fucose.

(6)退火:铝卷退火温度为320℃,保温时间为2小时;(6) Annealing: The annealing temperature of the aluminum coil is 320°C, and the holding time is 2 hours;

(7)矫平覆膜:利用横切机将铝卷矫平覆膜后剪切成板材,铝卷塑性变形率为0.49%,所覆PE膜剥离强度为30g/25mm。(7) Leveling and coating: Use a cross-cutting machine to flatten and coat the aluminum coil and cut it into plates. The plastic deformation rate of the aluminum coil is 0.49%, and the peeling strength of the covered PE film is 30g/25mm.

从上表可知,按照本实施例生产的新能源汽车动力电池侧板用铝合金冷轧板材表面洁净度达到1级,撕膜后达因值达到42dyne新能源汽车动力电池侧板用铝合金冷轧板材要求,并且铸锭均热时间为2小时,冷轧轧制道次为2道次,生产时间短,生产成本低。It can be seen from the above table that the surface cleanliness of the aluminum alloy cold-rolled plate for new energy vehicle power battery side panels produced according to this embodiment reaches level 1, and the dyne value after tearing off the film reaches 42dyne. The rolling plate requirements, and the ingot soaking time is 2 hours, and the cold rolling passes are 2 passes, the production time is short, and the production cost is low.

实施例5:Example 5:

本实施例为一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法,包括以下生产流程:熔铸→锯切→铣面→加热→热轧→冷轧→清洗→退火→矫平覆膜。This embodiment is a production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side panels, which includes the following production process: casting → sawing → milling → heating → hot rolling → cold rolling → cleaning → annealing → leveling and coating membrane.

Si≤0.10%、Fe≤0.35%、Cu≤0.05%、Mn 0.40~0.50%、Mg 4.20~4.50%、Cr0.05~0.10%、Zn≤0.15%、Ti≤0.15%Si≤0.10%, Fe≤0.35%, Cu≤0.05%, Mn 0.40~0.50%, Mg 4.20~4.50%, Cr0.05~0.10%, Zn≤0.15%, Ti≤0.15%

(1)熔铸:熔铸后铸锭的化学元素质量百分数为(1) Casting: The mass percentage of chemical elements in the ingot after melting and casting is

(2)加热:铸锭加热温度为500℃,保温时间为4小时。(2) Heating: The heating temperature of the ingot is 500°C, and the holding time is 4 hours.

(3)热轧:热连轧机轧制,热轧终轧温度为332℃,热轧卷坯厚度为4.0mm。(3) Hot rolling: hot rolling mill, the final hot rolling temperature is 332°C, and the thickness of the hot rolled coil is 4.0mm.

(4)冷轧:将热轧卷坯用粗糙度为0.30um,机械凸度为0.20mm的轧辊轧至成品厚度1.5mm,轧制道次为3.5-2.2-1.5mm,道次加工率为37.5~40%,成品道次轧制速度为150mpm。(4) Cold rolling: Roll the hot-rolled coil with a roll with a roughness of 0.30um and a mechanical crown of 0.20mm to a finished product thickness of 1.5mm. The rolling passes are 3.5-2.2-1.5mm. The processing rate of each pass is 37.5~40%, and the rolling speed of the finished product is 150mpm.

(5)清洗:铝卷在清洗机进行碱洗和水洗,碱液中游离碱度为1.5pt,碱液温度为60℃;碱洗用碱液中还添加有5g/L的碱液清洗加强剂,所述碱液清洗加强剂由以下重量份的组分组成:六偏磷酸钠25份、三聚磷酸钠25份、岩藻糖12份。(5) Cleaning: The aluminum coil is subjected to alkali cleaning and water washing in a cleaning machine. The free alkalinity in the alkali solution is 1.5pt, and the alkali solution temperature is 60°C; 5g/L alkali solution is added to the alkali cleaning solution to strengthen cleaning. The alkali cleaning enhancer is composed of the following components by weight: 25 parts of sodium hexametaphosphate, 25 parts of sodium tripolyphosphate, and 12 parts of fucose.

