CN1164255C - Use of DL-cystine, DL-cysteine and their salt in dyeing and perming hair - Google Patents
Use of DL-cystine, DL-cysteine and their salt in dyeing and perming hair Download PDFInfo
- Publication number
- CN1164255C CN1164255C CNB011273283A CN01127328A CN1164255C CN 1164255 C CN1164255 C CN 1164255C CN B011273283 A CNB011273283 A CN B011273283A CN 01127328 A CN01127328 A CN 01127328A CN 1164255 C CN1164255 C CN 1164255C
- Authority
- CN
- China
- Prior art keywords
- hair
- salt
- cysteine
- dyeing
- waving
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XUJNEKJLAYXESH-UHFFFAOYSA-N Cysteine Chemical compound SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 229940078469 dl- cysteine Drugs 0.000 title claims abstract description 16
- 238000004043 dyeing Methods 0.000 title claims abstract description 16
- 150000003839 salts Chemical class 0.000 title claims abstract description 15
- LEVWYRKDKASIDU-UHFFFAOYSA-N cystine Chemical compound OC(=O)C(N)CSSCC(N)C(O)=O LEVWYRKDKASIDU-UHFFFAOYSA-N 0.000 title abstract 3
- 239000000118 hair dye Substances 0.000 claims abstract description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 10
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- -1 alkyl sulfate salt Chemical class 0.000 claims description 5
- 239000002480 mineral oil Substances 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 4
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 4
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 4
- 239000008213 purified water Substances 0.000 claims description 4
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 3
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 3
- 239000001587 sorbitan monostearate Substances 0.000 claims description 3
- 235000011076 sorbitan monostearate Nutrition 0.000 claims description 3
- 229940035048 sorbitan monostearate Drugs 0.000 claims description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 230000007886 mutagenicity Effects 0.000 abstract description 2
- 231100000299 mutagenicity Toxicity 0.000 abstract description 2
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000003700 hair damage Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 230000000638 stimulation Effects 0.000 abstract 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 206010002198 Anaphylactic reaction Diseases 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 230000036783 anaphylactic response Effects 0.000 description 2
- 208000003455 anaphylaxis Diseases 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 235000004515 gallic acid Nutrition 0.000 description 2
- 229940071826 hydroxyethyl cellulose Drugs 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 229910000358 iron sulfate Inorganic materials 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 239000002674 ointment Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 description 2
- 229960001763 zinc sulfate Drugs 0.000 description 2
- 206010049865 Achromotrichia acquired Diseases 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- LEVWYRKDKASIDU-IMJSIDKUSA-N L-cystine Chemical compound [O-]C(=O)[C@@H]([NH3+])CSSC[C@H]([NH3+])C([O-])=O LEVWYRKDKASIDU-IMJSIDKUSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 230000003648 hair appearance Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
The present invention relates to DL-cystine, DL-cysteine and salt thereof for hair dyeing and waving. The present invention has the advantages of no stimulation, no hypersensitization, no mutagenicity, no peculiar smell and no hair damage. The DL-cystine, DL-cysteine and salt thereof achieve the effects of good hair-dyeing firmness and high natural light when used as hair dye, achieve the effects of good hair curliness, durability of the wavily curled hair and natural lustre of the hair when used as a hair-waving agent (cold waving liquid), and achieve the effects of natural lustre, durability of the hairstyle and capability of once completing hair dyeing and waving in two hours when used as a composition for hair dyeing and waving.
Description
Technical field
The present invention relates to a kind of DL-cysteine or its salt, particularly relate to a kind of DL-cysteine or the application of its salt in hair dyeing.
Background technology
The p-phenylenediamine (PPD) of the hair dyeing product overwhelming majority employing chemosynthesis of selling on the market at present, and other band benzene ring type compounds are as stain.Quantity research and report prove greatly: p-phenylenediamine (PPD) and other band benzene ring type compounds have zest, cause anaphylaxis skin, and easily by skin absorbs, the meeting accumulate poisoning, and can bring out various cancers.Safety issue about hair dyeing product more and more causes people's attention.
Summary of the invention
The purpose of this invention is to provide a kind of DL-cysteine or its salt and it is used for hair dyeing, can overcome the above-mentioned shortcoming of prior art.
DL-cysteine or its salt are used for hair dyeing.
The present invention is a Reducing agent with DL-cysteine or its salt, and the cystine linkage-S-S-that forms in the hard hair keratin protein chain is reduced into-SH, unclamps its tight structure to a certain extent, and the hair scale sheet is opened, and helps the infiltration of hair-dyeing agent.Advantage of the present invention is that nonirritant, nothing cause anaphylaxis, do not have mutagenicity, are as good as stink, do not damage hair quality.Make hair dye with DL-cysteine or its salt, the hair dyeing fastness is good, naturally light.
