CN1164594A - Method for manufacturing dyeable fine denier polypropylene fibre - Google Patents
Method for manufacturing dyeable fine denier polypropylene fibre Download PDFInfo
- Publication number
- CN1164594A CN1164594A CN 96116348 CN96116348A CN1164594A CN 1164594 A CN1164594 A CN 1164594A CN 96116348 CN96116348 CN 96116348 CN 96116348 A CN96116348 A CN 96116348A CN 1164594 A CN1164594 A CN 1164594A
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- CN
- China
- Prior art keywords
- copolyesters
- fine denier
- glycol
- blend
- spinning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 36
- -1 polypropylene Polymers 0.000 title claims abstract description 30
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 28
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000178 monomer Substances 0.000 claims abstract description 23
- 229920001634 Copolyester Polymers 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 239000000654 additive Substances 0.000 claims abstract description 18
- 230000000996 additive effect Effects 0.000 claims abstract description 18
- 238000004043 dyeing Methods 0.000 claims abstract description 17
- 238000002074 melt spinning Methods 0.000 claims abstract description 10
- 150000001298 alcohols Chemical class 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000005469 granulation Methods 0.000 claims abstract 2
- 230000003179 granulation Effects 0.000 claims abstract 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000004804 winding Methods 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 238000009987 spinning Methods 0.000 abstract description 11
- 230000000704 physical effect Effects 0.000 abstract description 4
- 239000003607 modifier Substances 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 14
- 239000000975 dye Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 230000036314 physical performance Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- VNGOYPQMJFJDLV-UHFFFAOYSA-N dimethyl benzene-1,3-dicarboxylate Chemical compound COC(=O)C1=CC=CC(C(=O)OC)=C1 VNGOYPQMJFJDLV-UHFFFAOYSA-N 0.000 description 1
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Abstract
The present invention relates to a method for making dyeable fire denier polypropylene fibre whose filament size is 1.11-2.22 dtex by using polypropylene resin and dyeing modifier additive and making them pass through such processes of granulation and melt-spinning or pass through the process of direct melt-spinning. Said dyeing modifier additive is made up by using DMT, glycol and monomer A, B and C through copolymerization, in which A is 5-sulfonic acid alkali metal salt dimethyl iso(tere)phthalate, B is dibasic alcohol of C3-C6 and C is polydibasic alcohol type compound. The limiting inherent viscosity [eta] of said copolyester is 0.45-0.60, and its melting point is 200-260 deg.C. The weight percentage of said copolyester in the mixture is 5-15%. Said invention possesses the advantages of that said fibre possesses high dye uptake, good physical properties and spinnability, and its spinning speed can be up to 800-3200 m/min.
Description
The present invention relates to the manufacture method of polypropylene fibre, it is by adding the blend with it of other high polymer, so that the fiber of making has dyeability preferably in the polypropylene resin.
Polypropylene fibre is one of four big synthetic fiber, and its sufficient raw is cheap for manufacturing cost, and fiber then has plurality of advantages such as light specific gravity, warmth retention property are good, intensity height.Particularly in recent years with the appearance of fine denier polypropylene fibers, polypropylene fibre has also had very big development in the application facet of taking textile material.But because polar functionalities not in the big molecule of polypropylene adds that the stereochemical structure of its isotactic makes that big molecule regularity is very high, so that the fibre structure of making is tight, and dyeability is very poor.Usually people adopt Masterbatch to carry out original liquid coloring spinning colored fibre, but it has the diversity of high dyeing flexibility and color not as fiber or fabric printing after all.So improve the dyeability of polypropylene fibre is very active subject of this field always, and has obtained certain achievement so far.As patent US4,520,155, US4,764,551, CN90105404.6, CN92108576.1 and CN93114967.3 etc. have all proposed a kind ofly to carry out melt spinning after will having the additive of accepting the dyestuff ability and the blend of polypropylene resin, the fiber that makes has good dyeability, makes general dyeing method also can be applied to polypropylene fibre or fabric.But all there are some shortcomings more or less in these existent method, or rate of dyeing is not high enough, maybe can't spin fine count fiber, or the too low no industrial value of spinning silk winding speed.
The manufacture method that the purpose of this invention is to provide a kind of dyeable polypropylene fibre, it can be with higher spinning speed spinning fine denier dyeable polypropylene fibre.