(6)退火:铝卷退火温度为350℃,保温时间为4小时;(6) Annealing: The annealing temperature of the aluminum coil is 350°C, and the holding time is 4 hours;

(7)矫平覆膜:利用横切机将铝卷矫平覆膜后剪切成板材,铝卷塑性变形率为0.12%,所覆PE膜剥离强度为40g/25mm。(7) Leveling and coating: Use a cross-cutting machine to flatten and coat the aluminum coil and then cut it into plates. The plastic deformation rate of the aluminum coil is 0.12%, and the peeling strength of the PE film is 40g/25mm.

从上表可知,按照本实施例生产的新能源汽车动力电池侧板用铝合金冷轧板材表面洁净度达到1级,撕膜后达因值达到40dyne新能源汽车动力电池侧板用铝合金冷轧板材要求,并且铸锭均热时间为4小时,冷轧轧制道次为2道次,生产时间短,生产成本低。It can be seen from the above table that the surface cleanliness of the aluminum alloy cold-rolled plate for new energy vehicle power battery side panels produced according to this embodiment reaches level 1, and the dyne value after tearing off the film reaches 40dyne. The rolling plate requirements, and the ingot soaking time is 4 hours, and the cold rolling passes are 2 passes, the production time is short, and the production cost is low.

实施例6:Example 6:

本实施例为一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法,包括以下生产流程:熔铸→锯切→铣面→加热→热轧→冷轧→清洗→退火→矫平覆膜。This embodiment is a production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side panels, which includes the following production process: casting → sawing → milling → heating → hot rolling → cold rolling → cleaning → annealing → leveling and coating membrane.

Si≤0.10%、Fe≤0.35%、Cu≤0.05%、Mn 0.40~0.50%、Mg 4.20~4.50%、Cr0.05~0.10%、Zn≤0.15%、Ti≤0.15%Si≤0.10%, Fe≤0.35%, Cu≤0.05%, Mn 0.40~0.50%, Mg 4.20~4.50%, Cr0.05~0.10%, Zn≤0.15%, Ti≤0.15%

(1)熔铸:熔铸后铸锭的化学元素质量百分数为(1) Casting: The mass percentage of chemical elements in the ingot after melting and casting is

(2)加热:铸锭加热温度为510℃,保温时间为3小时。(2) Heating: The heating temperature of the ingot is 510°C, and the holding time is 3 hours.

(3)热轧:热连轧机轧制,热轧终轧温度为338℃,热轧卷坯厚度为3.0mm。(3) Hot rolling: hot rolling mill, the final hot rolling temperature is 338°C, and the thickness of the hot rolled coil is 3.0mm.

(4)冷轧:将热轧卷坯用粗糙度为0.28um,机械凸度为0.18mm的轧辊轧至成品厚度1.2mm,轧制道次为3.0-1.9-1.2mm,道次加工率为36.7~36.8%,成品道次轧制速度为180mpm。(4) Cold rolling: Roll the hot-rolled coil with a roll with a roughness of 0.28um and a mechanical crown of 0.18mm to a finished product thickness of 1.2mm. The rolling passes are 3.0-1.9-1.2mm. The processing rate of each pass is 36.7~36.8%, and the rolling speed of the finished product is 180mpm.

(5)清洗:铝卷在清洗机进行碱洗和水洗,碱液中游离碱度为1.0pt,碱液温度为55℃;碱洗用碱液中还添加有4g/L的碱液清洗加强剂,所述碱液清洗加强剂由以下重量份的组分组成:六偏磷酸钠22份、三聚磷酸钠23份、岩藻糖10份。(5) Cleaning: The aluminum coil is subjected to alkali cleaning and water washing in a cleaning machine. The free alkalinity in the alkali solution is 1.0pt, and the alkali solution temperature is 55°C; 4g/L alkali solution is added to the alkali cleaning solution to strengthen cleaning. The alkali cleaning enhancer is composed of the following components by weight: 22 parts of sodium hexametaphosphate, 23 parts of sodium tripolyphosphate, and 10 parts of fucose.