The specific embodiment
Take by weighing 10 kilograms of DL-cysteine hydrochlorates, 4 kilograms of ethanolamine, 2 kilograms of aliphatic alcohol, 3 kilograms of white mineral oils, 1 kilogram of fatty alcohol-polyoxyethylene ether, 3 kilograms of polyoxyethylene sorbitan monostearate, 1 kilogram of alkyl sulfate salt, 3 kilograms of glyceryl monostearates, 3 kilograms of anhydrous sorbitol monostearates, 70 kilograms of Purified Waters mix stirring with them, make the 1st dose of unguentum; Take by weighing 5 kilograms of slaines (iron sulfate, zinc sulfate or copper sulfate) again, 4 kilograms of carboxymethyl celluloses (or hydroxyethyl-cellulose), 91 kilograms of Purified Waters are made into second dose of colloidal sol; Take by weighing 6 kilograms of gallic acids again, 4 kilograms of ethanolamine, 3 kilograms of white mineral oils, 1 kilogram of fatty alcohol-polyoxyethylene ether, 2 kilograms of polyoxyethylene sorbitan monostearate, 3 kilograms of glyceryl monostearates, stearic 3 kilograms of anhydrous sorbitol list, 76 kilograms of Purified Waters mix stirring with them, make the 3rd dose.During hair dyeing, the moistening hair of first water, combing hair removes excessive moisture with the towel stranding, is as the criterion not drip.The 1st dose is applied on the hair again, rubs evenly with hands, poliosis need be rubbed repeatedly than many places, makes unguentum be deep into root of hair, puts on plastic cap then and keeps 20～30 minutes.Take plastic cap, the 2nd dose be applied on the hair, with plastic comb repeatedly before and after combing, until the 2nd dose is smeared evenly.Put on plastic cap then, keep taking plastic cap after 15～30 minutes, clean with warm water washing, wipe excessive moisture with towel or absorbent paper.At last, again the 3rd dose is applied on the hair,, is coated in equably on the hair until the 3rd dose, stop after 10～20 minutes, totally can dye beautiful natural color and luster with warm water washing with combing repeatedly before and after the plastic comb.
The each component that present embodiment is the 1st dose and the percetage by weight scope of employing are respectively: DL-cysteine or its salt 5-15, ethanolamine 3-5, aliphatic alcohol 1-3, white mineral oil 1-5, fatty alcohol-polyoxyethylene ether 0.1-2, polyoxyethylene sorbitan monostearate 0.5-5, alkyl sulfate salt 0.5-2, glyceryl monostearate 0.5-5, sorbitan monostearate 0.5-5, all the other are Purified Water.The adoptable percetage by weight scope of the 2nd dose each component is respectively: slaine (iron sulfate, zinc sulfate or copper sulfate) 2～10, and carboxymethyl cellulose (or hydroxyethyl-cellulose) 2～5, all the other are Purified Water.The adoptable percetage by weight scope of the 3rd dose each component is respectively: gallic acid 3～10, ethanolamine 2～6, aliphatic alcohol 1～4, white mineral oil 1～5, fatty alcohol-polyoxyethylene ether 0.2～2, polyoxyethylene sorbitol acid anhydride monostearate 0.5～3, glyceryl monostearate 0.5～5, sorbitan monostearate 0.5～5, all the other are Purified Water.
Claims (2)
1, DL-cysteine or its salt are used for hair dyeing.
2, DL-cysteine as claimed in claim 1 or its salt are used for hair dyeing, it is characterized in that the hair dye of described hair dyeing employing based on DL-cysteine or its salt, the percetage by weight scope of each component that this hair dye contains and employing is respectively: DL-cysteine or its salt 5-15, ethanolamine 3-5, aliphatic alcohol 1-3, white mineral oil 1-5, fatty alcohol-polyoxyethylene ether 0.1-2, polyoxyethylene sorbitan monostearate 0.5-5, alkyl sulfate salt 0.5-2, glyceryl monostearate 0.5-5, sorbitan monostearate 0.5-5, all the other are Purified Water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011273283A CN1164255C (en) | 2001-08-15 | 2001-08-15 | Use of DL-cystine, DL-cysteine and their salt in dyeing and perming hair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011273283A CN1164255C (en) | 2001-08-15 | 2001-08-15 | Use of DL-cystine, DL-cysteine and their salt in dyeing and perming hair |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1401310A CN1401310A (en) | 2003-03-12 |
| CN1164255C true CN1164255C (en) | 2004-09-01 |
Family
ID=4667296
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011273283A Expired - Fee Related CN1164255C (en) | 2001-08-15 | 2001-08-15 | Use of DL-cystine, DL-cysteine and their salt in dyeing and perming hair |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1164255C (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010094207A1 (en) | 2009-02-20 | 2010-08-26 | 浙江养生堂天然药物研究所有限公司 | A mordant and a hair dyeing composition comprising the said mordant |
| CN101812246B (en) * | 2009-02-20 | 2014-10-01 | 浙江养生堂天然药物研究所有限公司 | Mordant and hair dyeing product containing same |
| CN101879135B (en) * | 2009-11-12 | 2013-03-06 | 北京世纪博康医药科技有限公司 | Curcuma plant hair dye |
| CN101869536B (en) * | 2010-06-23 | 2012-08-29 | 刘玉勤 | Gallic acid hair dyes and preparation method and application thereof |
| CN102397170A (en) * | 2010-09-17 | 2012-04-04 | 庄国升 | Plant hair dye and method for dyeing hair by using same |
| CN105769596B (en) * | 2014-12-15 | 2018-11-27 | 中国中化股份有限公司 | A kind of hair dyeing synergist and its preparation and application |
| CN105748325A (en) * | 2016-03-10 | 2016-07-13 | 蚌埠团结日用化学有限公司 | Auxiliaries for hair perming and hair dyeing and preparation method thereof |
| CN108743429A (en) * | 2018-06-21 | 2018-11-06 | 王庆仙 | Settle environmentally friendly blanching agent for permanent hair waving and its application method at one go |
| KR102351627B1 (en) | 2019-07-02 | 2022-01-18 | 한국과학기술원 | Cosmetic composition for dyeing hair and method of dyeing using the same |
-
2001
- 2001-08-15 CN CNB011273283A patent/CN1164255C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1401310A (en) | 2003-03-12 |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20040901 Termination date: 20140815 |
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| EXPY | Termination of patent right or utility model |