The present invention also adopts after polypropylene resin and the blend of dyeing, modifying additive melt spinning to make dyable fine denier polypropylene fibre, it is characterized in that: 1) the described dyeing, modifying additive copolyesters that following monomer and corresponding copolymerization weight ratio form of serving as reasons:
1 part of DMT+A
Ethylene glycol+B 0.65-0.80 part
0.-0.15 part of C is wherein: DMT: A=(95-99): (1-5) (molar percentage)
Ethylene glycol: B=(60-90): (10-40) (molar percentage)
A be between the 5-sulfonic acid alkali metal salts (to) rutgers
B is the dihydroxylic alcohols of C3-C6
C is the poly-dihydric alcohol compounds; 2) inherent viscosity of this copolyesters [η] is 0.45-0.60, and fusing point is (200-260) ℃; 3) percentage by weight of this copolyesters is (5-15) % in the blend.
The spinning process that adopts can be a directly melt spinning under the temperature of (220-260) ℃ of blend, also can earlier blend be carried out melt pelletization, again with melt spinning after the particle drying.Winding speed during method spinning provided by the invention can reach (800-3200) m/min, can spin the fine denier polypropylene fibers of filament number for (1.11-2.22) dtex, and fiber or its fabric can boil under normal pressure with disperse dyes and dye dyeing.
In the present invention, the selected and addition of dyeing, modifying additive determines it is key problem in technology.Phase morphology to blend discovers that additive is to be scattered in equably in the polypropylene continuous phase with decentralized photo, and decentralized photo is spheroidal, and boundary is clear smooth, and two kinds of high polymers present phase-separated state in blend.Along with the increase of additive content, decentralized photo farmland density increases.As seen both compatibilities are not only relevant with the molecular structure of additive, and relevant with the content of additive.The inventor finds that when the content of dyeing, modifying additive in blend described in the present invention surpassed 15% (wt.), dispersed phase size obviously increased, whole system compatibility variation.Thereupon, the also obvious variation of the physical properties such as fracture strength of the spinnability of blend and fiber.
On the other hand, the content of additive obviously has direct influence to the dyeability of fiber.The inventor finds, when the content of this copolyesters in blend during less than 5% (wt.), the dye-uptake of fiber obviously descends.After the content of copolyesters improved, the dye-uptake of fiber also rose thereupon.But after content reached 10% (wt.), the rising that continues the content dye-uptake of raising copolyesters but tended towards stability.Therefore the inventor to think that the content of this copolyesters in blend is from 5% (wt.) to 15% (wt.) feasible, but the suggestion optimum content is that 7% (wt.) is to 10% (wt.).In this scope with existing comparatively ideal fiber dye-uptake, the not adding of reason copolyesters and the physical property of spinnability and fiber is had harmful effect again simultaneously.
Secondly, as the dyeing, modifying additive, the chemical composition of copolyesters and inherent viscosity have very important influence to it and polyacrylic compatibility.In each monomer, in fact A replaces DMT in order to part, makes copolyesters have the characteristic of similar ionomer, has more strengthened intermolecular dipole active force.B then replaces ethylene glycol in order to part, and the introducing of B and C makes copolyesters and polypropylene that more similar structure be arranged.B is the dihydroxylic alcohols of one or more C3-C6 in principle, and C is one or more poly-dihydric alcohol compounds.But the inventor thinks that B preferably takes from one or more compounds in propylene glycol, butanediol, pentanediol or the ethylene glycol; C preferably takes from one or more compounds in polyethylene glycol, polypropylene glycol or the polytetramethylene glycol.
The too high or too low spinnability to blend of the inherent viscosity of copolyesters is all unfavorable, finds that by test 0.45-0.60 is a proper scope.And the increase of monomers B content helps the improvement of spinnability, but the increase of monomers B will make that cost significantly increases, and can obtain spinnability and dyeability preferably equally and add monomer C and suitably reduce monomers B.Wherein the addition of monomer A should be appropriate, will influence spinnability to a certain extent when the mol ratio of A and DMT surpasses 1: 19.
Compared with prior art, because dyeing, modifying additive and the polypropylene selected in the method provided by the invention have good process compatibility.Thereby the fiber that not only makes spinning has higher dye-uptake, also has better spinnability simultaneously, and spinning speed can reach (800-3200) m/min, and fiber has the better physical performance.
To come below that the present invention is further described by a series of embodiment, the present invention not only is confined to cited example certainly.
In an embodiment, the method for testing of dye-uptake and being defined as follows:
Fiber was dyeed 60 minutes down at 100 ℃ with 1% (o.w.f) DISPERSE DYES, and the dyestuff pH value is 4.5-5.0, bath raio 1: 100.Dyeing finishes the back is tested dyeing residual liquid and former dye liquor respectively with spectrophotometer optical density E1 and E0.