(6)退火:铝卷退火温度为330℃,保温时间为3小时;(6) Annealing: The annealing temperature of the aluminum coil is 330°C, and the holding time is 3 hours;

(7)矫平覆膜:利用横切机将铝卷矫平覆膜后剪切成板材,铝卷塑性变形率为0.24%,所覆PE膜剥离强度为35g/25mm。(7) Leveling and coating: Use a cross-cutting machine to flatten and coat the aluminum coil and then cut it into plates. The plastic deformation rate of the aluminum coil is 0.24%, and the peeling strength of the covered PE film is 35g/25mm.

从上表可知,按照本实施例生产的新能源汽车动力电池侧板用铝合金冷轧板材表面洁净度达到1级,撕膜后达因值达到41dyne新能源汽车动力电池侧板用铝合金冷轧板材要求,并且铸锭均热时间为3小时,冷轧轧制道次为2道次,生产时间短,生产成本低。It can be seen from the above table that the surface cleanliness of the aluminum alloy cold-rolled plate for new energy vehicle power battery side panels produced according to this embodiment reaches level 1, and the dyne value after tearing off the film reaches 41dyne. The rolling plate requirements, and the ingot soaking time is 3 hours, and the cold rolling passes are 2 passes, the production time is short, and the production cost is low.

对比例1Comparative example 1

本实施例为一种5083铝合金冷轧板材生产方法,包括以下生产流程:熔铸→锯切→铣面→均匀化→热轧→冷轧→清洗→退火→精整。This embodiment is a production method of 5083 aluminum alloy cold-rolled plates, which includes the following production process: casting → sawing → milling → homogenization → hot rolling → cold rolling → cleaning → annealing → finishing.

(1)熔铸:熔铸后铸锭的化学元素质量百分数为(1) Casting: The mass percentage of chemical elements in the ingot after melting and casting is

(2)均匀化:铸锭加热至520℃后保温10小时。(2) Homogenization: The ingot is heated to 520°C and then kept warm for 10 hours.

(3)热轧:热轧终轧温度为335℃,热轧坯料厚度4.0mm。(3) Hot rolling: The final rolling temperature of hot rolling is 335°C, and the thickness of the hot-rolled billet is 4.0mm.

(4)冷轧:将热轧坯料轧至1.0mm,轧制道次为4.0-2.8-1.96-1.37-1.0mm。(4) Cold rolling: Roll the hot-rolled billet to 1.0mm, and the rolling passes are 4.0-2.8-1.96-1.37-1.0mm.

(5)精整:利用横切机将铝卷矫平覆膜后剪切成板材,所覆PE膜剥离强度为50g/25mm。(5) Finishing: Use a cross-cutting machine to flatten the aluminum coil and coat it with film and then cut it into plates. The peel strength of the PE film covered is 50g/25mm.

从上表数据可知,常规工艺生产的5083铝合金冷轧板材铸锭保温时间需10小时,冷轧轧制道次为4道次,成品表面洁净度为2级,撕膜后达因值为36dyne,并且撕膜后铝板表面有残胶。该工艺生产工艺流程长,生产成本高,表面质量无法满足新能源汽车动力电池侧板用铝合金冷轧板材要求。From the data in the above table, it can be seen that the heat preservation time of 5083 aluminum alloy cold-rolled plate ingots produced by conventional processes is 10 hours, the number of cold rolling passes is 4, the surface cleanliness of the finished product is level 2, and the dyne value after tearing off the film is 36dyne, and there is residual glue on the surface of the aluminum plate after peeling off the film. The production process of this process is long, the production cost is high, and the surface quality cannot meet the requirements of aluminum alloy cold-rolled sheets for new energy vehicle power battery side panels.