Dye-uptake is defined as:
The physical performance data of fiber is tested by FJ 555-86 and FJ 556-86.Embodiment:
Common spinning grade polypropylene resin and dyeing, modifying additive are in ratio blend listed in the table 1, and additive is formed by DMT, ethylene glycol, monomer A, monomers B and monomer C copolymerization, and the composition of this copolyesters and index are also listed as table 1.Blend through double screw extruder in (220-260) ℃ melt pelletization, particle after drying in screw extruder in (260-300) ℃ melt spinning.Spinning silk winding speed is (800-3200) m/min.
Table 1.
Among the embodiment 1-12 of table 1:
| Blend is formed (weight ratio) | Copolyesters is formed and index | |
| The polypropylene copolyesters | A(mol％)B(mol％)C(mol％)[η]Tm(℃) | |
| Embodiment 1 embodiment 2 embodiment 3 embodiment 4 embodiment 5 embodiment 6 embodiment 7 embodiment 8 embodiment 9 embodiment 10 embodiment 11 embodiment 12 embodiment 13 embodiment 14 embodiment 15 embodiment 16 | ????95????5 ????90????10 ????85????15 ????90????10 ????90????10 ????90????10 ????90????10 ????90????10 ????90????10 ????90????10 ????90????10 ????90????10 ????90????10 ????90????10 ????90????10 ????90????10 | ??2.0??????15?????5?????0.500??227 ??2.0??????15?????5?????0.500??227 ??2.0??????15?????5?????0.500??227 ??2.0??????15?????5?????0.518??229 ??3.3??????15?????5?????0.471??221 ??4.6??????15?????5?????0.462??217 ??2.0??????10?????5?????0.533??237 ??2.0??????15?????0?????0.514??227 ??2.0??????30?????0?????0.517??206 ??2.0??????40?????0?????0.537??204 ??2.0??????15?????10????0.517??207 ??2.0??????15?????15????0.536??212 ??2.0??????15?????5?????0.516??226 ??2.0??????17?????5?????0.463??216 ??2.0??????12?????5?????0.536??223 ??2.0??????15?????5?????0.528??214 |
Monomer A is a 5-sodium sulfonate dimethyl isophthalate, and monomers B is a butanediol, and monomer C is a polyethylene glycol.Among the embodiment 13:
Monomer A is a 5-sodium sulfonate dimethyl terephthalate (DMT), and monomers B and C are with embodiment 1-12.Among the embodiment 14: monomers B is 1, the 1-propylene glycol, and monomer A and C are with embodiment 1-12.Among the embodiment 15:
Monomers B is 1, the 6-hexylene glycol, and monomer A and C are with embodiment 1-12.Among the embodiment 16:
Monomer C is the fourth polyglycols, and monomer A and B are with embodiment 1-12.
The fiber physical property and the dyeability of each embodiment gained see Table 2.
Table 2.
| Filament number fracture strength extension at break (dtex) is (%) (CN/dtex) | Dye-uptake (%) (disperse red (3B)) | |
| Embodiment 1 embodiment 2 embodiment 3 embodiment 4 embodiment 5 embodiment 6 embodiment 7 embodiment 8 embodiment 9 embodiment 10 embodiment 11 embodiment 12 embodiment 13 embodiment 14 embodiment 15 embodiment 16 | ????1.78????2.97????87.8 ????2.03????2.97????93.8 ????2.81????2.08????78.0 ????2.04????3.90????58.5 ????2.09????3.60????78.8 ????2.08????3.20????42.5 ????1.83????4.20????28.6 ????1.84????4.40????58.7 ????1.82????3.50????78.8 ????1.52????3.29????78.6 ????1.91????3.80????28.5 ????1.87????3.20????22.8 ????1.87????3.80????62.5 ????1.87????3.51????28.5 ????1.86????3.31????25.8 ????1.84????3.50????24.8 | ????70.2 ????82.2 ????88.2 ????82.2 ????77.1 ????80.8 ????79.2 ????80.6 ????82.2 ????86.5 ????79.2 ????83.4 ????77.1 ????80.6 ????83.4 ????81.6 |
Claims (4)
1, a kind of employing polypropylene resin and the blend of dyeing, modifying additive, through granulation, melt spinning, or directly make the method for dyable fine denier polypropylene fibre through melt spinning, it is characterized in that: 1) the described dyeing, modifying additive copolyesters that following monomer and corresponding copolymerization weight ratio form of serving as reasons:
1 part of DMT+A
Ethylene glycol+B 0.65-0.80 part
0.-0.15 part of C
Wherein: DMT: A=(95-99): (1-5) (molar percentage)
Ethylene glycol: B=(60-90): (10-40) (molar percentage)
A be between the 5-sulfonic acid alkali metal salts (to) rutgers
B is the dihydroxylic alcohols of C3-C6
C is the poly-dihydric alcohol compounds; 2) inherent viscosity of this copolyesters [η] is 0.45-0.60, and fusing point is (200-260) ℃; 3) percentage by weight of this copolyesters is (5-15) % in the blend.
2, the method for manufacturing dyable fine denier polypropylene fibre according to claim 1 is characterized in that:
B is one or more compounds in propylene glycol, butanediol, pentanediol or the ethylene glycol;
C is one or more compounds in polyethylene glycol, polypropylene glycol or the polytetramethylene glycol.
3, the method for manufacturing dyable fine denier polypropylene fibre according to claim 1 is characterized in that the percentage by weight of this copolyesters is (7-10) % in the blend.
4, according to the method for claim 1,2 or 3 described manufacturing dyable fine denier polypropylene fibres, the temperature that it is characterized in that melt spinning is (260-300) ℃, and winding speed is (800-3200) m/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96116348A CN1064416C (en) | 1996-05-02 | 1996-05-02 | Method for manufacturing dyeable fine denier polypropylene fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96116348A CN1064416C (en) | 1996-05-02 | 1996-05-02 | Method for manufacturing dyeable fine denier polypropylene fibre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1164594A true CN1164594A (en) | 1997-11-12 |
| CN1064416C CN1064416C (en) | 2001-04-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96116348A Expired - Fee Related CN1064416C (en) | 1996-05-02 | 1996-05-02 | Method for manufacturing dyeable fine denier polypropylene fibre |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1064416C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1068640C (en) * | 1997-09-24 | 2001-07-18 | 山东虎山实业集团有限公司 | Process for producing fine denier polypropylene fiber short-staple |
| CN101812741A (en) * | 2009-02-20 | 2010-08-25 | 东丽纤维研究所（中国）有限公司 | Polypropylene alloy fiber |
| CN106868887A (en) * | 2017-02-10 | 2017-06-20 | 绍兴喜能纺织科技有限公司 | Polypropylene fiber coloring treatment method |
| CN107502983A (en) * | 2017-07-28 | 2017-12-22 | 阳信瑞鑫集团有限公司 | A kind of polypropylene fibre can dye the production technology of spinning |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101333691B (en) * | 2008-07-29 | 2010-06-09 | 浙江四通化纤有限公司 | Nylon-like modified fiber that can be dyed polypropylene |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0651906B2 (en) * | 1985-12-25 | 1994-07-06 | キヤノン株式会社 | Deposited film formation method |
| CN1030620C (en) * | 1992-09-29 | 1996-01-03 | 中国纺织大学 | Polypropylene fine denier and superfine denier blend resin, manufacture and application |
| TW268052B (en) * | 1993-04-15 | 1996-01-11 | Ciba Geigy | |
| CN1036798C (en) * | 1993-12-01 | 1997-12-24 | 北京服装学院 | Method for mfg. disperse dye dyeable polypropylene fibre |
| AU690997B2 (en) * | 1994-06-07 | 1998-05-07 | Equistar Chemicals, Lp | Dyeable polyolefin compositions and method |
| JP4212528B2 (en) * | 2004-08-09 | 2009-01-21 | 三洋電機株式会社 | Image forming apparatus |
| JP4100449B1 (en) * | 2007-01-26 | 2008-06-11 | いすゞ自動車株式会社 | Exhaust gas purification system control method and exhaust gas purification system |
-
1996
- 1996-05-02 CN CN96116348A patent/CN1064416C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1068640C (en) * | 1997-09-24 | 2001-07-18 | 山东虎山实业集团有限公司 | Process for producing fine denier polypropylene fiber short-staple |
| CN101812741A (en) * | 2009-02-20 | 2010-08-25 | 东丽纤维研究所（中国）有限公司 | Polypropylene alloy fiber |
| CN106868887A (en) * | 2017-02-10 | 2017-06-20 | 绍兴喜能纺织科技有限公司 | Polypropylene fiber coloring treatment method |
| CN106868887B (en) * | 2017-02-10 | 2019-04-05 | 绍兴喜能纺织科技有限公司 | Polypropylene fiber coloring treatment method |
| CN107502983A (en) * | 2017-07-28 | 2017-12-22 | 阳信瑞鑫集团有限公司 | A kind of polypropylene fibre can dye the production technology of spinning |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1064416C (en) | 2001-04-11 |
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