由上述检测结果可知,本发明一种新能源汽车动力电池侧板用铝合金冷轧板材生产方法,包括以下生产流程:熔铸→锯切→铣面→均匀化→热轧→冷轧→清洗→退火→精整;用粗糙度为0.25~0.30um的轧辊进行冷轧,可减少轧制过程产生的铝灰,成品道次轧制速度为150~200mpm可减少轧机出口带材的表面带油量(减少轧辊高速转动时将轧制油带到轧机出口处)也能有效提高出口空气吹扫的效果(延长单位长度通过空气吹扫的时间),使得本发明方法具有:生产流程短,生产成本低,适用于各种厚度产品的生产,铝板表面洁净度和达因值高的效果;清洗步骤中,碱洗用碱液中还添加特制的碱液清洗加强剂,清洗效果更好,能大幅降低碱液用量,还起到提高板材达因值的作用。It can be seen from the above test results that the production method of aluminum alloy cold-rolled plates for new energy vehicle power battery side panels of the present invention includes the following production process: casting → sawing → milling → homogenization → hot rolling → cold rolling → cleaning → Annealing → finishing; cold rolling with rolls with a roughness of 0.25~0.30um can reduce the aluminum ash produced during the rolling process. The rolling speed of the finished product pass is 150~200mpm, which can reduce the amount of oil on the surface of the strip at the outlet of the rolling mill. (Reduce the rolling oil being brought to the exit of the rolling mill when the roll rotates at high speed) It can also effectively improve the effect of the outlet air purge (prolong the time of air purging per unit length), so that the method of the present invention has the following advantages: short production process and low production cost Low, suitable for the production of products of various thicknesses, the surface cleanliness and dyne value of the aluminum plate are high; in the cleaning step, a special alkali cleaning enhancer is added to the alkali cleaning alkali solution, which has a better cleaning effect and can significantly Reducing the amount of alkali solution also plays a role in increasing the dyne value of the board.

虽然,上文中已经用一般性说明及具体实施方案对本发明作了详尽的描述,但在本发明基础上,可以对之作一些修改或改进,这对本领域技术人员而言是显而易见的。因此,在不偏离本发明精神的基础上所做的这些修改或改进,均属于本发明要求保护的范围。Although the present invention has been described in detail with general descriptions and specific embodiments above, it is obvious to those skilled in the art that some modifications or improvements can be made based on the present invention. Therefore, these modifications or improvements made without departing from the spirit of the present invention all fall within the scope of protection claimed by the present invention.

Claims (10)

1. The production method of the aluminum alloy cold-rolled sheet for the side plate of the power battery of the new energy automobile is characterized by comprising the following steps: casting, sawing, milling faces, heating, hot rolling, cold rolling, cleaning, annealing and leveling the coating film;
in the casting step, the aluminum alloy comprises the following chemical components in percentage by mass: less than or equal to 0.10 percent of Si, less than or equal to 0.35 percent of Fe, less than or equal to 0.05 percent of Cu, 0.40 to 0.50 percent of Mn, 4.20 to 4.50 percent of Mg, 0.05 to 0.10 percent of Cr, less than or equal to 0.15 percent of Zn, less than or equal to 0.15 percent of Ti, less than or equal to 0.05 percent of other impurity elements, less than or equal to 0.15 percent of other impurity elements in total, and the balance of Al;
in the heating step, the heating temperature of the cast ingot is 500-520 ℃ and the heat preservation time is 2-4 hours;
in the hot rolling step, a hot continuous rolling mill is adopted for rolling, the hot rolling finishing temperature is 330-345 ℃, and the thickness of a hot rolled coil blank is 2.5-4.0 mm;
in the cold rolling step, the hot rolled coil blank is rolled to the thickness of a finished product by a roller with the roughness of 0.25-0.30 mu m and the mechanical convexity of 0.15-0.20 mm, the pass processing rate is 35-40%, and the pass rolling speed of the finished product is 150-200 mpm;
in the cleaning step, the aluminum coil is subjected to alkaline cleaning and water washing in a cleaning machine, the free alkalinity in alkaline solution is 0.7-1.5 pt, and the temperature of the alkaline solution is 50-60 ℃;
in the annealing step, the annealing temperature of the aluminum coil is 320-350 ℃, and the heat preservation time is 2-4 hours;
in the leveling and laminating step, a transverse cutting machine is used for leveling and laminating an aluminum roll, then the aluminum roll is sheared into a plate, the plastic deformation rate of the aluminum roll is 0.1-0.5%, and the peel strength of the PE film is 30-40 g/25mm.
2. The method for producing an aluminum alloy cold-rolled sheet for a power battery side plate of a new energy automobile according to claim 1, wherein in the casting step, the aluminum alloy comprises the following chemical components in percentage by mass: less than or equal to 0.10 percent of Si, less than or equal to 0.35 percent of Fe, less than or equal to 0.05 percent of Cu, 0.45 to 0.50 percent of Mn, 4.30 to 4.50 percent of Mg, 0.07 to 0.10 percent of Cr, less than or equal to 0.15 percent of Zn, less than or equal to 0.15 percent of Ti, less than or equal to 0.05 percent of other impurity elements, less than or equal to 0.15 percent of other impurity elements in total, and the balance of Al.
3. The method for producing aluminum alloy cold-rolled sheet for power battery side plate of new energy automobile according to claim 1, wherein in the heating step, the heating temperature of the cast ingot is 510-520 ℃ and the heat preservation time is 3-4 hours.
4. The method for producing an aluminum alloy cold-rolled sheet for a power battery side plate of a new energy automobile according to claim 1, wherein in the hot rolling step, a hot continuous rolling mill is used for rolling, the hot rolling finishing temperature is 335-345 ℃, and the thickness of a hot rolled coil is 2.8-4.0 mm.
5. The method for producing an aluminum alloy cold-rolled sheet for a side plate of a power battery of a new energy automobile according to claim 1, wherein in the cold rolling step, a hot-rolled coil blank is rolled to a finished product thickness by a roll with a roughness of 0.27-0.30 μm and a mechanical convexity of 0.18-0.20 mm, a pass reduction ratio of 36-40% and a finished product pass rolling speed of 160-200 mpm.
6. The method for producing aluminum alloy cold-rolled sheet for power battery side plate of new energy automobile according to claim 1, wherein in the cleaning step, the aluminum coil is subjected to alkali cleaning and water cleaning in a cleaning machine, the free alkalinity in alkali solution is 0.8-1.5 pt, and the temperature of alkali solution is 55-60 ℃.
7. The method for producing the aluminum alloy cold-rolled sheet for the power battery side plate of the new energy automobile according to claim 1, wherein in the cleaning step, 2-5 g/L of alkali liquor cleaning reinforcing agent is added into alkali liquor for alkali cleaning, and the alkali liquor cleaning reinforcing agent consists of the following components in parts by weight: 20-25 parts of sodium hexametaphosphate, 20-25 parts of sodium tripolyphosphate and 8-12 parts of fucose.
8. The method for producing the aluminum alloy cold-rolled sheet for the power battery side plate of the new energy automobile according to claim 7, wherein in the cleaning step, 2-5 g/L of alkali liquor cleaning reinforcing agent is added in alkali liquor for alkali cleaning, and the alkali liquor cleaning reinforcing agent consists of the following components in parts by weight: 22-25 parts of sodium hexametaphosphate, 23-25 parts of sodium tripolyphosphate and 10-12 parts of fucose.
9. The method for producing an aluminum alloy cold-rolled sheet for a power battery side plate of a new energy automobile according to claim 1, wherein in the annealing step, the annealing temperature of the aluminum coil is 330-350 ℃ and the heat preservation time is 3-4 hours.
10. The method for producing the aluminum alloy cold-rolled sheet for the power battery side plate of the new energy automobile according to claim 1, wherein in the step of leveling and laminating, an aluminum coil is cut into a sheet material after being leveled and laminated by a transverse cutting machine, the plastic deformation rate of the aluminum coil is 0.2-0.5%, and the peel strength of a PE film is 35-40 g/25mm.
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